N Only In Unlinked Side-chain Or Side-ring Patents (Class 156/331.2)
-
Patent number: 10577521Abstract: The present application provides compositions, methods of making the compositions, methods of using the compositions, and kits having instructions for using the compositions for providing a bond between synthetic polymers or between a synthetic polymer and another type of substrate.Type: GrantFiled: March 12, 2018Date of Patent: March 3, 2020Inventor: Donald W. Meyers
-
Patent number: 9458361Abstract: An curable adhesive composition that can form a cured product exhibiting high shear adhesion strength, peel adhesion strength and impact adhesion strength and exhibiting, in particular, excellent cold/hot cycle resistance of adhesion strength, includes (a) a 2-cyanoacrylic acid ester, (b) a high molecular-weight component, such as a polymer, compatible with the 2-cyanoacrylic acid ester, (c) a multifunctional 2-cyano-3-vinylacrylic acid ester, and (d) an onium salt represented by the following general formula (1): C+A???(1) wherein C+ represents an onium cation, A? represents an anion such provided that the anion does not substantially initiate polymerization of the 2-cyanoacrylic acid, in which the curable adhesive contains components (b)-(d) in predetermined amounts relative to 100 parts by mass of the component (a).Type: GrantFiled: December 3, 2013Date of Patent: October 4, 2016Assignee: TOAGOSEI CO., LTD.Inventors: Kenichi Ishizaki, Yushi Ando
-
Patent number: 9353299Abstract: A 2-cyanoacrylate-based adhesive composition includes a 2-cyanoacrylic acid ester (a) and an onium salt (b) represented by general formula C+A?. In the formula, C+ is an onium cation, and A? is a hydrogen sulfate anion, bisulfite anion, sulfonate anion represented by R1SO3? (where R1 is an alkyl group, perfluoroalkyl group having 3 to 10 carbon atoms, cycloalkyl group, vinyl group, aryl group, perfluoroaryl group, aralkyl group, or halogen atom), or bis(substituted sulfonyl)imide anion represented by (R2SO2)2N? (where R2 is an alkyl group, perfluoroalkyl group, or aryl group).) The 2-cyanoacrylate-based adhesive composition has good storage stability and has an excellent adhesion rate to metals and thermoplastic elastomers.Type: GrantFiled: September 6, 2013Date of Patent: May 31, 2016Assignee: TOAGOSEI CO., LTD.Inventors: Kenichi Ishizaki, Yushi Ando
-
Patent number: 9096778Abstract: The present invention relates generally to cyanoacrylate adhesives and, more particularly, to a one-part adhesive, comprising one or more 2-cyanoacrylate esters, one or more bis-silanes and optionally one or more monosilanes and to the use of said adhesive as an instant adhesive with improved water resistance.Type: GrantFiled: March 5, 2013Date of Patent: August 4, 2015Assignee: Henkel IP & Holding GmbHInventors: Ruth Kelly, Robert J. Lambert, Lisa McDonagh, Marisa Phelan, Cormac Duffy, Nigel Fay
-
Patent number: 8287687Abstract: The present disclosure provides a cyanoacrylate-based composition comprising a cyanoacrylate component and an organic micropulp component dispersed in a curable (meth)acrylic monomer matrix. The composition is particularly useful as an adhesive composition for zero gap applications.Type: GrantFiled: October 21, 2009Date of Patent: October 16, 2012Assignee: Henkel CorporationInventors: Gregory T. Schueneman, Shabbir Attarwala, Karen R. Brantl
-
Publication number: 20120078296Abstract: Synthesis methods for creating polymeric compounds comprising dihydroxyphenyl derivatives (DHPD), or DHPp i.e. polymers modified with DHPD, with desired surface active effects are described. The polymer backbone of DHPp has structural or performance features that can be tailored to control physical properties of DHPp, allowing it to be useful for different applications i.e. tissue adhesives or sealants, adhesion promoting coatings, and antifouling coatings.Type: ApplicationFiled: September 26, 2011Publication date: March 29, 2012Applicant: KNC NER ACQUISITION SUB, INC.Inventor: Bruce P. Lee
-
Patent number: 8070908Abstract: The present invention relates to (meth)acrylic adhesives with high impact resistance and no or low odor. The compositions comprise at least a (meth)acrylic ester E which may be obtained by esterification of an alcohol ALC and methacrylic or acrylic acid, said alcohol ALC contains at least 5 carbon atoms; and at least a rubber block co-polymer RS being solid at room temperature and which is a co-polymer of styrene and butadiene and/or isoprene and/or ethylene propylene diene monomer; and at least a polymer PL having pending (meth)acrylic groups and is a butadiene/acrylonitrile co-polymer with terminal (meth)acrylic groups or a polyurethane (meth)acrylate or an ester obtainable by esterification of an alcohol ALC-II and methacrylic or acrylic acid and which has a molecular weight between 200 and 9000 g/mol. Such combinations E-RS-PL have lower viscosity than PL and a combination E-RS.Type: GrantFiled: May 1, 2008Date of Patent: December 6, 2011Assignee: Sika Technology AGInventors: Shingo Tsuno, Ria De Cooman
-
Patent number: 7816487Abstract: A die-attach composition includes a resin such as a thermosetting resin, a hardener, and a low molecular weight oligomer diluent. A die-attach composition includes a polyimide in a major amount and a resin such as a thermosetting resin in a minor amount. The die-attach composition also includes a reactive polymer diluent. Combinations of the low molecular weight oligomer diluent and the reactive polymer diluent are included. The die-attach composition is applied to surface mount technology such as wire-bond dice. A computing system is also included that uses the die-attach composition.Type: GrantFiled: September 30, 2004Date of Patent: October 19, 2010Assignee: Intel CorporationInventors: Rahul N. Manepalli, Ravindra V. Tanikella
-
Patent number: 7687551Abstract: Adhesive compositions useful for laminating cellulosic substrates are formulated using an aqueous emulsion of a vinyl ester polymer such as polyvinyl acetate, one or more monomers or oligomers functionalized with (meth)acrylate groups, and a photoinitiator. The adhesive is cured by drying and exposing the adhesive to UV or visible light and is particularly useful for attaching clear films to cellulosic substrates such as paper and boxboard (e.g., in the manufacture of envelopes or folding cartons having windows).Type: GrantFiled: September 6, 2006Date of Patent: March 30, 2010Assignee: Henkel CorporationInventors: Alexander P. Mgaya, Balasubramaniam Ramalingam
-
Patent number: 7507461Abstract: Core-skin bonding is improved between honeycomb and composite face sheets by applying a nylon-based (polyamide) adhesive to the edge of the honeycomb prior to bonding. Edge coating of honeycomb with polyamide adhesives is useful in further increasing the bond strength between honeycomb and prepreg face sheets, especially when the matrix resin of the prepreg is designed to adhere the prepreg to the honeycomb.Type: GrantFiled: September 1, 2004Date of Patent: March 24, 2009Assignee: Hexcel CorporationInventors: Yen-Seine Wang, Robert Morrison, Clark Smith
-
Patent number: 7431793Abstract: An activator composition for accelerating hardening and achieving cure-through-volume of cyanoacrylate adhesives) comprising; (a) one or more compounds selected from the group consisting of :(i) pyrazine; or a pyrazine derivative; said pyrazine derivative being pyrazine substituted with at least one electron-releasing group; (ii) pyridine N oxides substituted with at least one electron-releasing group; or (iii) 2,6 pyridines being pyridines substituted in the 2- and 6-positions by substituents, at least one of the substituents being electron-releasing provided that both substituents are not methyl; and (b) a volatile solvent carrier for the compound.Type: GrantFiled: November 13, 2002Date of Patent: October 7, 2008Assignee: Loctite (R&D) LimitedInventors: Bernard Ryan, Hanns Misiak, James Houlihan
-
Publication number: 20080202683Abstract: The present invention relates to (meth)acrylic adhesives with high impact resistance and no or low odor. The compositions comprise at least a (meth)acrylic ester E which may be obtained by esterification of an alcohol ALC and methacrylic or acrylic acid, said alcohol ALC contains at least 5 carbon atoms; and at least a rubber block co-polymer RS being solid at room temperature and which is a co-polymer of styrene and butadiene and/or isoprene and/or ethylene propylene diene monomer; and at least a polymer PL having pending (meth)acrylic groups and is a butadiene/acrylonitrile co-polymer with terminal (meth)acrylic groups or a polyurethane (meth)acrylate or an ester obtainable by esterification of an alcohol ALC-II and methacrylic or acrylic acid and which has a molecular weight between 200 and 9000 g/mol. Such combinations E-RS-PL have lower viscosity than PL and a combination E-RS.Type: ApplicationFiled: May 1, 2008Publication date: August 28, 2008Applicant: SIKA TECHNOLOGY AGInventors: Shingo TSUNO, Ria DE COOMAN
-
Patent number: 7247388Abstract: A vulcanizable adhesive composition, which comprises 100 parts by weight of phenolxylylene resin or phenolbiphenyl resin, 10 to 1,000 parts by weight of resol-type phenol resin, 0 to 1,000 parts by weight of novolak-type phenol resin, 10 to 1,000 parts by weight of unvulcanized nitrile rubber and 10 to 500 parts by weight of chlorinated polyethylene, is effectively applied to (hydrogenated) nitrile rubber with a nitrile content of 18 to 48%, and has a suppression effect on a decrease in the adhesiveness even if exposed to dip in various cryogenic liquids such as flon gas, polyalkylene glycol, water, etc. for a long time.Type: GrantFiled: August 27, 2003Date of Patent: July 24, 2007Assignee: NOK CorporationInventors: Kiyofumi Fukasawa, Tomohiro Kaise
-
Patent number: 7025853Abstract: A moisture-reactive hot-melt composition, useful as an adhesive, is provided that has improved balance of open time and green strength. In particular, the composition is made from a polyol, a polyisocyante, and an acrylic polymer. Also provided are a method for making such compositions and a method for using such compositions for bonding substrates.Type: GrantFiled: June 12, 2003Date of Patent: April 11, 2006Assignee: Rohm and Haas CompanyInventor: Mark Alan Kesselmayer
-
Patent number: 6964799Abstract: A shrinkage control material for elastomeric molding. On a surface of a resilient metal wire, an adhesive layer of a halogenated polymer-based or olefin-based adhesive is disposed. An elastomeric molding includes the shrinkage control material and a elastomeric extrusion formed around the shrinkage control material to cover, the elastomeric extrusion being bonded by vulcanization to the shrinkage control material.Type: GrantFiled: October 5, 2000Date of Patent: November 15, 2005Assignees: Nippon Ply Co., Ltd., Showa Electric Wire & Cable Co., Ltd.Inventors: Seinosuke Mizuno, Yoshiyuki Nishi, Yasunari Ashida, Tatsumi Hirano
-
Publication number: 20040258937Abstract: The invention relates to an adhesive based on highly saturated, carboxylated nitrile-butadiene rubber (HXNBR), to its use, to processes for its preparation, to its use for the bonding of substrates and to products manufactured therewith.Type: ApplicationFiled: June 14, 2004Publication date: December 23, 2004Inventors: Dirk Achten, Martin Hoch, Martin Mezger, Rudiger Musch, Hans-Rafael Winkelbach, Roland Parg
-
Patent number: 6797107Abstract: A solid cyanoacrylate adhesive composition is disclosed which can be applied to a substrate in solid form and which polymerizes into an adhesive polymer upon liquefying. Preferably the solid cyanoacrylate composition liquefies at temperatures slightly above room temperature and polymerizes upon liquification. &egr;-caprolactones are used as a solidifying polymer with cyanoacrylate monomers and other additives to form the solid cyanoacrylate adhesive composition. The solid cyanoacrylate adhesive composition is easy to apply, especially stable in solid form and is capable of use in a variety of industrial, consumer and medical applications.Type: GrantFiled: May 2, 2003Date of Patent: September 28, 2004Assignee: Chemence, Inc.Inventor: Dimiter L. Kotzey
-
Patent number: 6673192Abstract: Primers for cyanoacrylate adhesives which are based on compounds having multiple amine groups thereon (“multi-amines”) which have at least three secondary or tertiary amine groups, at least one of which is a tertiary amine group. The multi-amine compounds are characterized by having thereon at least three terminal and/or pendant aliphatic hydrocarbon groups of at least 4 carbon atoms in length. Such primers give substantially improved bond strengths to cyanoacrylate adhesive bonded assemblies comprising a polyolefin substrate such as high density polyethylene, LDPE or polypropylene. The multi-amine may have a cascade, dendrimer, hyperbranched or comb-like structure.Type: GrantFiled: September 25, 1997Date of Patent: January 6, 2004Assignee: Loctite CorporationInventors: John G. Woods, Jean M. J. Fréchet
-
Patent number: 6667051Abstract: The invention is directed to a method including the steps of providing at least one layer of unlaminated elastin or unlaminated elastin-based materials or unlaminated tropoelastin materials. Then, the unlaminated elastin or unlaminated elastin-based materials or unlaminated tropoelastin materials is subjected to heating and pressing steps. The pressing step of the present invention is preferably conducted in the presence of steam. The laminated elastin or laminated elastin-based materials or laminated tropoelastin materials preferably comprises a multi-layer composite material. Typically, the step of adhering with an adhesive material the laminated elastin or laminated elastin-based materials or laminated tropoelastin materials is employed in order to achieve a water-tight engagement with the tissue substrate. A biogradable cyanacrylate glue is generally used in order to achieve quick and easy way to secure the patch in place and provide watertight fusion instantly.Type: GrantFiled: November 28, 2001Date of Patent: December 23, 2003Assignees: Providence Health System-OregonInventor: Kenton W. Gregory
-
Patent number: 6607632Abstract: A one-part adhesive composition for bonding glass including: (a) a cyanoacrylate monomer; (b) 15 to 60% w/w of at least one plasticizer by weight of the composition; (c) 0.01% to 5.0% w/w of at least one silane by weight of the composition.Type: GrantFiled: February 12, 1999Date of Patent: August 19, 2003Assignee: Loctite (R&D) LimitedInventors: Patrick F. McDonnell, Robert J. Lambert, Edward P. Scott, Gerard M. Wren, Marie McGuinness
-
Publication number: 20030125449Abstract: One aspect of the present invention is an adhesive composition formed from two packs. One pack includes an isocyanate-functional prepolymer formed by reacting a polyisocyanate with an alcohol (e.g., polyol). The isocyanate equivalents from the polyisocyanate exceed the hydroxyl equivalents from the alcohol. The second pack is an aqueous polymer emulsion. These two packs are combined to form the novel adhesive composition. Another aspect of the invention is a method for joining together two surfaces of wood products by application of an adhesive thereto. The first step in this method is to mist with water the wood product surfaces to be joined. An adhesive composition then is applied to the misted wood product surfaces. Alternatively, the water misting can be replaced with an aqueous emulsion being part of the adhesive composition. Finally, the adhesive composition is cured.Type: ApplicationFiled: November 19, 2001Publication date: July 3, 2003Inventors: Gang-Fung Chen, Gary J. Walworth
-
Patent number: 6551438Abstract: Disclosed are a method of manufacturing a magnetic head slider and a method of fixing row bars, which realize improved fabrication accuracy without increasing manufacturing costs and can prevent adhesion of a foreign matter to a magnetic head slider. After forming a number of thin film magnetic head devices on a wafer by thin film process, the wafer is cut into a plurality of row bars. Before a rail is formed in a predetermined surface of each of the row bars by photolithography, a surface opposite to the surface to be processed of the row bar is bonded and fixed to a support substrate of a wafer shape. A protective film obtained by conducting a heat treatment on a polyimide precursor at temperature lower than temperature at which the polyimide precursor becomes polyimide is formed on the surface of the support substrate. A curing agent film containing a curing agent which promotes setting of the adhesive for bonding the row bars is formed on the surface of the protective film.Type: GrantFiled: September 27, 2000Date of Patent: April 22, 2003Assignee: TDK CorporationInventor: Shigeki Tanemura
-
Patent number: 6547917Abstract: Organic compounds containing the structural element —N═C—S—S—C═N— are suitable in dilute solution as activators for the accelerated hardening of cyanoacrylate adhesives. As compared with the known accelerators, they have the following advantage: good accelerating action, but they nevertheless permit a long waiting time between application of the activator and application of the adhesive. In addition, they avoid spontaneous, merely superficial hardening.Type: GrantFiled: February 12, 2002Date of Patent: April 15, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Hanns Misiak, Ingolf Scheffler
-
Publication number: 20030066603Abstract: An adhesive composition useful for bonding silicone and other peroxide-cured elastomers is disclosed. The adhesive comprises a solvent, a crosslinker and a film former reactive with the elastomer for bonding the elastomer to a substrate. Preferably, the crosslinker is at least one organic compound having at least two maleimide groups, and the film former is a block copolymer with a polysilicone segment and a hard segment. A method of bonding an elastomer to a substrate, a composite and an article of manufacture are also disclosed.Type: ApplicationFiled: August 20, 2001Publication date: April 10, 2003Applicant: Lord CorporationInventors: James R. Halladay, Hoa Quach, Douglas H. Mowrey
-
Patent number: 6475331Abstract: This invention relates to cyanoacrylate-containing compositions that include, in addition to the cyanoacrylate component, the combination of two accelerators to improve fixture speeds on certain substrates.Type: GrantFiled: June 26, 2001Date of Patent: November 5, 2002Assignee: Henkel Loctite CorporationInventors: John T. O'Connor, Roger J. Grismala
-
Patent number: 6306243Abstract: The pH-modified monomer and polymer compositions are useful as biomedical and surgical adhesives, sealants, implants and bioactive agent release carriers or matrices. They comprise a monomer or polymer; and an effective amount of an acidic or basic pH modifier effective to modify the pH of an immediate in vivo environment of the composition to a pH range at which the polymer biodegrades at a different rate than at physiologic pH. The invention also relates to in vivo applications in which surfaces are joined or treated with such pH-modified biocompatible compositions.Type: GrantFiled: June 7, 2000Date of Patent: October 23, 2001Assignee: Closure Medical CorporationInventors: Jeffrey G. Clark, Jeffrey C. Leung
-
Patent number: 6294629Abstract: This invention relates to cyanoacrylate-containing compositions that include, in addition to the cyanoacrylate component, the combination of two accelerators to improve fixture speeds on certain substrates.Type: GrantFiled: November 23, 1999Date of Patent: September 25, 2001Assignee: Loctite (R&D) LimitedInventors: Liam P. O'Dwyer, Fergal W. Tierney