Using Specific Materials Patents (Class 166/292)
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Patent number: 11634967Abstract: Methods for more reliably cementing and remediating oil and gas wells by plastically expanding the diameter of the wellbore casing at select locations along the wellbore to control fluid flow in the micro-annular leak paths formed in the casing annulus between the casing and cement sheath, or between the casing and wellbore. Such methods do not require pre-placement of casing packers or prediction of potential leak points of the casing annulus. In cementing operations, casing expansion can be performed at strategic locations along the wellbore to eliminate annular leak paths that permit detrimental flow, direct the flow of cement to the desired portions of the wellbore, and prevent the flow of cement to oil producing formations. In instances of inter-zonal communication between subterranean formations, casing expansion can be performed at location(s) between the formations to mitigate or prevent inter-zonal communication via annular leak paths in the casing annulus.Type: GrantFiled: May 31, 2021Date of Patent: April 25, 2023Assignee: WINTERHAWK WELL ABANDONMENT LTD.Inventor: Dale Kunz
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Patent number: 11572761Abstract: A method for zonal isolation in a subterranean formation includes identifying a zone of interest within the subterranean formation, determining a static temperature of the zone of interest, determining a time duration for gelation of a treatment fluid, determining a concentration of an accelerator in the treatment fluid, determining a volume of the treatment fluid to be delivered to the zone of interest, determining a correlation between cooling of a wellbore near the zone of interest and a delivery rate of the treatment fluid, determining a target wellbore temperature, delivering a cooling stage until the target wellbore temperature is reached, and delivering a treatment stage. Delivering the cooling stage and the treatment stage results in forming, within the zone of interest, a gel that is impermeable to fluid flow.Type: GrantFiled: December 14, 2021Date of Patent: February 7, 2023Assignee: Saudi Arabian Oil CompanyInventors: Mohamed Hassan Sherief, Ayman Mohammed Almohsin, Haider Jaffer Abdulal, Mohammed I. Alabdrabalnabi
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Patent number: 11499085Abstract: A method of controlling lost circulation includes introducing into a wellbore a lost circulation fluid comprising: an external oil phase, an internal aqueous phase, an emulsifier, a wetting agent, a magnesia sealant, and a; retarder; contacting the lost circulation fluid with a lost circulation zone; and forming a plug adjacent the lost circulation zone by reacting the magnesia sealant with water at a wellbore temperature, thereby reducing fluid loss into the lost circulation zone.Type: GrantFiled: November 29, 2021Date of Patent: November 15, 2022Assignee: BAKER HUGHES OILFIELD OPERATIONS LLCInventors: Shiv Shankar Sangaru, Pranjal Sarmah
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Patent number: 11499086Abstract: A method for strengthening a subterranean formation is disclosed herein. A method of strengthening a subterranean formation includes: introducing a first fluid into the subterranean formation, wherein the first fluid includes polyvalent cations; and introducing a second fluid into the subterranean formation, wherein the second fluid includes a dissolved silicate in an aqueous-base fluid; wherein the dissolved silicate reacts with the polyvalent cations in the subterranean formation to form a reaction product including precipitated silicate in the subterranean formation.Type: GrantFiled: December 20, 2021Date of Patent: November 15, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Dale E. Jamison, Brian Alan Evans, William Walter Shumway, Denise Nicole Benoit
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Patent number: 11466535Abstract: A casing segment comprising a cylinder, a downhole tool, a first channel in the cylinder, a degradable plug wherein the plug degrades when exposed to a degrading fluid, said degrading fluid concurrently not degrading to the cylinder or the downhole tool, and a fluid reservoir that stores the degrading fluid, wherein the fluid reservoir is in fluid communication with the plug. A method comprising obtaining a casing segment having a cylinder, a downhole tool, and a fluid reservoir with degrading fluid, said degrading fluid concurrently not degrading to the cylinder or the downhole tool, wherein the cylinder includes a first channel, installing a degradable plug within the first channel, deploying the casing segment downhole, and exposing the degradable plug to the degrading fluid to cause the downhole tool to be in fluid communication with the interior surface of the cylinder.Type: GrantFiled: December 18, 2014Date of Patent: October 11, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Zac Suresh Arackakudiyil, Gregory Scott Cunningham
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Patent number: 11459849Abstract: A sealing method for a drilled hole in three zones of overburden comprises: blocking the fissure zone and the caving zone with at least one filling bag; and transporting prepared cement slurry to the drilled hole through a hollow drill pipe, so as to block the curved subsidence zone. The three zones of overburden comprise a fissure zone, a caving zone and a curved subsidence zone.Type: GrantFiled: April 26, 2022Date of Patent: October 4, 2022Assignees: CHINA UNIVERSITY OF MINING AND TECHNOLOGY, BEIJING, Shaanxi Coal Caojiatan Mining Co., Ltd.Inventors: Yifan Zeng, Qiang Wu, Zhaolai Hua, Rui Wang, Zhenzhong Pang, Lu Wang, Yang Lv, Xin Du, Kai Pang, Aoshuang Mei
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Patent number: 11454082Abstract: An exemplary dissolvable assembly is provided. The dissolvable assembly includes a skeleton made from a first material, and a body made from a second material, wherein the first material and the second material dissolve at different rates.Type: GrantFiled: August 25, 2020Date of Patent: September 27, 2022Assignee: Saudi Arabian Oil CompanyInventors: Sakethraman Mahalingam, Graham Hitchcock, Daniele Colombo, Jianhui Xu
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Patent number: 11447685Abstract: Compositions and methods for inhibiting dissolution of carbonates in a subterranean formation are provided. In some embodiments, the methods comprise: providing a treatment fluid that comprises a base fluid and a carbonate dissolution inhibiting additive; contacting a portion of a carbonate-bearing subterranean formation with the treatment fluid; and allowing the carbonate dissolution inhibiting additive to chemically interact with the portion of the carbonate-bearing subterranean formation to inhibit dissolution of one or more carbonate minerals in the formation, whereby the susceptibility of at least a portion of the carbonate-bearing subterranean formation to fluid-induced damage is decreased.Type: GrantFiled: August 28, 2019Date of Patent: September 20, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Mallikarjuna Shroff Rama, Denise Nicole Benoit, Sumit Shivshankar Konale, Kristina Henkel Holan, Enrique Reyes
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Patent number: 11414513Abstract: A method for producing a nanocomposite sorbent comprising carbon nanotube-grafted acrylic acid/acrylamide copolymer which involves copolymerization of acrylic acid and acrylamide in the presence of an aqueous dispersion of carbon nanotubes. The method yields a nanocomposite sorbent material having a reversible adsorption capacity phenol of 5 to 2500 ?g of phenol per mg of nanocomposite sorbent. Also disclosed is a method for removing organic pollutants from water using the nanocomposite sorbent.Type: GrantFiled: October 18, 2019Date of Patent: August 16, 2022Assignee: Imam Abdulrahman Bin Faisal UniversityInventor: Asma Mohammed Zamil Elsharif
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Patent number: 11365612Abstract: A hydrocarbon wellbore production apparatus includes a tailpipe and a control valve connected with the tailpipe. The tailpipe has a fluid inlet receiving well fluids entering the casing from a formation, and a fluid outlet above the fluid inlet to deliver well liquid to a connected pump inlet. The control valve is operable to (i) open when a lower fluid pressure below the flow control valve exceeds an upper fluid pressure above the flow control valve to allow upward flow through the flow control valve, (ii) close when the upper fluid pressure exceeds the lower fluid pressure by an amount which does not exceed a prescribed pressure limit value to hold fluid in the apparatus above the flow control valve, and (iii) open when the upper fluid pressure exceeds the lower fluid pressure by an amount which exceeds the pressure limit value to release excess fluid back down the tailpipe.Type: GrantFiled: March 27, 2020Date of Patent: June 21, 2022Inventor: Brian Ellithorp
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Patent number: 11352546Abstract: A lost circulation material (LCM) is provided having an alkaline nanosilica dispersion and an ester activator. The alkaline nanosilica dispersion and the ester activator may form a gelled solid after interaction over a contact period. Methods of lost circulation control using the LCM are also provided.Type: GrantFiled: August 20, 2020Date of Patent: June 7, 2022Assignee: Saudi Arabian Oil CompanyInventors: Vikrant Wagle, Rajendra Kalgaonkar, Abdullah Al-Yami, Zainab Alsaihati
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Patent number: 11339626Abstract: A method for mitigating a fluid flow from a target wellbore using a relief wellbore includes receiving wellbore geometry information of the target wellbore, receiving an initial interception point of the target wellbore, simulating a change in a three-dimensional flow characteristic of a kill fluid flow from a simulated relief wellbore and a target fluid flow from a simulated target wellbore resulting from an interaction between the kill fluid flow and the target fluid flow at the initial interception point, the simulated target wellbore designed using the received wellbore geometry information, and determining a final interception point of the target wellbore based on the simulation.Type: GrantFiled: July 13, 2018Date of Patent: May 24, 2022Assignee: BP Corporation North America Inc.Inventors: Madhusuden Agrawal, Paulo Jorge Da Cunha Gomes, James H. Knight, Satpreet Nanda, Lei Zhou, Eugene Sweeney
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Patent number: 11313199Abstract: Examples of the present disclosure relate to a temporary seal within a wellbore. More specifically, embodiments include a temporary seal within casing that limits the flow of fluid through the casing until the temporary seal is released.Type: GrantFiled: September 7, 2020Date of Patent: April 26, 2022Assignee: VERTICE OIL TOOLS INC.Inventor: Mohamed Ibrahim Saraya
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Patent number: 11306574Abstract: Compositions of nanoparticle-based stimulation fluids and methods of use for acid diversion from high permeability zones into low permeability zones to achieve deep penetration of wormholes in subterranean formations, such as carbonate formations. Certain embodiments include a gel precursor composition comprising metal oxide nanoparticles, such as silicon dioxide nanoparticles as a gelling agent, and magnesium chloride.Type: GrantFiled: November 8, 2019Date of Patent: April 19, 2022Assignee: The Board of Regents of the University of OklahomaInventors: Sangho Bang, Bor Jier Shiau, Jeffrey H. Harwell, Elsayed R. Abdelfatah, Maysam Pournik
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Patent number: 11299662Abstract: Provided is a lost circulation material that may consist essentially of an alkaline nanosilica dispersion and a sodium bicarbonate activator. Further provided are methods that may control lost circulation in a lost circulation zone in a wellbore by introducing the lost circulation material such that it contacts the lost circulation zone and forms a gelled solid in the lost circulation zone.Type: GrantFiled: July 7, 2020Date of Patent: April 12, 2022Assignee: SAUDI ARABIAN OIL COMPANYInventors: Vikrant Wagle, Rajendra Arunkumar Kalgaonkar, Abdullah Al-Yami, Sara Alkhalaf
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Patent number: 11293252Abstract: Systems, methods, and apparatuses of the present disclosure generally relate to dissolvable plugs for separating fluids in a wellbore. A dissolvable plug includes a first end comprising a first fluid barrier. The first fluid barrier includes a polymer film. The dissolvable plug also includes a second end opposite to the first end. The second end comprises a second fluid barrier. The second fluid barrier comprises a polymer film. The dissolvable plug includes a solid structure made of a sand and salt mixture.Type: GrantFiled: April 16, 2020Date of Patent: April 5, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Samuel Jason Lewis, Paul Joseph Jones, Lonnie Carl Helms
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Patent number: 11293262Abstract: The present invention relates to a well tool device (1) comprising a housing (10) having an axial through bore (11). A sleeve section (20) is releasably connected to the housing (10) in the through bore (11). The sleeve section (20) comprises an axial bore (21) and a frangible disc (30) provided in the bore (21) of the sleeve section (20) in sealing engagement with the sleeve section (20). The sleeve section (20) is axially displaceable within the bore (11) between a first position (P1) and a second position (P2). The housing (10) comprises an axial bypass fluid passage (12) provided axially between a first location (L1) above the sleeve section (20) to a second location (L2) below the sleeve section (20) when the sleeve section (20) is in the first position (P1). The axial bypass fluid passage (12) is provided radially between the sleeve section (20) and the housing (10) when the sleeve section (20) is in the first position (P1).Type: GrantFiled: June 13, 2018Date of Patent: April 5, 2022Assignee: Interwell Norway ASInventors: Espen Hiorth, Stig Ove Bjørgum
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Patent number: 11255155Abstract: A downhole tool includes a casing string with a fluid barrier connected therein defining a lower end of a buoyancy chamber. A plug assembly connected in the casing string defines an upper end of the buoyancy chamber. The plug assembly has an outer case with a rupture disc positioned therein configured to block flow and to burst at a predetermined pressure. The rupture disk is removable from a flow path through the outer case upon the flow of fluid therethrough.Type: GrantFiled: May 9, 2019Date of Patent: February 22, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Min Mark Yuan, Frank Vinicio Acosta, Lonnie Helms, Rajesh Parameshwaraiah
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Patent number: 11219888Abstract: Provided is a method for preparing a solution B comprising at least one catalyst in at least one second solvent, comprising at least the following steps of (A) providing a solution A comprising the at least one catalyst in at least one first solvent, (B) treating the solution A from step (A) with activated carbon, (C) removing the activated carbon from the solution A, and (D) exchanging the at least one first solvent in solution A for at least one second solvent in order to obtain the solution B comprising the at least one catalyst in at least one second solvent, to a solution of at least one catalyst in at least one second solvent, obtainable by the method according to the invention, to the use of this solution for preparing a composition comprising the at least one catalyst, the at least one second solvent, at least one polyisocyanate and at least one NCO-reactive compound, to the use of this composition for producing a single-layered or multi-layered coating system and a corresponding process.Type: GrantFiled: July 24, 2020Date of Patent: January 11, 2022Assignee: Covestro Intellectual Property GmbH & Co. KGInventors: Michael Traving, Holger Rosellen, Salvatore Manzelli, Cosimo Calandrelli, Stephan Reimer, Frank Richter, Joerg Kolle
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Patent number: 11214725Abstract: A well treatment fluid comprising an aqueous base fluid and a sugar-based surfactant is provided. The sugar-based surfactant includes at least one betaine functionalized alkyl polyglucoside. Also provided is a method of treating an oil and gas well.Type: GrantFiled: August 28, 2020Date of Patent: January 4, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Sairam Eluru, Chetan Prakash, Shreya Mohan
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Patent number: 11186759Abstract: A lost-circulation material including a mixture of an aqueous colloidal dispersion and fatty acid. The aqueous colloidal dispersion includes silica nanoparticles and has a pH of at least 8. Combining the colloidal dispersion and the fatty acid initiates gelation of the lost-circulation material when the pH of the lost-circulation material is less than 8 and a temperature of the lost-circulation material is in a range of 5° C. to 300° C. Sealing an opening in a portion of a wellbore or a portion of a subterranean formation in which the wellbore is formed may include providing the aqueous colloidal dispersion and the fatty acid to the wellbore, mixing the colloidal dispersion and the fatty acid to yield the lost-circulation material, initiating gelation of the lost-circulation material, and solidifying the lost-circulation material in the wellbore to yield a set gel.Type: GrantFiled: July 23, 2019Date of Patent: November 30, 2021Assignee: Saudi Arabian Oil CompanyInventors: Rajendra Arunkumar Kalgaonkar, Vikrant Bhavanishankar Wagle, Abdullah Saleh Hussain Al-Yami, Ayman Mohammed Almohsin
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Patent number: 11180958Abstract: A rupture disc assembly and a float tool incorporating the rupture disc assembly is disclosed. The rupture disc assembly may include a rupture disc assembly comprising a rupture disc, an upper tubular portion and a lower tubular portion, and a securing mechanism for holding the rupture disc between the upper and lower tubular portions. A float tool for creating a buoyant chamber in a casing string may include the rupture disc assembly and a sealing device for sealing the lower end of the casing string, the buoyant, sealed chamber may be created there between. In operation, applied fluid pressure causes the rupture disc to move downward. The rupture disc may be shattered by contact with a surface on the lower tubular portion. Full casing internal diameter may be restored in the region where the rupture disc formerly sealed the casing.Type: GrantFiled: March 19, 2020Date of Patent: November 23, 2021Assignee: NCS MULTISTAGE INC.Inventors: Donald Getzlaf, Marty Stromquist, John Ravensbergen, David Devlin, Douglas Braden, Travis Harris
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Patent number: 11168243Abstract: A cement composition is disclosed that includes a cement slurry and an epoxy resin system that includes at least one epoxy resin and a curing agent. The cement slurry has a density in a range of from 65 pcf to 180 pcf and includes a cement precursor material, silica sand, silica flour, a weighting agent, and manganese tetraoxide. The epoxy resin system includes at least one of 2,3-epoxypropyl o-tolyl ether, alkyl glycidyl ethers having from 12 to 14 carbon atoms, bisphenol-A-epichlorohydrin epoxy resin, or a compound having formula (I): (OC2H3)—CH2—O—R1—O—CH2—(C2H3O) where R1 is a linear or branched hydrocarbyl having from 4 to 24 carbon atoms; and a curing agent.Type: GrantFiled: August 30, 2018Date of Patent: November 9, 2021Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Al-Yami, Vikrant Wagle, Zainab Alsaihati, Tushar Mukherjee, Ali BinAli, Ali Alqahtani
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Patent number: 11158434Abstract: A hazardous material repository includes a drillhole formed from a terranean surface into a subterranean zone that includes a geologic formation, where the drillhole includes a vertical portion and a non-vertical portion coupled to the vertical portion by a transition portion, the non-vertical portion includes a storage volume for hazardous waste; a casing installed between the geologic formation and the drillhole, the casing including one or more metallic tubular sections; at least one canister positioned in the storage volume of the non-vertical portion of the drillhole, the at least one canister sized to enclose a portion of hazardous material and including an outer housing formed from a non-corrosive metallic material; and a backfill material inserted into the non-vertical portion of the drillhole to fill at least a portion of the storage volume between the at least one canister and the casing.Type: GrantFiled: December 18, 2019Date of Patent: October 26, 2021Assignee: Deep Isolation, Inc.Inventors: Joe H. Payer, Stefan Finsterle, John Apps, Richard A. Muller
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Patent number: 11149190Abstract: Treatment fluids for acid diversion during acid stimulation of a subterranean formation may include at least an acidizing fluid, a nanoparticle dispersion, and an activator. The treatment fluid may include from 40 weight percent to 70 weight percent acidizing fluid based on the total weight of the treatment fluid. The treatment fluid may include from 20 weight percent to 40 weight percent nanoparticle dispersion based on the total weight of the treatment fluid. The treatment fluid may include from 5 weight percent to 15 percent activator based on the total weight of the treatment fluid. Methods of treating a subterranean formation with the treatment fluids are also disclosed.Type: GrantFiled: August 29, 2019Date of Patent: October 19, 2021Assignee: Saudi Arabian Oil CompanyInventors: Rajendra Arunkumar Kalgaonkar, Qasim Sahu
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Patent number: 11142679Abstract: Methods and systems of reducing lost circulation in a wellbore are provided. An example method includes providing a pozzolan slurry comprising a pozzolanic material and water; and providing a calcium slurry comprising a calcium source, a high pH activator, and water. The method further comprises allowing the pozzolan slurry and the calcium slurry to remain separate; wherein at least one of the pozzolan slurry and the calcium slurry comprise a thixotropic material; wherein at least one of the pozzolan slurry and the calcium slurry comprise a dispersant; wherein at least one of the pozzolan slurry and the calcium slurry comprise a weighting agent. The method additionally comprises mixing the pozzolan slurry and the calcium slurry to form a two-part thixotropic lost circulation slurry after the allowing the pozzolan slurry and the calcium slurry to remain separate.Type: GrantFiled: March 29, 2018Date of Patent: October 12, 2021Assignee: Halliburton Energy Services, Inc.Inventors: Thomas J. Pisklak, Samuel J. Lewis, Paul J. Jones
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Patent number: 11104839Abstract: Embodiments provide methods and compositions for mitigating water production for hydrocarbon recovery. According to an embodiment, the method involves a treatment fluid composition. The treatment fluid composition includes a base liquid, a gelling agent, and a crosslinking agent. The treatment fluid composition is introduced downhole where it is positioned in a high permeability streak adjacent to a wellbore. After crosslinking, the treatment fluid composition blocks water in the high permeability streak from penetrating into the wellbore.Type: GrantFiled: January 13, 2020Date of Patent: August 31, 2021Assignee: SAUDI ARABIAN OIL COMPANYInventors: Leiming Li, Rajesh Kumar Saini, Feng Liang
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Patent number: 11098235Abstract: A method of converting a drilling fluid into a geopolymer cement slurry includes introducing the drilling fluid into a wellbore, in which the drilling fluid comprises Na2SiO3, NaCl, or both. The method further includes introducing Saudi Arabian volcanic ash into the wellbore. The Saudi Arabian volcanic ash comprises SO3, CaO, SiO2, Al2O3, Fe2O3, MgO, and K2O. The method further includes allowing the Saudi Arabian volcanic ash to contact the drilling fluid in the wellbore, thereby converting the drilling fluid into the geopolymer cement slurry. A method of cementing a casing in a wellbore includes introducing a drilling fluid into a wellbore, in which the drilling fluid comprises Na2SiO3, NaCl, or both, and introducing Saudi Arabian volcanic ash into the wellbore to form the geopolymer cement slurry. The method further includes curing the geopolymer cement slurry to cement the casing in the wellbore.Type: GrantFiled: March 18, 2020Date of Patent: August 24, 2021Assignee: Saudi Arabian Oil CompanyInventors: Khawlah A. Alanqari, Abdullah S. Al-Yami
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Patent number: 11078400Abstract: Disclosed herein are methods, compositions, and systems for cementing. A method of cementing may comprise: providing a composite cement composition comprising a pozzolan, an accelerator, and water, wherein the accelerator comprises a chloride salt and a sulfate salt, wherein the composite cement composition is free of Portland cement or comprises Portland cement in an amount of about 50% by weight of cementitious components or less; and allowing the composite cement composition to set.Type: GrantFiled: February 22, 2017Date of Patent: August 3, 2021Assignee: Halliburton Energy Services, Inc.Inventors: Thomas Jason Pisklak, Sean William Riggio, Ronnie Glen Morgan, Thomas Singh Sodhi, Simone E A Lumsden, Samuel J. Lewis
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Patent number: 11053426Abstract: A lost-circulation material including a mixture of an aqueous colloidal dispersion and fatty acid. The aqueous colloidal dispersion includes silica nanoparticles and has a pH of at least 8. Combining the colloidal dispersion and the fatty acid initiates gelation of the lost-circulation material when the pH of the lost-circulation material is less than 8 and a temperature of the lost-circulation material is in a range of 5° C. to 300° C. Sealing an opening in a portion of a wellbore or a portion of a subterranean formation in which the wellbore is formed may include providing the aqueous colloidal dispersion and the fatty acid to the wellbore, mixing the colloidal dispersion and the fatty acid to yield the lost-circulation material, initiating gelation of the lost-circulation material, and solidifying the lost-circulation material in the wellbore to yield a set gel.Type: GrantFiled: June 24, 2019Date of Patent: July 6, 2021Assignee: Saudi Arabian Oil CompanyInventors: Rajendra Arunkumar Kalgaonkar, Vikrant Bhavanishankar Wagle, Abdullah Saleh Hussain Al-Yami, Ayman Mohammed Almohsin
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Patent number: 11053428Abstract: A method for plugging and sealing subsurface formations using alkaline nanosilica dispersion and a delayed activation chemistry is disclosed. In accordance with one embodiment of the present disclosure, the method includes introducing a mixture with a first pH into the subsurface formation. The mixture comprises an aqueous solution, an alkaline nanosilica dispersion and a water-insoluble hydrolyzable compound. The method further includes allowing the water-insoluble hydrolyzable compound to hydrolyze in the subsurface formation to form an acid at 70° C. or greater, thereby acidizing the mixture to a reduced second pH and causing the alkaline nanosilica dispersion to gel into a solid and seal the subsurface formation. A composition for sealing a subsurface formation is also disclosed. The composition includes an aqueous mixture including water, an alkaline nanosilica dispersion, and a water-insoluble hydrolyzable compound.Type: GrantFiled: October 29, 2019Date of Patent: July 6, 2021Assignee: Saudi Arabian Oil CompanyInventors: Rajendra Arunkumar Kalgaonkar, Vikrant Wagle
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Patent number: 11008499Abstract: The invention relates to the oil and gas industry, and more particularly to techniques for eliminating fluid loss during the drilling of oil and gas wells. The method includes successively pumping a blocking agent and a displacement fluid into a formation. The blocking agent is comprised of an emulsion-suspension system containing diesel fuel or processed oil from a central processing facility, an emulsifier, a colloidal solution of nanoparticles of silicon dioxide, dry amorphous silicon dioxide, microparticles of ilmenite or trimanganese tetraoxide, and an aqueous solution of calcium chloride or potassium chloride. The displacement fluid is comprised of an aqueous solution of calcium chloride or potassium chloride.Type: GrantFiled: November 13, 2018Date of Patent: May 18, 2021Assignee: LIMITED LIABILITY COMPANY “GR PETROLEUM”Inventor: Vitalii Vyacheslavovich Sergeev
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Patent number: 10968723Abstract: System and methods for cleaning debris or particulates from a wellbore using foam is provided, including predicting if a foam cleanout of a well is feasible by calculating foam properties at each of a number of segments in a well during a foam cleanout, comparing the foam properties to screening limits, providing an output to indicate if a foam cleanout is feasible. If feasible, the foam cleanout is performed.Type: GrantFiled: June 13, 2018Date of Patent: April 6, 2021Assignee: ExxonMobil Upstream Research CompanyInventors: Sai S. Rao, Kaustubh S. Kulkarni
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Patent number: 10954427Abstract: A method for plugging and sealing subsurface formations using alkaline nanosilica dispersion and a delayed activation chemistry is disclosed. In accordance with one embodiment of the present disclosure, the method includes introducing a mixture with a first pH into the subsurface formation. The mixture comprises an aqueous solution, an alkaline nanosilica dispersion and a water-soluble hydrolyzable compound. The method further includes allowing the water-soluble hydrolyzable compound to hydrolyze in the subsurface formation to form an acid at 70° C. or greater, thereby acidizing the mixture to a reduced second pH and causing the alkaline nanosilica dispersion to gel into a solid and seal the subsurface formation. A composition for sealing a subsurface formation is also disclosed. The composition includes an aqueous mixture including water, an alkaline nanosilica dispersion, and a water-soluble hydrolyzable compound.Type: GrantFiled: May 17, 2018Date of Patent: March 23, 2021Assignee: Saudi Arabian Oil CompanyInventors: Rajendra Arunkumar Kalgaonkar, Vikrant Wagle
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Patent number: 10927674Abstract: Methods and systems for the extraction of a formation fluid sample using a fluid extraction tool including an elongated body and a sealing pad extending therefrom, the sealing pad having an opening for establishing fluidic communication between an earth formation and the elongated body. The sealing pad communicable with from a container holding a selective permeability agent (SPA) capable of modifying the permeability of one or more fluids within the formation. The container coupled with a device for injecting the SPA into the earth formation and extracting a formation fluid sample therefrom.Type: GrantFiled: October 10, 2016Date of Patent: February 23, 2021Assignee: HALLIBURTON ENERGY SERVICES, INC.Inventor: Songhua Chen
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Patent number: 10920121Abstract: A method of reducing lost circulation includes introducing an activation solution comprising an aqueous solution, Na2SiO3, and NaOH into the wellbore and introducing Saudi Arabian volcanic ash into the wellbore. The Saudi Arabian volcanic ash comprises SO3, CaO, SiO2, Al2O3, Fe2O3, MgO, and K2O. The method further includes allowing the Saudi Arabian volcanic ash to contact the activation solution in the wellbore, thereby forming a geopolymer barrier between the wellbore and a subsurface formation to reduce lost circulation in the wellbore.Type: GrantFiled: March 18, 2020Date of Patent: February 16, 2021Assignee: Saudi Arabian Oil CompanyInventors: Khawlah A. Alanqari, Abdullah S. Al-Yami
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Patent number: 10889749Abstract: A composition including crosslinked expandable polymeric microparticles capable of hydrolysis at or below neutral pH and a method of modifying the permeability to water of a subterranean formation by introducing such compositions into the subterranean formation. This disclosure further relates to compositions and methods for the recovery of hydrocarbon fluids from a subterranean reservoir or formation subjected to CO2 or CO2 Water Alternating Gas flooding at low pH and increases the mobilization and/or recovery rate of hydrocarbon fluids present in the subterranean formations.Type: GrantFiled: December 4, 2018Date of Patent: January 12, 2021Assignee: ChampionX USA Inc.Inventors: Pious V. Kurian, Mingli Wei, Kin-Tai Chang
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Patent number: 10883328Abstract: Disclosed is a plug arrangement including glass arranged in one or more seats in a plug housing, the seat or seats forming support members supporting the glass or glasses in an axial direction. At least one of the support members includes an axially displaceable split sleeve which, in one direction, includes a support ring/face abutting against the glass, and in the other direction a number of split sleeve arms arranged to rest against an edge arranged in the plug housing.Type: GrantFiled: August 26, 2016Date of Patent: January 5, 2021Assignee: TCO ASInventor: Viggo Brandsdal
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Patent number: 10851279Abstract: A convertible composition comprising a nanosilica drilling fluid, the nanosilica drilling fluid comprising an aqueous based drilling mud, where the aqueous based drilling mud comprises water, and an alkaline nanosilica dispersion, where the alkaline nanosilica dispersion comprises nanosilica; and a chemical activator, the chemical activator operable to hydrolyze in the presence of water to produce an acid, where a weight ratio of the alkaline nanosilica dispersion to the chemical activator is between 1 to 0.001 and 1 to 0.25.Type: GrantFiled: March 6, 2020Date of Patent: December 1, 2020Inventors: Vikrant Wagle, Abdullah Al-Yami, Rajendra A. Kalgaonkar, Zainab Alsaihati
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Patent number: 10844265Abstract: A two-component lost circulation material (LCM) is provided. The two-component LCM includes a polymer component and a sodium hydroxide component. The polymer component may include may include a drilling fluid, a fibrous material such as polypropylene fibers, and an acrylic polymer, such as a 30% acrylic polymer solution. The sodium hydroxide component may include water and sodium hydroxide. The sodium hydroxide component is introduced to contact the polymer component to form the two-component LCM. Methods of lost circulation control and manufacture of a two-component LCM are also provided.Type: GrantFiled: January 10, 2019Date of Patent: November 24, 2020Assignee: Saudi Arabian Oil CompanyInventors: Jothibasu Ramasamy, Md Amanullah
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Patent number: 10844272Abstract: Cement slurries, cured cements, and methods of making cured cement and methods of using cement slurries are provided. The cement slurries have, among other attributes, increased yield point, reduced density, improved mechanical properties, increased resistance to H2S, and may be used, for instance, in the oil and gas drilling industry. The cement slurry comprises cement precursor material, Saudi Arabian volcanic ash, and an aqueous solution. The Saudi Arabian volcanic ash comprises SO3, CaO, SiO2, Al2O3, Fe2O3, MgO, and K2O and the cement slurry is free of any other SiO2 additive.Type: GrantFiled: November 6, 2019Date of Patent: November 24, 2020Assignee: Saudi Arabian Oil CompanyInventors: Zainab Alsaihati, Abdullah Al-Yami, Vikrant Wagle, Abdullah Al-Awadh, Abdulaziz Alhelal, Nasser Alhareth
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Patent number: 10738230Abstract: A composition includes an oil phase; a water phase emulsified in the oil phase; a viscosifier including a carbon chain and a polar group disposed along the carbon chain; and a hydrophobic nanomaterial having an average particle size of less than about 1 ?m. The hydrophobic nanomaterial including a silane or siloxane molecule having a nonpolar chain disposed on a surface thereof.Type: GrantFiled: September 17, 2018Date of Patent: August 11, 2020Assignee: Saudi Arabian Oil CompanyInventors: Vikrant Bhavanishankar Wagle, Abdullah Saleh Hussain Al-Yami
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Patent number: 10704351Abstract: This invention relates to a collecting device (1) for loosening and collecting particulate material from a well. The device includes a first end portion and a second end portion; a feed pipe (6) in the first end portion; a collecting container (8) including at least one container section (10), between the feed pipe (6) and the second end portion. A conveyor (18), in the feed pipe (6), moves the particulate material in toward the collecting device (1). The device further includes a tool (20) at the leading end portion of the conveyor (18) and a fluid outlet (38) at the second end portion; a mono pump (12) driven by a motor (22); and at least one container section (10) in a flow path (40) on the pressure side of the mono pump (12). A method for loosening and collecting particulate materials from a well by means of the collecting device (1) is described as well.Type: GrantFiled: March 18, 2015Date of Patent: July 7, 2020Assignee: QINTERRA TECHNOLOGIES ASInventor: Lasse Haugland
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Patent number: 10703676Abstract: A method may comprise: mixing a water having hardness at about 300 ppm or greater with a plurality of particulates, a swellable clay, a chelating agent at about 0.01% to about 5% by weight of the water (BWOW), and an alkali metal base at about 0.01% to about 5% BWOW to produce a treatment fluid; and introducing the treatment fluid into a wellbore penetrating a subterranean formation.Type: GrantFiled: October 13, 2016Date of Patent: July 7, 2020Assignee: Halliburton Energy Services, Inc.Inventors: Sandip Prabhakar Patil, Waseem Abdulrazzaq, Sheetal Singh, Vaishali Mishra, Reem Mohammed Alburaikan
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Patent number: 10655413Abstract: A sealing device relates to a plug that includes a crusher mechanism, where the sealing device includes one or more glass layers positionable in a wellbore. The glass in a barrier phase bears against at least one seat or support sleeve arranged axially displaceably in the wellbore, where the at least one seat or support sleeve bears against the glass by means of a supporting hydraulic fluid in a pressure support chamber, the seat or support sleeve being configured to be released, be displaced axially, and to crush the glass when the supporting hydraulic fluid is released from the pressure support chamber.Type: GrantFiled: May 31, 2016Date of Patent: May 19, 2020Assignee: TCO ASInventors: Viggo Brandsdal, Jan Tore Tveranger
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Patent number: 10611684Abstract: Disclosed is a method for enhancing the performance of concrete includes, providing a cementitious mixture comprising cement and processed high calcium fly ash; wherein a processing of the processed high calcium fly ash neutralizes a cementitious reactivity of a high calcium fly ash, wherein a pozzolanic reactivity of the processed high calcium fly ash is maintained during the processing of the high calcium fly ash. The processing of the high calcium fly ash includes hydrating and carbonating the high calcium fly ash. The processing further includes excavating the high calcium fly ash from a landfill or surface impoundment after the hydrating and carbonating. Also disclosed is a portland-pozzolan blended cement mixture with clinker, gypsum, and a pozzolanic material, such as processed high calcium fly ash. After processing, the cementitious reactivity of a high calcium fly ash is neutralized, while pozzolanic reactivity of the high calcium fly ash is maintained.Type: GrantFiled: August 8, 2016Date of Patent: April 7, 2020Assignee: Headwaters IncorporatedInventors: Rafic Y. Minkara, Eleazar Ivan Diaz-Loya, Douglas S. Rhodes
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Patent number: 10597575Abstract: A date tree trunk- and rachis-based lost circulation material (LCM) is provided. The date tree trunk and rachis LCM includes superfine date tree trunk fibers produced from date tree trunks and superfine date tree rachis fibers produced from date tree rachises. The date tree trunks and rachises may be obtained from the date tree waste produced by the processing of date trees in the production of date fruits. The date tree trunk and rachis LCM may include fibers having lengths in the range of about 20 microns to about 300 microns. Methods of lost circulation control using a date tree trunk and rachis LCM and manufacture of a date tree trunk and rachis LCM are also provided.Type: GrantFiled: May 20, 2019Date of Patent: March 24, 2020Assignee: Saudi Arabian Oil CompanyInventors: Md Amanullah, Jothibasu Ramasamy
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Patent number: 10584548Abstract: An oil-swellable lost circulation material (LCM) formed from an elastomeric polymer and a crosslinker amine is provided. The LCM may be formed from elastomeric polymer particles, a crosslinker amine, an anti-agglomerating agent, and may also be formed using a cure accelerator. A mixture of the elastomeric polymer particles, the crosslinker amine, the anti-agglomerating agent, and in some mixtures the cure accelerator, may be hot rolled at a temperature of at least 120° F. for a duration. The resulting LCM may swell by absorbing about 20 to about 34 times its weight when introduced to a loss circulation zone in the presence of a non-aqueous fluid such as a drilling mud or component of a drilling mud.Type: GrantFiled: May 1, 2018Date of Patent: March 10, 2020Assignee: Saudi Arabian Oil CompanyInventor: B. Raghava Reddy
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Patent number: 10584274Abstract: Systems and methods for forming a permanent plug in a subterranean formation include providing a solution of colloidal silica and pumping the colloidal silica into a bore of a subterranean well so that the colloidal silica penetrates pores of the subterranean formation. The colloidal silica within the pores of the subterranean formation is dehydrated to form a glass-like material within the pores of the subterranean formation.Type: GrantFiled: June 19, 2017Date of Patent: March 10, 2020Assignee: Saudi Arabian Oil CompanyInventors: Mohammed Bataweel, Prasad Baburao Karadkar, Ayman Al-Mohsin, Haitham A. Othman
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Patent number: 10550695Abstract: A plug for a void in a mine to divert water having a rigid closed cell foam which fills the void. The rigid closed cell foam having a plurality of pipes disposed within the foam. The pipes distributed throughout the void. The pipes are positioned in the foam so the pipes are staggered in length vertically with respect to various heights in the void, and the pipes are positioned in the foam every 4? to 6? horizontally with respect to the void. A method for diverting water from a void in a mine.Type: GrantFiled: May 30, 2018Date of Patent: February 4, 2020Assignee: Strata Products Worldwide, LLCInventor: Joshua Stephen Behling