Abstract: Mixtures of the compound 1,1,1,2,2,5,5,5-octafluoro-4-trifluoromethylpentane with alcohols, ethers, esters, ketones, nitrogen-containing organic compounds, and halogenated hydrocarbons are disclosed; as is a process for cleaning a solid surface which comprises treating the surface with said mixtures. Binary mixtures of 1,1,1,2,2,5,5,5-octafluoro-4-trifluoromethylpentane with about 5 to 13 weight percent methanol, with about 2 to 10 weight percent ethanol, with about 3 to 11 weight percent isopropanol, with about 50 to 58 weight percent dichloromethane, and with about 1 to 9 weight percent acetonitrile, are disclosed as azeotrope or azeotrope-like compositions and are particularly suited for use where solvent recovery and reuse is practiced.

Abstract: The invention relates to an azeotrope-type mixture which contains about 3-5% by weight of methanol and about 95-97% by weight of 1,4-dihydroperfluorobutane, and also to a process for cleaning electronic components, in particular soldered conductor boards or printed circuits, with the aid of said mixture.

Abstract: Mixtures of the compound 1,1,1,2,2,3,5,5,5-nonafluoro-4-trifluoromethylpentane with alcohols, ethers, esters, ketones, nitrogen-containing organic compounds, and halogenated hydrocarbons are disclosed; as is a process for cleaning a solid surface which comprises treating the surface with said mixtures. Binary mixtures of 1,1,1,2,2,3,5,5,5-nonafluoro-4-trifluoromethylpentane with about 5 to 13 weight percent methanol, with about 3 to 11 weight percent ethanol, with about 4 to 12 weight percent isopropanol, with about 52 to 60 weight percent trans-1,2-dichloroethylene, with about 47 to 55 weight percent dichloromethane, with about 1 to 9 weight percent trichloroethane, with about 0.1 to 7 weight percent acetonitrile, and with about 0.

Abstract: A process for removing protective coatings and/or bonding layers from metal parts, particularly gamma prime hardened nickel base alloy, solid solution superalloy, iron base superalloy, and cobalt base superalloy parts to render them brazable or otherwise bondable. The process uses a C--O--H--F atmosphere as the primary stripping material wherein the atmosphere has a H/O ratio of 10.sup.4 or greater. The preferred source of the C--O--H--F atmosphere is thermal decomposition of a fluorocarbon resin.

Abstract: A method and apparatus for stripping a photoresist layer from a semiconductor wafer, wherein oxidizing gas is fed from the edge of the wafer to the center. The oxidizing gas may be directed so that it is incident on the heated wafer support platform before it is incident on the wafer.

Abstract: A process for removing undesired material from a chosen substrate by exposing the substrate simultaneously to ultraviolet radiation and a selected dense fluid, wherein the radiation produces a photochemical reaction that removes the undesired material from the substrate and the dense fluid enhances the removal of the undesired material. In an alternative embodiment, a reactive agent may additionally be used. The process may be used to remove contaminants from a substrate, etch a substrate surface, or destroy toxic organic material in industrial wastes.

Abstract: Azeotropic mixtures of 2,2-dichloro-1,2-difluoroethane (HCFC-132c) with methanol, ethanol, or trans-1,2-dichloroethylene (t-HCC-1130), the azeotropic mixtures being useful in solvent cleaning applications.

Abstract: Azeotropic mixtures of 1,1,1,2,3,4,4,5,5,5-decafluoropentane and methanol or ethanol or isopropanol, the azeotropic mixtures being useful in solvent cleaning applications, as blowing agents, refrigerants, heating mediums and aerosol propellants.

Abstract: Azeotropic mixtures of 1,1,1,2,3,4,4,5,5,5-decafluoropentane and trans 1,2-dichloroethylene with methanl or ethanol, the azeotropic mixtures being useful in solvent cleaning applications.

Abstract: The invention provides a method for removing the fine particles deposited on an article of fluorine-containing resin, the method comprising conducting at least one of the procedures of:(i) maintaining the article of fluorine-containing resin at a high temperature,(ii) maintaining the article in the atmosphere of fluorine-containing gas, and(iii) bringing the article into contact with a polar solvent or an aqueous solution of polar solvent.

Abstract: Stable azeotrope-like compositions consisting essentially of 1,1,2-trichloro-1,2,2-trifluoroethane, 1,2-dichloroethylene, cyclopentane, methanol, nitromethane, and optionally diisopropylamine which are useful in a variety of industrial cleaning applications.

Abstract: Macromolecular material is removed from components contaminated therewith by means of a pyrolytic treatment in which the component is first subjected to a treatment for structural cleavage, the flowable medium formed is allowed to run off the component, and the component is subsequently subjected to a pyrolytic treatment.

Abstract: A venetian blind or similar flexible flat article is held in tension on a foraminous belt and passed through washing, rinsing and drying zones. The condensate from the air from the drying zone is used as final rinse. The slats of the blind are held at a slight angle to improve drainage and prevent sag or the blind below the edge of the belt.

Abstract: Components, especially of an electronic or electrical type, are cleaned by contact with a flammable liquid organic solvent (21), especially an alcohol. The surface of the solvent is covered with a non-flammable highly fluorinated compound vapor blanket (26), which vapor may also be used to transfer heat to the organic solvent. Both highly fluorinated compound and organic solvent are condensed and re-cycled.

Abstract: A cage boat having easily replaceable parts utilizes removable spacer rails for holding semiconductor wafers contained within a cage formed from slats removably attached to end pieces perpendicular to the slats.

Abstract: The present invention concerns a procuedure for washing off flux residues subsequent to soldering from a circuit board or equivalent component. The circuit board washing procedures of prior art have either been detrimental to the environment or poor in their washing result. These problems have in the present invention been solved by including at least one step in the procedure in which steam is sprayed on the circuit board or equivalent. The steam spraying step is advantageously combined with preceding water washing and rinsing steps. A circuit board or equivalent component rinsed with hot steam is recovered in a cleaner condition than before, and moreover, entirely dry.

Abstract: Azeotropic mixtures of n-perfluorobutylethylene and cis-1,2-dichloroethylene with methanol or ethanol or isopropanol, the azeotropic mixtures being useful as: cleaning agents, blowing agents, refrigerants, aerosol propellants, heat transfer media and power cycle working fluids.

Abstract: Stable azeotrope-like compositions consisting essentially of 1,1-dichloro-1-fluoroethane, dichloromethane and optionally alkanol which are useful in a variety of industrial cleaning applications and one of which is also useful as a blowing agent in the preparation of polyurethane foams.

Abstract: An azeotrope or azeotrope-like composition of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) and methanol, the azeotropic mixture being useful in solvent cleaning application.

Abstract: Azeotropic mixtures of n-perfluorobutylethylene and trans-1,2-dichloroethylene with methanol or ethanol or isopropanol are disclosed. The azerotropic mixtures are useful as: cleaning agents, blowing agents, refrigerants, aerosol propellants, heat transfer media and power cycle working fluids.

Abstract: The azeotropic mixture of 1,1-dichloro-1-fluoroethane and n-perfluorobutylethylene is disclosed. The azeotropic mixture is useful as: a cleaning agent, a blowing agent, a refrigerant, an aerosol propellant, a fire extinguishing agent, a heat transfer medium and a power cycle working fluid.

Abstract: Azeotropic mixtures of hexafluoropropylene/ethylene cyclic dimer with methanol or ethanol, the azeotropic mixtures being useful as: cleaning agents, blowing agents, refrigerants, aerosol propellants, heat transfer media and power cycle working fluids.

Abstract: Oxide material, on a substrate, in a reactor, is etched by dissolving a hydrogen halide reaction product in a liquid phase reaction product. Both the hydrogen halide and liquid phase reaction products are produced through a chemical reaction of a reactive gas containing hydrogen and halogen elements as well as at least one gaseous compound which has been remotely activated. The liquid phase reaction product is obtained by condensation on the oxide material. The use of charged particle beams and irradiating light is discussed.

Abstract: Azeotropic mixtures of perfluoro-1,2-dimethylcyclobutane, methanol and either 1,1-dichloro-1-fluoroethane or dichlorotrifluoroethane, are useful in solvent cleaning applications, and as refrigerants, aerosol propellants and polymer blowing agents.

Abstract: There is disclosed a method for the removal and recovery of hydrocarbons which are contained within the air/vapor mixture in bulk oil or gasoline storage tanks using fractional condensation with cryogenic cooling. The air/vapor mixture is flushed from the tank with fresh air and passed, successively, through several stages of a portable condenser train. When necessary, the first stage of the treatment comprises a caustic wash stage where the air/vapor mixture is contacted completely with a caustic solution to remove sulfur compounds. The desulfurized air/vapor mixture is then passed to the first condenser stage which condenses and removes substantially all moisture within the mixture. The de-humidified, desulfurized mixture is then passed to an intermediate stage where the heavier hydrocarbon fractions are condensed and separated and is then passed to a final condenser stage where it is cooled to a temperature of at least -100 degrees F., sufficient to condense substantially all hydrocarbon component therein.

Abstract: In a method, especially for stripping enamel and removing coatings from objects, the advantages of a solvent treatment are to be retained, without having to put up with the disadvantages of contaminating the environment. This is accomplished essentially by using in a closed treating vessel a treating mixture with at least a preponderance of a solvent with a proportion of water in excess of that required for an azeotropic mixture and carrying out the treatment while boiling the treating mixture. After the treating mixture is removed from the vessel, any solvent components still present are distilled off azeotropically from the system with water and removed before the vessel is opened.

Abstract: In non-aqueous liquid cleaning products compositions comprising dispersed particles of aluminosilicate builder, components sensitive to decomposition catalyzed by aluminosilicate, such as bleach precursors, can be protected if the aluminosilicate particles are deactivated by pre-treatment with an ammonium or substituted ammonium compound, followed by a heating step to reduce the water level of the aluminosilicate.

Abstract: Liquid solvent mixtures having superior cleaning power, especially for photoresist and fingernail enamel, include polar compounds, such as ethylene diacetate, and alicyclic carbonates, such as ethylene carbonate. The solvent mixtures exhibit a low toxicity and have chemical and physical properties that reduce the risk of exposing the user to other unnecessary hazardous conditions.

Abstract: A process for removing contaminants such as phenolic-containing dusts and mists from an inert gaseous process stream by contacting the gaseous stream with an aqueous alkali metal hydroxide solution whereby the contaminants react with the alkali metal hydroxide to produce alkali metal salts of the contaminant compounds and produce water soluble contaminant salts.

Abstract: The compressors of gas turbines are cleaned on-line or off-line by scrubbing them with an aqueous solution of dimethyl esters of succinic acid, glutaric acid and adipic acid together with nonionic and/or cationic surface active agents. The scrubbing solution components are easily biodegradable or break down during the operation of the turbine without forming corrosives or environmentally harmful components.

Abstract: Azeotropic mixtures of perfluoro-dimethylcyclobutane with 1,1-dichloro-1-fluoroethane or dichlorotrifluoroethane, are useful in solvent cleaning applications, and as refrigerants, aerosol propellants and polymer blowing agents.

Abstract: A process for treating oil-contaminated debris or like material in particular material to be washed such as mill scale, which is produced in industrial processes, as well as a plant and an apparatus for carrying out the process, are to be improved in such a way as to permit oil to be removed from the industrial material to be washed, in particular mill scale. For that purpose it is proposed that the oil-contaminated material, in particular the mill scale, be introduced into a washing drum and there washed in counter-flow mode in a washing lye with a pH-value of from 12 to 14, preferably 10 to 14, with the material to be washed being lifted at the wall of the drum by means of support surfaces. The washing lye is preferably mixed with about 2% of caustic soda and/or washing is at about 50.degree. C. or a higher temperature.

Abstract: A method for decontaminating PCB containing transformers. The transformer is initially cleaned using a vapor degreasing solvent. The internal parts are removed and given a second cleaning which combines vapor degreasing with mechanical tumbling. The transformer and its parts are cleaned to less than 10 .mu.g/100 cm.sup.2 PCB. These cleaned parts are reclaimed rather than disposed of as toxic waste.

Abstract: The primary object of the invention is to clean and activate the surface of metallic works prior to such thermal treatment as nitriding, thermal spraying or dip plating by removing oxidized and other passive layers and foreign matters from the metallic work surface.The method of pretreating metallic works comprises heating a metallic work in a furnace and introducing a fluorine- or fluoride-containing gas into the furnace in that state to thereby cause destruction and elimination of the foreign matters adhering to the metallic work surface and of the oxidized layer occurring on the metallic work surface and simultaneous formation of a fluorinated layer. Just prior to the main thermal treatment, for example nitriding, the fluorinated layer is decomposed and eliminated by introducing an appropriate gas, for example H.sub.2, into the furnace. In this way, the metallic work reveals its cleaned and activated surface.

Abstract: A volatile solvent conservation modular unit and method for effecting solvent conservation is provided. The cooling coil modular unit is arranged to be disposed in the freeboard zone of a cleaning or degreasing apparatus that uses a volatile solvent. The freeboard zone chiller positioned above the vapor zone and the primary condenser to recover solvent from the relatively less dense solvent/air mixture escaping above the primary condenser and is formed so as to be disposed along one side of the degreaser vessel rather than on all four sides to minimize the obstruction of access into the vapor zone. This one-sided single freeboard chiller positioned on but one side produces a vapor suppression blanket that is effective and is readily retrofitted on existing apparatus without the need for dismantling of the existing unit.

Abstract: A cleaning system of the apparatus utilizing the effect of surface tension forces (4) and phase changes between a liquid and gas. In one embodiment the surface (21) to be cleaned is submerged within a vessel (30), the pressure within the vessel being increased. A rapid depressurization of the vessel causes a plurality of bubbles (12) to form around undesired particulate matter (13) on the surface (14) of the article to be cleaned, the bubbles rising to the surface of the liquid (27) within the chamber, thereby cleaning the article. A second embodiment utilizes a cleaning fluid (52) which is applied to the surface of the article (49) to be cleaned. The fluid being subsequently frozen on the surface, thereby reducing the adhesion force between the surface of the article and undesired particulate matter. The surface of the article (49) is subsequently heated, and the undesired particulate matter is removed through the medium of the cleaning fluid (52).

Abstract: A washing arrangement for and method of removing burrs of moldable substances from upper and lower major surfaces of lead frames on portions of which the burrs were undesirably applied during molding comprises a transfer assembly which is located outside a washing chamber of the arrangement. The transfer assembly is not subject to the hot and humid environment existing within the washing chamber, thereby preventing corrosion, and facilitating ready inspection and maintenance of the arrangement.

Abstract: In a method of processing an article, the article is introduced into a supercritical atmosphere which is formed in a pressure vessel and which atmosphere comprises carbon dioxide. When the article comprises an exposed resist film on a surface layer formed on a substrate, the exposed resist film is selectively removed to leave a predetermined pattern in the supercritical atmosphere and is thus processed into a patterned resist film. After the surface layer is selectively etched through the patterned resist film to form a patterned surface layer, the patterned resist film may be introduced into the supercritical atmosphere to be completely removed from the patterned surface layer. On processing the article, such as a compact disc, a mechanical parts, or the like, the article may be also introduced into the supercritical atmosphere to be cleaned up.

Abstract: Decomposition of perchloroethylene is prevented by the addition of a stabilizer system containing N-substituted cyclic alkyl amine, alcohol of 3-7 carbon atoms and olefin components. The stabilizer system is advantageous in that it does not contain any environmentally undersirable materials.

Abstract: An equipment for surface treatment according to the present invention comprises a chamber capable of exhausting gas, a revolving stage disposed in said chamber for placing a material to be treated thereon, a quartz plate serving as a gap controlling means spaced from the material to be treated such that a gap between said revolving stage and said material to be treated is provided not to exceed 0.5 mm for forming a space of treatment, the quartz plate being provided with a gas supplying means for supplying a reactive gas containing oxygen into the space of treatment, and a gas exciting means provided on the a side of said quartz plate opposite that on which the material to be treated is located for exciting the oxygen contained in said reactive gas into metastable oxygen atoms.

Abstract: Azeotropic mixture of 1,1,2-trichlorotrifluoroethane (CFC-113) with cis-1,2-dichloroethylene and n-propanol or isopropanol with or without nitromethane, the azeotropic mixtures being useful in solvent cleaning applications.One azeotrope-like "mixture contains about 88-96 weight percent 1,1,2-trichlorotrifluoroethane, about 4-10 weight percent cis-1,2-dichloroethylene and about 0.1-2.0 weight percent n-propanol and boils at about 47.degree. C. at essentially atmospheric pressure. A second azeotrope-like mixture contains about 87-97 weight percent 1,1,2-trichlorotrifluoroethane, about 2-8 weight percent cis-1,2-dichloroethylene and about 1-5 weight percent isopropanol and boils at about 45.degree. C. at essentially atmospheric pressure. A third azeotrope-like mixture contains about 88-98 weight percent 1,2,2-trichlorotrifluoroethane, about 1-7 weight percent cis-1,2-dichloroethylene, about 1-5 weight percent isopropanol and about 0.1-2.0 weight percent nitromethane.

Abstract: A method for producing selectively controlled pressure pulses in a mass of gas, particularly contained in a space of large dimensions. To achieve a sufficiently high power in the pulses, the pulses are generated by a valveless displacement machine in which the pressure when the machine opens towards its outlet port differs from the pressure of the mass of gas. The pulse is generated as the working fluid, due to said pressure difference, flows at high velocity through the outlet port. An acoustic power of the generated pulses of up to 20 kW can be attained by the method. The invention also concerns a rotary displacement machine for performing the method.

Abstract: Object surfaces such as semiconductor wafers which are suspended in a rinsing fluid may be dried by replacing the rinsing fluid, such as water, with a drying vapor by directly displacing the water from the surfaces at such a rate that substantially no liquid droplets are left on the surfaces after replacement of the water with drying vapor. Preferably, the drying vapor is miscible with water and forms a minimum-boiling azeotrope with water, such as isopropanol. The drying vapor is then purged with a stream of dry, inert, non-condensable gas such as nitrogen. A vaporizer with automatic refill mechanism produces saturated drying vapor which may then be flashed to a superheated vapor prior to contacting the surfaces, which preferably are at the same temperature as the vapor. Preferably, no liquid is removed by evaporation, and the drying takes place in an enclosed, hydraulically full system which does not require movement or handling of the surfaces between rinsing and drying steps.

Abstract: The present invention relates to a method for decontaminating radioactively contaminated surfaces of metallic materials with the use of nitric acid and hydrofluoric acid. The surfaces to be decontaminated are subjected to a vapor mixture of water vapor, hydrogen fluoride and nitric acid vapor.

Abstract: A method and an apparatus for rinsing materials or articles to remove deposits attached onto the surfaces of those materials or articles and humidity from the them by vapor of rinsing solvent which is evaporated by heating and filled in a rinsing chamber. In the method or the apparatus when it is detected that the vapor having been cooled to a temperature lower than that of the predetermined reference level, occurence or generation of failure in rinsing operation can be grasped.

Abstract: A method of cleaning a magnetic disk comprises the steps of rotating a magnetic disk housed in a cage, feeding a gas into the case, and at the same time sucking the gas from the inside of the case via window openings formed in upper and lower surfaces of the case, whereby the efficiency of discharge of dust from the case is improved by interaction of the gas feeding with the gas suction. An apparatus for cleaning a magnetic disk comprises a rotation shaft for rotating a magnetic disk housed in a case. The rotation shaft is provided with a gas passageway in the inside, and a gas discharging hole which is formed near a leading end portion to communicate with the gas passageway and which is opened inward of the case. A gas feeder is disposed for feeding gas into the gas passageway, and two gas suction devices for sucking gas from the case in the course of rotation of the magnetic disk are disposed to face respectively window openings formed in upper and lower surfaces of the case.

Abstract: An aqueous solution, preferably an aqueous disinfectant solution, containing chlorine dioxide and which is capable of forming a foam, and methods for the preparation and use thereof. An aqueous disinfectant solution capable of forming a foam is prepared by adding a foaming agent, i.e., a suitable surfactant, to water. Chlorine dioxide may then be added to the solution or it may be generated in situ by reacting an oxidizing agent, a cationic exchange resin in the acidic form, or an acid with a metal chlorite dissolved therein. The resultant foam solution may subsequently be foamed by being mixed with air in a foam generator. The foam solutions of the instant invention are useful as cleaning and/or sanitizing agents.

Abstract: In order to dissolve oil or PCB which exists in the electrical insulation of parts to be cleaned, a solvent is evaporated during a heating phase by an evaporator located with the parts in an autoclave. The solvent vapor condenses on the parts and penetrates into the electrical insulation to form an oil or PCB-solvent mixture. In the heating phase, a plurality of intermediate pressure reductions are carried out in the autoclave, and during each intermediate pressure reduction the solvent is simultaneously distilled out of the oil or PCB-solvent mixture, directly from the autoclave. That is, during each of the pressure reductions, the solvent supply is discontinued and the mixture circulated through a circulating line. Following the completion of each intermediate pressure reduction, the pure oil or PCB present in a condensate vessel is pumped out by an intermediately located feed pump through a connecting line and into a reservoir.

Abstract: Equipment which is contaminated with an organometallic residue is treated with gaseous carbon dioxide to react with the organometallic compounds contained in the equipment.

Abstract: A method for using a foamed liquid for cleaning and/or inerting a vessel is described which allows for continuous recycling of the foam and its breakout liquid and gas components into regenerated foam which is continously directed back into the vessel.