Abstract: Methods and compositions that protect cement compositions from corrosion, particularly from wet carbon dioxide, are provided. A soluble salt additive is provided to react with reaction products generated during the reactions that occur when cement is exposed to wet carbon dioxide. The soluble salt reacts to form an insoluble salt that forms a protective layer on the surface of the cement that protects it from further corrosion from exposure to wet carbon dioxide.

Abstract: A method of servicing a wellbore in contact with a subterranean formation comprising placing a wellbore servicing fluid comprising a polyuronide polymer within the wellbore, contacting the wellbore servicing fluid with a divalent ion source, and allowing the wellbore servicing fluid to form a gel within the wellbore wherein the divalent ion source is located within the wellbore. A method of servicing a wellbore in contact with a subterranean formation comprising (a) placing a wellbore servicing fluid comprising a polyuronide polymer into the wellbore wherein the wellbore servicing fluid contacts a calcium ion source, (b) shutting the wellbore and allowing the servicing fluid to set into place for a period of time, and (c) repeating steps (a) and (b) until the permeability of a structure within the wellbore is reduced by about 50%.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment a method a cementing in a subterranean formation comprising: providing a set-delayed cement composition comprising water, pumice, hydrated lime, and a set retarder; foaming the set-delayed cement composition; activating the set-delayed cement composition; introducing the set-delayed cement composition into a subterranean formation; and allowing the set-delayed cement composition to set in the subterranean formation. Additional methods, foamed set-delayed cement composition, and systems for cementing are also provided.

Abstract: Of the many compositions and methods provided herein, one method includes providing a settable fluid that comprises an aqueous-based medium, a lime composition, and a cementitious blend that comprises metakaolin particulates and aluminosilicate particulates, wherein the cementitious blend is essentially free of Portland cement; introducing the settable fluid into a wellbore penetrating a subterranean formation that comprises a corrosive component; and allowing the settable fluid to set therein.

Abstract: Casing assemblies and methods of using the casing assemblies to isolate selected sections of a subterranean wellbore are provided. Also provided are methods of fabricating the casing assemblies. The casing assemblies comprise one or more water-swellable tubular collars disposed around the exterior surface of a conduit, such as a wellbore casing. The water-swellable collars are formed from a material comprising sodium bentonite, a swelling inhibitor and reinforcing fibers.

Abstract: Set-delayed cement compositions and methods of using set-delayed cement compositions in subterranean formations. Embodiments include a method of drilling a wellbore in a subterranean formation comprising: circulating a drilling fluid comprising a set-delayed cement composition in the wellbore while drilling the wellbore, wherein the set-delayed cement composition comprises: pumice, hydrated lime, a set retarder, and water. A method of displacing a fluid in a wellbore comprising: introducing a spacer fluid comprising a set-delayed cement composition into a wellbore such that the spacer fluid displaces one or more prior fluids from the wellbore, and wherein the set-delayed cement composition comprises: pumice, hydrated lime, a set retarder, and water.

Abstract: The present invention relates to the use of a composition for reinforcing cement, which comprises one or more compounds selected from group: a) sodium chloride, potassium chloride, magnesium chloride, calcium chloride, strontium chloride, barium chloride and ammonium chloride; b) aluminum chloride; and comprises one or more compounds selected from c) silica, zeolite, and apatite for cementing a wellbore. Moreover, the present invention relates to a cement slurry for cementing a wellbore, comprising I): cement; II) water; and III) a composition for reinforcing cement. In addition, the present invention relates to a method of cementing a wellbore.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a method of treating a well comprising: providing a treatment fluid comprising a base fluid and a blended cementitious component, wherein the blended cementitious component comprises kiln dust from two or more different sources; and introducing the treatment fluid into a well bore.

Abstract: The present invention includes well treatment fluids and methods utilizing nano-particles. An embodiment of a method of the present invention may comprise introducing a treatment fluid comprising nano-clay into a subterranean formation. The treatment fluid may be selected from the group consisting of a cement composition, a drilling fluid, a spacer fluid, and a lost circulation control composition. Another embodiment of the present invention may comprise a method of cementing. The method of cementing may comprise introducing a cement composition comprising a hydraulic cement, nano-clay, and water into a subterranean formation. The method further may comprise allowing the cement composition to set in the subterranean formation. Yet another embodiment of the present invention may comprise a treatment fluid, the treatment fluid comprising nano-clay. The treatment fluid may be selected from the group consisting of a cement composition, a drilling fluid, a spacer fluid, and a lost circulation control composition.

Abstract: A method of servicing a wellbore comprising preparing a composition comprising a non-aqueous carrier fluid, an oil-wetting surfactant, a water-imbibition enhancing surfactant, and a cementitious material; placing the composition within a detrimentally permeable zone; and contacting the composition with water. A method of servicing a wellbore comprising placing a composition comprising a non-aqueous carrier fluid, an oil-wetting surfactant, a water-imbibition enhancing surfactant, and a cementitious material into the wellbore wherein the wellbore comprises hydrocarbon-producing zones and water-producing zones and wherein the composition enters the water-producing zone and forms a solid mass that obstructs the flow of water in the water-producing zone.

Abstract: A cement composition for cementing an oil or gas well includes Portland cement, water and a sulfur component. The cement composition may be used to cement a well bore by creating a cement slurry including the sulfur component, pumping the slurry into the well bore to a selected location and allowing it to solidify.

Abstract: A thickened composition comprising a polymer, a divalent ions source, water and cement is disclosed. Such composition enables fluid loss reduction and higher gel strength. This may be useful for treating a well for example as a fluid spacer or a scavenger; this may also be used a hydraulic fracturing fluid.

Abstract: The present invention includes well treatment fluids and methods utilizing nano-particles. An embodiment of a method of the present invention may comprise introducing a treatment fluid comprising nano-clay into a subterranean formation. The treatment fluid may be selected from the group consisting of a cement composition, a drilling fluid, a spacer fluid, and a lost circulation control composition. Another embodiment of the present invention may comprise a method of cementing. The method of cementing may comprise introducing a cement composition comprising a hydraulic cement, nano-clay, and water into a subterranean formation. The method further may comprise allowing the cement composition to set in the subterranean formation. Yet another embodiment of the present invention may comprise a treatment fluid, the treatment fluid comprising nano-clay. The treatment fluid may be selected from the group consisting of a cement composition, a drilling fluid, a spacer fluid, and a lost circulation control composition.

Abstract: A composition comprising a carboxylated, sulfonated polysaccharide and a wellbore servicing fluid. A wellbore servicing composition comprising a hydraulic cement and a carboxylated, sulfonated polysaccharide. A wellbore servicing composition comprising a polysaccharide having carboxylate and sulfonate groups.

Abstract: A cement composition for cementing an oil or gas well includes Portland cement, water and a sulfur component. The cement composition may be used to cement a well bore by creating a cement slurry including the sulfur component, pumping the slurry into the well bore to a selected location and allowing it to solidify.

Abstract: A cement composition for use in an oil or gas well, the cement composition comprises: a calcium aluminate cement; water; an organic acid; and a polymeric mixture comprising: (A) water; (B) citric acid; (C) a first polymer, wherein the first polymer: (i) comprises a cellulose backbone and carboxymethyl functional groups; and (ii) has a molecular weight of less than 100,000; and (D) a second polymer, wherein the second polymer: (i) comprises a lignosulfonate; and (ii) has a molecular weight of less than 100,000, wherein a test composition consisting essentially of: the cement; the water; the organic acid; and the polymeric mixture, and in the same proportions as in the cement composition has a thickening time of at least 5 hours at a temperature of 300° F. (148.9° C.) and a pressure of 10,000 psi (68.9 MPa).

Abstract: A method of treating a treatment zone in a well to reduce the permeability of the treatment zone including the steps of: introducing into the treatment zone a water-based treatment fluid comprising: an aqueous silica sol; and a water-soluble chemical activator for gelling the silica sol, wherein the chemical activator is selected from the group consisting of: phytic acid, methylglycinediacetic acid, a water-soluble polyepoxysuccinic acid, salicylic acid, ascorbic acid, tannic acid, and an alkali metal salt or ammonium salt of any of the foregoing; and shutting in treatment zone for at least a sufficient time to allow the treatment fluid to in-situ form a solid gel at a design temperature for the method. Alternatively, a first treatment fluid including the aqueous silica sol and a second treatment fluid including the chemical activator can be introduced into the treatment zone separately, in any order.

Abstract: According to an embodiment, a composition is provided that can be used in a cementing. The composition includes at least: (i) a hydraulic cement; and (ii) a copolymer comprising at least the monomeric units (a) through (d) of the following formula: wherein the monomeric units (a) through (d) can be any sequence and any proportion in the copolymer. With water, the composition of the hydraulic cement and such a copolymer becomes a cement composition. According to the method, the cement composition is introduced into a well and allowed to set in the well.

Abstract: A method of servicing a wellbore comprising introducing to the wellbore a wellbore servicing fluid comprising an additive composition comprising a polysaccharide having carboxylate and sulfonate groups. A method of servicing a wellbore comprising preparing at the well site an additive composition comprising a polysaccharide having carboxylate and sulfonate groups, introducing the additive composition into a wellbore servicing fluid, and placing the wellbore servicing fluid into a subterranean formation. A method of preparing a wellbore servicing fluid comprising contacting a polysaccharide composition with an oxidizing agent to form an oxidized polysaccharide, and contacting the oxidized polysaccharide with a sulfonating agent to form a carboxylated sulfonated polysaccharide, and contacting the carboxylated sulfonated polysaccharide with a wellbore servicing fluid.

Abstract: According to an embodiment, a method of cementing in a subterranean formation comprises: introducing a cement composition into the subterranean formation, wherein the cement composition comprises: cement; water; and calcium silicate hydrate (C-S-H) seeds, wherein a test cement composition consisting essentially of: the cement; the water; and the C-S-H seeds, and in the same proportions as in the cement composition, develops a compressive strength of at least 1,200 psi (8.3 MPa) when tested at 24 hours, a temperature of 60° F. (15.6° C.), and a pressure of 3,000 psi (20.7 MPa); and allowing the cement composition to set. According to another embodiment, the C-S-H seeds are mesoscopic particles, nanoparticles, or combinations thereof, and wherein the C-S-H seeds are in a concentration in the range of about 1% to about 5% by weight of the cement.

Abstract: A self-adaptive cement system includes cement, water and at least one additive that reacts or/and expands in contact with oil and gas. Several chemical products have been identified including rubber alkylstyrene, polynorbornene, resins such precrosslinked substituted vinyl acrylate copolymers and diatomaceous earth. These additives have the effect of making the cement self-healing in the event of physical failure or damage such as micro-annuli. The self healing property is produced by the contact with subterranean hydrocarbon fluids, the potential repair mechanism is thus activated if and when needed in case of start of loss of zonal isolation. In another embodiment, the expansion is deliberately induced by pumping a hydrocarbon fluid in the vicinity of the set cement.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a method of cementing in a subterranean formation comprising: introducing a cement composition comprising cement, water, and a lignite-based copolymer into a subterranean formation, wherein the lignite-based copolymer comprises a lignite backbone, a first grafted monomer selected from the group consisting of -acrylamido-2-methylpropanesulfonic acid, a salt of 2-acrylamido-2-methylpropanesulfonic acid, and a second grafted monomer comprising N,N-dimethylacrylamide; and allowing the cement composition to set in the subterranean formation, wherein cement composition has a transition time of less than or equal to about 150 minutes.

Abstract: A method of servicing a wellbore in a subterranean formation comprising preparing a wellbore servicing fluid comprising cement, water and a polyuronide polymer, placing the wellbore servicing fluid in the wellbore, and allowing the wellbore servicing fluid to set. A method of servicing a wellbore in a subterranean formation comprising preparing a wellbore servicing fluid comprising a highly methylated pectin, cementitious material and water into the wellbore, placing the wellbore servicing fluid in the wellbore, and allowing the wellbore servicing fluid to set. A wellbore servicing fluid comprising cement, water and a polyuronide polymer.

Abstract: The invention concerns the use of a fluid loss control additive in a pumpable geopolymeric suspension for oil and/or gas industry applications, said suspension further comprising an aluminosilicate source, a carrier fluid, and an activator, and method of providing such a suspension in a borehole. In particular, the suspension according to the invention is used for well primary cementing operations and/or remedial applications.

Abstract: Cement compositions comprising polymeric particles with inorganic fillers have utilities in the context of well cementing. The fillers improve bonding between the polymeric particles and the cement matrix leading to improved mechanical parameters of the cement system. The filled particles may also lead to improved mixability and slurries that are easier to optimise.

Abstract: Disclosed are spacer fluids comprising cement kiln dust (“CKD”) and methods of use in subterranean formations.

Abstract: Single-phase microemulsions, comprising a solvent, a surfactant blend and a carrier fluid, are effective spacer fluids for use during cementing operations. The solvent may be selected from the group consisting of monoterpenes, diterpenes, and alkyl or aryl esters of short-chain alcohols. The surfactant blend comprises a water-wetting surfactant or nonionic surfactant, a co-surfactant and an oil-solubilizing surfactant. The carrier fluid is aqueous. The solvent and surfactant blend are combined with the carrier fluid to produce the well-treatment microemulsion.

Abstract: A method of servicing a wellbore comprising introducing to the wellbore a wellbore servicing fluid comprising an additive composition comprising a polysaccharide having carboxylate and sulfonate groups. A method of servicing a wellbore comprising preparing at the well site an additive composition comprising a polysaccharide having carboxylate and sulfonate groups, introducing the additive composition into a wellbore servicing fluid, and placing the wellbore servicing fluid into a subterranean formation. A method of preparing a wellbore servicing fluid comprising contacting a polysaccharide composition with an oxidizing agent to form an oxidized polysaccharide, and contacting the oxidized polysaccharide with a sulfonating agent to form a carboxylated sulfonated polysaccharide, and contacting the carboxylated sulfonated polysaccharide with a wellbore servicing fluid.

Abstract: Disclosed are spacer fluids comprising cement kiln dust (“CKD”) and methods of use in subterranean formations. An embodiment discloses a method comprising: providing a foamed spacer fluid comprising CKD, a foaming agent, a gas, and water; and introducing the foamed spacer fluid into a well bore to displace at least a portion of a first fluid present in the well bore. Another embodiment discloses a method comprising: providing a foamed spacer fluid comprising a partially calcined kiln feed removed from a gas stream, a foaming agent, a gas, and water, wherein the partially calcined kiln feed comprises SiO2, Al2O3, Fe2O3, CaO, MgO, SO3, Na2O, and K2O; and introducing the foamed spacer fluid into a well bore to displace at least a portion of a first fluid present in the well bore.

Abstract: Disclosed are spacer fluids and methods of use in subterranean formations. Embodiments may include use of consolidating spacer fluids in displacement of drilling fluids from a well bore annulus.

Abstract: Methods and compositions are provided that relate to cementing operations. Methods and compositions that include a latex strength enhancer for enhancing the compressive strength of slag compositions.

Abstract: A well treatment composition comprises: an aqueous liquid; a fluid loss additive, wherein the fluid loss additive comprises a high molecular weight, water-swellable polymer; and an amphiphilic dispersant, wherein the well treatment composition has an activity of at least 10%. A method of cementing in a subterranean formation comprises: introducing a cement composition into the subterranean formation, the cement composition comprising: (i) cement; (ii) water; and (iii) the well treatment composition; and allowing the cement composition to set.

Abstract: A method of consolidating a fracture in a formation comprises injecting a solution of an alkali metal silicate into the formation causing the solution to react with the surfaces of the calcium containing inorganic compound deposits, locking the fine material on these surfaces in place and preventing fines generation during production in a well.

Abstract: A cement composition for use in a wellbore comprising a cement blend and at least two polyvinylalcohols wherein the polyvinylalcohols have different degrees of hydrolysis such that the rheology of the cement slurry capable of being formed from the composition is stable during temperatures changes.

Abstract: A self-healing cement system includes cement, water and at least one additive that swells in contact with water from reservoir or from formation in the case of a structural failure in the set cement to provide a physical barrier in the zone of failure. Examples of such material include particles of super-absorbent polymer. These additives have the effect of making the cement self-healing in the event of physical failure or damage such as micro-annuli. The self healing property is produced by the contact of the water itself, the potential repair mechanism is thus activated if and when needed in case of start of loss of zonal isolation. Several super-absorbent polymers have been identified such as polyacrylamide, modified crosslinked poly(meth)acrylate and non-soluble acrylic polymers.

Abstract: A lightweight composite having an activated surface contains a lightweight hollow core particle having cement grains which may be adhered to the hollow core or embedded in the surface of the hollow core. The hollow core particle may be prepared from calcium carbonate and a mixture of clay, such as bentonite, and a glassy inorganic material, such as glass spheres, glass beads, glass bubbles, borosilicate glass and fiberglass.

Abstract: An embodiment of the present invention comprises a method of treating a subterranean formation comprising: providing a treatment fluid comprising a kiln dust, biowaste ash, and water; and introducing the treatment fluid into a subterranean formation. Another embodiment of the present invention comprises a method of cementing comprising: introducing a cement composition into a subterranean formation, wherein the cement composition comprises a kiln dust, biowaste ash, and water; and allowing the cement composition to set in the subterranean formation. Yet another embodiment of the present invention comprises a method comprising: providing a spacer fluid comprising biowaste ash and water; introducing the spacer fluid into a well bore to displace at least a portion of a first fluid from the well bore; and introducing a cement composition into the well bore, wherein the spacer fluid separates the cement composition and the first fluid.

Abstract: Methods of isolating a portion of a wellbore comprising placing a sealant composition into a subterranean formation after drilling of the wellbore therein and subjecting the sealant composition to ionizing radiation wherein subjecting the sealant composition to the ionizing radiation alters the set modifier. The sealant composition comprises a set modifier selected from the group consisting of an accelerator, an oxidizing agent, a set retarder, and combinations thereof. And the sealant composition comprises a polymeric component.

Abstract: Methods are provided that include a method comprising providing a consolidating agent emulsion composition comprising an aqueous fluid, an emulsifying agent, and a consolidating agent; and introducing the consolidating agent emulsion composition into at least a portion of a subterranean formation. In some embodiments, the consolidating agent emulsion composition may be introduced into at least a portion of a propped fracture that comprises proppant particulates and allowed to at least partially consolidate at least a portion of the propped fracture. In some embodiments, the consolidating agent emulsion composition comprises a resin composition. Additional methods are also provided.

Abstract: A method of treating a subterranean formation including providing a treatment fluid comprising an aqueous carrier fluid, a crosslinking agent, a pH-adjusting agent, and a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof, where the treatment fluid does not include any gel stabilizers, or only minimal amounts of gel stabilizers. The treatment fluid is introduced into a subterranean formation and is allowed to form a gel in the subterranean formation. The gel is broken, without using an external breaker, after the gel has been in the subterranean formation for at least about one day.

Abstract: An embodiment of the present invention comprises a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising unexpanded perlite, cement kiln dust, and water; and allowing the settable composition to set. Another embodiment of the present invention comprises a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising ground unexpanded perlite, Portland cement interground with pumicite, and water; and allowing the settable composition to set. Yet another embodiment of the present invention comprises a settable composition comprising: ground unexpanded perlite; cement kiln dust; and water.

Abstract: Cement compositions comprising carboxylated inulin and methods of using the same to cement a workspace. In one embodiment, a method of cementing includes providing a cement composition comprising a carboxylated inulin, for example, in a subterranean formation. The method further includes allowing the cement composition to set. In some embodiments, the cement composition has a thickening time of from about 2 hours to about 11 hours. In other embodiments, the cement composition has a viscosity that is about constant for a period of time after the cement composition is placed.

Abstract: Compositions containing an alkali swelling polymer and a pH buffer with a pH between 3 and 7 may be used to treat a wellbore. The pH buffer prevents the swelling of the alkali swellable polymer. The compositions may be placed in the wellbore, whereupon they contact another material with pH increasing properties. The pH of the compositions increases, causing the compositions to swell and form a seal. The alkali swelling polymer may be an alkali swelling latex.

Abstract: A method includes providing a cementing composition that includes an aqueous fluid, a cementitious particulate, and a copolymer particulate which includes a monofunctional monomer, a water degradable first crosslinker, and a second crosslinker. The method further includes placing the cementing composition in a subterranean formation so as to form a set cement sheath and swelling the copolymer particulate in response to a void created in the set cement sheath. The copolymer particulate allows the cementing composition to set to form the cement sheath before substantial swelling of the copolymer particulate occurs.

Abstract: A method of selectively blocking fractures in a subterranean formation by injecting a diversion agent into the well is disclosed. According to one embodiment, the method comprises injecting a diversion agent into a subterranean formation to form an alkaline-earth carbonate precipitate from decomposition of a carbonyl compound, wherein the diversion agent includes the carbonyl compound and an alkaline-earth halide salt.

Abstract: Methods for providing controlled delivery of subterranean fluid additives to a well bore treatment fluid and/or a surrounding subterranean environment using intelligent materials that respond to a magnetic stimulus to release subterranean fluid additives downhole in a subterranean environment. The methods include releasing a subterranean fluid additive in a subterranean formation including providing a magnetically-sensitive component that includes a subterranean fluid additive; providing a magnetic source; and releasing the subterranean fluid additive in the subterranean formation from the magnetically-sensitive component using a magnetic force generated from the magnetic source.

Abstract: Cement compositions and methods of their use in subterranean applications include the use of a self-degrading cement composition for use in fluid loss applications. A method includes placing a self-degrading cement composition in at least one fracture of a subterranean formation, the self-degrading cement including a cement composition including an acid-base cement, a particulate filler, and a solid acid precursor. The method includes allowing the self-degrading cement to set in the fracture.

Abstract: An embodiment of the present invention comprises a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising unexpanded perlite, cement kiln dust, and water; and allowing the settable composition to set. Another embodiment of the present invention comprises a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising ground unexpanded perlite, Portland cement interground with pumicite, and water; and allowing the settable composition to set. Yet another embodiment of the present invention comprises a settable composition comprising: ground unexpanded perlite; cement kiln dust; and water.

Abstract: Embodiments disclose method and compositions that comprise cement kiln dust and rice husk ash. An embodiment comprises a method of cementing comprising: placing a settable composition into a subterranean formation, the settable composition comprising cement kiln dust, rice husk ash, and water; and allowing the settable composition to set. Another embodiment discloses a settable composition comprising cement kiln dust, rice husk ash, and water.

Abstract: A system and method for extending a slotted liner shoe is disclosed. According to one embodiment, a low density material is injected into a liner having a plurality of openings. The liner is suspended below a cemented casing in a wellbore of a well in a subterranean formation. The low density material extrudes through a lower portion of the liner into an annulus between the liner and the wellbore. A cement is circulated into the liner above the low density material. The cement extrudes through an upper portion of the liner into the annulus between the liner and the wellbore Water is displaced from the wellbore, and a solid cemented casing string is formed at a desired depth.