Age Or Precipitation Hardened Or Strengthened Patents (Class 148/326)
  • Patent number: 11788177
    Abstract: A precipitation-hardened stainless steel alloy is disclosed including, by weight: 14.0-16.0% Cr; 6.0-7.0% Ni; 1.25-1.75% Cu; 0.5-1.0% Mo; 0.40-0.85% Nb; 0.025-0.05% C; up to 1.0% Mn; up to 1.0% Si; up to 0.1% V; up to 0.1% Co; up to 0.1% Sn; up to 0.02% N; up to 0.025% P; up to 0.05% Al; up to 0.008% S; up to 0.005% Ag; up to 0.005% Pb; up to 0.1% As; up to 0.01% Sb; and a balance of Fe. The alloy has a ratio of Nb:(C+N) of at least 15:1.
    Type: Grant
    Filed: April 27, 2021
    Date of Patent: October 17, 2023
    Assignee: GENERAL ELECTRIC COMPANY
    Inventor: Theodore Francis Majka
  • Patent number: 11639542
    Abstract: A multi-scale and multi-phase dispersion strengthened iron-based alloy, and preparation and characterization methods thereof are provided. The alloy contains a matrix and a strengthening phase. The strengthening phase includes at least two types of the strengthening phase particles with different sizes. A volume of the two types of the strengthening phase particles with different sizes having a particle size less than or equal to 50 nm accounts for 85-95% of a total volume of all the strengthening phase particles. The matrix is a Fe—Cr—W—Ti alloy. The strengthening phases include crystalline Y2O3 phase, Y—Ti—O phase, Y—Cr—O phase, and Y—W—O phase. The characterization method comprises electrolytically separating the strengthening phases in the alloy, and then characterizing by using an electron microscope. The tensile strength of the prepared alloy is more than 1600 MPa at room temperature, and is more than 600 MPa at 700° C.
    Type: Grant
    Filed: August 30, 2018
    Date of Patent: May 2, 2023
    Assignee: CENTRAL SOUTH UNIVERSITY
    Inventors: Zuming Liu, Quan Li, Boyun Huang, Xueqian Lv, Kai Peng, Fan Zhao
  • Patent number: 11499204
    Abstract: A martensitic stainless steel sheet has a composition containing, (mass %), from 0.10 to 0.15% of C, from 0.05 to 0.80% of Si, from 0.05 to 2.00% of Mn, 0.040% or less of P, 0.003% or less of S, from 0.05 to 0.50% of Ni, from 11.0 to 15.0% of Cr, from 0.02 to 0.50% of Cu, from 0.005 to 0.06% of N, from 0.001 to 0.20% of Al, from 0 to 1.00% of Mo, from 0 to 0.50% of V, from 0 to 0.01% of B, balance Fe and unavoidable impurities. An M value=420C?11.5Si+7Mn+23Ni?11.5Cr?12Mo?10V+9Cu?52Al+470N+189 is 100 or more. A carbonitride number density having a circle equivalent diameter of 1.0 ?m or more is 15.0 or less per 0.01 mm2. 0.2% yield strength is 1,100 N/mm2 or more.
    Type: Grant
    Filed: January 21, 2019
    Date of Patent: November 15, 2022
    Assignee: NIPPON STEEL STAINLESS STEEL CORPORATION
    Inventors: Taichiro Mizoguchi, Hiroyasu Matsubayashi, Katsuyuki Shiotsuki
  • Patent number: 11486015
    Abstract: The invention relates to a method for producing a steel material, particularly a corrosion-resistant steel material for pumps and similar, in which a steel corresponding to the following analysis (in wt. %) is smelted: C<0.050; Si<0.70; Mn<1.00; P<0.030; S<0.010; Cr=14-15.50; Mo=0.30-0.60; Ni=4.50-5.50; V<0.20; W<0.20; Cu=2.50-4.00; Co<0.30; Ti<0.05; Al<0.05; Nb<0.05; Ta<0.05; N<0.05.
    Type: Grant
    Filed: May 11, 2017
    Date of Patent: November 1, 2022
    Assignee: VOESTALPINE BÖHLER EDELSTAHL GMBH & CO. KG
    Inventors: Jochen Perko, Michael Haspel, Patric Schütz
  • Patent number: 11359268
    Abstract: The present invention relates to an iron-based alloy that is able to provide a coating on a substrate, the coating having simultaneously high hardness and wear resistance. The iron-based alloy consists of 3.0-7.0% by weight Cr; 1.3-3.0% by weight C; 0.2-2.0% by weight B; 2.0-10.0% by weight V; optionally 1.5% by weight or less Si; optionally 1.0% by weight or less Mn, optionally 2.0% by weight or less Mo; optionally 1.5% by weight or less Ni; the balance being Fe and unavoidable impurities. The present invention further relates to an article comprising a substrate and coating formed thereon, the coating being formed from the alloy, and to a method for forming a coated article. The method preferably employs HVOF, laser cladding or plasma cladding.
    Type: Grant
    Filed: June 21, 2017
    Date of Patent: June 14, 2022
    Assignee: HÖGANÄS GERMANY GMBH
    Inventors: Cecilia Cao, Crystal Liu, Kari Vesterling, Erik Wang, Hans Hallén
  • Patent number: 11198930
    Abstract: There is provided a precipitation-strengthened stainless steel plate having a chemical composition: by mass %, C: 0.01 to 0.10%; Si: 0.02 to 3.0%; Mn: 0.02 to 2.0%; Ni: 20 to 30%, Cr: 14 to 25.0%; Mo: 1.0 to 4.0%; Cu: 0.01 to 2.0%; Co: 0.01 to 0.5%; V: 0.1 to 1.0%; B: 0.001 to 0.01%; N: 0.02% or less; Ti: 2.0 to 5.0%; Al: 0.002 to 5.0%; Ti+Al: 3.3 to 6.0%; and the balance being Fe and impurities, the precipitation-strengthened stainless steel plate having a Vickers hardness Hv of 300 or higher, wherein the number density ??: Ni3(Al, Ti), which is an intermetallic compound, is 0 to 5/?m2. As a heat resistant component material, the precipitation-strengthened stainless steel plate is less expensive than conventional Ni-based alloys such as NCF625 and NCF718, and more excellent in high temperature properties than a precipitation-strengthened heat-resistant stainless steel such as SUH660.
    Type: Grant
    Filed: September 15, 2015
    Date of Patent: December 14, 2021
    Assignee: NIPPON STEEL CORPORATION
    Inventors: Masayoshi Sawada, Yuichi Fukumura
  • Patent number: 11072837
    Abstract: A martensitic stainless steel sheet comprises a chemical composition containing, in mass %, C: 0.035% to 0.090%, Si: 0.01% to 1.0%, Mn: 0.01% to 0.90%, P: 0.050% or less, S: 0.050% or less, Cr: 10.0% to 14.0%, Ni: 0.01% to 0.40%, Al: 0.001% to 0.50%, V: 0.05% to 0.50%, and N: 0.050% to 0.20%, with the balance being Fe and inevitable impurities, wherein a content of C and a content of N in the chemical composition satisfy C %+N % 0.10% and N % C %, the number of precipitates with a major axis length of 200 nm or more in a surface layer of the martensitic stainless steel sheet is 25 or less per 100 ?m2, and the martensitic stainless steel sheet has a tensile strength of 1300 MPa or more, a proof stress of 1100 MPa or more, and an elongation of 8.0% or more.
    Type: Grant
    Filed: October 6, 2017
    Date of Patent: July 27, 2021
    Assignee: JFE STEEL CORPORATION
    Inventors: Tetsuyuki Nakamura, Shin Ishikawa, Reiko Sugihara
  • Patent number: 11053979
    Abstract: A bearing ring for a rolling-element bearing or plain bearing has at least one first region that is inductively hardened or is configured to be inductively hardened and at least one second region that is not inductively hardened and is not intended to be inductively hardened, and the at least one second region includes at least one stress-relief recess and/or at least one stress-relief projection.
    Type: Grant
    Filed: July 11, 2019
    Date of Patent: July 6, 2021
    Assignee: AKTIEBOLAGET SKF
    Inventors: Martina Sticht, Fred Menig, Juergen Reichert, Jesko-Henning Tanke, Gerhard Wagner, Michael Wendel
  • Patent number: 11020801
    Abstract: The invention relates to a method for coding metal powder. Said method comprises the following steps: providing a melt, forming a melt stream, spraying the melt stream by means of a spraying fluid, and forming metal powder particles from the melt stream. The method is characterized in that, during the spraying of the melt and/or the spraying fluid, a coding component or a coding gas is added in such a way that the use of the coding component in the metal powder can be detected, wherein the gaseous coding component comprises one or more isotopes of at least one gas and the fraction of the at least one isotope is changed in comparison with the naturally occurring fraction of said isotope in the gas and/or wherein the gaseous coding component contains gaseous alloying elements.
    Type: Grant
    Filed: May 12, 2017
    Date of Patent: June 1, 2021
    Assignee: LINDE AKTIENGESELLSCHAFT
    Inventors: Jürgen Scholz, Ernst Miklos, Jim Fieret
  • Patent number: 10988824
    Abstract: A corrosion resistant steel having a yield strength of at least 758 MPa is described. The corrosion resistant steel comprises in weight %: 0.005?C<0.03, 14?Cr?17, 2.3?Mo?3.5, 3.2?Ni?4.5, Si?0.6, 0.5?Cu?1.5, 0.4?Mn?1.3, 0.35?V?0.6, 3.2×C?Nb?0.1, W?1.5, 0.5?Co?1.5, 0.02?N?0.05, Ti?0.05, P?0.03, S?0.005, Al?0.05, with the balance of the chemical composition of said corrosion resistant steel being constituted by Fe and inevitable impurities. A manufacturing method of such steel to obtain a quenched and tempered semi finished product is also described.
    Type: Grant
    Filed: June 29, 2016
    Date of Patent: April 27, 2021
    Assignee: VALLOUREC OIL AND GAS FRANCE
    Inventors: Christelle Gomes, Hafida El Alami, Florent Decultieux
  • Patent number: 10927439
    Abstract: Disclosed is an austenitic stainless steel alloy that includes or consists of, by weight, about 24% to about 26% chromium, about 11% to about 13% nickel, about 4.5% to about 5.5% manganese, about 1.3% to about 1.7% silicon, about 1.2% to about 1.6% niobium, about 0.40% to about 0.50% carbon, about 0.2% to about 0.4% nitrogen, and a balance of iron with inevitable/unavoidable impurities. The alloy is suitable for use in turbocharger turbine applications for temperatures up to about 1050° C.
    Type: Grant
    Filed: May 30, 2018
    Date of Patent: February 23, 2021
    Assignee: GARRETT TRANSPORTATION I INC
    Inventors: Balasubramani Nandagopal, Marc Wilson
  • Patent number: 10830379
    Abstract: Provided is a ductile stainless steel pipe made of stainless steel having an austenite type matrix structure and containing a copper component. The ductile stainless steel pipe has a delta ferrite matrix structure of about 1% or less on the basis of a grain area. The ductile stainless steel pipe includes a steel pipe having a set outer diameter to carry a refrigerant of an air conditioner. R410a is used as the refrigerant, and the ductile stainless steel pipe has a minimum thickness determined based on a saturated pressure of the refrigerant.
    Type: Grant
    Filed: March 6, 2018
    Date of Patent: November 10, 2020
    Assignee: LG ELECTRONICS INC.
    Inventor: Seokpyo Hong
  • Patent number: 10627168
    Abstract: Disclosed are a stainless steel having a new composition, which has properties of low strength as compared with a conventional stainless steel, that includes, percent by weight, C: 0.03% or less, Si: exceeding 0 to 1.7% or less, Mn: 1.5 to 3.5%, Cr: 15.0 to 18.0%, Ni: 7.0 to 9.0%, Cu: 1.0 to 4.0%, Mo: 0.03% or less, P: 0.04% or less, S: 0.04% or less, N: 0.03% or less, residue: Fe, and incidental impurities, and has an austenite matrix structure and an average diameter of 30 to 60 ?m, and a system such as an air conditioner including the stainless steel thereof.
    Type: Grant
    Filed: December 18, 2017
    Date of Patent: April 21, 2020
    Assignee: LG ELECTRONICS INC.
    Inventor: Seokpyo Hong
  • Patent number: 10513764
    Abstract: An austenitic steel for hydrogen technology has the following composition: 0.01 to 0.4 percent by mass of carbon, ?5 percent by mass of silicon, 0.3 to 30 percent by mass of manganese, 10.5 to 30 percent by mass of chromium, 4 to 12.5 percent by mass of nickel, ?3 percent by mass of molybdenum, ?0.2 percent by mass of nitrogen, ?5 percent by mass of aluminum, ?5 percent by mass of copper, ?5 percent by mass of tungsten, ?0.1 percent by mass of boron, ?3 percent by mass of cobalt, ?0.5 percent by mass of tantalum, ?2.0 percent by mass of at least one of the elements: niobium, titanium, vanadium, hafnium and zirconium, ?0.3 percent by mass of at least one of the elements: yttrium, scandium, lanthanum, cerium and neodymium, the remainder being iron and smelting-related steel companion elements.
    Type: Grant
    Filed: November 14, 2014
    Date of Patent: December 24, 2019
    Assignee: Bayerische Motoren Werke Aktiengesellschaft
    Inventors: Wolfgang Leistner, Thorsten Michler, Werner Theisen, Mauro Sebastian Martin, Sebastian Weber, Joerg Naumann
  • Patent number: 10280498
    Abstract: A nickel-base alloy is disclosed that has the following weight percent composition. C about 0.005 to about 0.06 Cr about 13 to about 17 Fe about 4 to about 20 Mo about 3 to about 9 W up to about 8 Co up to about 12 Al about 1 to about 3 Ti about 0.6 to about 3 Nb up to about 5.5 B about 0.001 to about 0.012 Mg about 0.0010 to about 0.0020 Zr about 0.01 to about 0.08 Si up to about 0.7 P up to about 0.05 and the balance is nickel, usual impurities, and minor amounts of other elements as residuals from alloying additions during melting. The alloy provides a combination of high strength, good creep resistance, and good resistance to crack growth. A method of heat treating a nickel base superalloy to improve the tensile ductility of the alloy is also disclosed. An article of manufacture made from the nickel base superalloy described herein is also disclosed.
    Type: Grant
    Filed: October 12, 2016
    Date of Patent: May 7, 2019
    Assignee: CRS HOLDINGS, INC.
    Inventors: Karl A. Heck, Samuel J. Kernion
  • Patent number: 10208367
    Abstract: A Ge-containing stainless steel is disclosed. The disclosed Ge-containing stainless steel is principally composed of Fe and Cr. Pitting corrosion is significantly reduced when a certain amount of Ge is added. When more Ge is added, the pitting corrosion is reduced to a minimum level.
    Type: Grant
    Filed: December 29, 2016
    Date of Patent: February 19, 2019
    Assignee: NATIONAL TSING HUA UNIVERSITY
    Inventor: Swe-Kai Chen
  • Patent number: 10180293
    Abstract: A method for producing a heat radiating plate, the method containing the steps of: finish cold-rolling an annealed material to obtain a strip; causing the strip to wind in the shape of a coil to prepare a coil stock; unwinding the coil stock by means of an uncoiler to obtain a strip; causing the strip to pass through a gap between the rolls of a leveler to correct the shape thereof; progressively feeding the corrected strip to a progressive die via a feeder to progressively press-working the strip to produce a heat radiating plate.
    Type: Grant
    Filed: September 28, 2016
    Date of Patent: January 15, 2019
    Assignee: DOWA METALTECH CO., LTD.
    Inventors: Tomotsugu Aoyama, Akira Sugawara
  • Patent number: 10094010
    Abstract: A strain-hardenable stainless steel alloy includes hard secondary phases dispersed in an austenitic primary phase, the alloy including 0.3-0.6% nitrogen by weight.
    Type: Grant
    Filed: June 18, 2015
    Date of Patent: October 9, 2018
    Assignee: THE OHIO STATE UNIVERSITY
    Inventors: Ryan Thomas Smith, Tapasvi Lolla, Sudarsanam Suresh Babu, David Wayne Gandy, John Albert Siefert, Gregory J. Frederick, Lou Lherbier, David Novotnak
  • Patent number: 9963757
    Abstract: A process includes: (a) providing a tantalum-coated metal alloy substrate; (b) heat annealing the tantalum-coated metal alloy substrate by heating to an annealing temperature for the tantalum-coated metal alloy substrate, holding at the annealing temperature for a period of time and then quenching to a temperature below 50 degrees Celsius; (c) heating the tantalum-coated metal substrate to the precipitation hardening temperature of the metal alloy substrate; and (d) cooling the tantalum-coated metal alloy substrate to a temperature below 50 degrees Celsius; wherein the process is further characterized by carrying out steps (b)-(d) under a tantalum-inert gas atmosphere and by quenching in step (b) and cooling in step (d) being carried out by flowing a tantalum-inert gas having a temperature of less than 50 degrees Celsius over the tantalum-coated metal alloy substrate.
    Type: Grant
    Filed: November 19, 2014
    Date of Patent: May 8, 2018
    Assignee: Dow Global Technologies LLC
    Inventors: Valentina A. Woodcraft, Eugene L. Liening
  • Patent number: 9885099
    Abstract: To provide a ferritic stainless steel sheet which has high scale spalling even at a high temperature around 1000° C. Provided is a ferritic stainless steel sheet having excellent Mn-containing oxide film-forming ability and scale spalling ability, containing, in terms of mass %: C: 0.001 to 0.020%, N: 0.001 to 0.020%, Si: 0.10 to 0.40%, Mn: 0.20 to 1.00%, Cr: 16.0 to 20.0%, Nb: 0.30 to 0.80%, Mo: 1.80 to 2.40%, W: 0.05 to 1.40%, Cu: 1.00 to 2.50%, and B: 0.0003 to 0.0030%, in which the above-mentioned components are contained satisfying the formula (1) below, and the balance is composed of Fe and inevitable impurities. At least one of N, Al, V, Mg, Sn, Co, Zr, Hf, and Ta may be added in a predetermined content range.
    Type: Grant
    Filed: March 8, 2013
    Date of Patent: February 6, 2018
    Assignee: NIPPON STEEL & SUMIKIN STAINLESS STEEL CORPORATION
    Inventors: Norihiro Kanno, Junichi Hamada, Yoshiharu Inoue
  • Patent number: 9856541
    Abstract: Disclosed are a heat-resistant alloy used in a heat-resistant bolt and the like for fastening high temperature parts of an engine in a vehicle and the like, and a method of manufacturing a heat-resistant bolt using the heat-resistant alloy. Particularly, the austenitic heat-resistant alloy includes, based on a total weight of the heat-resistant alloy, carbon (C) in an amount of about 0.01 to about 0.08 wt %, silicon (Si) in an amount of about 0.01 to about 1.00 wt %, manganese (Mn) in an amount of about 0.01 to about 2.00 wt %, nickel (Ni) in an amount of about 17 to about 22 wt %, titanium (Ti) in an amount of about 2.7 to about 3.2 wt %, chromium (Cr) in an amount of about 11 to 16 wt %, molybdenum (Mo) in an amount of about 0.3 to about 1.0 wt %, vanadium (V) in an amount of about 0.1 to about 0.4 wt %, and a remainder of iron (Fe) and optionally an inevitable impurity.
    Type: Grant
    Filed: December 6, 2014
    Date of Patent: January 2, 2018
    Assignees: Hyundai Motor Company, Kia Motors Corporation
    Inventors: Bo-Kyung Sa, Ho-Chul Shin, Jung-Suk Lee
  • Patent number: 9745649
    Abstract: The object of the present invention is to provide a heat-resistant steel for exhaust valves, having relatively small Ni content, high mechanical characteristics (for example, tensile strength, fatigue strength, wear resistance and hardness) at high temperature, and excellent oxidation resistance. The present invention provides a heat-resistant steel for exhaust valves, which includes: 0.45?C<0.60 mass %, 0.30<N<0.50 mass %, 19.0?Cr<23.0 mass %, 5.0?Ni<9.0 mass %, 8.5?Mn<10.0 mass %, 2.5?Mo<4.0 mass %, 0.01?Si<0.50 mass %, and 0.01?Nb<0.30 mass %, with the balance being Fe and unavoidable impurities, in which the steel satisfies 0.02?Nb/C<0.70 and satisfies 4.5?Mo/C<8.9.
    Type: Grant
    Filed: August 24, 2012
    Date of Patent: August 29, 2017
    Assignees: DAIDO STEEL CO., LTD., HONDA MOTOR CO., LTD.
    Inventors: Mototsugu Osaki, Shigeki Ueta, Takashi Tsuyumu
  • Patent number: 9677160
    Abstract: A purpose of the present invention is to provide a martensitic stainless steel tube exhibiting excellent performance even in severe corrosive environments in which a partial pressure of hydrogen sulfide exceeds 0.03 bar. Provided is a low C-high Cr alloy steel tube for OCTG (Oil Country Tubular Goods) having minimum yield strength of 862 MPa and excellent corrosion resistance, wherein the steel tube contains, in percent by mass, 0.005 to 0.05% C, 12 to 16% Cr, 1.0% or less Si, 2.0% or less Mn, 3.5 to 7.5% Ni, 1.5 to 3.5% Mo, 0.01 to 0.05% V, 0.02% or less N, and 0.01 to 0.06% Ta and satisfies the relationship in the following formula (1), and the rest comprises Fe and unavoidable impurities. 25-25 (% Ni)+5 (% Cr)+25 (% Mo)?0??(1).
    Type: Grant
    Filed: March 3, 2011
    Date of Patent: June 13, 2017
    Assignee: NKK Tubes
    Inventors: Shuji Hashizume, Yusuke Minami, Tomomi Taniguchi
  • Patent number: 9562274
    Abstract: An ultra-high strength stainless steel alloy with enhanced toughness includes in % by weight: 0 to 0.06% carbon (C); 12.0 to 18% chromium (Cr); 16.5 to 31.0% cobalt (Co); 0 to 8% molybdenum (Mo); 0.5 to 5.0% nickel (Ni); 0 to 0.5% titanium (Ti); 0 to 1.0% niobium (Nb); 0 to 0.5% vanadium (V); 0 to 16% tungsten (W); balance iron (Fe) and incidental deoxidizers and impurities. The heat treating method includes the steps of austenitizing at least once followed by quenching, tempering and sub-zero cooling to obtain no more than about 6-8% retained austenite in the finished alloy.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: February 7, 2017
    Assignee: Carnegie Mellon University
    Inventor: Warren M. Garrison, Jr.
  • Patent number: 9534268
    Abstract: A method of manufacturing a hot press-hardened component comprises the following production steps: a) providing a steel product produced at least in sections from a stainless steel comprising of the following composition (specified in % wt.) C: 0.010-1.200%, P: up to 0.1%, S: up to 0.1%, Si: 0.10-1.5%, Cr: 10.5-20.0% and optionally one or more elements from the group “Mn, Mo, Ni, Cu, N, Ti, Nb, B, V, Al, Ca, As, Sn, Sb, Pb, Bi, H” with the requirement Mn: 0.10-3.0%, Mo: 0.05-2.50%, Ni: 0.05-8.50%, Cu: 0.050-3.00%, N: 0.01-0.2%, Ti: up to 0.02%, Nb: up to 0.1%, B: up to 0.1%, V: up to 0.2%, Al: 0.001-1.50%, Ca: 0.0005-0.003%, As: 0.003-0.015%, Sn: 0.003-0.01%, Sb: 0.002-0.01%, Pb: up to 0.01%, Bi: up to 0.01%, H: up to 0.
    Type: Grant
    Filed: June 17, 2010
    Date of Patent: January 3, 2017
    Assignee: Outokumpu Nirosta GmbH
    Inventor: Evelin Ratte
  • Patent number: 9458743
    Abstract: An iron-based alloy includes, in weight percent, carbon from about 2 to about 3 percent; manganese from about 0.1 to about 0.4 percent; silicon from about 0.3 to about 0.8 percent; chromium from about 11.5 to about 14.5 percent; nickel from about 0.05 to about 0.6 percent; vanadium from about 0.8 to about 2.2 percent; molybdenum from about 4 to about 7 percent; tungsten from about 3 to about 5 percent; niobium from about 1 to about 3 percent; cobalt from about 3 to about 5 percent; boron from zero to about 0.2 percent; and the balance containing iron and incidental impurities. The alloy is suitable for use in elevated temperature applications such as in valve seat inserts for combustion engines.
    Type: Grant
    Filed: July 31, 2013
    Date of Patent: October 4, 2016
    Assignee: L.E. JONES COMPANY
    Inventors: Cong Yue Qiao, Peter Vennema, Douglas W. Dooley, David Doll
  • Patent number: 9395692
    Abstract: A hairspring material for a mechanical timepiece includes an alloy which contains 37.5 to 39.5% by mass of Ni, 9.2 to 9.9% by mass of Cr, 0.35 to 0.55% by mass of Ti, and 0.6 to 0.9% by mass of Be, based on the total amount of the alloy, and contains in the remainder Fe and unavoidable impurities, the alloy being an alloy containing, as the unavoidable impurities, C (carbon), Mn in an amount of more than 0% by mass but not more than 0.5% by mass and Al in an amount of more than 0% by mass but less than 0.03% by mass, the amount of the C (carbon) being limited to not more than 0.03% by mass. The hairspring material can provide a smaller variation in Young's modulus than that of conventional hairspring materials.
    Type: Grant
    Filed: August 29, 2013
    Date of Patent: July 19, 2016
    Assignees: CITIZEN HOLDINGS CO., LTD., CITIZEN WATCH CO., LTD., HITACHI METALS, LTD., HITACHI METALS NEOMATERIAL, LTD.
    Inventors: Yoshirou Hirai, Shinichi Matsumoto, Kenji Tsuchiya, Shinji Yamamoto
  • Patent number: 9334552
    Abstract: The invention relates to a steel for the production of submarine hulls having the chemical composition: 0.030%?C<0.080% 0.040%?Si?0.48% 0.1%?Mn?1.4% 2%?Ni?4% Cr?0.3% 0.30%?Mo+W/2+3(V+Nb/2+Ta/4)?0.89% Mo?0.15% V+Nb/2+Ta/4?0.004% Nb?0.004% Cu?0.45% Al?0.1% Ti?0.04% N?0.0300% the balance being iron and impurities resulting from the production operation, boron being an impurity whose content is less than 0.0005%, and P+S?0.015%, the chemical composition complying with the condition: 410?540×C0.25+245[Mo+W/2+3(V+Nb/2+Ta/4)]0.30?460.
    Type: Grant
    Filed: May 19, 2006
    Date of Patent: May 10, 2016
    Assignee: INDUSTEEL FRANCE
    Inventors: Jean Beguinot, Cédric Chauvy
  • Patent number: 9303691
    Abstract: The invention relates to a rolling bearing arrangement for a rotational connection for a roller/ball combination raceway system, for the purpose of relative movement of a plurality of rotating elements, in particular two rolling bearing rings supported on one another. At least one rolling element raceway is hardened along its annular shape in the contact area between rolling element and rolling bearing ring. The invention is characterized in that provided at the beginning and the end of the at least one hardened rolling element raceway is at least one overlap region which extends along the rolling element raceway, the overlap region comprising a region of lower hardness than the surrounding hardened region, the lower hardness gap region, extending at an inclination through the overlap region.
    Type: Grant
    Filed: December 21, 2012
    Date of Patent: April 5, 2016
    Assignee: IMO Holding GmbH
    Inventor: Hubertus Frank
  • Patent number: 9284632
    Abstract: Steel for nitrocarburizing includes, by mass %, C: 0% to less than 0.15%; Si: 0.01% to 1.00%; Mn: 0.01% to 1.00%; S: 0.0001% to 0.050%; Al: 0.0001% to 0.050%; Ti: more than 0.50% to 1.50%; N: 0.0005% to 0.0100%; and the balance consisting of Fe and inevitable impurities, in which P is limited to 0.050% or less; O is limited to 0.0060% or less; and the amount of Ti [Ti %], the amount of C [C %], the amount of N [N %], and the amount of S [S %] satisfy 0.48<[Ti %]?47.9×([C %]/12+[N %]/14+[S %]/32)?1.20.
    Type: Grant
    Filed: January 25, 2011
    Date of Patent: March 15, 2016
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventor: Manabu Kubota
  • Patent number: 9181597
    Abstract: The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M23C6 carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around 650° C.
    Type: Grant
    Filed: April 23, 2013
    Date of Patent: November 10, 2015
    Assignee: U.S. Department of Energy
    Inventors: Jeffrey A. Hawk, Paul D. Jablonski, Christopher J. Cowen
  • Publication number: 20150132144
    Abstract: It is an objective of the invention to provide a precipitation-hardening martensitic stainless steel having a far better balance between a high mechanical strength and a high toughness than conventional ones as well as having good corrosion resistance properties. There is provided a precipitation-hardening martensitic stainless steel throughout which precipitates of intermetallic compounds are dispersed, the martensitic stainless steel including: 0.1 mass % or less of C; 11 to 13 mass % of Cr; 7.5 to 11 mass % of Ni; 0.9 to 1.7 mass % of Al; 0.85 to 1.35 mass % of Mo; 1.75 to 2.75 mass % of W; and the balance including Fe and inevitable impurities, in which “[Mo content]+0.5×[W content]” is from 1.9 mass % to 2.5 mass %, and “[Mo content]/[W content]” is from 0.4 to 0.6.
    Type: Application
    Filed: November 7, 2014
    Publication date: May 14, 2015
    Inventors: Shinji OIKAWA, Shinya IMANO, Hiroyuki DOI
  • Patent number: 9028745
    Abstract: Various embodiments of the invention provide a low nickel austenitic stainless steel alloy composition including about 0.6% to about 0.8% by weight carbon; about 16% to about 18% by weight chromium; about 4.5% to about 5.5% by weight nickel; about 2.0% to about 5.0% by weight manganese; about 0.8% to about 1.2% by weight tungsten; about 0.8% to about 1.2% by weight molybdenum; about 0.65% to about 0.85% by weight niobium; about 0.3% to about 1.0% by weight silicon; balance iron and unavoidable impurities, wherein percentages are based on the overall weight of the composition. The invention further provides articles, such as turbine housings, prepared using the inventive alloys.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: May 12, 2015
    Assignee: Honeywell International Inc.
    Inventors: Shouxing Zhu, Li Xu, Balasubramani Nandagopal
  • Publication number: 20150076386
    Abstract: An iron-based alloy includes (in weight percent) carbon from about 1 to about 2 percent; manganese up to about 1 percent; silicon up to about 1 percent; nickel up to about 4 percent; chromium from about 10 to about 25 percent; molybdenum from about 5 to about 20 percent; tungsten up to about 4 percent; cobalt from about 17 to about 23 percent; vanadium up to about 1.5 percent; boron up to about 0.2 percent; sulfur up to about 0.03 percent; nitrogen up to about 0.4 percent; phosphorus up to about 0.06 percent; niobium up to about 4 percent; iron from about 35 to about 55 percent; and incidental impurities. The chromium/molybdenum ratio of the iron-based alloy is from about 1 to about 2.5. The alloy is suitable for use in elevated temperature applications, such as valve seat inserts for combustion engines.
    Type: Application
    Filed: September 19, 2013
    Publication date: March 19, 2015
    Applicant: L.E. Jones Company
    Inventors: Cong Yue Qiao, David Doll, Todd Trudeau, Peter Vennema
  • Patent number: 8980018
    Abstract: Ferritic stainless steel sheet for an exhaust part which has little deterioration in strength even if undergoing long term heat history and is low in cost, excellent in heat resistance and workability characterized by containing, characterized by containing, by mass %, C: less than 0.010%, N: 0.020% or less, Si: over 0.1% to 2.0%, Mn: 2.0% or less, Cr: 12.0 to 25.0%, Cu: over 0.9 to 2%, Ti: 0.05 to 0.3%, Nb: 0.001 to 0.1%, Al: 1.0% or less, and B: 0.0003 to 0.003%, having a Cu/(Ti+Nb) of 5 or more, and having a balance of Fe and unavoidable impurities.
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: March 17, 2015
    Assignee: Nippon Steel & Sumikin Stainless Steel Corporation
    Inventors: Junichi Hamada, Shinichi Teraoka, Yoshiharu Inoue, Norihiro Kanno
  • Patent number: 8900510
    Abstract: A heat-resistant, ferritic cast steel having excellent room-temperature toughness, which has a composition comprising by mass 0.32-0.48% of C, 0.85% or less of Si, 2% or less of Mn, 1.5% or less of Ni, 16-19.8% of Cr, 3.2-5% of Nb, Nb/C being 9-11.5, 0.15% or less of N, 0.002-0.2% of S, and 0.8% or less in total of W and/or Mo, the balance being Fe and inevitable impurities, and a structure in which a eutectic (?+NbC) phase formed from a ? phase and Nb carbide (NbC) has an area ratio of 60-90%, and an exhaust member made thereof.
    Type: Grant
    Filed: March 31, 2011
    Date of Patent: December 2, 2014
    Assignee: Hitachi Metals, Ltd.
    Inventor: Masahide Kawabata
  • Patent number: 8900379
    Abstract: Provided are a stainless steel for a proton-exchange membrane fuel cell separator having high durability and a low contact resistance (i.e., high electrical conductivity) and a proton-exchange membrane fuel cell using the same. More specifically, a stainless steel for a proton-exchange membrane fuel cell separator has a composition comprising 0.03% mass % or less of C, 16-45 mass % of Cr, 0.03 mass % or less of N, 0.1-5.0 mass % of Mo, wherein a total of the C content and the N content satisfies 0.03 mass % or less; a balance portion is comprised of Fe and unavoidable impurities; an atomic ratio of Cr/Fe with respect to Al, Cr, and Fe contained in a passive film on a surface of the stainless steel is 1 or greater.
    Type: Grant
    Filed: June 9, 2004
    Date of Patent: December 2, 2014
    Assignee: JFE Steel Corporation
    Inventors: Shin Ishikawa, Kunio Fukuda, Yasushi Kato, Osamu Furukimi, Kenji Takao
  • Patent number: 8808471
    Abstract: A martensitic stainless steel alloy is strengthened by copper-nucleated nitride precipitates. The alloy includes, in combination by weight percent, about 10.0 to about 12.5 Cr, about 2.0 to about 7.5 Ni, up to about 17.0 Co, about 0.6 to about 1.5 Mo, about 0.5 to about 2.3 Cu, up to about 0.6 Mn, up to about 0.4 Si, about 0.05 to about 0.15 V, up to about 0.10 N, up to about 0.035 C, up to about 0.01 W, and the balance Fe and incidental elements and impurities. The nitride precipitates may be enriched by one or more transition metals.
    Type: Grant
    Filed: April 13, 2009
    Date of Patent: August 19, 2014
    Assignee: QuesTek Innovations LLC
    Inventors: James A. Wright, Gregory B. Olson, Weijia Tang
  • Publication number: 20140209220
    Abstract: It is an object of the present invention to provide a metal diaphragm capable of achieving a higher strength, excellent corrosion resistance, and a smooth surface condition, and a pressure sensor including the diaphragm. The diaphragm according to the present invention includes a two-phase stainless steel having a composition of 24 to 26 mass % Cr, 2.5 to 3.5 mass % Mo, 5.5 to 7.5 mass % Ni, 0.03 mass % or less C, 0.08 to 0.3 mass % N, and the balance Fe and inevitable impurities, and having a 0.2% proof stress of 1300 MPa or higher.
    Type: Application
    Filed: January 23, 2014
    Publication date: July 31, 2014
    Applicant: Seiko Instruments Inc.
    Inventors: Takuma OTOMO, Keita NAITO, Ryo SUGAWARA, Tomoo KOBAYASHI
  • Patent number: 8747733
    Abstract: A precipitation hardenable martensitic stainless steel excellent in the stability of martensite, having the high strength, high toughness and high corrosion resistance is provided. The precipitation hardenable martensitic stainless steel contains at a mass rate, C: 0.05-0.10%, Cr: 12.0-13.0%, Ni: 6.0-7.0%, Mo: 1.0-2.0%, Si: 0.01-0.05%, Mn: 0.06-1.0%, Nb: 0.3-0.5%, V: 0.3-0.5%, Ti: 1.5-2.5%, Al: 1.0-2.3%, and the remainder consisting of Fe and an unavoidable impurity.
    Type: Grant
    Filed: April 14, 2011
    Date of Patent: June 10, 2014
    Assignee: Hitachi, Ltd.
    Inventors: Shinji Oikawa, Hideo Yoda, Masahiko Arai, Hiroyuki Doi
  • Patent number: 8721808
    Abstract: The ferrite system heat-resistant cast steel and the exhaust system component are provided, which are inexpensive and are able to improve the reliability by largely improving the toughness under normal temperature and thermal fatigue performance. The ferrite system heat-resistant cast steel includes composition structure comprised, percent by mass, of 0.1% to 0.4% carbon, 0.5% to 2.0% silicon, 0.2% to 1.2% manganese, 0.3% or less phosphorus, 0.01% to 0.4% sulfur, 14.0% to 21.0% chrome, 0.05% to 0.6% niobium, 0.01% to 0.8% aluminum, 0.15% to 2.3% nickel, residual iron and inevitable impurities.
    Type: Grant
    Filed: February 8, 2010
    Date of Patent: May 13, 2014
    Assignee: Aisin Takaoka Co., Ltd.
    Inventors: Daisuke Yamanaka, Zhong-zhi Zhang
  • Patent number: 8663403
    Abstract: A precipitation-hardened stainless steel alloy comprises, by weight: about 14.0 to about 16.0 percent chromium; about 6.0 to about 8.0 percent nickel; about 1.25 to about 1.75 percent copper; greater than about 1.5 to about 2.0 percent molybdenum; about 0.001 to about 0.025 percent carbon; niobium in an amount greater than about twenty times that of carbon; and the balance iron and incidental impurities. The alloy has an aged microstructure and an ultimate tensile strength of at least about 1100 MPa and a Charpy V-notch toughness of at least about 69 J. In one embodiment, the aged microstructure includes martensite and not more than about 10% reverted austenite. In another embodiment, the alloy includes substantially all martensite and substantially no reverted austenite. The alloy is useful for making turbine airfoils.
    Type: Grant
    Filed: June 8, 2011
    Date of Patent: March 4, 2014
    Assignee: General Electric Company
    Inventors: Jianqiang Chen, Thomas Michael Moors, Jon Conrad Schaeffer
  • Patent number: 8657971
    Abstract: A brake disk excellent in temper softening resistance and toughness comprising, by mass, 0.1% or less of C, 1.0% or less of Si, 2.0% or less of Mn, 10.5% to 15.0% of Cr, and 0.1% or less of N, the remainder being Fe and unavoidable impurities, such that the following inequalities are satisfied: 5Cr+10Si+15Mo+30Nb?9Ni?5Mn?3Cu?225N?270C<45 (1) and 0.03?{C+N?(13/92)Nb}?0.09 (2) wherein Cr, Si, Mo, Nb, Ni, Mn, Cu, N, and C each represent the content of the corresponding elements on a mass percent basis, and having a martensitic structure having prior-austenite grains with an average diameter of 8 to less than 15 ?m.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: February 25, 2014
    Assignee: JFE Steel Corporation
    Inventors: Junichiro Hirasawa, Takumi Ujiro, Osamu Furukimi
  • Publication number: 20140007981
    Abstract: A precipitation hardening type martensitic stainless steel of an embodiment contains: Cr: 8.5 to 12.5%; Mo: 1 to 2%; Ni: 8.5 to 11.5%; Ti: 0.6 to 1.4%; C: 0.0005 to 0.05%; Al: 0.0005 to 0.25%; Cu: 0.005 to 0.75%; Nb: 0.0005 to 0.3%; Si: 0.005 to 0.75%; Mn: 0.005 to 1%; and N: 0.0001 to 0.03% by mass, and the balance of Fe and unavoidable impurities.
    Type: Application
    Filed: June 28, 2013
    Publication date: January 9, 2014
    Inventors: Reki TAKAKU, Haruki OHNISHI, Masayuki YAMADA, Yoriharu MURATA, Kenichi IMAI
  • Publication number: 20130327447
    Abstract: A high strength corrosion resistant tubing comprises about 35 to about 55% Ni, about 12 to about 25% Cr, about 0.5 to about 5% Mo, up to about 3% Cu, about 2.1 to about 4.5% Nb, about 0.5 to about 3% Ti, about 0.05 to about 1.0% Al, about 0.005 to about 0.04% C, balance Fe plus incidental impurities and deoxidizers. The composition also satisfies the equation: (Nb?7.75 C)/(Al+Ti)=about 0.5 to about 9. A process for manufacturing the tubing includes: extruding the alloy to form a tubing; cold working the extruded tubing; annealing the cold worked tubing; and applying at least one age hardening step to the annealed tubing. Another process includes extruding the alloy at a temperature of about 2050° F. or less; annealing the extruded tubing; and applying at least one age hardening step to the annealed tubing.
    Type: Application
    Filed: June 11, 2012
    Publication date: December 12, 2013
    Applicant: HUNTINGTON ALLOYS CORPORATION
    Inventor: Sarwan K. Mannan
  • Publication number: 20130312880
    Abstract: Provided is a duplex stainless steel having a high strength and a high toughness. A stainless steel according to the present invention includes: a chemical composition containing, in mass percent, C: at most 0.030%, Si: 0.20 to 1.00%, Mn: at most 8.00%, P: at most 0.040%, S: at most 0.0100%, Cu: more than 2.00% and at most 4.00%, Ni: 4.00 to 8.00%, Cr: 20.0 to 30.0%, Mo: at least 0.50% and less than 2.00%, N: 0.100 to 0.350%, and sol. Al: at most 0.040%, the balance being Fe and impurities; and a structure, wherein a rate of ferrite in the structure is 30 to 70%, and a hardness of the ferrite in the structure is at least 300 Hv10gf.
    Type: Application
    Filed: February 10, 2012
    Publication date: November 28, 2013
    Applicant: NIPPON STEEL & SUMITOMO METAL CORORATION
    Inventors: Daisuke Motoya, Masahiko Hamada, Hisashi Amaya, Hiroyuki Nagayama, Kenta Yamada
  • Publication number: 20130220491
    Abstract: A stainless steel strip article is disclosed. The article is formed from a corrosion resistant alloy having the following composition in weight percent, about: C ?0.03 max. Mn ?1.0 max. Si ?0.75 max. P 0.040 max. S 0.020 max. Cr 10.9-11.1 Ni 10.9-11.1 Mo 0.9-1.1 Ti 1.5-1.6 Al ?0.25 max. Nb 0.7-0.8 Cu ???1 max. B 0.010 max. N 0.030 max. The balance is iron and usual impurities. The elongated thin strip article provides a room temperature tensile strength of at least about 280 ksi in the solution treated and age hardened condition. A method of making the strip article and a method of using it to make a golf club are also disclosed.
    Type: Application
    Filed: November 15, 2012
    Publication date: August 29, 2013
    Applicant: CRS HOLDINGS, INC.
    Inventor: CRS Holdings, Inc.
  • Publication number: 20130186106
    Abstract: The problem to be solved of the present invention is to provide a precipitation hardening martensitic stainless steel having excellent tissue stability, strength, toughness, and corrosion-resistance, requiring no sub-zero treatment, and having excellent productivity; and also a steam turbine long blade using the same. The problem is solved by providing a precipitation hardening martensitic stainless steel containing, by mass, 0.1% or less of C; 0.1% or less of N; 9.0% or more and 14.0% or less of Cr; 9.0% or more and 14.0% or less of Ni; 0.5% or more and 2.5% or less of Mo; 0.5% or less of Si; 1.0% or less of Mn; 0.25% or more and 1.75% or less of Ti; 0.25% or more and 1.75% or less of Al, and the rest is Fe and inevitable impurities; and a steam turbine long blade using the precipitation hardening martensitic stainless steel.
    Type: Application
    Filed: January 15, 2013
    Publication date: July 25, 2013
    Applicant: HITACHI, LTD.
    Inventor: Hitachi, Ltd.
  • Publication number: 20130160905
    Abstract: A method for producing a tempered martensitic heat resistant steel for high temperature applications at an application temperature of up to 650° C. and to a steel produced by the method. The use of the steel in the production of components for high temperature applications such as turbine blades or casings, bolting and boiler tubes, heat exchangers or other elements in power generation systems.
    Type: Application
    Filed: June 10, 2011
    Publication date: June 27, 2013
    Applicant: TATA STEEL NEDERLAND TECHNOLOGY BV
    Inventors: Urszula Alicja Sachadel, Peter Francis Morris, Philip Clarke, Cheng Liu
  • Patent number: RE44709
    Abstract: The soft Cr-containing steel includes, on a % by mass basis, C: from about 0.001% to about 0.020%, Si: more than about 0.10% and less than about 0.50%, Mn: less than about 2.00%, P: less than about 0.060%, S: less than about 0.008%, Cr: from about 12.0% to about 16.0%, Ni: from about 0.05% to about 1.00%, N: less than about 0.020%, Nb: from about 10×(C+N) to about 1.00%, Mo: more than about 0.80% and less than about 3.00%, wherein the contents of alloying elements, represented by Si and Mo, respectively, on a % by mass, satisfy the formula Si?1.2-0.4 Mo, so as to prevent precipitation of the Laves phase and to stably secure an effect of increasing high-temperature strength due to solid solution Mo.
    Type: Grant
    Filed: May 13, 2009
    Date of Patent: January 21, 2014
    Assignee: JFE Steel Corporation
    Inventors: Atsushi Miyazaki, Junichiro Hirasawa, Mineo Muraki, Yoshihiro Yazawa, Osamu Furukimi