Magnesium Base Patents (Class 148/420)
-
Patent number: 12226815Abstract: The present disclosure provides a method of forming an extruded billet from a coarse-grained magnesium alloy billet. The method includes extruding the coarse-grained magnesium alloy biller at temperatures greater than or equal to about 300° C. to less than or equal to about 360° C. to from the extruded billet. The coarse-grained magnesium alloy billet has an average grain size greater than or equal to about 800 ?m, and has a low aluminum content. The coarse-grained magnesium alloy billet includes greater than or equal to about 0.5 wt. % to less than or equal to about 3 wt. % of aluminum. The extruded billet may have a plurality of twins with lenticular morphology, which occupies an area fraction greater than or equal to about 20% of a total area of the extruded billet.Type: GrantFiled: July 25, 2022Date of Patent: February 18, 2025Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Henry Zhan, Congjie Wang
-
Patent number: 12214393Abstract: The present invention provides magnesium or magnesium alloys having high formability at room temperature, the magnesium or magnesium alloys having a grain size ?2 microns. The present invention also provides a method for manufacturing the magnesium or magnesium alloys having high formability at room temperature. The magnesium or magnesium alloys having high formability at room temperature are prepared by simple processing means. The present invention overcomes a problem of poor formability at room temperature.Type: GrantFiled: September 21, 2018Date of Patent: February 4, 2025Assignees: BAOSHAN IRON & STEEL CO., LTD., CHINA BAOWU STEEL GROUP CORP., LTD.Inventors: Jianfeng Nie, Zhuoran Zeng, Shiwei Xu, Nick Birbilis, Christopher H. J. Davies, Weineng Tang
-
Patent number: 12173384Abstract: Disclosed herein are magnesium alloy based objects and methods of making and use thereof. For example, disclosed herein are methods of making a magnesium alloy based object, the methods comprising: heating an object comprising a preliminary magnesium alloy at a first temperature for a first amount of time, the preliminary magnesium alloy comprising a first intermetallic phase, a second intermetallic phase, and an alloy phase, to thereby substantially dissolving the first intermetallic phase into the alloy phase to form an object comprising an intermediate magnesium alloy, the intermediate magnesium alloy comprising the second intermetallic phase and the alloy phase; and heating the object comprising the intermediate magnesium alloy at a second temperature for a second amount of time to thereby substantially dissolving the second intermetallic phase into the alloy phase and minimizing incipient melting of the alloy phase to form the magnesium alloy based object.Type: GrantFiled: August 6, 2020Date of Patent: December 24, 2024Assignee: Ohio State Innovation FoundationInventors: Aihua Luo, Thomas Avey
-
Patent number: 12134807Abstract: Provided is an alloy member including a substrate made of magnesium-lithium alloy with a sum of content of magnesium and content of lithium of 90 mass % or more and a coating film disposed on the substrate. The coating film contains fluorine and oxygen, with a fluorine content of more than 50 atom % and an oxygen content of less than 5 atom %.Type: GrantFiled: September 23, 2021Date of Patent: November 5, 2024Assignee: Canon Kabushiki KaishaInventor: Jun-ichi Sakamoto
-
Patent number: 12031009Abstract: A downhole hydraulic frac tool for use in a hydraulic fracturing system, the frac tool comprising a dissolvable frac tool member that includes a water-dissolvable composition, the composition including: a water-soluble thermoplastic polymer; and water-soluble bulk metallic glass (BMG) particles, wherein: the BMG particles are embedded within a matrix of the water-soluble thermoplastic polymer, the BMG particles have a greater tensile strength than a tensile strength the water-soluble thermoplastic polymer, and the BMG particles have a higher fracture toughness than a fracture toughness the water-soluble thermoplastic polymer. A method of manufacturing a dissolvable downhole hydraulic frac tool member and, a hydraulic fracturing system associated with a wellbore in which dissolvable downhole hydraulic frac tools of the disclosure can be used, are also disclosed.Type: GrantFiled: June 23, 2022Date of Patent: July 9, 2024Assignee: Halliburton Energy Services, Inc.Inventors: Shashwat Shukla, Arpana Singh, Sandeep Thatathil
-
Patent number: 11998978Abstract: Some variations provide a functionalized composite material comprising: a thermoplastic polymer binder matrix disposed in a distinct volume; a plurality of discrete metal or metal alloy particles dispersed in the thermoplastic polymer matrix; and a plurality of discrete particulates assembled on surfaces of the discrete metal or metal alloy particles, wherein the discrete particulates are in contact with the thermoplastic polymer binder matrix, wherein the discrete particulates are smaller than the discrete metal or metal alloy particles in at least one dimension, and wherein the discrete particulates are compositionally different than the discrete metal or metal alloy particles. The discrete particulates may be selected and/or configured to function as a grain refiner, a sintering aid, and/or a strengthening phase, within the functionalized composite material.Type: GrantFiled: January 28, 2019Date of Patent: June 4, 2024Assignee: HRL Laboratories, LLCInventors: Jacob M. Hundley, John H. Martin, Brennan Yahata, Julie Miller, Randall C. Schubert, Tobias A. Schaedler
-
Patent number: 11986877Abstract: A composite object for the production of hydrogen from water-reactive aluminum may include a first portion including an aluminum alloy having a non-recrystallized grain structure, and a second portion including an activation metal corrodible to the aluminum alloy, wherein the second portion and the first portion are coupled to one another with the activation metal of the second portion in contact with the aluminum alloy of the first portion at a plurality of points of contact stress, and the activation metal of the second portion is penetrable into the non-recrystallized grain structure of the aluminum alloy of the first portion via the addition of heat.Type: GrantFiled: December 10, 2020Date of Patent: May 21, 2024Assignee: LTAG SYSTEMS LLCInventors: Jonathan T. Slocum, Alexander H. Slocum
-
Patent number: 11931800Abstract: The invention is directed to the interventionless activation of wellbore devices using dissolving and/or degrading and/or expanding structural materials. Engineered response materials, such as those that dissolve and/or degrade or expand upon exposure to specific environment, can be used to centralize a device in a wellbore.Type: GrantFiled: July 16, 2021Date of Patent: March 19, 2024Inventor: Andrew J. Sherman
-
Patent number: 11840749Abstract: A magnesium-lithium-based alloy contains Mg, Li, and Al, and a sum of a content of the Mg and a content of the Li is 90% by mass or more. The magnesium-lithium-based alloy contains Ge.Type: GrantFiled: October 14, 2020Date of Patent: December 12, 2023Assignee: Canon Kabushiki KaishaInventor: Keiichi Ishizuka
-
Patent number: 11692256Abstract: Adding multiple solute elements could create fracture origin through formation of intermetallic compound due to bonding of added elements. While maintaining microstructure for activating non-basal dislocation movement, additive elements not to create fracture origin, but to promote grain boundary sliding are preferably found from among inexpensive and versatile elements. Provided is Mg-based wrought alloy material including two or more among group consisting of Mn, Zr, Bi, and Sn; and Mg and unavoidable constituents, having excellent room-temperature ductility and characterized by having finer crystal grain size in Mg parent phase during room-temperature deformation and in that mean grain size in matrix thereof is 20 ?m or smaller; rate of (?max??bk)/?max (maximum load stress (?max), breaking stress (?bk)) in stress-strain curve obtained by tension-compression test of the wrought material is 0.2 or higher; and resistance against breakage shows 200 kJ or higher.Type: GrantFiled: July 10, 2018Date of Patent: July 4, 2023Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventors: Hidetoshi Somekawa, Yoshiaki Osawa
-
Patent number: 11655513Abstract: Methods of making magnesium-based alloy components, such as automotive components, include treating a casting comprising a magnesium-based alloy to a first deforming process to form a preform. In one aspect, the first deforming process has a first maximum predetermined strain rate of greater than or equal to about 0.001/s to less than or equal to about 1/s in an environment having a temperature of ?to about 250° C. to ?to about 450° C. In another aspect, the first deforming process is cold deforming that is followed by annealing. The preform is then subjected to a second deforming process having a second maximum predetermined strain rate of ?about 1/s to ?about 100/s in an environment having a temperature of ?about 150° C. to ?about 450° C. to form the magnesium-based alloy component substantially free of cracking. A solid magnesium-based alloy component having select microstructures are also provided.Type: GrantFiled: December 10, 2020Date of Patent: May 23, 2023Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventor: Henry Zhan
-
Patent number: 11578396Abstract: Provided is Mg-based alloy wrought material having improved ductility, formality, and resistance against fracture. Intermetallic compounds may be formed by mutual bonding of added elements to be a fracture origin. While maintaining microstructure for activating non-basal dislocation movement of Mg-based alloy wrought material, added elements to create no fracture origin, but to promote grain boundary sliding were found from among inexpensive and versatile elements. Provided is Mg-based alloy wrought material including at least one element from Zr, Bi, and Sn and at least one element from Al, Zn, Ca, Li, Y, and Gd wherein remainder comprises Mg and unavoidable impurities; an average grain size in a parent phase is 20 ?m or smaller; a value of (?max??bk)/?max (maximum load stress (?max), breaking stress (?bk)) in a stress-strain curve obtained by tension-compression tests of the wrought material is 0.2 or higher; and resistance against breakage shows 100 kJ or higher.Type: GrantFiled: July 13, 2018Date of Patent: February 14, 2023Assignee: National Institute for Materials ScienceInventors: Hidetoshi Somekawa, Yoshiaki Osawa
-
Patent number: 11462671Abstract: A magnesium-based thermoelectric conversion material made of a sintered compact of a magnesium compound, in which, in a cross section of the sintered compact, a Si-rich metallic phase having a higher Si concentration than in magnesium compound grains is unevenly distributed in a crystal grain boundary between the magnesium compound grains, an area ratio of the Si-rich metallic phase is in a range of 2.5% or more and 10% or less, and a number density of the Si-rich metallic phase having an area of 1 ?m2 or more is in a range of 1,800/mm2 or more and 14,000/mm2 or less.Type: GrantFiled: May 11, 2018Date of Patent: October 4, 2022Assignee: MITSUBISHI MATERIALS CORPORATIONInventor: Yoshinobu Nakada
-
Patent number: 11345981Abstract: The present disclosure relates to a biodegradable metal alloy with multiple properties, containing: 0.05-0.15 wt % of calcium; a metal element X having a HCP structure, of a composition not forming a precipitated phase when mixed with magnesium; and magnesium as the remainder.Type: GrantFiled: December 20, 2018Date of Patent: May 31, 2022Assignee: U & I CORPORATIONInventors: Ja Kyo Koo, Hwa Chul Jung, Won Hyun Shim, Hyung Jin Roh, Hyun Kwang Seok, Yu Chan Kim
-
Patent number: 11066730Abstract: According to one embodiment of the present invention, a cast alloy material is provided. The cast alloy material includes a matrix metal and an alloy element, wherein oxide particles in a nanometer scale are decomposed in the matrix metal, so that a new phase including a metal element that is a component of the oxide particles and the alloy element forms a band or network structure, wherein the metal element and the alloy element have a relationship of a negative heat of mixing, and wherein oxygen atoms formed by decomposition of the oxide particles are dispersed in the matrix metal and do not form an oxide with the matrix metal.Type: GrantFiled: June 22, 2012Date of Patent: July 20, 2021Assignee: Industry-Academic Cooperation Foundation, Yonsei UniversityInventors: Dong Hyun Bae, Hun Kang
-
Patent number: 11060173Abstract: In order to improve the ductility or formability of a magnesium alloy, addition of rare earth elements or refinement of grain size is often used. However, conventional additional elements inhibit the action of grain boundary sliding for complementing plastic deformation. Therefore, it is required to search for additional elements that act to facilitate the grain boundary sliding not only at a conventional deformation speed but also in a higher speed range while maintaining a microstructure for activating non-basal dislocation. The present invention is to provide a wrought processed Mg-based alloy having excellent ductility at room temperature, which consists of 0.25 mass % or more to 9 mass % or less of Bi, and a balance of Mg and inevitable components, and is characterized by having an average grain size of an Mg parent phase after solution treatment and hot plastic working after casting of 20 ?m or less.Type: GrantFiled: March 8, 2017Date of Patent: July 13, 2021Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventors: Hidetoshi Somekawa, Alok Shingh, Tadanobu Inoue
-
Patent number: 10995392Abstract: Embodiments of the present disclosure include compositions that include magnesium and gadolinium or magnesium and one or more metals.Type: GrantFiled: April 20, 2020Date of Patent: May 4, 2021Assignee: University of Florida Research Foundation, Inc.Inventors: Michele Viola Manuel, Hunter B. Henderson, Kelly A. Jordan
-
Patent number: 10870905Abstract: A die-casting magnesium alloy. The die-casting magnesium alloy comprises, by mass percent, 1% to 5% of La, 0.5% to 3% of Zn, 0.1% to 2% of Ca, 0.1% to 1% of Mn and the balance Mg and other inevitable impurities. The die-casting magnesium alloy manufacturing method comprises smelting, refinement and die-casting. The die-casting magnesium alloy has good mechanical performance, die-casting performance and heat conduction performance.Type: GrantFiled: December 6, 2016Date of Patent: December 22, 2020Assignee: Baoshan Iron & Steel Co., Ltd.Inventors: Shiwei Xu, Jichun Dai, Weineng Tang, Changlong Zhuo, Haomin Jiang, Pijun Zhang
-
Patent number: 10751793Abstract: The invention provides magnesium alloys for high temperature applications that combine excellent castability with superior corrosion resistance, and with good creep resistance, ductility, impact strength, and thermal conductivity. The alloys contain mainly Al, La, Ce, and Mn, and are particularly useful for high-pressure die casting process.Type: GrantFiled: June 24, 2015Date of Patent: August 25, 2020Assignee: DEAD SEA MAGNESIUM LTD.Inventors: Boris Bronfin, Nir Nagar, Nir Moscovitch, Meir Cohen
-
Patent number: 10468577Abstract: A method for manufacturing a magnesium-based thermoelectric conversion material of the present invention includes a raw material-forming step of forming a raw material for sintering by adding silicon oxide in an amount within a range equal to or greater than 0.5 mol % and equal to or smaller than 13.0 mol % to a magnesium-based compound, and a sintering step of heating the raw material for sintering at a temperature within a range equal to or higher than 750° C. and equal to or lower than 950° C. while applying pressure equal to or higher than 10 MPa to the raw material for sintering so as to form a sintered substance.Type: GrantFiled: February 22, 2017Date of Patent: November 5, 2019Assignee: MITSUBISHI MATERIALS CORPORATIONInventor: Yoshinobu Nakada
-
Patent number: 10287657Abstract: There is provided a Mg—N-A based magnesium material (A is a metal or non-metal element configuring a nitride, N: nitrogen originating from the nitride). The magnesium material includes a spherical Mg—N-A eutectic phase and nitrogen atoms are dispersed in a magnesium matrix, whereby mechanical and ignition properties of the magnesium material are improved, as compared to a magnesium material or pure magnesium material in which the nitrogen atoms are not included and only the metal or non-metal element is included.Type: GrantFiled: April 13, 2015Date of Patent: May 14, 2019Assignee: Industry-Academic Cooperation Foundation, Yonsei UniversityInventors: DongHyun Bae, Hun Kang, SeungWon Kang
-
Patent number: 10266916Abstract: A grain refiner for a magnesium alloy according to the present invention contains aluminum (Al) and manganese (Mn), and contains a compound of aluminum (Al) and manganese (Mn) in the microstructure thereof, wherein the grain refiner is composed of a structure in which, in the compound of aluminum (Al) and manganese (Mn), the area of the compound having an Al/Mn compositional (atomic) ratio of 4-4.5 is larger than the area of the compound having an Al/Mn compositional (atomic) ratio of 5.5-6.5. When the grain refiner is added to molten magnesium, crystal grains can be refined to 50-100 ?m.Type: GrantFiled: April 6, 2015Date of Patent: April 23, 2019Assignee: KOREA INSTITUTE OF MACHINERY & MATERIALSInventors: Jun-ho Bae, Bong-sun You, Young-min Kim, Ha-sik Kim, Chang-dong Lim, Byeong-gi Moon, Sung-hyuk Park
-
Patent number: 9822432Abstract: A magnesium alloy that forms a stable protective film on the surface of molten metal, having excellent ignition resistance restricting natural ignition of a chip thereof as well as having excellent strength and ductility, so that the Mg alloy can be melted and cast in the air or a common inert atmosphere. The magnesium alloy includes, by weight, 7.0% or greater but less than 11% of Al, 0.05% to 2.0% of Ca, 0.05% to 2.0% of Y, greater than 0% but not greater than 6.0% of Zn, and the balance of Mg, and the other unavoidable impurities. The total content of the Ca and the Y is equal to or greater than 0.1% but less than 2.5% of the total weight of the magnesium alloy.Type: GrantFiled: October 4, 2011Date of Patent: November 21, 2017Assignee: KOREA INSTITUTE OF MACHINERY & MATERIALSInventors: Young Min Kim, Ha Sik Kim, Bong Sun You, Chang Dong Yim
-
Patent number: 9759035Abstract: At least a portion of a wellbore isolation device consists essentially of: a metal alloy, wherein the metal alloy: (A) comprises magnesium at a concentration of at least 50% by volume of the metal alloy; and (B) at least partially dissolves in the presence of an electrolyte. A method of removing the wellbore isolation device comprises: contacting or allowing the wellbore isolation device to come in contact with an electrolyte; and allowing at least a portion of the metal alloy to dissolve.Type: GrantFiled: March 6, 2014Date of Patent: September 12, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Michael L. Fripp, Zachary W. Walton, Zachary R. Murphree
-
Patent number: 9708700Abstract: The present invention provides a magnesium-lithium alloy having both corrosion resistance and cold workability balanced at high levels, a certain degree of tensile strength, and very light weight, as well as a rolled material and a formed article made of this alloy. The alloy of the invention contains not less than 10.5 mass % and not more than 16.0 mass % Li, not less than 0.50 mass % and not more than 1.50 mass % Al, and the balance of Mg, and has an average crystal grain size of not smaller than 5 ?m and not larger than 40 ?m, and a tensile strength of not lower than 150 MPa or a Vickers hardness (HV) of not lower than 50.Type: GrantFiled: December 25, 2009Date of Patent: July 18, 2017Assignee: SANTOKU CORPORATIONInventors: Kenki Kin, Takeki Matsumura, Shinji Namba, Shinichi Umino, Takayuki Goto, Yuji Tanibuchi, Yukihiro Yokoyama
-
Patent number: 9702033Abstract: The present invention provides a very lightweight magnesium-lithium alloy which has both corrosion resistance and cold workability balanced at high levels, a certain degree of tensile strength, low surface electrical resistivity, as well as a rolled material and a formed article made of the alloy, and a method of producing the alloy, by means of a magnesium-lithium alloy containing not less than 10.5 mass % and not more than 16.0 mass % Li, not less than 0.50 mass % and not more than 1.50 mass % Al, and the balance of Mg, and having an average crystal grain size of not smaller than 5 ?m and not larger than 40 ?m, a tensile strength of not lower than 150 MPa, and a surface electrical resistivity of not higher than 1? as measured with an ammeter by pressing a cylindrical two-point probe with a pin-to-pin spacing of 10 mm and a pin tip diameter of 2 mm (contact surface area of one pin is 3.14 mm2), against an alloy surface at a load of 240 g.Type: GrantFiled: September 10, 2010Date of Patent: July 11, 2017Assignee: SANTOKU CORPORATIONInventors: Kenki Kin, Takeki Matsumura, Shinji Namba, Shinichi Umino, Takayuki Goto
-
Patent number: 9702028Abstract: A magnesium-based alloy powder is made of a magnesium-based alloy that contains 0.2 mass % to 5 mass % of calcium, wherein the magnesium-based alloy powder has an average particle diameter of 100 ?m to 1,500 ?m, wherein the magnesium-based alloy powder has a particle average aspect ratio of 0.5 to 1, wherein the magnesium-based alloy powder has an apparent density of 0.2 g/cm3 to 1.2 g/cm3, and wherein the mean value of hardness variation index values obtained by dividing the difference of the maximum value and the minimum value of micro Vickers hardnesses taken at 10 measurement points in a particle cross section by the maximum value is 0.3 or less.Type: GrantFiled: February 27, 2014Date of Patent: July 11, 2017Assignee: Seiko Epson CorporationInventors: Isamu Otsuka, Hiroyoshi Otaka
-
Patent number: 9593397Abstract: An alloy and an implant having a three-dimensional structure based on such alloy. The alloy comprises a MgZnCa alloy containing nanosized precipitates being less noble than the Mg matrix alloy and having a Zn content ranging 0.1 wt. % Zn to 2 wt. % Zn and a calcium content ranging from 0.2 wt. % to 0.5 wt. %, and having less than 0.04 wt. % of one or more other elements with the remainder being Mg. For these micro-alloys, any second phase generated during the solidification process can be completely dissolved by a solution heat treatment. Finely dispersed nanosized precipitates can then be generated by a subsequent aging heat treatment step. These precipitates are used to “pin” the grain boundaries and to prevent the coarsening of the grain structure during further processing to achieve grain sizes below 5 ?m.Type: GrantFiled: March 11, 2014Date of Patent: March 14, 2017Assignee: DePuy Synthes Products, Inc.Inventors: Thomas Imwinkelried, Stefan Beck, Peter Uggowitzer, Joerg Loeffler
-
Patent number: 9518314Abstract: A production method of an extrusion billet includes a step of preparing a plate or lump starting material comprising a magnesium alloy, a step of performing a plastic deformation process at a rolling reduction of 70% or more to the starting material at a temperature of 250° C. or lower to introduce a strain without generating dynamic recrystallization, a step of producing powder by granulating the material after the plastic deformation process, and a step of producing a powder billet by compressing the powder.Type: GrantFiled: June 19, 2008Date of Patent: December 13, 2016Assignees: KURIMOTO LTD.Inventors: Katsuyoshi Kondoh, Makoto Hotta, Jinsun Liao, Kantaro Kaneko, Norio Fujii, Hirohito Kametani, Akihiko Koshi
-
Patent number: 9447482Abstract: The present invention relates to a magnesium-based alloy, and to a method for producing same. The method comprises the steps of: melting a magnesium alloy into a liquid state; adding a silicon compound to said molten magnesium alloy; exhausting the silicon compound through a full reaction between said molten magnesium alloy and said added silicon compound such that the silicon compound does not substantially remain in the magnesium alloy; and exhausting the silicon produced as a result of said exhaustion in the precious step such that the silicon may not substantially remain in said magnesium alloy.Type: GrantFiled: May 18, 2012Date of Patent: September 20, 2016Assignee: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGYInventors: Shae K. Kim, Young Ok Yoon, Jin Kyu Lee, Jung Ho Seo, Hyun Kyu Im
-
Patent number: 9373840Abstract: A negative electrode active material for a secondary battery contains an aluminum alloy. The internal structure of the aluminum alloy has a crystalline aluminum phase in a magnesium-supersaturated solid solution state, and an amorphous aluminum phase. The amorphous aluminum phase is dispersed in the crystalline aluminum phase in the magnesium-supersaturated solid solution state. Each of these phases has a columnar shape. The magnesium content of the aluminum alloy preferably is greater than 22 at % and less than 35 at %, and more preferably, lies within a range of 25±2 at %.Type: GrantFiled: February 20, 2014Date of Patent: June 21, 2016Assignee: Honda Motor Co., Ltd.Inventor: Kenshi Inoue
-
Patent number: 9362015Abstract: Growth and characterization of low cost, and high efficiency micro- and nanostructured p-n heterojunction solar cells through eutectic solidification are provided. Eutectic solidification results in self-assembly of lamellar or rod-like domains with length scales from hundreds of nanometers to micrometers that can be used for efficient extraction of minority carriers in metallurgical-grade materials. The material having a eutectic or near-eutectic composition can be used in making a low-cost and efficient inorganic solar cell.Type: GrantFiled: December 16, 2011Date of Patent: June 7, 2016Assignee: The Regents Of The University Of MichiganInventor: Akram Boukai
-
Patent number: 9334554Abstract: A magnesium alloy sheet having good press formability, a magnesium alloy structural member produced by pressing the sheet, and a method for producing a magnesium alloy sheet are provided. The magnesium alloy sheet is composed of a magnesium alloy containing Al and Mn. When a region from a surface of the alloy sheet to 30% of the thickness of the alloy sheet in a thickness direction of the magnesium alloy sheet is defined as a surface region and when a 200 ?m2 sub-region is arbitrarily selected from this surface region, the number precipitated impurity grains containing both Al and Mg and having a maximum diameter of 0.5 to 5 ?m is 5 or less. When a 50 ?m2 sub-region is arbitrarily selected from the surface region, the number of crystallized impurity grains containing both Al and Mn and having a maximum diameter of 0.1 to 1 ?m is 15 or less. In the grains of the crystallized phases, the mass ratio Al/Mn of Al to Mn is 2 to 5.Type: GrantFiled: June 8, 2010Date of Patent: May 10, 2016Assignee: SUMITOMO ELECTRIC INDUSTRIES, LTD.Inventors: Takahiko Kitamura, Yukihiro Oishi, Nozomu Kawabe
-
Patent number: 9085815Abstract: Provided is a magnesium alloy for room temperature, which is manufactured by adding CaO onto a surface of a molten magnesium alloy and exhausting the CaO through a reduction reaction of the CaO with the molten magnesium alloy. Resultantly, the magnesium alloy with CaO added has more improved room-temperature mechanical properties (tensile strength, yield strength, elongation) than magnesium alloys without using CaO. Furthermore, as the added amount of CaO increases, room-temperature mechanical properties (tensile strength, yield strength, elongation) increase as well.Type: GrantFiled: March 22, 2011Date of Patent: July 21, 2015Assignee: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGYInventors: Shae K. Kim, Jung-Ho Seo
-
Patent number: 9045335Abstract: A hydrogen absorbing and desorbing material formed by co-deposition of magnesium with a catalyst for the kinetic absorption and desorption of hydrogen. A hydrogen absorbing and desorbing material formed of an alloy of magnesium with a catalyst for the kinetic absorption and desorption of hydrogen in which the catalyst for the kinetic absorption and desorption of hydrogen forms a dispersed amorphous or nanocrystalline phase in the magnesium. A hydrogen absorbing and desorbing material having a catalytic surface formed by a process comprising the steps of depositing a layer of tantalum on the hydrogen absorbing and desorbing material and depositing a layer of palladium on the layer of tantalum. A hydrogen absorbing and desorbing material comprises a multilayer film having at least two layers of magnesium and at least two layers of catalyst for the kinetic absorption and desorption of hydrogen, in which the multilayer film comprises alternating layers of magnesium and catalyst.Type: GrantFiled: August 18, 2011Date of Patent: June 2, 2015Assignee: The Governors of the University of AlbertaInventors: David Mitlin, Beniamin Zahiri, Mohsen Danaie, Babak Shalchi Amirkhiz, XueHai Tan, Erik Luber, Christopher Harrower, Peter Kalisvaart
-
Publication number: 20150129092Abstract: A magnesium alloy includes <3% by weight of Zn, ?0.6% by weight of Ca, with the rest being formed by magnesium containing impurities, which favor electrochemical potential differences and/or promote the formation of intermetallic phases, in a total amount of no more than 0.005% by weight of Fe, Si, Mn, Co, Ni, Cu, Al, Zr and P, wherein the alloy contains elements selected from the group of rare earths with the atomic number 21, 39, 57 to 71 and 89 to 103 in a total amount of no more than 0.002% by weight.Type: ApplicationFiled: June 25, 2013Publication date: May 14, 2015Inventors: Heinz Mueller, Peter Uggowitzer, Joerg Loeffler
-
Publication number: 20150129091Abstract: A magnesium alloy includes 3 to 7.0% Zn, 0.001 to 0.5% Ca, the remainder being magnesium containing impurities, which promote electrochemical potential differences and/or the formation of intermetallic phases, in a total amount of no more than 0.005 of Fe, Si, Mn, Co, Ni, Cu, Al, Zr and P, wherein the alloying elements are selected from the group of the rare earths having the ordinal numbers 21, 39, 57 to 71 and 89 to 103 in a total amount of no more than 0.001% by weight.Type: ApplicationFiled: June 24, 2013Publication date: May 14, 2015Inventors: Heinz Mueller, Peter Uggowitzer, Joerg Loeffler
-
Publication number: 20150119995Abstract: A magnesium alloy, implants and method for the production thereof. The magnesium alloy includes 1.5 to 7.0% by weight Zn, 0.5 to 3.5% by weight Al, the remainder being magnesium which contains impurities, which promote electrochemical potential differences and/or the formation of precipitations and/or intermetallic phases, in a total amount of no more than 0.0063% by weight of Fe, Si, Mn, Co, Ni, Cu, Zr, Y, Sc or rare earths having the ordinal numbers 21, 57 to 71 and 89 to 103, Be, Cd, In, Sn and/or Pb as well as P.Type: ApplicationFiled: June 20, 2013Publication date: April 30, 2015Inventors: Heinz Mueller, Peter Uggowitzer, Joerg Loeffler
-
Publication number: 20150090374Abstract: To provide a magnesium alloy having high incombustibility, high strength and high ductility together. A magnesium alloy including Ca in an amount of “a” atomic %, Al in an amount of “b” atomic % and a residue of Mg, including (Mg, Al)2Ca in an amount of “c” volume %, wherein “a”, “b” and “c” satisfy the following equations (1) to (4), and having the (Mg, Al)2Ca dispersed therein. 3?a?7??(1) 4.5?b?12??(2) 1.2?b/a?3.Type: ApplicationFiled: April 16, 2013Publication date: April 2, 2015Inventors: Yoshihito Kawamura, Michiaki Yamasaki
-
Publication number: 20150083285Abstract: A magnesium alloy of the present invention has the chemical composition that contains 0.02 mol % or more and less than 0.1 mol % of at least one element selected from yttrium, scandium, and lanthanoid rare earth elements, and magnesium and unavoidable impurities accounting for the remainder. A magnesium alloy member of the present invention is produced by hot plastic working of the magnesium alloy in a temperature range of 200° C. to 550° C., followed by an isothermal heat treatment performed in a temperature range of 300° C. to 600° C. The magnesium alloy is preferred for use in applications such as in automobiles, railcars, and aerospace flying objects. The magnesium alloy and the magnesium alloy member can overcome the yielding stress anisotropy problem, and are less vulnerable to the rising price of rare earth elements.Type: ApplicationFiled: May 28, 2013Publication date: March 26, 2015Inventors: Hidetoshi Somekawa, Yoshiaki Osawa, Toshiji Mukai, Alok Singh, Kota Washio, Akira Kato
-
Publication number: 20150080998Abstract: A magnesium alloy and to a method for the production thereof and implants made thereof. The magnesium alloy includes up to 6.0% by weight Zn, and preferably 2.0 to 4.0% by weight Zn, 2.0 to 10.0% by weight Al, and preferably 3.0 to 6.0% by weight Al, where % by weight Al?% by weight Zn shall apply, the remainder being magnesium containing impurities, which promote electrochemical potential differences and/or the formation of precipitations and/or intermetallic phases, in a total amount of no more than 0.0063% by weight of Fe, Si, Mn, Co, Ni, Cu, Zr, Y, Sc or rare earths having the ordinal numbers 21, 57 to 71 and 89 to 103, Be, Cd, In, Sn and/or Pb as well as P, and the matrix of the alloy is solid solution hardening due to Al and An and is also particle hardening due to the intermetallic phases formed of Mg and Al.Type: ApplicationFiled: June 24, 2013Publication date: March 19, 2015Inventors: Heinz Mueller, Peter Uggowitzer, Joerg Loeffler
-
Publication number: 20150047756Abstract: Provided is an Mg alloy and a method for producing same able to demonstrate high strength without requiring an expensive rare earth element (RE). The high-strength Mg alloy containing Ca and Zn within a solid solubility limit and the remainder having a chemical composition comprising Mg and unavoidable impurities is characterized in comprising equiaxial crystal particles, there being a segregated area of Ca and Zn along the (c) axis of a Mg hexagonal lattice within the crystal particle, and having a structure in which the segregated area is lined up by Mg3 atomic spacing in the (a) axis of the Mg hexagonal lattice. The method for producing the high-strength Mg alloy is characterized in that Ca and Zn are added to Mg in a compounding amount corresponding to the above composition and, after homogenization heat treating an ingot formed by dissolution and casting, the above structure is formed by subjecting the ingot to hot processing.Type: ApplicationFiled: November 6, 2012Publication date: February 19, 2015Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, NATIONAL UNIVERSITY CORPORATION KOBE UNIVERSITY, NATIONAL INSITITUTE FOR MATERIALS SCIENCEInventors: Kota Washio, Akira Kato, Toshiji Mukai, Alok Singh, Hidetoshi Somekawa
-
Publication number: 20150000800Abstract: The invention belongs to magnesium alloy design field, and relates to a low-cost high-plasticity wrought magnesium alloy. The magnesium alloy is made from the raw materials with components as follows: between 0.10% and 1.00% by mass of tin, between 0.10% and 3.00% by mass of aluminum, between 0.10% and 1.00% by mass of manganese, and commercially pure magnesium and inevitable impurities in balance. The magnesium alloy is prepared by the steps of: melting magnesium and aluminum, adding tin and then adding microalloyed element manganese, stirring, refining, casting to form ingots followed by homogenized heat treatment, and extruding to obtain a corresponding profile; or directly extruding to obtain a corresponding profile without homogenization. The invention is characterized by controlling the content of the high-cost raw material tin through using the raw material aluminum that is low in cost and low in melting point to obtain a low-cost high-plasticity wrought magnesium alloy.Type: ApplicationFiled: May 23, 2014Publication date: January 1, 2015Applicant: Chongqing UniversityInventors: Fusheng PAN, Jia SHE, Aitao TANG, Jian PENG, Xianhua CHEN
-
Publication number: 20140373982Abstract: The present invention discloses a magnesium alloy sheet with low Gd content and high ductility and its hot rolling technology, which belongs to the field of metal material technology. The chemical components of the magnesium alloy sheet, based on the mass percent, take up respectively: 0.9˜2.1% as Zn, 0.2˜0.8% as rare earth element, namely Gd, 0˜0.9% as Mn, and the rest as Mg. The magnesium alloy sheet of the present invention is added with relatively lower rare earth element, Gd, which reduces the alloy costs; in addition, magnesium alloy has good rolling performance, which can realize continuous, multi-pass and large-deformation rolling, and also ensure the sheets rolled have non-basal texture and high room-temperature elongation which reaches 35˜50%, wherein the elongation, ?, in the rolling direction is no less than 35% and that in the horizontal direction no less than 45%.Type: ApplicationFiled: August 2, 2013Publication date: December 25, 2014Applicant: Institute of Metal Research Chinese Academy of SciencesInventors: Rongshi Chen, Hong Yan, Enhou Han, Wei Ke
-
Patent number: 8906293Abstract: An object of the invention is to provide a magnesium alloy having high strength and sufficient formability. A magnesium alloy mainly contains magnesium and has high tensile strength and high compression strength. The crystal grain structure of the alloy has a high angle grain boundary, and the inside of the crystal grain surrounded by the high angle grain boundary is composed of subgrains.Type: GrantFiled: October 2, 2008Date of Patent: December 9, 2014Assignee: National Institute for Materials ScienceInventors: Toshiji Mukai, Hidetoshi Somekawa, Tadanobu Inoue, Alok Singh
-
Publication number: 20140332121Abstract: A magnesium alloy having high ductility and high toughness, and a preparation method thereof are provided, in which the magnesium alloy includes 1.0-3.5 wt % of tin, 0.05-3.0 wt % of zinc, and the balance of magnesium and inevitable impurities, and a preparation method thereof. Magnesium alloy with a relatively small tin content is added with zinc, and optionally, with one or more alloy elements selected from aluminum, manganese and rare earth metal, at a predetermined content ratio. As a result, the alloy exhibits superior ductility and moderate strength due to the suppression of excessive formation of precipitates and some precipitates hardening effect, respectively. Accordingly, compared to extruded material prepared from conventional commercial magnesium alloys, higher ductility and toughness are provided, so that the alloy can be widely applied over the entire industries including automotive and aerospace industries.Type: ApplicationFiled: July 25, 2014Publication date: November 13, 2014Applicant: KOREA INSTITUTE OF MACHINERY AND MATERIALSInventors: Sung Hyuk Park, Young Min Kim, Ha-Sik Kim, Bong Sun You, Chang Dong Yim
-
Patent number: 8840736Abstract: An endoprosthesis, in particular an intraluminal endoprosthesis such as a stent, includes a carrier structure, which includes at least one component containing a magnesium alloy of the following composition: Magnesium: between about 60.0 and about 88.0% by weight Rare earth metals: between about 2.0 and about 30.0% by weight Yttrium: between about 2.0% and about 20.0% by weight Zirconium: between about 0.5% and about 5.0% by weight Balance: between 0 and about 10.0% by weight wherein the alloy components add up to 100% by weight.Type: GrantFiled: September 7, 2005Date of Patent: September 23, 2014Assignee: Biotronik VI Patent AGInventors: Claus Harder, Marc Kuttler, Bodo Gerold
-
Patent number: 8815148Abstract: Multi-component magnesium-based alloy consisting essentially of about 1.0-15.0 wt. % of scandium, about 0.1-3.0 wt. % of yttrium, about 1.0-3.0 wt. % of rare-earth metal, about 0.1-0.5 wt. % of zirconium. Purity degree of magnesium base is not less of 99.995 wt. %. Impurities of Fe, Ni and Cu do not exceed 0.001 wt. % of everyone, the contents of other impurity in an alloy does not exceed 0.005 wt. %. The alloy demonstrates an improved combination of strength, deformability and corrosion resistance at room temperature. The alloy does not contain harmful and toxic impurities. The alloy can be used in the various practical applications demanding a combination of high strength, deformability and corrosion resistance, preferably in the field of medicine.Type: GrantFiled: March 15, 2007Date of Patent: August 26, 2014Assignee: Acrostak Corp. BVIInventors: Youri Popowski, Igor Isakovich Papirov, Vladimir Sergeevitch Shokurov, Anatoliy Ivanovitch Pikalov, Sergey Vladimirovitch Sivtsov
-
Publication number: 20140212324Abstract: Provided by the present invention are a fine crystallite high-function metal alloy member, a method for manufacturing the same, and a business development method thereof, in which a crystallite of a metal alloy including a high-purity metal alloy whose crystal lattice is a face-centered cubic lattice, a body-centered cubic lattice, or a close-packed hexagonal lattice is made fine with the size in the level of nanometers (10?9 m to 10?6 m) and micrometers (10?6 m to 10?3 m), and the form thereof is adjusted, thereby remedying drawbacks thereof and enhancing various characteristics without losing superior characteristics owned by the alloy.Type: ApplicationFiled: April 10, 2012Publication date: July 31, 2014Applicant: THREE-O CO., LTD.Inventor: Kazuo Ogasa
-
Patent number: 8790497Abstract: A process for treating the surface of magnesium alloy comprises providing a substrate made of magnesium alloy. The substrate is then treated with a chemical conversion treatment agent containing ammonium dihydrogen phosphate and potassium permanganate, to form a chemical conversion film on the substrate. A ceramic coating is then formed on the chemical conversion film using vacuum sputtering.Type: GrantFiled: July 22, 2011Date of Patent: July 29, 2014Assignees: Hong Fu Jin Precision Industry (ShenZhen) Co., Ltd., Hon Hai Precision Industry Co., Ltd.Inventors: Hsin-Pei Chang, Wen-Rong Chen, Huann-Wu Chiang, Cheng-Shi Chen, Dun Mao