With Coating And/or Laminating Patents (Class 162/112)
  • Patent number: 6277241
    Abstract: The present invention is generally directed to base webs that are creped after a bonding material has been applied to at least one side of the web according to a predetermined pattern. The base web disclosed in the present application is made from at least three fibrous layers. The outer layers of the web contain synthetic staple fibers for increasing the tensile strength and abrasion resistant properties of the web. In one embodiment, the middle layer can further contain hardwood fibers, such as eucalyptus fibers, which improves the wipe dry properties of the web.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: August 21, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Joseph F. Merker, Ralph L. Anderson, Thomas C. Saffel, Stephen A. Hurst, Charles J. Garneski, Gary L. Zimmerman
  • Patent number: 6273995
    Abstract: A paper bulking promoter containing a compound represented by the following formula (1) with which a highly bulky sheet can be obtained without impairing paper strength: RO(EO)m(PO)nH  (1) wherein R represents a linear or branched alkyl or alkenyl group having 6 to 22 carbon atoms or an alkylaryl group in which the alkyl group has 4 to 20 carbon atoms; E represents an ethylene group; P represents a propylene group; m indicates the average number of moles added in the range of 0≦m≦20; and n is a number in the range of 0≦n≦50; provided that the EO and PO groups may have any of block and random arrangements and may begin with any of EO and PO.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: August 14, 2001
    Assignee: Kao Corporation
    Inventors: Yasushi Ikeda, Hiromichi Takahashi, Toshiki Sowa, Koji Hamaguchi
  • Patent number: 6267842
    Abstract: A water-based treatment agent for tissue paper suppresses any feeling of slipperiness or wetness in ordinary tissue paper and toilet paper so the paper has a dry touch, ample smoothness, and a clean, smooth, tactile impression. It also provides the paper with a superior softness. The water-based treatment agent consists of a silicone oil emulsion in which crosslinked silicone particles with a mean particle size of 0.01-100 &mgr;m are contained in silicone oil droplets with a mean particle size of 0.05-500 &mgr;m, which are dispersed in water. The particle size of the crosslinked silicone particles is smaller than the particle size of the silicone oil droplets.
    Type: Grant
    Filed: May 22, 2000
    Date of Patent: July 31, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Isao Ona, Hiroki Ishikawa, Tsutomu Naganawa, Kazuo Kobayashi, Yoshitsugu Morita
  • Patent number: 6265030
    Abstract: A method of impregnating paper with waterglass, such as soda waterglass or potassium silicate, the impregnated paper being usable as a dehumidifying element, wherein the method includes the steps of a) providing a sheet of paper such as facing paper and/or corrugated paper; b) immersing the paper into a highly concentrated waterglass solution at a temperature within the range of 45-95° C., with the highly concentrated waterglass solution having a viscosity of at least 350 mPa.s at a temperature of 45° C.; and c) cooling the immersed paper with air at a temperature no greater than 35° C. and preferably no greater than 25° C.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: July 24, 2001
    Assignee: Proflute AB
    Inventor: Per-Johan Aronson
  • Publication number: 20010008180
    Abstract: An improved cloth-like base web is disclosed. In particular, the base web of the present invention has a cloth-like look and feel and has improved absorbency. The base web is made by first hydroneedling a web containing pulp and/or staple fibers. A bonding material is then applied to at least one side of the web and the web is creped on at least one side. By combining a hydroneedling operation with a creping operation, a base web is produced that is strong, stretchable, very soft and absorbent.
    Type: Application
    Filed: October 30, 1997
    Publication date: July 19, 2001
    Inventors: RALPH L ANDERSON, FRITZ RADWANSKI, HENRY SKOOG, DONALD E WALDROUP
  • Patent number: 6248211
    Abstract: A method for making a throughdried tissue sheet is disclosed. The method includes the steps of depositing an aqueous suspension of papermaking fibers onto an endless forming fabric to form a wet web. The wet web is then transferred to a throughdrying fabric such that the wet web has a fabric side in contact with the throughdrying fabric and an opposite air side facing away from the throughdrying fabric. The wet web is routed over a throughdryer to dry the web. The web is then transferred to a Yankee dryer for further drying and is creped from the Yankee dryer to obtain a creped web having a basis weight of about 15.2 pounds per 2880 square feet. The creped web in then calendered in a calendering unit that includes a smooth calender roll and a resilient calender roll. The resilient calender roll has an exterior covering formed of ethylene propylene diene polymer and the creped web is oriented such that the fabric side is disposed toward the resilient calender roll.
    Type: Grant
    Filed: August 9, 1999
    Date of Patent: June 19, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Richard Douglas Jennings, Zeinab Salman
  • Patent number: 6248212
    Abstract: A web structure is formed by a process including first through-air drying the fibrous web comprising at least about 20% non-premium fiber, next applying a bonding material to the fibrous web, and next creping the fibrous web to form the web structure having a BLK/BW and CCDWT at least 85% of a wet-pressed web structure comprising 100% premium fiber. The web structure may alternatively or in addition to have a TWA and/or BLK/BW greater than the TWA and/or BLK/BW of a through-air-dried, bonded, and creped web structure comprising 100% premium fiber. The process may be repeated on the second side. The web structure may comprise a combination of hardwood, softwood, CTMP, and/or recycled fibers. The web structure may include at least about 40% recycled fibers.
    Type: Grant
    Filed: December 30, 1997
    Date of Patent: June 19, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ralph L. Anderson, Tom C. Saffel
  • Patent number: 6245197
    Abstract: A tissue paper of improved softness, strength and absorbency; and a manufacturing process for such a tissue paper where the generation of foam is reduced, or eliminated altogether. These are obtained using a tissue paper softener system comprising a substantially equimolar, ion-paired mixture of an anionic surfactant and a cationic quaternary ammonium compound, wherein the softener system is formulated such that the charge density of the anionic surfactant/cationic quaternary ammonium compound mixture will be about neutral.
    Type: Grant
    Filed: October 20, 1999
    Date of Patent: June 12, 2001
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Anthony O. Awofeso, Gary L. Schroeder, David W. White, Nga Thuy Luu, Bruce J. Kokko
  • Patent number: 6241850
    Abstract: A soft tissue product and method for making a soft tissue product which exhibits resistance to limiting while maintaining physical strength integrity. The process includes debonding and mechanically treating papermaking fibers, forming a tissue web and drying the tissue web. The process allows for the use of high levels of debonding agents and hardwood fibers.
    Type: Grant
    Filed: June 16, 1999
    Date of Patent: June 5, 2001
    Assignee: The Procter & Gamble Company
    Inventor: Stephen Robert Kelly
  • Patent number: 6238519
    Abstract: New and improved methods and products are disclosed relating to increasing the softness of paper sheets, without effecting their wetability. Increased softness, without loss of wetability is obtained by adding deactivated ketene dimer sizing agents to the sheet.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: May 29, 2001
    Assignee: Kimberly Clark Worldwide, Inc.
    Inventors: David A. Jones, Nancy C. Clungeon
  • Patent number: 6235155
    Abstract: Condensation polymers, such as polyamide epichlorohydrin (PAE) resins, can be combined with polysiloxanes in a single molecule to provide several potential benefits, depending upon the specific combination employed, including: (a) wet strength resins that soften; (b) softeners that do not reduce dry or wet tensile strength; (c) wet strength with improved wet/dry tensile ratio; (d) softeners/debonders with reduced linting and sloughing; (e) wet strength aids with controlled absorbency rate; and (f) Yankee dryer additives that provide surface protection and adhesion with controlled release properties.
    Type: Grant
    Filed: January 20, 2000
    Date of Patent: May 22, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
  • Patent number: 6214932
    Abstract: A process comprising mixing polyamide and another polymer, such as polyvinylalcohol and/or polyethyleneimine and reacting the polyamide/other polymer mixture with epichlorohydrin and the use of the reaction product as creping adhesive.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: April 10, 2001
    Assignee: Hercules Incorporated
    Inventor: William Walter Maslanka
  • Patent number: 6214146
    Abstract: The present invention is generally directed to wiping products having great softness and strength. The wiping products are made from a web of material containing binder fibers alone or in combination with pulp fibers. Once the web is formed, the web is adhered to a creping surface and creped. According to the present invention, the web may be creped once or creped multiple times. Of particular advantage, the web can be adhered to a creping surface through the use of the binder fibers without the use of an adhesive.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: April 10, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventor: Joseph F. Merker
  • Patent number: 6207734
    Abstract: An adhesive for applying to a creping surface in the process for dry creping tissue paper is disclosed. The adhesive comprises cationic starch and optionally a polyvinyl alcohol and a water-soluble, thermosetting, cationic polyamide-epihalohydrin resin. The adhesive provides high adhesion and doctorability for dry creping.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: March 27, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Douglas Vinson, Howard Thomas Deason, Bart Steven Hersko
  • Patent number: 6203663
    Abstract: Paper sheets, such as tissue sheets useful for facial tissue, bath tissue and the like, are formed with a decorative pattern imparted to the tissue sheet by the forming fabric. The decorative pattern is incorporated into the forming fabric by a variety of means, such as stitching, silk screening, printing, weaving, or overlaying a fabric with a decorative pattern onto a conventional forming fabric. The presence of decoratively-shaped areas in the forming fabric, which are areas of relatively slow water drainage, cause corresponding areas in the resulting sheet to have a translucent appearance attributable to a relatively lower basis weight and/or different fiber composition. The decorative patterns are preferably formed in the outer or surface layer(s) of the paper sheet.
    Type: Grant
    Filed: May 5, 1995
    Date of Patent: March 20, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Richard Joseph Kamps, Janica Sue Behnke, Fung-jou Chen, Darnell Clarence Radtke
  • Patent number: 6193838
    Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: February 27, 2001
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
  • Patent number: 6193841
    Abstract: This invention relates to compositions, paper, thermoplastic sheets, and medical paper containing cellulose ester, alkylpolyglycoside (APG) or a mixture of APG and polyether glycol, and, optionally, cellulose. The process of incorporating APG or a mixture of APG and polyether glycol in paper composed of cellulose ester fibers and cellulose fibers and to calendaring of such paper is also disclosed.
    Type: Grant
    Filed: November 30, 1998
    Date of Patent: February 27, 2001
    Assignee: Eastman Chemical Company
    Inventors: Charles Michael Buchanan, Eric Eugene Ellery, Matthew Davie Wood
  • Patent number: 6187137
    Abstract: A method of using a conventional wet-pressed creped tissue machine produces a textured tissue sheet that is dried on a conventional cylindrical drum dryer to create an uncreped product with throughdried-like properties. Machine modifications and a proper balance of adhesive compounds and release agents permit a textured sheet to be dried on a Yankee drier and then pulled off without use of a crepe blade.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: February 13, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Frank Gerald Druecke, Shan Liang Chen, Michael Alan Hermans, Sheng-Hsin Hu, Richard Joseph Kamps
  • Patent number: 6187139
    Abstract: The present invention is a method for making a high quality paper product at improved process efficiency through the use of high steam levels in the Yankee dryer. The product according to the present invention is creped from the Yankee dryer while it is still wet and is then drying is completed using conventional methods. Products made according to the present invention exhibit improved absorbency, softness and bulk.
    Type: Grant
    Filed: July 13, 1999
    Date of Patent: February 13, 2001
    Assignee: Fort James Corporation
    Inventors: Steven L. Edwards, Robert J. Marinack
  • Patent number: 6187140
    Abstract: A method of increasing the wet strength of a creped sheet, which method involves providing a sheet which includes cellulosic fibers, which sheet has a first side and a second side; applying a low temperature-curing latex adhesive binder composition to the first side of the sheet in a fine, spaced-apart pattern occupying from about 20 to about 50 percent of the surface area of the sheet; adhering the first side of the sheet to a creping surface; and creping the sheet from the creping surface. The binder composition is adapted to adhere the sheet to the creping surface and includes a functional group-containing latex, a functional group-reactive crosslinking agent, and a volatile base. In addition, the creping surface is heated at a temperature no greater than about 100° C.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: February 13, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ralph Anderson, Christopher Lee Davidson, Kenneth Curtis Larson, Thomas C. Saffel, Robert Emil Weber, Duane K. Zacharias
  • Patent number: 6187141
    Abstract: A water-disintegratable fibrous sheet having a layered structure comprising: (a) at least one first fiber web comprising pulp of conifer and pulp of hardwood; (b) at least one second fiber web comprising pulp of conifer, having a content of pulp of hardwood less than that in said first fiber web or containing no pulp of hardwood, said first and second fiber webs forming said layered structure; and (c) a water-insoluble or water-swellable binder being added to at least one of said first and second fiber webs. The fibrous sheet excellent in water-disintegratability and strength can be obtained.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: February 13, 2001
    Assignee: Uni-Charm Corporation
    Inventors: Naohito Takeuchi, Takayoshi Konishi, Daisuke Yamada
  • Patent number: 6187138
    Abstract: A method for producing creped paper products comprising applying to a drying surface, a film-forming semi-crystalline polymer and a non-thermosetting cationic resin wherein the resin is characterized by a highly branched structure that lacks reactive intralinker functionality and which has a prepolymer backbone comprised of intralinked polyamidoamine. The invention also comprises a method for producing creped paper products comprising applying to a drying surface a film-forming semi-crystalline polymer, a non-thermosetting cationic resin wherein the resin is characterized by a highly branched structure that lacks reactive intralinker functionality and which has a prepolymer backbone comprised of intralinked polyamidoamine, and an optional plasticizer.
    Type: Grant
    Filed: March 17, 1998
    Date of Patent: February 13, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Charles William Neal, Lois Jean Forde-Kohler, Donald Arthur Salsman
  • Patent number: 6183599
    Abstract: The present invention is a method of manufacturing a one-ply absorbent paper product such as a bathroom tissue. The tissue combines high strength and softness along with low sidedness. The paper product is produced as a stratified product using furnishes supplied from different headboxes. The paper is manufactured as a wet pressed, creped product. The paper tissue product made by the process of this invention exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross direction strength of at least 200 grams per 3 inches.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: February 6, 2001
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
  • Patent number: 6179961
    Abstract: Strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels are disclosed. At least one surface of the tissue papers has uniform discrete surface deposits of a substantively affixed chemical softening mixture comprising a mixture of a quartenary ammonium compound, an emollient, and a sorbitan ester.
    Type: Grant
    Filed: October 8, 1997
    Date of Patent: January 30, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Jonathan Andrew Ficke, Kenneth Douglas Vinson
  • Patent number: 6165319
    Abstract: The present invention relates to a soft, thick, single-ply, printed, absorbent paper product having a Yankee side and an air side wherein the absorbent paper is printed on before or after embossing on the Yankee side, air side, or both sides, said absorbent paper exhibiting a serpentine configuration. This inventions also relates to a process for the manufacture of such absorbent paper product having a basis weight of at least about 12.5 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting:a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.0 grams per 3 inches per pound per 3000 square foot ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 3.2 grams per inch per percent strain per pound per 3000 square foot ream, a friction deviation of less than 0.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: December 26, 2000
    Assignee: Fort James Corporation
    Inventors: Michael S. Heath, T. Philips Oriaran, Mark S. Siegel, Frank D. Harper, John H. Dwiggins
  • Patent number: 6162329
    Abstract: Disclosed is a composition for softening an absorbent tissue and tissue structures softened using the composition. The composition includes an effective amount of a softening active ingredient; a vehicle in which the softening active ingredient is dispersed; and an electrolyte dissolved in the vehicle. The electrolyte causes the viscosity of the composition to be less than the viscosity of a dispersion of the softening active ingredient in the vehicle alone. Preferably, the softening active ingredient is a quaternary ammonium compound with the formula:(R.sub.1).sub.4-m --N.sup.+ --[(CH.sub.2).sub.n --Y--R.sub.3 ].sub.m X.sup. -the vehicle is water, and the electrolyte is calcium chloride.
    Type: Grant
    Filed: April 1, 1998
    Date of Patent: December 19, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Douglas Vinson, Sean Patrick Fagin, Errol Hoffman Wahl, Richard Martin Ward
  • Patent number: 6156157
    Abstract: The invention relates to tissue products having improved softness properties and methods of making them. Specifically, improved softness is achieved by incorporating one or more softeners/debonders into the fiber furnish at the wet end of the tissue machine prior to formation, followed by a topical treatment with one or more softeners/debonders after the tissue web is dried. The result is a tissue product with added bulk and a smooth surface feel, both properties contributing to improved softness characteristics.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: December 5, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Wen Zyo Schroeder, Gary Vance Anderson, Duane Gerard Krzysik, Gary Lee Shanklin, Michael John Smith
  • Patent number: 6153053
    Abstract: The present invention relates to a soft, thick, single-ply, absorbent paper in the form of a bathroom tissue, facial tissue, or napkin wherein the cellulosic fibers incorporated in the furnish comprise: (a) at least 20 percent by weight of the fibers in the web have a coarseness exceeding 23 mg/100 m; (b) at least about 20 percent by weight of the fibers in the web have a coarseness of less than about 1.2 mg/100 m; and (c) the weight average coarseness to length ratio of the fibers in the web is less than about 8.5 mg/100 m/mm having a serpentine configuration and to a process for the manufacture of such absorbent paper having a basis weight of about 15 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting:a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.
    Type: Grant
    Filed: April 15, 1998
    Date of Patent: November 28, 2000
    Assignee: Fort James Corporation
    Inventors: Frank David Harper, Taiye Philips Oriaran, John Dennis Litvay
  • Patent number: 6149769
    Abstract: Disclosed is a soft, low density paper product made using papermaking fibers and a cationic temporary wet strength resin. Such paper products have a density less than about 0.6 grams per cubic centimeter, a basis weight is between about 10 and about 65 grams per square meter, a dry strength less than about 500 grams per inch (197 grams per centimeter), a ratio of an initial wet strength to the dry strength greater than about 0.15:1, and a ratio of a thirty minute wet strength to the initial wet strength less than about 0.4. Methods for producing such paper products are also disclosed. The paper products may be produced either as homogeneous structures or as multi-layered structures and may be either creped or uncreped.
    Type: Grant
    Filed: June 3, 1998
    Date of Patent: November 21, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Khosrow Parviz Mohammadi, Larry Odell Seward, David Mark Rasch
  • Patent number: 6149768
    Abstract: A method of making a bonded and creped type absorbent paper web that has improved bulk to peel strength characteristics includes steps of (a) printing a low density pattern of a bonding material onto a first and a second side of a paper web; and (b) in no particular sequence with respect to step (a), printing a high density pattern of a bonding material onto the first side of the paper web. Steps (a) and (b) are performed so that the high density pattern of bonding material penetrates into the paper web by a distance that is about 166 to about 470 percent of the distance by which the low density pattern of bonding material penetrates into the web. This results in a web that has superior bulk and peel strength characteristics. Another characteristic of the product is that it has a visible depression pattern in one surface, but not the other surface, which creates an attractive aesthetic effect and has functional benefits as well.
    Type: Grant
    Filed: April 8, 1998
    Date of Patent: November 21, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventor: Richard R. Hepford
  • Patent number: 6139686
    Abstract: A process and an apparatus for making a foreshortened paper web are disclosed. A wet web disposed on a fluid-permeable papermaking fabric is being pressed between two parallel and mutually opposed first and second press surfaces, the first press surface contacting the web, and the second press surface contacting the fabric. In the continuous process, the press surfaces, the web and the fabric move in a machine direction. Under pressure, at least selected portions of the web become densified and adhered to the first press surface which can be treated with a creping adhesive. The first surface is heated to create a temperature differential between two surfaces. The temperature differential causes the water contained in the web to move from the web into the fabric, thereby drying the web. After the web is released from the pressure, the web is foreshortened either by creping or by transferring the web to a slower moving transfer fabric.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: October 31, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Paul Dennis Trokhan, Mark Ryan Richards, Michael Gomer Stelljes, Jr.
  • Patent number: 6136147
    Abstract: Debonders, particularly including polysiloxanes, are applied to tissue webs by atomizing the debonder and applying the debonder to the tissue with a steam jet as a debonder/steam mixture. The debonder is applied after the creping blade and prior to the reel. Other suitable debonders include quaternary ammonium surfactants.
    Type: Grant
    Filed: August 1, 1994
    Date of Patent: October 24, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Steven Lawrence Edwards, Michael John Smith
  • Patent number: 6129815
    Abstract: The present invention provides a multi-layered wiping product that maintains desired characteristics of softness, strength, stretchability, absorbency, and the like. The wiping product is formed from a process using a multi-layered paper web, printing a bonding agent on both of its outer surfaces, pressing the web so it adheres tightly to a creping surface and lightly to a presser roll, and then creping one of its surfaces.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: October 10, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Kenneth C. Larson, Richard R. Hepford
  • Patent number: 6120644
    Abstract: The invention relates to tissue products having improved softness properties and methods of making them. Specifically, improved softness is achieved by incorporating a cationic amidoamine into the fiber furnish at the wet end of the tissue machine prior to formation and/or by topical addition to the tissue web. One or more softeners/debonders can be added to the furnish and/or topically applied to the tissue web after the tissue web is dried. The result is a tissue product with added bulk and a smooth surface feel, both properties contributing to improved softness characteristics.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: September 19, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Wen Zyo Schroeder, Gary Lee Shanklin
  • Patent number: 6113740
    Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: September 5, 2000
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
  • Patent number: 6103063
    Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: August 15, 2000
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Christian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
  • Patent number: 6096168
    Abstract: The present invention relates to biaxially undulatory single-ply and multi-ply tissues, single-ply and multi-ply towels, single-ply and multi-ply napkins and other personal care and cleaning products as well as novel creping blades and novel processes for the manufacture of such paper products. The present invention is directed to tissue and towel product having highly desirable bulk, appearance and softness characteristics produced by utilizing a novel undulatory creping blade having a multiplicity of serrulations formed in its rake surface which presents differentiated creping angles and/or rake angles to the web as it is being creped. The invention is also directed to a novel blade having an undulatory rake surface having trough-shaped serrulations in the rake surface of the blade. The undulatory creping blade has a multiplicity of alternating serrulated sections of either uniform depth or a multiplicity of arrays of serrulations having non-uniform depth.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: August 1, 2000
    Assignee: Fort James Corporation
    Inventors: Robert J. Marinack, Anthony O. Awofeso, Frank D. Harper, Thomas N. Kershaw
  • Patent number: 6059928
    Abstract: A paper product and a method of making a paper product with a glabrous surface and adapted for use either dry or for use in a manually pre-moistened condition. The paper product having temporary wet strength exhibiting an initial normalized CD wet tensile strength of at least about 75 g/3 inch strip, preferably 105 g/3 inch strip as measured by the Finch Cup Test 5 seconds after immersion and a subsequent CD wet strength of less than 1/2 as measured 10 minutes after immersion. A temporary wet strength agent comprising uncharged chemical moieties such as aldehydes, and aldehydes containing polymers, polyols and cyclic ureas or mixtures thereof in the range of from about 2 pounds per ton to about 30 pounds per ton is added to the web. Optionally starch and a cationic nitrogenous softener/debonder is added. The starch and softener/debonder are added to assist in tailor making the desired paper product having temporary wet strength.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: May 9, 2000
    Assignee: Fort James Corporation
    Inventors: Phuong Van Luu, Gary Worry, Robert J. Marinack, Henry S. Ostrowski, Dinesh M. Bhat
  • Patent number: 6054020
    Abstract: Amine-modified polysiloxanes are applied to the opposite outer surfaces of a tissue product, such as the two outer surfaces of a 3-ply facial tissue, providing improved softness to the surfaces and a degree of hydrophobicity to prevent wet through of liquids during use. However, the degree of hydrophobicity is controlled by the chemical structure of the amine-modified polysiloxane and/or by blending the amine-modified polysiloxane with a more hydrophilic modified polysiloxane such that liquid is still allowed to enter the tissue structure in a reasonably short time to be absorbed by the center ply, but the absorption in combination with the hydrophobicity of the other outer surface substantially delays the liquid from passing completely through the tissue product.
    Type: Grant
    Filed: January 23, 1998
    Date of Patent: April 25, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Mike Thomas Goulet, Dale Alan Burghardt, Duane Gerard Krzysik
  • Patent number: 6051104
    Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: April 18, 2000
    Assignee: Fort James Corporation
    Inventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
  • Patent number: 6033761
    Abstract: The present invention relates to a soft, thick, single-ply tissue and to a process for the manufacture of such tissue product having a basis weight of at least about 15 lbs./3,000 square foot ream and having low sidedness, said tissue exhibiting:a specific total tensile strength of between 40 and 75 grams per 3 inches per pound per 3000 square feet ream, a cross direction specific wet tensile strength of between 2.75 and 7.5 grams per 3 inches per pound per 3000 square feet ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 1.2 grams per inch per percent strain per pound per 3000 square feet ream, a friction deviation of less than 0.225, and a sidedness parameter of less than 0.275.
    Type: Grant
    Filed: December 23, 1996
    Date of Patent: March 7, 2000
    Assignee: Fort James Corporation
    Inventors: John H. Dwiggins, Ranga Ramesh, Frank D. Harper, Anthony O. Awofeso, T. Philips Oriaran, Galyn A. Schulz, Dinesh M. Bhat
  • Patent number: 5993602
    Abstract: Permanent wet strength agents are applied to the surface of the Yankee dryer along with the creping adhesive formulation and thereafter transferred to the tissue web as the tissue web is being adhered to the Yankee. When a sufficient amount of permanent wet strength agent is applied, improved temporary wet strength is attained.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: November 30, 1999
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Michael John Smith, James Martin Kaun, Victor Robert Gentile
  • Patent number: 5980690
    Abstract: A creping adhesive containing about 1% to about 25% by weight solids comprising a multipolymer blend of polyoxazoline, polyethyleneimine, and modified polyethyleneimine, which imparts softness and resistance to bleaching, to a cellulosic web, and methods of using same are provided.
    Type: Grant
    Filed: August 24, 1998
    Date of Patent: November 9, 1999
    Assignee: Hercules Incorporated
    Inventors: Joseph F. Warchol, Cynthia D. Walton
  • Patent number: 5961782
    Abstract: Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, polyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as dialdehydes or zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means.
    Type: Grant
    Filed: April 4, 1997
    Date of Patent: October 5, 1999
    Assignee: Fort James Corporation
    Inventors: Phuong Van Luu, Cristian M. Neculescu, Dawn M. Mews
  • Patent number: 5958185
    Abstract: Soft, strong, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels are disclosed. The tissue papers comprise fibers such as wood pulp and a non-cellulosic, water insoluble particulate filler such as kaolin clay and possess biased surface properties.
    Type: Grant
    Filed: November 7, 1995
    Date of Patent: September 28, 1999
    Inventors: Kenneth Douglas Vinson, Robert Michael Bourbon, Howard Thomas Deason, David Jochen Lorenz, Charles William Neal, Paul Thomas Weisman
  • Patent number: 5958187
    Abstract: A paper product and a method of making a paper product with a glabrous surface and adapted for use either dry or use in a manually pre-moistened condition. The paper product has temporary wet strength exhibiting an initial normalized CD wet tensile strength of at least about 25 g/1" strip, preferably 35 g/1" strip as measured by the Finch Cup Test 5 seconds after immersion and a subsequent CD wet tensile strength of less than about 2/3 the initial value as measured 30 minutes after immersion. A temporary wet strength agent comprising aldehydic units in the range of from about 2 pounds per ton to about 30 pounds per ton is added to the furnish. A cationic nitrogenous softener/debonder is preferably added to the furnish, in an amount of from about 1 pound per ton to about 6 pounds per ton. The CD dry tensile strength of the paper product is from at least about 133 g/1" up to about 267 g/1", and the tensile modulus is from about 10 to about 32 g/% strain while the GM MMD friction is from about 0.26 to about 0.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: September 28, 1999
    Assignee: Fort James Corporation
    Inventors: Dinesh M. Bhat, Robert J. Marinack, Henry S. Ostrowski, Scott D. Moesch
  • Patent number: 5944954
    Abstract: An adhesive for applying to a creping surface in the process for dry creping tissue paper is disclosed. The adhesive comprises cationic starch and optionally a polyvinyl alcohol and a water-soluble, thermosetting, cationic polyamide-epihalohydrin resin. The adhesive provides high adhesion and doctorability for dry creping.
    Type: Grant
    Filed: February 5, 1997
    Date of Patent: August 31, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Douglas Vinson, Howard Thomas Deason, Bart Steven Hersko
  • Patent number: 5935880
    Abstract: A soft, absorbent nonwoven fibrous web, such as a wet wipe, capable of dispersing in an aqueous environment into unrecognizable pieces, made by a method comprising the steps of forming a wet-laid nonwoven web from an aqueous slurry of fibers; hydraulically needling the wet-laid nonwoven web; partially drying the hydraulically needled web; applying a binder composition to one side of the web; creping the web such that interfiber adhesion is disrupted and z-direction fiber orientation is introduced; optionally applying a binder composition to the second side of the web; recreping the web; drying and curing the web; and, converting the dried and cured web into a wet wipe, dry wipe, or other absorbent article. In the case of a wet wipe, a solution containing about 100 ppm of calcium ion is applied to the web, such as in a preserving solution. In the case of a dry wipe, the calcium ion is added after the binder is added to the web, and the final product is stored in a dry state.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: August 10, 1999
    Inventors: Kenneth Y. Wang, Leroy M. Demeny, William S. Pomplun, Pavneet S. Mumick, Ralph L. Anderson, Joseph F. Merker
  • Patent number: 5908533
    Abstract: The present invention relates to biaxially undulatory single-ply and multi-ply tissues, single-ply and multi-ply towels, single-ply and multi-ply napkins and other personal care and cleaning products as well as novel creping blades and novel processes for the manufacture of such paper products. The present invention is directed to tissue and towel product having highly desirable bulk, appearance and softness characteristics produced by utilizing a novel undulatory creping blade having a multiplicity of serrulations formed in its rake surface which presents differentiated creping angles and/or rake angles to the web as it is being creped. The invention is also directed to a novel blade having an undulatory rake surface having trough-shaped serrulations in the rake surface of the blade. The undulatory creping blade has a multiplicity of alternating serrulated sections of either uniform depth or a multiplicity of arrays of serrulations having non-uniform depth.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: June 1, 1999
    Assignee: Fort James Corporation
    Inventors: Robert J. Marinack, Anthony O. Awofeso, Frank D. Harper, Thomas N. Kershaw
  • Patent number: 5904810
    Abstract: The invention relates to tissue products having improved softness properties and methods of making them. Specifically, improved softness is achieved by incorporating a cationic amidoamine into the fiber furnish at the wet end of the tissue machine prior to formation and/or by topical addition to the tissue web. One or more softeners/debonders can be added to the furnish and/or topically applied to the tissue web after the tissue web is dried. The result is a tissue product with added bulk and a smooth surface feel, both properties contributing to improved softness characteristics.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: May 18, 1999
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Wen Zyo Schroeder, Gary Lee Shanklin