Co2 Or Carbonated Gas Patents (Class 166/402)
  • Patent number: 7624801
    Abstract: A control system and control method for controlling a modular apparatus for extracting petroleum and/or generating electricity based on subsurface data as well as market prices of electricity and/or petroleum. One or more probes measure subsurface total pressure, partial pressure of carbon dioxide, partial pressure of hydrogen, oil flow rate, gas flow rate, underground temperature, and/or viscosity of the oil. The control system/method controls the apparatus based on the subsurface parameters by controlling an injection module and/or a gas separator module to increase or decrease output of driver gas. The control system/method may also control the injection module and/or the gas separator module to increase (or decrease) output of driver gas when the market price of electricity decreases (or increases) and/or petroleum increases (or decreases).
    Type: Grant
    Filed: June 30, 2008
    Date of Patent: December 1, 2009
    Assignee: Pioneer Energy Inc.
    Inventors: Robert M. Zubrin, Mark H. Berggren, Douwe Bruinsma
  • Publication number: 20080169096
    Abstract: A process for improved safety and productivity when undertaking oil recovery from an underground reservoir by the toe-to-heel in situ combustion process employing a horizontal production well. Water, steam, and/or a non-oxidizing gas, which in the preferred embodiment substantially comprises carbon dioxide which acts as a gaseous solvent, is injected into the reservoir for improving recovery in an in situ combustion recovery process, via either an injection well, a horizontal well, or both.
    Type: Application
    Filed: March 13, 2008
    Publication date: July 17, 2008
    Inventor: Conrad Ayasse
  • Patent number: 7303006
    Abstract: In a WAG flood oil is displaced from a subterranean formation by injecting water alternately with gas into a single injection completion per pattern. The ratio of water to gas injected is the WAG ratio. In this invention, two separate injection completions are used in each pattern, with one placed directly above the other. A very low WAG ratio is used for injection into the bottom extremity of the formation. A very high WAG ratio is injected into the upper interval, at as high a rate as can safely be used without fracturing the formation. In the preferred embodiment, two horizontal well bores serve as the two completion intervals. Proper design of this method gives a vertical sweep efficiency of the gas that is several-fold greater than the best of previous WAG flood designs, especially in thin formations.
    Type: Grant
    Filed: May 10, 2004
    Date of Patent: December 4, 2007
    Inventor: Herbert L. Stone
  • Patent number: 7299868
    Abstract: A method and system for recovery of hydrocarbons from a hydrocarbon-bearing formation. A gaseous component of the produced hydrocarbon-containing fluid is separated from the fluid. The gaseous component is combusted with air in a power plant. Mixing and compressing of the gaseous component and air are realized to produce a flammable and pressurized gas-air mixture prior to combustion. An exhaust gas resulting from combustion is injected into the formation.
    Type: Grant
    Filed: January 14, 2002
    Date of Patent: November 27, 2007
    Inventor: Alexei Leonidovich Zapadinski
  • Patent number: 7281590
    Abstract: The invention relates to an environmentally friendly method for generating energy from natural gas. Through the combustion of the natural gas with a mixture comprising substantially oxygen and CO2, a number of advantages are achieved with regard to the emission of CO2 and NOx. According to the invention, the CO2-rich product gas is injected into a natural gas reservoir from which natural gas has been extracted. By the underground replacement of natural gas by CO2, a pressure drop in the natural gas reservoir can be controlled, so that subsidence is prevented. Additionally, in this manner, the emission of CO2 is reduced or even wholly prevented.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: October 16, 2007
    Assignee: Dropscone Corporation N.V.
    Inventor: Wouter Willem van de Waal
  • Patent number: 7261159
    Abstract: A method for perforating a wellbore comprises placing a perforating device in a cased wellbore that passes through a subterranean formation. The perforating device comprises at least one explosive perforating charge that can be detonated in order to perforate the casing and allow the formation fluids to enter the wellbore. A perforating fluid is placed in the wellbore between the perforating device and the casing. The ratio of the critical temperature of the perforating fluid in ° K and the temperature of the subterranean formation adjacent to the casing in ° K is between about 1.0-1.3. When the at least one explosive charge in the perforating device is detonated, at least one perforation is formed in the casing, and at least a portion of the perforating fluid is forced into the subterranean formation.
    Type: Grant
    Filed: June 14, 2005
    Date of Patent: August 28, 2007
    Assignee: Schlumberger Technology Corporation
    Inventor: Philip Kneisl
  • Patent number: 7172030
    Abstract: Natural gas is produced from a reservoir above a bitumen reserve with minimal or no impact on concurrent or subsequent production of bitumen recovery techniques including SAGD. Greenhouse benefits over and above the benefits of coincidental recovery are available through the injection of waste gas containing carbon dioxide for maintaining pressure in the gas reservoir while producing natural gas. Carbon dioxide separates out of the waste gas through preferential absorption in connate or aquifer water, with the result that carbon dioxide is thereby both retarded from flowing to the natural gas production well and effectively sequestered in the reservoir water. Additional advantage is achieved wherein water influx at production wells can be managed and trapped gas can be recovered.
    Type: Grant
    Filed: October 5, 2004
    Date of Patent: February 6, 2007
    Assignee: Beavert Gas Services Ltd.
    Inventors: W. Norval Horner, David A. Guichon, Arthur Danielson, Dennis A. Beliveau
  • Patent number: 7128150
    Abstract: This invention is method of recovering gas from a gas-bearing subterranean formation in which gas is produced from an upper portion of the formation and a waste gas is injected into a lower portion of the formation to dispose of the waste gas. The waste gas is injected within a 3000 foot (914 m) radial distance from the production of the gas. The injection and production can be carried out using one well or a plurality of wells.
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: October 31, 2006
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Eugene R. Thomas, P. Scott Northrop, Hua Hu
  • Patent number: 7100692
    Abstract: A process for the recovery of oil from a subsurface reservoir in combination with the production of liquid hydrocarbons from a hydrocarbonaceous stream involving: (i) separating an oxygen/nitrogen mixture into a stream enriched in oxygen and an oxygen depleted stream; (ii) partial oxidation of the hydrocarbonaceous feed at elevated temperature and pressure using enriched oxygen produced in step (i) to produce synthesis gas; (iii) converting synthesis gas obtained in step (ii) into liquid hydrocarbons; and (iv) recovering oil from a subsurface reservoir using at least part of the oxygen depleted gas stream produced in step (i).
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: September 5, 2006
    Assignee: Shell Oil Company
    Inventors: Alan John Parsley, Christiaan Stouthamer
  • Patent number: 6871707
    Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. The portion may be allowed or forced to cool after mixture production is ended. Carbon dioxide may be stored within the portion.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: March 29, 2005
    Assignee: Shell Oil Company
    Inventors: John Michael Karanikas, Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, Ilya Emil Berchenko, George Leo Stegemeier, Kevin Albert Maher, Etuan Zhang, Lanny Gene Schoeling, Phillip Temmons Baxley
  • Patent number: 6860147
    Abstract: A method for predicting the secondary porosity system (SPS) porosity, and thereby permeability, of a coal bed involves determining an initial condition in the coal bed, including an initial SPS pressure and an initial sorbed gas composition, determining a pressure strain effect due to increasing the SPS pressure to a value greater than the initial SPS pressure, and determining a sorption strain effect due to changes in the sorbed gas composition resulting from decreasing the methane content and increasing the content of a stronger adsorbing fluid (SAG) relative to the initial sorbed gas composition. Preferably, the method uses data from test injections of water and/or a weaker adsorbing fluid (WAG) and a SAG. The data is used in the inventors' model to compute a SPS porosity and an absolute permeability at a reference SPS pressure and a reference sorbed gas composition. Preferably, the reference pressure is atmospheric pressure.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: March 1, 2005
    Assignee: Alberta Research Council Inc.
    Inventors: William Daniel Gunter, Matthew John Mavor
  • Patent number: 6763886
    Abstract: A coal formation may be treated using an in situ thermal process. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. The portion may be allowed or forced to cool after mixture production is ended. Carbon dioxide may be stored within the portion.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: July 20, 2004
    Assignee: Shell Oil Company
    Inventors: Lanny Gene Schoeling, Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, John Michael Karanikas, Ilya Emil Berchenko, George Leo Stegemeier, Kevin Albert Maher, Etuan Zhang, Phillip Temmons Baxley
  • Patent number: 6736215
    Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Pyrolysis products may be produced from the formation. After pyrolysis, the temperature of the portion may be raised to a synthesis gas production temperature. A synthesis gas producing fluid may be introduced into the formation to generate synthesis gas. After synthesis gas production, the portion may be cooled and used to store carbon dioxide or other fluids.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: May 18, 2004
    Assignee: Shell Oil Company
    Inventors: Kevin Albert Maher, Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, John Michael Karanikas, Ilya Emil Berchenko, Etuan Zhang, Lanny Gene Schoeling
  • Patent number: 6733573
    Abstract: A method for recovering large volumes of hydrocarbon fuels, particularly methane (CH4), using commercially available reagents which are strongly water-soluble and soluble in liquid CO2 in the presence of liquid CO2 injected into the methane hydrate formation. The reagents which are strongly water-soluble and soluble in liquid CO2 form dilute aqueous acids that significantly increase the rate of conversion of methane hydrate into methane and CO2 hydrate, thereby allowing the natural gas to be released in a form that can then be recovered in large quantities using conventional devices. The preferred embodiment uses SO3, HCl or other strongly water soluble gas to cause the methane hydrate ice crystals to melt and form an aqueous solution. The aqueous solution contacts the methane hydrate ice on one side and liquid carbon dioxide on the other side.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: May 11, 2004
    Assignee: General Electric Company
    Inventor: Richard Kenneth Lyon
  • Patent number: 6679326
    Abstract: The invention comprises a high pressure fluid barrier forming an enclosure boundary with respect to overburden and floor strata separated by one or more production strata containing desirable fluidizable deposits and/or potential reaction materials. A centrally located Super Daisy Shaft delivers a highest pressure fluid to the enclosure boundary by way of envelope conduits extending laterally horizontal and/or downward from the Super Daisy Shaft (or a trench from which such conduits may also extend) into the production strata.
    Type: Grant
    Filed: January 15, 2002
    Date of Patent: January 20, 2004
    Inventor: Bohdan Zakiewicz
  • Patent number: 6609895
    Abstract: There is disclosed a pump and pumping system for pumping dense phase gases, specifically for injecting carbon dioxide into an oil or gas reservoir that includes a pump, a motor, and a casing in which the pump and motor reside. There is also disclosed a pump and pumping system for injecting dense phase greenhouse gases into a reservoir or underwater. The pump may include a downhole electric submersible pump. A method of controlling the pump and pumping system is also described involving the use of a variable speed drive in conjunction with an on-line gas chromatograph to maintain a constant carbon dioxide injection rate.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: August 26, 2003
    Assignee: Occidental Permian Ltd.
    Inventors: Frederick A. Forthuber, Raul Valdez
  • Publication number: 20030037928
    Abstract: A method for enhancing the recovery of oil from underground formations is disclosed. A gas mixture which contains greater than 50% by volume carbon dioxide, the remainder being an inert gas, is injected in the underground formation to lower the oil viscosity and surface tension and increase the oil swelling. Preferably, the gas mixture contains greater than 60% by volume carbon dioxide with a gas mixture containing greater than 70% by volume carbon dioxide preferred.
    Type: Application
    Filed: May 16, 2001
    Publication date: February 27, 2003
    Inventors: Ramakrishnan Ramachandran, Kirk Walton Limbach, Shuen-Cheng Hwang
  • Publication number: 20030000711
    Abstract: A process for recovery of hydrocarbons from an underground reservoir penetrated by an injection well and a production well spaced from the injection well, the process comprising:
    Type: Application
    Filed: November 7, 2001
    Publication date: January 2, 2003
    Inventors: A.M. Harold Gutek, Brian Harschnitz, Ronald D. Myers, Tadahiro Okazawa
  • Patent number: 6439308
    Abstract: A foam drive method for enhancing oil recovery efficiently is initiated by injecting into a subterranean oil-bearing formation, an aqueous polymer solution as a preceding-slug. This is followed by periodically injecting simultaneously or alternately a non-condensible gas and an aqueous solution of foaming composition to form a combined foam under ground or periodically injecting the combined foam formed beforehand by the gas and said aqueous solution above ground. The aqueous solution of foaming composition comprises an alkali, a surfactant and a polymer. Thereafter, an aqueous polymer solution used as a protecting-slug is injected into the formation; followed by continuing water-flooding.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: August 27, 2002
    Assignee: Da Qing Petroleum Administration Bureau
    Inventor: Demin Wang
  • Patent number: 6302204
    Abstract: The present invention provides a method for forming wellbores. In one method, one or more wellbores are drilled along preplanned paths based in part upon seismic surveys performed from the surface. An acoustic transmitter conveyed in such wellbores transmits acoustic signals at a one or more frequencies within a range of frequencies at a plurality of spaced locations. A plurality of substantially serially spaced receivers in the wellbores and/or at surface receive signals reflected by the subsurface formations. The sensors may be permanently installed in the boreholes and could be fiber optic devices. The receiver signals are processed by conventional geophysical processing methods to obtain information about the subsurface formations. This information is utilized to update any prior seismographs to obtain higher resolution seismographs. The improved seismographs are then used to determine the profiles of the production wellbores to be drilled.
    Type: Grant
    Filed: June 27, 2000
    Date of Patent: October 16, 2001
    Assignee: Baker Hughes Incorporated
    Inventors: Nils Reimers, John W. Harrell, Paulo S. Tubel
  • Patent number: 6158517
    Abstract: Artificial aquifers for hydrologic cells are used to recover hydrocarbons from carbonaceous formations. Artificial aquifers of a hydrologic cell for primary or enhanced oil recovery are constructed through the use of a conventional hydrofrac technique to make a pair of vertical extensional fractures across two parallel horizontal boreholes. Hydrocarbons move under a pressure gradient from a source aquifer to a sink aquifer. In another arrangement, artificial aquifers for exploitation of tar sands and gas hydrates are constructed through the removal of hydrocarbons which plug the pore space of the host rock. Hydrocarbons are induced to move vertically across a very large cross-sectional area from a source aquifer to a sink aquifer.
    Type: Grant
    Filed: November 10, 1998
    Date of Patent: December 12, 2000
    Assignee: Tarim Associates for Scientific Mineral and Oil Exploration
    Inventor: Kenneth J. Hsu
  • Patent number: 6105672
    Abstract: Enhanced (WAG type) oil recovery process in an underground reservoir uses forced injection, through one or more wells, alternately of fluid slugs and gas slugs, and recovery, through one or more production wells, of petroleum fluids displaced by the wetting fluid and the gas injected. The process includes dissolving a pressurized gas in the liquid of certain slugs and, after injection, relieving the pressure prevailing in the reservoir so as to generate gas bubbles by nucleation in the smallest pores, which has the effect of driving the oil away from the less permeable zones into the more permeable zones (with large pores or with fractures) where the oil is swept by the gas slugs injected later on. Implementation of the process considerably increases the oil recovery ratio that is usually reached with WAG type processes.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: August 22, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Christian Deruyter, Jean-Claude Moulu
  • Patent number: 6016873
    Abstract: Fluid and/or heat are induced to flow from one natural or artificial undeound aquifer, which extends vertically, at an incline or horizontally, across a host-rock formation to a well. Alternatively, fluid and/or heat are induced to flow from a well across the host-rock formation to a natural or artificial aquifer. The aquifer and well constitute the polarities of a hydrologic cell, like the electrodes of a battery or electric cell. An aquifer can be formed by fracturing the host formation and by injecting proppants into the fracture. Fluid and/or heat is injected into the source of the hydrologic cell and is induced to flow across the hydrocarbon bearing host formation within the cell such that the displacement of the injected fluid or heat causes the hydrocarbon to flow into the sink of the hydrologic cell. Aquifer(s) or well(s) can serve as either the source or the sink of the hydrologic cell. At least one aquifer serves as one of the polarities of the hydrological cell.
    Type: Grant
    Filed: March 12, 1998
    Date of Patent: January 25, 2000
    Assignee: Tarim Associates for Scientific Mineral and Oil Exploration AG
    Inventors: Kenneth J. Hsu, Peter Hsu
  • Patent number: 5871053
    Abstract: The invention described here is a method for using produced fluid compositions to decide how to modify injection/production strategies in oil recovery processes that involve injection of non-aqueous recovery agents ("Injectant"). The procedure is based on the premise that once a given zone is swept by injectant, most subsequent hydrocarbon recovery from that zone will occur by vaporization or extraction into the injectant. Because only the most volatile hydrocarbon components can be extracted, hydrocarbons produced by displacement can be distinguished from those produced by extraction by examining the hydrocarbon composition. Heavy, non-volatile components are recovered only by displacement. The disclosed method determines quantities of displaced vs. extracted hydrocarbons by comparing the produced hydrocarbon composition to that of the original in-place oil. Such information may be used to modify operations in order to most effectively use injectant to recover hydrocarbons from the reservoir.
    Type: Grant
    Filed: March 21, 1997
    Date of Patent: February 16, 1999
    Assignee: Exxon Production Research Company
    Inventor: David Stern
  • Patent number: 5778977
    Abstract: This invention relates to the recovery of oil from an oil-bearing formation having a natural fracture network with substantial vertical communication and wherein gravity drainage is the primary means of recovery. A downwardly inflating gas-cap is pressured up with a chase gas having a density less than that of CO.sub.2. CO.sub.2 is injected and a CO.sub.2 -rich displacing slug is formed at the gas-liquid hydrocarbon contact. The chase gas is injected to facilitate displacing downwardly the CO.sub.2 -rich displacing slug to recover hydrocarbon from the reservoir. CO.sub.2 is replaced in the displacing slug as the CO.sub.2 is solubilized into the oil, including matrix oil, to facilitate recovery thereof. The oil is recovered through production wells in fluid communication with the reservoir, preferably the inlet to the well is below the water-liquid hydrocarbon contact at such a level to prevent free-gas production. The chase gas has a density less than that of the CO.sub.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: July 14, 1998
    Assignee: Marathon Oil Company
    Inventors: James L. Bowzer, Douglas E. Kenyon, Eugene E. Wadleigh
  • Patent number: 5711373
    Abstract: The invention disclosed herein is a method for producing oil from a reservoir after predetermining its residual oil saturation, S.sub.orm. Such a method would displace a hydrocarbon fluid in a subterranean formation using a substantially non-aqueous displacement fluid after a waterflood. The non-aqueous displacement fluid can be introduced as a single bank, in alternating sequence with water, or by other means. The method predetermines S.sub.orm using the difference in the solubility parameters between the hydrocarbon liquid in the formation and the displacement fluid to be used for displacing the hydrocarbon fluid. The solubility parameter of the hydrocarbon liquid can be determined by a variety methods including, but not limited to, (1) using the hydrocarbon liquid's energy of vaporization, .DELTA.E.sub.
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: January 27, 1998
    Assignee: Exxon Production Research Company
    Inventor: Elaine Austin Lange
  • Patent number: 5634520
    Abstract: An enhanced oil recovery process comprises of the at least periodic introduction of (i) a non-condensible gas preferably selected from among carbon dioxide, nitrogen, methane or mixtures thereof, and (ii) an aqueous drive solution, preferably brine, into a reservoir formation. In this process, the half cycle of non-condensible gas injection, prior to aqueous drive fluid injection, measured in hydrocarbon pore volume is less than 0.25%. In this preferred embodiment, the non-condensible gas, e.g., carbon dioxide, and water, are simultaneously injected into the formation.
    Type: Grant
    Filed: May 8, 1996
    Date of Patent: June 3, 1997
    Assignee: Chevron U.S.A. Inc.
    Inventors: Chris E. Stevens, Steven D. McPherson, John R. Larson, Donnell R. Robie, Ronald K. Wackowski
  • Patent number: 5632336
    Abstract: A method is provided for increasing the rate of injection of flooding fluids into injection wells. A slug of polar solvent or a mixture of polar solvent and non-aqueous flooding fluid is injected into the injection well to displace aqueous and hydrocarbon liquids in the rock surrounding the injection well. Thereafter, the solvent is removed from the vicinity of the injection well by flooding fluid. The process may be repeated following each time water is injected into the injection well.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: May 27, 1997
    Assignee: Texaco Inc.
    Inventors: Phillip K. Notz, John Prieditis, James F. Stevens
  • Patent number: 5307876
    Abstract: The present invention is a method to cement a wellbore in the presence of carbon dioxide, or when the wellbore will subsequently be exposed to carbon dioxide. The wellbore is cemented using a blast furnace slag cement slurry, and the resulting set cement is considerably less susceptible to degradation by carbon dioxide.
    Type: Grant
    Filed: October 22, 1992
    Date of Patent: May 3, 1994
    Assignee: Shell Oil Company
    Inventors: Kenneth M. Cowan, James J. W. Nahm, Arthur H. Hale