Feed Other Than Coal, Oil Shale Or Wood Patents (Class 201/25)
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Patent number: 4313011Abstract: A process for production and recovery of hydrocarbons from hydrocarbon-containing whole plants in a form suitable for use as chemical feedstocks or as hydrocarbon energy sources which process comprises: (a) pulverizing by grinding or chopping hydrocarbon-containing whole plants selected from the group consisting of Euphorbiaceae, Apocynaceae, Asclepiadaceae, Compositae, Cactaceae and Pinaceae families to a suitable particle size, (b) drying and preheating said particles in a reducing atmosphere under positive pressure (c) passing said particles through a thermal conversion zone containing a reducing atmosphere and with a residence time of 1 second to about 30 minutes at a temperature within the range of from about 200.degree. C. to about 1000.degree. C., (d) separately recovering the condensable vapors as liquids and the noncondensable gases in a condition suitable for use as chemical feedstocks or as hydrocarbon fuels.Type: GrantFiled: April 9, 1980Date of Patent: January 26, 1982Assignee: Standard Oil Company (Indiana)Inventors: Thomas A. Weil, Peter M. Dzadzic, Chien-Cheng J. Shih, Michael C. Price
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Patent number: 4309270Abstract: A technique is described which enables agglomerating coals (caking coals) to be flash pyrolyzed in a fluidized-bed reactor without agglomerates forming in the fluidized-bed. The technique requires the inert particles of the fluidized-bed to be coarser and denser than the particulate coal being pyrolyzed. With this arrangement the momentum of the inert particles in the fluidized-bed is believed to destroy the agglomerates as they form.Type: GrantFiled: June 12, 1979Date of Patent: January 5, 1982Assignee: Commonwealth Scientific and Industrial Research OrganizationInventors: Ralph J. Tyler, Ian W. Smith, James H. Edwards
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Patent number: 4308103Abstract: Apparatus for effecting the pyrolytic treatment of solid carbonizable materials, such as coal, shredded scrap-tires, comminuted municipal waste, sawdust and wood shavings, and the like. The treatment takes place in a cylindrical, horizontally-disposed reactor vessel including a material conveying device which transports the carbonizable materials through the vessel as a moving bed. A heating chamber is arranged coaxially around the reactor vessel and is configured as an annulus of substantially uniform inner diameter and of decreasing outer dimension from its forward end adjacent the materials outlet end of the reaction vessel, to its rearward end, adjacent the materials inlet end of such vessel. The material passing through the reaction vessel is subject to an indirect heat transfer relationship with a burning air-fuel mixture spirally swirling within the heating chamber and moving in a direction generally counter-current to the material passing through the reaction vessel.Type: GrantFiled: June 2, 1980Date of Patent: December 29, 1981Assignee: Energy Recovery Research Group, Inc.Inventor: Franz Rotter
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Patent number: 4308411Abstract: Organic waste is converted to hydrocarbons by a process which comprises the steps of:(a) pyrolyzing the organic waste to form a mixture including oxygenated hydrocarbons, and(b) contacting the oxygenated hydrocarbons with a crystalline aluminosilicate zeolite to form hydrocarbons.Type: GrantFiled: August 28, 1980Date of Patent: December 29, 1981Assignee: Occidental Research CorporationInventor: Theodore C. Frankiewicz
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Patent number: 4303477Abstract: The emission of halogens and sulfur dioxide and the formation of water-soluble compounds of heavy metals are suppressed in the pyrolysis of waste in a carbonization zone at a temperature in the range from 300.degree. to 600.degree. C. by adding a fine-grained basic material to the waste prior to completion of the pyrolysis of the waste in the carbonization zone.Type: GrantFiled: June 9, 1980Date of Patent: December 1, 1981Assignee: Babcock Krauss-Maffei Industrieanlagen GmbHInventors: Rudiger Schmidt, Franz Steininger
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Patent number: 4301137Abstract: The gas stream obtained from the pyrolysis of solid organic wastes and containing halogens, particularly chlorine in the form of the corresponding hydrogen halide is processed to obtain a halide free pyrolytic oil. The gas stream after solids removal is contacted with a solid metal halide acceptor above the dew point of pyrolyzate to form the corresponding metal halide which may be discarded. As an alternative the metal halide can be treated to release the hydrogen halide which is recovered as an acid and the acceptor regenerated for recycle. The preferred acceptor is calcium carbonate.Type: GrantFiled: May 7, 1979Date of Patent: November 17, 1981Assignee: Occidental Research CorporationInventors: Kenneth A. Williams, Hans F. Bauer
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Patent number: 4300915Abstract: A process for the pyrolysis of refuse of all kinds wherein the refuse is subjected to carbonization to produce solid residues and raw carbonization gases, the residues and gases are separated, the gases are divided into two parts, one part of the gases is completely burned to produce hot flue gases, the flue gases are mixed with the second part of the raw carbonization gases, the mixture of gases is cracked in a reactor, and the cracked gases are cooled.Type: GrantFiled: April 3, 1980Date of Patent: November 17, 1981Assignee: Babcock Krauss-MaffeiInventors: Rudiger Schmidt, Franz Steininger, Klaus Hillekamp
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Patent number: 4300985Abstract: Rubber-base wastes, such as tires and industrial rubber wastes, may be disposed of, without pretreatment thereof, by contacting the wastes with molten metallurgical slag on the site of the production of the slag. The molten slag causes flash thermal decomposition of the rubber-base wastes in a non-polluting manner. The solidified slag products obtained are useful for soil improvement or construction work consolidation.Type: GrantFiled: February 20, 1980Date of Patent: November 17, 1981Inventor: Francis Gagneraud
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Patent number: 4287025Abstract: The yield of good-quality bodies consisting of vitreous carbon is increased to substantially 100% when the pyrolysis is performed in a reaction vessel in which a collecting container or a collecting disc for the condensable volatile decomposition products which is open at its upper side is arranged above the polymeric substances to be pyrolized. The collecting disc divides the interior of the reaction vessel into two parts, a passage for gases remaining between the upper part and the lower part. During the pyrolysis, a spatial temperature distribution is adjusted in the reaction vessel which results in a pulsating evaporation and condensation of the decomposition products, so that the decomposition products are completely removed.Type: GrantFiled: October 5, 1979Date of Patent: September 1, 1981Assignee: U.S. Philips CorporationInventor: Bernhard Lersmacher
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Patent number: 4284616Abstract: The invention is a process for economically recovering carbon black, oil and fuel gas from used tires. Used tires are physically fragmented. The fragments are pyrolized at slightly subatmospheric pressure in a reactor while process char is being recycled to increase heat transfer and avoid coke on heat transfer surfaces. Entrained char is separated from the vapor phase products of the pyrolysis, and the vapor phase products of the pyrolysis are then fractionated into oil and fuel gas. A preferred embodiment condenses reactor vapors in two stages at two temperature levels to separate dust from an oil-dust mixture, without water in the first stage and light oil in the second stage. The fuel gas can be compressed and burnt to provide process heat. The entrained char dust and some heavy oil is returned to the reactor. Solid phase pyrolysis products are stripped of trash and milled to carbon black.Type: GrantFiled: January 15, 1979Date of Patent: August 18, 1981Assignee: Intenco, Inc.Inventors: Age Solbakken, Fred P. Apffel, Sam P. Robinson, Bobby L. Hayes
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Patent number: 4280879Abstract: A dry thermal processor for recovering hydrocarbons from oil sand solids comprises concentric, radially spaced, horizontal inner and outer tubular members connected for rotation together. The inner member provides a substantially open preheat zone and vaporization zone while the outer member provides, in the annular space between the tubular members, a substantially open combustion zone and heat transfer zone. The ends of the outer member are sealed by stationary feed end and product end structures. Advance means move the oil sand solids from the feed end structure through the preheat and vaporization zones to the product end structure and back through the combustion and heat transfer zones. Rotation of the inner member causes size reduction of the oil sand feed in the preheat zone, and oversize is discharged directly into the annular space at the second end of the preheat zone.Type: GrantFiled: November 6, 1979Date of Patent: July 28, 1981Assignee: Alberta Oil Sands Technology and Research AuthorityInventor: William Taciuk
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Patent number: 4273643Abstract: A process for the production of synthetic crude oil, alcohols, semi-coke (chars), and cokes which are obtained during the production of low temperature coal tars and are derived by careful temperature control during the carbonization of various carbon containing material such as bituminous coals, peat, lignite, trash, and other solid wastes.Type: GrantFiled: October 1, 1979Date of Patent: June 16, 1981Assignee: Bennett Engineering Inc.Inventor: Harold L. Bennett
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Patent number: 4272322Abstract: A method of manufacturing charcoal comprising the steps of mixing at least one kind of material selected from the group including coffee pulps, almond husks, orange peelings, walnut shells and bean jam waste etc. with paper sludge, molding the resultant mixture in any desired configuration, and then allowing the resultant moldings to subject to dry distillation at a temperature of about 300.degree. to 600.degree. C.An apparatus for carrying out the abovementioned method comprising a double-walled housing including an inner wall and an outer wall the space between the inner and outer walls being filled with water, the space surrounded by the double-walled housing being divided by a partition wall extending to a predetermined height from the base of the housing into a combustion chamber and a carbonization chamber.Type: GrantFiled: April 3, 1979Date of Patent: June 9, 1981Inventor: Masahiro Kobayashi
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Patent number: 4271326Abstract: A method of treating organic waste involves slurrying the organic waste in water with a member selected from the group consisting of potassium carbonate, ammonium nitrate and ammonium nitrite. The slurry is heated to a temperature of 100.degree. C. to 420.degree. C. After heating, volatile hydrocarbons and organic compounds are distilled therefrom. The volatile hydrocarbons are collected and the residue from the distillation is recovered.Type: GrantFiled: September 24, 1979Date of Patent: June 2, 1981Inventor: Ronald M. Mego
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Patent number: 4264414Abstract: A method of reducing the carbonization pressure in the coking of coal is provided which comprises randomly dispersing flakes through the coal, said flakes formed of a material that does not pass through a plastic phase such as pressed sawdust wherein the flakes have a thickness of between about 1/8" and about 3/4" and a length and width of between about 1" and about 5".Type: GrantFiled: August 10, 1979Date of Patent: April 28, 1981Assignee: Koppers Company, Inc.Inventor: Michael Perch
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Patent number: 4263125Abstract: A process and apparatus for production of synthetic hydrocarbon fuels from peat providing wide variation of the composite proportion of liquid-gas output while maintaining high overall carbon conversion to useful fuel. The process and apparatus utilizes three process stages in a single vessel providing functions of drying wet peat, provisions for addition of both wet and dry peat to a hydropyrolysis zone and gasification of the peat char.Type: GrantFiled: July 20, 1979Date of Patent: April 21, 1981Assignee: Institute of Gas TechnologyInventors: Sanford A. Weil, Dharamvir Punwani, William W. Bodle
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Patent number: 4261795Abstract: This disclosure is directed to an economical system for the pyrolysis of municipal solid waste to recover valuable by-products while reducing the putrefaction and bulk of the residue requiring disposal. Prior to this treatment, the solid waste has been processed to remove most of the metallic components, and shredded, which steps are not part of the invention disclosed. The pyrolysis and by-product recovery technology is complicated by (a) the inherent variability of the chemical and physical characteristics of the shredded solid waste as received at the pyrolysis plant and (b) the relatively low heat value of said waste as thus received.Type: GrantFiled: November 16, 1979Date of Patent: April 14, 1981Inventor: Bertram B. Reilly
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Patent number: 4260473Abstract: A process for producing organic liquid product from solid organic waste. The process comprises pyrolyzing the solid organic waste to produce pyrolysis vapors and solid pyrolysis residue. The solid residue is separated from the pyrolysis vapors leaving entrained particulate matter in the vapor. At least a portion of the pyrolysis vapor is condensed for producing pyrolysis liquid containing entrained particulate matter. The pyrolysis liquid is centrifuged producing a light fraction containing entrained particulate matter, a middle fraction substantially free of particulate matter and a heavy fraction containing entrained particulate matter. The middle fraction is recovered as organic liquid product substantially free of entrained particulate matter. The light fraction and heavy fraction are mixed and filtered. The liquid filtrate produced is distilled for producing additional organic liquid product.Type: GrantFiled: May 3, 1979Date of Patent: April 7, 1981Assignee: Occidental Research CorporationInventor: Hans F. Bauer
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Patent number: 4250158Abstract: The invention is a process for economically recovering carbon black, tar, oil and fuel gas from used tires. Used tires are physically sliced and fragmented. The fragments are pyrolized in an oxygen-limited, hydrocarbon vapor at subatmospheric pressure while being refluxed with process tar condensate. Vapor phase products of the pyrolysis are fractionated into tar, oil and fuel gas. The fuel gas can be compressed and burnt to provide process heat. Solid phase pyrolysis products are stripped of trash and milled to carbon black in an air swept roller mill. Carbon black is mechanically separated from the effluent air stream of the roller mill and formed into pellets that are dried in a series multi-stage fluid bed dryer.Type: GrantFiled: February 15, 1978Date of Patent: February 10, 1981Assignee: Intenco, Inc.Inventors: Age Solbakken, Fred P. Apffel, Sam P. Robinson, Bobby L. Hayes
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Patent number: 4246001Abstract: Latex-rich plants such as Guayule or extracts thereof pyrolyzed in an inert nitrogen atmosphere in inorganic salt melts such as a LiCl/KCl eutectic at a temperature of about 500.degree. C. yield over 60% of a highly aromatic, combustible hydrocarbon oil suitable for use as a synthetic liquid fuel.Type: GrantFiled: April 27, 1978Date of Patent: January 20, 1981Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventor: Albert J. Bauman
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Patent number: 4243489Abstract: A solid carbonaceous material is pyrolyzed in a descending flow pyrolysis reactor in the presence of a particulate source of heat to yield a particulate carbon containing solid residue. The particulate source of heat is obtained by educting with a gaseous source of oxygen the particulate carbon containing solid residue from a fluidized bed into a first combustion zone coupled to a second combustion zone. A source of oxygen is introduced into the second combustion zone to oxidize carbon monoxide formed in the first combustion zone to heat the solid residue to the temperature of the particulate source of heat.Type: GrantFiled: November 13, 1978Date of Patent: January 6, 1981Assignee: Occidental Petroleum Corp.Inventor: Norman W. Green
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Patent number: 4239599Abstract: A mixture of a high density particulate inorganic heat source and a low density particulate carbon containing residue formed in the pyrolysis of a solid waste is passed along with some entrained pyrolytic oil to a fluidized bed of particles, where a gas is injected to strip the entrained pyrolytic oil from the particles, and a mixture of a high density particulate heat source and low density particulate carbon containing solid residue of pyrolysis are separated from an intermediate point of the fluidized bed and passed to a decarbonization zone, where the carbon containing solid residue of pyrolysis is decarbonized to form a high density particulate inorganic solid heat source for use as the source of heat in the pyrolysis of organic solid waste.Type: GrantFiled: August 23, 1978Date of Patent: December 16, 1980Assignee: Occidental Petroleum CorporationInventor: Charles K. Choi
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Patent number: 4235676Abstract: An elongated tube is maintained at a temperature of about 1100.degree. F. throughout its length. Organic waste material such as shredded rubber automobile tires or industrial plastic waste or residential trash which preferably has metal and inorganic matter removed therefrom, is moved through the tube at a uniform rate of speed in the absence of air and/or oxygen, with the material being churned or tumbled as by means of a screw conveyor. The vapors and gases which are produced and/or liberated within the tube are quickly removed therefrom by means of a vacuum of from about four inches to about six inches of mercury, with the vapors being condensed and the gases separated therefrom. The char or residue which is a black, powdery, carbon-type material is also recovered.Type: GrantFiled: September 16, 1977Date of Patent: November 25, 1980Assignee: Deco Industries, Inc.Inventor: R. William Chambers
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Patent number: 4235675Abstract: A pyrolysis reactor is operated by passing the waste products into a reactor provided with a heating unit; after completion of the pyrolysis passing the gaseous and vaporous products including suspended solids resulting from said pyrolysis into a partial oxidation zone wherein preheated air is added in an amount insufficient for complete combustion but sufficient to cause the exiting gas to have a temperature of at least 1000.degree., thereby causing decomposition of substantially all hydrocarbons present; then passing the partially oxidized gas through separate heat exchange means in contact, successively, with (1) the purified gas, (2) the air to be fed into the heating unit of the reactor and (3) with the air for said partial oxidation; then subjecting the partial oxidation gas to a purification; introducing air separately to said oxidation zone and heating means of the reactor; and passing the purified gas together with part of said added air into the heating unit of the reactor.Type: GrantFiled: May 22, 1978Date of Patent: November 25, 1980Assignee: Ealther & Cie AktiengesellschaftInventor: Horst Bechthold
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Patent number: 4234388Abstract: The gas stream obtained from the pyrolysis of solid organic wastes and containing chlorine in the form of hydrogen chloride is processed to obtain a substantially chlorine free pyrolytic oil.The gas stream is first contacted with a hydrocarbon immiscible with the pyrolytic oils to quench the gas stream and reduce the gas stream temperature close to the dew point of water. This forms a two phase condensate of the quench hydrocarbon and pyrolytic oil. The phases are separated, the pyrolytic oil recovered and the hydrocarbon recycled as the quench. The resultant gas stream is then treated for removal of hydrogen chloride from the gas stream for disposal or recovery of hydrochloric acid.Type: GrantFiled: August 10, 1979Date of Patent: November 18, 1980Assignee: Occidental Petroleum CorporationInventors: George M. Mallan, George T. Preston
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Patent number: 4230602Abstract: A single-pass, continuous process converts organic feedstocks into activated carbonaceous products having high surface area values. The introduction of air and steam into the bed of material at selected locations, and at controlled rates, enables the economic, dependable and convenient production of such products, while maximizing the efficiency of energy utilization.Type: GrantFiled: October 12, 1979Date of Patent: October 28, 1980Assignee: American Can CompanyInventors: Mack D. Bowen, Kenneth R. Purdy
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Patent number: 4222823Abstract: The processing of liquid chlorinated hydrocarbon residues, which may contain solids and which form viscous to solid deposits during the separation of readily boiling components, into(1) distillable organic components,(2) hydrogen chloride, and(3) solid matter with a low chlorine content,is improved by gently concentrating the residues in a first step and, in a second step, decomposing the residues at temperatures of about 200.degree.-400.degree. C., preferably 270.degree.-330.degree. C., with a continuous separation of the vapor phase components from the solid components.Type: GrantFiled: September 3, 1976Date of Patent: September 16, 1980Assignee: Chemische Werke Huis AktiengesellschaftInventors: Reinhold Wickbold, Wolfgang H. E. Muller, Hans Regner, Gunter Scharein, Franz Langheim, Rolf Ruthemeier, Karl-Hans Simmrock, Rolf Baumann
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Patent number: 4210491Abstract: An improved method and apparatus for converting a substance containing organic matter into hydrocarbon vapors and solids residue by feeding the substance into the upstream portion of a substantially cylindrical retort having a substantially horizontal longitudinal axis, substantially conveying the substance through the retort toward the downstream portion thereof, heating the retort by means of a fluidized bed of heated particles to a sufficient temperature to convert the substance into hydrocarbon vapors and solids residue and removing the hydrocarbon vapors and solids residue from the retort.Type: GrantFiled: October 16, 1978Date of Patent: July 1, 1980Assignee: Tosco CorporationInventor: Bernard L. Schulman
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Patent number: 4208245Abstract: The present invention discloses a process of pretreating a waste black liquor which results from the pulping of various vegetative fibers and wherein the pulping liquor contains as its active pulping ingredient sodium and sulfur with the pretreatment taking place prior to the subjecting of the waste black liquor to a hydropyrolysis reaction. The method and the materials used in the pretreatment are derived from the reaction products resulting from the hydropyrolysis reaction. The pretreatment serves to enable one to regenerate the inorganic chemical values a pulping liquor in an easy and economical manner and the pretreatment, also, serves to appropriately adjust the physical and chemical characteristics of the char produced in the hydropyrolysis reaction. This is accomplished primarily by utilizing the products resulting from the hydropyrolysis reaction.Type: GrantFiled: September 7, 1978Date of Patent: June 17, 1980Assignee: St. Regis Paper CompanyInventors: John J. Watkins, Winfried G. Timpe, deceased
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Patent number: 4208252Abstract: An apparatus for treatment of rubber and plastic wastes, comprising in series an extruder for heating and melting rubber and plastic wastes to extrude the molten wastes, a decomposing section for heating the molten wastes to prepare decomposed products while optionally separating residues therefrom, a dry-distilling section for gasifying the decomposed products by dry-distillation, and a cooling section for cooling the dry-distilled products to separate gaseous materials from liquid materials.Type: GrantFiled: May 4, 1976Date of Patent: June 17, 1980Assignee: Sumitomo Chemical Industries, Ltd.Inventors: Masaaki Yoshida, Masao Watanabe, Kimio Tohma, Mitsuhiko Noda
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Patent number: 4206186Abstract: Organic refuse is pyrolyzed to form disposable solids and gas. The gas is washed at a temperature well above 100.degree. C. with wash oil, which is recirculated. Spent wash oil is pyrolyzed with contaminants and further organic refuse. The washed gas is filtered through sorption means to remove acid and or other noxious gases therefrom before being cooled well below 100.degree. C. to condense water vapor and other constituents having boiling points within the range of from, e.g., 75.degree. to 150.degree. C. After separating the resulting condensate, thus-purified combustion gas is used, e.g., as a fuel source for the organic-refuse pyrolysis.Type: GrantFiled: January 13, 1978Date of Patent: June 3, 1980Assignee: Holter Gesellschaft fur Patentverwertungsverfahren mbHInventors: Heinz Holter, Heinz Gresch, Heinrich Igelbuscher
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Patent number: 4204906Abstract: Equipment and method for treating solid waste in which a substantially nonoxidizing atmosphere is provided through which the shredded solid waste falls under gravity, unsupported and non-contacted, to prevent fusion of the plastics with each other, with other materials in the solid waste, or with the walls or components in the treating equipment. The unique atmosphere also allows a high treatment temperature to accelerate the debonding of fibrous combustible matter and fusion of the plastics into dense particles for substantially complete separation and recovery of plastics from the lighter fibrous but non-fusible combustible matter through gas classification during the fall. This same atmosphere also produces a clean, substantially, homogeneous, storageable and highly combustible fuel derived from the fibrous combustible matter.Type: GrantFiled: August 25, 1977Date of Patent: May 27, 1980Inventor: Hsin Liu
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Patent number: 4203804Abstract: A fluidized bed reactor for the pyrolysis of pieces of rubber or the like, especially old tires the reactor comprising a container at the lower part of which there is discharge device for non-volatile pyrolysis products; gas blowing nozzles arranged in a zone above the discharge device for supplying a fluidizing gas and for producing a fluidized bed from material such as sand or alumina added to the reactor; preferably a heating device, especially one comprising heating tubes extending across the container; a gas outlet disposed in the zone above the fluidized bed; and supply means for conveying pieces of material to be pyrolized to the container; this apparatus is characterized by the fact that the gas blowing nozzles are arranged to direct the gas downwardly, that at least one group of nozzles are arranged in a common horizontal plane, and that the material supply device is such that its dimensions are comparable with the cross-sectional surface of the fluidized bed.Type: GrantFiled: December 22, 1977Date of Patent: May 20, 1980Assignee: Carl Robert Eckelmann AGInventors: Jorg Janning, Walter Kaminsky, Hansjorg Sinn, Stanislav Tysarcyk
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Patent number: 4175211Abstract: A process for converting relatively ash-free solid polymeric wastes to more valuable liquid, solid, and gaseous products which comprises mixing rubber and/or plastic wastes at high temperatures in a refractory petroleum stream and catalytically cracking the mixture.Type: GrantFiled: March 1, 1978Date of Patent: November 20, 1979Assignee: Mobil Oil CorporationInventors: Nai Y. Chen, Tsoung-Yuan Yan
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Patent number: 4162959Abstract: In a continuous process for recovery of values from a solid carbonaceous material, the carbonaceous material is pyrolyzed in the presence of a particulate source of heat to yield a particulate carbon containing residue of pyrolysis and volatilized hydrocarbons while simultaneously the volatilized hydrocarbons are hydrogenated. The particulate source of heat is formed by oxidizing carbon in the solid residue to heat the particles. Hydrogen for hydrogenation is obtained by reacting at least a portion of the hot particulate carbon containing residue of pyrolysis with steam prior to feeding the hot particulate residue to the pyrolysis reaction zone. Steam and/or carbon dioxide can be introduced into the pyrolysis reaction zone to interact with carbon containing residue contained therein. The particulate source of heat can be introduced to the pyrolysis reaction zone over an overflow weir.Type: GrantFiled: December 7, 1977Date of Patent: July 31, 1979Assignee: Occidental Petroleum CorporationInventor: Kandaswamy Duraiswamy
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Patent number: 4155832Abstract: Coal or other solid carbonaceous material is contacted with an organic solvent containing both hydrogen and a transition metal catalyst in solution to hydrogenate unsaturated bonds within the carbonaceous material. This benefaction step permits subsequent pyrolysis or hydrogenolysis of the carbonaceous fuel to form gaseous and liquid hydrocarbon products of increased yield and quality.Type: GrantFiled: December 23, 1977Date of Patent: May 22, 1979Assignee: The United States of America as represented by the United States Department of EnergyInventors: John L. Cox, Wayne A. Wilcox
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Patent number: 4153420Abstract: A process for the wet carbonizing of peat, wherein the peat is diluted and screened to become a raw peat suspension in a suspension preparing apparatus, the peat suspension thus obtained is preheated in series-connected heat exchangers and in a preheating tower, the preheated suspension is wet carbonized in a reactor into which steam is introduced from a steam boiler, the wet carbonized peat suspension is cooled in the preheating tower, mechanically dewatered in a dewatering apparatus and dried in a drying apparatus with the aid of hot drying gas, the exhaust gases from the boiler being employed as drying gas in the drying apparatus and the dust and water vapor containing exhaust gas emerging from the drying apparatus being purified and cooled in a wet separator, wherein part of the water vapor in the exhaust gas condenses and wherein there is used as washing water, polluted water coming from the dewatering apparatus and being cooled by heat exchange with the raw peat suspension in the heat exchanger, and theType: GrantFiled: March 27, 1978Date of Patent: May 8, 1979Assignee: Ra Shipping Ltd. OyInventor: Bertel Myreen
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Patent number: 4153514Abstract: A process for the recovery of chemical values from waste solids, wherein shredded waste solids are intermixed with hot char and a carrier gas in turbulent flow and passed through a pyrolysis zone under turbulent conditions at a temperature ranging from about 300.degree. F. to about 2000.degree. F., with zone residence time of under 10 seconds, with subsequent segregation and recovery of volatilized organic chemical values, char and inorganic chemical values therefrom.Type: GrantFiled: May 17, 1976Date of Patent: May 8, 1979Assignee: Occidental Petroleum CorporationInventors: Donald E. Garrett, George M. Mallan
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Patent number: 4151044Abstract: Solid carbonaceous materials are pyrolyzed by introducing a low velocity stream of carbonaceous material into a cyclone reactor-separator and introducing a low velocity stream of a particulate source of heat into the cyclone reactor-separator at an angle inclined toward the path of travel of the carbonaceous material. A high velocity stream of the particulate source of heat is introduced into the cyclone reactor-separator along the inner surface of the separator to prevent carbonaceous material from caking along the walls of the separator. The velocity of the high velocity stream is at least about 50 feet per second greater than the velocity of both low velocity streams. The cyclone reactor separator induces separation of solids consisting of a particulate carbon containing solid residue of pyrolysis and particulate heat source from a vapor stream which contains hydrocarbon products of pyrolysis.Type: GrantFiled: January 23, 1978Date of Patent: April 24, 1979Assignee: Occidental Research CorporationInventor: Charles K. Choi
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Patent number: 4147593Abstract: Essentially carbon free inorganic particles formed from the decarbonization of a carbon containing solid residue of pyrolysis of comminuted organic solid waste is employed as the prime heat source for the pyrolysis of the comminuted organic solid waste.Type: GrantFiled: March 10, 1977Date of Patent: April 3, 1979Assignee: Occidental Petroleum CorporationInventors: Robert W. Frischmuth, Allan Sass
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Patent number: 4145274Abstract: In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source fed over an overflow weir to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue.Type: GrantFiled: May 5, 1977Date of Patent: March 20, 1979Assignee: Occidental Petroleum CorporationInventors: Norman W. Green, Kandaswamy Duraiswamy, Robert E. Lumpkin, Bruce L. Winter
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Patent number: 4145256Abstract: A carbonaceous residue or char having novel properties is produced from particulate agricultural waste material, such as peanut shells, which upon heating exhibits an exothermic decomposition into an off gas component and a solid component in which the off gas component is more highly reactive to oxygen than is the solid component. By introducing air into the reaction zone whereat the decomposition is effected and controlling the amount of air so introduced such that not all of the off gas component may be oxidized, the preferential reaction of the air with the off gas component will protect the solid component from any significant oxidation while at the same time it will elevate the temperature in the reaction zone sufficiently to effect substantially complete decomposition of the material so that the recovered product is of very high carbon content. At the same time, a temperature gradient is established in the reaction zone which will allow some of the vapor component of the decomposition (i.e.Type: GrantFiled: December 2, 1976Date of Patent: March 20, 1979Assignee: Georgia Tech Research InstituteInventor: Mack D. Bowen
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Patent number: 4141794Abstract: A carbonaceous material is pyrolyzed by introducing the carbonaceous material to a fast fluidized bed contained by a perforated wall and introducing a particulate source of heat through the perforations of the wall at an angle inclined to the path of travel of the carbonaceous material. The radially introduced particulate source of heat prevents carbonaceous material from caking on the walls of the bed.Type: GrantFiled: September 19, 1977Date of Patent: February 27, 1979Assignee: Occidental Petroleum CorporationInventor: Charles K. Choi
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Patent number: 4135968Abstract: A process of significantly increasing the capacity of and decreasing the pollution from an existing recovery boiler. The spent liquor is concentrated to 55 to 65 weight % solids and divided into two portions. One portion, containing 10 to 65 weight % of the solids is pyrolyzed, reducing the original fuel value of that portion by 25 to 70%. The remaining carboniferous char and inorganic material is carried to the recovery furnace. The other portion, containing the remainder of the solids, is carried directly to the furnace. The two portions may be combined prior to entering the furnace. In the latter case, the solids content of the combined portion should not be greater than 80 weight %.Type: GrantFiled: January 31, 1977Date of Patent: January 23, 1979Assignee: Weyerhaeuser CompanyInventor: Gerrit G. Dehaas
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Patent number: 4135983Abstract: Raw material coal for coke production having improved coking property is readily obtainable by a simple step of blending raw material coal having poor coking property with a highly aromatic bituminous substance obtained by heat-treating hydrocarbons.Type: GrantFiled: December 20, 1974Date of Patent: January 23, 1979Assignees: Kureha Kagaku Kogyo Kabushiki Kaisha, Sumikin Coke Co., Ltd.Inventors: Yoshio Kiritani, Michio Tsuyuguchi
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Patent number: 4129420Abstract: A process for converting cellulosic materials, including waste cellulosic materials, into a useful, low-sulfur and low-ash fuel by subjecting the cellulosic feed material to an autoclaving treatment at a controlled elevated temperature and controlled high pressure for a period of time to convert the moisture and a portion of the organic constituents therein to a gaseous phase and to effect a controlled thermal restructing of the chemical structure thereof, producing a solid carbonaceous or coke-like product and a by-product fuel gas. It is further contemplated that the low-sulfur coke product can be comminuted to a desired particle size range and admixed with high-sulfur fuel oils, providing a blended liquid slurry fuel of an acceptable sulfur content.Type: GrantFiled: September 7, 1977Date of Patent: December 12, 1978Inventor: Edward Koppelman
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Patent number: 4125578Abstract: Vulcanized rubber is reclaimed by treating pieces of the rubber to render a surface layer of each piece plastic while the inner core of the piece remains non-plastic. A chemical reagent can be used in the treatment, but it is preferred to render the surface layers of the rubber pieces plastic by a heat treatment which involves direct exposure of the pieces of rubber to either a flame or a heated gas. In a preferred embodiment of the invention vulcanized rubber pieces are dropped under gravity into a flame so that any attached textile residues are burnt away simultaneously with the plasticizing of the surface layers of the pieces, and the heated pieces then enter a stream of cold air which quenches the heat treatment.Vulcanized rubber articles made from the rubber reclaimed by the method of the invention have improved properties as compared with articles made by the conventional methods of reusing vulcanized rubber.Type: GrantFiled: June 1, 1977Date of Patent: November 14, 1978Assignee: Setech International LimitedInventor: Derek W. Sear
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Patent number: 4123332Abstract: Process and apparatus for treating a comminuted solid carbonizable material, such as comminuted municipal waste; sawdust, granulated coal, shredded tires and the like wherein the material is caused to be pyrolyzed in a horizontally disposed elongated reaction zone essentially free of any oxygen containing gases at ambient pressure and at a temperature of from 400.degree. C. to 900.degree. C. The material is passed through the reaction zone by paddle-like impellers mounted on a shaft while being subject to an indirect heat transfer relationship via a burning air fuel mixture spirally swirling within a heating zone about the reaction zone and the mixture being withdrawn from a lower portion of the heating zone. During pyrolysis, the material is chemically changed into valuable gaseous, liquid and solid products.Type: GrantFiled: September 6, 1977Date of Patent: October 31, 1978Assignee: Energy Recovery Research Group, Inc.Inventor: Franz Rotter
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Patent number: 4122036Abstract: A method of pyrolyzing sewage sludge to transform the same into activated carbon, with the combustible pyrogas and volatile liquids included therewith that arise from the pyrolysis operation being burned to sustain the transformation operation. A first portion of the hot activated carbon resulting from the operation is mixed with the wet sewage sludge to provide a dry sludge mixture that is subsequently subjected to the pyrolyzing operation. Water vapor that discharges as the hot activated carbon is mixed with the wet sewage sludge is heated by the burning of the pyrogas and transformed to steam. The resulting steam is in contact with the dry mixture during the pyrolyzing operation, and as a result the dry mixture is transformed to activated carbon. A second portion of the resulting activated carbon is separated from the first portion thereof, with this second portion being available for use apart from the method.Type: GrantFiled: January 7, 1977Date of Patent: October 24, 1978Assignee: Waterfront N.V.Inventor: Frederick Michael Lewis
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Patent number: 4118281Abstract: Solid organic wastes are slurried with hot coker recycle feed or fresh petroleum feedstocks at temperatures within the range from about 300.degree. to 1000.degree. F and the resulting mixture is coked to produce gas, oil, and coke. The oil can be used as clean liquid fuel, but preferably it is used as catalytic craker feed since it is a particularly suitable cracking stock and produces high yields of gasoline. This process affords a low-cost waste disposal method by a process compatible with current petroleum refining technology.Type: GrantFiled: April 15, 1977Date of Patent: October 3, 1978Assignee: Mobil Oil CorporationInventor: Tsoung-Yuan Yan