Abstract: A soft magnetic film having a high saturation magnetic flux density and superior soft magnetic properties and capable of maintaining superior soft magnetic properties when worked to a magnetic head. The magnetic film is represented by the general formula of Fe.sub.x M.sub.y L.sub.z J.sub.u Q.sub.w, wherein M denotes at least one selected from the group of Ru, Cr, Ti, Mo, W and Rh, L denotes at least one selected from the group of Y, Hf, Zr, Ta and Nb, J denotes at least one of Al and Ga, Q denotes at least one of Si and Ge and x, y, z, u and w denote the proportions of respective atoms in atom %, and wherein the composition is given by 68.ltoreq.x<80, 3.ltoreq.y<12, 3<z<5, 0.ltoreq.u<10 and 10<w<25. The soft magnetic film is formed on non-magnetic or magnetic ceramics and worked into a magnetic head.

Abstract: A torsionally reacting spring, such as a helical spring, a torsion bar, or a torsion tube, requires the ability to torsionally deform elastically during service and return to its original, undeformed shape. The torsionally reacting spring is made of a bulk-deforming amorphous alloy which may be cooled from the melt at a cooling rate of less than about 500.degree. C. per second, yet retain an amorphous structure. A preferred bulk-solidifying amorphous alloy has a composition, in atomic percent, of from about 45 to about 67 percent total of zirconium plus titanium, from about 10 to about 35 percent beryllium, and from about 10 to about 38 percent total of copper plus nickel, plus incidental impurities, the total of the percentages being 100 atomic percent.

Abstract: Alloy foils for liquid-phase diffusion bonding of heat-resisting metals in an oxidizing atmosphere comprise 6.0 to 15.0 percent silicon, 0.1 to 2.0 percent manganese, 0.50 to 30.0 percent chromium, 0.10 to 5.0 percent molybdenum, 0.50 to 10.0 percent vanadium, 0.02 to 1.0 percent niobium, 0.10 to 5.0 percent tungsten, 0.01 to 0.5 percent nitrogen, 0.10 to 5.0 percent boron, plus 0.005 to 1.0 percent carbon, and/or either or both of 0.01 to 5.0 percent titanium and 0.01 to 5.0 percent zirconium, all by mass, with the balance comprising nickel and impurities, and have a thickness of 3.0 to 300 .mu.m. Alloy foils for liquid-phase diffusion bonding of heat-resisting metals in an oxidizing atmosphere are also available with substantially vitreous structures.

Abstract: The present invention provides a ferrous metal glassy alloy having temperature interval .DELTA.Tx of supercooled liquid as expressed by the following formula:.DELTA.Tx=Tx-Tg(where, Tx is an onset temperature of crystallization, and Tg is a glass transition temperature) of at least 40 K, which realizes magnetic properties as a bulky alloy.

Abstract: At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is:(Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.dwherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

Abstract: An amorphous alloy which is resistant to hot corrosion in sulfidizing and oxidizing atmospheres at high temperatures, consisting of at least one element selected from the group of Al and Cr and at least one element selected from the refractory metals Mo, W, Nb, and Ta, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Fe, Co, Ni and Cu. The addition of Si further improves the alloy's oxidation resistance.

Abstract: Alloy foils for liquid-phase diffusion bonding of heat-resisting metals in an oxidizing atmosphere comprise 6.0 to 15.0 percent silicon, 0.1 to 2.0 percent manganese, 0.50 to 30.0 percent chromium, 0.10 to 5.0 percent molybdenum, 0.50 to 10.0 percent vanadium, 0.02 to 1.0 percent niobium, 0.10 to 5.0 percent tungsten, 0.05 to 2.0 percent nitrogen, 0.50 to 20.0 percent phosphorus, plus 0.005 to 1.0 percent carbon, and/or either or both of 0.01 to 5.0 percent titanium and 0.01 to 5.0 percent zirconium, all by mass, with the balance comprising nickel and impurities, and have a thickness of 3.0 to 300 .mu.m. Alloy foils for liquid-phase diffusion bonding of heat-resisting metals in an oxidizing atmosphere are also available with substantially vitreous structures.

Abstract: A process for producing an amorphous alloy ribbon by the single roll method is disclosed, which comprises injecting through a slot disposed at a nozzle tip a molten alloy having the composition represented by the general formula:(Fe.sub.1-a M.sub.a).sub.100-x-y-z-b Cu.sub.x Si.sub.y B.sub.z M'.sub.bwherein M is Co and/or Ni, M' is at least one element selected from the group consisting of Nb, Mo, W and Ta, and a, x, y, z and b satisfy the relationships: 0.ltoreq.a.ltoreq.0.1, 0.5.ltoreq.x.ltoreq.2 (atomic %), 5.ltoreq.y.ltoreq.20 (atomic %), 5.ltoreq.z.ltoreq.11 (atomic %), 14.ltoreq.y+z.ltoreq.25 (atomic %) and 2.ltoreq.b.ltoreq.5 (atomic %), provided that the ratio of y to z (y/z) is in the range of 0.5.ltoreq.y/z.ltoreq.3, onto a cooling wheel comprising a Cu alloy containing Be in an amount of 0.05 to 3.0% by weight. This process is advantageous in that the position of peel of the amorphous alloy ribbon formed on the cooling wheel can be controlled.

Abstract: Disclosed is a manufacture and coating method of mechanical products using ferrous alloy in order to improve wear, corrosion, and heat resistances of the mechanical products which are exposed to friction and wear environments with or without lubricating conditions. The mechanical products of the invention include rotation contact parts such as bush and shaft in the inside of caterpillar roller, mechanical seal under high surface pressure, and drawing dice and plug under sliding friction stress. A ferrous alloy composition used for coating in the invention comprises Cr:18.0-42.0 wt %, Mn: 1.0-3.2 wt %, B:3.0-4.5 wt %, Si: 1.0-3.0 wt %, C: less than 0.3 wt %, inevitably incorporated impurities, and Fe for the rest of content. A ferrous alloy composition used for manufacturing bush type product comprises C: less than 4.5%, Si:2.5%, Mn:less than 2%, Cr:0.5-35%, and Fe for the rest of content.

Abstract: An electrical heating system uses heating elements made of ribbons of amorphous metallic alloys. The heating elements have a large area using long and wide ribbons, to achieve good heat transfer to the surroundings, that is low thermal resistance. The area of the heating elements and thus the thermal resistance is determined according to the desired thermal power, under the constraint of a low operating temperature, that is a temperature well below the embrittlement temperature of the amorphous alloy used in the heating elements. The operating temperature is preferably kept low enough so as not to generate benzopyrene or other unhealthy or ecologically unfavorable fumes or gases. The thin ribbons with low thermal resistance also have a fast heating constant, that is the heater reaches its steady state temperature in a short time. The electrical heating system uses low cost insulation and support materials, that is materials intended for use at low temperatures only.

Abstract: A corrosion-resistant amorphous alloy containing Ta in an amount of from 10 to 40 atomic % and Mo, Cr, W, P, B and/or Si is disclosed.This alloy can be prepared by rapidly cooling and solidifying molten alloy, shows a satisfactory corrosion resistance in high-temperature concentrated phosphoric acid, and is adapted to be used as a plant structural material or a separator for a fuel cell.

Abstract: A magnetic core is obtained by winding or laminating at least one alloy ribbon and has excellent squareness characteristic and magnetic saturation characteristic in a high frequency region wherein the squareness ratio of the magnetic core is improved by restricting the surface roughness of the alloy ribbon to specific regions.

Abstract: At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula(ETM.sub.1-x Ti.sub.x).sub.a Cu.sub.b (Ni.sub.1-y Co.sub.y).sub.cwherein x is from 0.1 to 0.3, y.cndot.

Abstract: A high-strength aluminum-based alloy consisting of a composition represented by the general formula: Al.sub.bal Q.sub.a M.sub.b X.sub.c, wherein Q is at least one element selected from the group consisting of Mn and Cr; M is at least one element selected from the group consisting of Co, Ni, and Cu; X is at least one of rare earth elements including Y, or Misch metal (Mm); and a, b and c are, in atomic percentages, 1.ltoreq.a.ltoreq.7, 0.5.ltoreq.b.ltoreq.5, and 0<c.ltoreq.5, the aluminum-based alloy containing quasicrystals in the structure thereof. The quasicrystals may be of an icosahedral phase (I phase), a decagonal phase (D phase), or a crystalline phase akin thereto and the structure may comprise the quasicrystalline phase and a phase formed of any one of an amorphous phase, aluminum, and a supersaturated aluminum solid solution or a composite (mixed phase) thereof.

Abstract: Amorphous metal alloys rich in noble metals prepared by rapid solidification processing are disclosed. The alloys have at least a ternary composition having the formula M.sub.a G1.sub.b G2.sub.c, wherein M is at least one element selected from the group consisting of Ag, Au, Ru, Os, Rh, Ir, Pd, and Pt, and G1 is at least one element selected from the group consisting of B, C, Cu, Ni, Si, and Be, and G2 is at least one element selected from the group consisting of Y, the lanthanides, Zr, Hf, Ca, Mg, Ti, Nb, and Ta. The subscripts a, b, and c are atomic percentages; a ranges from 70 to 90 percent, and b and c range from 5 to 15 percent each. Preferably, a is at least 80 percent and b and c are generally equal. The amorphous metal alloys are readily glass forming and thermally stable at room temperatures.

Abstract: A high strength aluminum-based alloy, which having a composition of the general formula: Al.sub.bal Q.sub.a M.sub.b X.sub.c T.sub.d, wherein Q represents at least one element selected from the group consisting of Mn, Cr, V, Mo and W; M represents at least one element selected from the group consisting of Co, Ni, Cu and Fe; X represents at least one element selected from rare earth elements including Y or Mm; T represents at least one element selected from the group consisting of Ti, Zr and Hf; and a, b, c and d represent the following atomic percentages: 1.ltoreq.a.ltoreq.7, 0>5, 0>c.ltoreq.5 and 0>d.ltoreq.2, and contains quasi-crystals in the structure thereof. The alloy of the present invention is excellent in the hardness and strength at both room temperature and a high temperature, and also in thermal resistance and ductility.

Abstract: There is provided according to the present invention a magnetic alloy with ultrafine crystal grains having a composition represented by the general formula:Fe.sub.100-x-y M.sub.x B.sub.y (atomic %)wherein M represents at least one element selected from Ti, Zr, Hf, V, Nb, Mo, Ta, Cr, W and Mn, 4.ltoreq.x.ltoreq.15, 2.ltoreq.y.ltoreq.25, and 7.ltoreq.x+y.ltoreq.35, at least 50% of the alloy structure being occupied by crystal grains having an average grain size of 500 .ANG. or less, and the crystal grains being based on a bcc structure. It may further contain X (Si, Ge, P, Ga, etc.) and/or T (Au, Co, Ni, etc.). This magnetic alloy has an excellent saturation magnetic flux density, permeability and heat resistance.

Abstract: Bearings are made having at least one surface made of an amorphous alloy having a coefficient of friction of less than 0.5 and having a tensile strength of 1.0 GPa or greater. In the case of a bearing shaft, the shaft can be smaller than a comparable steel shaft. Articles can be fabricated by heating the amorphous metal to a temperature above its plastic flow temperature and below its crystallization temperature so that it is flowable. The heated material is molded or formed into a desired shape and then the molded article is cooled to its metastable, amorphous state. A preferred configuration for the bearing shaft is in a parabola of revolution form so it acts as a thrust bearing.

Abstract: An amorphous alloy which is resistant to hot corrosion in sulfidizing and oxidizing atmospheres at high temperatures, consisting of at least one element selected from the group of Al and Cr and at least one element selected from refractory metals of Mo. W, Nb and Ta, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti, Zr, Fe, Co, Ni and Cu. The addition of Si further improves the alloy's oxidation resistance.

Abstract: An amorphous metal wire having the following composition by atomic %:(Fe.sub.a Co.sub.b).sub.100-(y+z) Si.sub.y B.sub.zwhere 0.4.ltoreq.a.ltoreq.0.6, a+b=1, 6.ltoreq.y.ltoreq.8, and 13.ltoreq.z.ltoreq.16. The wire shows a Large Barkhausen effect and is excellent in pulse voltage generating properties and toughness. The amorphous metal wire according to the present invention is widely applicable to pulse voltage generating elements and various magnetic markers.

Abstract: Amorphous alloy comprising 30 to 75 atomic % Cr, the remainder being substantially at least one element selected from the group consisting of Ti and Zr and alloys represented by the general formula: X.sub.a Cr.sub.b M.sub.c wherein X is at least one element selected from the group consisting of Ti and Zr; M is at least one element selected from the group consisting of Mg, Al, Fe, Co, Ni, Cu, Mo and W; and a, b, and c are, in atomic percentage, a>20, 20 .ltoreq.b.ltoreq.75, 0<c .ltoreq.20 and a+b+c=100. The alloys are excellent in corrosion resistance and wear resistance, form a stable protective film and are spontaneously passive, even in corrosive environment such as a poorly oxidizing, highly corrosive HCl solution containing chlorine ions.

Abstract: A process is described for producing amorphous metal alloys wherein impure ferrophosphorus slag, a by-product from a phosphorus-producing electric furnace, is used to supply phosphorus, chromium, vanadium and iron values to such alloys by mixing it with iron and any other desired metalloid and/or elements to form a molten mixture, treating the molten mixture to a separation step to remove insoluble slag formed in said molten mixture, and rapidly cooling the molten mixture to below its vitrification temperature to form a solid amorphous metal alloy.

Abstract: A glassy metal alloy consists essentially of the formula Co.sub.a Fe.sub.b Ni.sub.c M.sub.d B.sub.e Si.sub.f C.sub.g, where M is selected from molybdenum and chromium and "a", "b", "c", "d", "e", "f" and "g" are in atom percent, "a" ranges from about 40 to about 43, "b" ranges from about 35 to about 42 and "c" ranges from 0 to about 5, "d" ranges from 0 to about 3, "e" ranges from about 10 to about 25, "f" ranges from 0 to about 15 and "g" ranges from 0 to about 2. The alloy can be cast by rapid solidification into ribbon, annealed to enhance magnetic properties thereof, and formed into a marker that is especially suited for use in magneto-mechanically actuated article surveillance systems. Advantageously, the marker is characterized by relatively linear magnetization response in the frequency regime wherein harmonic marker systems operate magnetically.

Abstract: Protection of a metal surface is carried out by applying a coating of vitreous enamel to the surface so that the enamel forms a strong bond with the metal and then spraying a coating of an atomized protective metal on the enamel. Preferably a peening operation is carried out on the surface of the sprayed metal simultaneously with or immediately after the spraying of the metal. The method is particularly advantageous in protecting steel marine structures against corrosion and, where the protective metal is cupro-nickel, fouling by marine creatures. The vitreous enamel forms an electrically insulating layer preventing galvanic action between the steel and the cupro-nickel in the presence of sea water.

Abstract: The present invention provides a high strength and anti-corrosive aluminum-based alloy essentially consisting of an amorphous structure or a multiphase amorphous/fine crystalline structure, which is represented by the general formula Al.sub.x M.sub.y R.sub.z. In this formula, M represents at least one metal element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Cu, Zr, Nb, Mo and Ni, and R represents at least one element or mixture selected from the group consisting of Y, Ce, La, Nd and Mm (misch metal). Additionally, in the formula, x, y and z represent the composition ratio, and are atomic percentages satisfying the relationships of x+y+z=100, 64.5.ltoreq.x.ltoreq.95, 5.ltoreq.y.ltoreq.35, and 0<z.ltoreq.0.4.

Abstract: A process for producing an aluminum alloy in the form of mass includes: preparing as a material to be formed a mixed powder of aluminum and at least one kind of metal or non-metallic substance selected from the elements belonging to Groups 4a, 4b, 5a, 6a, 7a and 8a of the periodic table and boron, or a compact or a cast material formed of the mixed powder; placing the material to be formed in a die, and performing plastic deformation repeatedly on the material to be formed at 100.degree. to 400.degree. in an inert atmosphere while retaining at least part of the material to be formed in a confined state, so as to cause diffusion reaction between phases constituting the material to be formed, thereby forming the quasi-stable phase composed mainly of amorphous phases and/or supersaturated solid solution phases.

Abstract: A glassy metal alloy consists essentially of the formula Co.sub.a Fe.sub.b Ni.sub.c M.sub.d B.sub.e Si.sub.f C.sub.g, where M is selected from molybdenum and "a", "b", "c", "d", "e", "f" and "g" are in atom percent, "a" ranges from about 40 to about 43, "b" ranges from about 35 to about 42 and "c" ranges from 0 to about 5, "d" ranges from 0 to about 3, "e" ranges from about 10 to about 25, "f" ranges from 0 to about 15 and "g" ranges from 0 to about 2. The alloy can be cast by rapid solidification into ribbon or otherwise formed into a marker that is especially suited for use in magneto-mechanically actuated article surveillance systems. Advantageously, the marker is characterized by relatively linear magnetization response in the frequency regime wherein harmonic marker systems operate magnetically. Voltage amplitudes detected for the marker are high, and interference between surveillance systems based on mechanical resonance and harmonic re-radiance is virtually eliminated.

Abstract: An amorphous alloy which is resistant to hot corrosion in sulfidizing and oxidizing atmospheres at high temperatures, consisting of at least one element selected from the group of Al and Cr and at least one element selected from refractory metals of Mo. W, Nb and Ta, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti, Zr, Fe, Co, Ni and Cu. The addition of Si further improves the alloy oxidation resistance.

Abstract: Amorphous alloys having an extremely high corrosion resistance comprise Cr and at least one element selected from Ta and Nb, as essential components, and are spontaneously passive owing to the formation of stable protective films, even in very corrosive environments such as poorly oxidizing concentrated hydrochloric acid. The amorphous alloy may further include one or more elements appropriately selected from other alloying elements of Al, Ti, Zr, Fe, Co, Ni, Cu, Mo and W. The amorphous alloys have advantageous properties, such as very high corrosion resistance, high corrosion resistance at elevated temperatures and high wear resistance, and, therefore are useful in chemical plants or other industrial and domestic applications.

Abstract: A high-strength aluminum alloy consisting of an amorphous phase containing quasicrystals constituted of aluminum as the principal element, a first additive element consisting of at least one rare earth element and a second additive element consisting of at least one element other than aluminum and rare earth elements, and a crystalline phase consisting of the principal element and the first additive element and the second additive element contained in a supersaturated solid solution form, the amorphous phase containing quasicrystals being contained in a volume percentage of 60 to 90%. The contents of the additive elements preferably fall within a hatched range in the figure, still preferably within a range covered with dot-dash lines in the figure.

Abstract: An amorphous alloy which is resistant to hot corrosion in sulfidizing and oxidizing atmospheres at high temperatures, consisting of at least one element selected from the group of Al and Cr and at least one element selected from refractory metals of Mo. W, Nb and Ta, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti, Zr, Fe, Co, Ni and Cu. The addition of Si further improves the alloy's oxidation resistance.

Abstract: A process for producing nanocrystalline materials, and in particular nanocrystalline nickel having an average grain size of less than about 11 nanometers and ternary and quaternary nickel-iron alloys, such as NiFeCr and NiFeCrMn alloys, having a grain size less than about 100 nm is described. The nanocrystalline nickel is electrodeposited onto the cathode in an aqueous acidic electrolytic cell by application of a pulsed D.C. current. The ternary and quaternary Nickel-Iron alloys and other binary, ternary and quaternary alloys may be produced by D.C. electroplating or by pulsed D.C. electroplating. The cell electrolyte also contains a stress reliever, such as saccharin, which helps to control the grain size. The novel products of the invention find utility as wear resistant coatings, hydrogen storage materials, magnetic materials and as catalysts for hydrogen evolution.

Abstract: A high strength aluminum alloy is expressed by a general formula, Al.sub.a X.sub.b Mm.sub.c, in which "X" stands for at least one element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zr, "Mm" stands for a misch metal, a content "a" of aluminum falls in a range of from 95.2 to 97.5 atomic %, and a content "b" of "X" and a content "c" of the "Mm" fall in a hatched area enclosed by points "A," "B," "C" and "D" of accompanying FIG. 1 on atomic % basis, and whose metallic phase includes microcrystalline phases or mixed phases containing amorphous phases in a volume content of less than 50% and the balance of microcrystalline phases. As a result, the amorphous phases or the microcrystalline phases are dispersed uniformly in its base microcrystalline phases appropriately, and at the same time the thus generating base microcrystalline phases are reinforced by forming solid solutions including the "Mm" and the transition metal element "X" as well.

Abstract: Metallic glass/amorphous metal electrodes produced by rapid solidification (i) having a structure that is either amorphous or nanocrystalline, (ii) containing the principal alloying element as Ni, (iii) containing alloying conditions of Co and Mo in the range of 0 to 8 at . %, and when combined with NI, represent 0.75 to 0.85 of the atomic fraction of the alloy, and (iv) containing metalloid elements comprised of one or more of the elements C,B,Si and P either singly or in combination to represent 0.15 to 0.25 atomic faction of the alloy. The electrodes have excellent thermal stability, improved stability in an aqueous electrolyte and can provide improved current efficiency--anodic overpotential performance. They are used in the electrolysis of aqueous electrolyte solutions such as mixtures of caustic and water in the production of oxygen and hydrogen.

Abstract: A palladium-based alloy is disclosed having a composition consisting essentially of nickel in the range of about 3 to about 30 atom percent, silicon in the range of about 15 to about 20 atom percent, the balance being palladium plus incidental impurities. The alloys of the present invention are particularly suited for joining stainless steels employed in orthodontic devices at brazing temperatures less than about 900.degree. C. The alloys are typically produced in the form of a foil having a thickness of at least about 150 .mu.m.

Abstract: Deposition of a hard film of Ti-Si-N composite material on a substrate is carried out by using a source of evaporation possessing a composition of Ti.sub.a Si.sub.b (wherein "a" and "b" stand for atomic percentages respectively falling in the ranges of 75 at % .ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.25 at %, providing a+b=100 at %). Deposition is effected by a sputtering process or ion plating process in an atmosphere of an inert gas containing a nitrogen-containing reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of nitrogen is kept constant or varied continuously or stepwise. By this method there can be obtained a film having fine TiN crystalline particles uniformly dispersed in the matrix phase of Ti-Si amorphous metal or a film of functionally gradient structure in which the ratio of fine TiN crystalline particles dispersed in the matrix phase increases continuously or stepwise in the direction of thickness of the film.

Abstract: An alloy based on titanium and containing 0.5 to 30% by weight of magnesium, calcium or lithium is produced by vapor quenching to yield a metastable solid solution of solute in titanium. Exemplified alloys containing magnesium have age hardening or solution strengthening characteristics. Vapor quenching enables these alloys to be produced despite the differences in melting temperature between solute and solvent by separate vaporization of each of the species and mixing in the vapor phase. This method provides a route to achieving rapid solidification microstructures unobtainable by other rapid solidification methods. Preferred alloys comprise Ti with 1-15% or 3-7% by weight of magnesium. The alloys may contain other strengthening ingredients currently used in titanium alloys.

Abstract: An aluminum-based alloy which consists Al and 0.1 to 25 atomic % of at least two transition metal elements and has a structure in which at least quasicrystals are homogeneously dispersed in a matrix composed of Al or a supersaturated Al solid solution. The quasicrystals are preferably composed of an I-phase alone or a mixed phase of an I-phase and a D-phase and preferably has a volume nfraction of 20% or less. Specifically, the aluminum-based alloy has the composition represented by the general formula Al.sub.bal Ni.sub.a X.sub.b or Al.sub.bal Ni.sub.a X.sub.b M.sub.c wherein X is one or two elements selected between Fe and Co; M is at least one element selected from among Cr, Mn, Nb, Mo, Ta and W; 5.ltoreq.a.ltoreq.10; 0.5.ltoreq.b.ltoreq.10; and 0.1.ltoreq.c.ltoreq.5. The alloy is excellent in hardness and strength both at room temperature and high temperature and in heat resistance and has a high specific strength. It can retain the excellent characteristics even when affected by the heat of working.

Abstract: Deposition of a hard film of Ti--Si--N composite material on a substrate is carried out by using a source of evaporation possessing a composition of Ti.sub.a Si.sub.b (wherein "a" and "b" stand for atomic percentages respectively falling in the ranges of 75 at %.ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.25 at %, providing a+b=100 at %). Deposition is effected by a sputtering process or ion plating process in an atmosphere of an inert gas containing a nitrogen-containing reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of nitrogen is kept constant or varied continuously or stepwise.

Abstract: A high strength amorphous aluminum-based alloy comprises 75 atom % (inclusive) to 90 atom % (inclusive) of Al; 3 atom % (inclusive) to 15 atom % (inclusive) of Ni; and 3 atom % (inclusive) to 12 atom % (inclusive) of at least one element selected from the group consisting of Dy, Er and Gd, and has an amorphous phase volume fraction (Vf) of at least 50%. This leads to a higher amorphous phase forming ability and a wider plastically workable temperature region so that the workability of the alloy is satisfactory to produce structural members utilizing a working process such as a hot extruding process, a hot forging process or the like.

Abstract: An amorphous alloy which is resistant to hot corrosion in sulfidizing and oxidizing atmospheres at high temperatures, consisting of Cr and at least one element selected from refractory metals of Nb and Ta, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti, Zr, Fe, Co, Ni and Cu. The addition of Si further improves the alloy's oxidation resistance.

Abstract: The finishes of the present invention consist essentially of metal alloys having the general formula:T.sub.a Cr.sub.b Zr.sub.c B.sub.d M.sub.e M'.sub.f X.sub.g I.sub.h(I)in which a+b+c+d+e+f+g+h=100 atomic percent;T is Ni, Co, Ni--Co or any combination of at least one of Ni and Co with Fe, wherein 3<Fe<82 at. % and 3<a<85 at. %;M is one or more elements of the group consisting of Mn, Cu, V, Ti, Mo, Ru, Hf, Ta, W, Nb, Rh, wherein 0<e<12 at. %;M' is one or more rare earths, including Y, wherein 0<f<4 at. %;X is one or more metalloids of the group consisting of C, P, Ge and Si, wherein 0<g<17 at. %;I represents inevitable impurities, wherein h<1 at. %, and 5.ltoreq.b.ltoreq.25, 5.ltoreq.c.ltoreq.15, and 5.ltoreq.d.ltoreq.18.Powders obtained from these alloys that are deposited on substrates by thermal projection provide finishes having increased hardness in addition to high ductility and excellent resistance to corrosion.

Abstract: Alloys which form metallic glass upon cooling below the glass transition temperature at a rate appreciably less than 10.sup.6 K/s comprise beryllium in the range of from 2 to 47 atomic percent and at least one early transition metal in the range of from 30 to 75% and at least one late transition metal in the range of from 5 to 62%. A preferred group of metallic glass alloys has the formula (Zr.sub.1-x Ti.sub.x).sub.a (Cu.sub.1-y Ni.sub.y).sub.b Be.sub.c. Generally, a is in the range from 30 to 75% and the lower limit increases with increasing x. When x is in the range of from 0 to 0.15, b is in the range of from 5 to 62%, and c is in the range of from 6 to 47%. When x is in the range of from 0.15 to 0.4, b is in the range of from 5 to 62%, and c is in the range of from 2 to 47%. When x is in the range of from 0.4 to 0.6, b is in the range of from 5 to 62%, and c is in the range of from 2 to 47%. When x is in the range of from 0.6 to 0.

Abstract: The present invention provides high strength, heat resistant aluminum-based alloys having a composition represented by the general formula: Al.sub.a M.sub.b X.sub.cwherein:M is at least one metal element selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si;X is at least one metal element selected from the group consisting of Hf, Nb, and Ta; anda, b and c are atomic percentages falling within the following ranges:50.ltoreq.a.ltoreq.95, 0.5.ltoreq.b.ltoreq.35 and 0.5.ltoreq.c.ltoreq.25, the aluminum-based alloy being in an amorphous state, microcrystalline state or a composite state thereof. The aluminum-based alloys possess an advantageous combination of properties of high strength, heat resistance, superior ductility and good processability which make then suitable for various applications.

Abstract: A hard wear-resistant film is formed on a substrate in an atmosphere of an inert gas by using a target of a composition of Al.sub.a Ti.sub.b (wherein "a" and "b" stand for atomic percentages respectively in the ranges of 62 at %.ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.38 at %, providing a+b=100 at %) or Al.sub.c Ta.sub.d (wherein "c" and "d" stand for atomic percentages respectively in the ranges of 60 at %.ltoreq.c.ltoreq.80 at % and 20 at %.ltoreq.d.ltoreq.40 at %, providing c+d=100 at %) and by a sputtering process or ion plating process while varying continuously or stepwise the feed rate of a nitrogen-containing reaction gas into a chamber. The film consequently formed has a composition and structure thereof continuously or stepwise varied from a substantially amorphous metal of a part being in contact with the substrate to an (Al, Ti)N or (Al, Ta)N crystalline ceramic phase with the nitrogen content continuously or stepwise increased in the direction of the surface of the film.

Abstract: A cast magnetic refrigerant having a composition represented byLn.sub.a A.sub.b M.sub.cwherein Ln is at least one element selected from the group consisting of Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and Yb; A is any one of elements of Al and Ga; M is at least one element selected from the group consisting of Fe, Co, Ni, Cu and Ag; each of a, b and c is atomic %, with the proviso that a+b+c=100 atomic %, 20 atomic % .ltoreq.a.ltoreq.80 atomic %, 5 atomic % .ltoreq.b .ltoreq.50 atomic %, 5 atomic % .ltoreq.c.ltoreq.60 atomic %, and having an amorphous structure with a difference .DELTA.T of 10K or more between a glass transition temperature Tg and a crystallization temperature Tx.

Abstract: In amorphous materials including at least one iron-transition metal of Fe, Co, and Ni, and at least one metalloid of B, C, Si, and P, excellent magnetic characteristics can be provided subject to the condition that 0.5 to 10 atomic % of the above-described iron-transition metals are substituted by Mn. In addition, when the amorphous material partially substituted with Mn as described above is further comprised of at least one element selected from Groups IIIa, IVa, Va, and VIa in the periodic table, the crystallization temperature is considerably raised.

Abstract: A process for producing amorphous alloy materials having high toughness and high strength from various alloy powders, thin ribbons or bulk materials consisting of an amorphous phase by heating them to a temperature at which intermetallic compounds or other compounds are not produced. During this heating, fine crystal grains consisting of a supersaturated solid solution made of a main alloying element and additive elements and having a mean grain diameter of 5 nm to 500 nm are precipitated and uniformly dispersed in a volume percentage of 5 to 50% throughout an amorphous matrix. In the process, when deformation, pressing or other working is simultaneously conducted with the heating, consolidation or combining of the resultant alloy materials can also be effected in the same production procedure. The amorphous alloy used in the production process preferably comprises Al, Mg or Ti as a main element and, as additive elements, rare earth elements and/or other elements.

Abstract: An amorphous magnesium alloy has a composition of Mg.sub.a M.sub.b X.sub.c (M is Zn and/or Ga, X is La, Ce, Mm (misch metal), Y, Nd, Pr, Sm and Gd), a is from 65 to 96.5 atomic %, b is from 3 to 30 atomic %, and c is from 0.2 to 8 atomic %). The magnesium alloy has a high specific strength and does not embrittle at room temperature.

Abstract: A process for making a large number of magneto-mechanically resonant markers having distinct resonant characteristics is disclosed. The process comprises modifying at least one surface of a glassy metal alloy strip so as to cause the effective length of the alloy strip to be different from the physical length thereof. Resonant markers comprising alloy strips treated by the process of the present invention display unique and distinguishable resonant characteristics which gives the marker a unique identity. The resonant markers can be used for article surveillance, inventory control and personnel identification.