Excess Component Or Non-product Appearing Component Contains A Metal Atom Patents (Class 117/67)
  • Publication number: 20150128847
    Abstract: An objective of the present invention is to provide a high-quality SiC single crystal in which the threading dislocation density including screw dislocation, edge dislocation and micropipe defect is reduced, and a method for producing such SiC single crystal according to a solution technique. The method for producing the SiC single crystal according to a solution technique which involves bringing an SiC seed crystal into contact with an Si—C solution having a temperature gradient in which the temperature is lower towards the surface from the inner part and growing an SiC single crystal comprises setting the temperature gradient of the surface region of the Si—C solution to 10° C.
    Type: Application
    Filed: April 5, 2013
    Publication date: May 14, 2015
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Katsunori Danno
  • Patent number: 8945302
    Abstract: Method for crystal growth from a surfactant of a metal-nonmetal (MN) compound, including the procedures of providing a seed crystal, introducing atoms of a first metal to the seed crystal thus forming a thin liquid metal wetting layer on a surface of the seed crystal, setting a temperature of the seed crystal below a minimal temperature required for dissolving MN molecules in the wetting layer and above a melting point of the first metal, each one of the MN molecules being formed from an atom of a second metal and an atom of a first nonmetal, introducing the MN molecules which form an MN surfactant monolayer, thereby facilitating a formation of the wetting layer between the MN surfactant monolayer and the surface of the seed crystal, and regulating a thickness of the wetting layer, thereby growing an epitaxial layer of the MN compound on the seed crystal.
    Type: Grant
    Filed: March 4, 2012
    Date of Patent: February 3, 2015
    Assignee: Mosaic Crystals Ltd.
    Inventor: Moshe Einav
  • Patent number: 8940095
    Abstract: An apparatus for growth of uniform multi-component single crystals is provided. The single crystal material has at least three elements and has a diameter of at least 50 mm, a dislocation density of less than 100 cm?2 and a radial compositional variation of less than 1%.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: January 27, 2015
    Assignee: Rensselaer Polytechnic Institute
    Inventor: Partha Dutta
  • Patent number: 8815011
    Abstract: The present invention relates to a magnetic garnet single crystal prepared by the liquid phase epitaxial (LPE) process and an optical element using the same as well as a method of producing the single crystal, for the purpose of providing a magnetic garnet single crystal at a reduced Pb content and an optical element using the same, as well as a method of producing the single crystal. The magnetic garnet single crystal is grown by the liquid phase epitaxial process and is represented by the chemical formula BixNayPbzM13-x-y-zFe5-wM2wO12 (M1 is at least one element selected from Y, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; and M2 is at least one element selected from Ga, Al, In, Ti, Ge, Si and Pt, provided that 0.5<x?2.0, 0<y?0.8, 0?z<0.01, 0.19?3-x-y-z<2.5, and 0?w?1.6).
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: August 26, 2014
    Assignee: TDK Corporation
    Inventor: Atsushi Ohido
  • Patent number: 8702864
    Abstract: In a method for growing a silicon carbide single crystal on a silicon carbide single crystal substrate by contacting the substrate with a solution containing C prepared by dissolving C into the melt that contains Cr and X, which consists of at least one element of Ce and Nd, such that a proportion of Cr in a whole composition of the melt is in a range of 30 to 70 at. %, and a proportion of X in the whole composition of the melt is in a range of 0.5 at. % to 20 at. % in the case where X is Ce, or in a range of 1 at. % to 25 at. % in the case where X is Nd, and the silicon carbide single crystal is grown from the solution.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: April 22, 2014
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Yukio Terashima, Yasuyuki Fujiwara
  • Patent number: 8685163
    Abstract: A method for growing a silicon carbide single crystal on a single crystal substrate comprising the steps of heating silicon in a graphite crucible to form a melt, bringing a silicon carbide single crystal substrate into contact with the melt, and depositing and growing a silicon carbide single crystal from the melt, wherein the melt comprises 30 to 70 percent by atom, based on the total atoms of the melt, of chromium and 1 to 25 percent by atom, based on the total atoms of the melt, of X, where X is at least one selected from the group consisting of nickel and cobalt, and carbon. It is possible to improve morphology of a surface of the crystal growth layer obtained by a solution method.
    Type: Grant
    Filed: November 18, 2008
    Date of Patent: April 1, 2014
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Yukio Terashima, Yasuyuki Fujiwara
  • Patent number: 8287644
    Abstract: In a method for growing a silicon carbide single crystal on a silicon carbide single crystal substrate by contacting the substrate with a solution containing C by dissolving C into the melt that contains Si, Cr and X, which consists of at least one element of Sn, In and Ga, such that the proportion of Cr in the whole composition of the melt is in a range of 30 to 70 at. %, and the proportion of X is in a range of 1 to 25 at. %, and the silicon carbide crystal is grown from the solution.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: October 16, 2012
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Yukio Terashima, Yasuyuki Fujiwara
  • Publication number: 20120211769
    Abstract: A SiC single crystal wafer on which a good quality epitaxial film by suppressing defects derived from the wafer can be grown has an affected surface layer with a thickness of at most 50 nm and a SiC single crystal portion with an oxygen content of at most 1.0×1017 atoms/cm3. This SiC single crystal wafer is manufactured from a high purity SiC bulk single crystal obtained by the solution growth method using raw materials with an oxygen content of at most 100 ppm and a non-oxidizing atmosphere having an oxygen concentration of at most 100 ppm.
    Type: Application
    Filed: February 27, 2012
    Publication date: August 23, 2012
    Applicant: SUMITOMO METAL INDUSTRIES, LTD.
    Inventors: Kazuhiko Kusunoki, Kazuhito Kamei, Nobuyoshi Yashiro, Junichi Koike
  • Publication number: 20120017825
    Abstract: A method for growing a crystalline composition, the first crystalline composition may include gallium and nitrogen. The crystalline composition may have an infrared absorption peak at about 3175 cm?1, with an absorbance per unit thickness of greater than about 0.01 cm?1. In one embodiment, the composition ay have an amount of oxygen present in a concentration of less than about 3×1018 per cubic centimeter, and may be free of two-dimensional planar boundary defects in a determined volume of the first crystalline composition.
    Type: Application
    Filed: November 9, 2006
    Publication date: January 26, 2012
    Applicant: General Electric Company
    Inventors: Mark Philip D'Evelyn, Kristi Jean Narang, Dong-Sil Park, Huicong Hong, Xian-An Cao, Larry Qiang Zeng
  • Patent number: 8088220
    Abstract: In accordance with various embodiments, crystalline structures are formed by providing, at a growth temperature, a liquid comprising AlN and having a quality factor greater than approximately 0.14 and forming solid AlN from the liquid, the growth temperature being lower than the melting point of AlN.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: January 3, 2012
    Assignee: Crystal IS, Inc.
    Inventors: Glen A. Slack, Sandra B. Schujman
  • Publication number: 20110274609
    Abstract: A group 13 nitride crystal substrate according to the present invention is produced by growing a group 13 nitride crystal on a seed-crystal substrate by a flux method, wherein a content of inclusions in the group 13 nitride crystal grown in a region of the seed-crystal substrate except for a circumferential portion of the seed-crystal substrate, the region having an area fraction of 70% relative to an entire area of the seed-crystal substrate, is 10% or less, preferably 2% or less.
    Type: Application
    Filed: July 15, 2011
    Publication date: November 10, 2011
    Applicant: NGK Insulators, Ltd.
    Inventors: Takanao Shimodaira, Katsuhiro Imai, Makoto Iwai, Takayuki Hirao
  • Publication number: 20110200833
    Abstract: A method capable of stably manufacturing a SiC single crystal in the form of a thin film or a bulk crystal having a low carrier density of at most 5×1017/cm3 and preferably less than 1×1017/cm3 and which is suitable for use in various devices by liquid phase growth using a SiC solution in which the solvent is a melt of a Si alloy employs a Si alloy having a composition which is expressed by SixCryTiz wherein x, y, and z (each in atomic percent) satisfy 0.50<x<0.68, 0.08<y<0.35, and 0.08<z<0.35, or??(1) 0.40<x?0.50, 0.15<y<0.40, and 0.15<z<0.35.??(2) x, y, and z preferably satisfy 0.53<x<0.65, 0.1<y<0.3, and 0.1<z<0.3.
    Type: Application
    Filed: February 28, 2011
    Publication date: August 18, 2011
    Applicant: SUMITOMO METAL INDUSTRIES, LTD.
    Inventors: Kazuhito KAMEI, Kazuhiko Kusunoki, Nobuyoshi Yashiro, Akihiro Yauchi, Shinji Shimosaki
  • Patent number: 5664366
    Abstract: A shipping container for sea worms contains a fibrous bed of vegetable matter which is degraded by fermentation. The bed is both wetted and seeded with a microorganism in order to insure the fermentation.
    Type: Grant
    Filed: April 15, 1994
    Date of Patent: September 9, 1997
    Inventors: Michel Lopuszanski, Daniel Lopuszanski
  • Patent number: 5544616
    Abstract: A liquid phase epitaxy method for forming thin crystalline layers of device quality silicon having less than 3.times.10.sup.16 Cu atoms/cc impurity, comprising: preparing a saturated liquid solution of Si in a Cu/Al solvent at about 20 to about 40 at. % Si at a temperature range of about 850.degree. to about 1100.degree. C. in an inert gas; immersing or partially immersing a substrate in the saturated liquid solution; super saturating the solution by lowering the temperature of the saturated solution; holding the substrate in the saturated solution for a period of time sufficient to cause Si to precipitate out of solution and form a crystalline layer of Si on the substrate; and withdrawing the substrate from the solution.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: August 13, 1996
    Assignee: Midwest Research Institute
    Inventors: Theodore F. Ciszek, Tihu Wang
  • Patent number: 5517942
    Abstract: A process for producing optoelectric articles, in which an optoelectric single crystal film is formed on an optoelectric single crystal substrate, is disclosed. The optoelectric single crystal substrate is exposed to a liquid phase in a supercooling state of a melt including a solute and a melting medium, and the optoelectric single crystal film is formed by a liquid phase epitaxial process. In this case, a viscosity of the liquid phase is set to 75%.about.95% preferably 75%.about.90% with respect to a viscosity at which a degree of supercooling of the liquid phase is zero.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: May 21, 1996
    Assignee: NGK Insulators, Ltd.
    Inventors: Tsuguo Fukuda, Yasunori Okano, Tatsuo Kawaguchi, Minoru Imaeda
  • Patent number: 5500390
    Abstract: A method for controlling the Si concentration in a GaP single crystal layer grown in a series of runs of GaP liquid phase epitaxial growth with the repeated use of one and the same Ga solution, which comprise the steps of: measuring the Si concentrations of the GaP single crystal layers in preceding runs; then determining the additional Si amounts to be added into the Ga solution to refresh the Si effective concentration therein in reference to the Si concentrations in the layers; and adding Si of the thus determined amount into the Ga solution to commence the subsequent run, wherein the Si concentration in each of the GaP liquid phase epitaxial growth layers is determined from measurement of the O/G ratio in the layer, which is computed from each pair of the both values of the photoluminescent spectral peak intensity around the wavelength of 6300 .ANG. (O component) as the numerator and the other photoluminescent spectral peak intensity around the wavelength of 5540 .ANG.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: March 19, 1996
    Assignee: Shin-Etsu Handatoi Co., Ltd.
    Inventors: Munehisa Yanagisawa, Yuki Tamura, Norihide Kokubu