With Ageing, Solution Treating (i.e., For Hardening), Precipitation Hardening Or Strengthening Patents (Class 148/671)
-
Patent number: 5326409Abstract: A system for developing a metal workpiece in which the center and the periphery have different properties. The workpiece is processed to put it into a first metallurgical condition. Then, a portion of the periphery is dipped into a molten salt bath and the workpiece is rotated so that the periphery is converted to a second metallurgical condition by the heat of the salt bath.Type: GrantFiled: May 1, 1992Date of Patent: July 5, 1994Assignee: Wyman-Gordon CompanyInventor: Wilford H. Couts, Jr.
-
Patent number: 5304263Abstract: A titanium alloy part having a structure comprising ex-beta acicular grains and with equi-axial alpha phases gathered in a plurality of rows at boundaries of the grains. The alloy comprises, by weight, 2 to 5% Mo, 3.5 to 6.5% Al, 1.5 to 2.5% Sn, 1.5 to 4.8% Zr, Fe.ltoreq.1.5%, 4 to 12% Mo+V+Cr, and the balance, titanium and impurities.Type: GrantFiled: June 30, 1993Date of Patent: April 19, 1994Assignee: Compagnie Europeenne Du Zirconium CezusInventors: Bernard Champin, Bernard Prandi
-
Patent number: 5281285Abstract: Tri-titanium aluminide alloys are preferably deformed and heat treated below the beta transus temperature of the alloys to produce an improved combination of mechanical properties, specifically elevated temperature yield strength and creep resistance, and room temperature ductility and toughness. A preferred composition consists essentially of, in atomic percent, 24.5% aluminum, 12.5% niobium, 1.5% molybdenum, balance titanium.Type: GrantFiled: June 29, 1992Date of Patent: January 25, 1994Assignee: General Electric CompanyInventor: Brian J. Marquardt
-
Patent number: 5277718Abstract: A titanium alloy billet having improved response to ultrasonic inspection is described. The billet is given a thermomechanical treatment above the beta transus of the alloy immediately prior to ultrasonic inspection. The treatment may include beta annealing or mechanical deformation above the beta transus. The invention is particularly effective for beta-stabilized alpha-beta and beta titanium alloys.Type: GrantFiled: June 18, 1992Date of Patent: January 11, 1994Assignee: General Electric CompanyInventors: Allen J. Paxson, Clifford E. Shamblen
-
Patent number: 5264055Abstract: A method of producing a part having high strength and improved ductility from a titanium alloy having a composition, in percent by weight, or Mo equivalent 5 to 13 and Al equivalent 3 to 8, the balance being titanium and impurities, comprising the steps of hot working an ingot of the alloy including a roughing down under heat and preparation of a blank under heat, preheating to a temperature situated above the real beta transus of the hot worked alloy, and then final working of at least a part of this blank, after which the blank obtained is subjected to a solution heat treatment and then aged. The hot worked blank is cooled from the preheating temperature to a temperature for the beginning of final working which, under the conditions of the cooling of the blank, is at least 50.degree. C. below the real beta tansus and at least 10.degree. C. above the temperature of appearance of the alpha phase, so that the final working is sufficient to end within the alpha nucleation range.Type: GrantFiled: May 14, 1992Date of Patent: November 23, 1993Assignee: Compagnie Europeenne du Zirconium CezusInventors: Bernard Champin, Bernard Prandi
-
Patent number: 5264054Abstract: A method for providing improved ductility in a gamma titanium aluminide is taught. The method involves adding inclusions of boron to the titanium aluminide containing chromium, carbon, and niobium and thermomechanically working the casting. Boron additions are made in concentrations between 0.5 and 2 atomic percent. Fine grain equiaxed microstructure is found from solidified melt. Property improvements are achieved by the thermomechanical processing.Type: GrantFiled: May 18, 1992Date of Patent: November 23, 1993Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5256218Abstract: A method and apparatus for applying heat sufficient to permit plastic deformation of intermetallic material. The heat is applied to a fractional region of a workpiece, and then manipulations capable of causing the workpiece to deform are applied using conventional sheet metal forming equipment. The invention utilizes elevated forming temperatures to heat the fractional region of the intermetallic workpiece so that the fractional region has sufficient ductility to permit a plastic deformation required for the forming operation. The apparatus is a sheet metal-working machine which has been modified to provide the localized heating required to carry out the process of the present invention.Type: GrantFiled: October 3, 1991Date of Patent: October 26, 1993Assignee: Rockwell International CorporationInventors: Allen D. Bakalyar, Peter Lydia
-
Patent number: 5244517Abstract: A titanium alloy is prepared containing 2 to 4% by weight of aluminum, 1.5 to 2.5% by weight of vanadium, 0.20 to 0.45% by weight of a rare earth element (not essential). 0.05 to 0.11% by weight of sulfur (not essential), and titanium substantially for the remainder, the ratio of the rear earth element content to the sulfur content ranging from 3.8 to 4.2. This titanium alloy is rough-formed and hot-forged at a temperature in a .beta. region, and the resulting titanium alloy ingot is processed directly into a titanium alloy component having a desired shape. The titanium alloy component thus manufactured has a satisfactory fatigue strength and is also excellent in machinability, and can be used for connecting rods, valves, retainers, etc. to be incorporated in the engine of an automobile.Type: GrantFiled: November 15, 1991Date of Patent: September 14, 1993Assignees: Daido Tokushuko Kabushiki Kaisha, Honda Giken Kogyo Kabushiki KaishaInventors: Atsuyoshi Kimura, Sachihiro Isogawa, Toshihiko Matsubara
-
Patent number: 5232661Abstract: This invention relates to TiAl based intermetallic compound alloy and process for producing; the object of this invention is to improve high temperature deformability. The alloy comprises basic components: Ti.sub.y AlCr.sub.x, wherein 1%.ltoreq.X.ltoreq.5%, 47.5%.ltoreq.Y.ltoreq.52%, and X+ 2Y.gtoreq.100%, and comprises a fine-grain structure with a .beta. phase precipitated on a grain boundary of equiaxed .gamma. grain having grain size of less than 30 .mu.m, and possessing a superplasticity such that the strain rate sensitivity factors (m value) is 0.40 or more and tensile elongation is 400% or more tested at 1200.degree. C. and a strain rate of 5.times.10.sup.-4 S.sup.-1.Type: GrantFiled: August 8, 1991Date of Patent: August 3, 1993Assignee: Nippon Steel CorporationInventors: Munetsugu Matsuo, Naoya Masahashi, Keizo Hashimoto, Toshihiro Hanamura, Hideki Fujii, Masao Kimura, Youji Mizuhara, Hiroo Suzuki
-
Patent number: 5226985Abstract: A first method for producing articles of gamma titanium alumide alloy having improved properties comprises the steps of: (a) shaping the article at a temperature between the titanium-aluminum eutectoid temperature of the alloy and the alpha-transus temperature of the alloy, and (b) aging the thus-shaped article at a temperature between about 750.degree. and 1050.degree. C. for about 4 to 150 hours. Shaping is preferably carried out at a temperature about 0.degree. to 50.degree. C. below the alpha-transus temperature.A second method for producing articles of gamma titanium aluminide alloy having improved properties comprises the steps of: (a) shaping the article at a temperature in the approximate range of about 130.degree. C. below the titanium-aluminum eutectoid temperature of the alloy to about 20.degree. C.Type: GrantFiled: January 22, 1992Date of Patent: July 13, 1993Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Young-Won Kim, Dennis M. Dimiduk
-
Patent number: 5226981Abstract: A method of manufacturing corrosion resistant tubing from seam welded stock of a titanium or titanium alloy metallic material having a hexagonal close-packed crystal structure. The method includes cold pilgering a seam welded tube hollow having a weld area along the seam in a single pass to a final sized tube. The cold pilgering effects a reduction in cross sectional area of the tube hollow of at least 50% and a reduction of wall thickness of at least 50% thereby orienting the crystals in a radial direction. The method also includes annealing the final sized tubing at a temperature and for a time sufficient to effect complete recrystallization and reform grains in the weld area into smaller, homogeneous radially oriented grains. After the recrystallization annealing step, the tubing exhibits enhanced corrosion resistance which is similar to seamless tubing.Type: GrantFiled: January 28, 1992Date of Patent: July 13, 1993Assignee: Sandvik Special Metals, Corp.Inventors: Steven E. Meredith, James F. Benjamin
-
Patent number: 5226989Abstract: Leaders are attached to opposite ends of a titanium foil or thin strip element and are partially coiled on respective reels spaced at opposite sides of a cluster rolling mill to transfer the titanium element back and forth between the reels to move the element between pressure rolls of the mill a plurality of times and under forward and back tension in air at room temperature to initially reduce the element thickness enough to permit the element to be coiled on the reels and then to partially coil the element on the reels to further reduce element thickness. Iron aluminide material is interleaved with a loose coil of the element and the element is heated in a protective atmosphere to stress relieve and partially recrystallize the element material between the reductions in thickness.Type: GrantFiled: December 16, 1991Date of Patent: July 13, 1993Assignee: Texas Instruments IncorporatedInventor: Israil Sukonnik
-
Patent number: 5217548Abstract: A process for working .beta. titanium alloy comprises the steps of first elongating the alloy at a temperature not higher than a .beta. transus temperature and at a working ration of 30% or more. Next, conducting a subsequent aging treatment. Then, elongating the alloy at a temperature not higher than the aging treatment temperature and at a working ratio of 70% or more when combined with that in the first step for elongating. Then a recrystallization treatment is carried out at a treating temperature not higher than the .beta. transus temperature or isothermal working is carried out within a temperature range of the .beta. transus temperature minus 200.degree. C. to the .beta. transus.Type: GrantFiled: September 5, 1991Date of Patent: June 8, 1993Assignee: Seiko Instruments Inc.Inventors: Isao Kuboki, Kenzo Kato, Yutaka Wakabayashi
-
Patent number: 5201457Abstract: A process for manufacturing welded titanium alloy tubes and pipes having good corrosion resistance and good mechanical properties from a titanium alloy which consists essentially, by weight, of one or more of the platinum group metals in a total amount of 0.01-0.14%, at least one of Ni and Co each in an amount of 0.1%-2.0%, not more than 0.35% of oxygen, not more than 0.30% of iron, optionally at least one of Mo, W, and V each in an amount of 0.1%-2.0%, and a balance of Ti. The process comprises preparing a slab by hot working from an ingot of the titanium alloy after heating in a temperature range of from 750.degree. C. to a temperature 200.degree. C. above the beta-transus point, hot-rolling the slab with a finishing temperature of not lower than 400.degree. C. to form a hot-rolled strip after heating in a temperature range of from 650.degree. C. to a temperature 150.degree. C. above the beta-transus point, optionally performing annealing in a temperature range of from 550.degree. C. to a temperature 20.Type: GrantFiled: July 12, 1991Date of Patent: April 13, 1993Assignee: Sumitomo Metal Industries, Ltd.Inventors: Shiroh Kitayama, Yoshiaki Shida
-
Patent number: 5201967Abstract: The invention relates to a process for improving the aging response and uniformity in a beta titanium alloy comprising the steps of:(a) cold working said beta titanium alloy to at least about 5% so that a reasonable degree of recrystallization can be obtained during subsequent solution treatment;(b) pre-aging said cold worked alloy at about 900.degree. to about 1300.degree. F. for a time in excess of about 5 minutes to obtain a pre-aged alloy;(c) solution treating said pre-aged alloy at a time and temperature to achieve a reasonable degree of recrystallization of said pre-aged alloy above the beta transus; and(d) aging said solution treated alloy at temperature and times to achieve a pre-aged, solution treated and aged beta titanium alloy substantially in a state of metallurgical equilibrium.Type: GrantFiled: December 11, 1991Date of Patent: April 13, 1993Assignee: RMI Titanium CompanyInventors: Ronald W. Schutz, Stanley R. Seagle
-
Patent number: 5194101Abstract: This is an improved method of fabricating Zircaloy-4 strip. The method is of the type wherein Zircaloy-4 material is vacuum melted, forged, hot reduced, beta-annealed, quenched, hot rolled, subjected to a post-hot-roll anneal and then reduced by at least two cold rolling steps, including a final cold rolling to final size, with intermediate annealing between the cold rolling steps and with a final anneal after the last cold rolling step. The improvement comprises: (a) utilizing a maximum processing temperature of 620.degree. C. between the quenching and the final cold rolling to final size; (b) utilizing a maximum intermediate annealing temperature of 520.degree. C.; and (c) utilizing hot rolling, post-hot-roll annealing, intermediate annealing and final annealing time-temperature combinations to give an A parameter of between 4.times.10.sup.-19 and 7.times.10.sup.Type: GrantFiled: March 16, 1990Date of Patent: March 16, 1993Assignee: Westinghouse Electric Corp.Inventors: Samuel A. Worcester, James P. Dougherty, John P. Foster
-
Patent number: 5190603Abstract: A process for producing a workpiece from an alloy containing dopant and based on titanium aluminide. The process is intended to produce a workpiece of high oxidation and corrosion resistance, good high-temperature strength and adequate ductility. The process steps include melting the alloy, casting the melt to produce a cast body, cooling the cast body to room temperature and removing its casting skin and its scale layer. The descaled cast body is subjected to high-temperature isostatic pressing at a temperature between 1200.degree. and 1300.degree. C. and a pressure between 100 and 150 MPa, and cooling the isostatically pressed cast body. The cooled cast body is heated to temperatures of 1050.degree. to 1200.degree. C., deformed isothermally one or more times at this temperature for the purpose of molding and structure improvement, and cooled to room temperature. The deformed cast body is machined to produce a workpiece by material removal.Type: GrantFiled: June 26, 1991Date of Patent: March 2, 1993Assignee: Asea Brown Boveri Ltd.Inventors: Mohamed Nazmy, Markus Staubli
-
Patent number: 5185045Abstract: A process as described for treating Ti.sub.3 Al-based alloys comprising, in ddition to titanium and aluminum as .alpha.-phase-stabilizing element, niobium and further elements stabilizing the .beta.-phase in an amount of from 20 to 30% by weight, wherein the further elements stabilizing the .beta. phase are present in an amount of at least 4% by weight by(a) preparing the alloys by melting or via the powder-metallurgical route,(b) deforming at a temperature within the (.alpha..sub.2 +.beta.)-phase area by more than 60% in one or more steps with stress-relief annealing without complete recrystallization effected between these steps,(c) solution annealing the formed part for from 5 minutes to 120 minutes below the .beta.-transus temperature of the alloy,(d) quenching, and(e) subsequent aging/stress-relief annealing at temperatures within the range of from 500.degree. for 75.degree. C. for from 0.5 to 24 hours.Type: GrantFiled: July 25, 1991Date of Patent: February 9, 1993Assignee: Deutsche Forschungsanstalt fur Luftund Raumfahrt e.V. Linder HoheInventors: Manfred Peters, Karl-Josef Grundhoff, Hartmut Schurmann, Yong-Tai Lee
-
Patent number: 5178694Abstract: Disclosed is a process of surface hardening of Ti-6A1-4V alloy that can be performed by electrolytic charging in an acid solution, subsequent solution treatment, followed by dehydrogenation to obtain an equiaxed alpha grain in transformed beta matrix. Surface hardnesses of the processed specimens are better than that of the mill-annealed specimen. The depth of hardened layer depends on the charging time.Type: GrantFiled: January 8, 1992Date of Patent: January 12, 1993Assignee: National Science CouncilInventors: Jiann-Kuo Wu, Tair-I Wu
-
Patent number: 5173134Abstract: High performance titanium alloys useful as impellers and disks for gas turbine engines are provided, together with processes for their preparation.Type: GrantFiled: December 3, 1990Date of Patent: December 22, 1992Assignee: Aluminum Company of AmericaInventors: Amiya K. Chakrabarti, George W. Kuhlman, Jr., Robert Pishko
-
Patent number: 5171375Abstract: The titanium alloy treatment process of the present invention comprises molding an .alpha.+.beta. titanium alloy and a .beta. alloy, subjecting the resultant article to a .beta. solution treatment above the .beta. transformation point, quenching the treated article to room temperature to form a martensitic single phase or a .beta. single phase, subjecting the article to an aging treatment below the .beta. transformation point to finely precipitation an .alpha. precipitate on the martensite phase or the .beta. phase, and then subjecting the article to a mirror fining treatment to attain a mirror state.Type: GrantFiled: September 6, 1990Date of Patent: December 15, 1992Assignee: Seiko Instruments Inc.Inventors: Yutaka Wakabayashi, Kenzo Kato, Shigeru Miyama, Akihiko Abe
-
Patent number: 5118363Abstract: High performance Ti-6A1-4V alloys skewed with oxygen and nitrogen and useful as impellers are provided and a process for their preparation.Type: GrantFiled: November 24, 1989Date of Patent: June 2, 1992Assignee: Aluminum Company of AmericaInventors: Amiya K. Chakrabarti, George W. Kuhlman, Jr., Stanley R. Seagle