Abstract: Adhesion between an adhesive of the class of polymerizable liquid ethylenically unsaturated compounds containing a single vinyl group and solid polyester-containing plastic materials is improved by treating the substrate with a primer composition comprising an aromatic polyisocyanate and an amino resin and moisture-curing the polyisocyanate compound prior to application of the adhesive. The adhesive-joined assemblies are cured in a first stage at room temperature and, in a second stage, are post-baked at 100.degree. to 150.degree. C. to complete cure of the adhesive and the primer.

Abstract: A continuous process for producing reinforced resin laminates comprising the steps of impregnating a fibrous substrate with a liquid resin which is free of volatile solvent and is capable of curing without generating liquid and gaseous byproducts, laminating a plurality of the resin-impregnated substrates into a unitary member, sandwiching the laminate between a pair of covering sheets, and curing the laminate between said pair of covering sheets without applying appreciable pressure. The improvement comprises adjusting the final resin content in said resin impregnated substrate at 10 to 90% by weight based on the total weight of said impregnated substrate.

Abstract: Polyamide resins are used as primer for highway repairs using asphaltic membranes.

Abstract: A base material for the production of printed circuits according to the additive method includes a laminate base made up of laminated-together core sheets impregnated with hardenable resin, and a cover layer made up of a substrate sheet preimpregnated with phenolic resol resin and provided with an adhesive layer of an elastomeric polymer. The preimpregnated substrate sheet is also provided with a further resin impregnation containing a self-crosslinking copolymer of acrylic monomers and up to 30% by weight of a hardenable phenolic resol resin.

Abstract: A method of bonding a silicone rubber to a non-silicone pressure sensitive adhesive comprising the steps of treating the surface of the silicone rubber to be bonded with a silicone adhesive, and thereafter applying a layer of the non-silicone pressure sensitive adhesive to the treated silicone rubber surface.

Abstract: The method for producing foil paper and foil board with a bright surface, by first metalizing a transfer-carrier, applying a compatible tacky dress to the metalized carrier, pressing the metalized carrier at its tacky surface against a base of paper or board; then separating the carrier from the metalized portion transferred to the base of paper or board, and curing it at an elevated temperature.

Abstract: Unvulcanized or partially vulcanized rubber is coated with a coating poly capable of co-vulcanizing with the rubber and having functional groups capable of reacting with an adhesive. The coated rubber is then subjected to vulcanizing conditions. When the treated rubber surface is bonded to an adhesive, the functional groups react with the adhesive forming strong bonds.

Abstract: A method of manufacturing peelable adhesive structures. It comprises preparing a first paint solution containing vinyl resin and a stably emulsified hydrocarbon or natural resin having softening point less than 180.degree. C. and concentration between 50 and 200 parts by weight per 100 parts of vinyl resin dispersed in a continuous phase of the vinyl resin. The first paint solution is applied onto a metal base material (1) to form a first coating layer (2). A second coating layer (3) is formed by applying a second paint solution containing epoxy resin and polyethylene oxide at a concentration of between 0.5 and 90 weight percent of epoxy resin over the first coating layer. The first and second coating layers have thicknesses ranging from about 0.5 to 100 mg/m.sup.2. A layer of olefin resin (4) is joined to the second coating layer.

Abstract: Plasticized elastomer is securely bonded to a metal surface by interposing between the adhesive-coated metal surface and the elastomer a sheet of material obtained by combining adhesive with a portion of the elastomer that has been treated to remove plasticizers therefrom and heating the assembly in a mold under pressure. The sheet material is made up by dissolving a portion of the plasticized elastomer in an organic solvent, casting the solution, exposing it to a vacuum to remove the solvent and plasticizers, dissolving the de-plasticized material in liquid adhesive and casting and drying the resulting liquid.

Abstract: An arrangement and method for tiling bath enclosures, shower stalls, and the like, comprises providing a sheet of imperforate, substantially waterproof material with a dry, solvent-based film adhesive formed on the exterior side of the sheet. The interior side of the sheet is adhered to those substrate walls to be tiled, and tile adhesive is applied over the film adhesive on the exterior side of the sheet. The tile adhesive includes a solvent which partially dissolves the film adhesive, and a crosslinking agent which securely bonds the adhesives to each other and the waterproof sheet. Ceramic tiles are pressed into the wet adhesive, and are fixedly anchored in place as the adhesive cures, such that the waterproof sheet forms a barrier between the tiles and the substrate walls which is substantially impervious to moisture.

Abstract: The present disclosure is concerned with solvent free or very low solvent coating compositions suitable for use on flexible sheet form substrates particularly textile substrates. The composition comprises a urethane group-containing prepolymer with OH or CONH.sub.2 terminal groups mixed with a urea or melamine formaldehyde resin and a stable aqueous polymer dispersion or solution. The composition may also contain small amounts of an organic solvent. The coating can be applied to the substrate by direct or reverse coating techniques.

Abstract: Substrates which are susceptible to corrosion by the action of chemical agents in gas-containing and/or gas-generating media are rendered resistant to said corrosion by the application thereto of a coating of a gas-permeable elastomeric or plastic material, and providing for means of escape of gases permeating the coating, thereby maintaining the adhesion of the coating to the substrate. Preferably the coating in applied first to a porous backing material such as woven glass cloth, so that the pores of the backing material are left substantially open to let gas escape. The laminate of coating and porous backing material is then adhesively secured to the substrate in such a way that the pores in the backing material are left partly open to let gas escape.

Abstract: A lamination process is provided for the lamination of a vinyl film to a cellulosic substrate, such as a wood product, e.g., particleboard, wherein grain swelling of the substrate is avoided. The process involves coating the wood product substrate with an organic polyisocyanate having at least two active isocyanate groups per molecule as a primer coat, and thereafter applying a vinyl acetate-ethylene copolymer emulsion adhesive to the primed substrate to form an interlaminate adhesive layer. A vinyl polymeric film is then applied to the adhesive-coated substrate to form a permanently bonded laminate of the substrate and the film. The lamination process of the present invention is particularly suitable for use in a continuous hot-line heat reactivated laminating procedure.

Abstract: A protective covering for the protection of surface seals against mechanical damage in building constructions and other civil engineering constructions which comprises a composite of an elastic, waterproof thermoplastic synthetic resin film sheet and/or synthetic resin layer and a lattice-like fabric having knot couplings or points of intersection of the threads that yield under the effect of a load.

Abstract: A method of making a solar heat energy collecting system which comprises: forming a potentially foamable, resinous base layer containing a blowing agent; applying a printing composition to the surface of the potentially foamable, resinous base layer in the form of at least one continuous path extending from one edge point to another edge point of the potentially foamable, resinous base layer, the printing composition comprising a blowing inhibitor and a release agent; applying a top surface layer to the surface of the printed potentially foamable, resinous base layer which adheres thereto except in those areas containing the blowing inhibitor and release agent; heating the potentially foamable, resinous base layer to decompose or to activate the blowing agent in those portions of the potentially foamable, resinous base layer not lying under the blowing inhibitor and release agent, whereby such portions are blown and expand to extend and stretch upwardly so as to form upright walls of foamed, relatively lower

Abstract: A laminate, particularly useful for application to resin extrusion strips applied as trim molding to sides and doors of automobile bodies, is formed of a surface metalized polyester resin film bonded to a vinyl resin sheeting by an in-situ formed polyester-isocyanate adhesive.

Abstract: A cylinder liner for liquid-cooled engines having a bandlike sealant on the outer-surface thereof wherein the sealant is formed by a two-layer laminate of silicone resin having a completely cured inner layer and a half-cured outer layer. This cylinder liner has an excellent sealing effect.

Abstract: An ultra thin laminate is made by: (1) assembling a laminate stack-up consisting of: one paper sheet having a top decorative surface and a bottom surface coated with a resinous film, about 0.25 mil to about 5 mil thick, effective to opacify the paper and provide a barrier to resin flow, and one abrasion resistant protective overlay sheet disposed in contact with the decorative surface of the paper sheet; (2) heat and pressure consolidating the stack-up to form a unitary decorative laminate having a thickness of between about 5 mil and about 15 mil, and having a resinous film on one side that is glue adherable.

Abstract: A painted surface is applied to a piece of hardboard simultaneously while the board is being formed in a press. A heat-resistant paint layer is coated onto a carrier, and the painted carrier is placed over a loose layer of exploded wood fibers in a heated press. The press applies pressure in excess of 400 psi and heat above 400.degree. F. to compact the wood fibers into an integral hardboard piece while the heat from the press simultaneously transfers the paint layer from the carrier and bonds it to a surface of the board. In one embodiment of the invention, the paint layer is a thermosetting resinous paint system, and the paint coat is sufficiently heat-resistant to remain in a hardened condition at or above the temperature at which the board is formed, thus forming a separate hardened paint layer on the surface of the board. The carrier can include an adherence coat which is heat-activated in the press to crosslink and bond the paint layer to the wood fibers.

Abstract: Rubber compounds are readily bonded to nylon or polyamides, particularly tire cords of polyamides in which a high proportion of the amide linkages are attached directly to aromatic rings, using a two-step dip process in which the first dip comprises a liquid dispersion or solution of an epoxide having an average of from about two to four epoxide groups per molecule and a molecular weight up to about 600 and the second dip comprises an aqueous dispersion of a mixture of a major amount of a rubbery vinyl pyridine copolymer and a minor amount of a heat reactable 2,6-bis(2,4-dihydroxy phenylmethyl)-4-chlorophenol composition. High H-adhesions are obtained with this process. It is particularly useful for the bonding to rubber compounds of crystalline polyamides having a large number of aromatic groups in the polymeric structure, e.g., "Fiber B".

Abstract: A method of forming a heat-sealable carton having a pair of mating surfaces to be sealed includes the steps of coating at least one of the carton surfaces with a heat-activated thermosetting adhesive, spraying a fine mist of a water-based adhesive which exhibits high contact tackiness when dry, to form a discontinuous film on the coated surface, heating the water-based adhesive coated surface to a temperature sufficient to dry the water-based adhesive and activate the thermosetting adhesive, placing the mating carton surfaces in contact with each other and applying pressure for a time sufficient to seal the contacting surfaces together. A carton formed by the method is provided with flaps sealed by the combination of thermosetting heat-activated adhesive and high tack water-based adhesive. This allows the mating surfaces to be rapidly sealed by automatic carton closing apparatus and results in a sealed carton which exhibits good seal integrity at high temperatures.

Abstract: A method wherein uncured urethane formulations are bonded to a cured rubber or synthetic rubber substrate in such a manner so as to provide greater bonding strength than has been achieved previously in urethane formulation bonding to rubber or synthetic rubber.

Abstract: A process for separating a collated stack of carbonless copy paper sheets into form sets, which comprises pretreating the edge of the stack of sheets to be padded with a non-aqueous material, drying, applying an adhesive composition, drying and separating the unit sets.

Abstract: A peroxy catalyst activator is dissolved in a methyl methacrylate, ethyl methacrylate or styrene lacquer containing, in addition, an adhesion promotor, e.g., an acrylic or methacrylic compound such as the carboxylic acids, amides esters having in the ester moiety amino groups or epoxy groups. The lacquer comprises a copolymer of the monomers dissolved in a volatile liquid solvent such as a mixture of toluene and isopropanol. In use, the lacquer containing the activator is applied to at least one of two substrates and allowed to dry. Thereafter, an adhesive composition containing peroxy catalyst is applied to at least one substrate and both substrates are brought into contact and held until the adhesive bond is formed.The lacquer acts to seal porous substrates and permits the cure to take place rapidly without air inhibition. It forms a surface which retains its activity over a long time period, running into years. Thus, component parts may be coated with the lacquer and stored until needed.

Abstract: A multi-layered sheeting material is disclosed whereby conductive properties are imparted to one surface and antistatic properties are imparted to the other. In a further embodiment, the sheeting material contains a reinforcing layer. This light-weight sheeting material may be used in applications whereby the accumulation of electrical charge may be dangerous, e.g. in the presence of volatile and flammable materials.

Abstract: A flexible acoustical wall covering, method of making same, and wall panel employing same are provided wherein such wall covering is comprised of a laminated construction comprised of a substrate and an outer layer bonded against the substrate with the outer layer having a roughened outside surface defined by projections and indentations which serve as miniature sound baffles and a plurality of spaced openings in and disposed perpendicularly through the laminated construction which allow sound waves to pass therethrough with a fluid impervious film sealing the openings and enabling the wall covering to be used as a fluid impervious covering yet with the film allowing substantially unobstructed passage of the sound waves therethrough.

Abstract: Adhesive bonds between materials, such as woods having porous surfaces, formed by polymerizing in situ alphacyanoacrylate monomers, are accelerated in curing and strengthened by precoating the surfaces to be joined with a solid mixture of alkaline or basic accelerator, such as sodium or potassium hydroxide or sodium borosilicate spheres of micro-size, combined in a chalkable calcareous binder to form a light but adhesive permeable coating, before the monomeric adhesive is applied. The latter permeates in part through the light precoating to bond into the wood and is accelerated in its polymerization so that it is not excessively absorbed into the porous substrate, resulting in a bond of superior strength.

Abstract: Rubber compounds are readily bonded to tire cords using a dip process in which the dip contains an alkaline aqueous dispersion of a mixture of a major amount by weight of a rubbery vinyl pyridine/styrene/butadiene copolymer and a minor amount of a lignin amine-resorcinol-formaldehyde reaction product.

Abstract: A method of making a composite product having a preformed, self-sustaining pliable skin sheet and a preformed non-rigid void containing, low density plastic layer which comprises:(1) establishing a layer of said low density plastic,(2) applying to at least one side a liquid sprayable curative,(3) next applying to the same said side thereof a liquid sprayable polymer which together with said curative is reactive at elevated temperature to form a tenacious, essentially non-porous adhesive which bonds to both said sheet and said layer,(4) next contacting said skin sheet with said side of the low density plastic layer,(5) curing said polymer at elevated temperature whereby said skin sheet is adhered to said layer.

Abstract: A patch or insert, which may be applied to clothing or the like, consists of a substrate, which is preferably a textile fabric, on which is mounted a discontinuous pattern, in raster-like formation, of a heat sealing adhesive. The coating consists of two superposed layers of adhesive, each adhesive having a different adhesive quality.

Abstract: Adhesive compositions comprising a solution of polymer dissolved in acrylic monomers containing an organic sulfonyl chloride, a polymerization catalyst and an accelerator.

Abstract: This invention relates to a method of making transparent laminated windows with a minimum of opacity problems that may result from adhering preformed polyurethane sheeting to acrylic or polyurethane sheeting that constitute components of said transparent windows. The preferred embodiment of the invention comprises applying a dilute solution of up to 5 percent by weight, preferably 1 to 4 percent and most preferably about 2 percent, of finely divided particles of a polyurethane in an organic solvent in which it is highly soluble. A preferred solvent is chloroform. A preferred polyurethane composition is a polyesterurethane that is the reaction product of (a) a polyester having the ester linkage ##STR1## and a pair of groups reactive with isocyanate or isothiocyanate groups; (b) a diisocyanate, disisothiocyanate or a compound containing an isocyanate and an isothiocyanate group; and (c) a compound containing at least two active hydrogens per molecule reactive with isocyanate or isothiocyanate groups.

Abstract: A method for bonding steel plates with a polyamide adhesive, comprising applying a composition comprising (1) a polyester resin comprising the reaction product of (a) a polycarboxylic acid component comprising at least one of a polycarboxylic acid, an anhydride thereof, an ester thereof or a mixture thereof with (b) a polyhydric alcohol component comprising at least one polyhydric alcohol or a mixture thereof, with at least some of one of the polycarboxylic acid component and the polyhydric alcohol component being trivalent or higher, and (2) a bisphenol A-type epoxy resin, on a steel plate; baking the coating by heating; juxtaposing the coated steel plates to be bonded with a polyamide adhesive therebetween; and bonding the steel plates with the polyamide adhesive, a primer composition for use therein and a polyester resin for use in the primer composition.

Abstract: The present disclosure is concerned with an improved method of reverse coating textile sheets with storage stable polyurethane top and adhesive coats which are formulated to have improved resistance to deformation under heat and pressure. At least one of the coats is formulated from a diisocyanate, a high molecular weight dihydroxy compound and a mixture of at least one low molecular weight diol with a low molecular weight monoalkanolamine. The coatings are applied in the usual reverse coating manner, i.e. the top coat is applied to a release substrate from solution; dried; the adhesive coat is applied from solution onto the dried top coat; and the textile substrate is laminated to the adhesive coat.

Abstract: Materials are bonded together by means of an adhesive which comprises a blend of a poly(arylene sulfide) and polytetrafluoroethylene. Coatings of the adhesive can be applied to each of the materials to be bonded and partially cured. The coated surfaces can then be placed in contact with one another and curing of the adhesive completed.

Abstract: Process for the manufacture of polyurethane adhesives with uniform molecular weights which are accurately adjustable and reproducible consisting of diisocyanates, polyols, chain extenders if required, catalysts and additives, all of which are soluble in polar, organic solvents which are inert with respect to isocyanate groups. The polyaddition process is carried out by using an excess of diisocyanate, the reaction is terminated upon reaching the desired molecular weight, and the still existing excess isocyanate groups are allowed to react with alcohols, ammonia and/or amines. The process is characterized in that the polyurethanepolyaddition products are crushed into particles of 1-15 mm and that they are treated with possibly substituted primary, aliphatic mono- to trivalent alcohols, ammonia and/or aliphatic, cycloaliphatic or aromatic mono- or diamines in the liquid or vapor phase in the absence of organic solvents.

Abstract: Process for transferring overlayed multiple ink patterns from the surface of a release blanket to a receiving surface on a container or other formed article being printed. A substantially transparent film is first formed on the release blanket, with each ink pattern being printed sequentially over this release film. Proper printing on the release film without picking the release film or previously applied ink films is obtained when certain adhesive and cohesive relationships are maintained between the ink films and the release film. An adhesive film may be formed on the article to be printed, or it may be formed over the ink films and the release film on the release blanket. The receiving surface on the article to be printed is brought into contact with the films on the release blanket, with a resulting total transfer of the films on the blanket to the surface of the article.

Abstract: A fusion adhesive comprising an olefin copolymer comprising 70 to 95 percent by weight ethylene, 0.5 to 10 percent by weight of an amide of an unsaturated carboxylic acid and 0.5 to 15 percent by weight of an unsaturated carboxylic acid, the use of such fusion adhesive to secure two objects together, especially a polymeric plastic composition to a metal composition.

Abstract: A method is disclosed for adhesively securing an open mesh, woven nylon or polyester scrim fabric to avoid distortion or movement of the individual yarns or thread members of said fabric said method comprising applying to said fabric a coating of a dispersion of a carboxylated copolymer of chloroprene and methacrylic acid and drying said coating thereby bonding the warp and fill yarns of said fabric together at their cross over points.

Abstract: Fibrous carbon material such as graphite cloth which is to be combined with a thermosetting resin and a boron containing compound to form a carbon-carbon composite is provided with a protective coating consisting of cured furfuryl alcohol copolymers. When formed into a laminate and heated to at least 2150.degree. C. to carbonize and at least partially graphitize the thermosetting resin, the boron greatly increases the interlaminar tensile strength while the coating protects the fibrous material from adverse effects of the boron which reduce the tensile strength in the directions of the fibers of the fibrous carbon material of the composite.

Abstract: Rubber-metal composite structures are provided wherein such structures comprise a metal substrate, at least a portion of at least one surface of such substrate is coated with a fused epoxy resin powder composition, and at least one elastomeric element, said elastomeric element being vulcanization bonded through an intermediate adhesive phase to at least a portion of the fused epoxy coating. Such composite structures exhibit improved resistance to corrosion.

Abstract: The specification discloses noncracking permanent adhesives which utilize mixtures of phenolic resins and methacrylate resins having a Mw greater than about 100,000 and preferably about 400,000 bonding plasticized vinyl resin coverings, e.g., PVC, to hard polymeric substrate surfaces such as ABS, etc. Also, it is preferable that the vinyl resin covering contain plasticizers which are no more than limited in compatibility with the adhesive. It is theorized that the adhesive mixture prevents migration of plasticizer from the plasticizer-containing vinyl resin covering into the adhesive and eventually into the polymeric substrate.

Abstract: An adhesion assistant or binder composition for bonding polyolefin surfaces with metal surfaces comprising an aqueous dispersion of an ethylene/vinyl acetate copolymer from 0.5 to 5 parts by weight based on 100 parts of the copolymer of a cross-linking peroxide compound and from 1 to 10 parts by weight based on 100 parts of the copolymer of a low-molecular-weight 1,2-polybutadiene; as well as a process for producing composite bodies by heat and pressure utilizing the above adhesion assistant between polyolefin surfaces and metal surfaces.

Abstract: Bonded textile sheet materials having improved water vapor absorbency can be manufactured by bonding the sheets with polymeric binders and additionally impregnating these sheets with glycidyl ethers, chlorohydrin compounds corresponding thereto and/or reaction products of the chlorohydrin compounds with compounds containing NH groups, and drying the impregnated sheets at elevated temperatures and at the same time fixing the impregnants by means of compounds containing NH groups.

Abstract: A nylon-base adhesive composition for metals is composed of 100 parts by weight of a mixture of nylon 11 and nylon 12 and about 2-40 parts by weight of nylon 6-12. The adhesive composition has excellent heat resistance and water resistance and is particularly useful for making cans. The properties of the adhesive composition can be further improved by adding thereto polyethylene, an ionomer, or a mixture thereof.A process for bonding steel sheets using the adhesive is also disclosed.

Abstract: Process for transferring overlayed multiple ink patterns from the surface of a release blanket to a receiving surface on a container or other formed article being printed. A substantially transparent film is first formed on the release blanket, with each ink pattern being printed sequentially over this release film. Proper printing on the release film without picking the release film or previously applied ink films is obtained when certain adhesive and cohesive relationships are maintained between the ink films and the release film. An adhesive film may be formed on the article to be printed, or it may be formed over the ink films and the release film on the release blanket. The receiving surface on the article to be printed is brought into contact with the films on the release blanket, with a resulting total transfer of the films on the blanket to the surface of the article.

Abstract: The adhesion of propylene polymer layers to enamel coated metal surfaces is improved by incorporating an adhesion promoting amount of a carboxyl modified polypropylene resin in the enamel.

Abstract: A metal laminate having high thermal stability is produced by forming a cured film layer of a thermally stable heterocyclic polymer such as polyamide imide having only a small volatile content on at least one surface of one or both of metal plates or foils such as aluminum, separately forming an adhesive layer of a thermally stable heterocyclic polymer having a thickness of one-third or less of the above film layer and containing a volatile matter in an amount of not more than 20% by weight, and then heat bonding both of the metal plates or foils through the above adhesive layer with the film layer being allowed to face the adhesive layer. The metal plates and foils are mutually insulated.

Abstract: Propylene polymers are heat sealed to enamel coated metal surfaces, the enamel having incorporated therein an adhesion promoting carboxyl modified polypropylene resin. The bond strength of the heat seal is improved by incorporating the carboxyl modified polypropylene resin in the enamel coating formulation dissolved in a hot (heated above 100.degree. C) organic solvent solution selected from aliphatic acids, alcohols and hydrocarbons having at least 10 carbon atoms.

Abstract: Making film adhesives from a thermosettable resin composition presents difficulties if the composition is not soluble in a volatile solvent, or not readily fusible without gelling prematurely, or undergoes undesirable advancement on being subjected to extrusion procedures.Such compositions in the form of solid particles can be made into film adhesives by coating a carrier with a readily-curable thermosettable resin composition, which is preferably tacky, applying the solid particles to the coating, and then curing the coating under conditions such that the particles of thermosettable resin composition remain curable.