With Ageing, Solution Treating (i.e., For Hardening), Precipitation Hardening Or Strengthening Patents (Class 148/671)
  • Patent number: 5326409
    Abstract: A system for developing a metal workpiece in which the center and the periphery have different properties. The workpiece is processed to put it into a first metallurgical condition. Then, a portion of the periphery is dipped into a molten salt bath and the workpiece is rotated so that the periphery is converted to a second metallurgical condition by the heat of the salt bath.
    Type: Grant
    Filed: May 1, 1992
    Date of Patent: July 5, 1994
    Assignee: Wyman-Gordon Company
    Inventor: Wilford H. Couts, Jr.
  • Patent number: 5304263
    Abstract: A titanium alloy part having a structure comprising ex-beta acicular grains and with equi-axial alpha phases gathered in a plurality of rows at boundaries of the grains. The alloy comprises, by weight, 2 to 5% Mo, 3.5 to 6.5% Al, 1.5 to 2.5% Sn, 1.5 to 4.8% Zr, Fe.ltoreq.1.5%, 4 to 12% Mo+V+Cr, and the balance, titanium and impurities.
    Type: Grant
    Filed: June 30, 1993
    Date of Patent: April 19, 1994
    Assignee: Compagnie Europeenne Du Zirconium Cezus
    Inventors: Bernard Champin, Bernard Prandi
  • Patent number: 5281285
    Abstract: Tri-titanium aluminide alloys are preferably deformed and heat treated below the beta transus temperature of the alloys to produce an improved combination of mechanical properties, specifically elevated temperature yield strength and creep resistance, and room temperature ductility and toughness. A preferred composition consists essentially of, in atomic percent, 24.5% aluminum, 12.5% niobium, 1.5% molybdenum, balance titanium.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: January 25, 1994
    Assignee: General Electric Company
    Inventor: Brian J. Marquardt
  • Patent number: 5277718
    Abstract: A titanium alloy billet having improved response to ultrasonic inspection is described. The billet is given a thermomechanical treatment above the beta transus of the alloy immediately prior to ultrasonic inspection. The treatment may include beta annealing or mechanical deformation above the beta transus. The invention is particularly effective for beta-stabilized alpha-beta and beta titanium alloys.
    Type: Grant
    Filed: June 18, 1992
    Date of Patent: January 11, 1994
    Assignee: General Electric Company
    Inventors: Allen J. Paxson, Clifford E. Shamblen
  • Patent number: 5264055
    Abstract: A method of producing a part having high strength and improved ductility from a titanium alloy having a composition, in percent by weight, or Mo equivalent 5 to 13 and Al equivalent 3 to 8, the balance being titanium and impurities, comprising the steps of hot working an ingot of the alloy including a roughing down under heat and preparation of a blank under heat, preheating to a temperature situated above the real beta transus of the hot worked alloy, and then final working of at least a part of this blank, after which the blank obtained is subjected to a solution heat treatment and then aged. The hot worked blank is cooled from the preheating temperature to a temperature for the beginning of final working which, under the conditions of the cooling of the blank, is at least 50.degree. C. below the real beta tansus and at least 10.degree. C. above the temperature of appearance of the alpha phase, so that the final working is sufficient to end within the alpha nucleation range.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: November 23, 1993
    Assignee: Compagnie Europeenne du Zirconium Cezus
    Inventors: Bernard Champin, Bernard Prandi
  • Patent number: 5264054
    Abstract: A method for providing improved ductility in a gamma titanium aluminide is taught. The method involves adding inclusions of boron to the titanium aluminide containing chromium, carbon, and niobium and thermomechanically working the casting. Boron additions are made in concentrations between 0.5 and 2 atomic percent. Fine grain equiaxed microstructure is found from solidified melt. Property improvements are achieved by the thermomechanical processing.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: November 23, 1993
    Assignee: General Electric Company
    Inventor: Shyh-Chin Huang
  • Patent number: 5256218
    Abstract: A method and apparatus for applying heat sufficient to permit plastic deformation of intermetallic material. The heat is applied to a fractional region of a workpiece, and then manipulations capable of causing the workpiece to deform are applied using conventional sheet metal forming equipment. The invention utilizes elevated forming temperatures to heat the fractional region of the intermetallic workpiece so that the fractional region has sufficient ductility to permit a plastic deformation required for the forming operation. The apparatus is a sheet metal-working machine which has been modified to provide the localized heating required to carry out the process of the present invention.
    Type: Grant
    Filed: October 3, 1991
    Date of Patent: October 26, 1993
    Assignee: Rockwell International Corporation
    Inventors: Allen D. Bakalyar, Peter Lydia
  • Patent number: 5244517
    Abstract: A titanium alloy is prepared containing 2 to 4% by weight of aluminum, 1.5 to 2.5% by weight of vanadium, 0.20 to 0.45% by weight of a rare earth element (not essential). 0.05 to 0.11% by weight of sulfur (not essential), and titanium substantially for the remainder, the ratio of the rear earth element content to the sulfur content ranging from 3.8 to 4.2. This titanium alloy is rough-formed and hot-forged at a temperature in a .beta. region, and the resulting titanium alloy ingot is processed directly into a titanium alloy component having a desired shape. The titanium alloy component thus manufactured has a satisfactory fatigue strength and is also excellent in machinability, and can be used for connecting rods, valves, retainers, etc. to be incorporated in the engine of an automobile.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: September 14, 1993
    Assignees: Daido Tokushuko Kabushiki Kaisha, Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Atsuyoshi Kimura, Sachihiro Isogawa, Toshihiko Matsubara
  • Patent number: 5232661
    Abstract: This invention relates to TiAl based intermetallic compound alloy and process for producing; the object of this invention is to improve high temperature deformability. The alloy comprises basic components: Ti.sub.y AlCr.sub.x, wherein 1%.ltoreq.X.ltoreq.5%, 47.5%.ltoreq.Y.ltoreq.52%, and X+ 2Y.gtoreq.100%, and comprises a fine-grain structure with a .beta. phase precipitated on a grain boundary of equiaxed .gamma. grain having grain size of less than 30 .mu.m, and possessing a superplasticity such that the strain rate sensitivity factors (m value) is 0.40 or more and tensile elongation is 400% or more tested at 1200.degree. C. and a strain rate of 5.times.10.sup.-4 S.sup.-1.
    Type: Grant
    Filed: August 8, 1991
    Date of Patent: August 3, 1993
    Assignee: Nippon Steel Corporation
    Inventors: Munetsugu Matsuo, Naoya Masahashi, Keizo Hashimoto, Toshihiro Hanamura, Hideki Fujii, Masao Kimura, Youji Mizuhara, Hiroo Suzuki
  • Patent number: 5226985
    Abstract: A first method for producing articles of gamma titanium alumide alloy having improved properties comprises the steps of: (a) shaping the article at a temperature between the titanium-aluminum eutectoid temperature of the alloy and the alpha-transus temperature of the alloy, and (b) aging the thus-shaped article at a temperature between about 750.degree. and 1050.degree. C. for about 4 to 150 hours. Shaping is preferably carried out at a temperature about 0.degree. to 50.degree. C. below the alpha-transus temperature.A second method for producing articles of gamma titanium aluminide alloy having improved properties comprises the steps of: (a) shaping the article at a temperature in the approximate range of about 130.degree. C. below the titanium-aluminum eutectoid temperature of the alloy to about 20.degree. C.
    Type: Grant
    Filed: January 22, 1992
    Date of Patent: July 13, 1993
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Young-Won Kim, Dennis M. Dimiduk
  • Patent number: 5226981
    Abstract: A method of manufacturing corrosion resistant tubing from seam welded stock of a titanium or titanium alloy metallic material having a hexagonal close-packed crystal structure. The method includes cold pilgering a seam welded tube hollow having a weld area along the seam in a single pass to a final sized tube. The cold pilgering effects a reduction in cross sectional area of the tube hollow of at least 50% and a reduction of wall thickness of at least 50% thereby orienting the crystals in a radial direction. The method also includes annealing the final sized tubing at a temperature and for a time sufficient to effect complete recrystallization and reform grains in the weld area into smaller, homogeneous radially oriented grains. After the recrystallization annealing step, the tubing exhibits enhanced corrosion resistance which is similar to seamless tubing.
    Type: Grant
    Filed: January 28, 1992
    Date of Patent: July 13, 1993
    Assignee: Sandvik Special Metals, Corp.
    Inventors: Steven E. Meredith, James F. Benjamin
  • Patent number: 5226989
    Abstract: Leaders are attached to opposite ends of a titanium foil or thin strip element and are partially coiled on respective reels spaced at opposite sides of a cluster rolling mill to transfer the titanium element back and forth between the reels to move the element between pressure rolls of the mill a plurality of times and under forward and back tension in air at room temperature to initially reduce the element thickness enough to permit the element to be coiled on the reels and then to partially coil the element on the reels to further reduce element thickness. Iron aluminide material is interleaved with a loose coil of the element and the element is heated in a protective atmosphere to stress relieve and partially recrystallize the element material between the reductions in thickness.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: July 13, 1993
    Assignee: Texas Instruments Incorporated
    Inventor: Israil Sukonnik
  • Patent number: 5217548
    Abstract: A process for working .beta. titanium alloy comprises the steps of first elongating the alloy at a temperature not higher than a .beta. transus temperature and at a working ration of 30% or more. Next, conducting a subsequent aging treatment. Then, elongating the alloy at a temperature not higher than the aging treatment temperature and at a working ratio of 70% or more when combined with that in the first step for elongating. Then a recrystallization treatment is carried out at a treating temperature not higher than the .beta. transus temperature or isothermal working is carried out within a temperature range of the .beta. transus temperature minus 200.degree. C. to the .beta. transus.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: June 8, 1993
    Assignee: Seiko Instruments Inc.
    Inventors: Isao Kuboki, Kenzo Kato, Yutaka Wakabayashi
  • Patent number: 5201457
    Abstract: A process for manufacturing welded titanium alloy tubes and pipes having good corrosion resistance and good mechanical properties from a titanium alloy which consists essentially, by weight, of one or more of the platinum group metals in a total amount of 0.01-0.14%, at least one of Ni and Co each in an amount of 0.1%-2.0%, not more than 0.35% of oxygen, not more than 0.30% of iron, optionally at least one of Mo, W, and V each in an amount of 0.1%-2.0%, and a balance of Ti. The process comprises preparing a slab by hot working from an ingot of the titanium alloy after heating in a temperature range of from 750.degree. C. to a temperature 200.degree. C. above the beta-transus point, hot-rolling the slab with a finishing temperature of not lower than 400.degree. C. to form a hot-rolled strip after heating in a temperature range of from 650.degree. C. to a temperature 150.degree. C. above the beta-transus point, optionally performing annealing in a temperature range of from 550.degree. C. to a temperature 20.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: April 13, 1993
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Shiroh Kitayama, Yoshiaki Shida
  • Patent number: 5201967
    Abstract: The invention relates to a process for improving the aging response and uniformity in a beta titanium alloy comprising the steps of:(a) cold working said beta titanium alloy to at least about 5% so that a reasonable degree of recrystallization can be obtained during subsequent solution treatment;(b) pre-aging said cold worked alloy at about 900.degree. to about 1300.degree. F. for a time in excess of about 5 minutes to obtain a pre-aged alloy;(c) solution treating said pre-aged alloy at a time and temperature to achieve a reasonable degree of recrystallization of said pre-aged alloy above the beta transus; and(d) aging said solution treated alloy at temperature and times to achieve a pre-aged, solution treated and aged beta titanium alloy substantially in a state of metallurgical equilibrium.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: April 13, 1993
    Assignee: RMI Titanium Company
    Inventors: Ronald W. Schutz, Stanley R. Seagle
  • Patent number: 5194101
    Abstract: This is an improved method of fabricating Zircaloy-4 strip. The method is of the type wherein Zircaloy-4 material is vacuum melted, forged, hot reduced, beta-annealed, quenched, hot rolled, subjected to a post-hot-roll anneal and then reduced by at least two cold rolling steps, including a final cold rolling to final size, with intermediate annealing between the cold rolling steps and with a final anneal after the last cold rolling step. The improvement comprises: (a) utilizing a maximum processing temperature of 620.degree. C. between the quenching and the final cold rolling to final size; (b) utilizing a maximum intermediate annealing temperature of 520.degree. C.; and (c) utilizing hot rolling, post-hot-roll annealing, intermediate annealing and final annealing time-temperature combinations to give an A parameter of between 4.times.10.sup.-19 and 7.times.10.sup.
    Type: Grant
    Filed: March 16, 1990
    Date of Patent: March 16, 1993
    Assignee: Westinghouse Electric Corp.
    Inventors: Samuel A. Worcester, James P. Dougherty, John P. Foster
  • Patent number: 5190603
    Abstract: A process for producing a workpiece from an alloy containing dopant and based on titanium aluminide. The process is intended to produce a workpiece of high oxidation and corrosion resistance, good high-temperature strength and adequate ductility. The process steps include melting the alloy, casting the melt to produce a cast body, cooling the cast body to room temperature and removing its casting skin and its scale layer. The descaled cast body is subjected to high-temperature isostatic pressing at a temperature between 1200.degree. and 1300.degree. C. and a pressure between 100 and 150 MPa, and cooling the isostatically pressed cast body. The cooled cast body is heated to temperatures of 1050.degree. to 1200.degree. C., deformed isothermally one or more times at this temperature for the purpose of molding and structure improvement, and cooled to room temperature. The deformed cast body is machined to produce a workpiece by material removal.
    Type: Grant
    Filed: June 26, 1991
    Date of Patent: March 2, 1993
    Assignee: Asea Brown Boveri Ltd.
    Inventors: Mohamed Nazmy, Markus Staubli
  • Patent number: 5185045
    Abstract: A process as described for treating Ti.sub.3 Al-based alloys comprising, in ddition to titanium and aluminum as .alpha.-phase-stabilizing element, niobium and further elements stabilizing the .beta.-phase in an amount of from 20 to 30% by weight, wherein the further elements stabilizing the .beta. phase are present in an amount of at least 4% by weight by(a) preparing the alloys by melting or via the powder-metallurgical route,(b) deforming at a temperature within the (.alpha..sub.2 +.beta.)-phase area by more than 60% in one or more steps with stress-relief annealing without complete recrystallization effected between these steps,(c) solution annealing the formed part for from 5 minutes to 120 minutes below the .beta.-transus temperature of the alloy,(d) quenching, and(e) subsequent aging/stress-relief annealing at temperatures within the range of from 500.degree. for 75.degree. C. for from 0.5 to 24 hours.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: February 9, 1993
    Assignee: Deutsche Forschungsanstalt fur Luftund Raumfahrt e.V. Linder Hohe
    Inventors: Manfred Peters, Karl-Josef Grundhoff, Hartmut Schurmann, Yong-Tai Lee
  • Patent number: 5178694
    Abstract: Disclosed is a process of surface hardening of Ti-6A1-4V alloy that can be performed by electrolytic charging in an acid solution, subsequent solution treatment, followed by dehydrogenation to obtain an equiaxed alpha grain in transformed beta matrix. Surface hardnesses of the processed specimens are better than that of the mill-annealed specimen. The depth of hardened layer depends on the charging time.
    Type: Grant
    Filed: January 8, 1992
    Date of Patent: January 12, 1993
    Assignee: National Science Council
    Inventors: Jiann-Kuo Wu, Tair-I Wu
  • Patent number: 5173134
    Abstract: High performance titanium alloys useful as impellers and disks for gas turbine engines are provided, together with processes for their preparation.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: December 22, 1992
    Assignee: Aluminum Company of America
    Inventors: Amiya K. Chakrabarti, George W. Kuhlman, Jr., Robert Pishko
  • Patent number: 5171375
    Abstract: The titanium alloy treatment process of the present invention comprises molding an .alpha.+.beta. titanium alloy and a .beta. alloy, subjecting the resultant article to a .beta. solution treatment above the .beta. transformation point, quenching the treated article to room temperature to form a martensitic single phase or a .beta. single phase, subjecting the article to an aging treatment below the .beta. transformation point to finely precipitation an .alpha. precipitate on the martensite phase or the .beta. phase, and then subjecting the article to a mirror fining treatment to attain a mirror state.
    Type: Grant
    Filed: September 6, 1990
    Date of Patent: December 15, 1992
    Assignee: Seiko Instruments Inc.
    Inventors: Yutaka Wakabayashi, Kenzo Kato, Shigeru Miyama, Akihiko Abe
  • Patent number: 5118363
    Abstract: High performance Ti-6A1-4V alloys skewed with oxygen and nitrogen and useful as impellers are provided and a process for their preparation.
    Type: Grant
    Filed: November 24, 1989
    Date of Patent: June 2, 1992
    Assignee: Aluminum Company of America
    Inventors: Amiya K. Chakrabarti, George W. Kuhlman, Jr., Stanley R. Seagle