Abstract: Methods of fracturing a subterranean formation containing a hydrocarbon include introducing a first fracturing fluid that includes natural gas into the formation at a rate and pressure sufficient to create a complex fracture in the formation; introducing a second fracturing fluid into the formation, wherein the second fracturing fluid comprises water, a gelling agent, a foaming agent, natural gas, and proppant particulates; and allowing the second fracturing fluid to transport a portion of the proppant particulates into the complex fracture.

Abstract: A method, comprising contacting a proppant, water, and a water external emulsion to form a mixture, wherein the water external emulsion has an organic internal phase comprising a surface modifying agent; contacting the mixture with an emulsion breaker to form a wellbore servicing fluid comprising a proppant coated with the surface modifying agent; an placing the wellbore servicing fluid in a wellbore penetrating a subterranean formation. A method comprising contacting a proppant, water, and a water external emulsion to form a first mixture, wherein the water external emulsion has an organic internal phase comprising a surface modifying agent; contacting the first mixture with an emulsion breaker to form second mixture comprising a proppant coated with the surface modifying agent; and recovering a coated proppant from the second mixture.

Abstract: The present invention relates to a proppant laden fracture fluid having a Mitchell quality of at least 50% and fracturing a subterranean formation therewith.

Abstract: A method may include: placing into a wellbore penetrating a subterranean formation a foaming agent, wherein the wellbore comprises a produced fluid from the subterranean formation; and foaming the produced fluid. The foaming agent may include at least one of the following structures: wherein R1 and R2 are individually selected from an alkyl group, an alkenyl group, a heteroatom substituted alkyl group, or a heteroatom substituted alkenyl group, wherein R1 comprises 5 carbon atoms to 22 carbon atoms in length, and wherein R2 comprises 1 carbon atom to 8 carbon atoms.

Abstract: Various embodiments disclosed relate to methods of treating subterranean formations including sequential use of at least two surfactants. In various embodiments, the present invention provides a method of treating a subterranean formation including sequentially placing in the subterranean formation a penetrating-aid surfactant and a pore-declogging surfactant.

Abstract: This invention relates to foam-forming surfactant compositions having at least two surfactants whereof at least one is a sulfosuccinamate, and at least one is a sulfosuccinate, and optionally including, a solvent. Methods of recovering oil or gas by generating a foam, feeding the foam into a subterranean oil- or gas-bearing geological formation, and collecting mineral oil or natural gas driven by the foam in a production well, wherein the foam is generated by intimate mixing of one or more foam-forming surfactant compositions described herein with a gas in a foam generator, or by introduction of at least one of water and gases, together or intermittently or in alternating sequence, slugs of a gas which may be in a supercritical or non-supercritical state, and of water, wherein the foam-forming surfactant composition(s) can be admixed to the water or to the gas if the gas is in a supercritical state or be introduced separately as solution into the geological formation, are also provided.

Abstract: Disclosed herein are compositions and methods for increasing the viscosity of a calcium-containing fluid by addition of a modifying agent. The resulting enhanced viscosity fluid may be used in a variety of applications including drilling, to create an enhanced-viscosity fluid, and demolition/mining to create an expansive putty for use in underwater and overhead applications.

Abstract: Methods of evaluating and/or selecting formation stabilization treatments for subterranean formations are provided. In some embodiments, the methods comprise: subjecting a test formation sample to stress loads, wherein sample comprises: two wafers of a formation material from a subterranean formation, and a plurality of proppant particulates between and in contact with the two wafers; measuring a conductivity of a test fluid through the test formation sample, wherein an eluted test fluid is collected after passing through the test formation sample; determining one or more damage properties of the test formation sample using computed tomography images; determining one or more properties of the eluted test fluid; and selecting a formation stabilization treatment for the subterranean formation based at least in part on the conductivity of the test fluid through the test formation sample, the damage properties of the test formation sample, and/or the properties of the eluted test fluid.

Abstract: Foamable compositions useful for deliquifying gas wells, particularly gas wells having at least 40 vol. % of a hydrocarbon condensate, are disclosed. The compositions comprise, in addition to the condensate, an aqueous brine and 250 to 10,000 ppm of a monounsaturated betaine or sulfobetaine. A method for deliquifying the production line of a natural gas well is also disclosed. The method comprises introducing into a gas well a monounsaturated betaine or sulfobetaine to form a foamed composition, and removing at least a portion of the foamed composition from the production line. Certain betaines and sulfobetaines are remarkably effective in producing foams useful for gas well deliquification, particularly gas wells characterized by high or very high condensate levels. The inventive compositions and method provide a cost-effective way to enable thousands of gas wells to be utilized more productively.

Abstract: In some embodiments, the present disclosure pertains to compositions for enhanced oil recovery. In some embodiments, such compositions include: (1) a first agent, wherein the first agent acts as a foam booster; (2) a second agent, wherein the second agent includes a sulfonated or sulfated anionic surfactant; a (3) a third agent, wherein the third agent includes an alkoxylated and anionic surfactant; and (4) a base liquid. In some embodiments, the compositions of the present disclosure further include a gas, such as nitrogen. Further embodiments of the present disclosure pertain to methods of formulating the aforementioned compositions for enhanced oil recovery. Additional embodiments of the present disclosure pertain to methods of recovering oil from a reservoir by utilizing the aforementioned compositions.

Abstract: A proppant pack may be formed in a fracture that extends from a wellbore formed in a subterranean formation and is accomplished through different methods. The methods involve providing multiple spaced apart proppant slugs within a hydraulic fracturing fluid that is introduced into the wellbore at a pressure above the fracturing pressure of the formation.

Abstract: A pneumatic fracturing method for exploiting shale gas, the method including: 1) applying a compressed gas for a first period of time at a first pressure to a shale formation; 2) applying the compressed gas for a second period of time at a second pressure to the shale formation; and 3) repeating steps 1) and 2) to produce fissures in the shale formation. A temperature of the compressed gas is at least 80° C. A maximum pressure of the compressed gas is at least 25 megapascal, and a minimum pressure of the compressed gas is between ¼ and ? of the maximum pressure.

Abstract: Embodiments herein include a method comprising proving a treatment fluid comprising an activator and providing gas-forming particulates comprising coating particulates with a binding agent, wherein the binding agent holds a gas-generating chemical onto the particulates. The gas-forming particulates are suspended in the treatment fluid and the treatment fluid comprising the gas-forming particulates is introduced into a subterranean formation. The gas-generating chemical and the activator then react to generate gas-formed particulates.

Abstract: The disclosed compositions and methods provide a system that is effective for hydraulic fracturing, which can be used to extract natural gas and oil from subterranean formations, such as deep shale and coal bed type rack formations. In a first aspect, the invention features a composition for hydraulic fracturing, which includes a low pH product, a surfactant, and a thickening agent, all in an aqueous composition. The composition includes i) from about 0.01 wt % to about 20.0 wt % of a low pH product that includes an ammonium salt (e.g., ammonium bicarbonate, ammonium carbonate, or ammonium hydroxide) and hydrogen chloride (and optionally a carborane).

Abstract: Gellable treatment fluids containing a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, acrylic acid monomer units can be used in various subterranean operations where it is necessary for the treatment fluid to remain in a gelled state for extended periods of time at high formation temperatures. Methods for treating a subterranean formation can comprise providing a treatment fluid comprising an aqueous carrier fluid, a crosslinking agent, a gel stabilizer, and a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof; introducing the treatment fluid into a subterranean formation; allowing the treatment fluid to form a gel in the subterranean formation; and breaking the gel after it has been in the subterranean formation for at least about one day.

Abstract: Methods of making a degradable ball composition comprising a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, or a combination thereof comprising the steps of: forming a thermoplastic mass, and allowing the thermoplastic mass to cool as to form a degradable ball that is introduced in subterranean treatments by a carrier fluid.

Abstract: Disclosed herein is a foamed fracturing fluid comprising a carrier fluid; a polymer that is soluble in the carrier fluid; the polymer being a synthetic polymer, wherein the synthetic polymer comprises a labile group that is operative to facilitate decomposition of the synthetic polymer upon activation of the labile group; a foaming agent; and a gas constituent, the synthetic polymer, foaming agent and gas constituent being operative to increase the viscosity of the carrier fluid to about 50 centipoise or greater at 100 s?1, the foamed fracturing fluid being operative to reduce friction during a downhole fracturing operation and to transport a proppant during the downhole fracturing operation. A method for treating a hydrocarbon-bearing formation is also disclosed herein.

Abstract: An improvement over known hydraulic fracturing fluids. Boundary layer kinetic mixing material is added to components of fracturing fluid wherein kinetic mixing material is a plurality of particles wherein at least 25% of particles are several types, i.e., having surface characteristics of thin walls, three dimensional wedge-like sharp blades, points, jagged bladelike surfaces, thin blade surfaces, three-dimensional blade shapes that may have shapes similar to a “Y”, “V” or “X” shape or other geometric shape, slightly curved thin walls having a shape similar to an egg shell shape, crushed hollow spheres, sharp bladelike features, 90° corners that are well defined, conglomerated protruding arms in various shapes, such as cylinders, rectangles, Y-shaped particles, X-shaped particles, octagons, pentagon, triangles, and diamonds.

Abstract: A method of servicing a wellbore in a subterranean formation comprising placing a foamed wellbore servicing fluid into a wellbore; flowing the foamed wellbore servicing fluid back to the wellbore surface; and contacting the foamed wellbore servicing fluid with an immobilized defoaming agent structure comprising an inert substrate and a defoamer. A system comprising a foamed wellbore servicing fluid in contact with a de-foaming structure, wherein the de-foaming structure comprises a defoamer covalently bonded to an inert substrate.

Abstract: A method foamed fracturing may include providing a wellbore that extends into a subterranean formation and introducing a foamed fracturing fluid into the subterranean formation at a pressure sufficient to create or enhance at least one fracture in at least a portion of the subterranean formation. The foamed fracturing fluid may generally include an aqueous base fluid, a sugar derivative foaming agent, and a gas.

Abstract: Methods and compositions that include a method of treating a subterranean formation comprising the steps of providing a carrier fluid comprising degradable balls that comprise a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, a fatty acid salt, or a combination thereof, and introducing the carrier fluid to the subterranean formation during a treatment.

Abstract: The present invention relates to a method of obtaining and using foaming compositions with wettability-modifying and corrosion inhibitory properties that control the channeling of fluids in naturally fractured carbonate reservoirs, favorably alter the rock wettability in crude oil enhanced recovery processes and control uniform corrosion problems occurring in production rigs under high temperature and ultra-high salinity conditions by the synergistic effect resulting from the supramolecular interaction of alkyl amido propyl hydroxysultaines or alkyl hydroxysultaines with sodium alkyl hydroxysulfonates and sodium alkenyl sulfonates having the formula (1). The foaming compositions with wettability-modifying and corrosion inhibitory properties are tolerant to high concentrations of divalent ions such as calcium, magnesium, strontium and barium and are suitable for use in the reservoir, seawater and/or congenital water characteristic of the reservoir for transporting the crude oil from the reservoir.

Abstract: The present invention relates to the preparation of foaming formulations for high temperature, salinity and concentration of divalent ions, such as Calcium and Magnesium, that apply the synergistic effect of sodium alpha olefin sulfonates and alkyl amido propyl betaines; said inventions may use, as solvent, water, sea water, connate water, alcohols or mixtures all thereof. Said formulations control the piping of gas in reservoirs of the naturally fractured carbonate type.

Abstract: Well treatment fluids and methods of treating high temperature subterranean formations of up to about 500° F. (260° C.) are provided. The well treatment fluids and methods utilize a high molecular weight synthetic copolymer and a pH buffer than maintains a pH in a range of about 4.5 to about 5.25 for the fluids. The high molecular weight synthetic copolymer is derived from acrylamide, acrylamidomethylpropanesulfonic acid, and vinyl phosphonates. The well treatment fluids may be energized or foamed.

Abstract: A method for delivering a scale treatment agent to a hydrocarbon producing system. The method includes the steps of contacting the system with a foam comprising the scale treatment agent, and shutting the scale treatment agent in the system for at least 0.5 hour.

Abstract: A method for fracturing a downhole formation, includes: preparing an energized fracturing fluid including mixing gaseous natural gas and a fracturing base fluid in a mixer; injecting the energized fracturing fluid through a wellhead and into a well; and continuing to inject the energized fracturing fluid until the formation is fractured. An apparatus for generating an energized fracturing fluid for use to fracture a downhole formation, the apparatus includes: a fracturing base fluid source; a natural gas source; and a mixer for accepting natural gas from the natural gas source and fracturing base fluid from the fracturing base fluid source and mixing the natural gas and the fracturing base fluid to generate the energized fracturing fluid.

Abstract: Methods for using complementary surfactant systems and downhole fluids, where the systems are tailored to foam the fluids, which include the analyzed crude and/or condensate.

Abstract: Viscoelastic surfactant based aqueous fluid systems useful as thickening agents in various applications, e.g. to suspend particles produced during the excavation of geologic formations. The surfactants are zwitterionic/amphoteric surfactants such as dihydroxyl alkyl glycinate, alkyl ampho acetate or propionate, alkyl betaine, alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils. The thickening agent is used in conjunction with an inorganic water-soluble salt or organic additive such as phthalic acid, salicylic acid or their salts.

Abstract: A composition comprising a fluorinated pyridinium cationic compound of formula (I) wherein Rf is R1(CH2CH2)n—, R1 is a C7 to C20 perfluoroalkyl group interrupted by at least one catenary oxygen atom, each oxygen bonded to two carbon atoms, n is an integer of 1 to 3, and R is H, C1 to C5 linear or branched alkyl, or C1 to C5 linear or branched alkoxy, having surfactant properties for lowering surface tension in an aqueous medium or solvent medium, and for use as a foaming agent.

Abstract: Disclosed are imidazoline-based foamers and corrosion inhibitors for treatment of oil and gas wells for enhanced production. The invention also includes methods of foaming a fluid by introducing the disclosed foamers to oil and gas wells.

Abstract: Complementary surfactant systems and downhole fluids made using the systems are disclosed along with methods for making and using same, where the surfactant systems include from 0 wt. % to 100 wt. % of a first surfactant subsystem, from 100 wt. % to 0 wt. % of a second surfactant subsystem, and from 0 wt. % to 100 wt. % of a solvent subsystem based on the wt. % of the surfactant subsystems, where the system is tailored to foam the fluid including the analyzed crude and/or condensate.

Abstract: A method of treating a subterranean formation penetrated by a wellbore by contacting an energized fluid with the subterranean formation; and reducing a partial pressure of the energized fluid by an amount sufficient to form polymeric foam structure within the subterranean formation

Abstract: The present invention relates to a method for introducing a foaming composition including an imidazoline-based compound to a fluid. The foaming composition comprises at least one quaternized compound having an imidazoline moiety. An example of the quaternized compound is a quaternized imidazoline.

Abstract: In a method of hydraulically fracturing a hydrocarbon-bearing subterranean formation, a proppant stage is introduced into the fracture which contains a gaseous fluid and an ultra lightweight proppant suspended in a viscosified aqueous fluid. The gaseous fluid of the proppant stage contains at least about 90 volume percent of the combination of gaseous fluid and aqueous fluid. A pad fluid may first be introduced into the formation, the pad fluid containing a gaseous fluid and, optionally, an aqueous fluid. The gaseous fluid of the pad fluid mixture typically contains at least 70 volume percent of the mixture.

Abstract: A method foamed fracturing may include providing a wellbore that extends into a subterranean formation and introducing a foamed fracturing fluid into the subterranean formation at a pressure sufficient to create or enhance at least one fracture in at least a portion of the subterranean formation. The foamed fracturing fluid may generally include an aqueous base fluid, a sugar derivative foaming agent, and a gas.

Abstract: The invention describes improved fracturing compositions, methods of preparing fracturing compositions and methods of use. Importantly, the subject invention overcomes problems in the use of mists as an effective fracturing composition particularly having regard to the ability of a mist to transport an effective volume of proppant into a formation. As a result, the subject technologies provide an effective economic solution to using high ratio gas fracturing compositions that can be produced in a continuous (i.e. non-batch) process without the attendant capital and operating costs of current pure gas fracturing equipment.

Abstract: Surfactant based viscoelastic fluids for enhancing the productivity of a hydrocarbon-bearing formations have particular applicability in acid fracturing of subterranean formations surrounding oil and gas wells. The viscoelastic fluid contains an organic acid, an inorganic monovalent salt and a quaternary ammonium aromatic salt and water. The fluid may further be foamed or energized.

Abstract: A composition comprising a nonionic fluorinated polymeric surfactant having a weight average molecular weight of least 100,000 grams per mole, the nonionic fluorinated polymeric surfactant comprising: divalent units independently represented by formula (I): in a range from 30% to 65% by weight, based on the total weight of the nonionic fluorinated polymeric surfactant; and divalent units independently represented by formula (II): in a range from 70% to 35% by weight, based on the total weight of the nonionic fluorinated polymeric surfactant. Rf is a perfluoroalkyl group having from 3 to 4 carbon atoms; R and R2 are each independently hydrogen or alkyl of 1 to 4 carbon atoms; R1 is alkyl of 16 to 24 carbon atoms; and n is an integer from 2 to 11. Foams comprising the nonionic fluorinated polymeric surfactant and a liquid hydrocarbon and methods of making and using the foams are also disclosed.

Abstract: Methods and compositions that include a method comprising: providing a treatment fluid comprising at least a plurality of degradable diverting agents that comprise at least one degradable material selected from the group consisting of a fatty alcohol, a fatty acid salt, a fatty ester, a proteinous material, and a combination thereof; and introducing the treatment fluid into a subterranean formation during a subterranean operation via a well bore.

Abstract: Well treatment fluids and methods of treating high temperature subterranean formations of up to about 500° F. (260° C.) are provided. The well treatment fluids and methods utilize a high molecular weight synthetic copolymer and a pH buffer than maintains a pH in a range of about 4.5 to about 5.25 for the fluids. The high molecular weight synthetic copolymer is derived from acrylamide, acrylamidomethylpropanesulfonic acid, and vinyl phosphonates. The well treatment fluids may be energized or foamed.

Abstract: The present invention relates to aqueous oilfield treatment fluids containing a gas component and fibers, wherein the fluids may further include a viscosifying agent and/or proppant. The fluids have good proppant suspension and transport properties as well as excellent gas phase stability. Use of fluids comprising an aqueous medium, a gas component, viscosifying agent, and fibers for hydraulically fracturing a subterranean formation, cleanup operations, and gravel packing a wellbore, are also disclosed.

Abstract: The amount of crystallized salt in an oil and/or gas well may be minimized or reduced by use of a fructan, such as inulin, or a derivative as a salt block inhibitor. A preferred salt inhibitor is the salt of carboxyalkyl inulin such as a sodium salt of carboxymethyl inulin. The salt block inhibitor may be adsorbed onto a water-insoluble adsorbent.

Abstract: Hydrocarbon fluid compositions comprising a liquid hydrocarbon, an aluminum soap, a hydrocarbon foaming agent and a gas. The fluids can be used in various oil field operations.

Abstract: An aqueous, foamable composition useful for formation fracturing is disclosed, which includes an ionically coupled gel system. These compositions are well suited in fracturing formation where there are insufficient or non-existent hydration units. Methods for making the compositions and methods using the foamable compositions to fracture formation with insufficient hydration units.

Abstract: A method and apparatus for initiating and propagating a vertical hydraulic fracture in unconsolidated and weakly cemented sediments from a single bore hole to control the fracture initiation plane and propagation of the hydraulic fracture, enabling greater yield and recovery of petroleum fluids from the formation. An injection casing with multiple fracture initiation sections is inserted and grouted into a bore hole. A foam fracture fluid carrying a proppant is injected into the injection casing and opens the fracture initiation sections to dilate the formation in a direction orthogonal to the required fracture azimuth plane. Propagation of the fracture is controlled by limiting the fracture fluid form to that of a stable foam fracturing fluid during the fracturing process. The injection casing initiation section remains open after fracturing providing direct hydraulic connection between the production well bore, the permeable proppant filled fracture and the formation.

Abstract: Methods are provided that include a method comprising mixing particulates with a consolidating agent emulsion to form a slurry; creating a foamed slurry by adding a foaming agent and a gas to the slurry; placing the foamed slurry into a portion of a subterranean formation so as to create a particulate pack; and flushing the particulate pack with a postflush fluid. In some embodiments, the consolidating agent emulsion composition comprises a resin composition. Additional methods are also provided.

Abstract: A method and apparatus for processing a subterranean formation comprising stimulating and fracturing a subterranean formation, and drilling the subterranean formation wherein the drilling and fracturing occurs without removing equipment for drilling from the formation. A method and apparatus for drilling and fracturing a subterranean formation, comprising a drill string assembly and a hydraulic fracturing system, wherein the drill string and fracturing system are in communication with a wellbore and wherein the drill string and a fracture formed by the hydraulic fracturing system are less than about 1000 feet apart. A method and apparatus for processing a subterranean formation comprising fracturing a subterranean formation using a hydraulic fracturing system and drilling the subterranean formation using a drill string assembly wherein the drilling and fracturing occurs without removing the drill string from the formation, and wherein the fracturing occurs via ports in the drill string assembly.

Abstract: Provided herein are methods and compositions for generating acids for use downhole, for example, to break fluid-loss control pills. The delayed-release acid breakers of the present invention comprise orthoesters and/or poly(orthoesters).

Abstract: A method of stimulating gas production from a coalbed methane well that involves injecting a foam forming liquid and an expandable fluid into a coal seam proximate the wellbore. When the wellbore pressure is reduced, at least a portion of the expandable fluid can vaporize, which can generate foam that aids in the formation and/or enlargement of a cavity in the coal seam proximate the wellbore.

Abstract: The present invention provides a method of generating an acid downhole that comprise providing a degradable surfactant; introducing the degradable surfactant into a well bore that penetrates a subterranean formation; and allowing at least a portion of the degradable surfactant to degrade, thereby releasing an acid. Also provided are methods of degrading an acid-soluble component present within a subterranean formation, and methods of reducing the viscosity of a viscosified treatment fluid.