Gallium Containing Patents (Class 136/262)
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Patent number: 8309843Abstract: Novel structures of photovoltaic cells (also treated as solar cells) are provided. The Cells are based on the nanometer-scaled wire, tubes, and/or rods, which are made of the electronics materials covering semiconductors, insulator or metallic in structure. These photovoltaic cells have large power generation capability per unit physical area over the conventional cells. These cells can have also high radiation tolerant capability. These cells will have enormous applications such as in space, in commercial, residential and industrial applications.Type: GrantFiled: August 18, 2005Date of Patent: November 13, 2012Assignee: Banpil Photonics, Inc.Inventors: Nobuhiko P. Kobayashi, Achyut K. Dutta
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Publication number: 20120273037Abstract: An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (VOC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.Type: ApplicationFiled: June 21, 2012Publication date: November 1, 2012Inventors: WLADYSLAW WALUKIEWICZ, KIN MAN YU
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Publication number: 20120273043Abstract: A device, system, and method for solar cell construction and bonding/layer transfer are disclosed herein. An exemplary structure of solar cell construction involves providing a monocrystalline donor layer. A solder bonding layer bonds the donor layer to a carrier substrate. A porous layer may be used to separate the donor layer.Type: ApplicationFiled: April 30, 2012Publication date: November 1, 2012Applicant: AMBERWAVE INC.Inventors: Anthony Lochtefeld, Chris Leitz, Mark Carroll
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Patent number: 8298849Abstract: Methods for forming Cu—In—Ga—N (CIGN) layers for use in TFPV solar panels are described using reactive PVD deposition in a nitrogen containing atmosphere. In some embodiments, the CIGN layers can be used as an absorber layer and eliminate the need of a selenization step. In some embodiments, the CIGN layers can be used as a protective layer to decrease the sensitivity of the CIG layer to oxygen or moisture before the selenization step. In some embodiments, the CIGN layers can be used as an adhesion layer to improve the adhesion between the back contact layer and the absorber layer.Type: GrantFiled: October 10, 2011Date of Patent: October 30, 2012Assignee: Intermolecular, Inc.Inventors: Guowen Ding, Hien Minh Huu Le, Guizhen Zhang
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Publication number: 20120266958Abstract: Described are embodiments including an apparatus that provides a thin film solar cell base structure for a photovoltaic device, a method of manufacturing a photovoltaic device, a roll to roll method of manufacturing a thin film solar cell base structure, and a ruthenium alloy sheet material.Type: ApplicationFiled: April 26, 2012Publication date: October 25, 2012Applicant: SoloPower, Inc.Inventors: Serdar Aksu, Sarah Lastella, Alan Kleiman-Shwarsctein, Shirish Pethe, Mustafa Pinarbasi
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Patent number: 8294023Abstract: A radioisotope power sources that includes radioisotope nanoparticles and scintillator materials. An embodiment of the radioisotope power source includes radioisotope nanoparticles suspended within a polycrystalline scintillator; additional polycrystalline scintillator at least partially surrounding the polycrystalline scintillator with the radioisotope nanoparticles; and a photovoltaic device in light communication with the surrounding polycrystalline scintillator. A system that employs the radioisotope power source and a method of generating an electrical current are also disclosed. The present invention has been described in terms of specific embodiment(s), and it is recognized that equivalents, alternatives, and modifications, aside from those expressly stated, are possible and within the scope of the appending claims.Type: GrantFiled: October 29, 2009Date of Patent: October 23, 2012Assignee: General Electric CompanyInventors: Brent Allen Clothier, Matthew Christian Nielsen, Todd Ryan Tolliver, Allen Lawrence Garner
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Patent number: 8278549Abstract: The invention relates to a solar photovoltaic energy conversion apparatus. The apparatus consists of a substrate, a buffer layer formed on the substrate layer, a first transparent conductive oxide layer formed on the buffer layer, periodic protrusions containing first silicon layers formed on the first transparent conductive oxide layer, second silicon layers formed on the first silicon layers, a second transparent conductive oxide layer covering the first silicon layers, the second silicon layers and the first transparent conductive oxide layer, and an anti-reflective protective layer. The first silicon layer and the second silicon layer are the electrodes with the opposite type of charge carriers. The first transparent conductive layer and the second transparent conductive layer are the electrodes with the opposite type of charge carriers. This TCO-based hybrid solar photovoltaic energy conversion device not only can allow the transmission of visible sunlight but also can enhance the photovoltaic energy.Type: GrantFiled: October 1, 2008Date of Patent: October 2, 2012Assignee: Chang Gung UniversityInventors: Hsin-Chun Lu, Kuo-mei Wu, Pen-Hsiu Chang, Chun-Lung Chu, Chi-Yo Lai
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Publication number: 20120234391Abstract: The present disclosure relates to a method of manufacturing of a glass coated material that is suitable for use in the manufacture of flexible solar cells and other electronic devices. The invention is also to articles comprising the flexible solar cells described herein.Type: ApplicationFiled: September 14, 2011Publication date: September 20, 2012Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: Salah Boussaad, Damien Francis Reardon
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Publication number: 20120234368Abstract: The object of the invention is a substrate for photovoltaic cell comprising at least one sheet of float glass provided on a face of at least one electrode, characterized in that said glass has a chemical composition comprising the following constituents, in a weight content that varies within the limits defined below: SiO2 69-75% Al2O3 ?0-3% CaO + MgO 11-16.2%? MgO ?0-6.5% Na2O 9-12.4%? K2O ?0-1.5%.Type: ApplicationFiled: March 5, 2012Publication date: September 20, 2012Applicant: Saint-Gobain Glass FranceInventors: Octavio CINTORA, Guillaume Fourty
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Publication number: 20120234392Abstract: A photoelectric conversion device with high open-circuit voltage and high conversion efficiency is provided. A photoelectric conversion device including a p-n junction is formed by stacking a first semiconductor layer having p-type conductivity, a second semiconductor layer having p-type conductivity, and a third semiconductor layer having n-type conductivity between a pair of electrodes. The first semiconductor layer is a compound semiconductor layer, and the second semiconductor layer is formed using an organic compound and an inorganic compound. A material having a high hole-transport property is used as the organic compound, and a transition metal oxide having an electron-accepting property is used as the inorganic compound.Type: ApplicationFiled: March 2, 2012Publication date: September 20, 2012Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.Inventors: Yoshinobu Asami, Shunpei Yamazaki
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Patent number: 8268270Abstract: A coating solution for forming a light-absorbing layer of a chalcopyrite solar cell, including a hydrazine-coordinated Cu chalcogenide complex, a hydrazine-coordinated In chalcogenide complex and hydrazine-coordinated Ga chalcogenide complex dissolved in dimethylsulfoxide, the hydrazine-coordinated Cu chalcogenide complex being obtained by dissolving Cu or Cu2Se and a chalcogen in dimethylsulfoxide having hydrazine added, and adding a poor solvent to the resulting solution.Type: GrantFiled: June 10, 2011Date of Patent: September 18, 2012Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Masaru Kuwahara, Koichi Misumi, Hidenori Miyamoto
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Publication number: 20120227798Abstract: The present application utilizes an oxidation process to fabricating a Group III-V compound semiconductor solar cell device. By the oxidation process, a window layer disposed on a cell unit is oxidized to enhance the efficiency of the solar cell device. The oxidized window has an increased band gap to minimize the surface recombination of electrons and holes. The oxidized window also improves transparency at the wavelengths that were absorbed in the conventional window layer.Type: ApplicationFiled: May 29, 2012Publication date: September 13, 2012Applicant: MICROLINK DEVICES, INC.Inventors: Noren PAN, Christopher YOUTSEY, David S. MCCALLUM, Victor C. ELARDE, John M. DALLESASSE
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Publication number: 20120227809Abstract: An assembly including a pressure sensitive adhesive layer at least 0.25 mm in thickness disposed on a barrier assembly, wherein the barrier assembly comprises a polymeric film substrate and a barrier film. The assembly is flexible and transmissive to visible and infrared light. A pressure sensitive adhesive in the form of a film at least 0.25 mm thick is also provided, the pressure sensitive adhesive including a polyisobutylene having a weight average molecular weight less than 300,000 grams per mole; and a hydrogenated hydrocarbon tackifier. Methods of making and using the assembly and the pressure sensitive adhesive are also included.Type: ApplicationFiled: November 17, 2010Publication date: September 13, 2012Inventors: Vivek Bharti, Timothy J. Hebrink, Andrew J. Henderson, Jay M. Jennen, Alan K. Nachtigal, Gregg A. Patnode, Karl B. Richter, Mark A. Roehrig, Mark D. Weigel
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Publication number: 20120227790Abstract: The assemblies of the present disclosure comprise an electrode, and a polyimide film. The polyimide film comprises a sub-micron filler and a polyimide. The polyimide is derived from at least one aromatic dianhydride component selected from rigid rod dianhydride, non-rigid rod dianhydride and combinations thereof, and at least one aromatic diamine component selected from rigid rod diamine, non-rigid rod diamine and combinations thereof. The mole ratio of dianhydride to diamine is 48-52:52-48 and the ratio of X:Y is 20-80:80-20 where X is the mole percent of rigid rod dianhydride and rigid rod diamine, and Y is the mole percent of non-rigid rod dianhydride and non-rigid rod diamine. The sub-micron filler is less than 550 nanometers in at least one dimension; has an aspect ratio greater than 3:1; is less than the thickness of the film in all dimensions.Type: ApplicationFiled: November 19, 2010Publication date: September 13, 2012Applicant: E. I DU PONT DE NEMOURS AND COMPANYInventors: Brian C. Auman, Meredith L. Dunbar, Tao He, Kostantinos Kourtakis
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Publication number: 20120227811Abstract: The present invention describes a method of producing a photovoltaic solar cell with stoichiometric p-type copper indium gallium diselenide (CuInxGa1-xSe2) (abbreviated CIGS) as its absorber layer and II-IV semiconductor layers as the n-type layers with electrodeposition of all these layers. The method comprises a sequence of novel procedures and electrodeposition conditions with an ionic liquid approach to overcome the technical challenges in the field for low-cost and large-area production of CIGS solar cells with the following innovative advantages over the prior art: (a) low-cost and large-area electrodeposition of CIGS in one pot with no requirement of post-deposition thermal sintering or selenization; (b) low-cost and large-area electrodeposition of n-type II-VI semiconductors for the completion of the CIGS solar cell production; and (c) low-cost and large-area deposition of a buffer layer of CdS or other compounds with a simple chemical bath method.Type: ApplicationFiled: September 8, 2010Publication date: September 13, 2012Applicant: THE UNIVERSITY OF WESTERN ONTARIOInventors: Leo W. M. Lau, Zhifeng Ding, David Anthony Love, Mohammad Harati, Jun Yang
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Publication number: 20120227797Abstract: Inverted metamorphic multijunction solar cells having a heterojunction middle subcell and a graded interlayer, and methods of making same, are disclosed herein. The present disclosure provides a method of manufacturing a solar cell using an MOCVD process, wherein the graded interlayer is composed of (InxGa1-x)y Al1-yAs, and is formed in the MOCVD reactor so that it is compositionally graded to lattice match the middle second subcell on one side and the lower third subcell on the other side, with the values for x and y computed and the composition of the graded interlayer determined so that as the layer is grown in the MOCVD reactor, the band gap of the graded interlayer remains constant at 1.5 eV throughout the thickness of the graded interlayer.Type: ApplicationFiled: May 17, 2012Publication date: September 13, 2012Applicant: Emcore Solar Power, Inc.Inventors: Mark A. Stan, Arthur Cornfeld
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Patent number: 8263853Abstract: A method of forming a plurality of discrete, interconnected solar cells mounted on a carrier by providing a first semiconductor substrate; depositing on the first substrate a sequence of layers of semiconductor material forming a solar cell structure; forming a metal back contact layer over the solar cell structure; mounting a carrier on top of the metal back contact; removing the first substrate; and lithographically patterning and etching the solar cell structure to form a plurality of discrete solar cells mounted on the carrier.Type: GrantFiled: August 7, 2008Date of Patent: September 11, 2012Assignee: Emcore Solar Power, Inc.Inventor: Tansen Varghese
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Patent number: 8263855Abstract: Apparatus and Method for Optimizing the Efficiency of a Bypass Diode in Solar Cells. In a preferred embodiment, a layer of TiAu is placed in an etch in a solar cell with a contact at a doped layer of GaAs. Electric current is conducted through a diode and away from the main cell by passing through the contact point at the GaAs and traversing a lateral conduction layer. These means of activating, or “turning on” the diode, and passing the current through the circuit results in greater efficiencies than in prior art devices. The diode is created during the manufacture of the other layers of the cell and does not require additional manufacturing.Type: GrantFiled: May 7, 2010Date of Patent: September 11, 2012Assignee: Emcore Solar Power, Inc.Inventors: Paul R. Sharps, Marvin Brad Clevenger, Mark A Stan
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Publication number: 20120222742Abstract: A compound thin film solar cell of an embodiment includes: as a light-absorbing layer a semiconductor thin film which contains Cu, an element A (A is at least one element selected from a group consisting of Al, In and Ga) and Te, and has a chalcopyrite crystal structure, wherein a buffer layer that forms an interface with the light-absorbing layer is a compound which contains at least one element selected from Cd, Zn and a group consisting of In and Ga and at least one element selected from a group consisting of S, Se and Te, and has any crystal structure of a sphalerite structure, a wurtzite structure and a defect spinel structure, and a lattice constant “a” of the buffer layer with the sphalerite structure or a lattice constant “a” of the buffer layer at the time of converting the wurtzite structure or the defect spinel structure to the sphalerite structure is not smaller than 0.59 nm and not larger than 0.62 nm.Type: ApplicationFiled: March 16, 2012Publication date: September 6, 2012Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Naoyuki Nakagawa, Shinya Sakurada, Yasutaka Nishida, Satoshi Itoh, Michihiko Inaba
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Publication number: 20120211074Abstract: CIGS absorber layers fabricated using coated semiconducting nanoparticles and/or quantum dots are disclosed. Core nanoparticles and/or quantum dots containing one or more elements from group 13 and/or IIIA and/or VIA may be coated with one or more layers containing elements group IB, IIIA or VIA. Using nanoparticles with a defined surface area, a layer thickness could be tuned to give the proper stoichiometric ratio, and/or crystal phase, and/or size, and/or shape. The coated nanoparticles could then be placed in a dispersant for use as an ink, paste, or paint. By appropriate coating of the core nanoparticles, the resulting coated nanoparticles can have the desired elements intermixed within the size scale of the nanoparticie, while the phase can be controlled by tuning the stochiomctiy, and the stoichiometry of the coated nanoparticle may be tuned by controlling the thickness of the coating(s).Type: ApplicationFiled: May 7, 2012Publication date: August 23, 2012Inventors: Brian M. Sager, Dong Yu, Matthew R. Robinson
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Patent number: 8247684Abstract: A solar cell includes a graphite substrate, an amorphous carbon layer having a thickness of not less than 20 nm and not more than 60 nm formed on the graphite substrate, an AlN layer formed on the amorphous carbon layer, a n-type nitride semiconductor layer formed on the AlN layer; a light-absorption layer including a nitride semiconductor layer formed on the n-type nitride semiconductor layer; a p-type nitride semiconductor layer formed on the light-absorption layer; a p-side electrode electrically connected to the p-type nitride semiconductor layer; and an n-side electrode electrically connected to the n-type nitride semiconductor layer. The amorphous carbon layer is obtained by oxidizing the surface of the graphite substrate.Type: GrantFiled: April 29, 2011Date of Patent: August 21, 2012Assignee: Panasonic CorporationInventors: Nobuaki Nagao, Takahiro Hamada, Akihiro Itoh
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Publication number: 20120204957Abstract: A method for growing an In(x)Al(y)Ga(1?x?y)N layer (where x is greater than zero and less than or equal to one, y is greater than or equal to zero and less than or equal to one and the sum of x and y is less than or equal to one). The method includes supplying plasma-activated nitrogen atoms as a source of nitrogen for the In(x)Al(y)Ga(1?x?y)N layer to a growth surface, where a flux of the plasma-activated nitrogen atoms supplied to the growth surface is at least four times higher than a total flux of aluminium and gallium atoms also supplied to the growth surface, where either the aluminium or gallium flux may or may not be zero; and simultaneously supplying indium atoms and nitrogen-containing molecules to the growth surface.Type: ApplicationFiled: February 10, 2011Publication date: August 16, 2012Inventors: David NICHOLLS, Tim Michael Smeeton, Valerie Berryman-Bousquet, Stewart Edward Hooper
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Patent number: 8241943Abstract: A method of sodium doping in fabricating CIGS/CIS based thin film solar cells includes providing a shaped substrate member. The method includes forming a barrier layer over the surface region followed by a first electrode layer, and then a sodium bearing layer. A precursor layer of copper, indium, and/or gallium materials having an atomic ratio of copper/group III species no greater than 1.0 is deposited over the sodium bearing layer. The method further includes transferring the shaped substrate member to a second chamber and subjecting it to a thermal treatment process within an environment comprising gas-phase selenium species, followed by an environment comprising gas-phase sulfur species with the selenium species being substantially removed to form an absorber layer.Type: GrantFiled: May 5, 2010Date of Patent: August 14, 2012Assignee: Stion CorporationInventors: Robert D. Wieting, Steven Aragon, Chester A. Farris, III
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Publication number: 20120199185Abstract: A photovoltaic (PV) device, comprising a PV interband cascade (IC) stage, wherein the IC PV stage comprises an absorption region with a band gap, the absorption region configured to absorb photons, an intraband transport region configured to act as a hole barrier, and an interband tunneling region configured to act as an electron barrier. An IC PV architecture for a photovoltaic device, the IC PV architecture comprising an absorption region, an intraband transport region coupled to the absorption region, and an interband tunneling region coupled to the intraband transport region and to the adjacent absorption region, wherein the absorption region, the intraband transport region, and the interband tunneling region are positioned such that electrons will flow from the absorption region to the intraband transport region to the interband tunneling region.Type: ApplicationFiled: February 9, 2011Publication date: August 9, 2012Applicant: BOARD OF REGENTS UNIVERSITY OF OKLAHOMAInventors: Rui Q. Yang, Zhaobing Tian, Tetsuya D. Mishima, Michael B. Santos, Matthew B. Johnson, John F. Klem
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Publication number: 20120199203Abstract: Provided are a glass sheet for a CIGS solar cell which satisfies both of high power generation efficiency and high glass transition temperature, and a CIGS solar cell having high power generation efficiency. A glass sheet for a Cu—In—Ga—Se solar cell containing, in terms of mol % on the basis of the following oxides, 60 to 75% of SiO2, 3 to 10% of Al2O3, 0 to 3% of B2O3, 5 to 18% of MgO, 0 to 5% of CaO, 4 to 18.5% of Na2O, 0 to 17% of K2O, and 0% or more and less than 10% of SrO+BaO+ZrO2, wherein K2O/(Na2O+K2O) is 0 to 0.5, and the glass sheet has a glass transition temperature (Tg) of more than 550° C.Type: ApplicationFiled: April 18, 2012Publication date: August 9, 2012Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Manabu Nishizawa, Yuichi Kuroki, Tatsuo Nagashima, Yasushi Kawamoto, Shigeru Niki, Shogo Ishizuka
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Publication number: 20120192923Abstract: In one aspect of the present invention, a photovoltaic device is provided. The photovoltaic device includes a first semiconductor layer; a p+-type semiconductor layer; and an interlayer interposed between the first semiconductor layer and the p+-type semiconductor layer, wherein the interlayer includes magnesium and tellurium.Type: ApplicationFiled: February 1, 2011Publication date: August 2, 2012Applicant: GENERAL ELECTRIC COMPANYInventors: Bastiaan Arie Korevaar, James William Bray
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Patent number: 8232470Abstract: An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (VOC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.Type: GrantFiled: September 11, 2009Date of Patent: July 31, 2012Assignee: Rosestreet Labs Energy, Inc.Inventors: Wladyslaw Walukiewicz, Kin Man Yu
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Publication number: 20120186640Abstract: A photoelectric conversion device which is a semiconductor device comprising a first conductive layer having a first conductivity type; a second conductive layer formed on the first conductive layer and having a second conductivity type; and a photosensitizing layer formed between the first conductive layer and the second conductive layer, wherein charge carriers generated by photoelectric conversion in the photosensitizing layer are freely movable to at least one of the first conductive layer and the second conductive layer.Type: ApplicationFiled: August 5, 2010Publication date: July 26, 2012Applicant: NATIONAL UNIVERSITY CORPORATION CHIBA UNIVERSITYInventors: Akihiko Yoshikawa, Yoshihiro Ishitani, Kazuhide Kusakabe
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Patent number: 8227885Abstract: A selective light absorbing semiconductor surface is disclosed. Said semiconductor surface is characterized by the presence of indentations or protrusions comprising a grating of dimensions such as to enhance the absorption of selected frequencies of radiation. In a preferred embodiment of the present invention, said grating is formed on the surface of a doped semiconductor for the purposes of optical frequency down conversion. The semiconductor is doped so as to create energy levels within the forbidden zone between the conduction and valence bands. Incident radiation excites electrons from the valence to conduction band from where they decay to the meta-stable newly created energy level in the forbidden zone. From there, electrons return to the valence band, accompanied by the emission of radiation of lower frequency than that of the incident radiation. Optical frequency down-conversion is thus efficiently and rapidly accomplished.Type: GrantFiled: July 5, 2007Date of Patent: July 24, 2012Assignee: Borealis Technical LimitedInventors: Avto Tavkhelidze, Amiran Bibilashvili, Zaza Taliashvili
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Publication number: 20120180870Abstract: A photoelectric conversion device includes a layered structure formed on a substrate including a first electrode, a photoelectric conversion semiconductor layer and a second electrode, the photoelectric conversion semiconductor layer being mainly composed of a compound semiconductor containing group Ib, group IIIb and group VIb elements, and containing an alkaline(-earth) metal, wherein the alkaline(-earth) metal concentration distribution in the photoelectric conversion layer in the thickness direction includes a valley with the lowest alkaline(-earth) metal concentration and an area with an alkaline(-earth) metal concentration higher than that at the valley, the area being nearer to the substrate from the valley, and wherein Expressions (1) and (2) below are satisfied: 1.0×10?6?a [mol/cc]?2.0×10?5??(1) and 1.5?b/a?4.Type: ApplicationFiled: September 30, 2010Publication date: July 19, 2012Applicant: FUJIFILM CORPORATIONInventor: Kana Yamamoto
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Publication number: 20120180857Abstract: A conversion solar cell structure responds to a greater portion of the solar spectrum. The solar-cell structure has a solar cell and a conversion material disposed over the solar cell.Type: ApplicationFiled: January 17, 2012Publication date: July 19, 2012Inventor: Michael Tischler
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Publication number: 20120180869Abstract: Provided are a solar cell apparatus and a method of manufacturing the same. The solar cell apparatus includes a substrate, a rear electrode layer disposed on the substrate, a thin film layer disposed on the rear electrode layer, the thin film layer including a Group VI-based element, a light absorption layer disposed on the thin film layer, and a front electrode layer on the light absorption layer.Type: ApplicationFiled: September 30, 2010Publication date: July 19, 2012Applicant: LG INNOTEK CO., LTD.Inventors: Suk Jae Jee, Kyung Am Kim
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Publication number: 20120180868Abstract: A III-nitride photovoltaic device structure and method for fabricating the III-nitride photovoltaic device that increases the light collection efficiency of the III-nitride photovoltaic device. The III-nitride photovoltaic device includes one or more III-nitride device layers, and the III-nitride photovoltaic device functions by collecting light that is incident on the back-side of the III-nitride device layers. The III-nitride device layers are grown on a substrate, wherein the III-nitride device layers are exposed when the substrate is removed and the exposed III-nitride device layers are then intentionally roughened to enhance their light collection efficiency. The collection of the incident light via the back-side of the device simplifies the fabrication of the multiple junctions in the device. The III-nitride photovoltaic device may include grid-like contacts, transparent or semi-transparent contacts, or reflective contacts.Type: ApplicationFiled: October 21, 2011Publication date: July 19, 2012Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Robert M. Farrell, Carl J. Neufeld, Nikholas G. Toledo, Steven P. DenBaars, Umesh K. Mishra, James S. Speck, Shuji Nakamura
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Patent number: 8217261Abstract: A method for fabricating a thin film solar cell includes providing a soda lime glass substrate comprising a surface region and a concentration of sodium oxide of greater than about 10 wt % and treating the surface region with one or more cleaning process, using a deionized water rinse, to remove surface contaminants having a particles size of greater than three microns. The method also includes forming a barrier layer overlying the surface region, forming a first molybdenum layer in tensile configuration overlying the barrier layer, and forming a second molybdenum layer in compressive configuration using a second process overlying the first molybdenum layer. Additionally, the method includes patterning the first molybdenum layer and the second molybdenum layer to form a lower electrode layer and forming a layer of photovoltaic material overlying the lower electrode layer. Moreover, the method includes forming a first zinc oxide layer overlying the layer of photovoltaic materials.Type: GrantFiled: September 25, 2009Date of Patent: July 10, 2012Assignee: Stion CorporationInventor: Robert D. Wieting
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Patent number: 8217258Abstract: Extremely high efficiency solar cells are described. Novel alternating bias schemes enhance the photovoltaic power extraction capability above the cell band-gap by enabling the extraction of hot carriers. In conventional solar cells, this alternating bias scheme has the potential of more than doubling their yielded net efficiency. In solar cells incorporating quantum wells (QWs) or quantum dots (QDs), the alternating bias scheme has the potential of extending such solar cell power extraction coverage, possibly across the entire solar spectrum, thus enabling unprecedented solar power extraction efficiency. Within such cells, a novel alternating bias scheme extends the cell energy conversion capability above the cell material band-gap while the quantum confinement structures are used to extend the cell energy conversion capability below the cell band-gap.Type: GrantFiled: June 21, 2011Date of Patent: July 10, 2012Assignee: Ostendo Technologies, Inc.Inventors: Hussein S. El-Ghoroury, Dale A. McNeill, Selim E. Guncer
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Patent number: 8206616Abstract: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.Type: GrantFiled: October 31, 2007Date of Patent: June 26, 2012Assignee: Nanosolar, Inc.Inventors: Dong Yu, Jacqueline Fidanza, Brian M. Sager
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Patent number: 8193443Abstract: The present invention relates to a photovoltaic cell, a method of manufacturing such photovoltaic cell, and to uses of such cell.Type: GrantFiled: December 21, 2007Date of Patent: June 5, 2012Assignees: Sony Deutschland GmbH, Sony CorporationInventors: Michael Duerr, Gabriele Nelles, Akio Yasuda, Masahiro Morooka, Yusuke Suzuki, Kazuhiro Noda
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Patent number: 8193442Abstract: CIGS absorber layers fabricated using coated semiconducting nanoparticles and/or quantum dots are disclosed. Core nanoparticles and/or quantum dots containing one or more elements from group IB and/or IIIA and/or VIA may be coated with one or more layers containing elements group IB, IIIA or VIA. Using nanoparticles with a defined surface area, a layer thickness could be tuned to give the proper stoichiometric ratio, and/or crystal phase, and/or size, and/or shape. The coated nanoparticles could then be placed in a dispersant for use as an ink, paste, or paint. By appropriate coating of the core nanoparticles, the resulting coated nanoparticles can have the desired elements intermixed within the size scale of the nanoparticle, while the phase can be controlled by tuning the stochiometry, and the stoichiometry of the coated nanoparticle may be tuned by controlling the thickness of the coating(s).Type: GrantFiled: December 11, 2007Date of Patent: June 5, 2012Assignee: Nanosolar, Inc.Inventors: Brian M. Sager, Dong Yu, Matthew R. Robinson
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Publication number: 20120132281Abstract: A thin-film solar cell and a manufacturing method thereof are disclosed. The method of manufacturing the thin-film solar cell includes the steps of providing a substrate; forming a diffusion barrier layer on the substrate; forming a back electrode layer on the diffusion barrier layer; forming a precursor layer on the back electrode layer, and the precursor layer including at least Cu, In and Ga; providing an alkali layer on an upper surface of the precursor layer, and the alkali layer being formed of Li, Na, K, Rb, Cs, or an alkali metal compound; providing a selenization process for the precursor layer and the alkali layer to form an absorber layer, such that an atomic percentage concentration of the alkali metal in the absorber layer is ranged between 0.01%˜10%; forming at least a buffer layer on the absorber layer; and forming at least a front electrode layer on the buffer layer.Type: ApplicationFiled: November 26, 2010Publication date: May 31, 2012Applicant: NEXPOWER TECHNOLOGY CORPORATIONInventors: CHIEN-PANG YANG, CHIH-HUNG YEH
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Publication number: 20120132282Abstract: A compositional range of high strain point alkali metal free, silicate, aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points ?570° C., thermal expansion coefficient of from 5 to 9 ppm/° C.Type: ApplicationFiled: November 28, 2011Publication date: May 31, 2012Inventors: Bruce Gardiner Aitken, James Edward Dickinson, JR.
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Patent number: 8188367Abstract: A method of forming a doped Group IBIIIAVIA absorber layer for solar cells by reacting a partially reacted precursor layer with a dopant structure. The precursor layer including Group IB, Group IIIA and Group VIA materials such as Cu, Ga, In and Se are deposited on a base and partially reacted. After the dopant structure is formed on the partially reacted precursor layer, the dopant structure and partially reacted precursor layer is fully reacted. The dopant structure includes a dopant material such as Na.Type: GrantFiled: January 11, 2011Date of Patent: May 29, 2012Assignee: SoloPower, Inc.Inventor: Bulent M. Basol
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Patent number: 8182720Abstract: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.Type: GrantFiled: October 31, 2007Date of Patent: May 22, 2012Assignee: Nanosolar, Inc.Inventors: Dong Yu, Jacqueline Fidanza, Brian M. Sager
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Patent number: 8182721Abstract: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.Type: GrantFiled: October 31, 2007Date of Patent: May 22, 2012Assignee: Nanosolar, Inc.Inventors: Dong Yu, Jacqueline Fidanza, Brian M. Sager
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Publication number: 20120118384Abstract: In order to provide a CIS-based thin film solar cell having high photoelectric conversion efficiency, this CIS-based thin film solar cell is laminated in order of a high distortion point glass substrate (1), an alkali control layer (2), a back electrode layer (3), a p-type CIS-based light absorbing layer (4), and an n-type transparent conductive film (6), wherein said alkali control layer (2) is a silica film whose film thickness is within a range of 2.00-10.00 nm and whose refractive index is within a range of 1.450-1.500.Type: ApplicationFiled: June 18, 2010Publication date: May 17, 2012Applicant: SHOWA SHELL SEKIYU K.K.Inventors: Hideki Hakuma, Hiroki Sugimoto, Shunsuke Kijima, Yoshiaki Tanaka
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Publication number: 20120118363Abstract: Disclosed is a device comprising: an anode; a cathode; an inorganic substrate; and at least one organic window layer positioned between: the anode and the inorganic substrate; or the cathode and the inorganic substrate. Also disclosed is a method of enhancing the performance of a photosensitive device having an anode, a cathode, and an inorganic substrate, comprising: positioning at least one organic window layer between the anode and the cathode. In one embodiment the organic window layer may absorb light and generate excitons that migrate to the inorganic where they convert to photocurrent, thereby increasing the efficiency of the device. Also disclosed is a method of enhancing Schottky barrier height of a photosensitive device, the method being substantially similar to the previously defined method.Type: ApplicationFiled: September 14, 2011Publication date: May 17, 2012Inventors: Stephen R. Forrest, Ning Li
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Patent number: 8173891Abstract: Modeling a monolithic, multi-bandgap, tandem, solar photovoltaic converter or thermophotovoltaic converter by constraining the bandgap value for the bottom subcell to no less than a particular value produces an optimum combination of subcell bandgaps that provide theoretical energy conversion efficiencies nearly as good as unconstrained maximum theoretical conversion efficiency models, but which are more conducive to actual fabrication to achieve such conversion efficiencies than unconstrained model optimum bandgap combinations. Achieving such constrained or unconstrained optimum bandgap combinations includes growth of a graded layer transition from larger lattice constant on the parent substrate to a smaller lattice constant to accommodate higher bandgap upper subcells and at least one graded layer that transitions back to a larger lattice constant to accommodate lower bandgap lower subcells and to counter-strain the epistructure to mitigate epistructure bowing.Type: GrantFiled: May 15, 2008Date of Patent: May 8, 2012Assignee: Alliance for Sustainable Energy, LLCInventors: Mark W. Wanlass, Angelo Mascarenhas
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Patent number: 8173888Abstract: A solar energy collection system and components includes a vacuum and an air compressor. The system includes a plurality of flexible units each having a backing portion and a solar cell portion upwardly adjacent and coupled to the backing portion. Each backing portion includes adhesive and at least one channel in the adhesive. Each channel is configured for communication with the vacuum to withdraw air from the channel when the adhesive is initially coupled to a structure and for communication with an air compressor to provide air to the channel to separate the adhesive from the structure. Each solar cell portion has an electricity generating element. The structure for coupling units transfers electricity between units. Each unit has an electricity outlet for passing electricity generated by at least one generating element for storage or use.Type: GrantFiled: January 19, 2009Date of Patent: May 8, 2012Inventor: Paul C. Dziadik
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Publication number: 20120103411Abstract: A photovoltaic module may include a back glass including a cobalt oxide or copper oxide.Type: ApplicationFiled: October 28, 2011Publication date: May 3, 2012Inventor: Pedro Gonzalez
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Publication number: 20120103419Abstract: A group-III nitride solar cell is grown on a thin piece of a group-III nitride crystal that has been mounted on a carrier comprised of a foreign material. The thin piece is a thin layer with a thickness that ranges from approximately 5 microns to approximately 300 microns.Type: ApplicationFiled: October 25, 2011Publication date: May 3, 2012Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Siddha Pimputkar, Shuji Nakamura, Steven P. DenBaars
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SINGLE JUNCTION TYPE CIGS THIN FILM SOLAR CELL AND METHOD FOR MANUFACTURING THE THIN FILM SOLAR CELL
Publication number: 20120103418Abstract: Provided is a single junction type CIGS thin film solar cell, which includes a CIGS light absorption layer manufactured using a single junction. The single junction type CIGS thin film solar cell includes a substrate, a back contact deposited on the substrate, a light absorption layer deposited on the back contact and including a P type CIGS layer and an N type CIGS layer coupled to the P type CIGS layer using a single junction, and a reflection prevention film deposited on the light absorption layer.Type: ApplicationFiled: August 11, 2011Publication date: May 3, 2012Applicant: ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTEInventors: Yong-Duck CHUNG, Won Seok Han