Carbohydrate Patents (Class 162/175)
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Patent number: 5789031Abstract: A process for manufacturing a coated paper for use in printing is characterized in that the coated paper for printing is produced by coating a color consisting mainly of pigment and a water-soluble binder made of starch or starch derivatives to the surface of a base paper, then drying and finishing it. Steam or an aqueous penetrant solution having a penetrating force of less than 50 seconds is sprayed or applied over the dry coated layer surface of the coated paper, prior to it being finished with a calender, for redistributing the water-soluble binder in the coated layer in order to correct its uneven distribution, which is the cause of printing mottle during the offset printing operation.Type: GrantFiled: December 16, 1996Date of Patent: August 4, 1998Assignee: Oji Paper Co., Ltd.Inventors: Tetsuya Hirabayashi, Hideyuki Suzuki, Terunobu Fukui
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Patent number: 5785813Abstract: An efficient and effective method for treating tissue making stock to make soft tissues involves adding a softening agent to a first papermaking furnish of short fibers, such as eucalyptus fibers. A second papermaking furnish of long fibers, such as softwood fibers, is blended with the short fiber furnish. Thereafter, wet strength agents and/or dry strength agents are added to the blended furnish. The treated furnish is then fed to a headbox and processed into soft tissue in any suitable manner.Type: GrantFiled: February 24, 1997Date of Patent: July 28, 1998Assignee: Kimberly-Clark Worldwide Inc.Inventors: Michael John Smith, Vinay Kumar Rao, Gary Lee Shanklin
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Patent number: 5779859Abstract: A method for improving retention of filler in papermaking systems includes a split stream feed to either the head box or fan pump of a papermaking system. The split stream divides the pulp flow into two streams, one stream having a retention aid and filler added thereto. The retention aid and filler-containing stream is then added back to the other stream upstream of the fan pump or head box. Treating only a portion of the overall pulp flow with the filler/retention aid lowers retention aid consumption, improves paper product appearance and maintains or increases filler retention during papermaking.Type: GrantFiled: December 13, 1996Date of Patent: July 14, 1998Assignee: J.M. Huber CorporationInventors: Richard Douglas Carter, Britt Ciccrchi
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Patent number: 5770013Abstract: A method for manufacturing paper having given physical characteristics is described, and which includes, providing a paper stock slurry of a given composition; removing water from the paper stock slurry to form a continuous sheet of paper; and without the use of a sizing press, providing and applying an aqueous solution of a substantially amylose free starch to the resulting paper in a predetermined amount effective to provide the resulting paper with the given physical characteristics, the paper manufactured at a production rate which is at least 10% faster than the production rate which can be achieved for substantially identical paper having the same given physical characteristics, but which is manufactured using a sizing press.Type: GrantFiled: June 21, 1996Date of Patent: June 23, 1998Assignee: Potlatch CorporationInventors: Nicholas R. Chance, Christopher J. Elskamp, Timothy H. Switzer
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Patent number: 5759249Abstract: Sizing emulsions comprised of (a) hydrophobic cellulose-reactive sizing agents and (b) amines, amine salts and/or quaternary amines are disclosed, as well as low shear and high shear processes for making said emulsions and methods of using said emulsions for sizing paper.Type: GrantFiled: February 4, 1997Date of Patent: June 2, 1998Assignee: Cytec Technology Corp.Inventor: Richard Barkman Wasser
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Patent number: 5759346Abstract: A method for producing uncreped, strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels is disclosed. The tissue papers comprise fibers such as wood pulp and a non-cellulosic, water insoluble particulate filler such as kaolin clay.Type: GrantFiled: September 27, 1996Date of Patent: June 2, 1998Assignee: The Procter & Gamble CompanyInventor: Kenneth Douglas Vinson
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Patent number: 5755930Abstract: Filled paper is made by adding a cationising amount of cationic polymer to precipitated calcium carbonate or other filler either as a slurry or in a thick stock component, producing a thin stock containing the cationised filler and then treating the thin stock with a formaldehyde resin and polyethylene oxide as a retention system prior to drainage and drying.Type: GrantFiled: February 13, 1996Date of Patent: May 26, 1998Assignees: Allied Colloids Limited, Minerals Technologies Inc.Inventors: Brian Frederic Satterfield, Bruce Evans, Thomas Adrian Cauley
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Patent number: 5749954Abstract: A perlite-based insulation board includes, by dry weight, between about 50% and about 76% expanded perlite; between about 15% and about 45% fibers; between about 1% and about 5% starch; between about 2% and about 9% bituminous material; and about 0% to about 3% alum. The fibers are between about 50% and about 95% by dry weight recycled newsprint fibers and between about 5% and about 50% by dry weight virgin cellulose fibers, such as flax and/or peanut hull fibers. In one embodiment, the virgin cellulose fibers are, by dry weight, between about 10% and 40% flax fibers and about 60% and 90% peanut hull fibers.Type: GrantFiled: July 15, 1996Date of Patent: May 12, 1998Assignee: Johns Manville International, Inc.Inventors: David Chee-Fai Law, Christopher Paul Sandoval, Ruben G. Garcia
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Patent number: 5738759Abstract: A recording material including paper containing cellulose fibers as the main component, with the elongation percentage of the paper in the cross direction thereof when immersed in water at 20.degree. C. for 1 minute being 1.8 % or less, is produced and recycled. In addition, paper containing cellulose fibers, with the same elongation percentage as mentioned above in the machine direction thereof is also provided.Type: GrantFiled: October 2, 1995Date of Patent: April 14, 1998Assignee: Ricoh Company, Ltd.Inventors: Hiroshi Kitazawa, Shigeaki Kimura, Eiichi Kawamura, Toshiyuki Kawanishi, Masato Igarashi
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Patent number: 5723023Abstract: The method of making paper wherein the use of a selected ether or ester modified, cationic starch as an additive in the papermaking wet end provides significantly improves retention and drainage properties particularly in alkaline microparticle containing systems.Type: GrantFiled: September 27, 1996Date of Patent: March 3, 1998Assignee: National Starch and Chemical Investment Holding CorporationInventors: John Tsai, Walter Maliczyszyn, Teresa Capitani, Christopher Kulp
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Patent number: 5707493Abstract: A temperature-activated polysilicic acid is prepared by heating an acidified aqueous alkali metal silicate. The temperature-activated polysilicic acid is used in the production of paper for improvement of retention and water removal.Type: GrantFiled: January 29, 1996Date of Patent: January 13, 1998Assignee: J.M. Huber CorporationInventor: Sakari Saastamoinen
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Patent number: 5700352Abstract: A process for incorporating a fine particulate filler such as kaolin clay into tissue paper is disclosed. The process results in strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels.Type: GrantFiled: April 3, 1996Date of Patent: December 23, 1997Assignee: The Procter & Gamble CompanyInventors: Kenneth Douglas Vinson, Howard Thomas Deason
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Patent number: 5695609Abstract: The invention relates to a process for the production of paper by adding to an aqueous fiber suspension, which possibly contains a filler, auxiliary agents for improving retention and/or dewatering, the auxiliary agents being a cationic long-chain polyacrylamide and an aluminum salt, and by dewatering the obtained fiber suspension during the sheet-forming stage. According to the invention, the said aqueous fiber suspension, possibly containing a filler, to which the cationic long-chain polyacrylamide has first been added, is subjected to shearing forces, whereafter there is added to it, directly before sheet forming, a polymeric aluminum salt or an aluminum salt, in which case a base or an acid is added, when necessary, to the said fiber suspension so that the pH be within the range 7-9 before the sheet forming, in which case aluminum hydroxy particles having anionic surface charges will be formed in situ.Type: GrantFiled: January 19, 1996Date of Patent: December 9, 1997Assignee: Kemira OyInventors: Lars Harald Petander, Tore Anders Duvnas
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Patent number: 5690790Abstract: The present invention relates to paper products having temporary wet strength. The paper products contain cellulosic fibers that are treated with a polyaldehyde polymer having free aldehyde groups and a water soluble polyhydroxy polymer. The initial wet strength obtained with the combined use of these materials is significantly greater than that obtained by use of either the polyaldehyde or pelyhydroxy polymer alone. At the same time, the wet strength decays at a rate that is rapid enough to enable the paper product to be flushed under conditions of normal use.Type: GrantFiled: March 28, 1996Date of Patent: November 25, 1997Assignee: The Procter & Gamble CompanyInventors: Michael Martyn Headlam, David Jay Smith
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Patent number: 5672249Abstract: A process for incorporating a fine particulate filler such as kaolin clay into tissue paper is disclosed. The process results in strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels.Type: GrantFiled: April 3, 1996Date of Patent: September 30, 1997Assignee: The Procter & Gamble CompanyInventors: Kenneth Douglas Vinson, John Paul Erspamer, Charles William Neal, Jonathan Andrew Ficke, Jeffress Paul Halter
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Patent number: 5667637Abstract: The invention relates to paper and similar products made with at least a portion of the papermaking furnish being essentially water insoluble carboxyethyl cellulose fibers. A cationic additive material, such as a polyamide epichlorohydrin wet strength resin or cationic starch, is also required. From 2-100% of the modified fiber is used in conjunction with a usual papermaking fiber. The D.S. of the carboxyethylated fiber is in the range of about 0.01-0.3, preferably about 0.025-0.10. A notable feature of paper products made with the fiber/cationic additive system is an improved ratio of wet to dry tensile and burst strengths compared with sheets made from unmodified fiber.Type: GrantFiled: November 3, 1995Date of Patent: September 16, 1997Assignee: Weyerhaeuser CompanyInventors: Richard A. Jewell, David W. Park
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Patent number: 5651862Abstract: Described is a wet-formed composite. The wet-formed composite is formed from a combination of fibers and absorbent material. Specifically, the wet-formed composite is formed from absorbent material and a fiber slurry wherein the absorbent material is swellable in the dispersion medium of the slurry. Also disclosed is a method of forming the wet-formed composite. The method involves forming a fiber slurry, combining an absorbent material with the fiber slurry prior to forming the composite and then forming and drying the composite. The absorbent material is swellable in the dispersion medium of the fiber slurry.Type: GrantFiled: August 13, 1991Date of Patent: July 29, 1997Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Richard Allen Anderson, Richard John Schmidt
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Patent number: 5637193Abstract: A method for bleaching a paper web with peroxide and to a paper surface treatment mixture intended for such a method. According to the invention, peroxide is introduced onto a moving paper web as part of the said mixture, which in addition to the peroxide contains another active component, such as a bonding agent or a surface coating, to be introduced onto the web. The bonding agent may be made up of starch and a surface coating pigment, such as calcium carbonate, kaolin or talc. Peroxide is added to these so that its amount on each side of the web to be bleached will be approx. 0.08-1.0 g/m.sup.2.Type: GrantFiled: October 24, 1994Date of Patent: June 10, 1997Assignee: Kymi Paper Mills Ltd.Inventors: Heikki Y. Hassi, Markku T. O. Johansson, Outi-Maija K. Teittinen
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Patent number: 5635028Abstract: Soft creped tissue paper products comprising papermaking fibers and a crepe facilitating composition are disclosed. The crepe facilitating composition comprises a bonding inhibitor, a cationic starch and a carboxymethyl cellulose. Preferably, the bonding inhibitor is a quaternary ammonium compound. The use of a bonding inhibitor, a cationic starch and a carboxymethyl cellulose results in a creped tissue paper that is both strong and soft. A creped papermaking process comprising the addition of the crepe facilitating composition is also disclosed. The crepe facilitating composition offers the potential to improve production capacity.Type: GrantFiled: April 19, 1995Date of Patent: June 3, 1997Assignee: The Procter & Gamble CompanyInventors: Kenneth D. Vinson, Paul T. Weisman, Dean V. Phan
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Patent number: 5624532Abstract: Tissue paper having an enhanced bulk softness through incorporation of an effective amount of a polyhydroxy compound is disclosed. Preferably, from about 0.1% to about 2.0% of the polyhydroxy compound, on a dry fiber weight basis. These nonionic compounds have high rates of retention when applied to wet tissue paper webs according to the process described herein. Tissue embodiments of the present invention may further comprise a quantity of strength additive, such as starch, to increase paper strength.Type: GrantFiled: February 15, 1995Date of Patent: April 29, 1997Assignee: The Procter & Gamble CompanyInventors: Paul D. Trokhan, Dean V. Phan
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Patent number: 5614062Abstract: A process for controlling the deposition of stickies from paper stock suspensions in papermaking involving the steps of: (a) providing a paper stock suspension containing stickies; and (b) contacting the stickies in the paper stock suspension with a native starch.Type: GrantFiled: October 6, 1995Date of Patent: March 25, 1997Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Heinz-Guenther Schulte, Klaus Hornfeck, Dieter Kaps
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Patent number: 5595630Abstract: A process for producing paper, utilizing a combination of anionic and cationic aluminum compound additives and providing superior freeness and diminished turbidity, is provided.Type: GrantFiled: August 31, 1995Date of Patent: January 21, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert H. Moffett
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Patent number: 5595631Abstract: The invention involves the method of sizing paper products using a size composition comprising an aqueous dispersion of:a) cyclic dicarboxylic acid anhydride containing hydrophobic substitution, and b) cationic, non-degraded starch which is further modified to a DS of from about 0.005 to 0.4 with either:i) an ether group, R--O-- where R is an hydroxyalkyl or alkyl of 1 to 4 carbon atoms, or alkenyl of 2 to 4 carbon atoms, orii) an ester group, ##STR1## where R is an alkyl of 1 to 4 carbon atoms or alkenyl of 2 to 4 carbon atoms, and wherein;the non-degraded, fully modified starch has a viscosity of at least 1,000 cPs at 30.degree. C. in an 8% aqueous solution.Type: GrantFiled: May 17, 1995Date of Patent: January 21, 1997Assignee: National Starch and Chemical Investment Holding CorporationInventors: John J. Tsai, Walter Maliczyszyn
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Patent number: 5584966Abstract: An improved method of paper formation, utilizing a combination of polysilicate microgel, anionic and cationic polymers with the optional utilization of an aluminum salt, is provided.Type: GrantFiled: February 21, 1995Date of Patent: December 17, 1996Assignee: E. I. du Pont de Nemours and CompanyInventor: Robert H. Moffett
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Patent number: 5582682Abstract: The specification discloses an unorthodox system for manufacturing strong, light-weight and weather-resistant cellulosic composite materials from discarded paper and newsprint, and papermill sludge--and from an unlimited variety of particulated fibrous lignocellulosics--without the use of an extrinsic adhesive. Both the matrix-forming resin and the fiber-substrate, which comprise the entire composite, are spontaneously created in situ at ambient conditions by the ammoniation of a mixture of a protein-containing material and a particulated cellulosic. Heating an article shaped from such a mixture to above 175.degree. C. polymerizes the resin and bonds the fiber-substrate into a cellulosic composite product. Also disclosed is a process for manufacturing reinforced and laminated composites as well as a composition which simplifies the production of both cellulosic composites and all-biomass thermosetting resins.Type: GrantFiled: May 31, 1994Date of Patent: December 10, 1996Inventor: Arthur Ferretti
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Patent number: 5578169Abstract: The invention relates to a method for reducing the amount of interference substances in the water circulations of processes involving wood-based fibre suspensions by binding the disturbance substances to the fibres by means of cationic starch. The amount of the said starch added to the fibre suspension is approximately 0.04-0.5% of the fibre weight.Type: GrantFiled: May 5, 1994Date of Patent: November 26, 1996Assignee: Raision Tehtaat OY ABInventor: Tapio Vihervaara
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Patent number: 5573637Abstract: Tissue paper products comprising a two component chemical softener composition and binder materials, either permanent or temporary wet strength binders, and/or dry strength binders are disclosed. The two component chemical softening composition comprises a quaternary ammonium compound and a polysiloxane compound. Preferred quaternary ammonium compounds include dialkyl dimethyl ammonium salts such as di(hydrogenated)tallow dimethyl ammonium chloride and/or di(hydrogenated)tallow dimethyl ammonium methyl sulfate. Preferred polysiloxanes include amino-functional polydimethyl polysiloxanes wherein less than about 10 mole percent of the side chains on the polymer contain an amino-functional group.Type: GrantFiled: December 19, 1994Date of Patent: November 12, 1996Assignee: The Procter & Gamble CompanyInventors: Robert S. Ampulski, Joel K. Monteith, Ward W. Ostendorf, Dean Van Phan, Paul D. Trokhan
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Patent number: 5543459Abstract: Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free moneothylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule,in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.Type: GrantFiled: March 9, 1995Date of Patent: August 6, 1996Assignee: BASF AktiengesellschaftInventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz, Friedrich Linhart, Andreas Stange
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Patent number: 5538595Abstract: Tissue paper products comprising a two component chemical softener composition and binder materials, either permanent or temporary wet strength binders, and/or dry strength binders are disclosed. The two component chemical softening composition comprises an ester-functional ammonium compound and a polysiloxane compound. Preferred ester-functional ammonium compounds include diester dialkyl dimethyl ammonium salts such as diester di(touch hardened)tallow dimethyl ammonium chloride and/or di(hydrogenated)tallow dimethyl ammonium chloride. Preferred polysiloxanes include amino-functional polydimethyl polysiloxanes wherein less than about 10 mole percent of the side chains on the polymer contain an amino-functional group.Type: GrantFiled: May 17, 1995Date of Patent: July 23, 1996Assignee: The Proctor & Gamble CompanyInventors: Paul D. Trokhan, Dean V. Phan, Ward W. Ostendorf, Joel K. Monteith, Bart S. Hersko, Robert S. Ampulski
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Patent number: 5512135Abstract: The present invention relates to a process for improved dewatering and retention in the production of paper, where an anionic retention agent based on starches, cellulose derivatives or guar gums having no cationic groups and an acidic solution of an aluminum compound are added to the stock containing lignocellulose-containing fibres and optionally fillers. The pH of the stock prior to the addition of the aluminium compound should be at least about 6 to obtain the desired cationic aluminium hydroxide complexes in the stock. The present invention is cost effective and insensitive to the content of calcium in the white water.Type: GrantFiled: January 3, 1994Date of Patent: April 30, 1996Assignee: Eka Nobel ABInventors: Bruno Carre, Ulf Carlson
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Patent number: 5501771Abstract: Homogeneous and regular paper sheets are shaped, via conventional papermaking technique, from nonpolluting papermaking compositions comprising an aqueous suspension of cellulosic papermaking fibers that also include (a) an inorganic filler material, (b) a papersizing agent and (c) a ternary retention additive which comprises (c)(1) a cationic starch, (c)(2) a polyaluminum chloride and (c)(3) an anionic silica.Type: GrantFiled: April 28, 1994Date of Patent: March 26, 1996Assignee: Elf Atochem S.A.Inventor: Lucien Bourson
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Patent number: 5501774Abstract: Filled paper is made by providing an aqueous feed suspension containing filler and cellulosic fibre, coagulating the fibre and filler in the suspension by adding cationic coagulating agent, making an aqueous thinstock suspension by diluting a thickstock consisting of or formed from the coagulated feed suspension, adding anionic particulate material to the thinstock or to the thickstock from which the thinstock is formed, subsequently adding polymeric retention aid to the thinstock and draining the thinstock for form a sheet and drying the sheet.Type: GrantFiled: January 21, 1994Date of Patent: March 26, 1996Assignee: Allied Colloids LimitedInventor: Anthony J. Burke
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Patent number: 5500087Abstract: Amino-multicarboxylate starch ether derivatives are provided having the following structure: ##STR1## wherein St-O represents a starch molecule,R is H or CH.sub.3 ;R' is H, CH.sub.3 or COOH;M is a cation;n is 2 or 3; andR" is H or alkyl of 1 to 18 carbon atoms.These starch derivatives are particularly useful as retention and strength aids in papermaking.Type: GrantFiled: May 23, 1995Date of Patent: March 19, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventors: Karen A. Bernard, John Tsai, Robert L. Billmers, Robert W. Sweger
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Patent number: 5496440Abstract: A process for improved dewatering and retention in the manufacture of paper, where a retention agent containing anionic groups and being based on a polysaccharide or being an acrylamide-based polymer and an alkaline solution of an aluminate are added to the stock containing lignocellulose-containing fibres and optionally fillers. The pH of the stock prior to the addition of the aluminate should be below about 7 to obtain the desired cationic aluminum hydroxide complexes in the stock. The present process is cost effective and insensitive to the content of calcium in the white water.Type: GrantFiled: January 3, 1994Date of Patent: March 5, 1996Assignee: Eka Nobel ABInventors: Bruno Carre/, Ulf Carlson
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Patent number: 5487419Abstract: A process for the production of and a composition of redispersible mechanically disassembled cellulose and the resultant product, referred to as microdenominated cellulose (MDC). The process is characterized by drying the MDC in the presence of a dispersion agent. The product is characterized by a settled volume of greater than 50%, as determined on the basis of a 1% by weight suspension in water after twenty-four hours, and a water retention value of over 350%. MDC is useful as an ingredient in foods, pharmaceutical and cosmetic products.Type: GrantFiled: July 9, 1993Date of Patent: January 30, 1996Assignee: Microcell, Inc.Inventor: Michael K. Weibel
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Patent number: 5487813Abstract: Soft creped tissue paper products comprising papermaking fibers and a biodegradable crepe facilitating composition is disclosed. The crepe facilitating composition is a biodegradable bonding inhibitor, a cationic starch and a carboxymethyl cellulose. Preferably, the biodegradable bonding inhibitor is a biodegradable quaternary ammonium compound. The use of a biodegradable bonding inhibitor, a cationic starch and a carboxymethyl cellulose results in a creped tissue paper that is both strong and soft. A creped paper process comprising the addition of the crepe facilitating composition is also disclosed. The composition offers the potential to improve production capacity.Type: GrantFiled: December 2, 1994Date of Patent: January 30, 1996Assignee: The Procter & Gamble CompanyInventors: Kenneth D. Vinson, Paul T. Weisman, Dean V. Phan
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Patent number: 5482595Abstract: A method of improving the drainage characteristics of a pulp slurry in a papermaking operation utilizing the sequential steps of adding alum, ionic polyacrylamide and cationic starch. The cationic starch can be added to the slurry prior to or after the primary screen.Type: GrantFiled: March 22, 1994Date of Patent: January 9, 1996Assignee: Betz PaperChem, Inc.Inventors: John C. Harrington, IV, Michael A. Schuster
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Patent number: 5474856Abstract: A photographic printing paper support which comprises a raw paper coated with a film-forming resin on both sides; said raw paper being a paper made from paper stock comprising (i) cationic starch, (ii) polyamidepolyamine epichlorohydrin and (iii) an epoxidized higher fatty acid amide and/or an alkylketene dimer, and optionally (iv) a metal salt of carboxymethyl cellulose and/or an acrylamide/diallylamine salt copolymer, and being adjusted to pH 6.5-8.5 and controlled so as to have a zeta potential in the range of -10 mV to +5 mV.Type: GrantFiled: July 27, 1994Date of Patent: December 12, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigehisa Tamagawa, Shinichiro Serizawa, Jun Naitoh
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Patent number: 5474655Abstract: The invention relates to a process for controlling the deposition of stickies from paper stock suspensions in papermaking. According to the invention, the deposition of stickies is controlled by addition of an effective quantity of a degradation product of native starch to the paper stock suspension.Type: GrantFiled: January 17, 1995Date of Patent: December 12, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Heinz-Guenther Schulte, Klaus Hornfeck, Dieter Kaps
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Patent number: 5473059Abstract: Water soluble quaternary ammonium ethers of polysaccharides or polyols wherein the quaternary ammonium ether substituents correspond to the formula ##STR1## wherein R.sub.1 is a monohydroxylated or polyhydroxylated alkyl group containing between about one and about six carbon atoms; R.sub.2 and R.sub.3 are independently, alkyl groups containing between about one and about six carbon atoms; R.sub.4 is an alkyl group containing between about six and about 24 carbon atoms; and X is a halide, wherein the degree of substitution of said ethers ranges from about 0.001 to about 0.5. is provided. The composition have multiple uses as thickeners and are particularly suited for use in personal care products.Type: GrantFiled: October 13, 1994Date of Patent: December 5, 1995Assignee: Rhone-Poulenc Inc.Inventor: Michael H. Yeh
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Patent number: 5470435Abstract: An improved method for the production of water soluble polyaluminosilicate microgels, formed by the reaction of solutions of alkali metal silicates with solutions of acids containing dissolved aluminum compounds, is provided.Type: GrantFiled: November 23, 1994Date of Patent: November 28, 1995Assignee: E. I. du Pont de Nemours and CompanyInventors: John D. Rushmere, Robert H. Moffett
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Patent number: 5464472Abstract: The present invention relates to a fine aqueous dispersion of an organophilic sheet silicate, consisting essentially of a sheet silicate capable of cation exchange and a quaternary organic onium salt reacted therewith, which dispersion comprises from 3 to 30% by weight, based on the organophilic sheet silicate, of a water-soluble, natural polymer and/or a derivative thereof.Type: GrantFiled: June 24, 1994Date of Patent: November 7, 1995Assignee: Hoechst AktiengesellschaftInventors: Ute Horn, Guido Dessauer
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Patent number: 5447604Abstract: Silica sols which have a large alkali excess, i.e. a low molar ratio SiO.sub.2 to M.sub.2 O, and which contain silica particles with a high specific surface area. The silica sols can be prepared through acidification of a water glass solution and subsequent alkalization of the acid sol to the molar ratio in question. The sols are particularly suitable for use as additives, in combination with cationic polymers, in papermaking.Type: GrantFiled: May 8, 1992Date of Patent: September 5, 1995Assignee: Eka Nobel ABInventors: Hans E. Johansson, Bo V. Larsson
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Patent number: 5437766Abstract: Multi-ply facial tissue paper products comprising biodegradable chemical softener compositions and a combination of a wet strength binder, either permanent and/or temporary, and a dry strength binder is disclosed.The multi-ply facial tissue paper products contain a biodegradable chemical softening composition comprising a mixture of a biodegradable quaternary ammonium compound and a polyhydroxy compound. The multi-ply facial tissue paper products also contain an effective amount of a wet strength binder, either permanent and/or temporary, and a dry strength binder to control linting and/or to offset the loss in tensile strength, if any, resulting from the use of the biodegradable chemical softening compositions. The use of both wet strength binder, either permanent and/or temporary, and dry strength binder also improves the retention of the chemical softening composition in the sheet.Type: GrantFiled: October 22, 1993Date of Patent: August 1, 1995Assignee: The Procter & Gamble CompanyInventors: Dean Van Phan, Paul D. Trokhan, Stephen R. Kelly, Ward W. Ostendorf, Bart S. Hersko
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Patent number: 5433826Abstract: The invention relates to an improvement in the art of making saturating kraft paper. In particular, the invention relates to a method for reducing the amount of fuzz generated by the production and use of saturating kraft paper. The improved saturating kraft paper is particularly useful in the production of laminated materials.Type: GrantFiled: November 24, 1993Date of Patent: July 18, 1995Assignee: Westvaco CorporationInventors: John W. Glomb, Yvette A. Tramount
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Patent number: 5415736Abstract: A sheet material, typically paper or cardboard, contains a natural, chemically untreated fibrous material and a secondary long-staple fiber material in a weight ratio comprised between (50-90):(10-50). It further contains fiber fines, at least one retention agent for these fines and at least one sheet strength improving agent. The sheet may be manufactured on paper making machines after preparing a mash from the components listed above and refining. The sheet material is intended to replace paper or cardboard normally made from chemically treated, expensive raw materials.Type: GrantFiled: February 5, 1993Date of Patent: May 16, 1995Inventor: Till Grether
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Patent number: 5411637Abstract: The invention relates to an improvement in the art of making high pressure laminated materials utilizing saturating kraft paper. In particular, the invention relates to a method for making laminated materials which greatly reduces pressure mark defects caused by fuzz balls.Type: GrantFiled: November 24, 1993Date of Patent: May 2, 1995Assignee: Westvaco CorporationInventors: John W. Glomb, Yvette A. Tramount
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Patent number: 5411639Abstract: A papermaking process with improved sizing efficiency and reduced size reversion is characterized by the use of a calcium carbonate pigment which is surface treated with an anionic starch-soap complex. The starch-soap complex is precipitated onto the pigment surfaces to provide bonding sites for sizing agents which impart water repellency to the paper. The sizing agents become bound to the starch component of the starch-soap complex to yield more reacted size in paper webs formed from the furnish than would be present without the use of the treated pigment. The use of the surface treated pigment also allows the papermaker to increase the filler content of the paper without sacrificing dry strength properties.Type: GrantFiled: October 15, 1993Date of Patent: May 2, 1995Assignee: Westvaco CorporationInventor: Frederick L. Kurrle
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Patent number: 5407537Abstract: Size dispersion in paper stock is improved by treatment of cellulose water slurry with cationizing compounds and mixing a sizing product, either neat or in solution, with the water and injecting the mixture in droplet form into said cellulose water slurry before, during or after the paper web formation whether said paper web is dry or not and drying the paper web, an apparatus for carrying out the improved process is included.Type: GrantFiled: May 5, 1994Date of Patent: April 18, 1995Assignee: Exxon Chemical Patents IncInventors: Alberto Malatesta, Christian Pierre, Rene Cohard
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Patent number: 5405501Abstract: Multi-layered tissue paper webs comprising chemical softener compositions and binder materials are disclosed. The multi-layered tissue webs are useful in the manufacture of soft, absorbent paper products such as facial tissues and/or toilet tissues. The multi-layered tissue paper products contain a chemical softening composition comprising a mixture of a quaternary ammonium compound and a polyhydroxy compound. Preferred quaternary ammonium compounds include dialkyl dimethyl ammonium salts such as di(hydrogenated)tallow dimethyl ammonium chloride, di(hydrogenated)tallow dimethyl ammonium methyl sulfate. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, sorbitols, polyglycerols having a weight average molecular weight of from about 150 to about 800, polyoxyethylene glycols and polyoxypropylene glycols having a weight average molecular weight from about 200 to 4000.Type: GrantFiled: June 30, 1993Date of Patent: April 11, 1995Assignee: The Procter & Gamble CompanyInventors: Dean V. Phan, Paul D. Trokhan