Abstract: A hose for automotive fuel piping has an inner layer formed of a molding of a terpolymeric fluoro-resin prepared from tetrafluoroethylene, hexafluoropropylene and vinylidene fluoride, so that it can be provided with suitable flexibility. Both the vulcanization composition of an epichlorohydrin rubber or NBR/PVC blend to be disposed outside the inner layer and the vulcanization composition of an NBR rubber or fluororubber to be disposed inside the inner layer contain 1,8-diazablcylco(5.4.0)undecene-7 salts and organophosphonium salts. A satisfactory bonding strength can be attained merely by the vulcanlzation bonding without any surface treatment such as corona discharge on the surface of the inner layer fluororesin.

Abstract: A coolant conduit, which is an elongate tubular article for an apparatus requiring cooling by a cooling agent, includes a plurality of layers which are provided by, in combination, discharging a co-axial melt hose, 3D tubing manipulation, and blow molding thereof, each layer of the plurality being composed of a polymeric material which is thermoplastically processable. The plurality of layers preferably includes at least one inner layer which is composed of a polymeric material which is substantially inert to the cooling agent and which is substantially non-swelling; and an outer layer which is composed of at least one polyamide and which has a high pressure resistant which conveys a high bursting strength.

Abstract: A wooden tube made up of tubular layers of wood veneer and the method of making it in which the various tubular layers are made from flat sheets of wood veneer having the grain in one layer extending longitudinally and the grain in an adjacent layer extending circumferentially of the tube so that the grain in adjacent layers extend transversely of each other with all joints extending in the direction of the wood grain being edge to edge butt joints and all joints extending transversely to the wood grain being interlocking finger joints and with adjoining tubular layers being bonded to each other to form a unitary tube.

Abstract: An improved pipe is produced from phenylene sulfide/biphenylene sulfide copolymers, The improved pipe has greater flexibility and ductility than pipe produced from normal PPS resin. Such pipe is produced by preparing a phenylene sulfide/biphenylene sulfide copolymer and forming the copolymer into essentially amorphous pipe by extrusion followed by rapid and uniform quench to avoid pipe crystallization, Also disclosed is a method wherein such amorphous pipe is oriented by subsequent die extrusion.

Abstract: Hoses are provided which are resistant to chemical and thermal attack and which include a polymeric liner having an integral resilient member axially located along its wall. The resilient member includes a tensile strength which is significantly greater than the polymeric material of the liner, so as to minimize the incidence of plastic deformation and kinking during manufacture, installation, and use.

Abstract: The present invention provides a composite or hose which minimizes hydrocarbon emission in fuel systems. The composite or hose is especially suitable for motor vehicles. The composite or hose uses a thin, inner layer of a polyfluorocarbon polymer and an outer layer of a thermoplastic elastomer.

Abstract: A molding process includes flowing a polymer melt into the cavity of a mold which includes a core pin. After the mold is filled and skin layers of solidified polymer have formed adjacent the mold wall and core pin wall, the core pin is spun transversely to the direction of polymer melt flow. The invention includes hollow articles of improved mechanical properties made by the process.

Abstract: An elongated fuel and vapor tube suitable for conveying fluids containing hydrocarbons having a first layer disposed radially innermost and having an inner surface capable of prolonged exposure to the hydrocarbon-containing fluid made up of a melt processible fluoroplastic terpolymer composed of a polyfluorinated alkylene, an .alpha.-fluoro-olefin and a fluorinated vinyl compound and a second layer bonded directly to the outwardly oriented face of the first layer. The second layer is composed of a resinous thermoplastic material which is preferably a polyamide such as Nylon 12, Nylon 11, Nylon 6 or Nylon 6.6.

Abstract: A fire safety coating, particularly intended for application to hydrocarbon-conducting steel pipes (1) in the splash zone underneath oil plants at sea, consists of at least three layers, where the outer layer (5) is a mechanical protecting layer of rubber or plastic material, the next inside layer (4) is a flame-stopping layer comprising inorganic fibers and a rubber material, and an inside layer (3) is a rubber material which reacts particularly at a high temperature to liberate gases which both prevent inward penetration of oxygen and cause a transformation of the rubber material in the flame-stopping layer (4) to form a hard shell.

Abstract: Multilayered tubing which exhibits one or more desirable characteristics of polyvinyl chloride (PVC) tubings, such as clarity, flexibility and toughness, but without the environmental and health hazards associated with PVC materials, is provided. Also provided is a method of preparing such tubing.

Abstract: An insert system for repairing defects in underground conduits in situ comprises a tubular inner liner of stiff material having a generally smooth inner surface and a plurality of integral outer circumscribing ribs defining a plurality of valleys between the ribs. An outer sleeve circumscribes the inner liner and is formed of an elastomeric material. A mid-layer of reinforcing woven material is wrapped about the inner liner within the outer sleeve. A hardenable resin saturates the mid-layer and fills the valleys. The resin bonds to the inner liner to form a structural insert, and the outer sleeve provides a deformable seal against an inner surface of a conduit when the insert system is operatively positioned.

Abstract: A coolant conduit which is an elongate tubular article for an apparatus requiring cooling by a cooling agent, such as an engine, for example, an internal combustion engine, includes a plurality of layers which are provided by sequential coextrusion thereof and which are adjoined thereby, each layer of the plurality being comprised of a polymeric material which is thermoplastically processable. The plurality of layers may include an inner layer which is composed of a polymeric material which is substantially inert to cooling agent and which is substantially non-swelling, and an outer layer which is composed of at least one polyamide and which is pressure resistant. The coolant conduit may include a plurality of longitudinal sections, and at least one layer of the plurality of layers may then be composed of a polymeric material which differs between longitudinal sections thereof as is made possible by sequential coextrusion thereof.

Abstract: Multilayer plastic pipes having at leastI. a layer based on a molding composition of polyamide; andII. a layer adjacent to layer I and based on a molding containing a mixture of(a) from 97.5 to 50% by weight of polyvinylidene fluoride; and(b) from 2.5 to 50% by weight of an acrylate copolymer,with the layers adhering to one another, are provided. These pipes exhibit improved resistance to chemical agents such as, methanol-containing fuels, without the loss of typical properties of polyamide and polyvinylidene fluoride.

Abstract: A shell for protectively enveloping insulation of pipes and pipe fittings is disclosed. The shell comprises a thermoformed laminate of (a) polyvinyl fluoride layer having a thickness of about 0.0015 to 0.004 inch, (b) polycarbonate layer having a thickness of about 0.005 to 0.060 inch and (c) a heat activated, stretchable adhesive layer having a thickness of about 0.0002 to 0.0004 inch interposed between said (a) and said (b).In a preferred embodiment, the adhesive layer is acrylate based.

Abstract: A reinforced rubber hose having a layer of ethylene-propylene rubber outside or inside a fiber-reinforcing layer. The two layers are firmly bonded to each other by an extruded adhesive layer of butyl rubber which exhibits a high bond strength after vulcanization. This obviates the necessity of treating (usually by dipping) the fibrous reinforcement with an adhesive before its braiding or knitting.

Abstract: This invention relates to novel macrocomposite bodies. More particularly, it has been discovered that the properties of a ceramic, ceramic matrix composite or metal matrix composite body may be improved by providing on at least a portion of the surface of the body a polymer-based material which serves to protect the body from damage which might occur in the absence of the polymer-based material. One particularly preferred embodiment of the present invention is a macrocomposite shaft sleeve. Another particularly preferred embodiment is a macrocomposite apex used in a hyrocyclone separator.

Abstract: A multi-layer tube having a metal tube having an outer surface and a zinc layer bonded to the metal tube outer surface. The zinc layer being selected from the group consisting of zinc plating, zinc nickel alloys, zinc cobalt alloys, zinc aluminum alloys, and mixtures thereof. A surface treatment layer is bonded to the zinc layer, wherein the surface treatment layer is selected from the group consisting of a zinc/aluminum/rare earth alloy, phosphate, chromate and mixtures thereof. A first polymeric layer is bonded to the surface treatment layer, wherein the first polymeric layer is selected from the group consisting of a thermoplastic elastomer, an ionomer, a nylon, a fluoropolymer, and mixtures thereof. A second polymeric layer is bonded to the first polymeric layer, wherein the second polymeric layer is selected from the group consisting of a nylon, a thermoplastic elastomer, a fluoropolymer, and mixtures thereof.

Abstract: There is provided a hose end structure comprising an inner layer of a low gas permeability material having a radially outwardly extended end portion, and a rubber layer on an inner surface of the radially outwardly extended end portion.

Abstract: A method and apparatus for extruding a multi-layer plastic pipe are provided wherein a second liquified plastic is injected into and through a prow and, subsequently, into a radial flow conduit of a die assembly in which a first liquified plastic flows through the radial flow conduit. Subsequently, the first and second liquified plastic are introduced into and through an annular flow conduit and a third liquified plastic is injected into the annular flow conduit of the die assembly. Wherein within the die assembly the first liquified plastic forms a first layer, the second liquified plastic forms a second layer inside the first layer and the third liquified plastic forms a third layer outside the first layer. Additionally, a multi-layered plastic pipe which can be produced by the inventive die assembly is provided. The multi-layered plastic pipe has an ultraviolet light-protective outer layer and a light-reflecting inner layer.

Abstract: A laminated hose is present which is suitable for a fuel conducting hose or other hose, or diaphragm, used for example in an automotive vehicle, which structure is required to have excellent heat resistance and gasoline permeation resistance while maintaining suitable properties of bonding and flexibility. The hose is constituted by an inner veneer layer of fluorovinylidene-hexafluoropropylene backed by a thin layer of Teflon. These layer are then reinforced by an elastomeric tie layer, a reinforcing layer and an elastomeric cover.

Abstract: The section of a main pipe wall made of synthetic resin material is formed to be substantially triangular and one inclined wall approaches the other inclined wall while the inclined wall goes over a center line passing through a top of both the inclined walls forming the main pipe wall and the approaching posture is capable of being maintained by itself. A second pipe wall, the wall thickness of which is smaller than that of the main pipe wall, is integrally connected with the inside of the pipe main wall, the section of the second pipe wall is substantially triangular, a bottom of the second pipe wall and predetermined portions of both the inclined walls at the bottom side adhere to a bottom of the main pipe wall and both the inclined walls, and a small space is formed between a top of the second pipe wall and the top of the main pipe wall.

Abstract: The present invention relates to a plastic pipe having improved resistance, inter alia, to methanol-containing fuels and improved mechanical properties, comprising.(I) at least one outer layer,(II) at least one inner layer comprising a polyvinylidene fluoride molding composition, and(III) a layer, disposed between the inner layer II and the outer layer I, comprising a molding composition comprising a mixture of:(a) polyamide and(b) polyalkyl acrylate,wherein the layers (I)-(III) are adhesively bonded to one another.

Abstract: A rigid, glass fiber airduct for conveying an airstream has an interior surface, adapted to be in contact with the airstream, which is coated with a polymeric coating comprising an organic or inorganic biocide. The polymeric coating has a dry solids content between 10 and 20 grams per square foot of duct board surface and retains its abrasion strength and puncture resistance whereby the interior surface of the airduct can be cleaned by conventional industrial or commercial cleaning procedures while in service without exposing glass fibers to the airstream.

Abstract: Multilayer plastic pipes comprising a polyamide-based inner and outer layer, wherein the inner and outer layer are connected force-lockingly by means of at least one intermediate layer made of a mixture of a linear crystalline polyester and a polyamide, have improved stability to chemical agents and improved mechanical properties.

Abstract: A layered tubing for use in a motor vehicle has a thick tubular inner layer formed of one or more sublayers of a synthetic resin having a predetermined hardness and a predetermined thickness and designed for use in a temperature range down to -40.degree. C., and a thin tubular outer crack-absorbing layer bonded externally to and surrounding the inner layer. The outer crack-absorbing layer is formed of a synthetic resin resistant to attach by lacquer solvent over the temperature range of the inner layer and having a hardness equal to at most 0.8 of the hardness of the inner layer and a thickness equal to at most 0.5 of the thickness of the inner layer. When lacquer is intentionally or accidentally applied to such tubing and the tubing subsequently is flexed at extremely low temperatures, the lacquer will crack but the soft outer layer will not transmit the sudden change in shape and energy to the inner layer, causing a crack therein.

Abstract: A plastic pipe having improved resistance, inter alia, to methanol-containing fuels and improved mechanical properties comprising:(I) an outer layer made of a moulding compound based on polyamide,(II) an intermediate layer adjacent to the outer layer and made of a moulding compound based on a mixture of:(a) of from 95 to 99% by weight of a linear crystalline polyester, and(b) of from 1 to 5% by weight of a compound having at least two isocyanate groups,wherein the isocyanate groups originating from component (IIb) are present in the mixture of (IIa) and (IIb) in a concentration of from 0.03 to 0.

Abstract: A multilayer synthetic material tube manufactured by co-extrusion and adapted to convey motor vehicle fuel, from the inside towards the outside, a layer of high-density polyethylene, a layer of polyethylene, comprising acrylic acid and/or maleic anhydride copolymer adhesive, and an outer layer of polyamide.

Abstract: A new curable compounded halopolymer that exhibits in the cured state good to excellent adhesion to polyamides. These curable halopolymer achieves better adhesion due to a balance of carbon black relative to talc, preferable with the cyclohexyl benzothiazole sulfenamide or related benzothiazole sulfenamide and are highly desirable in making specialty hoses and belts.

Abstract: A seamless double-walled metal tube which has an outer wall composed of steel having a face-centered cubic grain structure, an inner wall concentrically disposed within the outer wall, the inner wall composed of a steel having a face-centered cubic grain structure, the inner wall having an outerwardly oriented surface directed toward an inwardly oriented surface of the outer wall. The seamless double-wall metal tube also has an intermediate bonding metal region interposed between and metallurgically bonded to the inner wall and the outer wall. The intermediate bonding region is composed of a metal capable of metallurgically bonding with the inner wall and the outer wall.

Abstract: A plastic laminate having an apliphatic polyamide resin surface layer and a fluororesin surface layer is produced by using an intermediate layer formed of a blend of an aliphatic polyamide resin with a fluorine-containing graft copolymer, which is obtained by graft polymerization of a suitable monomer such as vinylidene fluoride, or a mixture of monomers, with an elastomeric copolymer of at least two principal monomers including at least one fluorine-containing monomer, e.g. vinyliden fluoride and chlorotrifluoroethylene, and an unsaturated peroxy compound. The fluorine-containing graft copolymer is a soft, flexible resin and is well compatible with aliphatic polyamide resins and also with various fluororesins. The fluororesin surface layer uses, for example, polyvinylidene fluoride, a vinyliden fluoride based copolymer or the fluorine-containing graft copolymer. The lamination can be accomplished by simply welding the two surface layers to the intermediate layer.

Abstract: A structural member of fiber reinforced composite material suitable for secondary processing and a method of processing is described. The structural member before secondary processing is typically a multi-ply tube, rod, or sheet formed with an outer sheath of fiber reinforced thermoplastic material having a melting temperature t.sub.m1 and an inner core material, also fiber reinforced thermoplastic, having a melting temperature, t.sub.m2 lower than t.sub.m1. The member, prior to secondary processing, is thermoplastic.In a secondary process the member is heated to a temperature between t.sub.m1 and t.sub.m2, but sufficient to render the outer sheath malleable. The member is deformed to a desired geometry, such as a helix, and cooled to a hardened state.

Abstract: A polyamide-based tube for transporting a gasoline having resistance to permeability therethrough of the gasoline consisting essentially of an outer polyamide layer and an inner polyvinylidene fluoride layer bonded together by an adhesion binder.

Abstract: A multilayer plastic pipe having improved barrier action against diffusion of the substance being transported, particularly methanol-containing fuels, dimensional stability, resistance to mechanical stress, and particularly improved adhesion between layers is provided comprising:(A) an inner layer and an outer layer, each of which comprise a polyamide-based molding composition, wherein the inner layer and outer layer may be the same or different, and (B) at least one intermediate layer comprisinga) 95 to 60% by weight of a linear, crystalline polyester andb) 5 to 40% by weight of a polymer containing reactive groups other than epoxide groups,wherein the reactive groups are contained in a concentration of from 4 to 95 mmol/kg based on the total amount of component (B); and wherein the layers are intimately bonded to one another.

Abstract: A layered tubing for use in a motor vehicle has a thick tubular inner layer formed of a synthetic resin having a predetermined hardness and a predetermined thickness and a thin tubular outer relax layer bonded externally to and surrounding the inner layer. This outer layer is formed of a synthetic resin having a hardness equal to at most 0.8 of the hardness of the inner layer and a thickness equal to at most 0.5 of the thickness of the inner layer. The inner layer can be one layer or can be formed of a plurality of coextruded and coaxial sublayers.

Abstract: A polymeric pipe lining composition consisting of 100 parts by weight of polyvinyl chloride, 0.5 to 3.5 parts of stabilizer, 5 to 30 parts of plasticizer, 0.4 to 2.0 parts of internal lubricant or wax, and 0.4 to 2.0 parts of external lubricant or wax. The composition is especially useful for in situ lining of sewers.

Abstract: Process for the manufacture of a flexible polymeric structure comprising a sealant barrier, consisting of a multilayer film a few microns thick, oriented longitudinally, in a continuous manner, whereby all of the components of said flexible structure are intimately bonded by a final heat treatment. Flexible polymeric structures manufactured according to this process. Application to the fields of the transport of all fluids and protection against external aggressive agents.

Abstract: A rigid fiber glass air duct for conveying an airstream has an interior surface, adapted to be in contact with the airstream, which is coated with a polymeric coating with an organic biocide. The polymeric coating has a dry solids content of between 10 and 20 grams per square foot of duct board surface and retains its abrasion strength and puncture resistance whereby the interior surface of the duct can be cleaned by conventional industrial or commercial cleaning methods while in service without exposing glass fibers to the airstream.

Abstract: A method and material for the manufacturing or retrofitting of fluid transport systems. The material chosen for the lining, or the pipe itself, will be selected based on physical properties such as a high impact strength and a low coefficient of friction. The low coefficient of friction will be essential to prevent the initial adhesion of foreign substances to the inner surface of pipes. In particular, an improved pipe composite will be useful in the lining or construction of water intake pipes where there is a well-recognized problem of the buildup of foreign substances including algae and other marine microorganisms. Therefore, by preventing buildup, the present invention will provide a more economical and efficient method to maintain the overall piping system.

Abstract: Process for the manufacture of a flexible tubular structure comprising a sealant barrier, consisting of a monolayer film a few microns thick, oriented longitudinally, in a continuous manner, whereby all of the components of said flexible structure are intimately bonded by a final heat treatment. Flexible tubular structures realized according to this process. Application to the fields of the transport of all fluids and protection against external aggressive agents.

Abstract: A shaft sleeve is made of ceramics and provided in confrontation with a stationary sliding member in a sliding bearing or plain bearing. The shaft sleeve made of ceramics comprises a cylindrical body made of ceramics and having a circular outer surface and a circular inner surface, and an elastic member molded on the inner surface of the cylindrical body and being formed with an inner opening having a shape corresponding to the cross section of a shaft. The shaft sleeve is usable under high temperature conditions and with liquids containing much slurry such as, for example, as a shaft sleeve of a pump.

Abstract: A water transmission tubing for controlling the flow of water under pressure comprises a tubular inner layer of generally uniform cross-sectional configuration continuous with the length of the tubing and having a biocide for killing bacteria in the water, and a tubular outer layer having an inner wall disposed against and bonded to an outer wall of the inner layer and being made of a material thickness for inhibiting the migration of biocide from the inner layer to the outside of the tubing.

Abstract: A composite plastic duct structure comprised of an outer layer of fabric material impregnated with a fire-resistant resin material and an inner liner layer of chemically corrosion resistant resin material impregnated with a fabric material. The invention includes a method wherein multiple wrappings of resin impregnated material are wound on a mandrel to form the inner and outer layers.

Abstract: A plastic valve comprising a valve body, integral plastic valving duct means with rigid tubular plastic end portions for attachment to flow ducts carrying liquids to be valved, and a collapsible and distensible tubular plastic valving portion welded to the tubular end portions, the valving portion have sidewalls of plastic film laminae free of each other, but welded to each other at edges to form resilient side rib portions, squeezing linkages traversing flexible wall portions and applying squeezing pressure onto the flexible wall portions to close the flow passage therebetween, tiltable squeeze bars extending along the flexible wall adjacent the squeezing linkages and progressively deforming the flexible wall portions during application of squeezing pressure, camming impeller portions applying and relieving squeezing pressure against the squeezing linkages and squeeze bars and camming against the camming surfaces of the body portion as a driving head moves the impeller portions in the valve body portion.

Abstract: Iron pipe and other hollow articles are lined with a cementitious mortar containing a quantity of polymer particles and the pipe is rotated about its axis so as to stratify the mortar and develop a polymer rich inner surface that is subsequently cured, dried and heated to the polymer fusion temperature and then coated with a continuous layer of pure polymer.

Abstract: A hose composition is provided which comprises a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene, fillers, rubber compounding additives and a curing agent. A hose comprising at least a portion made from this hose composition is also provided.

Abstract: The present invention provides: (1) a formed tubular thermal insulator comprising a felt piece of carbon fibers spirally wound to form a laminate of felt layers integrally bonded to each other with the carbonized substance present between the felt layers with substantially no wavy deformation of spiral winding form, and (2) a process for preparing a formed thermal insulator, the process comprising spirally winding a felt piece of carbon fibers and a film and/or net with a carbonizable resin inserted therebetween while applying a tensile force on the film and/or net to form a laminate, followed by curing and carbonization.

Abstract: A coextruded innerduct which would include an outer layer of polyethylene, impregnated or filled with a filler material, such as calcium carbonate, talc, microglass beads or strands, or any material which would reduce the contraction and expansion properties of the polyethylene innerduct in relation to the properties of the outer casing, and an inner layer of unfilled polyethylene innerduct which would provide for a smooth surface, to lower the coefficient of friction between itself and the fiber optic cables being pulled therethrough. There is further provided a lubricity agent added to the inner layer, and the innerduct is positioned as part of a multi-cell system when installed for use.

Abstract: A refrigerant-transport hose having an inner tube, an outer tube located radially outwardly of the inner tube, and a reinforcing fiber layer interposed between the inner and outer tubes, the reinforcing fiber layer and the inner and outer tubes providing an integral tubular body, and inner tube including a gas-impermeable resinous layer formed of a composition containing a polyamide resin produced by reaction of hexamethylene diamine and an aliphatic dicarboxylic acid having eight to sixteen carbon atoms.

Abstract: A double-wall composite pipe comprises a permeable annulus structure separating impermeable inner and outer walls. The permeable annulus structure has micro-fractures formed therein that function to reduce the flow rate and pressure of fluids leaking through the inner wall to thus inhibit fluid leakage. The annulus structure resists the stresses produced by internal fluid pressures and other service loads. The inner and outer walls will remain permanently impermeable while the pipe annulus structure undergoes stress-induced dimensional changes. A coupler assembly mechanically connects each longitudinally adjacent pair of pipes together and comprises two semi-cylindrical half-couplers, a compressible seal ring, a cylindrical retaining sleeve, and a flexible boot that encloses and seals the assembled half-couplers. A leak detecting sensor may be located at the coupler assembly. A preferred method and apparatus for making the pipe and coupler assembly are also taught.

Abstract: Cold impact-resistant tubing especially useful as a fuel line for motor vehicles which is stable in length, has a brief thermal overload capacity, and consists of at least three layers of at least two different mutually compatible polyamides. The tubing also preferably has an internal and an external layer of impact resistance-modified polyamide, with or without a plasticizer, and a barrier between the layers of impact resistance modifier-free homopolyamide, copolyamide or blends thereof.