Using An Organic Precursor (e.g., Propane, Metal-organic, Mocvd, Movpe) Patents (Class 117/104)
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Patent number: 5772760Abstract: A method and system for manufacturing nanocrystalline diamond film on a substrate such as field emission tips. The method involves forming a carbonaceous vapor, providing a gas stream of argon, hydrocarbon and possibly hydrogen, and combining the gas with the carbonaceous vapor, passing the combined carbonaceous vapor and gas carrier stream into a chamber, forming a plasma in the chamber causing fragmentation of the carbonaceous vapor and deposition of a diamond film on the field emission tip.Type: GrantFiled: October 11, 1995Date of Patent: June 30, 1998Assignee: The University Of ChicagoInventors: Dieter M. Gruen, Alan R. Krauss
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Patent number: 5767301Abstract: A method is provided for applying chemical vapor deposition (CVD) copper (Cu) to integrated circuit substrates using a Cu(hfac)(ligand) precursor with a silylolefin ligand including combinations of C1-C8 alkyl groups with at least one C2-C8 alkyloxy group. The alkyloxy groups include, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, and aryloxy, while the alkyl groups include methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, and aryl. The oxygen atoms of the alkyloxy groups, and the long carbon chains of both the alkyl and alkyloxy groups, increase the stability of the precursor by contributing electrons to the Cu(hfac) complex. The improved bond helps insure that the ligand separates from the (hfac)Cu complex at consistent temperatures when Cu is to be deposited. Combinations of alkyloxy and alkyl groups allow the molecular weight of the precursor to be manipulated so that the volatility of the precursor is adjustable for specific process scenarios.Type: GrantFiled: January 21, 1997Date of Patent: June 16, 1998Assignees: Sharp Microelectronics Technology, Inc., Sharp Kabushiki KaishaInventors: Yoshihide Senzaki, Masato Kobayashi, Lawrence J. Charneski, Tue Nguyen
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Patent number: 5755879Abstract: A method is presented to manufacture substrates for growing monocrystalline diamond films by chemical vapor deposition (CVD) on large area at low cost. The substrate materials are either Pt or its alloys, which have been subject to a single or multiple cycle of cleaning, roller press, and high temperature annealing processes to make the thickness of the substrate materials to 0.5 mm or less, or most preferably to 0.2 mm or less, so that either (111) crystal surfaces or inclined crystal surfaces with angular deviations within .+-.10 degrees from (111), or both, appear on the entire surfaces or at least part of the surfaces of the substrates. The annealing is carried out at a temperature above 800.degree. C. The present invention will make it possible to markedly improve various characteristics of diamond films, and hence put them into practical use.Type: GrantFiled: November 17, 1995Date of Patent: May 26, 1998Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Yoshihiro Shintani, Takeshi Tachibana, Kozo Nishimura, Koichi Miyata, Yoshihiro Yokota, Koji Kobashi
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Patent number: 5753039Abstract: An object formed of a semiconductor is heated to and kept at such a temperature that a semiconductor crystal formed of a II-VI Group compound semiconductor mainly containing Zn and Se can be grown. A molecular beam including elements constituting the II-VI Group compound semiconductor mainly containing Zn and Se is irradiated onto the heated object, and a gas beam composed of a nitrogen molecule being in a ground electronic state and having a gas pressure of not less than 3.times.10.sup.-5 Torr, to form a p-type semiconductor crystal on the object.Type: GrantFiled: November 28, 1995Date of Patent: May 19, 1998Assignee: Sanyo Electric Co., Ltd.Inventors: Yuji Hishida, Tomoyuki Yoshie
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Patent number: 5741360Abstract: In a method of selectively growing a crystal of a compound semiconductor layer which is composed of gallium and arsenic, a selective growth is selectively carried out on a substrate by using a combination of metallic gallium and a reactive gas, such as trisdimethylminoarsine, which includes a metallic compound of arsenic specified by at least one amine. The combination may includes organometallic gallium, such as trimethylgallium, triethylgallium instead of the metallic gallium. Such a combination serves to selectively deposit the compound semiconductor layer only on an exposed portion uncovered with a mask. Any other compound semiconductor layer may be selectively deposited on the exposed portion. The exposed portion may be composed of GaAs, AlGaAs, or InGaAs.Type: GrantFiled: August 11, 1995Date of Patent: April 21, 1998Assignee: Optoelectronics Technology Research CorporationInventors: Shigeo Goto, Yasuhiko Nomura, Yoshitaka Morishita, Seikoh Yoshida, Masahiro Sasaki
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Patent number: 5738721Abstract: A chemical composition consists essentially ((t-amyl)GaS).sub.4. The chemical composition can be employed as a liquid precursor for metal organic chemical vapor deposition to thereby form a cubic-phase passivating/buffer film, such as gallium sulphide.Type: GrantFiled: April 6, 1995Date of Patent: April 14, 1998Assignees: President and Fellows of Harvard College, Triquint Semiconductor, Inc.Inventors: Andrew R. Barron, Michael B. Power, Andrew N. MacInnes
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Patent number: 5728215Abstract: A method for forming a film by selective area growth by MDCVD technique includes forming a mask on a semiconductor substrate having a (100) plane, the mask having a mask opening to selectively growing a compound semiconductor layer, and a slit which is narrower than the mask opening in width and controls the growth rate of the compound semiconductor layer at the mask opening; and selectively growing the compound semiconductor layer at a growth rate which is on the mask in the mask opening and the slit.Type: GrantFiled: November 14, 1995Date of Patent: March 17, 1998Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Takushi Itagaki, Masayoshi Takemi, Norio Hayafuji
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Patent number: 5718761Abstract: A method of forming a crystalline compound semiconductor film comprises introducing into a crystal forming space housing a substrate on which a non-nucleation surface (S.sub.NDS) having a smaller nucleation density and a nucleation surface (S.sub.NDL) having a fine surface area sufficient for crystal growth only from a single nucleus and having a larger nucleation density (ND.sub.L) than the nucleation density (NDs) of the non-nucleation surface (S.sub.NDS) are arranged adjacent to each other an organometallic compound (VI) for supplying an element belonging to the group VI of Periodic Table represented by the general formula R.sub.1 --X.sub.n --R.sub.2 wherein n is an integer of 2 or more; R.sub.1 and R.sub.Type: GrantFiled: April 17, 1996Date of Patent: February 17, 1998Assignee: Canon Kabushiki KaishaInventors: Hiroyuki Tokunaga, Jun-ichi Hanna, Isamu Shimizu
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Patent number: 5667586Abstract: A structure is fabricated comprising a substrate, a dielectric layer formed over the substrate, and a single crystal layer of a compound formed over the dielectric layer. The single crystal layer is formed by the chemical reaction of at least a first element with an initial single crystal layer of a second element on the dielectric layer having an initial thickness of about 100 to about 10,000 angstroms.According to another aspect, a carbide single crystal layer is provided on a substrate by depositing carbon from a solid carbon source at a low rate and low temperature, followed by reacting the carbon with the underlying layer to convert it to the carbide.Type: GrantFiled: April 1, 1996Date of Patent: September 16, 1997Assignee: International Business Machines CorporationInventors: Bruce Allen Ek, Stephen McConnell Gates, Fernando Jose Guarin, Subramanian Srikanteswara Iyer, Adrian Roger Powell
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Patent number: 5663391Abstract: A process for producing a .beta. copper diketone complex which consists of the steps: (a) mixing and reacting Cu.sub.2 O, 1,1,1,5,5,5-Hexafluoro-2, 4-pentanedione, and an additional cuprous L, an electronic donator; and (b) dehydrating the crude material, which is performed at the same time and/or right after the reaction in step (a).Type: GrantFiled: March 6, 1996Date of Patent: September 2, 1997Assignee: Tri-Chemical Laboratory, Inc.Inventors: Hideaki Machida, Hiroshi Kokubun
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Patent number: 5660628Abstract: There is provided a method for suppressing generation of cracks or damages on a compound semiconductor epitaxial wafer during an epitaxial growth due to growth of an epitaxial layer on the rear surface at the edge of the epitaxial layer which is located at the upstream side of the flow of the source gas. In manufacturing a semiconductor wafer by growing a single crystal semiconductor epitaxial layer having a zinc blend structure on a single crystal semiconductor substrate having a zinc blend structure, the surface of the single crystal semiconductor substrate has (100) surface orientation having an off angle and a source gas is supplied in the direction of the off angle or in a direction at 30.degree. or less to the direction at 180.degree. thereto.Type: GrantFiled: August 18, 1994Date of Patent: August 26, 1997Assignee: Mitsubishi Kasei Corp.Inventors: Tadashige Sato, Hitora Takahashi
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Patent number: 5656540Abstract: On a surface of a p-type GaAs (111)B substrate 11, a mesa groove is formed along a [211]A direction. TDMAAs as a group V material and TMGa as a group III material are supplied at 8.times.10.sup.-3 Pa and 8.times.10.sup.-4 Pa, respectively, to grow n-type GaAs 13 dominantly on a side surface of a mesa 12. Subsequently, the group V material is changed to metal As. As.sub.4 and MAGa are supplied at 5.times.10.sup.-3 Pa and 8.times.10.sup.-4 Pa, respectively, to grow p-type GaAs 14 only on a side surface of the GaAs 13. Then, the group V material is again changed to TDMAAs. TDMAAs and TMGa are supplied both at 8.times.10.sup.-4 Pa to grow p-type GaAs 15.Type: GrantFiled: March 28, 1995Date of Patent: August 12, 1997Assignee: Optoelectronics Technology Research CorporationInventors: Yasuhiko Nomura, Shigeo Goto, Yoshitaka Morishita
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Patent number: 5653798Abstract: A substrate for the growth of monocrystalline .beta.-SiC is formed by providing a body of monocrystalline hexagonal material having a planar surface with a lattice parameter that is within .+-.5% of the lattice parameter of 6H.alpha.-SiC in the basal plane and growing a body of monocrystalline cubic material on the surface to provide a planar cubic material surface that is without grain boundaries, subgrain boundaries, double positioning boundaries, and pits. The cubic material, for example TiC, ZrC, HfC, or TiN, has a rock salt structure and a lattice parameter within .+-.5% of the lattice parameter of .beta.-SiC. Monocrystalline .beta.-SiC can be nucleated and grown on the surface of the cubic material.Type: GrantFiled: June 7, 1995Date of Patent: August 5, 1997Assignee: Oregon Graduate Institute of Science and TechnologyInventors: James D. Parsons, Ajay Kumar Chaddha, Her Song Chen, Jin Wu
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Patent number: 5653952Abstract: A modified process for synthesizing diamond having developed by further improving a process of diamond synthesis based on combustion method, which provides diamond grains 1.5 mm or larger in crystal diameter at good economy. The process comprises burying one or two or more seed crystal diamond grain(s) 2 into the surface of a substrate 1, and striking a combustion flame on said seed crystal diamond grain(s) 2 while cooling the substrate 1 to thereby allow diamond to grow on the seed crystal diamond 2 into a larger diamond grain.Type: GrantFiled: May 9, 1994Date of Patent: August 5, 1997Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Tomio Suzuki, Yoshiaki Morinishi
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Patent number: 5648114Abstract: A substrate is prebaked in an oxygen furnace. A thin film of layered superlattice oxide is formed on the substrate by a chemical vapor deposition process. The film is RTP baked to provide grains with a mixed phase of A-axis and C-axis orientation. The film may be treated by ion implantation prior to the RTP bake and oxygen furnace annealed after the RTP bake. An electrode is deposited on the layered superlattice thin film and then the film and electrode are oxygen furnace annealed.Type: GrantFiled: July 12, 1993Date of Patent: July 15, 1997Assignees: Symetrix Corporation, Olympus Optical Co., Ltd.Inventors: Carlos A. Paz De Araujo, Hitoshi Watanabe, Michael C. Scott, Takashi Mihara
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Patent number: 5628824Abstract: The deposition of high quality diamond films at high linear growth rates and substrate temperatures for microwave-plasma chemical vapor deposition is disclosed. The linear growth rate achieved for this process is generally greater than 50 .mu.m/hr for high quality films, as compared to rates of less than 5 .mu.m/hr generally reported for MPCVD processes.Type: GrantFiled: March 16, 1995Date of Patent: May 13, 1997Assignee: The University of Alabama at Birmingham Research FoundationInventors: Yogesh K. Vohra, Thomas S. McCauley
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Patent number: 5622559Abstract: The vapor phase growth method of the group III-V compound semiconductor thin-film, using hydrides and organic metals containing no halogen elements as a raw material for the growth, is disclosed. The method is carried out by alternately introducing group III organic metals raw material gas as well as halides gas and/or halogens gas into a growth chamber, and also by repeating the introducing to grow a thin-film. In accordance with the present invention, it is possible to obtain such high-quality crystal growth as the planarization of hetero junction interface, the improvement of surface morphology or facet, and no deposit of polycrystals on the mask in a wide range.Type: GrantFiled: June 1, 1993Date of Patent: April 22, 1997Assignee: Mitsubishi Chemical CorporationInventors: Hideki Goto, Katsushi Fujii, Kenji Shimoyama
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Patent number: 5616178Abstract: A method for growth of II-VI compound semiconductors grows a p-type II-VI compound semiconductor such as a p-type ZnSe by vapor deposition such as metallorganic chemical vapor deposition and molecular beam epitaxy using gaseous materials. The method uses as a p-type dopant an organic compound including at least one nitrogen atom and at least two groups of atoms each having a molecular weight larger than 12 and both combined with the nitrogen atom. One of such organic compounds is di-isopropylamine.Type: GrantFiled: May 31, 1995Date of Patent: April 1, 1997Assignee: Sony CorporationInventors: Atsushi Toda, Daisuke Imanishi
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Patent number: 5604151Abstract: .beta.-silicon carbide which is optically transmitting in the visible and infrared regions is produced by chemical vapor deposition. Deposition conditions are temperatures within a 1400.degree.-1500.degree. C. range, pressure 50 torr or less, H.sub.2 /methyltrichlorosilane molar ratios of 4-30 and a deposition rate of 1 .mu.m or less.Type: GrantFiled: May 11, 1995Date of Patent: February 18, 1997Assignee: CVD, IncorporatedInventors: Jitendra S. Goela, Lee E. Burns, Raymond L. Taylor
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Patent number: 5603764Abstract: A process for crystal growth of III-V group compound semiconductor, which comprises pyrolyzing, in a gas phase, a material consisting of an organometallic compound and/or a hydride in the presence of an organic compound containing an oxygen atom-carbon atom direct bond, used as a dopant to grow a III-V group compound semiconductor crystal layer containing at least aluminum, of high electric resistance. Said process can grow a compound semiconductor layer of high electric resistance by the use of a dopant which enables the independent controls of oxygen concentration and aluminum concentration and which has a small effect of oxygen remaining.Type: GrantFiled: January 5, 1995Date of Patent: February 18, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshinobu Matsuda, Masahiko Hata, Noboru Fukuhara, Toshio Ishihara
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Patent number: 5597411Abstract: A method of growing an epitaxial like, single crystal, superconducting film by promoting the epitaxial-like growth of film from a single nucleation site in deference to substantially all other nucleation sites on the substrate. The present invention contemplates the use of a mask to systematically expose sections of the substrate to the deposition apparatus. This mask may include an adjustable or fixed aperture and is manipulated as herein described to systematically expose areas of the substrate to the deposition apparatus.Type: GrantFiled: February 19, 1991Date of Patent: January 28, 1997Assignee: Energy Conversion Devices, Inc.Inventors: Helmut Fritzsche, Stanford R. Ovshinsky, Rosa Young
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Patent number: 5591260Abstract: The invention provides a method for growing GaAs crystals wherein GaAs crystal growth is carried out by means of an equipment by which Indium containing crystals were grown before carrying out the GaAs crystal growth, and the GaAs crystal growth is caused by thermal organic metal decomposition technique using trimethyl gallium as a source of gallium (Ga).Type: GrantFiled: September 9, 1994Date of Patent: January 7, 1997Assignee: NEC CorporationInventor: Tadahiko Kishi
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Patent number: 5587013Abstract: A flat free-standing diamond film is produced by growing alternately at least one pair of a potential-concave diamond layer and a potential-convex diamond layer on a non-diamond substrate and eliminating the substrate. The potential-concave films are made by a CVD method under a condition (b), which is characterized by of a substrate temperature of 880.degree. C. to 950.degree. C. and a hydrocarbon ratio of 2.5 vol % to 3.5 vol %. The potential-convex films are made by a CVD method under the condition (a) which is charcterized by of a substrate temperature of 800.degree. C. to 850.degree. C. and a hydrocarbon ratio of 0.5 vol % to 1.5 vol %. The condition (a) can make a potential-convex film of a good crystal quality in spite of a slow deposition speed. It is preferable to employ an assembly of thinner potential-convex films and thicker potential-concave films to curtail the total time of synthesis.Type: GrantFiled: January 27, 1995Date of Patent: December 24, 1996Assignee: Sumitomo Electric Industries, Ltd.Inventors: Akihiko Ikegaya, Keiichiro Tanabe, Naoji Fujimori
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Patent number: 5580382Abstract: An process for efficient controlled N-type silicon doping of Group III-V materials. Through the present invention silicon may be introduced into Group III-V materials at incorporation efficiencies in excess of 10.sup.-4. In a preferred embodiment doping with silicon tetrabromide attains incorporation efficiencies of approximately 0.37. Silicon incorporation efficiencies of approximately 1 should be obtained using silicon tetraiodide. The silicon dopant sources of the present invention may be used to accurately selectively produce net electron concentrations varying from approximately 1.times.10.sup.16 to 1.2.times.10.sup.20 cm.sup.-3. Favorable room temperature vapor pressures of the dopants used in accordance with the present invention allow for production of abrupt doping profiles. Additionally, high photoluminescence peak values, and low contact and sheet resistances are obtained through the present invention.Type: GrantFiled: March 27, 1995Date of Patent: December 3, 1996Assignee: Board of Trustees of the University of IllinoisInventors: Steven L. Jackson, Gregory E. Stillman
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Patent number: 5554220Abstract: In a method using organic vapor phase deposition (OCPD), for the growth of thin films of optically nonlinear organic salts, a volatile precursor of each component of the salt is carried as a vapor to a hot-wall reaction chamber by independently controlled streams of carrier gas. The components react to form a polycrystalline thin film on substrates of glass and gold. Excess reactants and reaction products are purged from the system by the carrier gas. For example, the method provides the growth of polycrystalline, optically nonlinear thin films of 4'-dimethylamino-N-methyl-4-stilbazolium tosylate (DAST) with >95% purity.Type: GrantFiled: May 19, 1995Date of Patent: September 10, 1996Assignee: The Trustees of Princeton UniversityInventors: Stephen R. Forrest, Vladimir S. Ban, Paul E. Burrows, Jeffrey Schwartz
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Patent number: 5525538Abstract: An amorphous compound is changed to single crystal structure by heating at an elevated temperature in an inert atmosphere or in an atmosphere of a forming gas, the amorphous compound is composed of at least one Group III-A element of the Periodic Table and at least one Group V-A element, the amorphous compound having an excess over stoichiometric amount of at least one Group V-A element. The single crystal phase compound, intrinsically doped with at least one element from Group V-A, has the properties of high conductivity for a semiconductor without using any extrinsic dopant and a non-alloyed ohmic contact with a metal.Type: GrantFiled: March 8, 1995Date of Patent: June 11, 1996Assignee: The United States of America as represented by the Secretary of the NavyInventors: Mark E. Twigg, Mohammad Fatemi, Bijan Tadayon
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Patent number: 5497726Abstract: A surface acoustic wave element has a diamond layer, a piezoelectric thin film formed on the diamond layer, and a pair of electrodes for generating a surface acoustic wave having a specific wavelength and extracting the surface acoustic wave, wherein at least one electrode is a copper electrode epitaxially grown on the surface of the diamond layer. To manufacture this surface acoustic wave element, after the diamond layer is formed on a substrate by epitaxial growth, the copper electrodes each having the predetermined shape are formed on the surface of the diamond layer by epitaxial growth. Since the copper electrodes formed on the diamond layer consist of high-quality single crystal copper, resistances to electromigration and stress migrations can be increased. As a result, there is provided an excellent surface acoustic wave element free from electrical defects caused by degradation and failure of the copper electrodes or free from degradation of the electrical characteristics.Type: GrantFiled: May 11, 1994Date of Patent: March 12, 1996Assignee: Sumitomo Electric Industries, Ltd.Inventors: Shinichi Shikata, Akihiro Hachigo, Hideaki Nakahata, Kenjiro Higaki
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Patent number: 5487357Abstract: The invention relates to the use of boron-containing organic group-V compounds for the deposition of the elements of the Vth main group on substrates by gas-phase deposition.Type: GrantFiled: January 28, 1994Date of Patent: January 30, 1996Assignee: Merck Patent Gesellschaft Mit Beschrankter HaftungInventors: Ludwig Pohl, Herbert Schumann, Christian Marschall
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Patent number: 5487356Abstract: A chemical vapor deposition method for forming films or coatings of metal oxide films showing a giant magnetoresistive effect, with the metal oxides having the formula La.sub.x A.sub.1-x MnO.sub.3 wherein A is selected from the group consisting of barium, calcium, manganese, and strontium, and x is a number in the range of from 0.2 to 0.4. The method uses a liquid source delivery CVD approach, wherein source reagent solution precursor is flash vaporized and is delivered to a CVD chamber, wherein it decomposes to deposit the multicomponent metal oxide films with well-controlled stoichiometry.Type: GrantFiled: November 28, 1994Date of Patent: January 30, 1996Assignee: Advanced Technology Materials, Inc.Inventors: Yi-Oun Li, Jiming Zhang
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Patent number: 5462008Abstract: Semiconductor films of the formula (InP).sub.1-x (TlP.sub.3).sub.x on InP substrates which cover the bandgap of 2-12 .mu.m for use with long wavelength infrared detector and laser applications are disclosed.Type: GrantFiled: December 12, 1994Date of Patent: October 31, 1995Assignee: Northwestern UniversityInventor: Manijeh Razeghi
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Patent number: 5458085Abstract: A method of manufacturing a semiconductor device having a step of growing a plurality of electrically connected p-type group III-V compound semiconductor layers by organo-metallic vapor phase epitaxy. In growing the plurality of p-type group III-V compound semiconductor layers, all or some of the p-type layers are grown by using a Mg organo-metallic compound as a p-type impurity and adding an Al organo-metallic compound of a predetermined amount. Doping both the Mg organo-metallic compound and Al organo-metallic compound at the same time considerably shortens the Mg doping delay.Type: GrantFiled: October 19, 1994Date of Patent: October 17, 1995Assignee: Fujitsu LimitedInventors: Makoto Kondo, Chikashi Anayama
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Patent number: 5459097Abstract: In accordance with the invention, aluminum-containing layers are grown by molecular beam processes using as an arsenic precursor phenylarsine (PhAs). Because PhAs is more reactive than arsine and less reactive than arsenic, it decomposes selectively on III-V surfaces but not on mask materials. Thus in contrast to conventional processes, growth using PhAs permits selective growth on unmasked gallium arsenide surfaces but inhibits growth on typical mask materials such as silicon nitride.Type: GrantFiled: October 7, 1993Date of Patent: October 17, 1995Assignee: AT&T Corp.Inventors: Cammy R. Abernathy, Stephen J. Pearton, Fan Ren, Patrick W. Wisk
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Patent number: 5456207Abstract: Triisopropylindium diisopropyltelluride adduct, ((CH.sub.3).sub.2 CH).sub.3 In:Te(CH(CH.sub.3).sub.2).sub.2 is synthesized and is used as a universal n-type dopant for both II/VI semiconductor materials as well as III/V semiconductor materials is disclosed. This dopant precursor is particularly suited for indium doping of II/V semiconductor materials at low carrier concentrations down to 10.sup.14 cm.sup.-3 and does not exhibit an appreciable memory effect.Type: GrantFiled: May 16, 1994Date of Patent: October 10, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventors: Robert W. Gedridge, Jr., Ralph Korenstein, Stuart J. C. Irvine
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Patent number: 5450812Abstract: A process and structure wherein a film comprised of a perovskite or a spinel is built epitaxially upon a surface, such as an alkaline earth oxide surface, involves the epitaxial build up of alternating constituent metal oxide planes of the perovskite or spinel. The first layer of metal oxide built upon the surface includes a metal element which provides a small cation in the crystalline structure of the perovskite or spinel, and the second layer of metal oxide built upon the surface includes a metal element which provides a large cation in the crystalline structure of the perovskite or spinel. The layering sequence involved in the film build up reduces problems which would otherwise result from the interfacial electrostatics at the first atomic layers, and these oxides can be stabilized as commensurate thin films at a unit cell thickness or grown with high crystal quality to thicknesses of 0.5-0.7 .mu.m for optical device applications.Type: GrantFiled: December 8, 1993Date of Patent: September 19, 1995Assignee: Martin Marietta Energy Systems, Inc.Inventors: Rodney A. McKee, Frederick J. Walker
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Patent number: 5438952Abstract: A method of fabricating a compound semiconductor device includes the steps of supplying an amine-adduct of a compound that contains a constituent element of a crystal layer that forms the semiconductor device, to a substrate on which the semiconductor device is formed, as a source material of the crystal layer, decomposing the amine-adduct in the vicinity of the substrate such that the constituent element is released, and depositing the constituent element on the substrate to cause a growth of the crystal layer on the substrate.Type: GrantFiled: January 31, 1994Date of Patent: August 8, 1995Assignee: Fujitsu LimitedInventor: Nobuyuki Otsuka
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Patent number: 5433170Abstract: A metal-organic chemical vapor-phase deposition process for fabricating a layer of a Group II-VI compound semiconductor using an organometallic compound based on bis(cyclopentadienyl)magnesium having a vapor pressure in the range of from 1.3.times.10 Pa to 1.3.times.10.sup.2 Pa at a temperature of 330.degree. K. The present invention also provides a light-emitting device which is fabricated by means of the metal-organic vapor-phase deposition process above. The process according to the present invention provides a magnesium-containing compound semiconductor layer having an accurately controlled composition, and it readily enables the fabrication of a compound semiconductor layer having a grated structure.Type: GrantFiled: November 4, 1994Date of Patent: July 18, 1995Assignee: Sony CorporationInventors: Atsushi Toda, Takeharu Asano
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Patent number: 5423284Abstract: A method which permits the growth of high-quality crystals of n-type II-VI compound semiconductors containing sulfur, by suppressing the reaction of a group III or VII element as a dopant with a group II material at low temperature. A raw material gas containing an organometallic material of the group III or organic material of the group VII is premixed with a raw material gas containing organic sulfur material, then the premixture is mixed with a raw material gas containing an organometallic material of the group II, and the mixture is used to grow a crystal of an n-type II-VI compound semiconductor on a semiconductor substrate by a metal organic vapor phase epitaxial growth method.Type: GrantFiled: March 14, 1994Date of Patent: June 13, 1995Assignee: Kokusai Denshin Denwa Kabushiki KaishaInventors: Kohsuke Nishimura, Kazuo Sakai, Yasuyuki Nagao
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Patent number: 5415129Abstract: Alkyl arsines are made by a reaction of gaseous arsine and the corresponding gaseous olefin in contact with at least one Bronsted acid catalyst. Products produced thereby are mono- and di-substituted arsines, e.g. alkyl and di-alkyl arsines, which contain substantially no metallic or oxygenating impurities.Type: GrantFiled: June 4, 1993Date of Patent: May 16, 1995Assignee: Cytec Technology Corp.Inventors: C. Joseph Calbick, Mark A. Kuck, Donald H. Valentine
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Patent number: 5404837Abstract: A method for preparing a graphite intercalation compound having a metal or a metal compound inserted between adjacent graphite layers, comprising simultaneously introducing a mixture of a vapor of both a hydrocarbon compound and an organo metallic compound together with a carrier gas into a reactor, and decomposing said hydrocarbon compound and said organo metallic compound on a single-crystalline substrate at a relatively low temperature.Type: GrantFiled: April 22, 1993Date of Patent: April 11, 1995Assignee: Sharp Kabushiki KaishaInventors: Yoshikazu Yoshimoto, Tomonari Suzuki, Yoshiyuki Higashigaki, Shigeo Nakajima, Toshio Inoguchi
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Patent number: 5395791Abstract: A method for using atomic layer epitaxy (ALE) and/or migration enhanced epitaxy (MEE) to grow high efficiency quantum wells in II-VI laser diodes. The substrate and previously grown layers of the laser diode are heated to a temperature less than or equal to about 200.degree. C. in an MBE chamber. Sources of Cd, Zn, and Se are injected alternately into the chamber to grow a short-period strained-layer superlattice (SPSLS) quantum well layer including overlaying monolayers of Cd, Zn and Se. The quantum well layer is described by the notation [(CdSe).sub.m (ZnSe).sub.n ].sub.p where m, n and p are integers.Type: GrantFiled: October 20, 1993Date of Patent: March 7, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Hwa Cheng, James M. DePuydt, Michael A. Haase, Jun Qiu
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Patent number: 5394826Abstract: A group II-VI epitaxial layer grown on a (111) silicon substrate has a lattice mismatch which is minimized, as between the group II-VI epitaxial layer and the silicon substrate. The grown group II-VI epitaxial layer also has a (111) plane at the interface with the substrate, and a 30.degree. in-plane rotation slip is formed at the interface between the (111) silicon substrate and the group II-VI epitaxial layer. The above structure is produced by a metal organic chemical vapor deposition method (MOCVD), in which a mol ratio of a group VI gas source supply to a group II gas source supply is kept greater than 15 during the growth. The (111) silicon substrate is preferably mis-oriented toward the <110> direction of the silicon substrate. When a HgCdTe layer is grown on the epitaxial layer, the product thus formed has utility as a monolithic infrared detector in which a plurality of detector elements are formed in the HgCdTe layer and a signal processing circuit is formed in the silicon substrate.Type: GrantFiled: October 22, 1993Date of Patent: March 7, 1995Assignee: Fujitsu LimitedInventors: Hiroji Ebe, Akira Sawada
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Patent number: 5392730Abstract: A crystal of a compound semiconductor is deposited on a substrate using a metal organic vapor phase epitaxy within a reaction enclosure having a vertical flow of deposition gas supplied through a gas injector within the deposition enclosure. The deposition gas is supplied in a plurality of divided flow paths in which the flow rates are individually controlled. The injector comprises a plurality of gas jet ports which receive respective, plural flow paths and which are disposed in a two-dimensional array having dimensions corresponding to the two-dimensional main surface dimensions of the substrate thereby to supply a uniform flow of deposition gas over the entire two-dimensional main surface of the substrate. The method and apparatus have special application in the deposition of quaternary III--V compound semiconductor.Type: GrantFiled: September 2, 1993Date of Patent: February 28, 1995Assignee: Fujitsu LimitedInventors: Makoto Kondo, Hiroshi Sekiguchi
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Patent number: 5386798Abstract: A method for growing a deposit upon a substrate of semiconductor material involves the utilization of pulsed laser deposition techniques within a low-pressure gas environment. The substrate and a target of a first material are positioned within a deposition chamber and a low-pressure gas atmosphere is developed within the chamber. The substrate is then heated, and the target is irradiated, so that atoms of the target material are ablated from the remainder of the target, while atoms of the gas simultaneously are adsorbed on the substrate/film surface. The ablated atoms build up upon the substrate, together with the adsorbed gas atoms to form the thin-film deposit on the substrate. By controlling the pressure of the gas of the chamber atmosphere, the composition of the formed deposit can be controlled, and films of continuously variable composition or doping can be grown from a single target of fixed composition.Type: GrantFiled: October 6, 1993Date of Patent: February 7, 1995Assignee: Martin Marietta Energy Systems, Inc.Inventors: Douglas H. Lowndes, James W. McCamy
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Patent number: 5387310Abstract: A single crystal diamond film having good electrical characteristics is produced by a method which comprises steps of decomposing a raw material gas comprising a hydrogen gas and a carbon-containing compound and epitaxially growing a single crystal diamond film on a single crystal substrate in a vapor phase, wherein a molar ratio of the carbon atoms in the carbon-containing compound to the hydrogen is from 2:100 to 10:100 and a lattice constant of the single crystal substrate satisfies the following relation:.vertline.(a-a.sub.0)/a.vertline..times.100.ltoreq.20 (I)wherein a.sub.0 is the lattice constant of diamond (3.567 .ANG.) and a is a lattice constant of the single crystal substrate.Type: GrantFiled: April 16, 1993Date of Patent: February 7, 1995Assignee: Sumitomo Electric Industries, Ltd.Inventors: Hiromu Shiomi, Naoji Fujimori
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Patent number: 5381756Abstract: A method of manufacturing a semiconductor device having a step of growing a plurality of electrically connected p-type group III-V compound semiconductor layers by organo-metallic vapor phase epitaxy. In growing the plurality of p-type group III-V compound semiconductor layers, all or some of the p-type layers are grown by using a Mg organo-metallic compound as a p-type impurity and adding an Al organo-metallic compound of a predetermined amount. Doping both the Mg organo-metallic compound and Al organo-metallic compound at the same time considerably shortens the Mg doping delay.Type: GrantFiled: March 4, 1993Date of Patent: January 17, 1995Assignee: Fujitsu LimitedInventors: Makoto Kondo, Chikashi Anayama
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Patent number: 5379720Abstract: A process for growing a semiconductor crystal, comprising growing a group III-V compound semiconductor containing P as a group V element by an organometal vapor phase epitaxy by using tertiary butyl phosphine (TBP) as a source of P constituting a grown layer and doping the semiconductor with a dopant gas during a growth of the semiconductor. In this process, the source gas and dopant gas are fed under a condition satisfying a requirement represented by the following formula, to conduct a growth of the crystal: ##EQU1## wherein n is a carrier concentration of the growing semiconductor crystal, T is a temperature of the substrate and an atmosphere in the vicinity of the substrate, P.sub.TBP.sup.0 is an equilibrium vapor pressure of TBP or a decomposition product thereof, P.sub.D.sup.0 is an equilibrium vapor pressure of a dopant or a decomposition product thereof, P.sub.0 is a total pressure, f.sub.0 is a total flow rate, and f.sub.TBP is a flow rate of TBP.Type: GrantFiled: April 18, 1994Date of Patent: January 10, 1995Assignee: Fujitsu LimitedInventor: Akito Kuramata
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Patent number: 5377616Abstract: A method for vaporizing an organometal compound and supplying the resulting vapor thereof to a crystal growth chamber which comprises the steps of heating an organometal compound to a predetermined temperature to obtain vapor of the compound at a predetermined vapor pressure and supplying, in a constant flow rate, the vapor to the surface of a substrate heated under a reduced pressure: an apparatus for vaporizing an organometal compound and supplying the resulting vapor thereof to a crystal growth chamber 11 comprising a first gas flow path for the vapor of the organometal compound which connects a container 20, in which the organometal compound is charged, to a crystal growth chamber heated under a reduced pressure through a first valve 21, a first massflow controller 22 and a second valve 23 in this order; and a constant temperature oven 24 and 25 for controlling the temperature of the container 20 and the first gas flow path extending from the container 20 to the second valve 23, are herein disclosed.Type: GrantFiled: November 9, 1993Date of Patent: January 3, 1995Assignees: Stec, Inc., Shin-Etsu Chemical Co., Ltd.Inventors: Hiroshi Mihira, Tetsuo Shimizu, Kazuhiro Hirahara, Toshinobu Ishihara, Seiki Takaya
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Patent number: 5326425Abstract: The new compound tertiarybutyldimethylantimony is prepared by reacting an timony trihalide SbX.sub.3 with the tertiarybutyl Grignard reagent ((CH.sub.3).sub.3 C)MgX, treating the resulting product with the methyl Grignard reagent (CH.sub.3)MgX. where X is a halide, and recovering tertiarybutyldimethylantimony from the reaction mixture. The reaction is preferably carried out by a one pot synthesis in a suitable solvent such as diethyl either using approximately one equivalent of ((CH.sub.3).sub.3 C)MgX in relation to the SbX.sub.3 at about -50.degree. C., followed by treatment with approximately two equivalents of (CH.sub.3)MgX in relation to the SbX.sub.3 at about 0.degree. C. The tertiarybutyldimethylantimony is used as a precursor in forming antimony-containing semiconductor material by chemical vapor deposition.Type: GrantFiled: January 28, 1993Date of Patent: July 5, 1994Assignee: The United States of America as represented by the Secretary of the NavyInventor: Robert W. Gedridge, Jr.