Hydrocarbon Resin Patents (Class 156/334)
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Patent number: 5024710Abstract: A novel method is disclosed for producing specular surfaces, composed of pure carbon, on carbon-carbon composites of arbitrary weave configuration. The method utilizes a thin sheet of fine grained polycrystalline graphite as a stress-isolating interlayer between the composite substrate and the specular surface layer. The interlayer is bonded to the carbon-carbon substrate with a high char yield carbonizable adhesive. An outer layer of glassy carbon is then applied using a high char yield resin solution or (lacquer). The resulting assembly is then carbonized to convert all uncarbonized polymer to carbon. The interlayer prevents the propagation of the substrate carbon-carbon composite's crack structure to the glossy carbonized polymer surface thus formed, resulting in a high degree of specularity and zero gas permeability.Type: GrantFiled: March 9, 1990Date of Patent: June 18, 1991Assignee: The Aerospace CorporationInventors: Patrick M. Sheaffer, James A. Noblet
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Patent number: 5021113Abstract: An adhesive composition comprising a plurality of selectively hydrogenated block copolymers, each of said block copolymers comprising at least one polymeric block containing predominantly monoalkenyl aromatic hydrocarbon monomer units and at least one polymeric block containing predominantly conjugated diolefin monomer units, at least one of which block copolymers is carboxylated and at least one of which block copolymers is not carboxylated and laminated structures comprising a plurality of polymeric layers tied together with said adhesive composition. The adhesive composition contains a relatively minor amount of carboxyl groups, on average, per polymer chain in the composition and is particularly useful in the preparation of laminated structures via coextrusion or similar processes, wherein the various layers are brought together in the molten phase while in motion, when one or more layers in the laminated structure comprises a polar group reactive with the carboxyl groups.Type: GrantFiled: June 25, 1990Date of Patent: June 4, 1991Assignee: Shell Oil CompanyInventors: Andrea Sanders, Glenn R. Himes
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Patent number: 5013785Abstract: In the present invention, a polymer having a number average molecular weight (Mn) of from 200 to 40,000 and a glass transition point of from -75.degree. C. to +10.degree. C. which is obtained by the cationic polymerization of a branched alpha-olenin is used as a tackifier (a tacky producer) for a hot melt adhesive or a pressure-sensitive adhesive. An adhesive composition containing the polymer described above as a tackifier has excellent heat resistance, hue, weather resistance, and the like and has such excellent characteristics that its odor is weak.Type: GrantFiled: August 8, 1988Date of Patent: May 7, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Kinya Mizui
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Patent number: 4963218Abstract: A method of preserving or otherwise reinforcing the thin, pre-existing tissue-like paper patterns used in dressmaking, crafts, and the like, in which a sturdy backing paper is bonded to the thin, pre-existing tissue-like paper pattern pieces allowing the pattern pieces to be reused many times without deterioration, which method may be practiced without extensive commercial equipment.Type: GrantFiled: June 23, 1989Date of Patent: October 16, 1990Inventor: Tina N. Rainey
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Patent number: 4956207Abstract: Rigid substrates for case and carton sealing and traymaking applications are bonded by spray application of a hot melt adhesive composition comprising 25 to 50 percent of an isotactic thermoplastic polybutene-1/ethylene copolymer containing from about 5.5 to about 10% by weight ethylene; 20 to 60 percent of a tackifier; 15 to 30 percent of an amorphous diluent having a softening point greater than 90.degree. C.; 0 to 2 percent antioxidant; and 0 to 10 percent wax or oil.Type: GrantFiled: November 14, 1988Date of Patent: September 11, 1990Assignee: National Starch and Chemical Investment Holding CorporationInventors: Thomas F. Kauffman, Paul P. Puletti
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Patent number: 4942195Abstract: Thus, the present invention is directed to hot melt adhesive compositions suitable for bookbinding application comprising tackifying resins, at least one wax diluent and a substantially radial styrene-butadiene block copolymer, the copolymer having a styrene content greater than about 35% by weight, a modulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than about 1000 cps.Type: GrantFiled: August 17, 1988Date of Patent: July 17, 1990Assignee: National Starch and Chemical Investment Holding CorporationInventors: Thomas P. Flanagan, Paul Puletti
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Patent number: 4937138Abstract: A hot melt adhesive, a laminar structure, and non-woven article fabricated from a blend comprising:from about 50 percent by weight to about 5 percent by weight of a butene-1 homopolymer or copolymer;from about 50 percent by weight to about 95 percent by weight of a tackifying resin;from a 0.01 to about 1 phr of a nucleating agent;up to about 1 part per hundred (phr) of a stabilizer;up to about 30 phr of a plasticizer; andup to about 30 phr of a wax.Type: GrantFiled: February 29, 1988Date of Patent: June 26, 1990Assignee: Shell Oil CompanyInventor: Simon Mostert
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Patent number: 4933235Abstract: Novel rubber-based adhesive coatings adapted for use as a primer coating for pipelines, which coatings include a reagent which inhibits formation of hydroxide ions resulting from electrons generated by cathodic protection, and novel protective pipewrap systems including same.Type: GrantFiled: November 16, 1988Date of Patent: June 12, 1990Assignee: The Kendall CompanyInventor: Jordan D. Kellner
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Patent number: 4923549Abstract: A multilayer polymeric film having dead bend characteristics which are substantially planar isotropic is a laminate of at least two layers of one or more polymeric films, in which:A. each polymeric film layer is highly oriented in one direction, such that each polymeric film layer has dead bend properties with respect to bending deformations substantially normal to the direction of orientation; andB. the direction of orientation of each polymeric film layer forms an angle of at least about 30 degrees with the direction of orientation of each adjacent polymeric film layer.A method for making the multilayer polymeric film having dead bend characteristics also is provided.Type: GrantFiled: June 30, 1989Date of Patent: May 8, 1990Assignee: Kimberly-Clark CorporationInventor: Steven B. Warner
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Patent number: 4919976Abstract: Adhesive tapes comprised of a curable composition comprising: (A) at least one polymer selected from the group consisting of ethylene/alphaolefin copolymer, ethylene/alphaolefin/nonconjugated polyene terpolymer, polyacrylate, polymethacrylate, polyisoprene, polyacrylonitrile, polymethacrylonitrile and polybutadiene, said polymer having a number average molecular weight of between about 500 and about 14,000; (B) an effective amount of curative having an activation temperature of at least about 100.degree. C; and (C) (optionally) a blowing agent possess admirable qualities for use as insulating compositions. Also disclosed are composites comprised of a substrate having cured insulating tape compositions adhered thereto.Type: GrantFiled: May 8, 1989Date of Patent: April 24, 1990Assignee: Uniroyal Chemical Company, Inc.Inventors: Frank C. Cesare, Robert G. Davis, William D. Sigworth
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Patent number: 4911983Abstract: An adhesive made from a thermosetting resin composition consisting of (a) a condensed polycyclic aromatic compound, (b) an aromatic crosslinking agent and (c) an acid catalyst is applied to each surface of adherends treated with a particular surface treating agent and heated at a temperature of 100.degree.-400.degree. C. in an oxidizing or non-oxidizing atmosphere to produce an adhesion structure. In order to provide a conductive adhesion structure, a conductive promotion catalyst is included in the adhesive. Further, a carbonaceous or graphitic adhesion structure is obtained by carbonization or graphitization of the adhesion structure.Type: GrantFiled: December 5, 1986Date of Patent: March 27, 1990Assignee: Ibiden Company, Ltd.Inventors: Sugio Otani, Hiroya Kakegawa
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Patent number: 4902370Abstract: This invention presents a series of synthetic based cold seal adhesives which are capable of forming a strong bond at room temperature, yet which may be reeled up without blocking and stored for extended periods of time. Such adhesives can be used in place of the natural rubber based cold seal adhesives currently used, and thus, can be employed in any packaging application where cold seal properties are desirable.Type: GrantFiled: August 17, 1989Date of Patent: February 20, 1990Assignee: National Starch and Chemical CorporationInventors: Richard A. Dust, Peter Causton
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Patent number: 4880487Abstract: A hot melt adhesive composition which is especially useful for bonding polyamide article to surfaces, particularly polyamide surfaces. The composition contains an ethylene-vinyl ester copolymer or a polyamide polymer, and additionally contains a poly(p-hydroxystyrene) homopolymer or a copolymer of poly(p-hydroxystyrene) with a C.sub.1 to C.sub.4 alkyl acrylate.Type: GrantFiled: June 24, 1988Date of Patent: November 14, 1989Assignee: Hoechst Celanese CorporationInventors: Michael T. Sheehan, Bakulesh N. Shah
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Patent number: 4875964Abstract: The liquid mixtures according to the invention comprise at least one ethylene polymer (A) and at least one solvent (B), and are characterized in that:(a) the ethylene polymer (A) comprises at least one terpolymer having a fluidity index comprised between 2 and 500 dg/min and comprising:from 83 to 95.7 moles % of units derived from ethylene,from 4 to 15 moles % of units derived from at least one alkyl acrylate or methacrylate, the alkyl group having from 1 to 6 atoms of carbon, andfrom 0.3 to 2 moles % of units derived from maleic anhydride,(b) the solvent (B) is selected from amongst aliphatic, cycloaliphatic and aromatic hydrocarbons having from 5 to 12 atoms of carbon, dechlorinated solvents and esters.The process comprises in a first step the dissolution of polymer (A), by stirring, in the solvent (B) at a temperature T (expressed in Celcius degrees) such that: 35.ltoreq.T.ltoreq..theta., .theta. being the boiling temperature of the solvent (B).Type: GrantFiled: December 16, 1986Date of Patent: October 24, 1989Assignee: Societe Chimique Des Charbonnages S.A.Inventor: Hert Marius
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Patent number: 4857131Abstract: A two-part, heat stable, peroxide-free adhesive that can be mixed in equal parts with rapid cure for the bonding of plastics and metals has been discussed. Part A of the adhesive contains a polymeric material, an olefinically unsaturated monomer, an acid material, a compound containing a sulfonyl halide group, and a compound containing a transition metal; and Part B contains a polymeric material (preferably a phenoxy resin) and monomer of the same class and a Zn, Cu or Cd metal powder.Type: GrantFiled: November 27, 1987Date of Patent: August 15, 1989Assignee: Lord CorporationInventors: Dennis J. Damico, Kenneth W. Mushrush, Ruth M. Bennett
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Patent number: 4855172Abstract: A roofing adhesive particularly suited for use in connection with membrane roofing materials such as EPDM or neoprene is preferably compounded from butyl rubber, a cross-linking system for the butyl rubber and a tackifier. The tensile strength, elongation, modulus at 300% elongation and modulus at failure of the composition are adjusted within range by choice of components and concentration. The adhesive composition may preferably be formed into a tape for joining sheets of the membrane roofing material.Type: GrantFiled: October 16, 1987Date of Patent: August 8, 1989Inventor: Jessie T. Chiu
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Patent number: 4844765Abstract: Lamination of a tufted, primary carpet backing to a secondary backing is conducted using a composite hot melt adhesive in sheet form. The composite adhesive overcomes the unfavorable temperature-viscosity gradient within the carpet structure during the lamination process, yielding tufted pile carpets with good tuft encapsulation, tuft bind strength and delamination strength. Also disclosed are hot melt adhesive compositions suitable for use in sheet form in such a process.Type: GrantFiled: October 14, 1987Date of Patent: July 4, 1989Assignee: Amoco CorporationInventor: Robert A. Reith
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Patent number: 4826939Abstract: Disclosed are highly amorphous olefin terpolymers from propylene, 1-hexene, and ethylene in which the ethylene units are incorporated in the polymer chain in a highly random manner, and a process for producing such terpolymers.Type: GrantFiled: August 31, 1987Date of Patent: May 2, 1989Assignee: Eastman Kodak CompanyInventor: Richard K. Stuart, Jr.
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Patent number: 4824500Abstract: Damaged composites are repaired by use of a rubber modified vinyl ester resin composition as either an adhesive for bonding metal or cured composite to the area surrounding the damaged area or by placing an uncured reinforcing material saturated with a rubber modified vinyl ester resin composition over the prepared damaged zone and curing in place.Type: GrantFiled: November 3, 1987Date of Patent: April 25, 1989Assignee: The Dow Chemical CompanyInventors: Warren D. White, Paul M. Puckett, Larry T. Blankenship, Mary N. White
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Patent number: 4824512Abstract: Rubber based adhesives containing liquid stereospecific polybutadiene rubber, one or more hardeners or hardener systems, fillers and optionally primers, which contain one or more chemically irreversibly depolymerized solid rubbers of natural or synthetic origin in quantities of from 1.5 to 5% by weight, based on the sum of the constituents, to a process for the production of these low-viscosity rubber-based adhesives by chemically irreversible depolymerization of one or more solid rubbers of natural or synthetic origin, and to the use of these low-viscosity rubber-based adhesives in the bonding of metal components in automotive manufacturing.Type: GrantFiled: July 24, 1987Date of Patent: April 25, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Hans-Peter Kohlstadt
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Patent number: 4816097Abstract: A method of manufacturing a non-metallic honeycomb having a perforated septum embedded therein in a plane extending perpendicularly to cell walls of the honeycomb, the cell walls of the honeycomb each having discontinuous opposite outer edge surfaces, including the steps of protecting the cell walls with a protectant mixture applied to one of the outer edge surfaces; and laser drilling the septum with a plurality of laser beams originating from a point exterior to the cell walls opposite the covered edge surface in a direction parallel to said cell walls and perpendicular to the plane of the septum, the protectant mixture covering an area of the outer edge surface sufficient to prevent damage to the cell walls.Type: GrantFiled: April 5, 1988Date of Patent: March 28, 1989Assignee: The Boeing CompanyInventors: Charles J. Williams, Robert A. Coleman
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Patent number: 4812363Abstract: A coupling agent for chemically linking metal substrates to thermoset polymers is composed of a hydrophobic polymer backbone having functional groups attached thereto at spaced intervals, the functional groups having the ability to form chemical bonds to both the metal substrate and the thermosetting polymeric resin. In a preferred embodiment, the hydrophobic polymeric coupling agent comprises mercaptoester functional groups placed along a strong, hydrophobic polymeric backbone. This polymeric backbone preferably comprises polyethylene resulting in an ethylene mercaptoester (EME) copolymer.Type: GrantFiled: October 26, 1987Date of Patent: March 14, 1989Inventors: James P. Bell, Randall G. Schmidt
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Patent number: 4810565Abstract: A fire retardant composite roofing material comprising an upper layer of a fire retardant EPDM material and a lower layer of a non-fire retardant EPDM material, wherein this composite material is a cured sheet membrane, a vulcanizable flashing material, or non-vulcanizing flashing material.Type: GrantFiled: July 29, 1987Date of Patent: March 7, 1989Assignee: The Firestone Tire & Rubber CompanyInventors: William A. Wasitis, James L. Hoff
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Patent number: 4801668Abstract: Processes for the preparation of low non-transannular, high softening point hydrocarbon resins from 1,5-cyclooctadiene are disclosed. In one aspect of the invention, 1,5-cyclooctadiene is heated in the presence of an aluminum halide catalyst at temperatures at or above 80.degree. C. to give the desired resin. In another aspect of the invention, 1,5-cyclooctadiene is combined with a copolymerizable olefin in the presence of an aluminum halide catalyst at temperatures ranging from 30.degree. C. to 250.degree. C. The high softening point resins produced by these processes have levels of non-transannular impurities below 20% by weight, and these resins are particularly useful as wetting or bonding agents for coatings, adhesives, and other applications.Type: GrantFiled: July 6, 1987Date of Patent: January 31, 1989Assignee: Eastman Kodak CompanyInventor: William A. Beavers
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Patent number: 4798644Abstract: A removable foam backed carpet may be prepared by laminating a non-woven scrim, having a cohesive strength less than the cohesive strength of the foam, to the back of a foam backed carpet. The foam backed carpet is gelled, crushed and vulcanized to produce a resilient backing having a good delamination strength. The carpet is particularly useful when it is cut into tiles. The carpet tile may be easily removed to install wiring of if wear is excessive.Type: GrantFiled: March 24, 1988Date of Patent: January 17, 1989Assignee: Polysar Financial Services, S.A.Inventors: Richard L. Scott, John J. Martin, Landon Smith
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Patent number: 4789498Abstract: A resinous block copolymer, such as butadiene/styrene block copolymer, having an antiblocking agent incorporated therein, such as a microcrystalline wax, is bonded or welded together with a composition containing at least one hydroxyl-ether and/or keto-ether such as 4-methoxy-4-methyl-2-pentanone.Type: GrantFiled: March 2, 1987Date of Patent: December 6, 1988Assignee: Phillips Petroleum CompanyInventor: Harold D. Boultinghouse
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Patent number: 4771935Abstract: A polyolefin container is disclosed which is hermetically sealed with a complementary lid extending across the open container the opposed faces of the container surface and the lid being bonded together by a peelable, heat seal layer intermediate between the opposed faces. The heat seal layer is comprised of a mixture of a particulate filler and first and second polyolefin resins, the second polyolefin resin having a melt flow rate at least about three times greater than the melt flow rate of the first polyolefin resin.Type: GrantFiled: June 3, 1987Date of Patent: September 20, 1988Assignee: Continental Can Company, Inc.Inventor: Ihab M. Hekal
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Patent number: 4770757Abstract: A presoaked perhalogenated polymer cation exchange membrane containing at least one type of acid groups, carboxyl or sulfonyl, is bonded to other articles such as edge-reinforcing tape, gasket, electrolytic cell frame, etc., by means of a pressure-sensitive adhesive material from the group of butyl rubber, styrene-butadiene rubber, and polyacrylate rubber. Presoaking of the membranes is done either in water or in an aqueous alkaline solution.Type: GrantFiled: March 3, 1987Date of Patent: September 13, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Thomas C. Bissot, James T. Keating
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Patent number: 4761341Abstract: Temporarily bonded constructions, i.e., credit cards attached to paper stock for mailing to customers, may be prepared utilizing a non-pressure sensitive hot melt adhesive comprising 5-40% of specific A-B.A block copolymers and 95-60% plasticizing oil.Type: GrantFiled: April 10, 1987Date of Patent: August 2, 1988Assignee: National Starch and Chemical CorporationInventors: Edward A. Rosiak, Frank A. Bozich
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Patent number: 4761198Abstract: Hot melt pressure sensitive prepared from (a) a rubbery block copolymer containing a rubbery polyisoprene midblock portion and a plurality of crystalline poly(vinylarene) endblocks; (b) a tackfying resin compatible with the midblock portion and (c) poly(alkyloxazoline); and (d) an antioxidant. These adhesives are characterized by exceptional elastic memory, high tensile strength and excellent peel adhesion and, as such, are especially suited for use in elasticized bands for disposable items.Type: GrantFiled: July 13, 1987Date of Patent: August 2, 1988Assignee: National Starch and Chemical CorporationInventor: Catherine E. Salerno
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Patent number: 4759874Abstract: The invention is a die attach adhesive composition comprising a homogeneous blend of an organopolysiloxane-bridged bisbenzocyclobutene monomer, an organosilane adhesion aid, and a finely divided electrically conductive metal. The composition is easy to apply, exhibits good adhesive strength and thermal stability at high temperatures, and does not require solvents, initiators, or curing agents. Weight loss on cure is minimal.Type: GrantFiled: August 3, 1987Date of Patent: July 26, 1988Assignee: The Dow Chemical CompanyInventor: William A. Gros
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Patent number: 4753708Abstract: A film forming dispersion for the heat sealing of dissimilar substrate said dispersion comprising at least two different types of polymers having different adhesive properties in an organic solvent system, at least one of the polymer types being fully miscible at room temperature with the organic solvent system, both of said two polymer types having an acid number ranging from 0 to 160 mg KOH per gram of polymer, and said dispersion further containing a third graft polymer containing components corresponding to said two different polymer types.Type: GrantFiled: April 6, 1987Date of Patent: June 28, 1988Assignee: Rohm GmbHInventors: Gerhard Markert, Horst Pennewiss, Waldemar Schleier, Reiner Schnee
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Patent number: 4749429Abstract: A sealing structure is disposed between a metal-casting ingot mold bottom portion and a bottom plate to prevent the leakage of molten steel between the mold and plate. A clay rope disposed in a closed configuration corresponding to the bottom of the ingot mold is affixed to the cardboard sheet with an adhesive system. Overlapping portions of the cardboard sheet are grasped to position the clay rope directly under the ingot mold, and the mold is lowered onto the bottom plate. Hot glue (or pressure sensitive adhesive tape and/or white glue) holds the clay rope on the cardboard sheet. The clay rope is offset at a central portion of the sheet to allow folding of the sheet for transport.Type: GrantFiled: July 16, 1981Date of Patent: June 7, 1988Assignee: Foseco International LimitedInventors: Thomas E. Condon, Marshall E. Billig
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Patent number: 4735669Abstract: A method is disclosed for forming laminates of plastics resin films and metallic foils. The plastics resin film is adhesively bonded to the metallic foil. The bonded laminate is then rolled under pressure to thin both the plastics resin film and metallic foil layers. In addition to reducing the thickness of the laminate, the rolling operation increases the length of the laminate and orients the plastics resin film in the machine direction.Type: GrantFiled: September 2, 1986Date of Patent: April 5, 1988Assignee: Reynolds Metals CompanyInventors: James H. Guida, Thomas E. Kirk
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Patent number: 4729928Abstract: A durable high gloss water-based coating composition highly useful for multicolor printing or as printing inks, and like uses, and which is characterized by a proportioned mixture of ethylene acrylic acid and N-methylpyrrolidone, with resultant avoidance of environmental or toxicity problems, as well as formulation, application, or utilization difficulties.Type: GrantFiled: April 10, 1987Date of Patent: March 8, 1988Inventors: Attilio V. Schiappa, Wilson M. Ferrell
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Patent number: 4726869Abstract: An adhesive, suitable for joining cured polyolefin articles, comprising a water curable polyolefin having a melt index of from 0.1 to 20, and a method of joining cured polyolefin articles, especially cured polyethylene pipes, comprising a step to apply the above adhesive to the surface of the articles and a step to join both of the surfaces to each other with the melt of the adhesive.Type: GrantFiled: September 30, 1985Date of Patent: February 23, 1988Assignee: Dainichi-Nippon Cables, Ltd.Inventors: Masatake Matsui, Chiaki Momose, Kazunori Terasaki
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Patent number: 4726864Abstract: Hectograph master webs and sheets formulated to provide sharper, more-complete transfer under reduced imaging pressures, and sharper, more-numerous duplicate copies in the hectograph duplicating process and resistance to adhesion and coating-transfer under the pressures exerted by a hectograph duplicating machine. The receptive surface formed on the master sheet comprises a hard, pressure-adhesive coating consisting by weight essentially of 45 to 65 percent paraffinic wax, 5 to 20 percent hard wax and 15 to 40 percent polybutene polymer having a Staudinger molecular weight of from 10,400 to 12,300 which bonds to the hectograph transfer layer under relatively low, localized imaging pressure but which is sufficiently hard to resist adhesion, sticking and pick-over to hectograph copy sheets during the hectograph copying processes. The receptive coating also provides a barrier against the migration of the hectograph composition and/or of the spirit duplicating fluid into the master sheet.Type: GrantFiled: June 30, 1986Date of Patent: February 23, 1988Assignee: Leedall Products IncorporatedInventors: Albert E. Brown, Robert T. Emerson
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Patent number: 4702950Abstract: A carpet tile and method of production wherein the carpet tile comprises a carpet tile having a fibrous face, such as a tufted face, and a fibrous back surface secured to a primary backing and comprising three separate hot melt coating composition layers and a secondary backing on the back surface of the carpet tile.Type: GrantFiled: February 6, 1987Date of Patent: October 27, 1987Assignee: Heuga Holding bvInventors: David K. Slosberg, David S. Reece, Johannes A. H. Claessen
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Patent number: 4693772Abstract: A hot applicable, heat expandable, thermosetting sealing composition particularly adapted for use in the automotive industry is disclosed. Such a sealant comprises a styrene-butadiene rubber mixed with conventional thermoplastic resin blowing agents, vulcanizing agent, oils and thickening agents wherein the addition of an activator selected from the family of sulfonamide materials results in a sealer which can be hot applied without causing it to prematurely blow or cross-link yet remain affixed to the component until such time as it is desired to blow and cure the sealant.Type: GrantFiled: December 22, 1986Date of Patent: September 15, 1987Assignee: United Technologies Automotive, Inc.Inventor: William A. Douglas
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Patent number: 4687534Abstract: Film faced expanded polystyrene foam board is prepared by heat laminating expanded polystyrene board with a film composition comprising a high density polyethylene film layer and a heat activated low density adhesive film layer. This board is useful in the construction industry.Type: GrantFiled: June 17, 1985Date of Patent: August 18, 1987Assignee: BASF CorporationInventors: Robert A. Alford, Mark C. Braemer
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Patent number: 4684421Abstract: A promoter for improving the adhesion of rubber to metals is obtained by reacting an alkaline earth borate such as calcium borate with a cobalt or nickel carboxylate. Preferred carboxylates contain 3-24 carbon atoms.Type: GrantFiled: January 21, 1986Date of Patent: August 4, 1987Assignee: Manchem LimitedInventor: Philip E. R. Tate
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Patent number: 4670125Abstract: A bipolar membrane is produced by fastening an anion exchange membrane to a cation exchange membrane with the aid of an ion-permeable adhesive, by a process in which an aqueous solution of a polyvinylamine is used as the adhesive, and the bipolar membrane, which consists of two ion exchange membranes and the film-like adhesive, is subjected to electrodialysis.Type: GrantFiled: February 26, 1986Date of Patent: June 2, 1987Assignee: BASF AktiengesellschaftInventors: Hans Mueller, Hermann Puetter
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Patent number: 4663228Abstract: Laminated articles, particularly safety glass, comprising a lamina of ionomer resin film laminated to a sheet of glass. The ionomer resin film is preferably an ionically crosslinked ethylene-methacrylic acid copolymer. The laminated articles may also comprise a sheet of polycarbonate laminated to the ionomer resin film opposite the glass. The laminated articles may further comprise an ionomer resin film sandwiched between two sheets of glass. The laminated articles may still further comprise a sheet of polycarbonate or other plastics sandwiched between sheets of ionomer resin film, which are in turn sandwiched between sheets of glass.Type: GrantFiled: December 17, 1985Date of Patent: May 5, 1987Assignee: Advanced Glass Systems Corp.Inventors: Nelson P. Bolton, W. Novis Smith, Jr.
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Patent number: 4661193Abstract: Two solid substrates are bonded together by using a functionally effective amount of an arylcyclobutene monomeric composition as an adhesive.Type: GrantFiled: August 30, 1985Date of Patent: April 28, 1987Assignee: The Dow Chemical CompanyInventors: Robert A. Kirchhoff, Jo Ann Gilpin
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Patent number: 4640730Abstract: This process of adhering sheet roofing materials uses a SBS block copolymer mixed with hydrocarbon resin. No primer is needed, both dry bonding with heat and wet bonding processes have good green strength.Type: GrantFiled: March 22, 1985Date of Patent: February 3, 1987Assignee: Ashland Oil, Inc.Inventors: Roger L. Streets, Thomas G. Rabito, David N. Peresie
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Patent number: 4634488Abstract: A material intended to form a joint between at least two bodies on the outside of their interface, at least one of the bodies being deformable, is characterized by the following features:(a) it is formed of a fluid mixture having a viscosity, measured at normal temperature, of from 0.3 Pa.s to 700 Pa.s;(b) a dry extract of the fluid mixture, measured at normal temperature and pressure, is from 20% by weight to 80% by weight, based on the weight of the fluid mixture;(c) the dry extract of the fluid mixture comprises an elastomer fraction at least 20% by weight of which elastomer fraction is formed of at least one unsaturated elastomer capable of cross-linking either at ambient temperature or by heating for a period of time of less than one minute.Methods for producing assemblies with this material, consisting, for instance, of manufacturing, repairing or recapping a tire.Assemblies obtained by these methods.Type: GrantFiled: November 18, 1985Date of Patent: January 6, 1987Assignee: Compagnie Generale des Establissements MichelinInventor: Jean-Louis Tournier
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Patent number: 4623414Abstract: A process for preparing an aqueous adhesive composition which comprises preparing a solvent dispersion by mixing rubber, carbon black, vulcanizing agent, tackifying resin and accelerator with sufficient organic solvent to form a solvent dispersion and thereafter emulsifying the solvent dispersion in the presence of water to form an aqueous emulsion. The aqueous emulsion may be used to bond unvulcanized rubber compounds, such as a tread stock to the carcass portion during the formation of a tire.Type: GrantFiled: July 12, 1984Date of Patent: November 18, 1986Assignee: SWS Silicones CorporationInventors: Wendell Collins, Howard L. Brooks
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Patent number: 4616687Abstract: Disclosed are vulcanized compositions of (1) from about 80% to about 99% of a rubber material selected from the group consisting of butyl rubber, halogenated butyl rubber having from about 1% to about 3% by weight of halogen and mixtures thereof, and (2) from about 1% to about 20% of a chlorinated hydrocarbon polymer having a chlorine content of from about 30% to about 70% by weight of chlorine, said composition having good impermeability to gases and tear resistance and being useful in tire inner tubes and inner liners.Type: GrantFiled: January 13, 1986Date of Patent: October 14, 1986Assignee: Hercules IncorporatedInventor: Dominic A. Berta
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Patent number: 4616686Abstract: Disclosed are crosslinking compositions having both sulfur and nonsulfur curative systems which are particularly adapted for crosslinking rubber blends of (a) from about 35% to about 85% halobutyl rubber or a mixture of butyl rubber and halobutyl rubber wherein the halobutyl rubber is at least 50% by weight of the mixture and (b) from about 15% to about 65% of an epihalohydrin rubber, and the rubber materials crosslinked therewith. The rubber materials crosslinked with these crosslinking compositions have an excellent balance of cure rate, cure state and scorch safety; have improved tire carcass adhesion and good impermeability to gases; and are useful in tire inner tubes and inner liners.Type: GrantFiled: January 13, 1986Date of Patent: October 14, 1986Assignee: Hercules IncorporatedInventor: Dominic A. Berta
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Patent number: 4599275Abstract: A metal-deposited paper comprising a paper substrate, a thin continuous coating of a film-forming resin having good adhesion to metals on at least one surface thereof, and a metal film deposited on the resin coating. The aforesaid paper can be produced by applying a thin continuous coating of a film-forming resin having good adhesion to metals on at least one surface of a paper substrate, and then vacuum-depositing a metal on the surface of the resin coating.Type: GrantFiled: June 13, 1984Date of Patent: July 8, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Akira Hayashi, Yutaka Hirota, Mitsuhiro Tanaka