Abstract: Multi-layered tissue paper webs comprising chemical softener compositions and binder materials are disclosed. The multi-layered tissue webs are useful in the manufacture of soft, absorbent paper products such as facial tissues and/or toilet tissues. The multi-layered tissue paper products contain a chemical softening composition comprising a mixture of a quaternary ammonium compound and a polyhydroxy compound. Preferred quaternary ammonium compounds include dialkyl dimethyl ammonium salts such as di(hydrogenated)tallow dimethyl ammonium chloride, di(hydrogenated)tallow dimethyl ammonium methyl sulfate. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, sorbitols, polyglycerols having a weight average molecular weight of from about 150 to about 800, polyoxyethylene glycols and polyoxypropylene glycols having a weight average molecular weight from about 200 to 4000.

Abstract: Disclosed is a method for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means, treating said adhered web with an amido amine salt derived from a partially acid-neutralized amine, and creping said treated web from said thermal drying means.

Abstract: Multi-ply facial tissue paper products comprising chemical softener compositions and a combination of a wet strength binder, permanent and/or temporary, and a dry strength binder is disclosed.The multi-ply facial tissue paper products contain a chemical softening composition comprising a mixture of a quaternary ammonium compound and a polyhydroxy compound. Preferred quaternary ammonium compounds include dialkyl dimethyl ammonium salts such as di(hydrogenated)tallow dimethyl ammonium chloride and/or di(hydrogenated)tallow dimethyl ammonium methyl sulfate. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, polyglycerols having a weight average molecular weight of from about 150 to about 800, polyoxyethylene glycols and polyoxypropylene glycols having a weight average molecular weight from about 200 to 1000.

Abstract: Disclosed is a process for making soft tissue paper which includes providing a dry tissue web and then applying a sufficient amount of a functional-polysiloxane softener compound to the dry web. The softener application process includes the steps of mixing a functional-polysiloxane compound with a suitable nonvolatile diluent, such as a mineral oil, forming an emulsion containing the functional-polysiloxane compound and nonvolatile diluent using a volatile solvent, such as water, and surfactant emulsifier, applying the emulsion to a heated transfer surface, evaporating the volatile solvent from the emulsion to form a film, and then contacting the dry tissue web with the heated transfer surface. Preferably, the tissue web is dried to a moisture level below its equilibrium moisture content before application of the functional-polysiloxane material.

Abstract: A process for making tissue papers, in particular pattern densified tissue papers, having an enhanced tactile sense of softness when treated with tri-component biodegradable softener compositions are disclosed. These tri-component softener compositions comprise nonionic softeners, nonionic surfactant compatibilizers and polyhydroxy compounds. The weight ratio of the nonionic softeners to the nonionic surfactant compatibilizers ranges typically from about 10:1 to 1:10. The weight ratio of the nonionic softeners to the polyhydroxy compounds ranges typically from about 10:1 to 1:10. The tri-component biodegradable softeners are typically applied from an aqueous dispersion to at least one surface of the dry tissue paper web.

Abstract: Disclosed is a process for making soft tissue paper which includes providing a dry tissue web and then applying a sufficient amount of a functional-polysiloxane softener compound to the dry web. The softener application process includes the steps of mixing a functional-polysiloxane compound with a suitable nonvolatile diluent, such as a nonfunctional-polysiloxane, forming an emulsion containing the functional-polysiloxane compound and nonvolatile diluent using a volatile solvent, such as water, and surfactant emulsifier, applying the emulsion to a heated transfer surface, evaporating the volatile solvent from the emulsion to form a film, and then contacting the dry tissue web with the heated transfer surface. Preferably, the tissue web is dried to a moisture level below its equilibrium moisture content before application of the functional-polysiloxane material.

Abstract: The present invention is directed to an embossed ply suitable for use in a multi-ply, embossed paper. The embossed ply has bosses of two different depths wherein the bosses having a greater depth or the "big bosses" alternate with the more shallow bosses or "small bosses". When the embossed ply is used to form a multi-ply paper, the small bosses are arranged in a tip-to-tip relation with bosses in a second embossed ply, while the big bosses of the first ply are positioned to nest between the bosses of the second ply. Furthermore, a method and apparatus for manufacturing the embossed, multi-ply paper is described.

Abstract: Improved halogen-free Yankee Dryer adhesives based on cross linked cat ionic polyaminoamide polymers are described. The adhesives are obtained by crosslinking a backbone cationic polymer formed by reacting a difunctional carboxylic acid with a polyamine containing at least one secondary amine, said crosslinking achieved by the use of a multi-functional aidehyde. The preferred adhesive is that obtained by reacting adipic acid with diethylenetriamine, at essentially equimolar ratios of from about 1.2: 1.0 to about 1.0: 1.2, and then crosslinking with a dialdehyde selected from glutaraldehyde, glyoxal, or mixtures thereof. Improved adhesion and peel strength are obtained when using the new materials as compared to materials now commercially used.

Abstract: The invention provides a method for manufacturing tissue paper. According to the method, a yankee dryer adhesive composition is applied to a metal surface of a drying drum. The yankee dryer adhesive composition preferably includes from about 1 to about 100 mole percent vinylamine and from about 1 to about 99 of at least one monomer selected from the group consisting of vinylformamide, vinyl acetate and vinyl alcohol. The yankee dryer adhesive composition is contacted with a continuous paper web. The continuous paper web is then dried. The dry continuous paper web is creped with a metal blade to form tissue paper.

Abstract: Disclosed is a method for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of an adhesive compositon that includes a non-self-crosslinkable polymer or oligomer having functional groups that can be crosslinked by ionic crosslinking, a metallic crosslinking agent having a valence of four or more, and a phosphate surfactant, and creping said treated web from said thermal drying means.

Abstract: Tissue papers, in particular pattern densified tissue papers, having an enhanced tactile sense of softness when treated with certain polyhydroxy fatty acid amide softener systems that are biodegradable are disclosed. The polyhydroxy fatty acid amides have the formula: ##STR1## wherein R.sup.1 is H, C.sub.1 -C hydrocarbyl, 2-hydroxyethyl, 2-hydroxypropyl, methoxyethyl, methoxypropyl or a mixture thereof; R.sup.2 is a C.sub.5 -C.sub.31 hydrocarbyl group; and Z is a polyhydroxyhydrocarbyl moiety having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain.

Abstract: A method for producing a decorative panel wall paper and the like out of a flat piece of creaseable material wherein the piece is first creased along a multitude of crease lines to form a relatively flat production blank configured with a topography having peak portions and valley portions formed by regions of the piece between various ones of the crease lines, comprising the step of either spraying a sprayable pigment onto at least one side of the piece in an oblique direction so that the sprayable pigment impinges and is retained on windward sides of the peak portions with valley portions and leeward sides of the peak portions being shielded from the sprayable pigment, or immersing the piece into a fluid dip to coat the surface portions with a film operative to alter the appearance thereof and thereafter forming a relatively flat production blank.

Abstract: Tissue papers, in particular pattern densified tissue papers, having an enhanced tactile sense of softness when treated with tri-component biodegradable softener compositions are disclosed. These tri-component softener compositions comprise nonionic softeners, nonionic surfactant compatibilizers and polyhydroxy compounds. The weight ratio of the nonionic softeners to the nonionic surfactant compatibilizers ranges typically from about 10:1 to 1:10. The weight ratio of the nonionic softeners to the polyhydroxy compounds ranges typically from about 10:1 to 1:10. The tri-component biodegradable softeners are typically applied from an aqueous dispersion to at least one surface of the dry tissue paper web.

Abstract: Addition of a polyhydric alcohol to creping adhesive formulation comprising a water soluble binder increases operational efficiency.

Abstract: Fibrous cellulose materials useful in the manufacture of soft, absorbent paper products such as paper towels, facial tissues, and toilet tissue are disclosed. The paper products contain a biodegradable chemical softening composition comprising a mixture of a biodegradable quaternized ester-amine compound and a polyhydroxy compound. Preferred biodegradable quaternized ester-amine compounds include diester dialkyldimethylammonium salts such as the diester ditallow dimethyl ammonium chloride, diester di(touch hydrogenated) tallow dimethyl ammonium chloride and diester di(hydrogenated) tallow dimethyl ammonium chloride. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, and polyethylene glycols and polypropylene glycols having a weight average molecular weight from about 200 to 4000.

Abstract: Tissue paper webs useful in the manufacture of soft, absorbent products such as paper towels, napkins, and facial tissues, and processes for making the webs. The tissue paper webs comprise papermaking fibers, a biodegradable quaternized amine-ester softening compound, a wetting agent, and a permanent wet strength resin. The process comprises a first step of forming an aqueous papermaking furnish from the above-mentioned components. The second and third steps in the basic process are the deposition of the papermaking furnish onto a foraminous surface such as a Fourdrinier wire and removal of the water from the deposited furnish. An alternate process involves the use of the furnish containing the aforementioned components in a papermaking process which will produce a pattern densified fibrous web having a relatively high bulk field of relatively low fiber density in a patterned array of spaced zones of relatively high fiber density.

Abstract: Tissue paper webs useful in the manufacture of soft, absorbent products such as napkins, facial tissues, and sanitary tissues, and processes for making the webs. The tissue paper webs comprise papermaking fibers, a biodegradable quaternized amine-ester softening compound, a wetting agent, and a temporary wet strength resin. The process comprises a first step of forming an aqueous papermaking furnish from the above-mentioned components. The second and third steps in the basic process are the deposition of the papermaking furnish onto a foraminous surface such as a Fourdrinier wire and removal of the water from the deposited furnish. An alternate process involves the use of the furnish containing the aforementioned components in a papermaking process which will produce a pattern densified fibrous web having a relatively high bulk field of relatively low fiber density in a patterned array of spaced zones of relatively high fiber density.

Abstract: A creping adhesive is described which provides the ability to readily control glass transition temperature (Tg) and adhesion and which can be easily removed from dryer surfaces. The creping adhesive contains a crosslinkable polymer and preferably an ionic crosslinking agent such as metal cations having a valence of three or more.

Abstract: Disclosed is a process for making soft tissue paper which includes providing a dry tissue web and then applying a sufficient amount of a polysiloxane softener compound to the dry web. The softener application process includes the steps of diluting a polysiloxane compound with a suitable solvent, applying the diluted polysiloxane solution to a heated transfer surface, evaporating the solvent from the dilute solution to form a film, and then contacting the dry tissue web with the heated transfer surface. Preferably, the tissue web is dried to a moisture level below its equilibrium moisture content before application of the polysiloxane material. The process may further include the steps of applying an effective amount of a surfactant material to enhance softness and/or wettability control; and/or an effective amount of a binder material such as starch, for linting control, and/or to contribute tensile strength to the tissue paper.

Abstract: Disclosed is a process for making soft tissue paper which includes providing a dry tissue web and then applying a sufficient amount of a chemical papermaking additive from a thin film to the dry web. The chemical papermaking additives are added to the surface of the tissue paper to enhance properties of the paper such as strength, softener, absorbency, and/or aesthetics. The chemical papermaking additive application process includes the steps of diluting the chemical papermaking additive with a suitable solvent, applying the diluted chemical solution to a heated transfer surface, evaporating the solvent from the dilute solution to form a film, and then transferring the film to the tissue by contacting the dry tissue web with the heated transfer surface. Preferably, the tissue web is dried to a moisture level below its equilibrium moisture content before application of the papermaking additive.

Abstract: Fibrous cellulose material useful in the manufacture of soft, absorbent paper products such as paper towels, facial tissues, and toilet tissue are disclosed. The paper products contain a chemical softening composition comprising a mixture of a quaternary ammonium compound and a polyhydroxy compound. Preferred quaternary ammonium compound include dialkyldimethylammonium salts such as di(hydrogenated) tallow dimethyl ammonium chloride and di(hydrogenated) tallow dimethyl ammonium methyl sulfate. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, and polyethylene glycols and polypropylene glycols having a weight average molecular weight from about 200 to 4000.

Abstract: A method of creping a paper is described which comprises applying to the creping drum prior to the application of the paper web to be creped, a synthetic anionic polymer.

Abstract: Novel multi-layer paper and tissue products are provided, which possess strength, softness and absorbency. The products comprise either at least two foam deposited paper layers, wherein the foams have different air contents therein, or foam and water deposited layers. The layers can be deposited at about identical feed pressures from a single headbox while still possessing differing tensile strength ratios. Novel processes for forming such products are also provided.

Abstract: Tissue paper webs useful in the manufacture of soft, absorbent products such as paper towels, napkins, and facial tissues, and processes for making the webs. The tissue paper webs comprise papermaking fibers, a quaternary ammonium compound, a polyhydroxy plasticizer, and a permanent wet strength resin. The process comprises a first step of forming an aqueous papermaking furnish from the above-mentioned components. The second and third steps in the basic process are the deposition of the papermaking furnish onto a foraminous surface such as a Fourdrinier wire and removal of the water from the deposited furnish. An alternate process involves the use of the furnish containing the aforementioned components in a papermaking process which will produce a pattern densified fibrous web having a relatively high bulk field of relatively low fiber density in a patterned array of spaced zones of relatively high fiber density.

Abstract: A sheet of fibrous web material having one textile-like surface and an opposite substantially smooth surface, a grain depth memory factor greater than 80, an apparent density in the range of about 4 to about 7 pound ream/caliper point in mils, a caliper (at a basis weight between about 50 and about 75 pounds/3000 square feet) greater than 0.008 inch, and a machine-direction sheet stretch of at least 5%.

Abstract: Tissue paper webs useful in the manufacture of soft, absorbent products such as napkins, facial tissues, and sanitary tissues, and processes for making the webs. The tissue paper webs comprise papermaking fibers, a quaternary ammonium compound, a polyhydroxy plasticizer, and a temporary wet strength resin. The process comprises a first step of forming an aqueous papermaking furnish from the above-mentioned components. The second and third steps in the basic process are the deposition of the papermaking furnish onto a foraminous surface such as a Fourdrinier photo-polymer wire and removal of the water from the deposited furnish. An alternate process involves the use of the furnish containing the aforementioned components in a papermaking process which will produce a pattern densified fibrous web having a relatively high bulk field of relatively low fiber density in a patterned array of spaced zones of relatively high fiber density.

Abstract: Disclosed is a process for making soft tissue paper which includes the steps of wet-laying cellulosic fibers to form a web; drying the web and elevating the web temperature, creping the hot web, and applying low levels of a polysiloxane material to the hot, creped web. Preferably, the hot web is dried to a moisture level below its equilibrium moisture content before application of the polysiloxane material. The process may further include the steps of applying an effective amount of a surfactant material to enhance softness and/or wetability control; and/or an effective amount of a binder material such as starch, for linting control, and/or to contribute tensile strength to the tissue paper.

Abstract: Glyoxylated vinyl amide polymers in combination with polyols provide improved adhesive coating agents for Yankee Dryers.

Abstract: The bulk and absorbency of multi-ply tissue products can be improved by brushing at least one surface of at least one ply of the tissue and plying the tissue product together such that at least one brushed surface is facing inwardly, i.e. is in the middle and not on the outside of the multi-ply product.

Abstract: Improved creping compositions comprising glyoxylated vinylamide polymers in combination with polyvinyl alcohol are disclosed.

Abstract: A foam-formed nonlaminated stratified paper tissue and method of making the same includes a first zone of foam-formed paper tissue formed from a furnish of hardwood fiber. A second zone of foam-formed paper tissue is formed from a furnish of softwood fiber. The second zone is formed unitary and entangled with the first zone to form a nonlaminated stratified paper tissue. A high softness integument is defined adjacent to an outer surface of the first zone and a substratum is defined adjacent to a surface of the second zone spaced away from the integument. The integument on the outer surface of the first zone includes an enriched region having a substantial purity of hardwood fiber and the substratum on the surface of the second zone includes an enriched region having a substantial purity of softwood fiber. The enriched region of substantially pure hardwood fiber provides an extremely soft and smooth surface detectable by human somatic sensibility.

Abstract: A combined sheet material including at least two absorbent sheets, such as of cellulose-cotton, each having a density of between from 10 to 40 g/m.sup.2. Each of the sheets is separately embossed by calendaring them into a pattern of protuberances distributed in a first pitch along a first direction for each sheet (P.sub.1 sm, P.sub.2 sm) and in a second pitch in a second direction for each sheet (P.sub.1 st, P.sub.2 st) which subtends the first direction at an angle other than zero. The end of the protuberances extending away from the plane of each of the sheets includes a flat bonding element whereby the two sheets are bonded to each other, preferably by gluing. The pattern of each of the sheets is characterized in that the first pitch of each sheet along the first direction is different and related by the equation..vertline.1/P.sub.1 sm-1/P.sub.2 sm.vertline..gtoreq.

Abstract: A foam-formed nonlaminated stratified paper tissue includes a first layer of bulky anfractuous fiber blend and a second layer of fiber blend having enhanced softness and caliper as compared to a conventional tissue of equivalent basis weight and strength. In a preferred embodiment, the first layer is a fiber blend of a bulky anfractuous fiber and a chemithermomechanical pulp. A method of forming a foam-formed nonlaminated stratified web of paper tissue material includes supplying a first furnish of a bulky anfractuous fiber blend directly to a foraminous support member. A second furnish of fiber blend is supplied onto the first furnish disposed on the foraminous support member. The furnishes may also be supplied in reverse order depending upon the forming configuration of the machine used. The first and second furnishes form a web of paper tissue material which is dried in a drying device to a predetermined dryness.

Abstract: A process for making soft tissue paper which includes the steps of wet-laying cellulosic fibers to form a web, applying to the wet web, at a fiber consistency level of from about 10% to about 80%, a polysiloxane material, and then drying and creping the web to form the finished tissue paper. The process may further include the steps of applying an effective amount of a surfactant material to enhance softness and/or wettability control; and/or an effective amount of a binder material, such as starch, for linting control, and/or to contribute tensile strength to the tissue paper.

Abstract: Absorbent paper products, such as towels, absorbent wipes, toilet tissue, facial tissue and the like fibrous webs of relatively high bulk, are produced by a method comprising the steps of treating hydrophilic cellulosie fibers to impart kinks, curls, bends, twists, to the fibers; dispersing the treated fibers in an aqueous forming medium, and wet-forming a stratified single-ply web constituted of at least one stratum of the treated fibers and at least one stratum of conventional paper-making fibers. The treating step may consist of wet or dry mechanical working, chemical treatment or a combination of mechanical and chemical treatments. The web forming step comprises preparing a first aqueous furnish of the treated fibers, preparing a second aqueous furnish of the conventional fibers, and concurrently depositing the two furnishes in contiguous layers on a moving foraminous support.

Abstract: In the manufacture of creped tissue products, the adhesion between the tissue sheet and the creping cylinder can be increased by applying one component of an adhesive complex to the sheet and another component of an adhesive complex to the creping cylinder. When the two components are brought into contact at the pressure roll nip, an adhesive complex is formed which adheres the sheet to the creping cylinder.

Abstract: An improved method, and resulting product, for creping a web of papermaking fibers by adhering the web to a creping dryer and with a creping blade removing the web from the creping dryer which provides increased absorbency with less reduction in strength. The improvement comprises reducing the cohesive forces between the fibers to a greater extent than reducing the adhesive forces between the web and the creping dryer accomplished by applying a fluid at least primarily comprising water overall to the side of the web away from the creping dryer in sufficient quantity and at a position to accomplish the improved results. The method is particularly useful in the practice of wet creping wherein the web is creped from the creping dryer at a dryness of from 45% to 60%.

Abstract: Processes are described for making highly absorbent tissues and towels by wet-laying pulps comprising particular polycarboxylate polymer-modified fibrous pulps such as mildly hydrolyzed methyl acrylate-grafted softwood kraft pulps; these pulps have distinct protonated and alkali-metal-cation-exchanged states. The wet-laying processes are adapted to exploit the very different behavior of the polymer-modified fibrous pulps in function of the two states. The preferred wet-laying processes described herein are continuous processes embodying one or more on-line chemical treatment steps which chemically switch state of the polymer-modified fibrous pulp component in a wet web on the papermaking machine to improve the processing thereof by averting or minimizing tendencies to mechanically or thermally degrade.

Abstract: Temporary wet strength resins, and paper products containing same, having a molecular weight of from about 20,000 to about 200,000, most preferably from about 30,000 to aboug 95,000 having the fomula: ##STR1## wherein: A is 0 or ##STR2## and X is --O--, --NH--, or --NCH.sub.3 --, and R is a substituted or unsubstituted aliphatic group; Y.sub.1 and Y.sub.2 are independently --H, --CH.sub.3, or a halogen; W is a nonnucleophilic, water-soluble nitrogen heterocyclic moiety; and Q is a cationic monomeric unit. The mole percent of "a" ranges from about 30% to about 70%, preferably from about 45% to about 55%; the mole percent of "b" ranges from about 30% to about 70%, preferably from about 45% to about 55%; and the mole percent of "c" ranges from about 1% to about 40%, most preferably from about 2% to about 5%.

Abstract: The absorbent laminated sheet is composed of at least two plies (1.9), embossed, constituted essentially of cellulose fibers, bonded together at least partially by means of protruding elements relative to the surface of said plies and pointing inward to the sheet; it is characterized in that the protruding elements (101) are positioned essentially according to lines or combinations of lines reproducing spaced motifs (100), which recur indefinitely.Application as domestic or sanitary paper.

Abstract: An insulating polyolefin laminate paper and a method for producing such a paper in which first and second fiber paper layers are laminated to a polyolefin film layer. The fiber paper layers have an impermeability of 20 to 4000 Gurley-seconds. At least one of the fiber paper layers is mechanically deformed in such a manner that irregularities are produced having a depth of 2 to 50% of the thickness of the fiber paper layer. The mechanical deformation is accomplished prior to lamination. Before lamination, the water content of the fiber paper layers is controlled to be no more than 4%. Preferably, the thickness of the fiber paper layers is at least 30 microns. Furthermore, an electric power supply cable includes an insulating polyolefin laminate paper as an insulating layer.

Abstract: Tissue paper having an enhanced tactile sense of softness through incorporation of an effective amount of a noncationic surfactant is disclosed. Preferably, less than about 2.0% of the noncationic surfactant, on a dry fiber weight basis, is incorporated in the tissue paper: more preferably, only about 1.0% or less is so retained. Tissue paper embodiments of the present invention may further contain a quantity of a binder material, such as starch, for linting control, and to increase paper strength.

Abstract: Disclosed is a process for making soft tissue paper which includes the steps of wet-laying cellulose fibers to form a web, applying to the wet web, at a fiber consistency level of from about 10% to about 80%, a noncationic surfactant, and then drying and creping the web to form the finished tissue paper. The process may further include the steps of applying an effective quantity of a binder material, such as starch, to the wet web for linting control, and to contribute tensile strength to the tissue paper.

Abstract: A method and apparatus is disclosed for the production of a multi-ply sheet product in which separate non-woven fibrous webs are combined into a multi-ply sheet before embossment, embossed as a multi-ply sheet, the embossed webs separated from one another and longitudinally displaced relative to one another, and then recombined into an embossed multi-ply sheet with the embossments out of register with one another. The resulting product exhibits enhanced softness and absorbence as compared with similar products comprising simultaneously embossed multi-ply webs.

Abstract: There has been provided a recreped absorbent product manufactured by forming a web from an aqueous stock, drying the web to a selected consistency and creping one side thereof. The creped web is then conveyed at a selected rate for drying and recreping on the same side. The web moisture consistency, draw speeds, crepe angle and nip pressures as well as crepe adhesive qualities are controlled parameters.

Abstract: A creping adhesive formulation comprising 10-100% by weight of a polymer or copolymer having a Tg greater than 50.degree. C.

Abstract: Addition of a phosphate salt to creping adhesive composition comprising a water soluble binder increases operational efficiency.

Abstract: Disclosed are soft, absorbent and bulky cellulosic fibrous webs which have been treated so that they impart a soothing or emollient effect to the human skin when used for wiping or drying while essentially retaining their water-absorbent property and strength. The agent used in the present invention is a condensation product of an amino acid with a reducing sugar.

Abstract: A process for making a soft, strong cellulosic sheet weighing from about 2 to about 15 pounds per 2880 sq. ft., comprising selectively treating a face surface of a cellulosic fibrous web with a dilute aqueous solution of a chemical debonding agent in an amount effective to soften a surface zone of the web proximate the treated face surface, whereby a composite strong zone/soft surface zone structure results, with the soft surface zone thereof including the treated face surface and being from about 10 to about 40% of the total thickness of the web, and with the strong zone being effectively untreated by the agent. The cellulosic sheet made by this process is characterized by a strong inner surface zone of from about 50 to about 90% of the total thickness of the sheet, and a soft and pleasing-to-the-touch outer surface zone comprising the remainder of the thickness of the sheet.

Abstract: Disclosed are soft, absorbent and bulky cellulosic fibrous webs which have been treated so that they impart a soothing or emollient effect to the human skin when used for wiping or drying while essentially retaining their water-absorbent property and strength. The agent used in the present invention is lauroamphoglycinate.