Amorphous, I.e., Glassy Patents (Class 148/403)
  • Patent number: 4786468
    Abstract: New alloys highly resistant to corrosion by concentrated acid and having excellent adhering properties when coated on stainless steel are formed of 60 to 90 atomic percent tantalum or tungsten, with the remainder being iron, chromium and nickel in the proportions found in stainless steel, e.g., 304L stainless steel. They may be formed in situ on the surface to be coated by sputter deposition, using a sputter target which is part tungsten or tantalum, and part stainless steel.
    Type: Grant
    Filed: June 4, 1987
    Date of Patent: November 22, 1988
    Assignee: Battelle Memorial Institute
    Inventors: Rong Wang, Martin D. Merz
  • Patent number: 4782994
    Abstract: An apparatus for the in-line annealing of amorphous strip includes feed rolls for substantially continuously feeding the strip during annealing. The strip is first fed into a nip of cooperating heated pressure rolls. The heated pressure rolls rapidly heat the strip to an annealing temperature at a rate of substantially 10.sup.2 -10.sup.4 .degree.C./second while also subjecting the strip to localized plastic deformation. Where multiple ribbons are being fed simultaneously through the heating pressure rolls, bonding occurs to produce a composite strip. The strip is fed from the pressure rolls through an in-line annealer immediately downstream from the pressure rolls. During annealing, the strip is continuously fed and maintained under tension by operation of a winding roll. The strip is annealed at a temperature of between 420.degree.-510.degree. C. for 0.01-10.0 minutes.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: November 8, 1988
    Assignee: Electric Power Research Institute, Inc.
    Inventors: Derek Raybould, Dulari L. Sawhney, Anthony J. Esposito
  • Patent number: 4781771
    Abstract: An amorphous Co-based metal filament having a circular cross-section made of an alloy composed mainly of Co-Si-B or Co-Me-Si-B (wherein Me is at least one metal selected from the group consisting of Fe, Ni, Cr, Ta, Nb, V, Mo, Mn, W and Zr). This filament is produced by jetting the above alloy into a rotating member containing therein a cooling liquid through a spinning nozzle having a hole diameter which is determined according to the amorphous metal-forming ability (critical thickness to form an amorphous phase) to thereby cool-solidify the jetted molten alloy and form a filament, and then winding the filament continuously on the inner walls of the rotating member by the rotary centrifugal force thereof. This amorphous metal filament is corrosion resistant, is tough and has high electromagnetic characteristics, and is very useful as industrial materials, such as electric and electronic parts, composite materials and fibrous materials.
    Type: Grant
    Filed: December 30, 1986
    Date of Patent: November 1, 1988
    Assignees: Unitika Ltd., Tsuyoshi Masumoto
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Michiaki Hagiwara, Kiyomi Yasuhara
  • Patent number: 4781803
    Abstract: Improved electrolytic processes employing oxygen anodes. The improvement comprises the step of conducting a electrolysis process in an electrolytic cell having a platinum based amorphous metal alloy oxygen anode having the formulaPt.sub.p A.sub.a D.sub.dwhereA is Cr, Mo, W, Fe, Os, Ir, Cu, Ni, Rh, Pd, Ag, Ti, Ru, Nb, V, Ta, Au and mixtures thereof;D is B, C, Si, Al, Ge, P, As, Sb, Sn and mixtures thereof;p ranges from about 40 to 92;a ranges from about 0 to 40; andd ranges from about 8 to 60, with the proviso that p+a+d=100.
    Type: Grant
    Filed: June 16, 1986
    Date of Patent: November 1, 1988
    Assignee: The Standard Oil Company
    Inventors: Jonathan H. Harris, Michael A. Tenhover, Robert K. Grasselli, Michael D. Ward
  • Patent number: 4770949
    Abstract: Electrode materials and method for their surface activation are described. Alloys consisting of at least one element of the group consisting of Nb, Ta, Ti and Zr, at least one element of the group consisting of Ru, Rh, Pd, Ir and Pt, and balance being Ni are prepared by methods for preparation of amorphous alloys, and are amorphous or supersaturated solid solution. Their surfaces are activated to enhance electrocatalytic activity by enrichment of electrocatalytically active platinum group elements in the surface region in addition to surface roughening as a result of selective dissolution of Ni, Nb, Ta, Ti and Zr from the alloys during immersion in corrosive solutions. The surface-activated amorphous and supersaturated solid solution alloys possess high electrocatalytic activity and selectivity for a specific reaction as well as high corrosion resistance.
    Type: Grant
    Filed: August 4, 1986
    Date of Patent: September 13, 1988
    Assignees: Daiki Engineering Co., Ltd., Koji Hashimoto
    Inventors: Koji Hashimoto, Naokazu Kumagai, Katsuhiko Asami, Asahi Kawashima
  • Patent number: 4769094
    Abstract: Amorphous Nickel-base alloys for electrical resistors, which contain, by atomic %, 81-x% Ni, x% Cr, 6% B and 13% Si (z=0.about.25), or 70% Ni, 11% Cr, 19-y% B and y% Si (y=0.about.19 except 13), or 100-z% of 0.864 Ni and 0.136 Cr and z% of 0.316 B and 0.684 Si (x=15.about.25 except 19), and have a relatively high electrical resistivity and a small temperature coefficient of resistivity, are disclosed. Their resistance values can be adjusted by heat treatment and the thermal stability of them after heat treatment is very good in the conventional operating temperature range of electrical components.
    Type: Grant
    Filed: November 25, 1985
    Date of Patent: September 6, 1988
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Tae S. Park, Dong H. Ahn
  • Patent number: 4767678
    Abstract: The invention is an oxalloy consisting essentially of about 5 to about 57 weight percent magnesium or aluminum and about 0.5 to about 10 weight percent of one or more alloying materials selected from the group consisting of B, Al, Si, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ge, As, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, Ga, In, Sn, Sb, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Th, and rare earths; and the remainder oxygen.The invention also includes a method for forming the above oxalloys and a substrate coated with the oxalloys of the present invention.
    Type: Grant
    Filed: February 18, 1986
    Date of Patent: August 30, 1988
    Assignee: The Dow Chemical Company
    Inventors: Ronald L. Yates, Patrick L. Hagans
  • Patent number: 4763030
    Abstract: A metallic glass ribbon of the formulaFe.sub.w B.sub.x Si.sub.y C.sub.zwherein0.78.ltoreq.w.ltoreq.0.83,0.13.ltoreq.x.ltoreq.0.17,0.03.ltoreq.y.ltoreq.0.07,0.005.ltoreq.z.ltoreq.0.03,andw+x+y+z=1,is annealed to remove mechanical strains and exposed to a magnetic field in the plane of the ribbon and transverse to the long axis of the ribbon. The resulting metalic glass ribbons have very large magnetic coupling coefficients (k.sub.33 >0.9). The treated ribbons are useful in magnetostrictive transducers and in passive listening devices such as hydrophones or pressure sensors.
    Type: Grant
    Filed: May 24, 1984
    Date of Patent: August 9, 1988
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Arthur E. Clark, Lawrence T. Kabacoff, Howard T. Savage, Christine Modzelewski
  • Patent number: 4756747
    Abstract: Amorphous metallic precipitates having the formula (M.sub.1).sub.a (M.sub.2).sub.b wherein M.sub.1 is at least one transition metal, M.sub.2 is at least one main group metal and the integers "a" and "b" provide stoichiometric balance; the precipitates having a degree of local order characteristic of chemical compounds from the precipitation process and useful electrical and mechanical properties.
    Type: Grant
    Filed: July 24, 1986
    Date of Patent: July 12, 1988
    Assignee: The United States of America as represented by the Department of Energy
    Inventor: Robert C. Haushalter
  • Patent number: 4755239
    Abstract: Cobalt rich amorphous metal alloys have a value of magnetostriction of about -6.times.10.sup.-6 to +4.times.10.sup.-6 and a saturation induction of about 0.1 to 1.0T. The alloys, especially suited for soft magnetic applications, have the formula (Co.sub.1-x T.sub.x).sub.100-b (B.sub.1-y Y.sub.y).sub.b, where T is at least one of Cr and V, Y is at least one of carbon and silicon, B is boron, x ranges from about 0.05 to 0.25, y ranges from about 0 to 0.75 and b ranges from about 14 to 28.
    Type: Grant
    Filed: July 2, 1986
    Date of Patent: July 5, 1988
    Assignee: Allied-Signal Inc.
    Inventor: Robert C. O'Handley
  • Patent number: 4755237
    Abstract: Improvements are provided in the structures of cutting tools and methods for producing such tools. The tool structures include providing a select portion or portions of a cutting tool, such as one or more portions adjacent a cutting or forming portion or edge or plurality of edges of a tool, of amorphous or non-crystalline metal or metal alloy having strength and wear characteristics which are superior to those of conventional metals and alloys which are crystalline in structure. Such amorphous metal may be formed in situ along the cutting edge portion of a cutting tool or blade by intense radiation beam scanning or may be formed of deposited or otherwise secured amorphous metal strip.
    Type: Grant
    Filed: September 15, 1986
    Date of Patent: July 5, 1988
    Inventor: Jerome H. Lemelson
  • Patent number: 4750951
    Abstract: An amorphous alloy for making a magnetic head comprises a composition of the formula:(Fe.sub.1-a, Co.sub.a).sub.100-e-f-b Cr.sub.e Ru.sub.f (Si.sub.c, B.sub.d).sub.bwhere a is from 0.93 to 0.95, c/c+d is from 0.55 to 0.65, b is from 22 to 27, e is from 0.4 to 2.6 and f is from 1.5 to 4.0.
    Type: Grant
    Filed: February 11, 1987
    Date of Patent: June 14, 1988
    Assignee: Alps Electric Co., Ltd.
    Inventors: Akihiro Makino, Mikio Nakashima
  • Patent number: 4749625
    Abstract: An amorphous metal laminate sheet having an excellent electromagnetic wave-shielding effect including a core layer containing at least one amorphous metal sheet layer which may be plated with an electroconductive metal, at least one flexible polymeric coating layer laminated on at least one surface of the amorphous metal-coating core layer, and optionally, at least one reinforcing fibrous fabric layer.
    Type: Grant
    Filed: March 16, 1987
    Date of Patent: June 7, 1988
    Assignee: Hiraoka & Co., Ltd.
    Inventors: Tsutomu Obayashi, Saburo Baba, Manabu Imoto, Shinobu Watanabe
  • Patent number: 4747888
    Abstract: An improved alloy used in the form of an amorphous soft magnetic thin film having a desirable combination of saturation magnetic flux density and saturation magnetostriction constant, the alloy having the compositional formula:Co.sub.x Zr.sub.y Pd.sub.zwherein:0.85.ltoreq.x.ltoreq.0.940.04.ltoreq.y.ltoreq.0.070.01.ltoreq.z.ltoreq.0.10.
    Type: Grant
    Filed: February 14, 1986
    Date of Patent: May 31, 1988
    Assignee: Sony Corporation
    Inventors: Hiroshi Takino, Kiyonori Hayakawa, Kazuko Kawabata, Makoto Tsuruoka
  • Patent number: 4746379
    Abstract: Nickel based alloy compositions are disclosed comprising between about 25 and about 35 atom percent palladium, about 10 to about 13 atom percent of at least one of boron and silicon, from about 5 to about 20 atom percent cobalt, up to about 5 atom percent molybdenum, the alloys exhibiting a liquidus temperature of less than about 950.degree. C. The alloys are particularly suited for brazing stainless steel and cemented carbide joints. Also disclosed are brazing processes utilizing the alloys.
    Type: Grant
    Filed: August 25, 1987
    Date of Patent: May 24, 1988
    Assignee: Allied-Signal Inc.
    Inventor: Anatol Rabinkin
  • Patent number: 4746584
    Abstract: Novel amorphous metal alloy electrodes have the formulaePt.sub.p A.sub.a D.sub.dwhereA is Ir, Pd, Rh, Ru and mixtures thereof;D is B, Al, As, P, Sb, Ge, Sn, Si and mixtures thereof;p is from about 40 to 92 percent;a is from about 1 to 40 percent;d is from about 8 to 40 percent; and p+a+d=100; andNi.sub.n E.sub.e F.sub.f G.sub.gwhereE is Mo, W and mixtures thereof;F is Pt, Pd, Rh, Ir, Cr and mixtures thereof;G is Al, Ga and mixtures thereof;n is from about 30 to 90 percent;e is from about 10 to 50 percent;f is from about 0 to 25 percent;g is from about 10 to 40 percent; and n+e+f+g=100.These electrodes are useful for hydrogen formation and oxidation and operate at lower potentials than existing electrodes.
    Type: Grant
    Filed: June 24, 1985
    Date of Patent: May 24, 1988
    Assignee: The Standard Oil Company
    Inventors: Michael A. Tenhover, Robert K. Grasselli
  • Patent number: 4745037
    Abstract: Brazing of metal parts employing a thin, homogeneous, ductile, filler metal foil is disclosed. The brazing foil, useful for brazing stainless steels, is less than about 0.064 mm (0.0025 inch) thick and has a composition consisting essentially of 0 to about 6 atom percent iron, 0 to about 21 atom percent chromium, 0 to about 4 atom percent molybdenum, 0 to about 5 atom percent tungsten, 0 to about 20 atom percent cobalt, 0 to about 19 atom percent boron, 0 to about 12 atom percent silicon, 0 to about 22 atom percent phosphorus, 0 to about 3 atom percent carbon and the balance nickel and incidental impurities. In addition to containing the foregoing elements within the above-noted composition ranges, the composition must be such that the total of iron, chromium, molybdenum, tungsten, cobalt and nickel ranges from about 70 to 84 atom percent and the total of boron, silicon, phosphorus and carbon ranges from about 16 to 30 atom percent.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: May 17, 1988
    Assignee: Allied Corporation
    Inventors: Nicholas DeCristofaro, Peter Sexton
  • Patent number: 4744838
    Abstract: A plurality of separate blanks or punchings can be continually processed by first cutting the strips into the dimensions needed for core punchings prior to thermal and magnetic annealing. Thereafter the cut punchings can be fed into the annealing line a conveyor in the sequence of one after another in series, alternatively side-by-side in parallel. The punchings will be flattened with rollers or a press during the stage of heating from room temperature to approximately 300.degree. C. The molten metals adhering to the laser-cut edges or burrs from the mechanical shear can be mechanically removed at this point by brushing. The strips may then be thermally and magnetically annealed in the soaking area. In one embodiment, the temperature may be 400.degree. C. .+-.20.degree. C. for 2605-S2 Metglas material and 360.degree. C. .+-.10.degree. C. for 2605S-C Metglas material with a field of 10 Oe in a non-oxidizing environment.
    Type: Grant
    Filed: July 10, 1986
    Date of Patent: May 17, 1988
    Assignee: Electric Power Research Institute, Inc.
    Inventors: Kou C. Lin, Charles E. Burkhardt, Paul W. Martincic
  • Patent number: 4743314
    Abstract: A highly corrosion-resistant amorphous Ni-Cu-Ti-Ta, Ni-Cu-Ti-Nb and Ni-Cu-Ti-Ta-Nb alloys in which the sum of Ti and Ta and/or Nb is 30-62.5 atomic %.
    Type: Grant
    Filed: September 21, 1987
    Date of Patent: May 10, 1988
    Assignees: Mitsui Engineering & Shipbuilding Co., Ltd., Koji Hashimoto
    Inventors: Koji Hashimoto, Kimikado Miura, Katsuhiko Asami, Asahi Kawashima
  • Patent number: 4743513
    Abstract: Wear-resistant materials and articles, wherein an amorphous material having a hardness of greater than about 1600 VHN is utilized to protect wear-susceptible portions of substrates or is itself made into a wear-resistant article. Amorphous materials having hardnesses greater than about 1600 VHN are found to have surprisingly great wear resistance and can be used to prepare wear-resistant articles. Particularly satisfactory results have been obtained with metal-metalloid systems such as W--Ru--B, Re--Mo--B, Mo--Ru--B, and Co--Nb--B materials.
    Type: Grant
    Filed: June 10, 1983
    Date of Patent: May 10, 1988
    Assignee: Dresser Industries, Inc.
    Inventor: David M. Scruggs
  • Patent number: 4743313
    Abstract: An amorphous alloy for use in magnetic heads having the following composition formula:(Fe.sub.1-a, Co.sub.a).sub.100-b (Si.sub.c,B.sub.d).sub.bwherea=0.93-0.95b=23-27 atomic %c/c+d)=0.55-0.65.Cr and Ru may be desirably added to the amorphous alloy for improving the corrosion and abrasion resistance. Further, secondary phase particles may be dispersed in the alloy matrix for improving the effective magnetic permeability, particularly, at high frequency region.
    Type: Grant
    Filed: November 12, 1985
    Date of Patent: May 10, 1988
    Assignee: Alps Electric Co., Ltd.
    Inventors: Akihiro Makino, Mikio Nakashima, Tadashi Sasaki, Koichi Mukasa
  • Patent number: 4735789
    Abstract: Catalytically-active metallic glasses containing at least one element from a subgroup of the periodic system and at least one element from a main group of the periodic system. Process for the production of catalytically-active metallic glasses where the metallic glass is produced from at least one element from a subgroup of the periodic system and at least from one element from a main group of the periodic system. The metallic glasses are activated by self-activation or by an oxidative and/or reductive treatment. The catalytically-active metallic glasses can be used as hydrogenation oxidation or isomerization catalysts.
    Type: Grant
    Filed: July 25, 1985
    Date of Patent: April 5, 1988
    Assignee: Lonza Ltd.
    Inventors: Volker Franzen, Hans-Joachim Guntherodt, Alphons Baiker, Erich Armbruster, Halim Baris
  • Patent number: 4735864
    Abstract: Amorphous metal filaments having a substantially circular cross-section comprising an alloy containing Fe as a main component, and a process for producing such amorphous metal filaments, are described; the process comprises jetting a molten alloy having amorphism forming ability into a revolving body containing a cooling liquid from a spinning nozzle to form a solidified filament by cooling, and continuously winding the filament on the inner wall of said revolving body by means of the centrifugal force of said revolving body, wherein the circumferential rate of revolution of said revolving body is equal to or higher than the rate of jetting of molten metal from the spinning nozzle. These metal filaments have good corrosion resistance, toughness, and high magnetic permeability and are very useful in various industrial applications, such as electric and electronic parts, materials for reinforcement, and fiber materials.
    Type: Grant
    Filed: April 2, 1987
    Date of Patent: April 5, 1988
    Assignee: Tsuyoshi Masumoto and Unitika, Limited
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Michiaki Hagiwara
  • Patent number: 4731133
    Abstract: The invention is directed to microcrystalline Al-based alloys produced by annealing an alloy formed initially in a substantially amorphous state by rapid solidification (about 10.sup.4 K/sec) and having a composition consisting essentially of, in atomic %:from 5 to 30% Sifrom 11 to 22% Niwherein the Ni may be partially substituted by Fe up to 10%, by V or B up to 5 atomic % each, or totally substituted by Mn up to 22 atomic %, and wherein Fe+Ni+Si.ltoreq.42%. In the microcrystalline state, in the vicinity of the first crystallization peak, there is a metastable hexagonal phase whose crystalline parameters are about a=0.661 nm and c=0.378 nm.
    Type: Grant
    Filed: February 13, 1986
    Date of Patent: March 15, 1988
    Assignee: Cegedur Pechiney
    Inventor: Salim Dermarkar
  • Patent number: 4728580
    Abstract: Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co. Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.
    Type: Grant
    Filed: March 29, 1985
    Date of Patent: March 1, 1988
    Assignee: The Standard Oil Company
    Inventors: Robert K. Grasselli, Michael A. Tenhover, Jonathan H. Harris
  • Patent number: 4725512
    Abstract: A process for protecting an article from wear, wherein a frictionally transformable material is provided at the surface of the article, and then the surface of the article is subjected to frictional wear. The wear transforms the outermost layer of the material to the amorphous state, which is more wear resistant and corrosion resistant than is the material in its nonamorphous state. As the material is worn away gradually, the frictional transformation continues, thereby replenishing the amorphous outermost layer, so that a protective outermost layer remains.
    Type: Grant
    Filed: June 8, 1984
    Date of Patent: February 16, 1988
    Assignee: Dresser Industries, Inc.
    Inventor: David M. Scruggs
  • Patent number: 4715893
    Abstract: The invention provides an aluminum based alloy consisting essentially of the formula Al.sub.bal Fe.sub.a V.sub.b X.sub.c, wherein X is at least one element selected from the group consisting of Zn, Co, Ni, Cr, Mo, Zr, Ti, Hf, Y and Ce, "a" ranges from about 7-15 wt %, "b" ranges from about 2-10 wt %, "c" ranges from about 0-5 wt % and the balance is aluminum. The alloy has a distinctive microstructure which is at least about 50% composed of a generally spherical, intermetallic O-phase.Particles composed of the alloys of the invention can be heated in a vacuum and compacted to form a consolidated metal article have high strength and good ductility at both room temperature and at elevated temperatures of about 350.degree. C. The consolidated article is composed of an aluminum solid solution phase containing a substantially uniform distribution of dispersed intermetallic phase precipitates therein.
    Type: Grant
    Filed: April 4, 1984
    Date of Patent: December 29, 1987
    Assignee: Allied Corporation
    Inventors: David J. Skinner, Richard L. Bye, Jr., Kenji Okazaki, Colin M. Adam
  • Patent number: 4710246
    Abstract: A substantially amorphous or microcrystalline Al-based alloy, wherein said Al-based alloy is represented by the formula:Al.sub.a M.sub.b M'.sub.c X.sub.d Y.sub.ein which:a+b+c+d+e=10050.ltoreq.a.ltoreq.95 atom %0.ltoreq.b.ltoreq.40 atom %0.ltoreq.c.ltoreq.15 atom %0.ltoreq.d.ltoreq.20 atom %0.ltoreq.e.ltoreq.3 atom %wherein at least two of the subscripts b, c or d are strictly positive, and wherein M is at least one metal selected from the group consisting of Mn, Ni, Cu, Zr, Cr, Ti, V, Fe and Co; M' is Mo, W, or a mixture thereof, X is at least one element selected from the group consisting of Ca, Li, Mg, Ge, Si, and Zn; and Y is the inevitable production impurities, with the proviso that when element M is Co, Mn and/or Ni, the total amount of these elements is at least 12 wt % of the alloy.
    Type: Grant
    Filed: September 27, 1984
    Date of Patent: December 1, 1987
    Assignee: Centre National de la Recherche Scientifique "CNRS"
    Inventors: Gerard Le Caer, Jean-Marie Dubois
  • Patent number: 4710235
    Abstract: A process for bonding together two or more pieces of material, at least one of which is an amorphous material, wherein an intermediate interlayer is placed between the two pieces and the assembly is hot pressed at a temperature above the melting point of the interlayer but below the crystallization temperature of the amorphous piece. The composition of the interlayer is chosen so that the elements diffusing into the pieces being bonded are compatible with retention of the amorphous structure. When the bonding operation is carried to completion, no evidence of the interlayer as a separate phase remains. Alternatively, the bonding operation may be halted before completion and the interlayer will remain as a separate, observable phase. For bonding hard metal amorphous materials, alloys of aluminum with silver, gold, silicon and germanium, and alloys of gold with silicon, with the addition of fluxing elements such as phosphorus and boron, have been found to provide particularly satisfactory results.
    Type: Grant
    Filed: March 5, 1984
    Date of Patent: December 1, 1987
    Assignee: Dresser Industries, Inc.
    Inventor: David M. Scruggs
  • Patent number: 4707198
    Abstract: An amorphous alloy consists of iron and tellurium and has a tellurium content of from about 14 to 90 atomic%. The amorphous alloy can be utilized as an information material for optical recording and the like, and as a magnetic material and the like. The corrosion resistance and particularly heat resistance are excellent.
    Type: Grant
    Filed: June 19, 1986
    Date of Patent: November 17, 1987
    Assignee: Teijin Limited
    Inventors: Kiyoshi Chiba, Hiromitsu Ino, Kazuto Tokumitsu
  • Patent number: 4704169
    Abstract: A composite rapidly quenched alloy material comprises a matrix composed of a rapidly quenched alloy, such as an amorphous or crystalline alloy, or a mixture thereof, and particles of at least one second-phase substance dispersed in the matrix uniformly and three-dimensionally.
    Type: Grant
    Filed: September 8, 1983
    Date of Patent: November 3, 1987
    Inventors: Hiroshi Kimura, Tsuyoshi Masumoto
  • Patent number: 4701226
    Abstract: Amorphous chromium-metalloid alloys exhibiting corrosion resistance in acid environments are described. The alloys contain a relatively low amount of a metalloid selected from the group of B, C, P, N, S, Sb and As. Additional metalloid elements such as Al, Si and Ge may also be present to enhance other properties of the amorphous alloy.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: October 20, 1987
    Assignee: The Standard Oil Company
    Inventors: Richard S. Henderson, Gary A. Shreve, Michael A. Tenhover
  • Patent number: 4696703
    Abstract: An amorphous metal alloy composition exhibiting corrosion resistance in acidic environments of the formula:Cr.sub.a M.sub.b B.sub.c C.sub.d R.sub.ewhereinM is at least one metal selected from the group consisting of Mo, W, Nb and Ta;R is at least one element selected from the group consisting of N, P, As, S and Se; andwhereina ranges from about greater than 0.4 to about 0.6;b ranges from about 0.15 to about less than 0.4; andc ranges from zero to about 0.16.d ranges from zero to about 0.2; ande ranges from zero to about 0.3;with the proviso that the sum of (c+d+e) ranges from about 0.04 to about 0.35.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: September 29, 1987
    Assignee: The Standard Oil Company
    Inventors: Richard S. Henderson, Michael A. Tenhover, Robert K. Grasselli
  • Patent number: 4692305
    Abstract: A novel alloy is disclosed which is characterized by high resistance to wear and corrosion. The alloy consists essentially of 2 to 25% chromium, 5 to 30% molybdenum, 3 to 15% tungsten, 2 to 8% copper, 2 to 8% boron, and 0.2 to 2% carbon; the balance being incidental impurities and at least 30% of a metal selected from the group consisting of nickel, cobalt and combinations thereof, with the total of molybdenum and tungsten being at least 16%. The alloy is preferably in the form of a powder for thermal spraying, and coating produced thereby generally have an amorphous structure.
    Type: Grant
    Filed: November 5, 1985
    Date of Patent: September 8, 1987
    Assignee: Perkin-Elmer Corporation
    Inventors: Subramaniam Rangaswamy, John H. Harrington
  • Patent number: 4675239
    Abstract: A perpendicular magnetization amorphous thin film of an alloy of samarium, cobalt and bismuth having an easy magnetizing axis perpendicular to a plane of substrate, and the preparation thereof. According to the thin film, a large saturation magnetization is obtained along an easy magnetizing direction perpendicular to the plane of substrate. The thin film can be prepared by depositing samarium, cobalt and bismuth on the substrate without any applying a bias voltage to the substrate.
    Type: Grant
    Filed: June 10, 1985
    Date of Patent: June 23, 1987
    Assignees: Yoshifumi Sakurai, Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yoshifumi Sakurai, Koji Saiki
  • Patent number: 4670353
    Abstract: A magnetooptical recording medium comprises a ternary amorphous magnetic alloy of Tb-Fe-Co.
    Type: Grant
    Filed: October 1, 1985
    Date of Patent: June 2, 1987
    Assignee: Canon Kabushiki Kaisha
    Inventor: Yoshifumi Sakurai
  • Patent number: 4668310
    Abstract: Amorphous alloys having high strength, high hardness, high crystallization temperature, high saturation magnetic induction, low coercive force, high magnetic permeability and particularly low deterioration of magnetic properties with lapse of time, have a composition formula ofT.sub.a X.sub.b Z.sub.c or T.sub.a' X.sub.b' Z.sub.c' M.sub.d,whereinT is at least one of Fe, Co and Ni,X is at least one of Zr, Ti, Hf and Y,Z is at least one of B, C, Si, Al, Ge, Bi, S and P,a is 70-98 atomic %,b is not more than 30 atomic %,c is not more than 15 atomic %,sum of a, b and c is 100 atomic %,M is at least one Mo, Cr, W, V, Nb, Ta, Cu, Mn, Zn, Sb, Sn, Be, Mg, Pd, Pt, Ru, Os, Rh, Ir, Ce, La, Pr, Nd, Sm, Eu, Gd, Tb and Dy,a' is 70-98 atomic %,b' is not more than 30 atomic %,c' is not more than 15 atomic %,d is not more than 20 atomic %, andsum of a', b', c' and d is 100 atomic %.
    Type: Grant
    Filed: March 14, 1983
    Date of Patent: May 26, 1987
    Assignees: Hitachi Metals, Ltd., Hitachi, Ltd.
    Inventors: Mitsuhiro Kudo, Shinji Takayama, Yoshizo Sawada, Yasunobu Ogata
  • Patent number: 4657604
    Abstract: A fine amorphous metallic wire having a circular cross section and stability to a bias magnetic field, said wire being composed of an alloy having the following composition formula(Co.sub.1-a-b Fe.sub.a M.sub.b).sub.100-x-y Si.sub.x B.sub.ywherein M is at least one element selected from Cr, Mo, Ni, Nb, Ta, Pd, Pt, and Cu, x<20 atomic %, 7 atomic %.ltoreq.y<35 atomic %, 7 atomic %<x+y.ltoreq.35 atomic %, 0.01.ltoreq.a.ltoreq.0.1, and 0.001.ltoreq.b.ltoreq.0.05. The fine amorphous metallic wire has low magnetostriction, high magnetic permeability, high saturation magnetic flux density, and excellent toughness, and is stable against a bias magnetic field. Hence, it can be used as a material for electromagnetic devices such as a coordinate reading device, a current sensor, an eddy current sensor, a magnetic sensor, or a displacement sensor.
    Type: Grant
    Filed: July 28, 1986
    Date of Patent: April 14, 1987
    Assignee: Unitika Ltd.
    Inventors: Isamu Ogasawara, Kiyotsugu Maekawa, Hiroyuki Tomioka, Shinji Furukawa
  • Patent number: 4657605
    Abstract: A fine amorphous metallic wire having a circular cross section and stability to a bias magnetic field, said wire being composed of an alloy having the following composition formula(Co.sub.1-a Fe.sub.a).sub.100-x-y-z Si.sub.x B.sub.y Mn.sub.zwherein x<20 atomic %, 7 atomic %.ltoreq.y<35 atomic %, 7 atomic %<x+y.ltoreq.35 atomic %, 0.1 atomic %.ltoreq.z.ltoreq.3 atomic %, and 0.01.ltoreq.a.ltoreq.0.1. The fine amorphous metallic wire has low magnetostriction, high magnetic permeability, high saturation magnetic flux density, and excellent toughness, and is stable against a bias magnetic field. Hence, it can be used as a material for electromagnetic devices such as a coordinate reading device, a current sensor, an eddy current sensor, a magnetic sensor, or a displacement sensor.
    Type: Grant
    Filed: July 28, 1986
    Date of Patent: April 14, 1987
    Assignee: Unitika Ltd.
    Inventors: Isamu Ogasawara, Kiyotsugu Maekawa, Hiroyuki Tomioka, Shinji Furukawa
  • Patent number: 4644310
    Abstract: An actuator system comprises a magnetomechanical cantilever beam adapted to be responsive to magnetic fields of various magnitudes. The system provides precise and rapid repositioning of the free end of the beam corresponding to the magnitude of the applied magnetic field. The beam is comprised of magnetostrictive ferromagnetic amorphous material and provides efficient, high force, high speed actuation to devices requiring electronically controlled variable displacement motion.
    Type: Grant
    Filed: March 22, 1984
    Date of Patent: February 17, 1987
    Assignee: Allied Corporation
    Inventors: Philip M. Anderson, III, Jeffrey C. Urbanski
  • Patent number: 4640816
    Abstract: Bulk metastable, amorphous or fine crystalline alloy materials are produced by reacting cold-worked, mechanically deformed filamentary precursors such as metal powder mixtures or intercalated metal foils. Cold-working consolidates the metals, increases the interfacial area, lowers the free energy for reaction, and reduces at least one characteristic dimension of the metals. For example, the grains (13) of powder or the sheets of foil are clad in a container (14) to form a disc (10). The disc (10) is cold-rolled between the nip (16) of rollers (18,20) to form a flattened disc (22). The grains (13) are further elongated by further rolling to form a very thin sheet (26) of a lamellar filamentary structure (FIG. 4) containing filaments having a thickness of less than 0.01 microns.
    Type: Grant
    Filed: August 31, 1984
    Date of Patent: February 3, 1987
    Assignee: California Institute of Technology
    Inventors: Michael Atzmon, William L. Johnson, John D. Verhoeven
  • Patent number: 4639363
    Abstract: Amorphous phases are prepared by heat treatment of intermetallic compounds of Zr-Al alloys in hydrogen-containing gas.
    Type: Grant
    Filed: March 12, 1985
    Date of Patent: January 27, 1987
    Assignee: Osaka University
    Inventors: Masao Komatsu, Hiroshi Fujita
  • Patent number: 4637843
    Abstract: The present invention relates to the core of a noise filter.Conventionally, ferrite or iron powder is used as the core of a noise filter. Some patent publications disclose the core of a noise filter made of an amorphous magnetic alloy.An amorphous magnetic alloy which as a low pulse-noise resistance deterioration percentage is that on or within the curve X and Y of FIG. 3.
    Type: Grant
    Filed: May 3, 1985
    Date of Patent: January 20, 1987
    Assignee: TDK Corporation
    Inventors: Suguru Takayama, Masao Shigeta
  • Patent number: 4637927
    Abstract: Amorphization of intermetallic compounds of Zr-Al alloys is accelerated by arranging previously and artificially the lattice defects at given positions in the crystals.
    Type: Grant
    Filed: March 12, 1985
    Date of Patent: January 20, 1987
    Assignee: Osaka University
    Inventors: Masao Komatsu, Hiroshi Fujita
  • Patent number: 4634306
    Abstract: A writing point for a writing or recording instrument is completely or partially formed of a metallic glass or amorphous metal or the writing tip may be provided with a coating or surface layer of metallic glass or amorphous metal.
    Type: Grant
    Filed: November 28, 1983
    Date of Patent: January 6, 1987
    Assignee: Firma J.S. Staedtler
    Inventor: Peter Dzuik
  • Patent number: 4626296
    Abstract: Amorphous metallic precipitates having the formula (M.sub.1).sub.a (M.sub.2).sub.b wherein M.sub.1 is at least one transition metal, M.sub.2 is at least one main group metal and the integers "a" and "b" provide stoichiometric balance; the precipitates having a degree of local order characteristic of chemical compounds from the precipitation process and useful electrical and mechanical properties.
    Type: Grant
    Filed: February 11, 1985
    Date of Patent: December 2, 1986
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Robert C. Haushalter
  • Patent number: 4623408
    Abstract: Nitrogen-containing amorphous alloys having a combination of superior properties which are highly valuable and desirable for ferromagnetic materials or superconducting materials are produced by sputtering metallic materials and nitrogen compounds containing semi-metal or semiconducting metal, such as boron or silicon, without requiring the use of nitrogen gas. The produced alloy has a novel structure, represented by the formula:MxLyNz(wherein M is at least one metal or alloy; L is at least one semimetal or semiconducting element; and x, y and z are fractional atomic percentages totaling 100 (i.e., x+y+z=100) and the value of y+z being 10 or more and the respective values of x, y, z being not zero).
    Type: Grant
    Filed: January 16, 1985
    Date of Patent: November 18, 1986
    Assignees: Hideaki Karamon, Research Development Corporation of Japan
    Inventors: Hideaki Karamon, Keiichi Ogawa
  • Patent number: 4623387
    Abstract: Amorphous alloys containing zirconium as an amorphous forming metal and having teh formula X.sub..alpha. Z.sub..gamma. wherein X is at least one of Fe, Co and Ni, .alpha. is 80 to 92 atomic %, Z is zirconium, .gamma. is 8 to 20 atomic % and the sum of .alpha. and .gamma. is 100 atomic %, cause little variation of properties during aging and embrittlement because they contain no metalloid as the amorphous forming element, and they further have excellent strength, hardness, corrosion resistance and heat resistance and maintain superior magnetic properties which are characteristic of iron group elements.
    Type: Grant
    Filed: February 5, 1985
    Date of Patent: November 18, 1986
    Assignee: Shin-Gijutsu Kaihatsu Jigyodan
    Inventors: Tsuyoshi Masumoto, Kiyoyuki Esashi, Masateru Nose
  • Patent number: 4621031
    Abstract: A composite material bonded by an amorphous metal. In one embodiment, a bonded piece is bonded to a substrate by a layer of amorphous metal interposed between the piece and the substrate. In another embodiment, a bonded composite material is formed with pieces of a second phase distributed throughout the volume of an amorphous matrix. In both embodiments, the second component of the composite is preferably a very hard material of low ductility, so that the composite material is useful in tooling applications. The solid composite material is formed by solid state processing, wherein the pieces are placed in contact and then consolidated at a temperature which does not exceed the crystallization temperature of the amorphous metal.
    Type: Grant
    Filed: November 16, 1984
    Date of Patent: November 4, 1986
    Assignee: Dresser Industries, Inc.
    Inventor: David M. Scruggs
  • Patent number: 4619720
    Abstract: A magnetic amorphous alloy having a compositional formula(Co.sub.100-y Fe.sub.y).sub.100-x Zr.sub.100-w Nb.sub.w).sub.xin which 5.ltoreq.x.ltoreq.10, 0.5.ltoreq.y.ltoreq.4, and 20.ltoreq.w.ltoreq.90.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: October 28, 1986
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Ikuo Sakai, Hiroyasu Karimoto, Yasuhiko Nakayama