Contains Lubricant Or Oil Or Overcoat Thereof Patents (Class 148/246)
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Patent number: 5584943Abstract: A lubricant and surface conditioner for formed metal surfaces, particularly beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. An aqueous composition for forming the conditioner by contact with metal surfaces includes a water-soluble organic material selected from a phosphate ester, alcohol, fatty acid including mono-, di-, tri-, and polyacids; fatty acid derivatives such as salts, hydroxy acids, amides, esters, ethers and derivatives thereof; and mixtures thereof and at least one of the elements selected from zirconium, titanium, cerium, aluminum, iron, tin, vanadium, tantalum, niobium, molybdenum, tungsten, and hafnium in metallic or ionic form. In order to avoid formation of sludge in the aqueous lubricant and surface conditioner forming composition, the composition should contain as little as possible of materials containing phenanthrene rings, such as conventional surfactants made by ethoxylating rosin.Type: GrantFiled: December 22, 1994Date of Patent: December 17, 1996Assignee: Henkel CorporationInventors: Richard D. Banaszak, Timm L. Kelly, Gary L. Rochfort
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Patent number: 5540788Abstract: The present invention provides for forming an iron-phosphate conversion surface, or an iron-phosphate bi-metallic surface on metals, in situ, in internal combustion engines, pumps, hydraulic systems, compressors and other mechanical equipment and machinery, using the lubricating oil as the medium for bringing the phosphate and bi-metallic inorganic polymeric water complexes into contact with the metals in the machinery. The inorganic polymeric water complexes can be formed in accordance with U.S. Pat. Nos. 5,084,263 and 5,310,419 which are incorporated herein by reference. The bimetallic component can be any metal from Classes I through VIII of the Periodic Table. The phosphate and/or phosphate bi-metallic complexes are added to the lubricating oil while the engine is running.Type: GrantFiled: February 24, 1995Date of Patent: July 30, 1996Assignee: Mdechem, Inc.Inventors: Frank G. Defalco, Charles R. McCoy
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Patent number: 5486414Abstract: Article of manufacture and method of making the same in which a metal substrate has an undercoating is made from a combination of at least one pulverulent metal and a transition metal compound and a coating thereon containing an autodeposited resin formed under autodepositing conditions.Type: GrantFiled: July 18, 1994Date of Patent: January 23, 1996Assignee: Henkel CorporationInventors: Oscar E. Roberto, Marc A. Maxim
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Patent number: 5486316Abstract: The coefficient of friction of aluminum can surfaces after alkaline cleaning and drying can be substantially reduced by adding to the alkaline cleaner a mobility enhancing additive, preferably a surface active quaternary ammonium salt with hydroxyethyl substituents on the quaternary nitrogen atoms. A can surface suitable for automatic conveying and high quality lacquer or printing ink adhesion can thereby be obtained, if desired without including any substantial fluoride content in any treatment stage.Type: GrantFiled: September 21, 1994Date of Patent: January 23, 1996Assignee: Henkel CorporationInventors: James P. Bershas, Timm L. Kelly, Gary L. Rochfort
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Patent number: 5458698Abstract: A lubricant and surface conditioner for formed metal surfaces, particularly aluminum and tin beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. The conditioner includes a water-soluble organic material selected from alkoxylated or non-alkoxylated castor oil triglycerides and hydrogenated castor oil derivatives; alkoxylated and nonoalkoxylated amine salts of a fatty acid including mono-, di-, tri-, and poly-acids; alkoxylated and non-alkoxylated amino fatty acids; alkoxylated and non-alkoxylated fatty amine N-oxides, alkoxylated and non-alkoxylated quaternary ammonium salts, oxa-acid esters, and water-soluble alkoxylated and non-alkoxylated polymers.Type: GrantFiled: September 23, 1993Date of Patent: October 17, 1995Assignee: Henkel CorporationInventors: James P. Bershas, Timm L. Kelly, Gary L. Rochfort
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Patent number: 5415701Abstract: In a process for facilitating non-cutting cold working of ferrous materials by application of a phosphate coating, ferrous materials are dipped into a phosphating solution which is free of elements of group VIB of the periodic table which consists of Cr, Mo and W, of nitrogen compounds and preferably also free of nickel and contains5 to 20 g/l zinc1 to 15 g/l magnesium10 to 26 g/l phosphate calculated as P.sub.2 O.sub.51 to 15 g/l fluoroborate calculated as BF.sub.41 to 7 g/l chlorate calculated as ClO.sub.3and in which the weight ratio of Zn:Mg:BF.sub.4 is adjusted to from 1:0.15:0.15 to 1:1:1.Type: GrantFiled: March 2, 1994Date of Patent: May 16, 1995Assignee: Metallgesellschaft AktiengesellschaftInventors: Klaus-Dieter Nittel, Karl-Heinz Zander
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Patent number: 5389162Abstract: The present invention provides a surface-treating agent for a metal can, which has an effect of elevating smoothness of the metal can, shows a low foaming property and high thermal stability, but not uneasiness at safety, and thereby contributes to elevate a transferring speed of a metal can body in producing the metal can. A surface-treating agent for a metal can, comprising an emulsion containing a sorbitan fatty acid ester in a concentration of 100 to 2000 mg/l in a water medium, is sprayed to a metal can body in the final stage of a rinsing process which is carried out after a converting process.Type: GrantFiled: December 3, 1993Date of Patent: February 14, 1995Assignee: Nippon Paint Co., Ltd.Inventors: Syunichi Endou, Masahiro Jo, Satoshi Miyamoto
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Patent number: 5385655Abstract: The invention describes a method of producing an adherent and corrosion-inhibiting multi-layer coating on metal parts comprising the steps of(A) phosphating the metal parts with an aqueous metal phosphating solution;(B) electrophoretically depositing a film of a siccative organic coating composition on the phosphated metal parts;(C) applying a second film of a composition comprising at least one film-forming organic resin component as a seal coat;(D) curing the coating on the metal parts; and optionally(E) applying a corrosion-inhibiting film as a top seal coat.Type: GrantFiled: November 23, 1993Date of Patent: January 31, 1995Assignee: Man-Gill Chemical CompanyInventors: Randall J. Brent, David A. Blaha
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Patent number: 5378291Abstract: A coating composition for metallic surfaces contains:(1) Cr.sup.6+, or Cr.sup.6+ and Cr.sup.3+,(2) 1-50% of lubricant(s) dispersed by a nonionic emulsifying agent,(3) acryl-series polymer emulsion, which is obtained by emulsion-polymerizing, by means of a nonionic emulsifying agent which is essentially free of anionic and cationic emulsifying agent and which contains a polyoxyethylene-polyoxypropylene block polymer, monomers of A), B), and C):A) a monomer of ethylene-series, unsaturated carboxylic acidB) one or more monomers selected from a), b), and c):a) alkoxyethylene(metha)acrylamide and its derivative(s) expressed by the following general formula ##STR1## X is CnH.sub.2n+1 (n=0 or 1) Y is CmH.sub.2m+1 (m=0-4)b) acid phospho-oxyalkyl(metha)acrylate, andc) alkoxy-alkyl(metha)acrylateC) one or more acryl-series monomers (a part of which may consist of 2)(c)).Type: GrantFiled: May 17, 1993Date of Patent: January 3, 1995Assignee: Nihon Parkerizing Co., Ltd.Inventors: Masayasu Ara, Akira Katoh
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Patent number: 5236519Abstract: There are disclosed a method for lubricating treatment of an aluminum surface comprising subjecting the surface of aluminum or aluminum alloy to chemical zinc deposition plating, then to a treatment with a phosphating solution and further to a lubricating treatment, and a method for lubricating treatment of an aluminum surface comprising subjecting the surface of aluminum or aluminum alloy to chemical zinc deposition plating in a thickness of 0.2 .mu.m or more and further to a soap lubricating treatment.Type: GrantFiled: January 15, 1991Date of Patent: August 17, 1993Assignee: Nihon Parkerizing Co., Ltd.Inventors: Shigeru Nakano, Yoichi Nishimura
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Patent number: 5234509Abstract: In the practice of the instant invention, a lubricating phosphate coating is applied to the surface of a ferrous-base metal article by contacting the surface with an aqueous acidic phosphate coating solution which contains an amount of hydroxylamine which is effective in increasing the rate at which the phosphate coating deposits from the solution. The resulting coated article is then subjected to cold deformation.In a preferred embodiment, the metal article is additionally contacted with a second lubricating compound after the phosphate coating is applied. In addition to phosphate, the coating solutions employed preferably contain one or more of the following ions: zinc, manganese, nitrate, nickel, ferrous, ferric, copper, fluoride, or mixtures thereof.Type: GrantFiled: January 4, 1991Date of Patent: August 10, 1993Assignee: Henkel CorporationInventor: Thomas W. Tull
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Patent number: 5189720Abstract: A method for manufacturing a steel wire material for reinforcing an optical fiber is proposed. In this method, a steel wire is firstly subjected to a chemical conversion treatment. The wire is then drawn with a reduction of area of 30% or more. As a result, a coating capable of effectively restraining the production of hydrogen is formed on the surface of the wire.Type: GrantFiled: April 2, 1990Date of Patent: February 23, 1993Assignee: Sumitomo Electric Industries, Ltd.Inventors: Teruyuki Murai, Susumu Yamamoto
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Patent number: 5139586Abstract: An aqueous, acidic composition for application to aluminum and aluminum alloy surfaces comprising a source of zirconium ions, a source of fluoride ions, a source of phosphate ions, a phosphate acid ester, a polyethylene glycol ester of a fatty acid, and nitric acid, and a method for treating aluminum and aluminum alloy surfaces with such a composition.Type: GrantFiled: February 11, 1991Date of Patent: August 18, 1992Assignee: Coral International, Inc.Inventor: Narayan Das
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Patent number: 5073213Abstract: In order to ensure in sliding surface bearings a uniform distribution of the load over the bearing metal layer, a phosphate layer serving as a sliding layer has been applied to the bearing metal layer.In order to ensure a high resistantce to scuffing, the sliding layer is formed from an aqueous phosphating solution which contains 1.5 to 5.0 g/l Zn, 12 to 24 g/l Na, 11 to 22 g/l P.sub.2 O.sub.5, 17 to 33 g/l 16 to 30 g/l BF.sub.4, 20 to 39 g/l B(OH).sub.3 and 1.0 to 6.0 g/l NaF.Type: GrantFiled: May 18, 1990Date of Patent: December 17, 1991Assignee: Kolbenschmidt AktiengesellschaftInventor: Harald Pfestorf
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Patent number: 4983229Abstract: In the practice of the instant invention, a lubricating phosphate coating is applied to the surface of a ferrous-base metal article by contacting the surface with an aqueous acidic phosphate coating solution which contains an amount of hydroxylamine which is effective in increasing the rate at which the phosphate coating deposits from the solution. The resulting coated article is then subjected to cold deformation.In a preferred embodiment, the metal article is additionally contacted with a second lubricating compound after the phosphate coating is applied. In addition to phosphate the coating solutions employed preferably contain one or more of the following ions: zinc, manganese, nitrate, nickel, ferrous, ferric, copper, fluoride, or mixtures thereof.Type: GrantFiled: August 9, 1988Date of Patent: January 8, 1991Assignee: Henkel CorporationInventor: Thomas W. Tull
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Patent number: 4944813Abstract: The present invention relates to a process for phosphating metal surfaces, and more specifically of surfaces of iron, zinc, and aluminum and the alloys thereof as a pretreatment for cold working wherein the surfaces without previous activation are contacted in a temperature range of from 30.degree. C. to 70.degree. C. with an aqueous solution containing(a) from 10 to 40 g/l of Ca.sup.2+ ions,(b) from 10 to 40 g/l of Zn.sup.2+ ions,(c) from 10 to 100 g/l of OP.sub.4.sup.3- ionsand, as accelerator,(d) from 10 to 100 g/l of NO.sub.3.sup.- ions and/or(e) from 0.1 to 2.0 g/l of organic nitro compounds,said solution exhibiting a pH value in the range of from 2.0 to 3.8 and a ratio of free acid to total acid of from 1:4 to 1:100.Type: GrantFiled: January 13, 1989Date of Patent: July 31, 1990Assignee: Gerhard Collardin GmbHInventors: Kurt Hosemann, Reinhard Opitz
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Patent number: 4891268Abstract: A coated metal substrate protected against corrosion with a lubricious coating which, exclusive of lubricant, is resin-free and phosphate-free, which coating contains hexavalent-chromium, particulate metal and a lubricant.Type: GrantFiled: October 27, 1988Date of Patent: January 2, 1990Assignee: Metal Coatings International Inc.Inventors: Michel Fourez, Michel Lonca, Patrick Pichant