N Only In Unlinked Side-chain Or Side-ring Patents (Class 156/331.2)
  • Patent number: 9458361
    Abstract: An curable adhesive composition that can form a cured product exhibiting high shear adhesion strength, peel adhesion strength and impact adhesion strength and exhibiting, in particular, excellent cold/hot cycle resistance of adhesion strength, includes (a) a 2-cyanoacrylic acid ester, (b) a high molecular-weight component, such as a polymer, compatible with the 2-cyanoacrylic acid ester, (c) a multifunctional 2-cyano-3-vinylacrylic acid ester, and (d) an onium salt represented by the following general formula (1): C+A???(1) wherein C+ represents an onium cation, A? represents an anion such provided that the anion does not substantially initiate polymerization of the 2-cyanoacrylic acid, in which the curable adhesive contains components (b)-(d) in predetermined amounts relative to 100 parts by mass of the component (a).
    Type: Grant
    Filed: December 3, 2013
    Date of Patent: October 4, 2016
    Assignee: TOAGOSEI CO., LTD.
    Inventors: Kenichi Ishizaki, Yushi Ando
  • Patent number: 9353299
    Abstract: A 2-cyanoacrylate-based adhesive composition includes a 2-cyanoacrylic acid ester (a) and an onium salt (b) represented by general formula C+A?. In the formula, C+ is an onium cation, and A? is a hydrogen sulfate anion, bisulfite anion, sulfonate anion represented by R1SO3? (where R1 is an alkyl group, perfluoroalkyl group having 3 to 10 carbon atoms, cycloalkyl group, vinyl group, aryl group, perfluoroaryl group, aralkyl group, or halogen atom), or bis(substituted sulfonyl)imide anion represented by (R2SO2)2N? (where R2 is an alkyl group, perfluoroalkyl group, or aryl group).) The 2-cyanoacrylate-based adhesive composition has good storage stability and has an excellent adhesion rate to metals and thermoplastic elastomers.
    Type: Grant
    Filed: September 6, 2013
    Date of Patent: May 31, 2016
    Assignee: TOAGOSEI CO., LTD.
    Inventors: Kenichi Ishizaki, Yushi Ando
  • Patent number: 9096778
    Abstract: The present invention relates generally to cyanoacrylate adhesives and, more particularly, to a one-part adhesive, comprising one or more 2-cyanoacrylate esters, one or more bis-silanes and optionally one or more monosilanes and to the use of said adhesive as an instant adhesive with improved water resistance.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: August 4, 2015
    Assignee: Henkel IP & Holding GmbH
    Inventors: Ruth Kelly, Robert J. Lambert, Lisa McDonagh, Marisa Phelan, Cormac Duffy, Nigel Fay
  • Patent number: 8287687
    Abstract: The present disclosure provides a cyanoacrylate-based composition comprising a cyanoacrylate component and an organic micropulp component dispersed in a curable (meth)acrylic monomer matrix. The composition is particularly useful as an adhesive composition for zero gap applications.
    Type: Grant
    Filed: October 21, 2009
    Date of Patent: October 16, 2012
    Assignee: Henkel Corporation
    Inventors: Gregory T. Schueneman, Shabbir Attarwala, Karen R. Brantl
  • Publication number: 20120078296
    Abstract: Synthesis methods for creating polymeric compounds comprising dihydroxyphenyl derivatives (DHPD), or DHPp i.e. polymers modified with DHPD, with desired surface active effects are described. The polymer backbone of DHPp has structural or performance features that can be tailored to control physical properties of DHPp, allowing it to be useful for different applications i.e. tissue adhesives or sealants, adhesion promoting coatings, and antifouling coatings.
    Type: Application
    Filed: September 26, 2011
    Publication date: March 29, 2012
    Applicant: KNC NER ACQUISITION SUB, INC.
    Inventor: Bruce P. Lee
  • Patent number: 8070908
    Abstract: The present invention relates to (meth)acrylic adhesives with high impact resistance and no or low odor. The compositions comprise at least a (meth)acrylic ester E which may be obtained by esterification of an alcohol ALC and methacrylic or acrylic acid, said alcohol ALC contains at least 5 carbon atoms; and at least a rubber block co-polymer RS being solid at room temperature and which is a co-polymer of styrene and butadiene and/or isoprene and/or ethylene propylene diene monomer; and at least a polymer PL having pending (meth)acrylic groups and is a butadiene/acrylonitrile co-polymer with terminal (meth)acrylic groups or a polyurethane (meth)acrylate or an ester obtainable by esterification of an alcohol ALC-II and methacrylic or acrylic acid and which has a molecular weight between 200 and 9000 g/mol. Such combinations E-RS-PL have lower viscosity than PL and a combination E-RS.
    Type: Grant
    Filed: May 1, 2008
    Date of Patent: December 6, 2011
    Assignee: Sika Technology AG
    Inventors: Shingo Tsuno, Ria De Cooman
  • Patent number: 7816487
    Abstract: A die-attach composition includes a resin such as a thermosetting resin, a hardener, and a low molecular weight oligomer diluent. A die-attach composition includes a polyimide in a major amount and a resin such as a thermosetting resin in a minor amount. The die-attach composition also includes a reactive polymer diluent. Combinations of the low molecular weight oligomer diluent and the reactive polymer diluent are included. The die-attach composition is applied to surface mount technology such as wire-bond dice. A computing system is also included that uses the die-attach composition.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: October 19, 2010
    Assignee: Intel Corporation
    Inventors: Rahul N. Manepalli, Ravindra V. Tanikella
  • Patent number: 7687551
    Abstract: Adhesive compositions useful for laminating cellulosic substrates are formulated using an aqueous emulsion of a vinyl ester polymer such as polyvinyl acetate, one or more monomers or oligomers functionalized with (meth)acrylate groups, and a photoinitiator. The adhesive is cured by drying and exposing the adhesive to UV or visible light and is particularly useful for attaching clear films to cellulosic substrates such as paper and boxboard (e.g., in the manufacture of envelopes or folding cartons having windows).
    Type: Grant
    Filed: September 6, 2006
    Date of Patent: March 30, 2010
    Assignee: Henkel Corporation
    Inventors: Alexander P. Mgaya, Balasubramaniam Ramalingam
  • Patent number: 7507461
    Abstract: Core-skin bonding is improved between honeycomb and composite face sheets by applying a nylon-based (polyamide) adhesive to the edge of the honeycomb prior to bonding. Edge coating of honeycomb with polyamide adhesives is useful in further increasing the bond strength between honeycomb and prepreg face sheets, especially when the matrix resin of the prepreg is designed to adhere the prepreg to the honeycomb.
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: March 24, 2009
    Assignee: Hexcel Corporation
    Inventors: Yen-Seine Wang, Robert Morrison, Clark Smith
  • Patent number: 7431793
    Abstract: An activator composition for accelerating hardening and achieving cure-through-volume of cyanoacrylate adhesives) comprising; (a) one or more compounds selected from the group consisting of :(i) pyrazine; or a pyrazine derivative; said pyrazine derivative being pyrazine substituted with at least one electron-releasing group; (ii) pyridine N oxides substituted with at least one electron-releasing group; or (iii) 2,6 pyridines being pyridines substituted in the 2- and 6-positions by substituents, at least one of the substituents being electron-releasing provided that both substituents are not methyl; and (b) a volatile solvent carrier for the compound.
    Type: Grant
    Filed: November 13, 2002
    Date of Patent: October 7, 2008
    Assignee: Loctite (R&D) Limited
    Inventors: Bernard Ryan, Hanns Misiak, James Houlihan
  • Publication number: 20080202683
    Abstract: The present invention relates to (meth)acrylic adhesives with high impact resistance and no or low odor. The compositions comprise at least a (meth)acrylic ester E which may be obtained by esterification of an alcohol ALC and methacrylic or acrylic acid, said alcohol ALC contains at least 5 carbon atoms; and at least a rubber block co-polymer RS being solid at room temperature and which is a co-polymer of styrene and butadiene and/or isoprene and/or ethylene propylene diene monomer; and at least a polymer PL having pending (meth)acrylic groups and is a butadiene/acrylonitrile co-polymer with terminal (meth)acrylic groups or a polyurethane (meth)acrylate or an ester obtainable by esterification of an alcohol ALC-II and methacrylic or acrylic acid and which has a molecular weight between 200 and 9000 g/mol. Such combinations E-RS-PL have lower viscosity than PL and a combination E-RS.
    Type: Application
    Filed: May 1, 2008
    Publication date: August 28, 2008
    Applicant: SIKA TECHNOLOGY AG
    Inventors: Shingo TSUNO, Ria DE COOMAN
  • Patent number: 7247388
    Abstract: A vulcanizable adhesive composition, which comprises 100 parts by weight of phenolxylylene resin or phenolbiphenyl resin, 10 to 1,000 parts by weight of resol-type phenol resin, 0 to 1,000 parts by weight of novolak-type phenol resin, 10 to 1,000 parts by weight of unvulcanized nitrile rubber and 10 to 500 parts by weight of chlorinated polyethylene, is effectively applied to (hydrogenated) nitrile rubber with a nitrile content of 18 to 48%, and has a suppression effect on a decrease in the adhesiveness even if exposed to dip in various cryogenic liquids such as flon gas, polyalkylene glycol, water, etc. for a long time.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: July 24, 2007
    Assignee: NOK Corporation
    Inventors: Kiyofumi Fukasawa, Tomohiro Kaise
  • Patent number: 7025853
    Abstract: A moisture-reactive hot-melt composition, useful as an adhesive, is provided that has improved balance of open time and green strength. In particular, the composition is made from a polyol, a polyisocyante, and an acrylic polymer. Also provided are a method for making such compositions and a method for using such compositions for bonding substrates.
    Type: Grant
    Filed: June 12, 2003
    Date of Patent: April 11, 2006
    Assignee: Rohm and Haas Company
    Inventor: Mark Alan Kesselmayer
  • Patent number: 6964799
    Abstract: A shrinkage control material for elastomeric molding. On a surface of a resilient metal wire, an adhesive layer of a halogenated polymer-based or olefin-based adhesive is disposed. An elastomeric molding includes the shrinkage control material and a elastomeric extrusion formed around the shrinkage control material to cover, the elastomeric extrusion being bonded by vulcanization to the shrinkage control material.
    Type: Grant
    Filed: October 5, 2000
    Date of Patent: November 15, 2005
    Assignees: Nippon Ply Co., Ltd., Showa Electric Wire & Cable Co., Ltd.
    Inventors: Seinosuke Mizuno, Yoshiyuki Nishi, Yasunari Ashida, Tatsumi Hirano
  • Publication number: 20040258937
    Abstract: The invention relates to an adhesive based on highly saturated, carboxylated nitrile-butadiene rubber (HXNBR), to its use, to processes for its preparation, to its use for the bonding of substrates and to products manufactured therewith.
    Type: Application
    Filed: June 14, 2004
    Publication date: December 23, 2004
    Inventors: Dirk Achten, Martin Hoch, Martin Mezger, Rudiger Musch, Hans-Rafael Winkelbach, Roland Parg
  • Patent number: 6797107
    Abstract: A solid cyanoacrylate adhesive composition is disclosed which can be applied to a substrate in solid form and which polymerizes into an adhesive polymer upon liquefying. Preferably the solid cyanoacrylate composition liquefies at temperatures slightly above room temperature and polymerizes upon liquification. &egr;-caprolactones are used as a solidifying polymer with cyanoacrylate monomers and other additives to form the solid cyanoacrylate adhesive composition. The solid cyanoacrylate adhesive composition is easy to apply, especially stable in solid form and is capable of use in a variety of industrial, consumer and medical applications.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: September 28, 2004
    Assignee: Chemence, Inc.
    Inventor: Dimiter L. Kotzey
  • Patent number: 6673192
    Abstract: Primers for cyanoacrylate adhesives which are based on compounds having multiple amine groups thereon (“multi-amines”) which have at least three secondary or tertiary amine groups, at least one of which is a tertiary amine group. The multi-amine compounds are characterized by having thereon at least three terminal and/or pendant aliphatic hydrocarbon groups of at least 4 carbon atoms in length. Such primers give substantially improved bond strengths to cyanoacrylate adhesive bonded assemblies comprising a polyolefin substrate such as high density polyethylene, LDPE or polypropylene. The multi-amine may have a cascade, dendrimer, hyperbranched or comb-like structure.
    Type: Grant
    Filed: September 25, 1997
    Date of Patent: January 6, 2004
    Assignee: Loctite Corporation
    Inventors: John G. Woods, Jean M. J. Fr├ęchet
  • Patent number: 6667051
    Abstract: The invention is directed to a method including the steps of providing at least one layer of unlaminated elastin or unlaminated elastin-based materials or unlaminated tropoelastin materials. Then, the unlaminated elastin or unlaminated elastin-based materials or unlaminated tropoelastin materials is subjected to heating and pressing steps. The pressing step of the present invention is preferably conducted in the presence of steam. The laminated elastin or laminated elastin-based materials or laminated tropoelastin materials preferably comprises a multi-layer composite material. Typically, the step of adhering with an adhesive material the laminated elastin or laminated elastin-based materials or laminated tropoelastin materials is employed in order to achieve a water-tight engagement with the tissue substrate. A biogradable cyanacrylate glue is generally used in order to achieve quick and easy way to secure the patch in place and provide watertight fusion instantly.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: December 23, 2003
    Assignees: Providence Health System-Oregon
    Inventor: Kenton W. Gregory
  • Patent number: 6607632
    Abstract: A one-part adhesive composition for bonding glass including: (a) a cyanoacrylate monomer; (b) 15 to 60% w/w of at least one plasticizer by weight of the composition; (c) 0.01% to 5.0% w/w of at least one silane by weight of the composition.
    Type: Grant
    Filed: February 12, 1999
    Date of Patent: August 19, 2003
    Assignee: Loctite (R&D) Limited
    Inventors: Patrick F. McDonnell, Robert J. Lambert, Edward P. Scott, Gerard M. Wren, Marie McGuinness
  • Publication number: 20030125449
    Abstract: One aspect of the present invention is an adhesive composition formed from two packs. One pack includes an isocyanate-functional prepolymer formed by reacting a polyisocyanate with an alcohol (e.g., polyol). The isocyanate equivalents from the polyisocyanate exceed the hydroxyl equivalents from the alcohol. The second pack is an aqueous polymer emulsion. These two packs are combined to form the novel adhesive composition. Another aspect of the invention is a method for joining together two surfaces of wood products by application of an adhesive thereto. The first step in this method is to mist with water the wood product surfaces to be joined. An adhesive composition then is applied to the misted wood product surfaces. Alternatively, the water misting can be replaced with an aqueous emulsion being part of the adhesive composition. Finally, the adhesive composition is cured.
    Type: Application
    Filed: November 19, 2001
    Publication date: July 3, 2003
    Inventors: Gang-Fung Chen, Gary J. Walworth
  • Patent number: 6551438
    Abstract: Disclosed are a method of manufacturing a magnetic head slider and a method of fixing row bars, which realize improved fabrication accuracy without increasing manufacturing costs and can prevent adhesion of a foreign matter to a magnetic head slider. After forming a number of thin film magnetic head devices on a wafer by thin film process, the wafer is cut into a plurality of row bars. Before a rail is formed in a predetermined surface of each of the row bars by photolithography, a surface opposite to the surface to be processed of the row bar is bonded and fixed to a support substrate of a wafer shape. A protective film obtained by conducting a heat treatment on a polyimide precursor at temperature lower than temperature at which the polyimide precursor becomes polyimide is formed on the surface of the support substrate. A curing agent film containing a curing agent which promotes setting of the adhesive for bonding the row bars is formed on the surface of the protective film.
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: April 22, 2003
    Assignee: TDK Corporation
    Inventor: Shigeki Tanemura
  • Patent number: 6547917
    Abstract: Organic compounds containing the structural element —N═C—S—S—C═N— are suitable in dilute solution as activators for the accelerated hardening of cyanoacrylate adhesives. As compared with the known accelerators, they have the following advantage: good accelerating action, but they nevertheless permit a long waiting time between application of the activator and application of the adhesive. In addition, they avoid spontaneous, merely superficial hardening.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: April 15, 2003
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hanns Misiak, Ingolf Scheffler
  • Publication number: 20030066603
    Abstract: An adhesive composition useful for bonding silicone and other peroxide-cured elastomers is disclosed. The adhesive comprises a solvent, a crosslinker and a film former reactive with the elastomer for bonding the elastomer to a substrate. Preferably, the crosslinker is at least one organic compound having at least two maleimide groups, and the film former is a block copolymer with a polysilicone segment and a hard segment. A method of bonding an elastomer to a substrate, a composite and an article of manufacture are also disclosed.
    Type: Application
    Filed: August 20, 2001
    Publication date: April 10, 2003
    Applicant: Lord Corporation
    Inventors: James R. Halladay, Hoa Quach, Douglas H. Mowrey
  • Patent number: 6475331
    Abstract: This invention relates to cyanoacrylate-containing compositions that include, in addition to the cyanoacrylate component, the combination of two accelerators to improve fixture speeds on certain substrates.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: November 5, 2002
    Assignee: Henkel Loctite Corporation
    Inventors: John T. O'Connor, Roger J. Grismala
  • Patent number: 6306243
    Abstract: The pH-modified monomer and polymer compositions are useful as biomedical and surgical adhesives, sealants, implants and bioactive agent release carriers or matrices. They comprise a monomer or polymer; and an effective amount of an acidic or basic pH modifier effective to modify the pH of an immediate in vivo environment of the composition to a pH range at which the polymer biodegrades at a different rate than at physiologic pH. The invention also relates to in vivo applications in which surfaces are joined or treated with such pH-modified biocompatible compositions.
    Type: Grant
    Filed: June 7, 2000
    Date of Patent: October 23, 2001
    Assignee: Closure Medical Corporation
    Inventors: Jeffrey G. Clark, Jeffrey C. Leung
  • Patent number: 6294629
    Abstract: This invention relates to cyanoacrylate-containing compositions that include, in addition to the cyanoacrylate component, the combination of two accelerators to improve fixture speeds on certain substrates.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: September 25, 2001
    Assignee: Loctite (R&D) Limited
    Inventors: Liam P. O'Dwyer, Fergal W. Tierney