With Coating And/or Laminating Patents (Class 162/112)
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Patent number: 4741376Abstract: A process for manufacturing of kraft paper, especially kraft sack paper, on a multi-wire machine in which the web is dried by a combined cylinder drying and free drying and is optionally creped or micro-creped and optionally also glazed. By forming the web into two or more layers which are couched together in the wire part of the machine and subsequent shrinkage in order to obtain a stretch at break of at least 2.5% in the machine direction and of at least 5% in the tranverse direction, improved strength properties are provided.Type: GrantFiled: February 21, 1986Date of Patent: May 3, 1988Assignee: Korsnas AktiebolagInventors: Nils Landqvist, Sven Spangenberg, Torsten Jarnberg, Bengt Nordin
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Patent number: 4684439Abstract: An improved wettable creping adhesive comprises an aqueous admixture of polyvinyl alcohol and a water-soluble thermoplastic polyamide resin comprising the reaction product of a polyalkylene polyamine, a saturated aliphatic dibasic carboxylic acid, and a poly(oxyethylene) diamine.Type: GrantFiled: October 10, 1986Date of Patent: August 4, 1987Assignee: Kimberly-Clark CorporationInventor: Dave A. Soerens
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Patent number: 4673607Abstract: An insulating polyolefin laminate paper and a method for producing such a paper in which first and second fiber paper layers are laminated to a polyolefin film layer. The fiber paper layers have an impermeability of 20 to 4000 Gurley-seconds. At least one of the fiber paper layers is mechanically deformed in such a manner that irregularities are produced having a depth of 2 to 50% of the thickness of the fiber paper layer. The mechanical deformation is accomplished prior to lamination. Before lamination, the water content of the fiber paper layers is controlled to be no more than 4%. Preferably, the thickness of the fiber paper layers is at least 30 microns. Furthermore, an electric power supply cable includes an insulating polyolefin laminate paper as an insulating layer.Type: GrantFiled: September 10, 1984Date of Patent: June 16, 1987Assignee: Sumitomo Electric Industries, Ltd.Inventors: Ryosuke Hata, Shosuke Yamanouchi, Masayuki Hirose, Hidemitsu Kuwabara, Yasuharu Mizumoto, Yasuhiro Hagiuda
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Patent number: 4632730Abstract: Paper, especially wet- or dry-creped paper, is manufactured with a high rate of absorption of aqueous media by using carboxylic acid esters of carboxylic acids with 8 to 30 carbon atoms and at least one of ethoxylated and/or propoxylated primary and/or secondary alcohols with 12 to 40 C atoms, ethoxylated and/or propoxylated alkyl phenols, ethoxylated and/or propoxylated amines, and ethoxylated and/or propoxylated amides, with a degree of ethoxylation or propoxylation of 3 to 50; and/or by using polyethers obtained from the reaction of long-chain epoxides with 8 to 30 carbon atoms and at least one of ethoxylated and/or propoxylated primary and/or secondary alcohols with 12 to 40 C atoms, ethoxylated and/or propoxylated alkyl phenols, ethoxylated and/or propoxylated amines, and ethoxylated and/or propoxylated amides, with a degree of ethoxylation or propoxylation of 3 to 50.Type: GrantFiled: April 29, 1985Date of Patent: December 30, 1986Assignee: Akzo NVInventors: Hasan Ulubay, Horst Schurmann
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Patent number: 4619734Abstract: In order to achieve a sanitary paper web having high bulk, bulk softness and surface softness it is proposed according to the invention that said web contains expanded microspheres (11) of thermoplastic material in an amount of from 1 to 10% based on the weight of the dry web.Type: GrantFiled: April 24, 1985Date of Patent: October 28, 1986Assignee: KMW AktiebolagInventor: Ingmar A. Andersson
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Patent number: 4610743Abstract: Two or more webs (11 and 12) of highly bulked substrate are passed into a nip formed between a gravure roller (14) and an impression roller (15). The impression roller has raised areas defining an interconnected network of lines such that the webs are compressed only under the raised areas; as a result, the binding liquid applied by the gravure roller (14) to the laminate of the two webs is absorbed substantially through the webs in the compressed areas. The gravure roller (14) may have a uniform surface, such that a light coating of binding liquid is applied to the surface of the uncompressed areas in the laminate, or the gravure roller may have a pattern of etched grooves or cells which matches and registers with the pattern of raised areas on the impression roller. In the latter embodiment, binding liquid will be absorbed into the laminate only in the compressed areas.Type: GrantFiled: September 22, 1982Date of Patent: September 9, 1986Assignee: James River-Norwalk, Inc.Inventors: Nilo I. Salmeen, deceased, Bernard G. Klowak
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Patent number: 4587332Abstract: The present invention relates to second grade starches and wheat "B" starches in particular which, following conventional modification treatments to produce a correspondingly viscosity-reduced starch, are especially useful in the production of Stein-Hall corrugating adhesives. Corrugated paper board products manufactured using such adhesives have improved properties. In one aspect of the present invention there is provided a modified wheat "B" starch wherein aqueous dispersions of the modified "B" starch have reduced viscosities relative to comparable dispersions of a corresponding unmodified wheat "B" starch, the reduced viscosity not being less than about 12 centipoise grams per cubic centimeter for a specified dispersion.Type: GrantFiled: February 12, 1985Date of Patent: May 6, 1986Assignee: Ogilvie Mills Ltd.Inventors: Christopher C. Lane, Alexander B. Anonychuk, Peter Unger
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Patent number: 4507173Abstract: A web (12) of highly bulked substrate is passed into a nip formed between a gravure roller (14) and an impression roller (15). The impression roller has raised areas defining an interconnected network of lines such that the web is compressed only under the raised areas; as a result, the binding liquid applied by the gravure roller (14) to the web is absorbed substantially through the web in the compressed areas. The gravure roller (14) may have a uniform surface, such that a light coating of binding liquid is applied to the surface of the uncompressed areas in the web, or the gravure roller may have a pattern of etched grooves or cells which matches and registers with the pattern of raised areas on the impression roller. In the latter embodiment, binding liquid will be absorbed into the web only in the compressed areas.Type: GrantFiled: September 22, 1982Date of Patent: March 26, 1985Assignee: James River-Norwalk, Inc.Inventors: Bernard G. Klowak, Nilo I. Salmeen, Jr., deceased
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Patent number: 4487796Abstract: A method of laminating a two-ply product wherein the plies are laminated to one another and adhered to a creping surface in the same pattern. A first ply is directed about a patterned pressure and imprinting roll and laminating adhesive is applied to the first ply in a pattern corresponding to the pattern of the pressure roll. A second ply is brought into contact with the first ply, and the composite web is adhered to a creping surface with a creping adhesive at a nip formed between the creping surface and the patterned pressure roll. The composite web is creped from the creping surface in a pattern corresponding to the pattern of lamination. When creped, the densified laminated/creped portions add strength to the resulting product, while between the densified areas the webs are not adhered to one another and the void areas therebetween provide sites for water absorption.Type: GrantFiled: July 2, 1981Date of Patent: December 11, 1984Assignee: Kimberly-Clark CorporationInventors: William D. Lloyd, Richard W. Evers
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Patent number: 4482429Abstract: Paper webs are produced in a modified conventional felted wet press process in which the fiber furnish has a chemical debonding agent added thereto in high concentrations. The web (17) is formed on a conventional Fourdrinier wire (12), transferred to a moving felt (19) which presses the web against the surface of a drying cylinder (23) to reduce its water content, and is carried by the surface of the drying cylinder (23) to a creping blade (24). Liquid adhesive is applied to the surface of the creping cylinder (23) adhead of the contact with the web to provide substantial adherence of the web to the creping surface at the point of contact with the creping blade. The levels of addition of debonding agent to the pulp furnish and the amount of adhesive applied to the creping surface are selected such that the adhesion of the web to the surface at the creping blade is greater than the internal cohesion of the web.Type: GrantFiled: September 29, 1982Date of Patent: November 13, 1984Assignee: James River-Norwalk, Inc.Inventor: Bernard G. Klowak
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Patent number: 4448638Abstract: Paper webs are produced in a modified conventional felted wet press process in which the fiber furnish has a chemical debonding agent added thereto in high concentrations. The web (17) is formed on a conventional Fourdrinier wire (12), transferred to a moving felt (19) which presses the web against the surface of a drying cylinder (23) to reduce its water content, and is carried by the surface of the drying cylinder (23) to a creping blade (24). Liquid adhesive is applied to the surface of the creping cylinder (23) adhead of the contact with the web to provide substantial adherence of the web to the creping surface at the point of contact with the creping blade. The levels of addition of debonding agent to the pulp furnish and the amount of adhesive applied to the creping surface are selected such that the adhesion of the web to the surface at the creping blade is greater than the internal cohesion of the web.Type: GrantFiled: September 29, 1982Date of Patent: May 15, 1984Assignee: James River-Dixie/Northern, Inc.Inventor: Bernard G. Klowak
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Patent number: 4447294Abstract: A process for making soft, absorbent tissue paper webs and the webs made by that process. In the first step, a furnish of papermaking fibers and a wet strength resin is provided. A wet fibrous web is made from the furnish and the wet web is dried. Next, the wet strength resin in the web is at least partially cured. A nitrogenous cationic debonding agent is then incorporated into the dried web.Type: GrantFiled: December 30, 1981Date of Patent: May 8, 1984Assignee: The Procter & Gamble CompanyInventor: Thomas W. Osborn, III
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Patent number: 4441962Abstract: Tissue paper webs useful in the manufacture of soft, absorbent products such as paper towels, and processes for making the webs. The process comprises the steps of forming an aqueous papermaking furnish from paper pulp, at least one specified quaternary ammonium compound and at least one specified nonionic surfactant. The quaternary ammonium compounds are trimethylalkyl, trimethylalkylene, methylpolyoxyethylene alkyl and methylpolyoxyethylene alkylene quaternary ammonium compounds. The nonionic surfactants are ethylene oxide adducts of fatty alcohols and fatty acids. The second and third steps in the basic process are the deposition of the papermaking furnish onto a foraminous surface such as a Fordrinier wire and removal of the water from the deposited furnish.Type: GrantFiled: July 30, 1982Date of Patent: April 10, 1984Assignee: The Procter & Gamble CompanyInventor: Thomas W. Osborn, III
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Patent number: 4440898Abstract: A creping adhesive comprises an admixture of an ethylene oxide/propylene oxide copolymer and a high molecular weight thermoplastic polymer.Type: GrantFiled: June 17, 1982Date of Patent: April 3, 1984Assignee: Kimberly-Clark CorporationInventors: William S. Pomplun, Herbert E. Grube
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Patent number: 4440597Abstract: High bulk, absorbent paper having a relatively high MD elongation at rupture, and a substantially greater stress/strain modulus in the lowest one-third of its range of MD extensibility--preferably when wet--than equally machine-direction-stretchable, purely dry-foreshortened (e.g., dry-creped) paper having substantially identical MD elongation at rupture. The process includes a differential velocity transfer of a wet-laid embryonic web having relatively low fiber consistency from a carrier to a substantially slower moving, open-mesh transfer fabric having a substantial void volume; and thereafter drying the web while precluding substantial macroscopic rearrangement of the fibers in the plane of the web. The differential velocity transfer is effected without substantial compaction of the web by avoiding substantial mechanical pressing, centrifugal slinging, air blasting, and the like.Type: GrantFiled: March 15, 1982Date of Patent: April 3, 1984Assignee: The Procter & Gamble CompanyInventors: Edward R. Wells, Thomas A. Hensler
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Patent number: 4436867Abstract: A creping adhesive comprises an admixture of poly 2-ethyl-2-oxazoline and a high molecular weight thermoplastic polymer.Type: GrantFiled: June 17, 1982Date of Patent: March 13, 1984Assignee: Kimberly-Clark CorporationInventors: William S. Pomplun, Herbert E. Grube
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Patent number: 4429014Abstract: A multi-layered wiper and method of making it, the wiper having at least one strong surface region of fibers having a predominate length of less than one-fourth inch and having bonding material disposed therein in a fine spaced apart pattern, the areas in the strong surface region where the bonding material is disposed being finely creped and at least one inner core region of fibers having a predominate length of less than one-fourth inch and generally having less fiber concentration than the surface region, and at least one interior strong region of fibers having a predominate length of less than one-fourth inch and having a greater fiber concentration than in the inner core region and having bonding material disposed therein in a fine spaced apart pattern to bond the fibers in the interior strong region together into a strong network, the bonding material in the interior strong region being substantially unconnected to the bonding material in the strong surface region and a strengthening layer comprising aType: GrantFiled: July 16, 1982Date of Patent: January 31, 1984Assignee: Scott Paper CompanyInventors: William G. Isner, John C. Smoyer
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Patent number: 4406737Abstract: A procedure is disclosed for creping paper without conferring wet strength or sizing thereto.Type: GrantFiled: September 11, 1981Date of Patent: September 27, 1983Assignee: Rohm and Haas CompanyInventors: Joseph J. Latimer, Travis E. Stevens
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Patent number: 4356059Abstract: A system for producing a bulky, soft and absorbent paper web wherein the web is creped from a first creping surface, passes through a nip formed between a dewatering felt and imprinting fabric of a specified character and is applied to and creped from a second creping surface.Type: GrantFiled: November 16, 1981Date of Patent: October 26, 1982Assignee: Crown Zellerbach CorporationInventor: Ronald E. Hostetler
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Patent number: 4351699Abstract: Tissue paper webs useful in the manufacture of soft, absorbent products such as paper towels, and processes for making the webs. The process comprises the steps of forming an aqueous papermaking furnish from paper pulp, at least one specified quaternary ammonium compound and at least one specified nonionic surfactant. The quaternary ammonium compounds are trimethylalkyl, trimethylalkylene, methylpolyoxyethylene alkyl and methylpolyoxyethylene alkylene quaternary ammonium compounds. The nonionic surfactants are ethylene oxide adducts of fatty alcohols and fatty acids. The second and third steps in the basic process are the deposition of the papermaking furnish onto a foraminous surface such as a Fordrinier wire and removal of the water from the deposited furnish.Type: GrantFiled: October 15, 1980Date of Patent: September 28, 1982Assignee: The Procter & Gamble CompanyInventor: Thomas W. Osborn, III
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Patent number: 4326000Abstract: Disclosed is a unitary or integral laminate-like fibrous web having a first and second surface region and a central core region which has less fiber concentration than the first surface region. The first surface region has a surface disposition of bonding material disposed only in that region to form a strong, abrasion-resistant surface. The central core region has a penetrating disposition of bonding material extending through that region in a fine, spaced-apart pattern occupying less area in the plane of the web than the surface bonding material in the first surface region. The penetrating bonding material in the central core region penetrates entirely through that region and connects the first and second surface regions together by penetrating to at least within a fiber thickness of the web surface to provide abrasion-resistance for that surface region.Type: GrantFiled: October 29, 1975Date of Patent: April 20, 1982Assignee: Scott Paper CompanyInventor: Clifford J. Roberts, Jr.
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Patent number: 4308092Abstract: A procedure is disclosed for creping paper without conferring wet strength or sizing thereto.Type: GrantFiled: May 7, 1976Date of Patent: December 29, 1981Assignee: Rohm and Haas CompanyInventors: Joseph J. Latimer, Travis E. Stevens
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Patent number: 4304625Abstract: In the commercial production of tissue paper and the like a web, formed from a slurry of water and fiber, is creped while essentially (98%) dry, from a rotating cylindrical dryer. Adhesives are frequently employed to hold the web to the dryer surface and polyvinyl acetate-ethylene copolymer emulsions serve this function. Such adhesives are relatively soft, tend to adhere to the fabrics which carry the paper web to the dryer surface and tend to make cleaning of the carrying fabric difficult. Additionally, these adhesives tend to cause blocking of the tissue paper when in roll form and adjacent plies of the paper tend to be torn upon separation.Type: GrantFiled: November 13, 1979Date of Patent: December 8, 1981Assignee: Kimberly-Clark CorporationInventors: Herbert E. Grube, Terrence D. Ries
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Patent number: 4300981Abstract: A layered paper and method of making it, which paper is characterized by having a soft, relatively untextured smooth velutinous surface defined by a multiplicity of relatively flaccid papermaking fibers having unbonded free end portions of substantial length, and which surface is subjectively discernible by humans as being extremely soft and smooth. Exemplary embodiments include tissue paper, and tissue paper products comprising one or more plies of such paper. The method includes wet laying a layered web which has a relatively low bond surface layer comprising at least about 60% relatively short papermaking fibers, drying the web without imparting substantial texture thereto, breaking sufficient papermaking bonds in the surface layer to generate a velutinous surface having an FFE-Index of at least about 60 and preferably at least about 90, and calendering the dried web as required to provide said surface layer with an HTR-Texture of about 1.0 or less, and more preferably about 0.Type: GrantFiled: November 13, 1979Date of Patent: November 17, 1981Assignee: The Procter & Gamble CompanyInventor: Jerry E. Carstens
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Patent number: 4208459Abstract: A method is disclosed for forming a strong, soft, fibrous sheet material having substantial stretch in all directions in its own plane, by applying a pattern of bonding material to a fibrous web, adhering only portions of the web containing bonding material to a creping surface, removing the web from the creping surface by a creping blade to differentially crepe it, whereby a combination of high strength, softness, and bulk are imparted to the web. Sheet materials formed by the above method are also disclosed.Type: GrantFiled: November 12, 1976Date of Patent: June 17, 1980Inventors: Henry E. Becker, Albert L. McConnell, Richard W. Schutte
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Patent number: 4196044Abstract: A process for producing cellulosic products which are particularly suitable for use as electrical insulators. The product is produced by creping base paper or stock and thereafter calendering the paper so that its final density is equal or greater than its starting density. The resulting creped product desirably has a density in the range from 0.8 to 1.2 grams per cubic centimeter, an increased Gurley densometer reading and has such mechanical and electrical properties as flexibility, extensibility and insulative effect.Type: GrantFiled: May 12, 1978Date of Patent: April 1, 1980Assignee: Dennison Manufacturing CompanyInventors: Frank L. Mussoni, Gary A. Withrow
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Patent number: 4166001Abstract: A process for directly forming multiple layer web, and creping such webs to provide absorbent, soft and bulky, creped tissue. The process produces a laminar fibrous formation with outer layers of strongly bonded fibers separated by an intermediate central section of weakly bonded fibers, which outer layers are creped such that the crepe in one outer layer is independent of the crepe in the other outer layer.Type: GrantFiled: February 10, 1977Date of Patent: August 28, 1979Assignee: Kimberly-Clark CorporationInventors: Charles E. Dunning, William D. Lloyd, Joseph G. Bicho
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Patent number: 4158594Abstract: A method is disclosed for forming a strong, soft, fibrous sheet material having substantial stretch in all directions in its own plane, by formimg a web of cellulosic fibers having a basis weight of from about 5 to about 55 pounds per ream of 2,880 square feet, adhering one surface of the web to a creping surface in a fine pattern arrangement by a bonding material adhered to one surface of the web and to the creping surface in the fine pattern arrangement, and creping the web from the creping surface to form the sheet material. Sheet materials formed by the above method are also disclosed.Type: GrantFiled: June 24, 1971Date of Patent: June 19, 1979Assignee: Scott Paper CompanyInventors: Henry E. Becker, Albert L. McConnell, Richard W. Schutte
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Patent number: 4125659Abstract: A fibrous web is uniformly adhered to the surface of a smooth creping cylinder or other creping surface without causing substantial compression of the web. A raised pattern is pressed into the web toward the creping cylinder to cause the portions of the web that are pressed to adhere more strongly to the creping surface, while the portions of the web that are not pressed remain more lightly adhered to the creping surface. The web is creped from the creping surface with a creping blade, and the resulting product has a pattern creped appearance wherein the portions of the web that are pressed are finely creped while the portions of the web that were not so pressed are coarsely creped.Type: GrantFiled: June 1, 1976Date of Patent: November 14, 1978Assignee: American Can CompanyInventors: Bernard G. Klowak, Walter L. Pauls, Frederick J. Vermillon, Jr.
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Patent number: 4093765Abstract: A soft, absorbent fibrous web is formed from an aqueous slurry and includes randomly arranged and contacting wood pulp fibers produced by the sulfate process which constitute the predominate fiber component, by weight, of the web. A portion of the web thickness is substantially free of debonders and wet strength additives, and the fibers in that portion of the web are held together almost exclusively by papermaking bonds. A plurality of partially fractured areas are provided in spaced-apart regions which are substantially uniformly distributed throughout the web. An adhesive bonding material extends only partially through the web thickness to form adhesively bonded regions having a greater strength than underlying regions which are bonded together almost exclusively by the papermaking bonds. The web of this invention has a basis weight in the range of from about 25 to about 100 lbs/2,880 feet.sup.2, a density of from about 0.08 grams/cc to less than about 0.16 grams/cc.Type: GrantFiled: February 13, 1976Date of Patent: June 6, 1978Assignee: Scott Paper CompanyInventor: Frank P. Schmidt
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Patent number: 4078958Abstract: Method of manufacture of a hand-towel strip to be used in roll form in an automatic distributor with re-winding of the used portion, wherein a composite web comprising a flexible grid covered on each face with a layer of cellulose wadding, is dry creped and said creping is completely removed by stretching the composite web to a length superior to its initial length.Type: GrantFiled: August 2, 1976Date of Patent: March 14, 1978Assignee: Cie des Ets. de la Risle-Papeteries de Pont-AudemerInventor: Claude Patin
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Patent number: 4063995Abstract: Creping of fibrous webs to enhance their softness and bulk is improved and the resulting creped web is made strong, water dispersible and non-blocking by employing a bonder and creping adhesive composition containing four components which are blended to produce a mixture having a percent solids of from 10% to 40% and an initial modulus for a film of the solids of less than 1.75 .times. 10.sup.8 dynes/cm.sup.2. The composition (mixture) functions as a bonder for the fibers to impart strength and as a creping adhesive for the web so that creping enhances softness and bulkiness. Also disclosed are methods of creping employing such a bonder and creping adhesive composition and sheet materials creped with such compositions.Type: GrantFiled: October 26, 1976Date of Patent: December 20, 1977Assignee: Scott Paper CompanyInventor: Stephen Richard Grossman
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Patent number: 4064213Abstract: Mechanical creping of fibrous webs is improved by employing two creping adhesives applied at different points in the papermaking process and having relatively different adhesive properties for adhering the web to the creping surface. The process crepes the web from a conventional creping surface by applying a layer of a first creping adhesive directly onto the creping surface while applying a second creping adhesive to the web, followed by pressing the web onto the already formed layer of first creping adhesive and then creping the web from the creping surface.Type: GrantFiled: February 9, 1976Date of Patent: December 20, 1977Assignee: Scott Paper CompanyInventors: Nicholas W. Lazorisak, Fredric A. Christiansen, John M. Harriz
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Patent number: 3940529Abstract: Disclosed is a non-nested, two-ply, absorbent fibrous sheet material consisting of two webs which each have a plurality of crests and depressions on its surface facing the other web. The crests on each web are positioned between the crests of the other web and are spaced from the depressions of the other web to leave spaces in the sheet material for increased absorbency and bulk. The two webs are joined together at locations intermediate the crests and depressions of at least one of the webs, preferably by mechanical welding in a manner which produces perforations in the sheet material. Also disclosed is the method and apparatus for making the two-ply sheet material.Type: GrantFiled: July 5, 1973Date of Patent: February 24, 1976Assignee: Scott Paper CompanyInventors: Richard R. Hepford, Clifford J. Roberts, Jr.