Water Based Composition With Inorganic Material (epo) Patents (Class 166/308.3)
  • Patent number: 11499091
    Abstract: A novel surfactant composition that comprises of two surfactant components, a solvent, and water. The surfactant composition is added to a fracturing fluid, which is then pumped downhole into a subterranean formation where the novel characteristics of the fracturing fluid lend to improved oil production over the fracturing fluid without the surfactant composition.
    Type: Grant
    Filed: September 15, 2020
    Date of Patent: November 15, 2022
    Assignees: CNPC USA CORPORATION, BEIJING HUAMEI INC.
    Inventors: Jiangshui Huang, Nancy Zhou, Lijun Lin, Fuchen Liu, Guodong Wu, Bo Huang
  • Patent number: 11236266
    Abstract: Methods of treating a subterranean formation. A pad fluid is introduced into a wellbore penetrating the subterranean formation to create or enhance one or more fractures in the subterranean formation. A fracturing fluid is introduced into the wellbore. The fracturing fluid includes a polymer having a hydrophobic monomer and a hydrophilic monomer. The fracturing fluid further includes a proppant and a second aqueous base fluid. The fracturing fluid does not include a crosslinker or an oxidative breaker. The fracturing fluid is broken thereby settling the proppant in the fracture.
    Type: Grant
    Filed: December 23, 2019
    Date of Patent: February 1, 2022
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Hong Sun, Janette Montalvo, Linping Ke
  • Patent number: 11136870
    Abstract: A system for hydraulically fracturing an underground formation in an oil or gas well to extract oil or gas from the formation, the oil or gas well having a wellbore that permits passage of fluid from the wellbore into the formation. The system includes a plurality of electric pumps fluidly connected to the well, and configured to pump fluid into the wellbore at high pressure so that the fluid passes from the wellbore into the, and fractures the formation. The system can also include a plurality of natural gas powered generators electrically connected to the plurality of electric pumps to provide electrical power to the pumps.
    Type: Grant
    Filed: June 28, 2019
    Date of Patent: October 5, 2021
    Assignee: U.S. Well Services, LLC
    Inventors: Joel N. Broussard, Jeff McPherson, Robert Kurtz
  • Patent number: 11091686
    Abstract: Well treatment compositions comprise water, a lipophilic anionic surfactant, a hydrophilic non-ionic surfactant, a second non-ionic surfactant, a water-solubilizing solvent, a water-immiscible solvent and a lipophilic non-ionic surfactant. Optionally, a second solvent may be incorporated. When added to spacer fluids, chemical washes or both, the compositions promote the removal of non-aqueous drilling fluids from casing surfaces. Additionally, the treated casing surfaces are water wet, thereby promoting optimal bonding to cement.
    Type: Grant
    Filed: January 7, 2016
    Date of Patent: August 17, 2021
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Quentin Barral, Nicolas Droger, Slaheddine Kefi, Loic Regnault De La Mothe
  • Patent number: 10975290
    Abstract: Method of treating a portion of subterranean formation, comprising providing a water in oil emulsion of a water-soluble polymer, said emulsion comprising at least an inverting agent, and at least an emulsifying agent, wherein the mass ratio R of the total amount of inverting agent to the total amount of emulsifying agent is superior to 1.2, wherein the water in oil emulsion contains from 0.5% to 6% by weight of inverting agent; inverting the water in oil emulsion by adding it into an aqueous fluid to form an injection fluid; introducing the injection fluid into portion of the subterranean formation.
    Type: Grant
    Filed: July 26, 2019
    Date of Patent: April 13, 2021
    Assignee: S.P.C.M. SA
    Inventors: Cédrick Favero, Bruno Tavernier
  • Patent number: 10894934
    Abstract: The present invention relates to the field of liquid solubilizing systems. More specifically, the present invention relates to a ringing gel composition, one that is a self-thickened composition having a viscoelastic behavior and a viscosity comprised between 0.1 and 1000 Pa·s at 20° C. at 0.01 s?1 shear rate. The ringing gel has an aqueous phase, a surfactant system of one or more non-ionic surfactant(s), a linker and an oil phase that includes a hydrophobic active ingredient such as a perfume. Consumer products that contain the ringing gel composition, such as a self-thickened liquid laundry scent booster are also part of the present invention.
    Type: Grant
    Filed: October 17, 2017
    Date of Patent: January 19, 2021
    Assignee: Firmenich SA
    Inventors: Vera Tchakalova, Claudie Bellouard
  • Patent number: 10836665
    Abstract: A method of scale inhibition treatment of a water system comprising introducing an aqueous scale inhibiting composition into the water system wherein the aqueous scale inhibiting composition comprises a carboxylated hyperbranched polyglycerol.
    Type: Grant
    Filed: September 2, 2016
    Date of Patent: November 17, 2020
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company, The Board of Trustees of the University of Illinoi
    Inventors: Larisa Mae Q. Reyes, J. Keith Harris, Joshua S. Katz, Christopher J. Tucker, Steven C. Zimmerman, Brittany A. Walker
  • Patent number: 10759988
    Abstract: The instant invention relates to a process for the encapsulation of a non-amine hydrophilic compound C, comprising the steps of: (E1) providing a reverse emulsion containing: an oil phase (O), comprising a curable mixture of isocyanate and polyalkyldiene hydroxylated or polyol dispersed in said oil phase, drops of an aqueous phase W1, containing: said non-amine hydrophilic compound C; and at least 5% by weight of a compound C carrying more than 2 amine groups; (E2) pouring the reverse emulsion of step (E1) in a second water phase W2 to make a multiple emulsion water/oil/water; and, then, (E3) curing into polyurethane all or part of the curable mixture contained in the oil phase.
    Type: Grant
    Filed: September 25, 2015
    Date of Patent: September 1, 2020
    Assignee: RHODIA OPERATIONS
    Inventor: Arnaud Cadix
  • Patent number: 10093851
    Abstract: The present application provides for an acid precursor capsule that includes an acid precursor that is a non-aqueous ester and a polymerized shell that encapsulates the acid precursor. In some embodiments, the acid precursor converts into an associated acid during a hydrolysis period while in contact with water at an elevated temperature. In further embodiments, the associated acid is soluble in water and forms an aqueous acid solution with water. In certain embodiments, the polymerized shell contains the acid precursor and prevents interaction between the acid precursor and water at the elevated temperature until the polymerized shell dissolves in the water during a dissolution period. An acid precursor capsule suspension can include the acid precursor capsule and a suspension fluid.
    Type: Grant
    Filed: January 4, 2017
    Date of Patent: October 9, 2018
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Yun Chang, Mazen Kanj, Curt Thies
  • Patent number: 9429006
    Abstract: The method includes the introduction of a proppant-free stage and a proppant laden stage into the wellbore and/or subterranean formation. The method increases the effective fracture width and enhances fracture conductivity within the formation. Either the proppant-free stage or the proppant laden stage contains a breaker. At least one of the proppant-free stage or proppant laden stage contains a viscosifying agent to which the breaker has affinity. The viscosifying agent may be a superabsorbent, a viscosifying polymer (other than a superabsorbent) or a viscoelastic surfactant. The breaker has greater affinity for the viscosifying agent not present in the same stage as the breaker. Either the proppant-free stage or the proppant laden stage may be foamed.
    Type: Grant
    Filed: May 22, 2014
    Date of Patent: August 30, 2016
    Assignee: Baker Hughes Incorporated
    Inventors: Harold Dean Brannon, Brian N. Ward, D. V. Satyanarayana Gupta, Scott Gregory Nelson
  • Patent number: 9080043
    Abstract: An aqueous viscoelastic composition is provided comprising at least one viscoelastic surfactant, and at least one hydrophobically modified polymer, which is formed from polymerization of ethylenically unsaturated monomers; has a number average molecular weight of from 1,000 to 100,000 Da; and to a level of at least 0.1 mole %, based on the amount of monomer units in the polymer, contains monomeric units each covalently bonded to a pendant, optionally alkoxylated, hydrocarbyl group having from 6 to 40 carbon atoms, said pendant, optionally alkoxylated, hydrocarbyl group being connected to the backbone of said hydrophobically modified polymer via a non-ester containing linking group.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: July 14, 2015
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Qingwen Wendy Yuan-Huffman, Klin Aloysius Rodrigues, Jian Zhou, Stuart Peter Robert Holt, Elliot Isaac Band
  • Publication number: 20150129231
    Abstract: Produced or flowback water from an underground reservoir having been treated with a fluid containing a viscosifying polymer and a vitamin B1 and/or ylide breaker may be recycled by deactivating the vitamin B1 and/or ylide breaker with a sulfur or phosphorus containing nucleophilic agent.
    Type: Application
    Filed: October 27, 2014
    Publication date: May 14, 2015
    Inventors: Brandon Mark Vittur, Charles David Armstrong, Marshall G. Ault
  • Patent number: 9004172
    Abstract: A material to be used for hydraulic fracturing, comprising argon maintained as a supercritical fluid, and a proppant. The material may also include any one of a variety of gels, foaming agents, and/or gases. The material may be used in a system to recover resources from bedrock, the system comprising the fracturing material, at least one mixer, a pump to inject the material into a bore well, and a recovery unit to recover the resource from the well. The material and system may be used in a variety of methods for extracting resources from bedrock, the method including mixing the proppant with the supercritical argon to form a mixture, pumping the mixture into a bore well, and recovering the resource from the bore well. Additionally, the material and bore well may comprise a structure used in the extraction of resources from bedrock.
    Type: Grant
    Filed: September 1, 2011
    Date of Patent: April 14, 2015
    Assignee: Empire Technology Development LLC
    Inventors: William B. Carlson, Gregory D. Phelan
  • Patent number: 8991500
    Abstract: A method includes introducing a treatment fluid into a wellbore penetrating a subterranean formation, the treatment fluid including a polymer gel having a water-soluble polymer, a proppant, and a polymer gel-preserving amount of chlorine dioxide, the placing step includes applying the treatment fluid at a sufficient pressure and at a sufficient rate to fracture the subterranean formation.
    Type: Grant
    Filed: September 19, 2013
    Date of Patent: March 31, 2015
    Assignee: Sabre Intellectual Property Holdings LLC
    Inventor: John Mason
  • Publication number: 20150060066
    Abstract: This invention relates to oil and gas production, more specifically, to the methods of producing polymer emulsion for downhole operations and mixing degradable (hydrolysable) polymer emulsion with the treatment fluid.
    Type: Application
    Filed: August 4, 2014
    Publication date: March 5, 2015
    Inventors: Dean Willberg, Christopher N. Fredd, Vadim Kamilievich Khlestkin, Denis Olegovich Menshikov
  • Publication number: 20140374107
    Abstract: When used outside the pH range at which metal ion complexation normally occurs, aminopolycarboxylic acids can moderate the reaction rate of acids with carbonate minerals. Methods for treating a subterranean formation can comprise: providing a treatment fluid comprising an aqueous carrier fluid, an acid, and a chelating agent comprising an aminopolycarboxylic acid, the treatment fluid having a pH below that at which the carboxylic acid groups of the chelating agent are substantially protonated and the chelating agent is ineffective for complexing a metal ion; introducing the treatment fluid into a subterranean formation comprising a carbonate mineral; reacting the acid with the carbonate mineral, such that the acid at least partially spends and the pH of the treatment fluid rises; and once the pH of the treatment fluid rises above a pKa value for one or more of the carboxylic acid groups, complexing a metal ion with the chelating agent.
    Type: Application
    Filed: June 25, 2013
    Publication date: December 25, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Enrique Antonio Reyes, Alyssa Lynn Smith, Aaron M. Beuterbaugh
  • Publication number: 20140352969
    Abstract: Various embodiments disclosed relate to a composition including a crosslinkable ampholyte polymer or a crosslinked product of the same, methods of making and using the composition, and systems including the composition. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include obtaining or providing a composition including a crosslinkable ampholyte polymer. The crosslinkable ampholyte polymer can include an ethylene repeating unit including a —C(O)NH2 group, an ethylene repeating unit including a —S(O)2OR1 group, and an ethylene repeating unit comprising an —N+R23X? group. At each occurrence, R1 can be independently selected from the group consisting of —H and a counterion. At each occurrence, R2 can be independently substituted or unsubstituted (C1-C20)hydrocarbyl. At each occurrence, X? can be independently a counterion. The composition can also include at least one crosslinker.
    Type: Application
    Filed: March 11, 2014
    Publication date: December 4, 2014
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: HsinChen Chung, Yuntao Thomas Hu, Narongsak Tonmukayakul, Harvey Fitzpatrick
  • Publication number: 20140345870
    Abstract: Methods treating a subterranean formation including providing a one-step acidizing treatment fluid comprising a first aqueous base fluid, a formation stimulation agent, and a stabilizing emulsion, wherein the stabilizing emulsion is an aqueous external emulsion comprising a second aqueous base fluid, a surfactant, and an aqueous-based surface modification agent; introducing the one-step acidizing treatment fluid into the subterranean formation; contacting the formation stimulation agent with the subterranean formation so as to acidize the subterranean formation and create conductive channels therethrough; and contacting the stabilizing emulsion with the subterranean formation so as to release the aqueous-based surface modification agent and stabilize unconsolidated formation particulates therein.
    Type: Application
    Filed: May 21, 2013
    Publication date: November 27, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Loan K. Vo, Philip D. Nguyen, Christopher R. Parton
  • Publication number: 20140305650
    Abstract: Disclosed are compositions derived of mixtures of choline ion salts (typically choline chloride) in aqueous solution with suspended particulates of sparingly soluble borate minerals or with alkali or alkaline earth borate salts, boric acid and its ester derivatives and salts, or other aqueous soluble borate forms. These compositions are useful as cross-linkers for polysaccharides and other biopolymers and particularly as used in subterranean treatment fluids for completion and stimulation of oil and gas wells. Advantages of the compositions are the combination into a single package of the properties of clay stabilizing actives (choline ion) and crosslinking actives (borates, etc.), in relatively high concentrations, and these compositions are easy to handle, being stable and pumpable at low temperatures, and with attractive environmental profiles. Also disclosed are the analogous choline solutions mixed with metallic cross-linking ions know in the art such as Zr+, Ti4+, Al3+, & Fe3+.
    Type: Application
    Filed: April 9, 2014
    Publication date: October 16, 2014
    Applicant: ECOLAB USA INC.
    Inventors: Jingshe Song, Pious Kurian, Joseph Paul Street, Rhyn Cason
  • Publication number: 20140251624
    Abstract: A well may be serviced with a fluid formulated with components comprising a friction reducer having at least one polymer unit chosen from acrylamide groups, acrylate groups, sulfo groups, and maleic acid groups; and an anionic surfactant, a cationic surfactant and an aqueous base capable of forming a viscoelastic gel.
    Type: Application
    Filed: February 21, 2014
    Publication date: September 11, 2014
    Inventors: D.V. Satyanarayana Gupta, Justyna Ferraro, Kay Cawiezel
  • Patent number: 8813847
    Abstract: An improvement over known hydraulic fracturing fluids. Boundary layer kinetic mixing material is added to components of fracturing fluid wherein kinetic mixing material is a plurality of particles wherein at least 25% of particles are several types, i.e., having surface characteristics of thin walls, three dimensional wedge-like sharp blades, points, jagged bladelike surfaces, thin blade surfaces, three-dimensional blade shapes that may have shapes similar to a “Y”, “V” or “X” shape or other geometric shape, slightly curved thin walls having a shape similar to an egg shell shape, crushed hollow spheres, sharp bladelike features, 90° corners that are well defined, conglomerated protruding arms in various shapes, such as cylinders, rectangles, Y-shaped particles, X-shaped particles, octagons, pentagon, triangles, and diamonds.
    Type: Grant
    Filed: January 6, 2014
    Date of Patent: August 26, 2014
    Assignee: Ecopuro, LLC
    Inventor: William L. Johnson, Sr.
  • Patent number: 8807222
    Abstract: A process is provided for reducing the pressure for injecting a solution of water-soluble polymer from a given injection pump into various oil wells in a given field as a function of the fracturation pressure for each well. Between the injection pump and each well, a respective main volumetric pump is placed. The fracturation pressure of each well is detected with a respective manometer, and the flow rate of each volumetric pump is controlled, using a brake, as a function of detected fracturation pressure of the respective well.
    Type: Grant
    Filed: March 9, 2011
    Date of Patent: August 19, 2014
    Assignee: S.P.C.M. SA
    Inventor: Philippe Jeronimo
  • Patent number: 8770294
    Abstract: A proppant comprises a particle and a polyamide imide coating disposed on the particle. A method of forming the proppant comprises the steps of providing the particle, providing the polyamide imide coating, and coating the particle with the polyamide imide coating.
    Type: Grant
    Filed: July 20, 2011
    Date of Patent: July 8, 2014
    Assignee: BASF SE
    Inventors: Christopher Tanguay, Rajesh Kumar
  • Patent number: 8763704
    Abstract: A method or process for hydraulically fracturing an underground hydrocarbon deposit includes using as a source of water an underground aquifer which contains water which is stable and clear in the aquifer but which may include undesirable chemical compounds as soluble components that are not in solution when subjected to reduced pressure at atmospheric conditions. Water from the aquifer is used as a source of water for the hydrocarbon fracturing process. The water is pumped at a pressure above its bubble point pressure A source well and a disposal well are drilled into the aquifer. A pump capable of maintaining the water above its bubble point pressure is provided, and a closed loop is established with a manifold, or a manifold and pumps, to keep the aquifer water circulating at a pressure above its bubble point pressure. The hydrocarbon reserve is fractured using the water.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: July 1, 2014
    Assignee: Nexen Energy ULC
    Inventor: Dana Pettigrew
  • Patent number: 8752627
    Abstract: A method of fracturing a subterranean formation comprising at least in part shale formation, comprises providing a carrier fluid; providing a particulate blend including a first amount of particulates having a first average particle size between about 100 and 2000 microns and a second amount of particulates having a second average particle size between about three and twenty times smaller than the first average particle size, such that a packed volume fraction of the particulate blend exceeds 0.75; combining the carrier fluid and the particulate blend into a fracturing slurry; fracturing the formation with the fracturing slurry to create at least a fracture; and removing the second amount of particulates from the fracture.
    Type: Grant
    Filed: June 6, 2013
    Date of Patent: June 17, 2014
    Assignee: Schlumberger Technology Corporation
    Inventors: Ryan Hartman, Mohan K. R. Panga, Bruno Drochon, John W. Still
  • Patent number: 8739878
    Abstract: The method disclosed herein includes the introduction of proppant-free stage and a proppant laden stage into the wellbore and/or subterranean formation. The method increases the effective fracture width and enhances fracture conductivity within the formation. Either the proppant-free stage or the proppant laden stage contains a breaker. The other stage contains a viscosifying polymer or viscoelastic surfactant to which the breaker has affinity. The proppant-free stage may be introduced prior to introduction of the proppant laden stage into the wellbore and/or formation. Alternatively, the proppant laden stage may be introduced into the wellbore and/or formation prior to introduction of the proppant-free stage.
    Type: Grant
    Filed: March 1, 2013
    Date of Patent: June 3, 2014
    Assignee: Baker Hughes Incorporated
    Inventors: Harold Dean Brannon, Brian N. Ward
  • Patent number: 8739877
    Abstract: Methods for oil and/or gas production may employ mixed surfactants to treat a subterranean formation. The methods can comprise: providing a treatment fluid comprising: an aqueous base fluid, a first surfactant having a charge, a second surfactant having an opposite charge, and a compatibilizer; and introducing the treatment fluid into at least a portion of the subterranean formation.
    Type: Grant
    Filed: January 15, 2010
    Date of Patent: June 3, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Ian D. Robb, Richard D. Rickman, Jason E. Bryant
  • Patent number: 8720555
    Abstract: A method for diverting fluids across a perforation tunnel in high-rate water pack operations may include providing a wellbore extending into a subterranean formation, wherein a perforation tunnel provides a fluid connection between the wellbore and the subterranean formation; providing a diverting particulate that comprises a degradable plasticized polymer coating on a particulate; placing the diverting particulate into the perforation tunnel, wherein the step of placing the diverting particulate forms a particulate pack within the subterranean formation and the perforation tunnel; allowing the degradable plasticized polymer coating to deform and fill the interstitial spaces within the particulate pack in the perforation tunnel such that the fluid conductivity between the wellbore and the subterranean formation is substantially blocked; and allowing the plasticized polymer coating to degrade over time thereby substantially restoring the fluid conductivity between the wellbore and the subterranean formation.
    Type: Grant
    Filed: October 4, 2011
    Date of Patent: May 13, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Feng Liang, Bradley L. Todd, Rajesh K. Saini, Stanley J. Heath
  • Patent number: 8720569
    Abstract: A composition of a treatment fluid and method for treating a zone of well. In an embodiment, the composition includes at least: (i) an aqueous phase; (ii) at least 5 ppm iron ion in the aqueous phase; (iii) a source of at least 5 ppm iodide ion to be dissolved in the aqueous phase; (iv) a water-soluble viscosity-increasing agent dissolved in the aqueous phase; and (v) a source of an oxidative breaker to be dissolved in the aqueous phase. In an embodiment, a method of treating a zone of a subterranean formation of a well includes at least the steps of: (a) forming a treatment fluid according to the composition; and (b) introducing the treatment fluid into the zone.
    Type: Grant
    Filed: December 30, 2011
    Date of Patent: May 13, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: David Michael Loveless, Lucas Kurtis Fontenelle, Rajesh Kumar Saini
  • Publication number: 20140116710
    Abstract: The present invention relates to a process for treating a shale formation comprising introducing a fluid containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA),and/or N- hydroxyethyl ethylenediamine N,N?,N?-triacetic acid or a salt thereof (HEDTA) into the formation which process may optionally contain an additional fracturing step.
    Type: Application
    Filed: June 11, 2012
    Publication date: May 1, 2014
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Hisham Naser-El-Din, Cornelia Adriana De Wolf, Mohamed Ahmed Nasr-El-Din Mahmoud
  • Patent number: 8708045
    Abstract: Treatment of a subterranean formation can be conducted with viscosified treatment fluids that comprise a multifunctional boronic acid crosslinking agent. Methods for treating a subterranean formation can comprise providing a treatment fluid that comprises an aqueous base fluid, a gelling agent, and a multifunctional boronic acid crosslinking agent that comprises a copolymer comprising at least one boronic acid monomer unit and at least one water-soluble monomer unit; and introducing the treatment fluid into a subterranean formation.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: April 29, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: James William Ogle, Jeremy Holtsclaw, Rajesh Kumar Saini
  • Publication number: 20140110120
    Abstract: Crosslinked gelling agents employed during subterranean operations use electronically-modified boronic acids to enable higher operating temperatures while allowing reduced gelling agent loadings; the boronic acids having Formula I: X1 and X2 are independently selected from O, CH2, CH2O, OCH2, bond, and null, Y1 and Y2 are independently N or C, Ar is a 5- or 6-membered ring aryl or heteroaryl group with a link L to monomer unit M1, m is 1 or 2, n is 0, 1, 2, or 3, and each Z is independently an electron withdrawing group selected from nitro, ester, carboxylic acids, carboxylates, halogen, cyano, amide, acyl, alkylsulfonyl, arylsulfonyl, heteroarylsulfonyl, CF3, a quaternary ammonium salt, polyhaloalkyl, and carbamate, with the proviso that when n is 0, the link L between M1 and Ar includes an electron withdrawing group attached to Ar, and introducing the treatment fluids into subterranean formations.
    Type: Application
    Filed: October 24, 2012
    Publication date: April 24, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: James William Ogle, Jeremy Holtsclaw, David Loveless
  • Publication number: 20140083709
    Abstract: This disclosure is related to a method of treating a formation, a wellbore, or equipment in a wellbore. The method includes introducing a soluble abrasive material into a wellbore for various oil and gas operations. The method also includes introducing an acidic solution into the wellbore to dissolve at least a portion of the soluble abrasive material to allow for more efficient removal of the soluble abrasive material from the wellbore.
    Type: Application
    Filed: April 18, 2013
    Publication date: March 27, 2014
    Applicant: Thru Tubing Solutions, Inc.
    Inventors: Mark Britton, Roger Schultz
  • Patent number: 8657002
    Abstract: A method for minimizing the amount of metal crosslinked viscosifier necessary for treating a wellbore with proppant or gravel is given. The method includes using fibers to aid in transporting, suspending and placing proppant or gravel in viscous carrier fluids otherwise having insufficient viscosity to prevent particulate settling. Fibers are given that have properties optimized for proppant transport but degrade after the treatment into degradation products that do not precipitate in the presence of ions in the water such as calcium and magnesium. Crosslinked polymer carrier fluids are identified that are not damaged by contaminants present in the fibers or by degradation products released by premature degradation of the fibers.
    Type: Grant
    Filed: June 28, 2012
    Date of Patent: February 25, 2014
    Assignee: Schlumberger Technology Corporation
    Inventors: Dean M. Willberg, Christopher N. Fredd, Marina Bulova
  • Publication number: 20140034322
    Abstract: The present disclosure is directed to a method of servicing a well. The method comprises providing a well servicing fluid. The well servicing fluid is formulated with the following components comprising, at least one friction reducer chosen from polychloroprenes, vinyl acetate polymers, polyalkylene oxides, and polyalphaolefins; and a nonaqueous carrier fluid. The well servicing fluid is introduced into the well.
    Type: Application
    Filed: October 7, 2013
    Publication date: February 6, 2014
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: D.V. SATYANARAYANA GUPTA, HARPREET SINGH DINSA, RONALD CASEY PLASIER
  • Publication number: 20130333892
    Abstract: Fluids for use in operations involving wellbores and/or earth formations, the fluids including formation protective materials for application to an interior surface of earth and/or of a formation and/or of a fracture and/or of a fluid channel of a fracture; acidizing materials and methods; and, in certain aspects, materials for protecting an earth formation so that acid in acidizing fluids does not cause undesirable formation erosion and/or so that unprotected areas are eroded more than protected areas. This abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure and is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims, 37 C.F.R. 1.72(b).
    Type: Application
    Filed: March 5, 2013
    Publication date: December 19, 2013
  • Patent number: 8607870
    Abstract: The invention discloses a method of treating a subterranean formation of a well bore, that provides a first treatment fluid; subsequently, pumps the first treatment fluid to initiate a network of low conductivity fractures in the subterranean formation; provides a second treatment fluid comprising a second carrier fluid, a particulate blend including a first amount of particulates having a first average particle size between about 100 and 2000 ?m and a second amount of particulates having a second average particle size between about three and twenty times smaller than the first average particle size, such that a packed volume fraction of the particulate blend exceeds 0.74; and subsequently, pumps the second treatment fluid to initiate at least one high conductivity fracture in the subterranean formation, wherein the high conductivity fracture has a conductivity higher than the average of the conductivity of the low conductivity fractures and connects the network of the low conductivity fractures.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: December 17, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Hongren Gu, Yiyan Chen, Xiaowei Weng
  • Patent number: 8550165
    Abstract: The present disclosure is directed to a method of servicing a well. The method comprises providing a well servicing fluid. The well servicing fluid is formulated with the following components comprising, at least one friction reducer chosen from polychloroprenes, vinyl acetate polymers, polyalkylene oxides polyalphaolefins; and a nonaqueous carrier fluid. The well servicing fluid is introduced into the well.
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: October 8, 2013
    Assignee: Baker Hughes Incorporated
    Inventors: D. V. Satyanarayana Gupta, Harpreet Singh Dinsa, Ronald Casey Plasier
  • Patent number: 8540022
    Abstract: A method for the controlled delivery of a fracturing fluid to a well bore comprises formulating an aqueous base fluid such that it meets or exhibits desired physical and chemical characteristics for an optimal fracturing fluid. The formulation of the aqueous base fluid max involve commingling one or more sources of waste water with a source of fresh water followed by controlled injection of one or more additives. This process is substantially completed prior to delivering the aqueous base fluid to the well site. This allows the delivery of an optimal volume of the aqueous base fluid with homogeneously blended additives to the well bore.
    Type: Grant
    Filed: November 27, 2012
    Date of Patent: September 24, 2013
    Assignee: Tetra Technologies, Inc.
    Inventors: Enrico J. Termine, Robert I. Richie
  • Patent number: 8511381
    Abstract: A system and method are disclosed for low damage gravel packing. The system comprises a well bore; a gravel packing slurry comprising a carrier fluid and a solids mixture, wherein the solids mixture comprises a plurality of volume-averaged particle size distribution (PSD) modes such that a packed volume fraction (PVF) exceeds 0.75, wherein the solids mixture comprises at least a proppant PSD mode and a fines PSD mode; a pump to circulate the slurry in the wellbore and form a proppant pack; and a dispersant source effective to facilitate fines flowback from the pack. The method comprises circulating the slurry through a wellbore to form a proppant pack; contacting fines in the pack with a dispersant; and passing fluid through the pack to remove fines from the pack.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: August 20, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Mohan K. R. Panga, Balkrishna Gadiyar, Bruno Drochon, John W. Still
  • Patent number: 8505628
    Abstract: High solids content slurry, systems and methods. The slurry comprises a carrier fluid and a solids mixture of first, second, third and fourth particle size distribution (PSD) modes wherein the first PSD mode is at least three times larger than the second PSD mode, which is larger than the third PSD mode, which is larger than the fourth PSD mode, and wherein at least one of the second and third PSD modes is less than 3 times larger than the respective third or fourth PSD mode. The method comprises forming the slurry, positioning a screen in a wellbore and circulating the slurry through the wellbore such that the solids mixture is deposited between the screen and the wellbore. The system comprises a pump to circulate the slurry, a workstring to position the screen and means for converting the slurry to a gravel pack.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: August 13, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Mohan Panga, Jean-Philippe Bedel, Yiyan Chen
  • Patent number: 8505631
    Abstract: A monomer compound that contains at least one polymerizable functional group per molecule, and at least one bicycloheptyl-, bicycloheptenyl-, or branched (C5-C42)alkyl-polyether radical per molecule, wherein the bicycloheptyl- or bicycloheptenyl-polyether radical may optionally be substituted on one or more of the ring carbon atoms by one or two (C1-C6)alkyl groups per ring carbon atom is useful in making polymers, particularly pH responsive polymers.
    Type: Grant
    Filed: November 7, 2011
    Date of Patent: August 13, 2013
    Assignee: Rhodia Operations
    Inventors: Hui Shirley Yang, Derek Pakenham, Herve Adam, Pierre Hennaux, Brian Chung, Subramanian Kesavan, Seren Frantz
  • Patent number: 8499833
    Abstract: Disclosed herein are an acid emulsion fluid for use in sealing target portions of a hydrocarbon producing formation penetrated by a wellbore and the method of use thereof for fluid loss control.
    Type: Grant
    Filed: August 23, 2010
    Date of Patent: August 6, 2013
    Assignee: Saudi Arabian Oil Company
    Inventors: Saleh Haif Al-Mutairi, Ali Dahmal Al-Aamri, Khalid A. Al-Dossary, Mubarak Auodah Al-Dhufairi
  • Patent number: 8499832
    Abstract: The components of surfactant-laden fluids, such as those used in hydrocarbon recovery operations such as for stimulation, e.g. hydraulic fracturing, may be re-used and re-cycled into components for subsequent use in a wide range of similar or different operational fluids. In particular, aqueous fluids gelled with viscoelastic surfactants and having components therein to pseudo-crosslink the elongated VES micelles and for internal breaking may be separated into its component parts by relatively inexpensive methods such as filtration. One filtration method includes contacting the surfactant-containing fluid with a particle pack having particulate additives therein which filter out or extract fine solids from the fluid. In an alternate embodiment the surfactant-laden fluid is a nano- and/or micro-emulsion wellbore cleanup fluid.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: August 6, 2013
    Assignee: Baker Hughes Incorporated
    Inventors: James B. Crews, Tianping Huang
  • Patent number: 8496057
    Abstract: This invention refers to the oil and gas production industry and can be employed to enhance the productivity of wells by preventing the closure of fractures through application of proppant granular material during the formation fracturing operation.
    Type: Grant
    Filed: September 18, 2007
    Date of Patent: July 30, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Jose Rafael Silva Ferrero, Elena Mikhaylovna Pershikova
  • Patent number: 8496056
    Abstract: A method of fracturing a subterranean formation comprising at least in part shale formation, comprises providing a carrier fluid; providing a particulate blend including a first amount of particulates having a first average particle size between about 100 and 2000 microns and a second amount of particulates having a second average particle size between about three and twenty times smaller than the first average particle size, such that a packed volume fraction of the particulate blend exceeds 0.75; combining the carrier fluid and the particulate blend into a fracturing slurry; fracturing the formation with the fracturing slurry to create at least a fracture; and removing the second amount of particulates from the fracture.
    Type: Grant
    Filed: August 30, 2010
    Date of Patent: July 30, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Ryan Hartman, Mohan K. R. Panga, Bruno Drochon, John W. Still
  • Patent number: 8469099
    Abstract: Methods of hydraulically fracturing subterranean coal seams and formations resulting in improved permeability to stimulate Coalbed Methane. In one method, the coal seam is fractured using a proppant-containing fracturing fluid in alternating stages with an aqueous base solution that etches the fracture faces of the coal thereby creating channels for fluid flow. In another method, the coal seam is fractured using a fracturing fluid without propping agents in alternating stages with an aqueous oxidizing solution that is pumped at a pressure sufficient to maintain the fractures in an open position thereby etching the fracture faces to create channels for fluid flow. In yet another embodiment, the aqueous oxidizing agent solution is pumped into the formation at a pressure sufficient to create fractures therein and simultaneously etch the faces of the open fractures to thereby form channels in the faces for increased fluid flow.
    Type: Grant
    Filed: July 20, 2010
    Date of Patent: June 25, 2013
    Assignee: ACT Operating Company
    Inventor: Marshall Charles Watson
  • Patent number: 8459353
    Abstract: A wellbore fluid is an aqueous carrier liquid with first and second hydrophobic particulate materials suspended therein. The first hydrophobic particles have a higher specific gravity than the second hydrophobic particles and the fluid also comprises a gas to wet the surface of the particles and bind them together as agglomerates. The fluid may be a fracturing fluid or gravel packing fluid and the first particulate material may be proppant or gravel. The lighter second particulate material and the gas both reduce the density of the agglomerates which form so that they settle more slowly from the fluid, or are buoyant and do not settle. This facilitates transport and placement in a hydraulic fracture or gravel pack. One application of this is when fracturing a gas-shale with slickwater. The benefit of reduced settling is better placement of proppant so that a greater amount of the fracture is propped open.
    Type: Grant
    Filed: August 25, 2010
    Date of Patent: June 11, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Trevor Hughes, Evgeny Barmatov, Jill Geddes, Michael Fuller, Bruno Drochon, Sergey Makarychev-Mikhailov
  • Patent number: 8448706
    Abstract: A wellbore fluid comprises an aqueous carrier liquid, hydrophobic fibers suspended therein, hydrophobic particulate material also suspended in the carrier liquid, and a gas to wet the surfaces of the particles and fibers and bind them together as agglomerates. The wellbore fluid may be a slickwater fracturing fluid and may be used for fracturing a tight gas reservoir. Using a combination of hydrophobic particulate material, hydrophobic fibers and gas inhibits settling out of the particulate material from an aqueous liquid. Because the gas acts to wet the surfaces of both materials and agglomerates them, the particulate material is made to adhere to the fibers; the fibers form a network which hinders settling of the particulate material adhering to them, and the agglomerates contain gas and so have a bulk density which is less than the specific gravity of the solids contained in the agglomerates.
    Type: Grant
    Filed: August 25, 2010
    Date of Patent: May 28, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Trevor Hughes, Evgeny Barmatov, Jill Geddes, Michael Fuller, Bruno Drochon, Sergey Makarychev-Mikhailov
  • Patent number: 8445414
    Abstract: Alkaline earth metal compounds may be fluid loss control (FLC) agents for viscoelastic surfactant (VES) fluids used for fluid loss control pills, lost circulation material pills and kill pills in hydrocarbon recovery operations. The FLC agents may include, but not be limited to oxides and hydroxides of alkaline earth metal, and in one case magnesium oxide where the particle size of the magnesium oxide is between 1 nanometer to 0.4 millimeter. The FLC agent may alternatively be transition metal oxides and/or transition metal hydroxides. The FLC agent appears to associate with the VES micelles and together form a novel pseudo-filter cake quasi-crosslinked viscous fluid layer that limits further VES fluid flow into the porous media. The FLC agent solid particles may be added along with VES fluids. The pills may also contain internal breakers to reduce the viscosity thereof so that the components of the pill may be recovered.
    Type: Grant
    Filed: February 2, 2012
    Date of Patent: May 21, 2013
    Assignee: Baker Hughes Incorporated
    Inventors: James B. Crews, Tianping Huang