Magnesium Base Patents (Class 148/420)
  • Patent number: 8791005
    Abstract: A structure formed in an opening having a substantially vertical sidewall defined by a non-metallic material and having a substantially horizontal bottom defined by a conductive pad, the structure including a diffusion barrier covering the sidewall and a fill composed of conductive material.
    Type: Grant
    Filed: June 18, 2012
    Date of Patent: July 29, 2014
    Assignee: International Business Machines Corporation
    Inventors: Mukta G. Farooq, John A. Fitzsimmons, Troy L. Graves-Abe
  • Patent number: 8784579
    Abstract: A process of grain refining magnesium metal or magnesium based alloy including the step of a) providing a melt of the magnesium metal or magnesium based alloy, said melt including a grain refining agent in an amount effective to induce grain refinement of said magnesium or magnesium based alloy upon solidification, wherein the grain refining agent is vanadium metal, where said grain refinement comprises a reduction in average grain size of at least 50% (percent) as compared with the average grain size without addition of said grain refining agent.
    Type: Grant
    Filed: April 20, 2009
    Date of Patent: July 22, 2014
    Inventor: Joka Buha
  • Publication number: 20140186207
    Abstract: According to one embodiment of the present invention, a cast alloy material is provided. The cast alloy material includes a matrix metal and an alloy element, wherein oxide particles in a nanometer scale are decomposed in the matrix metal, so that a new phase including a metal element that is a component of the oxide particles and the alloy element forms a band or network structure, wherein the metal element and the alloy element have a relationship of a negative heat of mixing, and wherein oxygen atoms formed by decomposition of the oxide particles are dispersed in the matrix metal and do not form an oxide with the matrix metal.
    Type: Application
    Filed: June 22, 2012
    Publication date: July 3, 2014
    Applicant: INDUSTRY-ACADEMIC COOPERATION FOUNDATION, YONSEI UNIVERSITY
    Inventors: Dong Hyun Bae, Hun Kang
  • Patent number: 8734564
    Abstract: Provided are a magnesium-based alloy and a manufacturing method thereof. In the method, a magnesium alloy is melted into liquid phase, and an alkaline earth metal oxide is added into a molten magnesium alloy. The alkaline earth metal oxide is exhausted through surface reduction reaction between the melt and the alkaline earth metal oxide. Alkaline earth metal produced by the exhaustion reacts with Mg and/or other alloying elements in the magnesium alloy so that an intermetallic compound is formed. The magnesium prepared by the method is excellent in fluidity and hot-tearing resistance. To this end, the alkaline earth metal oxide added is CaO, and the added amount of CaO is 1.4 to 1.7 times the target weight of Ca to be contained in the final Mg alloy.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: May 27, 2014
    Assignee: Korea Institute of Industrial Technology
    Inventors: Shae K. Kim, Jung-Ho Seo
  • Publication number: 20140116580
    Abstract: Disclosed are a magnesium (Mg) alloy and a manufacturing method thereof. The Mg alloy has a composition including, by weight, 4% to 10% of Sn, 0.05% to 1.0% of Ca, 0.1% to 2% of at least one element selected from the group including Y and Er, the balance of Mg, and the other unavoidable impurities. The Mg alloy includes an Mg2Sn phase having excellent thermal stability, and is capable of being heat treated at a temperature of 480° C. or more.
    Type: Application
    Filed: February 1, 2013
    Publication date: May 1, 2014
    Applicant: KOREA INSTITUTE OF MACHINERY & MATERIALS
    Inventors: Young Min Kim, Ha Sik Kim, Bong Sun You, Chang Dong Yim, Sung Hyuk Park
  • Patent number: 8657973
    Abstract: Magnesium-based alloy wire excelling in strength and toughness, its method of manufacture, and springs in which the magnesium-based alloy wire is utilized are made available. The magnesium-based alloy wire contains, in mass %, 0.1 to 12.0% Al, and 0.1 to 1.0% Mn, and is provided with the following constitution. Diameter d that is 0.1 mm or more and 10.0 mm or less; length L that is 1000d or more; tensile strength that is 250 MPa or more; necking-down rate that is 15% or more; and elongation that is 6% or more. Such wire is produced by draw-forming it at a working temperature of 50° C. or more, and by heating it to a temperature of 100° C. or more and 300° C. or less after the drawing process has been performed.
    Type: Grant
    Filed: October 2, 2012
    Date of Patent: February 25, 2014
    Assignees: Sumitomo Electric Industries, Ltd., Sumitomo (SEI) Steel Wire Corp.
    Inventors: Yukihiro Oishi, Nozomu Kawabe
  • Patent number: 8636853
    Abstract: An Mg alloy provided with high strength and high ductility by matching the strength and ductility in tensile deformation and compressive deformation at the same levels is provided. The Mg alloy of the present invention is characterized by having a chemical composition consisting of Y: 0.1 to 1.5 at % and a balance of Mg and unavoidable impurities and having a microstructure with high Y regions with Y concentrations higher than an average Y concentration distributed at nanometer order sizes and intervals. The present invention further provides an Mg alloy characterized by having a chemical composition consisting of Y: more than 0.1 at % and a valance of Mg and unavoidable impurities, having a microstructure with high Y regions with Y concentrations higher than an average Y concentration distributed at nanometer order sizes and intervals and having an average recrystallized grain size within the range satisfying the following formula 1: ?0.87c+1.10<log d<1.14c+1.
    Type: Grant
    Filed: March 26, 2008
    Date of Patent: January 28, 2014
    Assignees: Toyota Jidosha Kabushiki Kaisha, National Institute for Materials Science
    Inventors: Tetsuya Shoji, Akira Kato, Toshiji Mukai, Hidetoshi Somekawa
  • Patent number: 8632326
    Abstract: A device for manufacturing finely powdered spherical magnesium includes a gas compressor that compresses argon gas, a gas heating unit that heats the compressed argon gas, and a tundish that receives molten magnesium. The device further includes a reactor having a nozzle injection unit that injects heated argon gas into the reactor, a recovery unit that recovers magnesium powder produced in the reactor, and a first gas cooler that cools the argon gas passing through the recovery unit. The device further includes a filtering unit that filters the cooled argon gas, a buffer tank that receives the filtered argon gas, and a compression blower that adiabatically compresses the argon gas. The device further includes a second gas cooler that cools the compressed argon gas, an adiabatic expansion duct that adiabatically expands the cooled argon gas, supplies the expanded argon gas to the reactor, and cools the magnesium powder.
    Type: Grant
    Filed: May 25, 2011
    Date of Patent: January 21, 2014
    Inventor: Kyu Yeub Yeon
  • Publication number: 20130333809
    Abstract: There are provided a magnesium alloy material and a method for producing the magnesium alloy material. In a magnesium (Mg) alloy material (e.g., Mg alloy sheet) having a sheet-shaped portion with a thickness of 1.5 mm or more, when a region having ¼ the thickness of the sheet-shaped portion in a thickness direction from a surface of the sheet-shaped portion is defined as a surface region and a remaining region is defined as an internal region, the ratio OF/OC of the basal plane peak ratio OF in the surface region to the basal plane peak ratio OC (degree of orientation of (002) planes) in the internal region satisfies 1.05<OF/OC. A sheet-shaped Mg alloy material is obtained by performing rolling on a twin-roll continuous cast material with multiple passes at a reduction ratio of each pass of 25% or less.
    Type: Application
    Filed: February 23, 2012
    Publication date: December 19, 2013
    Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Yukihiro Oishi, Nobuyuki Mori, Ryuichi Inoue, Nozomu Kawabe
  • Patent number: 8591674
    Abstract: A method of enhancing the ductility of magnesium alloy sheets containing 85% or more by weight of magnesium is described. An annealed, substantially strain free, sheet of generally uniform grain size is locally deformed in local regions to develop strained ‘islands’ of a predetermined strain embedded in a substantially strain-free matrix and then annealed. The deformed regions undergo recrystallization and grain growth while the remainder of the sheet suffers only minor change in grain size, leading to sheet with grains having a bimodal size distribution. The ductility of alloys processed in this way is significantly greater than the ductility of the unprocessed, uniform grain size alloy without compromise to the tensile strength of the alloy.
    Type: Grant
    Filed: November 11, 2011
    Date of Patent: November 26, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Sushil Kumar Mishra, Shashank Tiwari, Asim Tewari, Jon T. Carter, Deepika Sachdeva
  • Publication number: 20130220496
    Abstract: Provided are a magnesium alloy sheet having excellent corrosion resistance and a method for producing the same. The magnesium alloy sheet has dispersed therein particles of an intermetallic compound containing an additive element (e.g., Al) and Mg (a typical example of which is Mg17Al12), and the ratio obtained by dividing the diffraction intensity of the main diffraction plane (4,1,1) of the intermetallic compound by the diffraction intensity of the c plane (0,0,2) of the Mg alloy phase in an XRD analysis of the surface of the sheet is 0.040 or more. The method for producing a magnesium alloy sheet includes the following steps: a casting step of producing a cast material composed of a magnesium alloy containing an additive element by continuous casting; a heat treatment step of holding the cast material at 400° C. or higher and then cooling the cast material at a cooling rate of 30° C.
    Type: Application
    Filed: November 8, 2011
    Publication date: August 29, 2013
    Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Ryuichi Inoue, Kohji Inokuchi, Yukihiro Oishi, Nozomu Kawabe
  • Patent number: 8475608
    Abstract: Magnesium-based hydrogen storage alloys having metallic magnesium (Mg) and a magnesium-containing intermetallic compound (MgxMy wherein y is 1?x) and containing not less than 60 mass-% of magnesium in total, and having a phase of a primarily crystallized magnesium-containing intermetallic compound in its solidification structure.
    Type: Grant
    Filed: November 25, 2005
    Date of Patent: July 2, 2013
    Assignee: Japan Metals and Chemicals Co., Ltd.
    Inventors: Masahito Osawa, Hidenori Tomioka, Naoyoshi Terashita, Noboru Hayami, Shigeru Tsunokake
  • Publication number: 20130118657
    Abstract: A method of enhancing the ductility of magnesium alloy sheets containing 85% or more by weight of magnesium is described. An annealed, substantially strain free, sheet of generally uniform grain size is locally deformed in local regions to develop strained ‘islands’ of a predetermined strain embedded in a substantially strain-free matrix and then annealed. The deformed regions undergo recrystallization and grain growth while the remainder of the sheet suffers only minor change in grain size, leading to sheet with grains having a bimodal size distribution. The ductility of alloys processed in this way is significantly greater than the ductility of the unprocessed, uniform grain size alloy without compromise to the tensile strength of the alloy.
    Type: Application
    Filed: November 11, 2011
    Publication date: May 16, 2013
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Sushil Kumar Mishra, Shashank Tiwari, Asim Tewari, Jon T. Carter, Deepika Sachdeva
  • Publication number: 20130029180
    Abstract: Magnesium-based alloy wire excelling in strength and toughness, its method of manufacture, and springs in which the magnesium-based alloy wire is utilized are made available. The magnesium-based alloy wire contains, in mass %, 0.1 to 12.0% Al, and 0.1 to 1.0% Mn, and is provided with the following constitution. Diameter d that is 0.1 mm or more and 10.0 mm or less; length L that is 1000d or more; tensile strength that is 250 MPa or more; necking-down rate that is 15% or more; and elongation that is 6% or more. Such wire is produced by draw-forming it at a working temperature of 50° C. or more, and by heating it to a temperature of 100° C. or more and 300° C. or less after the drawing process has been performed.
    Type: Application
    Filed: October 2, 2012
    Publication date: January 31, 2013
    Applicants: SUMITOMO (SEI) STEEL WIRE CORP., SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Sumitomo Electric Industries, Ltd., Sumitomo (SEI) Steel Wire Corp.
  • Patent number: 8333924
    Abstract: Provided is a high-strength and high-toughness magnesium alloy which has practical level of both the strength and the toughness for expanded applications of the magnesium alloys, and is a method for manufacturing thereof. The high-strength and high-toughness magnesium alloy of the present invention contains: a atom % in total of at least one metal of Cu, Ni, and Co; and b atom % in total of at least one element selected from the group consisting of Y, Dy, Er, Ho, Gd, Tb, and Tm, while a and b satisfying the following formulae (1) to (3), 0.2?a?10??(1) 0.2?b?10??(2) 2/3a?2/3<b.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: December 18, 2012
    Assignees: National University Corporation Kumamoto University, Chiba University
    Inventors: Yoshihito Kawamura, Michiaki Yamasaki, Takaomi Itoi, Mitsuji Hirohashi
  • Patent number: 8329094
    Abstract: A magnesium alloy having excellent strength and elongation at high temperatures and further having excellent creep characteristics at high temperatures. Also provided is a process for producing the alloy. In producing the magnesium alloy, a magnesium alloy containing yttrium and samarium in respective specific amounts is cast and the resultant cast is subjected to a solution heat treatment, subsequently hot working, and then an aging treatment, thereby reducing the average crystal grain diameter of the structure. In addition, the amounts of the yttrium and samarium in solution in the magnesium matrix are balanced with the number of precipitate particles of a specific size in the crystal grains. The magnesium alloy thus obtained has excellent strength and elongation at high temperatures and further having excellent creep characteristics at high temperatures.
    Type: Grant
    Filed: March 30, 2009
    Date of Patent: December 11, 2012
    Assignee: Kobe Steel, Ltd.
    Inventors: Toshiaki Takagi, Mamoru Nagao
  • Patent number: 8308878
    Abstract: Magnesium-based alloy wire excelling in strength and toughness, its method of manufacture, and springs in which the magnesium-based alloy wire is utilized are made available. The magnesium-based alloy wire contains, in mass %, 0.1 to 12.0% Al, and 0.1 to 1.0% Mn, and is provided with the following constitution. Diameter d that is 0.1 mm or more and 10.0 mm or less; length L that is 1000 d or more; tensile strength that is 250 MPa or more; necking-down rate that is 15% or more; and elongation that is 6% or more. Such wire is produced by draw-forming it at a working temperature of 50° C. or more, and by heating it to a temperature of 100° C. or more and 300° C. or less after the drawing process has been performed.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: November 13, 2012
    Assignees: Sumitomo Electric Industries, Ltd., Sumitomo (SEI) Steel Wire Corp.
    Inventors: Yukihiro Oishi, Nozomu Kawabe
  • Patent number: 8293031
    Abstract: A magnesium alloy, comprising: Y: 0.5-10? Zn: 0.5-6?? Ca: 0.05-1?? Mn: ??0-0.5 Ag: 0-1 Ce: 0-1 Zr: 0-1 or Si: 0-0.4, wherein the amounts are based on weight-percent of the alloy and Mg, and manufacturing-related impurities constitute the remainder of the alloy to a total of 100 weight-percent. Also disclosed is a method for manufacturing such an alloy and a biodegradable implant formed therefrom.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: October 23, 2012
    Assignee: Biotronik VI Patent AG
    Inventors: Bodo Gerold, Heinz Mueller, Joerg Loeffler, Anja Haenzi, Peter Uggowitzer
  • Patent number: 8268235
    Abstract: An implant consisting entirely or in part of a biocorrodible magnesium alloy having the composition Gd: 2.7-15.0 wt %, Zn: 0-0.5 wt %, Zr: 0.2-1.0 wt %, Nd: 0-4.5 wt %, Y: 0-2.0 wt %, where magnesium and impurities due to the production process account for the remainder to a total of 100 wt %.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: September 18, 2012
    Assignee: Biotronik VI Patent AG
    Inventor: Bodo Gerold
  • Publication number: 20120227868
    Abstract: The present invention provides a very lightweight magnesium-lithium alloy which has both corrosion resistance and cold workability balanced at high levels, a certain degree of tensile strength, low surface electrical resistivity, as well as a rolled material and a formed article made of the alloy, and a method of producing the alloy, by means of a magnesium-lithium alloy containing not less than 10.5 mass % and not more than 16.0 mass % Li, not less than 0.50 mass % and not more than 1.50 mass % Al, and the balance of Mg, and having an average crystal grain size of not smaller than 5 ?m and not larger than 40 ?m, a tensile strength of not lower than 150 MPa, and a surface electrical resistivity of not higher than 1? as measured with an ammeter by pressing a cylindrical two-point probe with a pin-to-pin spacing of 10 mm and a pin tip diameter of 2 mm (contact surface area of one pin is 3.14 mm2), against an alloy surface at a load of 240 g.
    Type: Application
    Filed: September 10, 2010
    Publication date: September 13, 2012
    Applicant: SANTOKU CORPORATION
    Inventors: Kenki Kin, Takeki Matsumura, Shinji Namba, Shinichi Umino, Takayuki Goto
  • Publication number: 20120222784
    Abstract: The present invention provides a magnesium-lithium alloy having both corrosion resistance and cold workability balanced at high levels, a certain degree of tensile strength, and very light weight, as well as a rolled material and a formed article made of this alloy. The alloy of the invention contains not less than 10.5 mass % and not more than 16.0 mass % Li, not less than 0.50 mass % and not more than 1.50 mass % Al, and the balance of Mg, and has an average crystal grain size of not smaller than 5 ?m and not larger than 40 ?m, and a tensile strength of not lower than 150 MPa or a Vickers hardness (HV) of not lower than 50.
    Type: Application
    Filed: December 25, 2009
    Publication date: September 6, 2012
    Applicant: SANTOKU CORPORATION
    Inventors: Kenki Kin, Takeki Matsumura, Shinji Namba, Shinichi Umino, Takayuki Goto, Yuji Tanibuchi, Yukihiro Yokoyama
  • Patent number: 8211247
    Abstract: Compositions, apparatus incorporating a composition, and methods of use are described, one composition embodiment consisting essentially of one or more reactive metals in major proportion, and one or more alloying elements in minor proportion, with the provisos that the composition is high-strength, controllably reactive, and degradable under defined conditions. Compositions of the invention may exist in a variety of morphologies, including a reactive metal or degradable alloy processed into an alloy of crystalline, amorphous or mixed structure that may constitute the matrix of other composition, for instance a composite. Methods of using apparatus comprising a composition, particularly in oilfield operations are also described (e.g. flow and displacement control, sensors, actuators). This abstract allows a searcher or other reader to quickly ascertain the subject matter of the disclosure. It will not be used to interpret or limit the scope or meaning of the claims. 37 CFR 1.72(b).
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: July 3, 2012
    Assignee: Schlumberger Technology Corporation
    Inventors: Manuel P. Marya, Rashmi B. Bhavsar, Gary L. Rytlewski
  • Patent number: 8211331
    Abstract: A packaged reactive material includes a reactive material that is configured to increase in size when exposed to a predetermined gas, and an inert coating material surrounding a surface of the reactive material. The inert coating material is configured to allow the predetermined gas to diffuse through to the reactive material and has an elongation that will not accommodate expansion of the reactive material at full saturation of the predetermined gas.
    Type: Grant
    Filed: June 2, 2010
    Date of Patent: July 3, 2012
    Assignee: GM Global Technology Operations LLC
    Inventors: Scott W. Jorgensen, Martin P. Sulic
  • Publication number: 20120125487
    Abstract: A surface treatment method of a magnesium alloy article includes, instead of forming a primer on a magnesium alloy based composite first, directly performing a hairline finish process on the magnesium alloy based composite, to form a hairline structure on a surface of the magnesium alloy based composite, and performing a chemical oxidation process on the magnesium alloy based composite, to form a glossy film covering the hairline structure on the magnesium alloy based composite, thereby forming a magnesium alloy article structure. Alternatively, another chemical oxidation process is performed before the hairline finish process, to form an oxide film on the surface of the magnesium alloy based composite.
    Type: Application
    Filed: September 25, 2011
    Publication date: May 24, 2012
    Applicant: GETAC TECHNOLOGY CORPORATION
    Inventor: Chun-Hsiang CHEN
  • Patent number: 8123877
    Abstract: A heat-resistant magnesium alloy is for casting, and includes Ca in an amount of from 1 to 15% by mass, Al in a summed amount of from 4 to 25% by mass with the amount of Ca, and the balance being Mg and inevitable impurities when the entirety is taken as 100% by mass. The heat-resistant magnesium alloy is not only inexpensive, but also effects an advantage that cracks are inhibited from occurring when being cast. For example, a process for producing heat-resistant magnesium alloy cast product includes the step of pressure pouring an alloy molten metal, which has a target composition around Mg—3% Ca—3% Al—from 0.2 to 0.3% Mn, into a cavity of metallic die, which is preheated to a die temperature of from 130 to 140° C. in advance. The process makes it possible to produce die-cast products, which are free from cast cracks.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: February 28, 2012
    Assignee: Kabushiki Kaisha Toyota Jidoshokki
    Inventors: Motoharu Tanizawa, Kyoichi Kinoshita, Eiji Kishi, Katsufumi Tanaka, Yuki Okamoto, Takayuki Kato
  • Publication number: 20110315282
    Abstract: The quasicrystal phase and/or quasicrystal-like phase particles, which is composed of the Mg—Zn—Al, are dispersed into Mg-base alloy material for strain working. The microstructure in this material does not include the dendrite structure, and the size of the magnesium matrix is 40 ?m or less than 40 ?m. The present invention shows that the quasicrystal phase and/or quasicrystal-like phase is able to form by addition of the Zn and Al elements except for the use of rare earth elements. In addition, the excellent trade-off-balancing between strength and ductility and reduction of the yield anisotropy, which are the serious issues for the wrought processed magnesium alloys, is able to obtain by the microstructure controls before the strain working process.
    Type: Application
    Filed: January 19, 2010
    Publication date: December 29, 2011
    Inventors: Hidetoshi Somekawa, Yoshiaki Osawa, Alok Singh, Toshiji Mukai
  • Patent number: 8062439
    Abstract: A magnesium alloy sheet having an adequate strength and an excellent bendability is provided along with a method of manufacturing such an alloy sheet. The method comprises, rolling a magnesium alloy sheet through a reduction roll, the alloy thereof containing about 0.1-10.0 mass % of Al and about 0.1-4.0 mass % of Zn, wherein the magnesium alloy sheet has a surface temperature of about 100° C. or below at the time just before it is fed in the reduction roll, and the reduction roll has a surface temperature in the range of about 100° C. to 300° C. Particularly, when executing multipass rolling, at least the last pass is accomplished in non-preheat rolling wherein the magnesium alloy sheet and the reduction roll have specified surface temperatures, respectively.
    Type: Grant
    Filed: June 3, 2003
    Date of Patent: November 22, 2011
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Kenichi Shimizu, Nozomu Kawabe, Akira Kishimoto
  • Publication number: 20110220251
    Abstract: A magnesium alloy according to the present invention comprises: Al in an amount of from 2 to 6%; Ca in an amount making a compositional ratio (i.e., Ca/Al) being from 0.5 to 1.5; Mn in an amount of from 0.1 to 0.7%; strontium (Sr) in an amount of from 1 to 6%; and the balance being magnesium (Mg), and inevitable impurities and/or a modifying element; when the entirety is taken as 100% by mass. By means of this setting, Mg alloys, which are also good in terms of high-temperature characteristics, such as creep resistance and heat conductivity, in addition to ordinary-temperature characteristics, are obtained.
    Type: Application
    Filed: November 6, 2009
    Publication date: September 15, 2011
    Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventors: Yuki Okamoto, Kyoichi Kinoshita, Motoharu Tanizawa, Hiroya Akatsuka
  • Patent number: 8016957
    Abstract: The grain size of magnesium alloys is effectively refined and made smaller by the addition of a small amount of titanium. The effect of the reduction of grain size is often an improvement in the strength and processability of a cast magnesium alloy. Often less than about 0.1% by weight of titanium need be used. It may be preferred to incorporate the titanium with another alloying constituent (such as aluminum) for addition to a melt of a magnesium base alloy.
    Type: Grant
    Filed: February 3, 2006
    Date of Patent: September 13, 2011
    Assignee: GM Global Technology Operations LLC
    Inventors: Xiaoqin Zeng, Yingxin Wang, Wenjiang Ding, Aihua A. Luo
  • Patent number: 8012452
    Abstract: The invention relates to a method for preparation of a material adapted to reversible storage of hydrogen, including steps consisting of providing a first powder of a magnesium-based material, hydrogenating the first powder to convert at least part of the first powder into metal hydrides, mixing the first hydrogenating powder with a second powder additive, the proportion by mass of the second powder in the mix obtained being between 1% and 20% by mass, wherein the additive is formed from an alloy with a centred cubic structure based on titatnium, vanadium and at least one other metal chosen from chromium or manganese, and grinding the mix of first and second powders.
    Type: Grant
    Filed: April 25, 2007
    Date of Patent: September 6, 2011
    Assignee: Centre National de la Recherche Scientifique
    Inventors: Daniel Fruchart, Patricia De Rango, Jean Charbonnier, Salvatore Miraglia, Sophie Rivoirard, Nataliya Skryabina, Michel Jehan
  • Publication number: 20110203706
    Abstract: A formed product of a magnesium alloy having excellent impact resistance and a magnesium alloy sheet suitable as a material for the formed product are provided. The formed product is produced by press-forming a magnesium alloy sheet having an Al content of 7% by mass to 12% by mass and has a flat portion that is not subjected to drawing deformation. In a metal texture in a cross section of the flat portion in the thickness direction, the number of coarse intermetallic compound (Mg17Al12) particles having a particle size of 5 ?m or more present in a surface area region extending from a surface of the flat portion to a position one-third of the thickness from the surface in the thickness direction is five or less. The formed product has a texture in which the number of coarse precipitations d1 is small and in which fine precipitations d0 are dispersed.
    Type: Application
    Filed: September 29, 2009
    Publication date: August 25, 2011
    Inventors: Yukihiro Oishi, Nozomu Kawabe, Nobuyuki Okuda, Nobuyuki Mori, Masatada Numano, Koji Mori, Takahiko Kitamura, Ryuichi Inoue
  • Patent number: 7955447
    Abstract: A glassy metal composite material includes: a Mg-based amorphous metal matrix; and a plurality of porous metal particles dispersed in the Mg-based amorphous metal matrix. The Mg-based amorphous metal matrix penetrates into pores in the porous metal particles. The porous metal particles have a hardness less than that of the Mg-based amorphous metal matrix.
    Type: Grant
    Filed: July 22, 2008
    Date of Patent: June 7, 2011
    Assignee: I Shou University
    Inventors: Shian-Ching Jang, Chih-Ching Huang, Chih-Chiang Fu, Jia-Yu Ciou, Liang-Jan Chang
  • Patent number: 7942986
    Abstract: A magnesium-based alloy consists of 1.5-4.0% by weight rare earth element(s), 0.3-0.8% by weight zinc, 0.02-0.1% by weight aluminium, and 4-25 ppm beryllium. The alloy optionally contains up to 0.2% by weight zirconium, 0.3% by weight manganese, 0.5% by weight yttrium and 0.1% by weight calcium. The remainder of the alloy is magnesium except for incidental impurities.
    Type: Grant
    Filed: August 21, 2009
    Date of Patent: May 17, 2011
    Assignee: Cast Centre Pty Ltd
    Inventors: Colleen Joyce Bettles, Mark Antony Gibson
  • Patent number: 7935304
    Abstract: This invention relates to magnesium-based alloys particularly suitable for casting applications where good mechanical properties at room and at elevated temperatures are required. The alloys contain: 2 to 4.5% by weight of neodymium; 0.2 to 7.0% of at least one rare earth metal of atomic No. 62 to 71; up to 1.3% by weight of zinc; and 0.2 to 0.7% by weight of zirconium; optionally with one or more other minor component. They are resistant to corrosion, show good age-hardening behaviour, and are also suitable for extrusion and wrought alloy applications.
    Type: Grant
    Filed: October 8, 2004
    Date of Patent: May 3, 2011
    Assignee: Magnesium Electron Ltd.
    Inventors: Paul Lyon, John King, Hossein Karimzadeh, Ismet Syed
  • Patent number: 7922967
    Abstract: A high-strength and high-toughness magnesium based alloy contains, by weight, 1 to 8% rare earth element and 1 to 6% calcium and the maximum crystal grain diameter of magnesium constituting a matrix is not more than 30 ?m. At least one intermetallic compound (6) of rare earth element and calcium has a maximum grain diameter of 20 ?m or less and it is dispersed in a crystal grain boundary (5) and a crystal grain (4) of magnesium of the matrix.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: April 12, 2011
    Assignee: Toudai TLD, Ltd.
    Inventor: Katsuyoshi Kondoh
  • Publication number: 20110036466
    Abstract: A process of grain refining magnesium metal or magnesium based alloy including the step of a) providing a melt of the magnesium metal or magnesium based alloy, said melt including a grain refining agent in an amount effective to induce grain refinement of said magnesium or magnesium based alloy upon solidification, wherein the grain refining agent is vanadium metal, where said grain refinement comprises a reduction in average grain size of at least 50% (percent) as compared with the average grain size without addition of said grain refining agent.
    Type: Application
    Filed: April 20, 2009
    Publication date: February 17, 2011
    Inventor: JOKA BUHA
  • Publication number: 20110033332
    Abstract: A magnesium alloy material such as a magnesium alloy cast material or a magnesium alloy rolled material, excellent in mechanical characteristics and surface precision, a producing method capable of stably producing such material, a magnesium alloy formed article utilizing the rolled material, and a producing method therefor. The magnesium material includes a melting step of melting a magnesium alloy in a melting furnace to obtain a molten metal, a transfer step of transferring the molten metal from the melting furnace to a molten metal reservoir, and a casting step of supplying a movable mold with the molten metal from the molten metal reservoir, through a pouring gate, and solidifying the molten metal to continuously produce a cast material. Parts are formed by a low-oxygen material having an oxygen content of 20 mass % or less. The cast material is given a thickness of from 0.1 to 10 mm.
    Type: Application
    Filed: October 21, 2010
    Publication date: February 10, 2011
    Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Masatada NUMANO, Yoshihiro NAKAI, Toshiya IKEDA, Taichiro NISHIKAWA
  • Publication number: 20110030855
    Abstract: A method of improving the corrosion resistance of magnesium alloy castings containing more than about 2 per cent by weight of aluminum is described. The method comprises: first selecting a casting process suitable for developing at least on the surface of the casting a microstructure comprising aluminum-depleted magnesium grains surrounded by an aluminum-rich layer and preferably incorporating at least some of an intermetallic compound based on the composition Mg17Al12; and second, heat treating at least the outer layer of the casting to promote additional intermetallic compound precipitation as required.
    Type: Application
    Filed: August 7, 2009
    Publication date: February 10, 2011
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
    Inventors: Mridula D. Bharadwaj, Suresh Sundarraj, Shashank Tiwari, Aihua A. Luo, Deepika Sachdeva
  • Patent number: 7879165
    Abstract: The present invention provides a method for producing a magnesium alloy sheet capable of producing a magnesium alloy sheet having excellent plastic workability such as press workability. The method of the present invention includes rolling a magnesium alloy blank with a reduction roll. The rolling includes controlled rolling performed under the following conditions (1) and (2) wherein M (% by mass) is the Al content in a magnesium alloy constituting the blank: (1) the surface temperature Tb (° C.) of the magnesium alloy blank immediately before insertion into the reduction roll satisfies the following expression: 8.33×M+135?Tb?8.33×M+165 wherein 1.0?M?10.0; and (2) the surface temperature Tr of the reduction roll is 150° C. to 180° C.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: February 1, 2011
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Nobuyuki Mori, Nozomu Kawabe
  • Publication number: 20110017367
    Abstract: A magnesium alloy having excellent strength and elongation at high temperatures and further having excellent creep characteristics at high temperatures. Also provided is a process for producing the alloy. In producing the magnesium alloy, a magnesium alloy containing yttrium and samarium in respective specific amounts is cast and the resultant cast is subjected to a solution heat treatment, subsequently hot working, and then an aging treatment, thereby reducing the average crystal grain diameter of the structure. In addition, the amounts of the yttrium and samarium in solution in the magnesium matrix are balanced with the number of precipitate particles of a specific size in the crystal grains. The magnesium alloy thus obtained has excellent strength and elongation at high temperatures and further having excellent creep characteristics at high temperatures.
    Type: Application
    Filed: March 30, 2009
    Publication date: January 27, 2011
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventors: Toshiaki Takagi, Mamoru Nagao
  • Patent number: 7871537
    Abstract: A method for fabricating a magnesium-based hydrogen storage material according to the present invention comprises a) forming a mixture of a magnesium hydride powder and a transition metal halide powder, b) adding the mixture and balls into a vessel, c) filling the vessel with an inert gas or hydrogen, and d) subjecting the mixture to high energy ball milling.
    Type: Grant
    Filed: November 14, 2007
    Date of Patent: January 18, 2011
    Assignee: Korea Institute of Science and Technology
    Inventors: Jae-Hyeok Shim, Seon-Ah Jin, Young-Whan Cho
  • Patent number: 7871476
    Abstract: A magnesium alloy exhibiting high strength and high ductility, characterized in that it comprises 0.03 to 0.54 atomic % of certain solute atoms belonging to 2 Group, 3 Group or Lanthanoids of the Periodic Table and having an atomic radius larger than that of magnesium and the balanced amount of magnesium, and has a fine crystal grain structure wherein solute atoms having an average crystal grain diameter of 1.5 ?m or less and being unevenly present in the vicinity of crystal grain boundaries at a concentration being 1.5 to 10 times that within crystal grains, wherein an atom selected from the group consisting of Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu can be used as the above solute atom; and a method for producing the magnesium alloy. The above magnesium alloy is novel and achieves high strength and high ductility at the same time.
    Type: Grant
    Filed: June 28, 2005
    Date of Patent: January 18, 2011
    Assignee: National Institute for Materials Science
    Inventors: Toshiji Mukai, Kazuhiro Hono, Hidetoshi Somekawa, Tomoyuki Honma
  • Publication number: 20100242677
    Abstract: Disclosed are cover gas compositions comprising fluoroolefins for impeding the oxidation of molten nonferrous metals and alloys, such as magnesium. The cover gas compositions can include at least one fluoroolefin and a carrier gas.
    Type: Application
    Filed: June 10, 2010
    Publication date: September 30, 2010
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: Matthew H. Luly, Rajiv R. Singh, Robert G. Richard
  • Publication number: 20100206438
    Abstract: The present invention provides a magnesium alloy material excellent in mechanical properties without using specific manufacturing facilities and processes and a method of manufacturing the same. The magnesium alloy material is an Mg—Zn—RE alloy containing, as an essential component, Zn and at least one of Gd, Tb, and Tm as RE, and of the rest including Mg and unavoidable impurities, and has stacking faults of a thickened two-atomic layer of Zn and RE in the alloy structure of the Mg—Zn—RE alloy. A method of manufacturing a magnesium alloy material involves a casting step, a solution treatment step, and a heat treatment step and the heat treatment step is carried out in a condition satisfying ?14.58 [ln(x)]+532.32<y<?54.164 [ln(x)]+674.05 and 0<x?2, wherein y denotes the heat treatment temperature (K) and x denotes the heat treatment time (h).
    Type: Application
    Filed: September 18, 2008
    Publication date: August 19, 2010
    Applicants: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.), Nissan Motor Co., Ltd., NAT. UNIV. CORP. KUMAMOTO UNIV
    Inventors: Mamoru Nakata, Yuuichi Yamada, Koji Itakura, Yoshihito Kawamura, Michiaki Yamasaki
  • Publication number: 20100163141
    Abstract: An Mg alloy provided with high strength and high ductility by matching the strength and ductility in tensile deformation and compressive deformation at the same levels is provided. The Mg alloy of the present invention is characterized by having a chemical composition consisting of Y: 0.1 to 1.5 at % and a balance of Mg and unavoidable impurities and having a microstructure with high Y regions with Y concentrations higher than an average Y concentration distributed at nanometer order sizes and intervals. The present invention further provides an Mg alloy characterized by having a chemical composition consisting of Y: more than 0.1 at % and a valance of Mg and unavoidable impurities, having a microstructure with high Y regions with Y concentrations higher than an average Y concentration distributed at nanometer order sizes and intervals and having an average recrystallized grain size within the range satisfying the following formula 1: ?0.87c+1.10<log d<1.14c+1.
    Type: Application
    Filed: March 26, 2008
    Publication date: July 1, 2010
    Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, National Institute for Materials Science
    Inventors: Tetsuya Shoji, Akira Kato, Toshiji Mukai, Hidetoshi Somekawa
  • Patent number: 7743502
    Abstract: The present invention provides an apparatus including a magnesium alloy vessel that is substantially free of aluminum and zinc, but including magnesium in combination with a gettering metal and a method for making such apparatus. The magnesium alloy vessel has a hollow interior cavity containing a working fluid, with a stable, protective layer formed on the inside wall of the vessel so as to establish non-corrosive compatibility with the working fluid.
    Type: Grant
    Filed: February 28, 2006
    Date of Patent: June 29, 2010
    Assignee: Thermal Corp.
    Inventors: John H. Rosenfeld, G. Yale Eastman
  • Patent number: 7718118
    Abstract: The present invention relates to creep-resistant magnesium-based alloys with low susceptibility to hot tearing, and with improved ductility, impact strength and fracture toughness, and corrosion resistance. The alloys contain at least 96 wt % magnesium, 1.5 to 1.9 wt % neodymium, 0.10 to 0.30 wt % yttrium, 0.35 to 0.70 wt % zirconium, 0.05 to 0.35 wt % zinc, 0.01 to 0.10 wt % calcium, 0.01 to 0.15 wt % strontium, and 0.0000 to 0.0005 wt % beryllium, and they are suitable for low pressure and gravity castings. Articles, that are castings of the alloys, are suitable for applications at temperatures as high as 175-250° C.
    Type: Grant
    Filed: September 22, 2006
    Date of Patent: May 18, 2010
    Assignee: Dead Sea Magnesium Ltd.
    Inventors: Boris Bronfin, Nir Moscovitch, Mark Katzir, Soenke Schumann, Rudolph Boehm
  • Patent number: 7708937
    Abstract: A high-strength, high-toughness, weldable and deformable rare earth magnesium alloy comprised of 0.7˜1.7% of Ym, 5.5˜6.4% of Zn, 0.45˜0.8% of Zr, 0.02% or less of the total amount of impurity elements of Si, Fe, Cu and Ni, and the remainder of Mg, based on the total weight of the alloy. During smelting, Y, Ho, Er, Gd and Zr are added in a manner of Mg—Y-rich, Mg—Zr intermediate alloys into a magnesium melt; Zn is added in a manner of pure Zn, and at 690˜720° C., a round bar was cast by a semi-continuous casting or a water cooled mould, then an extrusion molding was performed at 380˜410° C. after cutting. Before the extrusion, the alloy is treated by the solid-solution treatment at 480˜510° C. for 2˜3 hours, however, the alloy can also be extrusion molded directly without the solid-solution treatment.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: May 4, 2010
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    Inventors: Jian Meng, Daqing Fang, Deping Zhang, Dingxiang Tang, Huayi Lu, Lianshan Zhao, Wei Sun, Xin Qiu, Hongjie Zhang
  • Patent number: 7682470
    Abstract: A magnesium-based alloy consists of 1.5-4.0% by weight rare earth element(s), 0.3-0.8% by weight zinc, 0.02-0.1% by weight aluminum, and 4-25 ppm beryllium. The alloy optionally contains up to 0.2% by weight zirconium, 0.3% by weight manganese, 0.5% by weight yttrium and 0.1% by weight calcium. The remainder of the alloy is magnesium except for incidental impurities.
    Type: Grant
    Filed: April 4, 2006
    Date of Patent: March 23, 2010
    Assignee: Cast Centre Pty Ltd
    Inventors: Colleen Joyce Bettles, Mark Antony Gibson
  • Patent number: 7677134
    Abstract: A forged product is made of a magnesium alloy and includes a through hole making portion to make a through hole that runs in a predetermined direction, and a bottom portion that lies on a plane intersecting with the predetermined direction. The through hole includes a first portion that has been formed by a forging process and a second portion that has been formed after the forging process. The second portion of the through hole has shifted toward the bottom portion with respect to the middle of the through hole in the predetermined direction.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: March 16, 2010
    Assignee: Yamaha Hatsudoki Kabushiki Kaisha
    Inventors: Toru Kitsunai, Osamu Matsushita