Perforated Or Foraminous Patents (Class 204/284)
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Patent number: 7118665Abstract: The present invention discloses a surface treatment process for enhancing both the release rate of metal ions from a sacrificial electrode, and the working life of the electrode. A high density of micro pores are formed on the surface of the sacrificial electrode. Chlorine ions are then implanted into the pores. The chlorine ions prevent a passive film from forming on the sacrificial electrode during use, in which an electric current flows through the sacrificial electrode.Type: GrantFiled: March 1, 2004Date of Patent: October 10, 2006Assignee: Industrial Technology Research InstituteInventors: Kon-Tsu Kin, Hong-Shiang Tang, Shu-Fei Chan, Wen-Tsang Chen
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Patent number: 7094492Abstract: A polymer electrolyte fuel cell has a catalytic layer comprising a material and a polymer electrolyte, and the catalytic layer contains a fibrous material such as carbon whiskers or hydrophilic fibers. The polymer electrolyte fuel cell in the present invention having a catalytic layer comprising a catalytic material, an ion conducting material, an electron conducting material, and a void forming agent, and voids having diameters of from 60 to 1000 nm in the catalytic layer has a void volume of from 0.15 to 0.25 cm3/g.Type: GrantFiled: October 10, 2002Date of Patent: August 22, 2006Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Takeshi Matsubara, Katsuhiko Kohyama, Hiroshi Shinkai
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Patent number: 7077937Abstract: A large surface area electrode well-suited to electrochemical applications is produced by winding many turns of a metallic fiber tow on to a sheet metal rectangle. In the preferred embodiment, an anode that can be used to purify water by electrochemical production of hydroxyl free radical is made by winding titanium fiber tow on to a rectangular substrate made of titanium sheet, and applying a suitable multilayered electrocatalytic coating. Made of other metals, an electrode of this description can also serve as the cathode of an electrochemical cell, or as a battery plaque.Type: GrantFiled: July 3, 2003Date of Patent: July 18, 2006Inventors: Oleh Weres, Henry Edward O'Donnell
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Patent number: 7077945Abstract: A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising the steps of providing a molten salt electrolyte at a temperature of less than 900° C. having alumina dissolved therein in an electrolytic cell having a liner for containing the electrolyte, the liner having a bottom and walls extending upwardly from said bottom. A plurality of non-consumable Cu—Ni—Fe anodes and cathodes are disposed in a vertical direction in the electrolyte, the cathodes having a plate configuration and the anodes having a flat configuration to compliment the cathodes. The anodes contain apertures therethrough to permit flow of electrolyte through the apertures to provide alumina-enriched electrolyte between the anodes and the cathodes. Electrical current is passed through the anodes and through the electrolyte to the cathodes, depositing aluminum at the cathodes and producing gas at the anodes.Type: GrantFiled: May 8, 2003Date of Patent: July 18, 2006Assignee: Northwest Aluminum TechnologiesInventors: S. Craig Bergsma, Craig W. Brown, Donald R Bradford, Robert J. Barnett, Michael B. Mezner
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Patent number: 7070878Abstract: A layered oxygen electrode incorporating a peroxide decomposition catalyst. The design of the oxygen electrode promotes oxygen dissociation and absorption within the oxygen electrode. The oxygen electrode has differing layers of hydrophobicity which allow chemical impregnation of the active catalyst material into the oxygen electrode where the active catalyst material is needed most.Type: GrantFiled: November 15, 2002Date of Patent: July 4, 2006Assignee: Ovonic Fuel Cell Company LLCInventors: Srinivasan Venkatesan, Hong Wang, Stanford R. Ovshinsky, Boyko Aladjov, Subhash Dhar
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Patent number: 7052586Abstract: We make particulates, especially magnetic Fe—Co alloys having high magnetic permeability, of controlled dimensions, especially those having a narrow thickness size distribution centered around a median or target thickness in the range of about 0.1–1.0 ?m, using electrodeposition typically on a smooth (polished) titanium cathode. Our preferred continuous process uses a rotating drum cathode inside a fixed anode to grow flakes and to produce them automatically by inherent instability in the deposited film. The drum preferably rotates about a substantially vertical axis. The particulates shed (slough off) into the electrolyte (because of mismatch between the cathode surface and the plated metal or alloy at the molecular level) where they are separated in a magnetic separator or other suitable device. If the flakes are soft iron or iron-cobalt alloys, the drum generally is titanium or titanium alloy.Type: GrantFiled: February 11, 2003Date of Patent: May 30, 2006Assignee: The Boeing CompanyInventors: Glen L. Rasmussen, Micheal E. Dickson, Robert J. Miller, Mary J. Nelson, Jonathan C. Hughes, Diane C. Rawlings
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Patent number: 6960406Abstract: A fluorinated carbon based gas diffusion layer for use in hydrogen and oxygen electrodes. The fluorinated carbon based gas diffusion layer provides for uniform distribution of hydrogen or oxygen across the electrode while maintaining a high level of hydrophobicity within the gas diffusion layer.Type: GrantFiled: October 18, 2002Date of Patent: November 1, 2005Assignee: Texaco Ovonic Fuel Cell LLCInventors: Stanford R. Ovshinsky, Srinivasan Venkatesan, Hong Wang, Boyko Aladjov, Subhash Dhar
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Patent number: 6942767Abstract: A reactor comprising an inlet, an outlet, and a conically spiraling fluid flow channel coupled between the inlet and the outlet. The reactor may be an electrochemical reactor comprising a fluid flow channel that spirals about an axis, the fluid flow channel comprising an anode, a cathode across from the anode, and a membrane disposed between the anode and the cathode. The reactor may have a number of design parameters that are based upon one or more reaction species and that favor the occurrence of a reaction associated with the species. The reactor may be used for the electrolysis of water or for the production of other chemical products.Type: GrantFiled: October 11, 2002Date of Patent: September 13, 2005Assignee: T-Graphic, LLCInventors: David Fazzina, Jack Matthews, Steve Taracevicz
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Patent number: 6881308Abstract: A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.Type: GrantFiled: March 4, 2002Date of Patent: April 19, 2005Assignee: Lynntech, Inc.Inventors: Adrian J. Denvir, Oliver J. Murphy, Alan J. Cisar, Priscilla Robertson, Kyle Uselton
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Patent number: 6881511Abstract: Gas-diffusion electrodes containing modified carbon products are described wherein the modified carbon product is a carbon product having attached at least one organic group. The modified carbon product can be used for at least one component of the electrodes such as the active layer and/or the blocking layer. Methods to extend the service life of electrodes as well as methods to reduce the amount of fluorine containing compounds are also described.Type: GrantFiled: August 8, 2003Date of Patent: April 19, 2005Assignees: Cabot Corporation, Edison Termoelettrica, S.p.A.Inventors: Paolo Tosco, Laurent Kosbach, Yuan Yu, Claudio Orecchia
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Patent number: 6866754Abstract: Acidity in water leaching from a mass of sulphide tailings is prevented by de-oxygenating the water prior to entering the mass. A cover comprising an electrolytic cell, either galvanic or impressed-current, gives rise to a cathode reaction in which the redox voltage of the water drops to 003 volts or less. The cover can be thinner, and much less expensive, than an equally-effective non-reactive cover. The electrolyte is water contained in water-retaining soil, or a depth of water, lying over the cathode. The cathode is steel mesh, or a layer of graphite, spread over the whole mass of tailings.Type: GrantFiled: May 17, 2002Date of Patent: March 15, 2005Assignee: Enpar Technologies Inc.Inventors: Gene Sidney Shelp, Rejean Joseph Henri Brousseau
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Patent number: 6866828Abstract: A photocatalysis apparatus has at least one unit structure (2). The unit structure has a photocatalyst module (6) and a pair of discharge electrodes (5) sandwiching the photocatalyst module. The photocatalyst module includes a photocatalyst and a three-dimensional ceramic mesh base carrying the photocatalyst. At least one of the discharge electrodes is a three-dimensional discharge electrode having an electrode body (3) and a conductive frame (4). The electrode body consists of cells made of a conductive foil and has front, back, and side faces. The front and back faces are separated from each other by a predetermined distance and have a shape selected from a group including a honeycomb, a lattice, and a mesh. The side faces of the electrode body is covered with the conductive frame.Type: GrantFiled: April 22, 2002Date of Patent: March 15, 2005Assignee: Kabushiki Kaisha ToshibaInventors: Noboru Segawa, Yutaka Uchida, Takeshi Imamura, Naohiko Shimura
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Patent number: 6838408Abstract: A method for producing gas diffusion electrodes, in particular for use in electrolysis cells, as well as electrodes and their uses are described. A method of the present invention involves first, a sheet-like structure is produced by means of a pair of rolls by rolling a powder mixture containing at least one catalyst or a catalyst mixture and a binder, and then the sheet-like structure is connected to an electrically conductive catalyst support by rolling by means of a pair of rolls. In one embodiment the clamping force of the rolls is preferably kept constant in the range from 0.2 kN/cm to 15 kN/cm.Type: GrantFiled: April 2, 2004Date of Patent: January 4, 2005Assignee: Bayer MaterialScience AGInventors: Andreas Bulan, Fritz Gestermann, Hans-Dieter Pinter, Peter Weuta, Walter Klesper
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Publication number: 20040265677Abstract: A stack, to be used in a fuel cell or electrolyser, comprises a collector layer, at least one diffusion layer and at least one anchoring layer. The collector layer being a metal foil or metal plate or foamed metal sheet, the diffusion layer being a metal mesh or expanded metal sheet. An anchoring layer having a thickness of less than 0.5 mm and comprising metal fibers, is sintered between the collector layer and the diffusion layer.Type: ApplicationFiled: July 13, 2004Publication date: December 30, 2004Inventors: Ronny Losfeld, Lieven Anaf
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Patent number: 6835489Abstract: A double layered oxygen electrode impregnated with an active catalyst material and method of making. The design of the oxygen electrode promotes oxygen dissociation and absorption within the oxygen electrode. The oxygen electrode has differing layers of hydrophobicity which allow chemical impregnation of the active catalyst material into the oxygen electrode where the active catalyst material is needed most.Type: GrantFiled: August 15, 2002Date of Patent: December 28, 2004Assignee: Texaco Ovonic Fuel Cell LLCInventors: Srinivasan Venkatesan, Hong Wang, Boyko Aladjov, Subhash Dhar, Stanford R. Ovshinsky
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Publication number: 20040256223Abstract: In a gas diffusion electrode assembly, and in an electrolyzer using the same, a bonding piece having on at least one surface a perfluorosulfonic acid layer, a perfluorosulfonyl fluoride layer or an alky ester of perfluorocarboxylic acid layer is positioned at its perfluoro compound layer surface with respect to the gas diffusion electrode assembly. Adjacent gas diffusion electrodes are heat fusion bonded together, or heat fusion bonding is carried out using the bonding piece in a frame form. Adjacent gas diffusion electrodes are sealed up by heat fusion bonding, using a material that is similar to the material that forms the gas diffusion electrodes.Type: ApplicationFiled: March 30, 2004Publication date: December 23, 2004Inventors: Shinji Katayama, Kiyohito Asaumi, Hiroaki Aikawa, Tsugiyoshi Osakabe, Mitsuharu Hamamori, Tatsuhito Kimura, Koji Saiki, Kenji Nonomura, Naoya Okada, Osamu Ichinose
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Patent number: 6818107Abstract: The invention relates to a chemical reactor having an electrochemical cell containing a three-layer structure for the decomposition and removal of a substance treated by a chemical reaction.Type: GrantFiled: March 20, 2002Date of Patent: November 16, 2004Assignees: National Institute of Advanced Industrial Science and Technology, Fine Ceramics Research AssociationInventors: Masanobu Awano, Yoshinobu Fujishiro, Hae Jin Hwang, Sergei Bredikhin, Kazuyuki Matsuda, Kunihiro Maeda, Takao Kanai, Motoyuki Miyata
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Patent number: 6802946Abstract: An apparatus which can control thickness uniformity during deposition of conductive material from an electrolyte onto a surface of a semiconductor substrate is provided. The apparatus has an anode which can be contacted by the electrolyte during deposition of the conductive material, a cathode assembly including a carrier adapted to carry the substrate for movement during deposition, and a conductive element permitting electrolyte flow therethrough. A mask lies over the conductive element and has openings permitting electrolyte flow. The openings define active regions of the conductive element by which a rate of conductive material deposition onto the surface can be varied. A power source can provide a potential between the anode and the cathode assembly so as to produce the deposition. A deposition process is also disclosed, and uniform electroetching of conductive material on the semiconductor substrate surface can additionally be performed.Type: GrantFiled: May 15, 2001Date of Patent: October 12, 2004Assignee: NuTool Inc.Inventors: Bulent M. Basol, Paul Lindquist
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Patent number: 6800828Abstract: Complex features and fine details in a Carbon—Carbon work piece, for example, are formed by electrical discharge machining (EDM). An electrode used in the EDM is made of a material that is mechanically and chemically compatible with Carbon—Carbon composite material.Type: GrantFiled: March 31, 2001Date of Patent: October 5, 2004Assignee: Honeywell International Inc.Inventor: Ilan Golecki
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Publication number: 20040188245Abstract: A metal coil or an elastic cushion formed by winding the metal coil around a corrosion-resistant frame is sandwiched between an electrode and an electrode collector or a cell wall or is used as an electrode. The elasticity of the metal coil or the elastic cushion enables the easy handling and the uniform contact between the electrode and another electrolysis element. The metal coil or the elastic cushion can be also used as an elastic cathode. The elasticity of the elastic cathode also enables the easy handling of the electrode itself and the uniform contact between the ion exchange membrane and the current collector.Type: ApplicationFiled: March 30, 2004Publication date: September 30, 2004Applicant: CHLORINE ENGINEERS CORP., LTD.Inventors: Shinji Katayama, Kiyohito Asaumi
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Patent number: 6797148Abstract: A drained-cathode cell for the electrowinning of aluminium comprises one or more anodes (14) suspended over one or more cathodes (16). The or each anode (14) and cathode (16) respectively have a sloped V-shaped active anode surface (22) and parallel sloped inverted V-shaped drained cathode surfaces (18) facing one another and spaced apart by two sloped inter-electrode gaps (20), arranged so the electrolyte circulates upwardly in the sloped inter-electrode gaps (20) assisted by anodically produced gas and then returns from a top part (22′) to a bottom part (22″) of each inter-electrode gap (20) along an electrolyte path (26,27,36,37).Type: GrantFiled: April 27, 2002Date of Patent: September 28, 2004Assignee: Moltech Invent S.A.Inventor: Vittorio De Nora
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Patent number: 6797136Abstract: The present invention relates to a retrofitted electrolytic cell and a method for retrofitting an electrolytic cell comprising an anode and a cathode compartment, a separator partitioning the compartments, said cathode compartment comprising a hydrogen evolving cathode. The method comprises making at least one substantially horizontal slit in the hydrogen evolving cathode resulting in plural cathode members, bending the edge of at least one cathode member at the slit away from the separator, arranging a gas diffusion electrode to the cathode members on the side facing the separator, and arranging an electrolyte layer to the gas diffusion electrode. The invention also relates to the use of a retrofitted electrolytic cell.Type: GrantFiled: September 4, 2002Date of Patent: September 28, 2004Assignee: Akzo Nobel N.V.Inventor: Takayuki Shimamune
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Publication number: 20040182695Abstract: A method for producing gas diffusion electrodes, in particular for use in electrolysis cells, as well as electrodes and their uses are described. A method of the present invention involves first, a sheet-like structure is produced by means of a pair of rolls by rolling a powder mixture containing at least one catalyst or a catalyst mixture and a binder, and then the sheet-like structure is connected to an electrically conductive catalyst support by rolling by means of a pair of rolls. In one embodiment the clamping force of the rolls is preferably kept constant in the range from 0.2 kN/cm to 15 kN/cm.Type: ApplicationFiled: April 2, 2004Publication date: September 23, 2004Inventors: Andreas Bulan, Fritz Gestermann, Hans-Dieter Pinter, Peter Weuta, Walter Klesper
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Publication number: 20040168922Abstract: A system for producing metal particles using a discrete particle electrolyzer cathode, a discrete particle electrolyzer cathode, and methods for manufacturing the cathode. The cathode has a plurality of active zones on a surface thereof at least partially immersed in a reaction solution. The active zones are spaced from one another by between about 0.1 mm and about 10 mm, and each has a surface area no less than about 0.02 square mm. The cathode is spaced from an anode also at least partially immersed in the reaction solution. A voltage potential is applied between the anode and cathode. Metal particles form on the active zones of the cathode. The particles may be dislodged from the cathode after they have achieved a desired size. The geometry and composition of the active zones are specified to promote the growth of high quality particles suitable for use in metal/air fuel cells. Cathodes may be formed from bundled wire, machined metal, chemical etching, or chemical vapor deposition techniques.Type: ApplicationFiled: April 24, 2003Publication date: September 2, 2004Inventors: Stuart I. Smedley, Martin De Tezanos Pinto, Stephen R. des Jardins, Donald James Novkov, Ronald Gulino
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Patent number: 6761809Abstract: An electrically regeneratable battery of electrochemical cells for capacitive deionization (including electrochemical purification) and regeneration of electrodes is operated at alternate polarities during consecutive cycles. In other words, after each regeneration step operated at a given polarity in a deionization-regeneration cycle, the polarity of the deionization step in the next cycle is maintained. In one embodiment, two end electrodes are arranged one at each end of the battery, adjacent to end plates. An insulator layer is interposed between each end plate and the adjacent end electrode. Each end electrode includes a single sheet of conductive material having a high specific surface area and sorption capacity, preferably a sheet formed of carbon aerogel composite. The battery further includes a plurality of generally identical double-sided intermediate electrodes that are equidistally separated from each other, between the two end electrodes.Type: GrantFiled: January 3, 2002Date of Patent: July 13, 2004Assignee: The Regents of the University of CaliforniaInventors: Tri D. Tran, David J. Lenz
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Patent number: 6733913Abstract: This invention is an improved fuel cell design for use at low pressure. The invention has a reduced number of component parts to reduce fabrication costs, as well as a simpler design that permits the size of the system to be reduced at the same time as performance is being improved. In the present design, an adjacent anode and cathode pair are fabricated using a common conductive element, with that conductive element serving to conduct the current from one cell to the adjacent one. This produces a small and simple system suitable for operating with gas fuels or alternatively directly with liquid fuels, such as methanol, dimethoxymethane, or trimethoxymethane. The use of these liquid fuels permits the storage of more energy in less volume while at the same time eliminating the need for handling compressed gases which further simplifies the fuel cell system.Type: GrantFiled: April 9, 2002Date of Patent: May 11, 2004Assignee: Lynntech, Inc.Inventors: Alan J. Cisar, Dacong Weng, Oliver J. Murphy
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Publication number: 20040084303Abstract: An electrochemical device (18) for generating a desired gas of the type includes an ionically conductive electrolyte layer (20), a porous electrode layer (22), and a current collector layer (16) that has a high electrical conductivity and is porous to a desired gas (24) generated by the electrochemical device (18). The current collector layer (16) is substantially formed as a film comprised of a layer of spherical refractory material objects (26) having a conductive coating (12) of a precious metal. The coated spherical objects (26) have a desired diameter (28) making them suitable for forming into the film.Type: ApplicationFiled: December 2, 2002Publication date: May 6, 2004Applicant: Litton Systems, Inc.Inventors: Scott R. Sehlin, Courtney J. Monzyk
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Publication number: 20040069621Abstract: The present invention relates to an electrochemical cell suitable for a membrane electrolysis process, comprising (i) at least one anode compartment having a metal electrode, (ii) a cathode compartment having a gas diffusion electrode (iii) and an ion exchange membrane arranged between the anode compartment and the cathode compartment. The metal electrode that functions as an anode is capable of being dipped into an electrolyte during use and is provided with one or more orifices for the passage of gas formed during operation. The metal electrode can optionally be angled and/or curved, and the orifices preferably have guide structures that conduct the gas formed to a side of the metal electrode that faces away from the cathode. The present invention also relates to electrodes per se as well as methods for use of electrodes and electrochemical cells.Type: ApplicationFiled: July 9, 2003Publication date: April 15, 2004Applicant: Bayer AktiengesellschaftInventors: Fritz Gestermann, Andreas Bulan, Richard Malchow, Hans-Dieter Pinter, Walter Klesper
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Patent number: 6716551Abstract: In a method of manufacturing a fluid diffusion layer for a solid polymer electrolyte fuel cell, a surface of the fluid diffusion layer is abraded so that the topography of the fluid diffusion layer surface is rendered more uniform. The fluid diffusion layer comprises a porous substrate, and may also comprise a carbon-containing sublayer, as well as hydrophobic material. The particles formed by the abrading operation may be deposited into at least some of the pores of the substrate to form a support structure for the direct depositing of a catalyst onto the abraded surface.Type: GrantFiled: May 2, 2001Date of Patent: April 6, 2004Assignee: Ballard Power Systems Inc.Inventors: Volker Peinecke, Jorg von der Osten-Fabeck, John Robert Gordon, Herwig Robert Haas
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Publication number: 20040045833Abstract: This specification discloses a thin-film gas diffusion electrode (GDE) and the method for making the same. The thin-film GDE is formed in a unitary way. A dual-nature porous thin film is used as the substrate. A surface processing is performed to make one surface of the thing film hydrophlic while the other surface hydrophobic. The hydrophlic area serves as the active layer for electrochemical reactions after chemical processing. The hydrophobic area is kept dry to form a smooth gas channel, functioning as a gas diffusion layer. In this method, the thin-film GDE is free from the use of binders and high-temperature high-pressure manufacturing processes.Type: ApplicationFiled: April 21, 2003Publication date: March 11, 2004Inventors: Wen-Chin Li, Shu-Chin Chou, Shinn-Horng Yeh, Kuan-Liang Chen, Kun-Lung Hsien, Min-Lun Chen
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Patent number: 6656870Abstract: A tungsten-containing fuel cell catalyst having high electrochemical activity and its method of making are described. The tungsten-containing catalyst may be formed in situ in a fuel cell after the fuel cell is assembled.Type: GrantFiled: September 27, 2001Date of Patent: December 2, 2003Assignee: Osram Sylvania Inc.Inventors: Joel B. Christian, Robert G. Mendenhall
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Patent number: 6649300Abstract: An electrode catalyst for fuel cells which comprises a conductive carbon, platinum supported on the conductive carbon in an amount of from 20% by mass to 70% by mass based on the mass of the catalyst, and oxygen bonded chemically to the conductive carbon and present in the range of from 0.7 to 3 in atomic ratio to the platinum. The present electrode catalyst can attain a high activity because the platinum crystallite diameter has been kept small even when the platinum is supported in a large quantity in the amount more than 20% by mass. The catalyst is useful in fuel cells, e.g., solid polymer electrolyte fuel cells.Type: GrantFiled: May 18, 2001Date of Patent: November 18, 2003Assignee: N.E. Chemcat CorporationInventors: Takashi Ito, Masahai Endou
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Patent number: 6630059Abstract: The present invention relates to methods and apparatus for plating a conductive material on a semiconductor substrate by rotating pad or blade type objects in close proximity to the substrate, thereby eliminating/reducing dishing and voids. This is achieved by providing pad or blade type objects mounted on cylindrical anodes or rollers and applying the conductive material to the substrate using the electrolyte solution disposed on or through the pads, or on the blades. In one embodiment of the invention, the pad or blade type objects are mounted on the cylindrical anodes and rotated about a first axis while the workpiece may be stationary or rotate about a second axis, and metal from the electrolyte solution is deposited on the workpiece when a potential difference is applied between the workpiece and the anode. In another embodiment of the present invention, the plating apparatus includes an anode plate spaced apart from the cathode workpiece.Type: GrantFiled: January 14, 2000Date of Patent: October 7, 2003Assignee: Nutool, Inc.Inventors: Cyprian Emeka Uzoh, Homayoun Talieh, Bulent Basol, Douglas W. Young
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Patent number: 6630268Abstract: Gas-diffusion electrodes containing modified carbon products are described wherein the modified carbon product is a carbon product having attached at least one organic group. The modified carbon product can be used for at least one component of the electrodes such as the active layer and/or the blocking layer. Methods to extend the service life of electrodes as well as methods to reduce the amount of fluorine containing compounds are also described.Type: GrantFiled: May 18, 2001Date of Patent: October 7, 2003Assignees: Cabot Corporation, Edison Termoelettrica S.p.A.Inventors: Paolo Tosco, Laurent Kosbach, Yuan Yu, Claudio Orecchia
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Publication number: 20030127321Abstract: The invention concerns a microporous diaphragm obtainable by filtering through a porous support, an aqueous dispersion free of asbestos fibres and titanate fibres, comprising organic fibres, at least a binding agent selected among halogenated polymers, at least a pore-forming agent and mineral particles with non-fibrous structure. The invention also concerns a combination comprising said diaphragm and a fibrous mat obtainable by filtration deposit through a porous support of a dispersion comprising fibres whereof part is electrically conductive, at least a binding agent selected among halogenated polymers, at least an electrolytic agent, at least a pore-forming agent. The invention further concerns the preparation of the diaphragm and the combination, and the use thereof to obtain an alkali metal hydroxide solution by electrolysis of aqueous alkali metal halide solutions.Type: ApplicationFiled: September 13, 2002Publication date: July 10, 2003Inventors: Jean-Guy Le Helloco, Jean-Maurice Perineau
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Patent number: 6589404Abstract: The electrolytic cell has a trough-like container with a bottom, with side walls and with at least one inlet and at least one outlet for the electrolyte. Numerous plate-like electrodes are disposed in the container and are partly immersed in an electrolyte bath. The bottom of the container which is in contact with the electrolyte bath has numerous openings for the passage of electrolyte, and below the bottom there is disposed at least one distribution chamber for recirculated electrolyte. At least one of the side walls of the container is equipped with at least one recirculation chamber for recirculating electrolyte from the electrolyte bath into the distribution chamber, the upper portion of the recirculation chamber being connected with the electrolyte bath and the lower portion of the recirculation chamber communicating with the distribution chamber.Type: GrantFiled: April 20, 2001Date of Patent: July 8, 2003Assignee: MG Technologies AGInventors: Nikola Anastasijevic, Stefan Laibach, Reinhard Dobner, Helmut Schatton
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Electrode characterized by highly adhering superficial catalytic layer and method for its production
Patent number: 6589406Abstract: The invention is relative to an electrode for gas evolution in electrolytic and electrometallurgical industrial applications, made of a metal substrate having a surface morphology characterized by a combination of micro-roughness and macro-roughness which favors high adherence of a superficial catalytic layer in order to prevent detachment of the same and passivation of the substrate even under critical operating conditions.Type: GrantFiled: May 16, 2001Date of Patent: July 8, 2003Assignee: De Nora Elettrodi S.p.A.Inventors: Rubén Ornelas Jacobo, Giuseppe Faita, Lawrence Gestaut, Corrado Mojana -
Patent number: 6585868Abstract: This invention relates to a reduced water producing apparatus, which can mass-produce reduced water, wherein oxidation-reduction potential maintains for a long period successively, from not only industrial water, natural water but pure water speedily and inexpensively, and that suited for industrial mass production of reduced water. The apparatus have a water tank, at least one electrode plate unit, and a voltage impressing means for impressing high-frequency alternating voltage, wherein the electrode plate unit includes two alternating electrode plates in which alternating voltages impressed by the voltage impressing means are varied to be modulated waves of mutually opposite phases and a ground electrode plate arranged to oppose the two alternating electrode plates, and wherein surfaces of these electrode plates are formed of titanium or platinum.Type: GrantFiled: November 28, 2000Date of Patent: July 1, 2003Assignee: Japan Matex Kabushiki KaishaInventor: Yasutaka Chihara
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Patent number: 6576110Abstract: An anode is configured to be used within a metal film plating apparatus. The anode has a substantially planar electric field generating portion and an electrolyte solution chemical reaction portion. The planar electric field generating portion is coated with an inert material that is impervious to the electrolyte solution. In one embodiment, the anode is formed as a perforated anode. In one aspect, the electric field generating portion is formed contiguous with the electrolyte solution chemical reaction portion. In another aspects, the planar electric field generating portion is formed as a distinct member from the electrolyte solution chemical reaction portion.Type: GrantFiled: February 28, 2001Date of Patent: June 10, 2003Assignee: Applied Materials, Inc.Inventor: Dan Maydan
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Patent number: 6569296Abstract: A grid anode for cathodic protection of steel reinforced concrete structures formed of multiple valve metal strips including multiple electric current-carrying valve metal strips. Valve metal strip grid anodes without an electrocatalytic metal surface can be used in a cathodic protection system operated at an anode current density up to about 20 milliamps per square foot. Composite anodes having an electrocatalytic metal coating are useful at higher anode current densities.Type: GrantFiled: January 30, 1996Date of Patent: May 27, 2003Inventors: John William Burgher, Dennis F. Dong, Richard Eric Loftfield
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Patent number: 6562229Abstract: A metal anode useful in a galvanic or impressed current cathodic protection system for a steel reinforced concrete article is a unitary, multi-plane, porous, metal anode strip or ribbon having a plurality of louvers defining a plane or planes at the lateral extremities of said louvers. In one embodiment, louvers extending in their long dimension longitudinally on the anode strip are spaced apart from adjacent louver units by an intermediate plane. Louvered anode strips consisting of a valve metal or alloy or mixture thereof are useful at an anode current density of up to about 20 milliamps per square foot. Louvered metal anodes comprising an electrocatalytically active coating on a valve metal substrate are useful at higher anode current densities. Sacrificial metal anodes such as zinc anodes are useful in galvanic cathodic protection systems.Type: GrantFiled: May 12, 1997Date of Patent: May 13, 2003Inventors: John W. Burgher, Dennis F. Dong, Richard E. Loftfield
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Patent number: 6558525Abstract: A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising the steps of providing a molten salt electrolyte at a temperature of less than 900° C. having alumina dissolved therein in an electrolytic cell having a liner for containing the electrolyte, the liner having a bottom and walls extending upwardly from said bottom. A plurality of non-consumable anodes and cathodes are disposed in a vertical direction in the electrolyte, the cathodes having a plate configuration and the anodes having a flat configuration to compliment the cathodes. The anodes contain apertures therethrough to permit flow of electrolyte through the apertures to provide alumina-enriched electrolyte between the anodes and the cathodes. Electrical current is passed through the anodes and through the electrolyte to the cathodes, depositing aluminum at the cathodes and producing gas at the anodes.Type: GrantFiled: March 1, 2002Date of Patent: May 6, 2003Assignee: Northwest Aluminum TechnologiesInventors: Donald R. Bradford, Robert J. Barnett, Michael B. Mezner
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Patent number: 6544391Abstract: A reactor assembly for electrochemically processing a microelectronic workpiece is set forth. The reactor assembly includes a processing bowl having one or more fluid inlets through which a flow of processing fluid is received. An electrode assembly is located within the process bowl in a fluid flow path of the fluid provided through the one or more fluid inlets. The electrode assembly includes a mesh electrode and a diffuser disposed in the fluid flow path prior to the mesh electrode to tailor the flow of processing fluid received from the one or more fluid inlets through the mesh electrode in a predetermined manner.Type: GrantFiled: October 17, 2000Date of Patent: April 8, 2003Assignee: Semitool, Inc.Inventor: Steven L. Peace
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Publication number: 20030062259Abstract: A plurality of polarizable electrodes, a laminate of a collector layer, a polarizable electrode layer of a porous sheet, and a carbon-based conductive material interposed therebetween, are disposed in a row arrangement, interposing separators between the polarizable electrodes, and an electrolyte is packed between said polarizable electrodes and said separators; the carbon-based conductive material penetrating into the voids in the polarizable electrode layers. A process is provided whereby the polarizable electrode is manufactured by applying a conductive material solution to the collector and/or polarizable electrode sheet surface, superposing the two, and then evaporating out the dispersion medium of the conductive material solution.Type: ApplicationFiled: April 1, 2002Publication date: April 3, 2003Inventors: Naofumi Mushiake, Koshi Inoue, Robert L. Sassa
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Patent number: 6527923Abstract: An electrode of use in electrolytic cells, particularly water electrolyser cells for the production of hydrogen, and comprising an electrically conductive first metal sheet having an electrochemically active gas-evolving planar surface; an electrically conductive second metal electrochemically active gas-evolving screen intimately adjacent and parallel to the planar surface to define an electrolyte and gas-evolving chamber between the sheet and the screen having a narrow width. The electrode provides improvements in voltage and efficiency, longer-term electrode stability and opportunity for periodic depolarization.Type: GrantFiled: March 22, 2001Date of Patent: March 4, 2003Inventors: Donald W. Kirk, John W Graydon
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Publication number: 20030019758Abstract: Improved methods and devices for the synthesis of hydrogen peroxide employing redox catalysts in a gas diffusion electrode or membrane electrode assembly in a semi-chemical/electrochemical system for the production of high purity, stable, usually acidic, aqueous solutions of peroxide at high conversion efficiencies without requiring organic solvents.Type: ApplicationFiled: July 19, 2002Publication date: January 30, 2003Applicant: The Electrosynthesis Company, Inc.Inventor: Ramanathan Gopal
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Patent number: 6511768Abstract: This invention relates to electrode substrates for electrochemical cells, particularly low-temperature fuel cells, and processes for their production. Graphitized fiber web structures are used that have a preferred non-planar fiber alignment resulting in high through-plane conductivity. These structures are further impregnated and processed to adjust the final product properties.Type: GrantFiled: March 1, 2001Date of Patent: January 28, 2003Assignee: SGL Carbon AGInventors: Victor Trapp, Peter Wilde, Heiko Leinfelder
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Publication number: 20030010649Abstract: An anode structure suitable for an electrochemical process is disclosed. The anode comprises a primary anode structure, also referred to as an anode frame, and a secondary metal substrate attached to the anode frame. The anode frame is a structural support and suitable electrical conductor. The metal substrate has an electrocatalytic coating and provides the anode with an anodic surface. The metal substrate is easily removable from the anode frame. Also disclosed is a method for refurbishing anodes according to the present invention. An anode comprising an anode frame and a metal substrate is refurbished by removing a depleted metal substrate from the frame and attaching a separate precoated metal substrate to the frame. The method of refurbishing optionally includes refurbishing the depleted metal substrate and using the refurbished substrate to refurbish the anode structure. A method for providing replacement anodes is also disclosed.Type: ApplicationFiled: July 16, 2001Publication date: January 16, 2003Inventors: Michael D. Waite, E. Michael Horonzy
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Patent number: 6503377Abstract: An electrolysis apparatus for producing halogen gases from aqueous alkali halide solution, having a number of plate-like electrolysis cells which are arranged beside one another in a stack and are in electrical contact and which each have a housing comprising two half-shells of electrically conductive material with external contact strips on at least one housing rear wall, and in each case having two essentially flat electrodes (anode and cathode) and the anode and cathode being provided with apertures like venetian blinds for the electrolysis starting materials and the electrolysis products to flow through, being separated from one another by a dividing wall and arranged parallel to one another and being electrically conductively connected to the respective associated rear wall of the housing by means of metal reinforcements, is intended to provide a solution with which, even at current densities above 4 kA/m2 and correspondingly increased production of gas in the boundary layer, it is possible to operate whType: GrantFiled: October 12, 2000Date of Patent: January 7, 2003Assignee: Krupp UHDE GmbHInventors: Thomas Borucinski, Jürgen Gegner, Karl-Heinz Dulle, Martin Wollny
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Patent number: 6503655Abstract: A thin, flat, and porous carbon gas diffusion electrode having a side in contact with a supply of gas and a side in contact with an electrolyte, comprises a pyrolysis product of a composite of an organic aerogel or xerogel and a reinforcing skeleton consisting at least in part of organic material. The porosity of the carbon gas diffusion electrode according to the invention can be regulated at will while the surface of the electrode is smooth.Type: GrantFiled: May 19, 2000Date of Patent: January 7, 2003Assignee: Siemens AktiengesellschaftInventors: Raino Petricevic, Jochen Fricke, Rainer Leuschner, Matthias Lipinski