Nitrogen Compounds Patents (Class 204/177)
  • Patent number: 10475625
    Abstract: A method of decreasing a water contact angle and/or increasing a surface energy of a liquid is disclosed herein, the method comprising exposing the liquid to a plasma treatment. Further disclosed is a plasma-treated liquid exhibiting a decreased water contact angle and/or increased surface energy, compared to the water contact angle and/or surface energy, respectively, of a non-treated corresponding liquid. Methods for combining a first liquid and a second liquid, or for enhancing an adhesion between a liquid and a surface of another substance, the methods comprising exposing a liquid to plasma treatment, are further disclose herein, as well as a method of predicting an apparent contact angle of a liquid droplet on a surface of a substance.
    Type: Grant
    Filed: August 6, 2015
    Date of Patent: November 12, 2019
    Assignee: Ariel-University Research and Development Company Ltd.
    Inventors: Edward Bormashenko, Yelena Bormashenko
  • Patent number: 10427128
    Abstract: A plasma gate device comprises a housing, a gas inlet, first and second dielectrics, and first, second, and third electrodes. The housing includes an internal reactor chamber. The gas inlet receives a source gas that flows to the reactor chamber. The first and second dielectrics are spaced apart from one another, with each dielectric including an upper surface and a lower surface. The two dielectrics are oriented such that the lower surface of the first dielectric faces the upper surface of the second dielectric. The first and second dielectrics form boundaries of the reactor chamber. The first electrode receives a first electric voltage. The second electrode receives a second electric voltage. The first and second electric voltages in combination generate an electric field in the reactor chamber through which the source gas flows creating a positive ion plasma and a cloud of electrons. The third electrode attracts the electrons.
    Type: Grant
    Filed: December 31, 2018
    Date of Patent: October 1, 2019
    Assignee: Pear Labs LLC
    Inventor: Christopher D. Hruska
  • Patent number: 10204765
    Abstract: A plasma gate device comprises a housing, a gas inlet, first and second dielectrics, and first, second, and third electrodes. The housing includes an internal reactor chamber. The gas inlet receives a source gas that flows to the reactor chamber. The first and second dielectrics are spaced apart from one another, with each dielectric including an upper surface and a lower surface. The two dielectrics are oriented such that the lower surface of the first dielectric faces the upper surface of the second dielectric. The first and second dielectrics form boundaries of the reactor chamber. The first electrode receives a first electric voltage. The second electrode receives a second electric voltage. The first and second electric voltages in combination generate an electric field in the reactor chamber through which the source gas flows creating a positive ion plasma and a cloud of electrons. The third electrode attracts the electrons.
    Type: Grant
    Filed: May 8, 2018
    Date of Patent: February 12, 2019
    Assignee: Pear Labs LLC
    Inventor: Christopher D. Hruska
  • Publication number: 20140275629
    Abstract: A reaction chamber includes: a catalyst that, in use, is wired to a power source in electrical short circuit configuration with a current limiting circuit in the power supply; and a reaction volume in which the catalyst is disposed and wherein reactants are introduced while a current is introduced across the short circuited catalyst. The reaction chamber may also be a part of system that includes the reactant feedstocks and a power supply. In operation, a plurality of reactant feedstocks are provided to a reaction volume within the reactor. The catalyst electrically activated through the short circuit to reacting the reactant feedstocks in the presence of the electrically activated catalyst. The yield product of the reactions is then collected.
    Type: Application
    Filed: March 13, 2014
    Publication date: September 18, 2014
    Inventors: Ed Ite Chen, Tara Cronin
  • Patent number: 8529855
    Abstract: A method for removing gas components SOx, NOx, and CO2 from a flue gas, comprises the steps of contacting the flue gas successively with first, second and third liquid mediums each of which provides a plasma containing reactive electrons or ions in an amount such that the gas molecules SOx, NOx, and CO2 are successively subjected to impingement of the electrons or ions in the respective plasma to enable the dissociation of the gas molecules SOx, NOx, and CO2 so as to remove SOx, NOx, and CO2 from the flue gas. A system for removing gas components SOx, NOx, and CO2 from a flue gas is also disclosed.
    Type: Grant
    Filed: May 26, 2010
    Date of Patent: September 10, 2013
    Assignee: Ecospec Global Technology Pte Ltd.
    Inventor: Hwee Hong Chew
  • Publication number: 20120273733
    Abstract: A plasma treatment has been used to modify the surface of BNNTs. In one example, the surface of the BNNT has been modified using ammonia plasma to include amine functional groups. Amine functionalization allows BNNTs to be soluble in chloroform, which had not been possible previously. Further functionalization of amine-functionalized BNNTs with thiol-terminated organic molecules has also been demonstrated. Gold nanoparticles have been self-assembled at the surface of both amine- and thiol-functionalized boron nitride Nanotubes (BNNTs) in solution. This approach constitutes a basis for the preparation of highly functionalized BNNTs and for their utilization as nanoscale templates for assembly and integration with other nanoscale materials.
    Type: Application
    Filed: June 19, 2012
    Publication date: November 1, 2012
    Applicant: The Regents of the University of California
    Inventors: Toby Sainsbury, Takashi Ikuno, Alexander K. Zettl
  • Publication number: 20120012453
    Abstract: The present invention relates to methods of production of chemical bonds and subsequent molecules by electrospray ionization and the design of an electrospray chemical synthesizer, for use in chemical synthesis and expedited organic chemical reactions.
    Type: Application
    Filed: January 15, 2010
    Publication date: January 19, 2012
    Applicant: CANAM BIORESEARCH INC.
    Inventor: Atiq Rehman
  • Publication number: 20110011212
    Abstract: A method for producing a cyanide including the steps of supplying a hydrocarbon and nitrogen source to an onsite plasma reactor and removing cyanide synthesised inside the onsite plasma reactor to thereby produce the cyanide is disclosed. Also disclosed is a method which includes a monitor for monitoring the cyanide requirement of an onsite cyanide utilising system and supplying the hydrocarbon and nitrogen source in accordance with the cyanide requirement. Additionally, a method for recovering, refining, purifying or treating a metal including the steps of monitoring a cyanide requirement of the method and supplying to the method in a just in time sequence a cyanide synthesised onsite to thereby recover, refine, purify or treat the metal is disclosed.
    Type: Application
    Filed: March 11, 2009
    Publication date: January 20, 2011
    Applicant: SYNERGEN MET LIMITED
    Inventor: Geoffrey Alexander Duckworth
  • Patent number: 7810319
    Abstract: An apparatus comprising an internal combustion engine, an exhaust system for conducting exhaust emitted by the engine, and a catalytic device associated with the exhaust system is disclosed, wherein the catalytic device comprises a catalytic conversion portion and a fuel cell portion disposed within an interior of the catalytic device, wherein the fuel cell portion comprises a first electrode and a second electrode configured to be in contact with exhaust gases in the interior of the catalytic device, the first electrode being disposed downstream of the second electrode in a direction of exhaust flow.
    Type: Grant
    Filed: February 14, 2006
    Date of Patent: October 12, 2010
    Assignee: Ford Global Technologies, LLC
    Inventors: Shane Elwart, James Kerns, Gopichandra Surnilla, David Bidner
  • Patent number: 7722813
    Abstract: A urea concentration identification device comprising a concentration identification sensor unit (2) and a support unit (4) attached at the bottom end thereof with this sensor unit and provided at the top end thereof with a mounting unit (4a) to a urea solution tank opening. The concentration identification sensor unit (2) has an indirectly-heated concentration detector and liquid temperature detector provided with metal fins (21c),(22c), respectively, for heat-exchanging with urea solution. The concentration identification sensor unit (2) is provided with a cover member (2d) that forms an opposite-ends-opened urea solution induction passage so as to surround the metal fins (21c), (22c).
    Type: Grant
    Filed: September 10, 2004
    Date of Patent: May 25, 2010
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Shinichi Inoue, Akiko Kubota, Takayuki Takahata
  • Publication number: 20090324930
    Abstract: An environmental coating system for silicon based substrates wherein a porous intermediate barrier layer having an elastic modulus of about 30 to 150 GPa is provided between a silicon metal containing bondcoat and a ceramic top environmental barrier layer.
    Type: Application
    Filed: June 25, 2008
    Publication date: December 31, 2009
    Applicant: UNITED TECHNOLOGIES CORPORATION
    Inventors: Sonia Tulyani, Tania Bhatia
  • Patent number: 7617671
    Abstract: A motor exhaust ozonator adapter is connected with the end of a motor vehicle exhaust pipe for receiving and passing exhaust gas. One arm of the adapter is connected with the end of the exhaust pipe and another arm of the adapter houses a powerful ozone light for ozonating intake air. The ozonated air thereby converts carbon monoxide to carbon dioxide and oxidizes other noxious chemicals therein.
    Type: Grant
    Filed: November 20, 2006
    Date of Patent: November 17, 2009
    Inventor: Richard Menelly
  • Patent number: 7600375
    Abstract: An apparatus comprising an internal combustion engine, an exhaust system for conducting exhaust emitted by the engine, and a catalytic device associated with the exhaust system is disclosed, wherein the catalytic device comprises a catalytic conversion portion and a fuel cell portion.
    Type: Grant
    Filed: February 14, 2006
    Date of Patent: October 13, 2009
    Assignee: Ford Global Technologies, LLC
    Inventors: Shane Elwart, James Kerns, Gopichandra Surnilla, David Bidner
  • Publication number: 20090184281
    Abstract: Nanotechnology methods for creating stoichiometric and non-stoichiometric substances with unusual combination of properties by lattice level composition engineering are described.
    Type: Application
    Filed: October 31, 2003
    Publication date: July 23, 2009
    Inventors: Tapesh Yadav, John Alexander
  • Patent number: 7541010
    Abstract: A method of making an exhaust treatment element includes washcoating a substrate with a slurry that includes a catalyst support material. At least some of the catalyst support material from the slurry may be transferred to the substrate, and silver metal (Ag) is dispersed within the catalyst support material.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: June 2, 2009
    Assignee: Caterpillar Inc.
    Inventors: Paul Worn Park, Virgil Raymond Hester, Christie Susan Ragle, Carrie L. Boyer
  • Publication number: 20090038953
    Abstract: A method for the electrochemical synthesis of dinitro compounds is disclosed. The method comprises using an anode to oxidize an inactive chemical mediator, such as a ferrocyanide (Fe(CN)6?4) ion, to an active chemical mediator or oxidizing agent, such as a ferricyanide (Fe(CN)6?3) ion, in the presence of a differential voltage. The oxidizing agent reacts with a nitro compound and a nitrite ion to form a geminal dinitro compound. The anode may continuously oxidize ferrocyanide to regenerate active ferricyanide, thus keeping sufficient amounts of ferricyanide available for reaction.
    Type: Application
    Filed: August 8, 2007
    Publication date: February 12, 2009
    Inventors: Tedd Edward Lister, Robert Vincent Fox
  • Patent number: 7311887
    Abstract: A process reduces SOx emissions in a flue gas stream by adding a wet collector plate section to an existing electrostatic precipitator (ESP) or by converting the last field of an existing ESP to wet operation. To achieve the conversion, the last field or fields of an existing dry ESP are removed and replaced with components made from materials suitable for operation in a wet environment. After the ESP contains wet operation, ammonia is added to the flue gas stream while it is progressing through the collection plates in the ESP.
    Type: Grant
    Filed: February 24, 2006
    Date of Patent: December 25, 2007
    Assignee: Siemens Enviromental Systems&Services
    Inventors: Ralph F. Altman, John Montgomery, Boris Altshuler, Wayne P. Buckley
  • Patent number: 7272925
    Abstract: The nitric oxide (NO) and nitrogen dioxide (NO2) content of lean-burn engine exhaust is beneficially prepared for selective catalytic reduction (SCR) of these oxides to nitrogen by two sidestream additions to the exhaust. An ozone-containing air stream is added to the exhaust to affect oxidation of NO to NO2. And a hydrocarbon(s) fuel constituent is added to a second humidified ozone-containing air stream and that mixture subjected to UV radiation. Strongly oxidizing hydroxyl radicals are formed by interaction of ozone, water, and UV radiation for reaction with the hydrocarbon. The resulting partially oxidized hydrocarbons (Pox) are added to the exhaust, providing effective reduction materials for the SCR of NO2 to nitrogen and water.
    Type: Grant
    Filed: October 25, 2005
    Date of Patent: September 25, 2007
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Kenneth B. Gross, Steven J. Schmieg, Byong K. Cho, Jerome P. Ortmann, Daniel Dziedzic, Thomas J. Chapaton
  • Patent number: 7156959
    Abstract: A system and method for the removal of metals such as mercury from a gas stream. The method involves contacting a gas stream containing the target metals with reactive chemical species generated in a plasma device. The metal to be removed is chemically converted into forms enabling capture in either conventional particulate removal devices or in a wet scrubber for the capture of a soluble chemical species.
    Type: Grant
    Filed: November 4, 2004
    Date of Patent: January 2, 2007
    Assignee: Continental Research & Engineering, LLC
    Inventor: Christopher A. Herbst
  • Patent number: 7074370
    Abstract: A plasma assisted reactor for the removal of carbonaceous combustion products or for simultaneous removal of carbonaceous products and nitrogen oxides from the exhaust emissions from an internal combustion engine, wherein the reactor includes a gas permeable bed made at least primarily of active materials comprising perovskite or vanadate.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: July 11, 2006
    Assignee: Accentus PLC
    Inventors: David Leslie Segal, David Raybone, James Timothy Shawcross, Michael Inman
  • Patent number: 7060231
    Abstract: A plasma reactor for automotive exhaust gas applications which efficiently promotes diffusion, mass transfer and chemical reaction processes of atoms, ions and radicals, in that the ground (outer) electrode has an axially discrete pattern which provides alternating regions of active and passive electric field along the axial direction of the plasma reactor. As the exhaust gas passes axially along the plasma reactor, each active region produces plasma atoms, ions and radicals, which then have time to react with the NOx over the course of the adjacent passive region. In this manner, successive active regions produce copious atoms, radicals and ions, and the adjacent passive regions provide time for these radicals and ions to react with the NOx and hydrocarbons before the next active region is encountered by the moving stream of exhaust gas, thereby enhancing the performance of the plasma reactor.
    Type: Grant
    Filed: October 11, 2002
    Date of Patent: June 13, 2006
    Assignee: General Motors Corporation
    Inventors: Byong K. Cho, Se H. Oh, Steven J. Schmieg
  • Patent number: 7048899
    Abstract: A process and apparatus for removing SO2, NO, and NO2 from a gas stream having the steps of oxidizing a portion of the NO in the flue gas stream to NO2, scrubbing the SO2, NO, and NO2 with an ammonia, ammonium hydroxide, alkali hydroxide or carbonate scrubbing solution, regenerating the scrubbing solution with limestone, and removing any particulate matter and aerosols generated by the scrubbing step in a wet electrostatic precipitator. The process can also remove Hg by oxidizing it to oxidized Hg and removing it in the wet electrostatic precipitator. The scrubbing solution is preferably regenerated with limestone or magnesium, and results in a Group II sulfite or sulfate that can be recovered and sold, or landfilled.
    Type: Grant
    Filed: August 12, 2002
    Date of Patent: May 23, 2006
    Assignee: Powerspan Corp.
    Inventors: Francis R. Alix, Joanna L. Duncan, Christopher R. McLarnon
  • Patent number: 7029636
    Abstract: A device for the pre-treatment of combustion air by exposure to non-thermal plasma at substantially atmospheric pressure and a method for operating the same. The device includes an inner electrode having a longitudinal channel defined therein to receive a fuel. An outer dielectric layer is separated a predetermined distance from the inner electrode so as to form a non-thermal atmospheric pressure plasma region therebetween for receiving the combustion air to be treated. The outer dielectric has at least one opening (e.g., capillaries or slots) defined therethrough from which the non-thermal plasma is emitted. At least one outer electrode (e.g., in the shape of a pin or ring) is disposed in fluid communication with the at least one opening. The treated combustion air and fuel are combined in a mixing region. The pretreatment device may be disposed in an unsealed or a sealed combustion burner.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: April 18, 2006
    Assignee: Plasmasol Corporation
    Inventors: Pascal J. Ricatto, Edward J. Houston, Richard Crowe
  • Patent number: 7011796
    Abstract: A catalytic material for the plasma-assisted treatment of the exhaust gases from internal combustion engines, consisting of an activated alumina, which contains silver or molybdena (MoO3). For silver doped alumina, a preferred silver concentration is between 0.1% and 5% by weight. The preparation and use of silver doped alumina material also is described.
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: March 14, 2006
    Assignee: Accentus plc
    Inventors: David Raybone, James Timothy Shawcross
  • Patent number: 6998027
    Abstract: A compact capacitively coupled electrode structure for use in a gas plasma reactor/generator is disclosed. The electrode structure comprises a parallel plate type anode and cathode spaced to define a gas flow path or volume therebetween. A plurality of electrically conductive fin elements are interposed in the space between the anode and cathode. The fin elements substantially increase the ratio of electrode surface area to volume, and subdivide the gas flow path or volume, thereby substantially increasing the efficiency of plasma gas processing that is possible over a broad range of operating parameters, without substantially increasing the spacing between the anode and cathode. Static or closed operation is also disclosed. Also disclosed is a multi-anode/multi-cathode electrode assembly embodying the basic electrode structure and a highly efficient and compact gas plasma reactor/generator employing the assembly.
    Type: Grant
    Filed: April 16, 2003
    Date of Patent: February 14, 2006
    Assignee: DryScrub, ETC
    Inventor: Kin-Chung Ray Chiu
  • Patent number: 6994830
    Abstract: In a non-thermal plasma reactor (300), at least a component of the active material (320) is selected or modified to provide the capability to adsorb or trap a predetermined chemical species in the gas flow thereby to increase the effective residence time of said species relative to the residence time of unadsorbed species in the gas flow.
    Type: Grant
    Filed: October 16, 2000
    Date of Patent: February 7, 2006
    Assignee: Accentus plc
    Inventors: David Raybone, James Timothy Shawcross, Anthony Robert Martin, Suzanne Elizabeth Thomas
  • Patent number: 6955794
    Abstract: A plasma reactor including a first dielectric having at least one slot defined therethrough, and a segmented electrode including a plurality of electrode segments, each electrode segment is disposed proximate an associated slot. Each electrode segment may be formed in different shapes, for example, a plate, bar, rim, or plug. The electrode segment may be hollow, solid, or made from a porous material. The reactor may include a second electrode and dielectric with the first and second dielectrics separated by a predetermined distance to form a channel therebetween into which the plasma exiting from the slots defined in the first dielectric is discharged. The fluid to be treated is passed through the channel and exposed to the plasma discharge. If the electrode segment is hollow or made of a porous material, then the fluid/gas to be treated may be fed into the slots defined in the first dielectric and exposed therein to the maximum plasma density.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: October 18, 2005
    Assignee: Plasmasol Corporation
    Inventors: Edward J. Houston, Jr., Kurt Kovach, Richard Crowe, Seth Tropper, Michael Epstein
  • Patent number: 6906280
    Abstract: A fast pulsed nonthermal plasma reactor includes a discharge cell and a charging assembly electrically connected thereto. The charging assembly provides plural high voltage pulses to the discharge cell. Each pulse has a rise time between one and ten nanoseconds and a duration of three to twenty nanoseconds. The pulses create nonthermal plasma discharge within the discharge cell. Accordingly, the nonthermal plasma discharge can be used to remove pollutants from gases or break the gases into smaller molecules so that they can be more efficiently combusted.
    Type: Grant
    Filed: March 21, 2003
    Date of Patent: June 14, 2005
    Assignee: The Regents of the University of California
    Inventor: Louis A. Rosocha
  • Patent number: 6852200
    Abstract: A gas treatment system and method for using the same is disclosed. The gas treatment system, comprises: a non-thermal plasma reactor; and a catalyst composition disposed within said non-thermal plasma reactor, said catalyst composition comprising a MZr4(PO4)6, wherein M is a metal selected from the group consisting of platinum, palladium, ruthenium, silver, rhodium, osmium, iridium, and combinations comprising at least one of said foregoing metals. The process comprises exposing said gas to a plasma field and to the catalyst composition.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: February 8, 2005
    Assignee: Delphi Technologies, Inc.
    Inventors: William J. LaBarge, Mark Hemingway, Joachim Kupe, Haskell Simpkins
  • Patent number: 6835358
    Abstract: A system and method for treating a combustion exhaust stream includes admitting an exhaust stream into a non-thermal plasma reactor having at least one segmented non-thermal plasma element including a plurality of individually energizable electrode segments defining a plurality of corona volumes. In a preferred embodiment, the electrode segments are progressively smaller in size in the exhaust flow direction to provide optimum plasma volume variation. Individually energizable electrodes are selectively activated to effect variable corona volumes for treating an exhaust stream. Additional reactor segments are activated only as needed, such as during periods of high exhaust flow, for efficient treatment of the exhaust stream so as to maintain optimized high space velocity in the active corona volume. The segmented elements may comprise a variety of shapes. The system and method are particularly suitable for gas pretreatment and downstream diesel particulate filter regeneration.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: December 28, 2004
    Assignee: Delphi Technologies, Inc.
    Inventors: Mark David Hemingway, Thomas Roger Thoreson, David Alexander Goulette, Joachim Kupe
  • Patent number: 6818193
    Abstract: A plasma reactor including a first dielectric having at least one capillary defined therethrough, and a segmented electrode including a plurality of electrode segments, each electrode segment is disposed proximate an associated capillary. Each electrode segment may be formed in different shapes, for example, a pin, stud, washer, ring, or disk. The electrode segment may be hollow, solid, or made from a porous material. The reactor may include a second electrode and dielectric with the first and second dielectrics separated by a predetermined distance to form a channel therebetween into which the plasma exiting from the capillaries in the first dielectric is discharged. The fluid to be treated is passed through the channel and exposed to the plasma discharge. If the electrode segment is hollow or made of a porous material, then the fluid to be treated may be fed into the capillaries in the first dielectric and exposed therein to the maximum plasma density.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: November 16, 2004
    Assignees: Plasmasol Corporation, Stevens Institute of Technology, LLC
    Inventors: Christos Christodoulatos, George Korfiatis, Richard Crowe, Erich E Kunhardt
  • Patent number: 6787002
    Abstract: A device for purifying an exhaust gas contains at least one first and one second component with a respective shell and core through which the exhaust flows, as well as with two front faces each. At least one of the front faces of the first component and at least one front face of the second component has a predetermined profile with elevations and depressions. The elevations of the front face of the first component extend into the depressions of the front face of the second component and vice versa, thereby configuring a penetration section. The first component is disposed electrically insulated from the second component. The components have a potential difference between them and plasma is generated in the penetration section. The compact plasma reactor reduces the pollutant concentration in the exhaust gas of an internal combustion engine operated in the lean mode, especially when combined with an oxidation catalyst.
    Type: Grant
    Filed: December 2, 2002
    Date of Patent: September 7, 2004
    Assignee: Emitec Gesellschaft fuer Emissionstechnologie mbH
    Inventors: Rolf Brück, Jörg-Roman Konieczny
  • Patent number: 6767434
    Abstract: An apparatus for treating harmful substances contained in a waste gas discharged from waste burning pants includes an insulating honeycomb structural body made of ceramics containing a photocatalytic material, a number of through holes formed in the honeycomb structural body in parallel with each other, first and second mesh electrodes arranged on respective end surfaces of the honeycomb structural body, and a pulse supply source connected across the first and second mesh electrodes. A waste gas flows through the through holes formed in the honeycomb structural body, while pulse corona discharge plasma is uniformly generated along the through holes. Harmful substances contained in the waste gas are decomposed by the high energy electrons and radicals generated by the discharge plasma, and the photocatalytic material is excited by ultraviolet radiation emitted from the discharge plasma to produce active oxygen which decomposes and/or oxidizes the harmful substances.
    Type: Grant
    Filed: September 26, 2000
    Date of Patent: July 27, 2004
    Assignees: NGK Insulators, Ltd.
    Inventors: Yuichiro Imanishi, Naohiro Shimizu, Shozo Ishii
  • Patent number: 6716398
    Abstract: A method and apparatus are provided for reducing pollutants in the exhaust gases produced from the combustion of a fuel by introducing hydroxyl and associated radicals and oxidizers into at least one of the precombustion and postcombustion gas stream of the combustion engine upstream of the catalytic converter and treating the exhaust gases with the catalytic converter.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: April 6, 2004
    Assignee: Litex, Inc.
    Inventors: Robert P. Caren, Jack A. Ekchian
  • Patent number: 6649132
    Abstract: The present invention relates to a process for removing nitrogen oxides, sulfur dioxides and mercury from gas streams such as furnace or utility boiler flue gas streams, particularly those derived from coal-fired utility boilers. A stream containing relatively low concentration of ozone from an ozone concentrator is feed to a barrier discharge reactor. Nitrogen oxides and mercury in the flue gas are oxidized by oxygen and hydroxyl radicals formed in the reactor. The flue gas is then directed to a reactor duct along with the ozone at a greater concentration wherein the remaining nitrogen oxides and mercury in the gas stream will react with the ozone to form nitric acid, nitric acid precursors, mixtures thereof and mercuric oxide. These impurities can then be removed from the gas stream by use of an aqueous scrubber, a wet electrostatic precipitator, a dry scrubber or a semi-dry scrubber.
    Type: Grant
    Filed: July 23, 2002
    Date of Patent: November 18, 2003
    Assignee: The BOC Group, Inc.
    Inventors: Shuen-Cheng Hwang, Neeraj Saxena, Naresh Suchak, Robert J. Ferrell
  • Patent number: 6524538
    Abstract: A method and an apparatus for plasma treatment of gas, particularly for transformation, passivation and stabilization of polluting and toxic admixtures is disclosed. A flowing gas (1) to be treated is passed through a hollow cathode (2) provided with a counter electrode (5) and a hollow cathode discharge plasma (3) is generated by a generator (4) connected to the hollow cathode (2). The flowing gas (1) undergoes interactions with oscillating electrons (6) in the hollow cathode discharge plasma being generated in the gas. The interaction of the hollow cathode discharge plasma with inner walls (8) of the hollow cathode is controlled and the inner walls should have a temperature below its melting point, whereby the inner walls can provide a catalytic effect. The inner walls may also release wall species (9) promoting plasma-chemical reactions in the hollow cathode discharge plasma. The flowing gas is then exhausted as a transformed gas (10) after being treated in the hollow cathode discharge plasma.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: February 25, 2003
    Inventors: Hana Barankova, Ladislav Bardos
  • Patent number: 6482368
    Abstract: A dielectric barrier discharge non-thermal plasma reactor system and method for treating a combustion exhaust stream includes admitting an exhaust stream into a non-thermal plasma reactor having at least one segmented non-thermal plasma element including a plurality of individually energizable electrodes defining a plurality of corona volumes. In a preferred embodiment, the individually energizable electrodes are progressively smaller in size in the exhaust flow direction to provide optimum plasma volume variation. Individually energizable electrodes are selectively activated to effect variable corona volumes for treating an exhaust stream. Additional electrode segments may be activated such as during periods of high exhaust flow. The segmented elements may comprise a variety of shapes, such as C-shaped elements, I-shaped elements, planar elements, swept-shaped elements, inter-digitized elements prepared from comb-shaped elements.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: November 19, 2002
    Assignee: Delphi Technologies, Inc.
    Inventors: Mark David Hemingway, Thomas Roger Thoreson
  • Patent number: 6479023
    Abstract: A system for converting particulate matter in exhaust gases, which system comprises a stoichiometrically-operated engine and an exhaust system including a plasma generator for converting water vapor in the exhaust gases into an oxidant and a filter downstream of the plasma generator. A method for converting particulate matter (PM) in exhaust gases by using plasma-treated water vapor as an oxidant to convert PM trapped on a filter disposed in an exhaust system, and/or to oxidize NO and/or N2 to NO2, in which water vapor, PM, NO and N2 are present in the exhaust gases of a stoichiometrically-operated gasoline engine. The NO2 is then used to combust the PM. Experimentally, the conversion of a gaseous hydrocarbon using a plasma with and without water vapor present can be followed using mass spectrometry.
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: November 12, 2002
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Julia Margaret Evans, Stephen Poulston, Raj Rao Rajaram, Andrew Peter Walker
  • Patent number: 6475350
    Abstract: An apparatus and a method for removing pollutants from gas streams using a reactor assembly. The reactor assembly includes an inlet, an outlet, at least two electrodes, a catalyst bed, and plasma generated from the electrodes. Electrical energy is applied, and catalytic surfaces enhanced by the plasma results in the reduction of NOx to N2 and oxidation of particulates and hydrocarbons to CO2. Furthermore, the present invention removes NOx, particulate, and hydrocarbons from O2 rich pollutant streams without the need for supplemental additives.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: November 5, 2002
    Assignee: Noxtech Inc
    Inventors: Vishwesh Palekar, Ralph J. Slone
  • Publication number: 20020131917
    Abstract: An improved non-thermal plasma apparatus for treating NOx bearing gas streams has a plasma reactor and an inlet and outlet. The plasma reactor is equipped with a plurality of dielectrically-coated electrodes between which a selected voltage is applied to generate a non-thermal plasma environment for driving selected electro-chemical reactions. A predefined voltage is applied across the electrodes to create microdischarges in the exhaust gas stream to convert nitric oxides into primarily nitrogen dioxides. The electrodes are constructed of metal plates, and a fluoropolymeric material, such as fluorocarbon, as the dielectrics. The electrodes are arranged in parallel formation and alternating between positive and negative charges. In one embodiment, fluoropolymeric spacers are positioned between adjacent electrodes and may be configured with selected thicknesses to provide a plurality of desired reaction zones or gaps therebetween.
    Type: Application
    Filed: November 15, 2001
    Publication date: September 19, 2002
    Inventors: Allen J. Nejezchleb, Keith C. Jamison, John W. Rogers, Steven P. Federle, Donald M. Littrell
  • Patent number: 6432280
    Abstract: A pollution control apparatus and method reduces contaminants, such as NOx and SOx pollutants, from an effluent gas stream. The pollution control device includes a resonance chamber that ionizes the effluent gas stream. The contaminants of the effluent gas stream are destroyed in a non-thermal plasma reactor. The effluent gas is then cooled in a cooling unit to substantially place the effluent gas in a non-excited state prior to releasing the effluent gas into the environment or re-injecting the effluent gas into the source of the effluent gas. Re-association of the radical oxides into harmful pollutants is thereby substantially prevented.
    Type: Grant
    Filed: October 23, 2000
    Date of Patent: August 13, 2002
    Assignee: Pioneer Industrial Technologies, Inc.
    Inventors: Edward Domenic Bianco, Michael A. Kline
  • Patent number: 6423190
    Abstract: An exhaust treatment system is provided for use with an internal combustion engine of a motor vehicle. The exhaust treatment system includes a parallel plate, monolithic plasma reactor for reducing nitrogen oxides in the exhaust gas from the engine, an electric power source for providing an electrical signal to the electrodes of the plasma reactor, and a controller interconnected between the electric power source and the plasma reactor for modulating the electrical signal to the plasma reactor. More specifically, the electric power source provides an alternating current electrical signal and the controller modulates the electrical signal off in accordance with a predetermined duty cycle, thereby achieving uniform barrier discharge in the plasma reactor.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: July 23, 2002
    Assignee: Delphi Technologies, Inc.
    Inventors: Mark David Hemingway, David Alexander Goulette, Eugene V. Ripley, Darrell R. Herling
  • Publication number: 20020076368
    Abstract: A system and method for treating a combustion exhaust stream includes admitting an exhaust stream into a non-thermal plasma reactor having at least one segmented non-thermal plasma element. The segmented element includes plurality of individually energizable electrode segments defining a plurality of corona volumes. in a preferred embodiment, the electrode segments are progressively smaller in size in the exhaust flow direction to provide optimum plasma volume variation. Individually energizable electrodes are selectively activated to effect variable corona volumes for treating an exhaust stream. Additional reactor segments are activated only as needed, such as during periods of high exhaust flow, for efficient treatment of the exhaust stream so as to maintain optimized high space velocity in the active corona volume.
    Type: Application
    Filed: December 19, 2000
    Publication date: June 20, 2002
    Inventors: Mark David Hemingway, Thomas Roger Thoreson
  • Patent number: 6368468
    Abstract: A zirconia based article having a core of ZrO2 and/or partially reduced ZrO2, is characterized in that it includes, over at least part of its surface, a superficial layer integral with the article, the thickness of the superficial layer including a plurality of regions of which one external region is formed of zirconium nitride having a gold metallic appearance.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: April 9, 2002
    Assignee: Asulab S.A.
    Inventor: Béatrice Michel
  • Patent number: 6357223
    Abstract: An apparatus and a method for enhancing the rate of a chemical reaction in a gas stream. The apparatus includes at least one heterogeneous catalyst having an upstream end and a downstream end, and at least one surface having a plurality of catalytically active sites on the surface, where the catalyst is positioned so that at least a portion of the gas stream contacts at least a portion of the catalytically active sites on the surface. At least one device for producing radicals or other active species from at least one of water vapor or other gaseous species, such as a corona discharge device or a UV light source is used to produce radicals or other active species, which are introduced into the gas stream at a position upstream of the downstream end of the catalyst.
    Type: Grant
    Filed: February 18, 2000
    Date of Patent: March 19, 2002
    Assignee: Litex, Inc.
    Inventors: Robert P. Caren, David Christeller, Jack A. Ekchian
  • Patent number: 6309610
    Abstract: An improved non-thermal plasma apparatus for treating NOx bearing gas streams has a plasma reactor and an inlet and outlet. The plasma reactor is equipped with a plurality of dielectrically-coated electrodes between which a selected voltage is applied to generate a non-thermal plasma environment for driving selected electrochemical reactions. A predefined voltage is applied across the electrodes to create microdischarges in the exhaust gas stream to convert nitric oxides into primarily nitrogen dioxides. At least a portion of the gas is diverted through an ethanol bath before entering the reactor. The dielectric is preferably a fluoropolymeric substance.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: October 30, 2001
    Assignee: Science Applications International Corporation
    Inventors: Allen J. Nejezchleb, Keith C. Jamison, John W. Rogers, Steven P. Federle, Donald M. Littrell
  • Patent number: 6296827
    Abstract: A method and an apparatus for plasma-chemical production of nitrogen monoxide is used to produce inhalation gas enriched with nitrogen monoxide for medical purposes. The nitrogen-monoxide production is achieved through the use of a dielectric barrier discharge created in a process gas containing nitrogen and oxygen.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: October 2, 2001
    Assignee: Siemens Aktiengesellschaft
    Inventors: Rolf Castor, Thomas Hammer
  • Patent number: 6238525
    Abstract: A process for reducing the nitrogen oxides content of the exhaust gas from an internal combustion engine includes treating the exhaust gas in an electric gas discharge such that at least one of nitrogen dioxide or nitric acid are formed from nitrogen oxides in the exhaust gas; storing the nitrogen dioxides and/or the nitric acid in the form of nitrates on a nitrogen oxides storage material during phases when the engine operates with a greater than a stoichiometric air/fuel ratio (i.e., the storage phase); decomposing the nitrates to give nitrogen oxides during brief phases when the engine operates with a less than the stoichiometric air/fuel ratio (i.e., the desorption phase); and reducing the nitrogen oxides which are released from the storage material to nitrogen. The nitrogen oxides storage material may be located in an electric gas discharge zone, and the exhaust gas may be passed through the discharge and then over the storage material.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: May 29, 2001
    Assignee: Degussa-Hüls Aktiengesellschaft
    Inventors: Egbert Lox, Jürgen Gieshoff, Wolfgang Strehlau, Thomas Kreuzer
  • Patent number: 6197234
    Abstract: To increase the anti-wettability of a body vis a vis a fluid the body is subjected in a treatment enclosure to a post-discharge nitrogen plasma. A fluorinated vapor is fed into the plasma on the input side or on the output side of the discharge cavity.
    Type: Grant
    Filed: June 12, 1997
    Date of Patent: March 6, 2001
    Assignee: Conte SA
    Inventors: Pierre Goudmand, Odile Dessaux, Jean-Denis Quensierre, Vincent Bedhome, Philippe Chavatte, José Duez
  • Patent number: 6168689
    Abstract: A method and an apparatus for cleaning smoke and reducing noises of an internal combustion engine or external combustion engine by using a high voltage field. The present invention relates to a method and an apparatus which can clean exhaust gases and reduce noise, wherein it comprises the step of burning up the granular particles with corona discharge after changing particles into plasma state, the step of removing gaseous materials with negative ions, the step of eliminating NOx with ultraviolet rays and the step of reducing noise.
    Type: Grant
    Filed: June 26, 1998
    Date of Patent: January 2, 2001
    Assignee: Seondo Electric Co., Ltd.
    Inventors: Chan-Ho Park, Yong-Hee Lee