Amorphous, I.e., Glassy Patents (Class 148/403)
  • Patent number: 5334266
    Abstract: High strength, heat resistant aluminum-based alloys have a composition consisting of the following general formula Al.sub.a M.sub.b X.sub.d or Al.sub.a' M.sub.b Q.sub.c X.sub.d, wherein M is at least one metal element selected from the group consisting of Co, Ni, Cu, Zn and Ag; Q is at least one metal element selected from the group consisting of V, Cr, Mn and Fe; X is at least one metal element selected from the group consisting of Li, Mg, Si, Ca, Ti and Zr; and a, a', b, c and d are, in atomic percentages; 80.ltoreq.a.ltoreq.94.5, 80.ltoreq.a'.ltoreq.94, 5.ltoreq.b.ltoreq.15, 0.5.ltoreq.c.ltoreq.3 and 0.5.ltoreq.d.ltoreq.10. In the above specified alloys, aluminum intermetallic compounds are finely dispersed throughout an aluminum matrix and, thereby, the mechanical properties, especially strength and heat resistance, are considerably improved.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: August 2, 1994
    Assignee: Yoshida Kogyo K.K.
    Inventors: Makoto Kawanishi, Hidenobu Nagahama
  • Patent number: 5332415
    Abstract: The present invention provides a compacted and consolidated aluminum-based alloy material which has been obtained by compacting and consolidating a rapidly solidified material having a composition represented by the general formula: Al.sub.a Ni.sub.b X.sub.c wherein X is one or two elements selected from Zr and Ti and a, b and c are, in atomic percentages, 87.5.ltoreq.a.ltoreq.92.5, 5 .ltoreq.b.ltoreq.10, and 0.5.ltoreq.c.ltoreq.5; and a production process comprising melting a material of the above composition; quenching and solidifying the resultant molten material into powder or flakes; compacting, compressing, forming and consolidating the powder or flakes by conventional plastic working. The consolidated material of the present invention has. elongation (toughness) sufficient to withstand secondary working, even when secondary working is applied. Moreover, the material allows the secondary working to be performed easily while retaining the excellent properties of its raw material.
    Type: Grant
    Filed: August 14, 1992
    Date of Patent: July 26, 1994
    Assignee: Yoshida Kogyo K.K.
    Inventor: Kazuhiko Kita
  • Patent number: 5324368
    Abstract: Disclosed herein is a process for forming an amorphous alloy material capable of showing glass transition, which comprises holding the material between frames arranged in combination; and heating the material at a temperature between its glass transition temperature (Tg) and its crystallization temperature (Tx) and, at the same time, producing a pressure difference between opposite sides of the material, whereby the material is brought into close contact against a forming mold disposed on one side of the material. As an alternative, the forming mold is brought into close contact against the amorphous material in a direction opposite to the pressing direction for the amorphous material. By the above processes, precision-formed products of amorphous alloys can be manufactured and supplied at low cost.
    Type: Grant
    Filed: May 19, 1992
    Date of Patent: June 28, 1994
    Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Yoshida Kogyo K.K.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Nobuyuki Nishiyama, Hiroyuki Horimura, Toshisuke Shibata
  • Patent number: 5320688
    Abstract: The present invention provides high strength, heat resistant aluminum-based alloys having a composition represented by the general formula:Al.sub.a M.sub.b X.sub.cwherein:M is at least one metal element selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si;X is at least one metal element selected from the group consisting of Y, La, Ce, Sm, Nd, Hf, Nb, Ta and Mm (misch metal); anda, b and c are atomic percentages falling within the following ranges:50.ltoreq.a.ltoreq.95, 0.5.ltoreq.b.ltoreq.35 and 0.5.ltoreq.c.ltoreq.25,the aluminum-based alloy being in an amorphous state, microcrystalline state or a composite state thereof. The aluminum-based alloys possess an advantageous combination of properties of high strength, heat resistance, superior ductility and good processability which make then suitable for various applications.
    Type: Grant
    Filed: February 19, 1993
    Date of Patent: June 14, 1994
    Assignees: Yoshida Kogyo K. K., Tsuyoshi Masumoto
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Katsumasa Odera, Masahiro Oguchi
  • Patent number: 5318641
    Abstract: Al.sub.100-a-b-c X.sub.a M.sub.b T.sub.c, in which X is Y (yttrium) and/or rare-earth element(s), M is Fe, Co, and/or Ni, and T is Mn, Mo, Cr, Zr and/or V, and, a=0.5-5 atomic %, b=5-15 atomic %, and c=0.2-3.0 atomic %, and, further, X and M fall on and within the hatched region range of the appended FIG. 1, has a complex, amorphous-crystalline structure with an amorphous matrix containing the Al, X, M and T, and minority crystalline phase consisting of aluminum-alloy particles containing super-saturated X, M and T as solutes. The alloy has a high strength due to the dispersed crystalline particles.
    Type: Grant
    Filed: June 6, 1991
    Date of Patent: June 7, 1994
    Assignees: Tsuyoshi Masumoto, Teikoku Piston Ring Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha, Yoshida Kogyo K.K.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Kazuhiko Kita, Hitoshi Yamaguchi, Hiroyuki Horimura, Noriaki Matsumoto
  • Patent number: 5312494
    Abstract: A high strength and high toughness aluminum alloy is produced by crystallization of one of two aluminum alloy blanks: one having a metallographic structure with a volume fraction Vf of a mixed-phase texture consisting of an amorphous phase and an aluminum crystalline phase being equal to or more than 50% (Vf.gtoreq.50%), and the other having a metallographic structure with a volume fraction Vf of an amorphous single-phase texture being equal to or more than 50% (Vf.gtoreq.50%). The aluminum alloy is represented by a chemical formula:Al.sub.(a) X.sub.(b) Z.sub.(c) Si.sub.(d)wherein X is at least one element selected from the group consisting of Mn, Fe, Co and Ni; Z is at least one element selected from the group consisting of Zr and Ti; and each of (a), (b), (c) and (d) is defined within the following range:84 atomic %.ltoreq.(a).ltoreq.94 atomic %,4 atomic %.ltoreq.(b).ltoreq.atomic %,0.6 atomic %.ltoreq.(c).ltoreq.4 atomic %, and0.5 atomic %.ltoreq.(d).ltoreq.(b)/3.
    Type: Grant
    Filed: May 4, 1993
    Date of Patent: May 17, 1994
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Hiroyuki Horimura, Noriaki Matsumoto, Kenji Okamoto
  • Patent number: 5312495
    Abstract: The present invention provides a process comprising the steps of forming a cast amorphous alloy from an alloy which exhibits glass transition behavior, heating the amorphous alloy to a temperature between Tg and Tx while subjecting the alloy to drawing to obtain a wire and cooling the wire to (Tg-50 K) or lower. By this process, it is possible to produce an amorphous alloy wire at a low cost and provide an ultrafine wire having high strength and high corrosion resistance as well as flexibility. The amorphous alloy wire can be utilized as a reinforcing wire for a composite material, a variety of reinforcing members, a woven fabric and the like.
    Type: Grant
    Filed: May 5, 1992
    Date of Patent: May 17, 1994
    Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Unitika Ltd., Kogyo K.K. Yoshida
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Hirokazu Yamamoto, Junichi Nagahora, Toshisuke Shibata
  • Patent number: 5306363
    Abstract: An aluminum-based alloy foil or thin aluminum-based alloy wire is produced from an amorphous material made by a quenching and solidifying process and having a composition represented by the general formula:Al.sub.a M.sub.b X.sub.cwherein M is one or more elements selected from a group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si; X is one or more elements selected from a group consisting of Y, Nb, Hf, Ta, La, Ce, Sm, Nd and Mm (misch metal); and a, b, and c are atomic percentages falling within the following range:50.ltoreq.a.ltoreq.950.5.ltoreq.b.ltoreq.35 and0.5.ltoreq.c.ltoreq.25Such foil or wire has a smooth surface and a very small and uniform foil thickness or wire diameter, contains at least 50% by volume of an amorphous phase, and has excellent strength and resistance to corrosion. The foil thickness and wire diameter are reduced in a rolling or drawing process at an elevated temperature over a short time period.
    Type: Grant
    Filed: August 20, 1990
    Date of Patent: April 26, 1994
    Assignees: Tsuyoshi Masumoto, Teikoku Piston Ring Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha, Kogyo K.K. Yoshida
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Hitoshi Yamaguchi, Noriaki Matsumoto, Kazuhiko Kita
  • Patent number: 5304260
    Abstract: The present invention provides high strength magnesium-based alloys which are composed a fine crystalline structure, the alloys having a composition represented by the general formula (I) Mg.sub.a X.sub.b ; (II) Mg.sub.a X.sub.c M.sub.d, (III) Mg.sub.a X.sub.c Ln.sub.e ; or (IV) Mg.sub.a X.sub.c M.sub.d Ln.sub.e (wherein X is one or more elements selected from the group consisting of Cu, Ni, Sn and Zn; M is one or more elements selected from the group consisting of Al, Si and Ca; Ln is one or more elements selected from the group consisting of Y, La, Ce, Nd and Sm or a misch metal of rare earth elements; and a, b, c, d and e are atomic percentages falling within the following ranges: 40.ltoreq.a.ltoreq.95, 5.ltoreq.b.ltoreq.60, 1.ltoreq.c.ltoreq.35, 1 .ltoreq.d.ltoreq.25 and 3.ltoreq.e.ltoreq.25). Since the magnesium-based alloys have a superior combination of properties of high hardness, high strength and good processability, they are very useful in various industrial applications.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: April 19, 1994
    Assignee: Yoshida Kogyo K.K.
    Inventors: Kazuo Aikawa, Katsuyuki Taketani
  • Patent number: 5296059
    Abstract: A process for producing an amorphous alloy material characterized by imparting ductility to an amorphous alloy having a supercooled liquid region by giving a prescribed amount of strain at a prescribed strain rate to the alloy in the glass transition temperature region of the alloy. The amorphous alloy may be in the form of spherical or irregular-shaped powders or thin ribbons or in the form of primary consolidated shapes thereof or an amorphous alloy casting. The amount of strain and strain rate are preferably 50% or greater and 2.times.10.sup.-2 /sec or higher, respectively, and the worked amorphous alloy material is preferably allowed to cool in a furnace or spontaneously. Suitable examples of the amorphous alloy to be employed include Al-TM-Ln, Mg-TM-Ln, Zr-TM-Al and Hf-TM-Al alloys, wherein TM is a transition metal element and Ln is a rare earth metal element. The thus obtained amorphous alloy is greatly improved in the prevention of embrittlement in hot working peculiar to the alloy.
    Type: Grant
    Filed: September 11, 1992
    Date of Patent: March 22, 1994
    Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Yoshida Kogyo K.K.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Junichi Nagahora, Kazuhiko Kita
  • Patent number: 5296056
    Abstract: A family of gamma titanium aluminide alloys is provided which is based on the intermetallic compound TiAl and includes alloying additions which enable the alloys to exhibit both sufficient mechanical properties and environmental capabilities for use in high temperature applications associated with gas turbine and automotive engines. The preferred alloys have a nominal aluminum content of about 46 atomic percent and further include niobium at about three to about five atomic percent and tungsten at about one atomic percent nominally, so as to selectively enhance the oxidation resistance of the alloy. As species of the preferred alloy, alloying additions of vanadium, chromium and manganese can be included at levels of up to about two atomic percent to enhance the toughness and ductility of the preferred alloy at lower temperatures, such as those encountered during fabrication and during low temperature operations.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: March 22, 1994
    Assignee: General Motors Corporation
    Inventors: Sushil K. Jain, James R. Roessler
  • Patent number: 5288344
    Abstract: Alloys which form metallic glass upon cooling below the glass transition temperature at a rate appreciably less than 10.sup.6 K/s comprise beryllium in the range of from 5 to 52 atomic percent and at least one early transition metal in the range of from 30 to 75% and at least one late transition metal in the range of from 2 to 52%. A preferred group of metallic glass alloys has the formula (Zr.sub.1-X Ti.sub.X).sub.a (Cu.sub.1-y Ni.sub.y).sub.b Be.sub.c. Generally, a is in the range from 30 to 75% and the lower limit increases with increasing x. When x is in the range of from 0 to 0.15, b is in the range of from 5 to 52%, and c is in the range of from 6 to 47%. When x is in the range of from 0.15 to 0.4, b is in the range of from 5 to 52%, and c is in the range of from 5 to 47%. When x is in the range of from 0.4 to 0.6, b is in the range of from 5 to 52%, and c is in the range of from 5 to 47%. When x is in the range of from 0.6 to 0.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: February 22, 1994
    Assignee: California Institute of Technology
    Inventors: Atakan Peker, William L. Johnson
  • Patent number: 5279642
    Abstract: Disclosed herein is a process for producing a high strength aluminum-based alloy powder comprising mixing Al or Al alloy powder with an Al--T--X alloy powder, wherein T is at least one selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, W, Ca, Li, Mg and Si; X is at least one selected from the group consisting of Y, Nb, Hf, Ta, La, Ce, Sm, Nd, Zr and Ti or Mm; and mechanically alloying the formed powder mixture. The aluminum-based alloy powder is excellent in workability and reliability by virtue of its high strength stability in the temperature range of from room temperature to an elevated temperature, its excellent ductility in the same temperature range and its low thermal expansion coefficient in the same temperature range.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: January 18, 1994
    Assignee: Yoshida Kogyo K.K.
    Inventor: Katsumasa Ohtera
  • Patent number: 5250124
    Abstract: A bulky amorphous magnesium alloy having heat-resistance and toughness is provided by setting the alloy composition as: Mg.sub.a M.sub.b Al.sub.c X.sub.d Z.sub.e (M is at least one element selected from the group consisting of La, Ce, Mm (misch metal) and Y, X is at least one element selected from the group consisting of Ni and Cu, and Z is at least one element selected from the group consisting of Mn, Zn, Zr, and Ti, and, a=70.about.90 at %, b=2.about.15 at %, c=1.about.9 at %, d=2.about.15 at %, e=0.1.about.8 at %, a+b+c+d+e=100 at %).
    Type: Grant
    Filed: March 16, 1992
    Date of Patent: October 5, 1993
    Assignees: Yoshida Kogyo K.K., Tsuyoshi Masumoto
    Inventors: Hitoshi Yamaguchi, Toshisuke Shibata, Akihisa Inoue, Akira Kato, Tsuyoshi Masumoto
  • Patent number: 5240517
    Abstract: The present invention provides high strength, heat resistant aluminum-based alloys having a composition represented by the general formula: Al.sub.a M.sub.b X.sub.c wherein:M is at least one metal element selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si;X is at least one metal element selected from the group consisting of Y, La, Ce, Sm, Nd, Hf, Nb, Ta and Mm (misch metal); anda, b and c are atomic percentages falling within the following ranges:50.ltoreq.a.ltoreq.95, 0.5.ltoreq.b.ltoreq.35 and 0.5.ltoreq.c.ltoreq.25,the aluminum-based alloy being in an amorphous state, microcrystalline state or a composite state thereof. The aluminum-based alloys possess an advantageous combination of properties of high strength, heat resistance, superior ductility and good processability which make then suitable for various applications.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: August 31, 1993
    Assignee: Yoshida Kogyo K.K.
    Inventors: Tsuyoshi Matsumoto, Akihisa Inoue, Katsumasa Odera, Masahiro Oguchi
  • Patent number: 5230753
    Abstract: Alloys of hydrogenated amorphous silicon and germanium are disclosed that exhibit unexpectedly low saturated defect densities, particularly relative to the initial defect densities of the alloys, so as to render them substantially resistant to Staebler-Wronski degradation. The alloys are producible using conventional equipment, but glow-discharge methods are preferred. The preferred amount of germanium in the alloy is about 15 at. % to about 50 at. %. The alloys are particularly useful for making photovoltaic cells. The alloys can be used as intrinsic semiconductors and doped for use as "n" or "p" materials. Methods for making the alloys are also disclosed.
    Type: Grant
    Filed: December 3, 1991
    Date of Patent: July 27, 1993
    Assignee: Princeton University
    Inventor: Sigurd Wagner
  • Patent number: 5224983
    Abstract: A rapidly solidified zirconium containing aluminum lithium alloy powder consisting essentially of the formula Al.sub.bal Li.sub.a Cu.sub.b Mg.sub.c Zr.sub.d where "a" ranges from 2.1 to 3.4 wt %, "b" ranges from about 0.5 to 2.0 wt %, "c" ranges from 0.2 to 2.0 wt % and "d" ranges from greater than about 0.6 to 1.8 wt %, the balance being aluminum. The powder is degassed in a vacuum at a temperature of at least about 450.degree. C. Components consolidated from the powder exhibit high tensile strength and elongation together with excellent notched impact toughness.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: July 6, 1993
    Assignee: Allied-Signal Inc.
    Inventors: Jerry C. LaSalle, Derek Raybould, Santosh K. Das, Edward V. Limoncelli
  • Patent number: 5221376
    Abstract: Disclosed are high strength magnesium-based alloys consisting essentially of a composition represented by the general formula (I) Mg.sub.a M.sub.b X.sub.d, (II) Mg.sub.a Ln.sub.c X.sub.d or (III) Mg.sub.a M.sub.b Ln.sub.c X.sub.d, wherein M is at least one element selected from the group consisting of Ni, Cu, Al, Zn and Ca; Ln is at least one element selected from the group consisting of Y, La, Ce, Sm and Nd or a misch metal (Mm) which is a combination of rare earth elements; X is at least one element selected from the group consisting of Sr, Ba and Ga; and a, b, c and d are, in atomic percent, 55.ltoreq.a.ltoreq.95, 3.ltoreq.b.ltoreq.25, 1.ltoreq.c.ltoreq.15 and 0.5.ltoreq.d.ltoreq.30, the alloy being at least 50 percent by volume composed of an amorphous phase.
    Type: Grant
    Filed: January 14, 1992
    Date of Patent: June 22, 1993
    Assignees: Tsuyoshi Masumoto, Japan Metals & Chemicals Co., Ltd., Yoshida Kogyo K.K.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Takashi Sakuma, Toshisuke Shibata
  • Patent number: 5221375
    Abstract: Disclosed is a corrosion resistant aluminum-based alloy which is composed of a compound having a composition consisting of the general formula: Al.sub.a M.sub.b Mo.sub.c X.sub.d Cr.sub.e wherein: M is one or more metal elements selected from the group consisting of Ni, Fe, Co, Ti, V, Mn, Cu and Ta; X is Zr or a combination of Zr and Hf; and a, b, c, d and e are, in atomic percentages; 50%.ltoreq.a.ltoreq.89%, 1%.ltoreq.b.ltoreq.25%, 2%.ltoreq.c.ltoreq.15%, 4%.ltoreq.d.ltoreq.20% and 4%.ltoreq.e.ltoreq.20%, the compound being at least 50% by volume composed of an amorphous phase. The Al-based alloy exhibits a very high corrosion resistance in severe corrosive environments, such as hydrochloric acid solution or sodium hydroxide solution, due to the formation of a highly passivative protective film. Therefore, the alloy exhibits a good durability in long services under such severe corrosive environments.
    Type: Grant
    Filed: February 22, 1991
    Date of Patent: June 22, 1993
    Assignee: Yoshida Kogyo K.K.
    Inventors: Junichi Nagahora, Kazuo Aikawa, Katsumasa Ohtera, Hideki Takeda, Keiko Yamagata
  • Patent number: 5200002
    Abstract: An amorphous, low-retentivity alloy contains cobalt, manganese, silicon and boron. The alloy has the composition(Co.sub.a Ni.sub.b T.sub.c Mn.sub.d Fe.sub.e).sub.100-t (Si.sub.x B.sub.y M.sub.z).sub.t,whereby T is at least one of the elements chromium, molybdenum, tungsten, vanadium, niobium, tantalumn, titanium, zirconium and hafnium and M is at least one of the elements phosphorous, carbon, aluminum, gallium, indium, germanium, tin, lead, arsenic, antimony, bismuth and beryllium and the following relationships apply: 0.39.ltoreq.a.ltoreq.0.99; 0.ltoreq.b.ltoreq.0.40; 0.ltoreq.c.ltoreq.0.08; 0.01.ltoreq.d.ltoreq.0.13; 0.ltoreq.e.ltoreq.0.02; 0.01.ltoreq.d+e.ltoreq.0.13; a+b+c+d+e=1; 18.ltoreq.t.ltoreq.35; 8.ltoreq.xt.ltoreq.24; 4.ltoreq.yt.ltoreq.24; 0.ltoreq.zt.ltoreq.8; and x+y+z=1. The inventive alloy is distinguished by a saturation magnetostriction .ltoreq.5.multidot.10.sup.-6 and is particularly suited for magnetic screens, sound heads and magnetic cores.
    Type: Grant
    Filed: June 5, 1980
    Date of Patent: April 6, 1993
    Assignee: Vacuumschmelze GmbH
    Inventor: Hans-Reiner Hilzinger
  • Patent number: 5198042
    Abstract: An aluminum alloy powder for coating materials and a coating material containing the aluminum alloy powder. The aluminum alloy powder comprises an amorphous aluminum alloy consisting essentially of from 83 to 91% of Al, from 0.5 to 5% of Ca and from 8 to 12% of Ni, all in atom %, and comprising a leaf-shaped particle having a thickness of 0.3 to 3 .mu.m, a minor axis of from 10 to 150 .mu.m, a ratio of the minor axis to a major axis of from 1 to 3, and an aspect ratio which is the ratio of the minor axis to the thickness of from 3 to 100, wherein the aluminum alloy powder is contained in an amount of from 5 to 25 parts by weight based on 100 parts by weight of the total weight of (i) the coating material resin component and (ii) aluminum alloy powder, and the coating material resin component is selected from the group consisting of a water-based synthetic latex and a water-soluble resin. The aluminum alloy powder has a superior dispersibility in a resin in a coating material.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: March 30, 1993
    Assignees: Tsuyoshi Masumoto, Yoshida Kogyo K.K., Teikoku Piston Ring Co., Ltd.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Kazuhiko Kita, Yoshio Harakawa, Masahiro Oguchi
  • Patent number: 5156693
    Abstract: An information recording medium is disclosed which records information through the transition of two phases of a recording material, utilizing electromagnetic wave energy. The information recording medium comprises a recording layer made up of a recording material of a composition represented by the formula:wherein6.ltoreq..alpha..ltoreq.138.ltoreq..beta..ltoreq.1718.ltoreq..gamma..ltoreq.2845.ltoreq..delta..ltoreq.66.alpha.+.beta.+.gamma.+.delta.=100.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: October 20, 1992
    Assignee: Ricoh Company, Ltd.
    Inventors: Yukio Ide, Makoto Harigaya, Yoshiyuki Kageyma, Hiroko Iwasaki
  • Patent number: 5149381
    Abstract: A process for the production of a powder having a nanocrystalline structure from powders of at least two materials of the groups including metals, metallic compounds, and ceramic materials, in a composition which tends to develop an amorphous phase. The starting powders are subjected to high stresses of at least 12 G in a neutral or reducing atmosphere at about 20.degree. C. until there are no crystallites larger than about 10 nm.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: September 22, 1992
    Assignee: Fried.Krupp GmbH
    Inventors: Hans Grewe, Wolfgang Schlump
  • Patent number: 5133929
    Abstract: Intermetallic compounds and hydrides thereof, characterized in that they have been prepared by reacting hydrides of the elements of the main groups I, II, III and IV of the Periodic Table, magnesium hydridehalides or magnesium dialkyls having the general formula MgR.sub.2 (R=alkyl) in a solvent with bisallyl metal compounds of the metals of the subgroup VIII of the Periodic Table or of zinc or with the homologues of the bisallyl compounds of said metals, and processes for preparing said compounds.
    Type: Grant
    Filed: July 2, 1990
    Date of Patent: July 28, 1992
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Borislav Bogdanovic, Ursula Wilczok
  • Patent number: 5133814
    Abstract: A novel soft magnetic amorphous alloy thin film which, on account of the composition of the film consisting in a combination of a transition metal, a metalloid or semiconducting element, namely B, C or Si and an oxide derived from the starting material, is endowed with a comminuted and dispersed structure of a magnetic amorphous phase and a nonmagnetic amorphous phase. The soft magnetic amorphous alloy thin film may be applied to a magnetic head for short wavelength recording which is required to cope with high frequency characteristics and high coercivity of the recording medium.
    Type: Grant
    Filed: September 17, 1990
    Date of Patent: July 28, 1992
    Assignee: Sony Corporation
    Inventors: Hideaki Matsuyama, Hideaki Karamon
  • Patent number: 5128099
    Abstract: A state changeable memory alloy and device employing same. The memory alloy is capable of changing from a first state to a second state in response to the input of energy, such as projected optical beam energy, electrical energy or thermal energy. The alloy has a first detectable characteristic when in the first state and a second detectable characteristic when in the second state. It is further characterized in that the first state comprises a single phase, and the second state comprises either: (1) a single phase having the same composition as the first phase or (2) a plurality of phases which have substantially similar crystallization temperatures and kinetics.
    Type: Grant
    Filed: February 15, 1991
    Date of Patent: July 7, 1992
    Assignee: Energy Conversion Devices, Inc.
    Inventors: David A. Strand, Stanford R. Ovshinsky
  • Patent number: 5128214
    Abstract: A metal target and a substrate are disposed in confronting relationship in a vacuum chamber whose interior is kept at high vacuum, and laser light is irradiated to the surface of the target to emit a high-speed evaporated material from the target. The high-speed evaporated material is then deposited on the substrate. By applying a predetermined voltage between the target and the substrate, the impact energy of the charged particles in the evaporated material on the substrate are controlled to form an amorphous metal film preferably a pure iron film.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: July 7, 1992
    Assignees: Toyota Jidosha Kabushiki Kaisha, Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Noboru Takayanagi, Kazuhiro Akihama, Yoshimi Kizaki
  • Patent number: 5123980
    Abstract: An amorphous aluminum-valve metal alloy with special characteristics such as high corrosion resistance, high wear resistance and considerable toughness, consisting of Al and at least one element selected from valve metals of Ti and Zr, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Mo, W, Ta and Nb.
    Type: Grant
    Filed: October 3, 1990
    Date of Patent: June 23, 1992
    Assignees: Yoshida Kogyo K.K., Koji Hashimoto
    Inventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
  • Patent number: 5122205
    Abstract: The present invention provides a corrosion resistant aluminum-based alloy consisting of a compound which has a composition represented by the general formula:Al.sub.a M.sub.b Mo.sub.c Hf.sub.d Cr.sub.ewherein:M is at least one metal element selected from Ni, Fe and Co and a, b, c, d and e are atomic percentages falling within the following ranges: 50%.ltoreq.a.ltoreq.88%, 2%.ltoreq.b.ltoreq.25%, 2%.ltoreq.c.ltoreq.15%, 4%.ltoreq.d.ltoreq.20% and 4%.ltoreq.e.ltoreq.20%,the compound being at least 50% by volume composed of an amorphous phase. The aluminum-based alloys not only have a high degree of hardness, strength and heat resistance but also exhibit a significantly improved corrosion resistance.
    Type: Grant
    Filed: April 23, 1990
    Date of Patent: June 16, 1992
    Assignee: Yoshida Kogyo K.K.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Junichi Nagahora, Katsumasa Ohtera, Kazuo Aikawa, Madoka Nakajima, Keiko Yamagata
  • Patent number: 5118368
    Abstract: Disclosed are high strength magnesium-based alloys consisting essentially of a composition represented by the general formula (I) Mg.sub.a M.sub.b X.sub.d, (II) Mg.sub.a Ln.sub.c X.sub.d or (III) Mg.sub.a M.sub.b Ln.sub.c X.sub.d, wherein M is at least one element selected from the group consisting of Ni, Cu, Al, Zn and Ca; Ln is at least one element selected from the group consisting of Y, La, Ce, Sm and Nd or a misch metal (Mm) which is a combination of rare earth elements; X is at least one element selected from the group consisting of Sr, Ba and Ga; and a, b, c and d are, in atomic percent, 55.ltoreq.a.ltoreq.95, 3.ltoreq.b.ltoreq.25, 1.ltoreq.c.ltoreq.15 and 0.5.ltoreq.d.ltoreq.30, the alloy being at least 50 percent by volume composed of an amorphous phase.
    Type: Grant
    Filed: June 7, 1991
    Date of Patent: June 2, 1992
    Assignees: Tsuyoshi Masumoto, Japan Metals & Chemicals Co., Ltd., Yoshida Kogyo K.K.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Takashi Sakuma, Toshisuke Shibata
  • Patent number: 5112388
    Abstract: There are described metallic powders comprising agglomerated nanocrystals of an electroactive alloy. The main component of the alloy can be of nickel, cobalt, iron or mixtures thereof while the alloying element is one or more transition metals such as Mo, W, V. Preferably the nanocrystals will be made of an alloy of nickel and molybdenum. An electrode which is used by compacting the powders is also disclosed. Also disclosed, is a process for producing the metallic powders by providing particles of nickel, cobalt and iron with particles of at least one transition metal, (Mo, W, V) and subjecting the particles to high energy mechanical alloying such as ball milling under conditions and for a sufficient period of time to produce a nanocrystalline alloy. Electrodes produced from these powders have an electrocatalytic activity for the hydrogen evolution which is comparable or higher than the electrodes which are presently used in the electrochemical industry.
    Type: Grant
    Filed: August 22, 1989
    Date of Patent: May 12, 1992
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Jean-Yves Huot, Michel Trudeau
  • Patent number: 5110372
    Abstract: A method for preparation of an aluminum based alloy composition comprising forming by spray deposition, a solid body having a composition comprising, by weight, 5.5 to 8.45% Zn, 2 to 3.5% Mg, 0.5 to 2.5% Cu, 0.1 to 0.5% Zr, 0.3 to 0.6% Cr, 0.3 to 1.1% Mn, up to 0.5% Fe, up to 0.5% Si, other elements <0.05% each, up to 0.15% total, and balance Al. The body is converted to a worked product at 300.degree. to 450.degree. C., optionally converted cold, and heat treated in a series of steps comprising dissolution, quenching and annealing in a T6 or T7 state.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: May 5, 1992
    Assignee: Pechiney Recherche
    Inventor: Jean-Francois Faure
  • Patent number: 5106430
    Abstract: A rapidly solidified, low density aluminum base alloy consisting essentially of the formula Al.sub.bal Li.sub.a Cu.sub.b Mg.sub.c Zr.sub.d wherein "a" ranges from about 2.1 to 3.4 wt %, "b" ranges from about 0.5 to 2.0 wt %, "c" ranges from about 0.2 to 2.0 wt % and "d" ranges from about 0.4 to 1.8 wt %, the balance being aluminum is consolidated to produce a strong, tough low density article.
    Type: Grant
    Filed: October 26, 1990
    Date of Patent: April 21, 1992
    Assignee: Allied-Signal, Inc.
    Inventor: Jerry C. LaSalle
  • Patent number: 5100614
    Abstract: A magnetic metallic glass alloy exhibits, in combination, high saturation induction and high Curie temperature. The alloy has a composition described by the formula Fe.sub.a Co.sub.b Ni.sub.c B.sub.d Si.sub.e C.sub.f, where "a"-"f" are in atom percent, "a" ranges from about 75 to about 81, "b" ranges from 0 to about 6, "c" ranges from about 2 to about 6, "d" ranges from about 11 to about 16, "e" ranges from 0 to about 4, and "f" ranges from 0 to about 4, with the provisos that (i) the sum of "b" and "c" may not be greater than about 8, (ii) "d" may not be greater than about 14 when "b" is zero (iii) "e" may be zero only when "b" is greater than zero, and (iv) "f" is zero when "e" is zero. This alloy is suitable for use in large magnetic cores used in various applications requiring high magnetization rates, and in the cores of line frequency power distribution transformers, airborne transformers, current transformers, ground fault interrupters, switch-mode power supplies, and the like.
    Type: Grant
    Filed: November 7, 1990
    Date of Patent: March 31, 1992
    Assignee: Allied-Signal Inc.
    Inventor: V. R. V. Ramanan
  • Patent number: 5091019
    Abstract: A rapidly solidified, low density aluminum base alloy consisting essentially of the formula Al.sub.ba1 Li.sub.a Cu.sub.b MG.sub.c Zr.sub.d wherein "a" ranges from about 2.1 to 3.4 wt %, "b" ranges from about 0.5 to 2.0 wt %, "c" ranges from about 0.2 to 2.0 wt % and "d" ranges from about 0.4 to 1.8 wt %, the balance being aluminum is consolidated to produce a strong, tough low density article.
    Type: Grant
    Filed: February 12, 1990
    Date of Patent: February 25, 1992
    Assignee: Allied-Signal, Inc.
    Inventor: Jerry C. LaSalle
  • Patent number: 5087298
    Abstract: A continuous thin sheet of a TiAl intermetallic compound consisting of from 35 to 44 wt % Al and the balance Ti and unavoidable impurities, having a thickness of from 0.2 to 3 mm, and having a solidified, as-cast structure comprising columnar crystals extending from both surfaces of the sheet toward the center of the sheet thickness, and a process for producing the same by using a twin-roll type continuous casting procedure.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: February 11, 1992
    Assignee: Nippon Steel Corporation
    Inventors: Toshiaki Mizoguchi, Kenichi Miyazawa, Toshihiro Hanamura, Naoya Masahashi
  • Patent number: 5076865
    Abstract: An amorphous aluminum-valve metal alloy with special characteristics such as high corrosion resistance, high wear resistance and coinsiderable toughness, consisting of Al and at least one element selected from valve metals of Ti and Zr, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Mo, W, Ta and Nb.
    Type: Grant
    Filed: October 13, 1989
    Date of Patent: December 31, 1991
    Assignees: Yoshida Kogyo K. K., Koji Hashimoto
    Inventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
  • Patent number: 5074936
    Abstract: A substantially amorphous aluminum/magnesium alloy optionally containing up to about ten atom percent calcium. The alloy contains from about 45 to about 75 atom percent aluminum and from about 25 to about 50 atom percent magnesium.
    Type: Grant
    Filed: May 2, 1990
    Date of Patent: December 24, 1991
    Assignee: The Dow Chemical Company
    Inventor: Lowell E. Hazelton
  • Patent number: 5074935
    Abstract: The present invention provides an amorphous alloy having superior mechanical strength, corrosion resistance for formability, at a relatively low cost. The amorphous alloy is a composition represented by the general formula: Al.sub.100-x-y M.sub.x Ln.sub.y wherein M is at least one element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Nb, Mo, Hf, Ta and W; Ln is at least one element selected from the group consisting of Y, La, Ce, Nd, Sm, Gd, Tb, Dy, Ho and Yb or misch metal (Mm) which is a combination of rare earth elements; and x and y are, in atomic percentages: 0<x.ltoreq.55 and 30.ltoreq.y.ltoreq.90, preferably 0<x.ltoreq.40 and 35.ltoreq.y.ltoreq.80, and more preferably 5<x.ltoreq.40 and 35.ltoreq.y.ltoreq.70, with the proviso that 100-x-y.gtoreq.5 the alloy having at least 50% (by volume) of an amorphous phase.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: December 24, 1991
    Assignees: Tsuyoshi Masumoto, Teikoku Piston Ring Co., Ltd., Yoshida Kogyo K.K.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Hitoshi Yamaguchi, Kazuhiko Kita, Hideki Takeda
  • Patent number: 5060478
    Abstract: As magnetically working substances capable of producing magnetically working abilities such as magnetic refrigeration or cooling in a wide range of temperatures with high efficiency, this invention utilizes amorphous alloys possessing a large magnetic moment and the spin glass property. Concrete examples of the amorphous alloys which meet the requirement are amorphous alloys containing rare earth metals, the same amorphous alloys absorbed hydrogen therein, and Fe-based amorphous alloys containing additional elements for formation of the amorphous phase. One element or the combination of two or more elements selected from the group just mentioned can be used, with the composition of alloys so adjusted for the desired magnetic transition points to be distributed or for the different magnetic transition points to be continuously distributed in a range of high to low temperatures.
    Type: Grant
    Filed: August 31, 1989
    Date of Patent: October 29, 1991
    Assignee: Research Development Corporation of Japan
    Inventor: Kazuaki Fukamichi
  • Patent number: 5055144
    Abstract: A method and apparatus are provided for monitoring in situ the transformation of some fraction of a starting material to another material during the course of a thermal treatment. The starting material is heated to a preselected temperature and its resistivity is measured. A signal is transmitted to an actuator, which indicates cooling of the material when a preselected resistivity or change therein is detected.
    Type: Grant
    Filed: June 26, 1990
    Date of Patent: October 8, 1991
    Assignee: Allied-Signal Inc.
    Inventors: Gordon E. Fish, Ryusuke Hasegawa, Ernest D. Buff
  • Patent number: 5053084
    Abstract: The present invention provides high-strength, heat resistant aluminum alloys having a composition represented by the general formula:Al.sub.a M.sub.b X.sub.d or Al.sub.a M.sub.b Q.sub.c X.sub.e(wherein M is at least one metal element selected from the group consisting of Cu, Ni, Co and Fe; Q is at least one metal element selected from the group consisting Mn, Cr, Mo, W, V, Ti and Zr; X is at least one metal element selected from the group consisting of Nb, Ta, Hf and Y; and a, b, c, d and e are atomic percentages falling within the following ranges: 45.ltoreq.a.ltoreq.90, 5.ltoreq.b.ltoreq.40, 0<c.ltoreq.12, 0.5.ltoreq.d.ltoreq.15 and 0.5.ltoreq.e.ltoreq.10, the aluminum alloy containing at least 50% by volume of amorphous phase.
    Type: Grant
    Filed: April 30, 1990
    Date of Patent: October 1, 1991
    Assignees: Yoshida Kogyo K.K., Tsuyoshi Masumoto
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Katsumasa Odera, Masahiro Oguchi
  • Patent number: 5053085
    Abstract: The present invention provides high strength, heat resistant aluminum-based alloys having a composition represented by the general formula, Al.sub.a M.sub.b X.sub.cwherein:M is at least one metal element selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg, and Si;X is at least one metal element selected from the group consisting of Y, La, Ce, Sm, Nd, Hf, Nb, Ta and Mm (misch metal); anda, b and c are atomic percentages falling within the following ranges:50.ltoreq.a.ltoreq.95, 0.5.ltoreq.b.ltoreq.35 and 0.5.ltoreq.c.ltoreq.25,the aluminum-based alloy being in an amorphous state, microcrystalline state or a composite state thereof. The aluminum-based alloys possess an advantageous combination of properties of high strength, heat resistance, superior ductility and good processability which make them suitable for various applications.
    Type: Grant
    Filed: April 28, 1989
    Date of Patent: October 1, 1991
    Assignees: Yoshida Kogyo K.K., Piston Ring Company, Ltd., Tsuyoshi Masumoto
    Inventors: Tsuyoshi Masumoto, Akihisa Inoe, Katsumasa Odera, Masahiro Oguchi
  • Patent number: 5045125
    Abstract: A component composed of a rapidly solidified aluminum-lithium alloy is subjected to thermal treatment at a temperature greater than 500.degree. C. for a time period greater than 5 hours under a protective atmosphere. Thus case toughened, the component exhibits notched impact toughness from 40 to 250% greater than that exhibited prior to the thermal treatment.
    Type: Grant
    Filed: April 2, 1990
    Date of Patent: September 3, 1991
    Assignee: Allied-Signal Inc.
    Inventor: Jerry C. LaSalle
  • Patent number: 5043029
    Abstract: An apparatus and method for casting metal strip include a moving chill body that has a quench surface. A nozzle mechanism deposits a stream of molten metal on a quenching region of the quench surface to form the strip. The nozzle mechanism has an exit portion with a nozzle orifice. A depletion mechanism supplies a reducing gas to a depletion region located adjacent to and upstream from the quenching region. The reducing gas reacts exothermically to lower the density provide a low density reducing atmosphere within the depletion and substantially prevent formation of gas pockets in the strip.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: August 27, 1991
    Assignee: Allied-Signal Inc.
    Inventors: Howard H. Liebermann, John A. Wellslager, Lance A. Davis
  • Patent number: 5043027
    Abstract: A method of reestablishing the deformability or malleability of embrittled amorphous alloys such as Fe.sub.40 Ni.sub.40 P.sub.20 or Fe.sub.20 Ni.sub.40 B.sub.20 or Cu.sub.64 Ti.sub.36. An alloy is first subjected to a first temperature for a specific first time interval. Subsequently, the alloy is subjected in a sudden manner to a second temperature for a specific second time interval. The effecting of change of the temperature of the alloy from the first temperature to the second temperature occurs at a rate of 100.degree. K./min. The first temperature is greater than the second temperature with the first temperature being in a temperature range between an embrittlement temperature and a crystallization temperature of the alloy.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: August 27, 1991
    Assignee: GKSS-Forschungszentrum Geesthacht GmbH
    Inventors: Rainer Gerling, Frank-Peter Schimansky
  • Patent number: 5041175
    Abstract: An amorphous aluminum-refractory metal alloy with special characteristics such as high corrosion resistance, high wear resistance and considerable toughness, consisting of Al and at least one element selected from refractory metals of Ta, Nb, Mo and W, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti and Zr.
    Type: Grant
    Filed: October 5, 1990
    Date of Patent: August 20, 1991
    Assignees: Yoshida Kogyo K.K., Koji Hashimoto
    Inventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
  • Patent number: 5037494
    Abstract: An amorphous alloy free of magnetostriction is employed in anti-theft labels, magnetic field detectors or the like, having a saturation induction of B.sub.s .ltoreq.0.5T and a good responsiveness given an annealing treatment in the magnetic field for achieving a remanance relationship of B.sub.r /B.sub.s >0.6.
    Type: Grant
    Filed: May 15, 1990
    Date of Patent: August 6, 1991
    Assignee: Vacuumschmelze GmbH
    Inventors: Hans R. Hilzinger, Giselher Herzer
  • Patent number: 5037706
    Abstract: A laminated amorphous metal strip has a first layer having at least two side-by-side strips of amorphous metal of unequal widths. A second layer has at least two side-by-side strips of amorphous metal of unequal widths, the layers being in reverse order with respect to the widths of the strips such that the wider strips overlap and form a brickwork cross-section pattern. A flexible polymeric bonding material is disposed between the layers. The polymeric bonding material is an adhesive and has excellent electrical properties. A device for forming the laminated strip of amorphous metal has a plurality of rolls of amorphous metal. Strips from a roll are positioned side-by-side with strips from a wider roll. A bonding material is applied from spray guns to the surface of the strips. Strips from a roll of metal and a wide roll of metal are positioned on the bonding material in a reverse order of the wider strips. Pressure is applied to the laminate.
    Type: Grant
    Filed: February 27, 1990
    Date of Patent: August 6, 1991
    Assignee: Asea Brown Boveri, Inc.
    Inventors: Kou C. Lin, Frank R. Zickar, Eugene E. Zook, Paul W. Martincie
  • Patent number: H1193
    Abstract: This invention describes a process for producing copper alloys by rapid sdification in order to improve their strength and thermal stability after being exposed to elevated temperatures. The method used to rapidly solidify the molten alloy is either by use of a high pressure non-oxidizing gas spray to atomize the molten alloy into a powder or to pour the molten alloy onto a rotating wheel to form a ribbon which is then attrited into powder. The powder is canned, compacted to full density and cold worked to the desired shape.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: June 1, 1993
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Ravi Batra, Jerry C. LaSalle, Sheldon Cytron