Abstract: A cathode boss structure for an aluminum electrolytic cell is disclosed. The cathode boss is arranged on the top surface of the cathode carbon block or on the top of the gap between two cathode carbon blocks. The distance between cathode bosses is 400 mm-900 mm. The length of the throughout elongate cathode boss is 100-250 mm longer than that of cathode carbon block, and two ends thereof are directly embedded into the paste around lateral portion. The length of the embedded and butted cathode boss is in a range of 3000-3200 mm, two ends thereof are fixed by binding carbon blocks respectively, and the binding carbon blocks are embedded into the paste around lateral portion. The cross-section of the cathode boss structure is in the shape of rectangle or isosceles trapezoid. The cathode boss structure is applicable to all types of current electrolytic cells.

Abstract: An electrode for use in a electrochemical sensor comprises carbon modified with a chemically sensitive redox-active compound, excluding an electrode based on carbon having derivatised thereron two redox-active species wherein at least one of said species is selected from anthraquinone, phenanthrenequinone and N,N?-diphenyl-p-phenylenediamine (DPPD). The invention further provides a pH sensor comprising: a working electrode comprising carbon modified with a chemically sensitive redox active material; and a counter electrode, wherein the ratio of the surface area of the working electrode to the surface area of the counter electrode is from 1:10 to 10:1. Also provided is a pH sensor comprising: a working electrode comprising carbon modified with a chemically sensitive redox active material, and a counter electrode, wherein the area of the working electrode is from 500 ?m2 to 0.1 m2. The uses of these electrodes and sensors are also described.

Abstract: An electrode comprises an acid treated, cathodically cycled carbon-comprising film or body. The carbon consists of single walled nanotubes (SWNTs), pyrolytic graphite, microcrystalline graphitic, any carbon that consists of more than 99% sp2 hybridized carbons, or any combination thereof. The electrode can be used in an electrochemical device functioning as an electrolyser for evolution of hydrogen or as a fuel cell for oxidation of hydrogen. The electrochemical device can be coupled as a secondary energy generator into a system with a primary energy generator that naturally undergoes generation fluctuations. During periods of high energy output, the primary source can power the electrochemical device to store energy as hydrogen, which can be consumed to generate electricity as the secondary source during low energy output by the primary source. Solar cells, wind turbines and water turbines can act as the primary energy source.

Abstract: The present invention provides an electrically conductive diamond electrode comprising an electrically conductive substrate and an electrically conductive diamond layer coated on the surface of the electrically conductive substrate, featuring that: 1) the thickness of the electrically conductive diamond layer is 1˜25 ?m, 2) the potential window fulfills Equation (1) and 3) the ratio (A/B) of the diamond component A and the non-diamond component B by the Raman spectroscopic analysis fulfills Equation (2). 2.1V?potential window?3.5V??(1) 1.5<A/B?6.5??(2) A: Intensity at the wave number 1300 cm?1 by the Raman spectroscopic analysis B: Intensity at the wave number 1500 cm?1 by the Raman spectroscopic analysis.

Abstract: The present invention discloses replaceable cathode choking devices of an aluminum reduction cell which comprises cathode carbon blocks and cathode choking devices placed at the bottom of the aluminum reduction cell. The cathode choking devices are placed on surfaces of the cathode carbon blocks. The cathode choking devices are made of mullite, spinel or zirconite which is high temperature resistant, corrosion resistant and of high specific gravity. The cathode choking devices have a cross-section of semicircular, arc or streamline shape. The cathode choking devices have a height of 50-150 mm and a width of 100-300 mm. The cathode choking devices are elongated block-shaped. The cathode choking devices are placed in a direction along a long side of a cathode of the reduction cell, wherein one or more cathode choking devices are placed as a group.

Abstract: A biosensor includes a plurality of electrodes and a receptor. The plurality of electrodes comprises a plurality of carbon nanotubes. The receptor are located between the plurality of electrodes and electrically connected to the plurality of carbon nanotubes of the plurality of electrodes. In addition, the receptor reacts to a measured object to lead current variation which is transmitted by the plurality of electrodes.

Abstract: The invention describes an electrode and an electrode coating which are based on a catalyst containing finely divided carbon modifications and noble metal (oxide)s.

Abstract: A microlectrode comprising a diamond layer formed from electrically non-conducting diamond and containing one or more pins or projections of electrically conducting diamond extending at least partially through the layer of non-conducting diamond presenting areas of electrically conducting diamond.

Abstract: A corrosion-resistant ceramic electrode material includes ceramic particles and, present between them, a three-dimensional network electroconducting path composed of a reductively fired product of a carbon-containing polymeric compound. This material is manufactured by a method in which a polymerization reaction of a polymerizable monomer previously contained in a ceramic slurry is performed to gel the ceramic slurry to thereby give a green body; and after drying and degreasing, the green body is fired in a reducing atmosphere.

Abstract: The present invention relates to a process for activating a diamond-based electrode, which includes a step consisting in subjecting, in the presence of an aqueous solution containing an ionic electrolyte, said electrode to an alternately cathodic and anodic polarization potential, of increasing amplitude so as to obtain an anodic and cathodic current density of between 10 ?A/cm2 and 1 mA/cm2. The present invention also relates to a diamond-based electrode activated by said process and to the uses thereof.

Abstract: A multi-layer cathode block (30) for an electrolytic cell (10) has at least a surface layer (32) with a surface expansion index and a second layer (34) with a second expansion index. The surface layer (32) includes a surface wetting agent in a first total amount. The second layer (34) includes a wetting agent in a second total amount. The surface layer (32) is directly superposed to the second layer (34). The second wetting agent in the second layer (34) includes metal boride precursors that react together to generate a metal boride component in situ when the cathode block (30) is exposed to start-up and operation conditions of the electrolytic cell (10). The second total amount is lower than the first total amount and is selected so as to minimize the difference between the expansion indexes of the surface layer (32) and the second layer (34).

Abstract: The present invention relates to an electrode composed of carbon having at least two different zones, wherein an outer zone (A) forms the base of the electrode and carries one or more inner zones, wherein the innermost zone (B) projects from the zone (A) at the top and has a lower specific thermal conductivity than zone (A).

Abstract: An electrode comprising an electrically conducting diamond plate wherein the diamond plate comprises at least one elongate aperture and having an aperture edge length per unit working area of the diamond plate of greater than about 4 mm/mm2, electrolysis cells comprising such electrodes, methods of treating water using such electrolysis cells and a method of production of ozone are disclosed.

Abstract: An apparatus is disclosed for electroplating an inside wall of a transfer mold, the transfer mold being suitable for use in semiconductor device encapsulation. Specifically, the apparatus comprises a fixture, as well as a through-hole in the fixture for receiving an electrode to electroplate the inside wall of the transfer mold. In particular, the through-hole is configured to receive the electrode in a slide-fit to form a mutual interference fit for securing the electrode to the fixture. Upon fitting the electrode into the through-hole, the apparatus can then be used to electroplate the inside wall of the transfer mold by introducing the electrode into the space adjacent to the inside wall of the transfer mold. A device for use as an electrode in the apparatus is also disclosed.

Abstract: The present invention provides a conductive diamond electrode structure for use in electrolytic synthesis of a fluorine-containing material with a fluoride ion-containing molten salt electrolytic bath, which comprises: a conductive electrode feeder; and a conductive diamond catalyst carrier comprising a conductive substrate and a conductive diamond film carried on a surface thereof, wherein the conductive diamond catalyst carrier is detachably attached to the conductive electrode feeder at a portion to be immersed in the electrolytic bath. Also disclosed is an electrolytic synthesis of a fluorine-containing material using the conductive diamond electrode structure.

Abstract: The invention relates to modified electrodes for ER fluids prepared by adding a rough, wear-resisting, and low conductive modified layer on the surface of metallic electrodes. The material for the modified layer can be at least one from diamond, alumina, titanium dioxide, carborundum, titanium nitride, nylon, polytetrafluoroethylene, adhesive, and adhesive film. Through the addition of the modified layer, the adhesion of the ER fluid to electrodes is increased so that the shear stress measured near the plates is close to the intrinsic value, which makes the ER fluid applicable, while reducing the leakage current and increasing the breakdown voltage of the ER fluid equipment.

Abstract: The present invention provides a process for producing an electrode for electrochemical reaction, wherein a conductive diamond layer is formed on an electrode substrate in the electrode; and the electrode substrate on which the conductive diamond layer is formed is kept at a temperature of 400° C. or more and 1,000° C. or less in a water vapor, thereby forming a micropore in the conductive diamond layer. Also, the present invention provides an electrode for electrochemical reaction obtained by the foregoing production process.

Abstract: The present invention provides a solid diamond electrode, a reactor, in particular a reactor comprising an anode, a cathode and at least one bipolar electrode having first and second major working surfaces positioned therebetween wherein the at least one bipolar electrode consists essentially of diamond, and methods in which the reactors are used.

Abstract: A gas generating device of present invention is generated a first gas at a first carbon electrode by applying a voltage between said first carbon electrode and a second electrode to electrolyzing an electrolytic solution. The first carbon electrode is an anode or a cathode. The first carbon electrode is provided with a plurality of fine gas flow channels which selectively pass said first gas generated on one surface of said first carbon electrode to the other surface without allowing said electrolytic solution to permeate therethrough.

Abstract: Activated carbon used for an electrochemical element in which when W1 and W2 satisfy 1.0 nm?W1<W2?2.0 nm, a total pore volume of the activated carbon in which a slit width obtained by an MP method is W1 or more and W2 or less is 15% or more of a total pore volume of the activated carbon in which the slit width obtained by the MP method is 2.0 nm or less. Furthermore, an electrode layer of the electrochemical element includes activated carbon having a large pore volume in which the slit width is W1 or more and W2 or less.

Abstract: A carbonaceous substrate of the present invention is such that an X-ray diffraction pattern thereof is a complex profile and includes at least two (002) diffraction lines; and the substrates contains crystallites with different interlayer spacings. Further, in the X-ray diffraction pattern, (002) diffraction lines between 2?=10° and 2?=30° have an asymmetric shape; and the X-ray diffraction pattern includes at least two pattern components which are a diffraction line whose center is at 2?=26° and a diffraction line whose center is at a lower angle than 2?=26°. Further, the carbonaceous substrate contains crystals wherein the periodic distance d002 is 0.34 nm or more and the crystallite size Lc002 is 20 nm or less based on the X-ray diffraction lines. An electrodes for fluorine electrolysis of the present invention includes the carbonaceous substrate on which a conductive diamond thin film is formed.

Abstract: The present invention relates to a conductive diamond electrode, comprising a substrate having a plurality of convex and concave part disposed over the entire surface of the conductive diamond electrode, and a diamond film coated on the surface of said substrate, wherein the width of each convex part of said convex and concave part is in a range from 0.2 mm to 1 mm. The present invention can provide a conductive diamond electrode, applying a thin film of conductive diamond and a thick substrate, being less expensive than a self-supported type conductive diamond electrode and also having mechanical strength enough to be used in the zero-gap electrolysis, functioning stably for a long time with smooth water supply or gas liberation, and an ozone generator using the conductive diamond electrode.

Abstract: The present invention provides a solid diamond electrode, a reactor, in particular a reactor comprising an anode, a cathode and at least one bipolar electrode having first and second major working surfaces positioned therebetween wherein the at least one bipolar electrode consists essentially of diamond, and methods in which the reactors are used.

Abstract: Nanoscale probes for forming stable, non-destructive seals with cell membranes. The probes, systems including these probes, and methods of fabricating and using the probes described herein may be used to sense from, stimulate, modify, or otherwise effect individual cells or groups of cells. In particular, described herein are nanoscale cellular probes that may be used to span the lipid membrane of a cell to provide stable and long lasting access to the internal cellular structures. Thus, the probes described herein may be used as part of a system, method or device that would benefit from stable, non-destructive access across a cell membrane. In some variations the nanoscale probe devices or systems described herein may be used as part of a drug screening procedure.

Abstract: A new invention in cathode composition, arrangement, and design for primary and secondary batteries that offers high power, high capacity, and high specific energy is proposed herein. The claimed technology described herein incorporates materials into the cathode that results in a cathode which may accept two electrons per active site. Other advantages of the technology included herein include: 1) lower cost, 2) environmental friendliness, 3) safety, 4) a wide operational temperature range, 5) backwards compatibility with present electrochemical cells, and 6) versatility. The technology is cross-cutting, and has high impact applications, such as for electric vehicles, which require both high power and high specific energy.

Abstract: The embodiments of the invention relate to an electrode for electrolysis comprising an electrode substrate and a coating of the electrode substrate with a polycrystalline diamond material, that the electrode substrate consists of a base body of carbon material and at least one contact layer of the electrode substrate carrying the coating consists of a non-metallic, electrically conductive material.

Abstract: Devices and methods for electrochemical phase transfer utilize at least one electrode formed from either glassy carbon or a carbon and polymer composite. The device includes a device housing defining an inlet port (42), an outlet port (44) and an elongate fluid passageway (36) extending therebetween. A capture electrode (12) and a counter electrode are positioned within said housing such that the fluid passageway extends between the capture and counter electrodes.

Abstract: An electrolytic cell includes at least one free-standing diamond electrode and a second electrode, which may also be a free-standing diamond, separated by a membrane. The electrolytic cell is capable of conducting sustained current flows at current densities of at least about 1 ampere per square centimeter. A method of operating an electrolytic cell having two diamond electrodes includes alternately reversing the polarity of the voltage across the electrodes.

Abstract: A transition metal/carbon nanotube composite includes a carbon nanotube and a transition metal oxide coating layer disposed on the carbon nanotube. The transition metal oxide coating layer includes a nickel-cobalt oxide.

Abstract: The subject of the invention is an anode block (13, 13a-13e) made of carbon for a pre-baked anode (4) for use in a metal electrolysis cell (1) comprising a higher face (24), a lower face (23), designed to be laid out opposite a higher face of a cathode (9), and four side faces (21,22,34), and including at least one first groove (31a-31e) leading onto at least one of the side faces, in which the first groove has a maximum length Lmax in a plane parallel to the lower face, and characterized in that the first groove does not lead onto said lower or higher faces, or leads onto said lower or higher faces over a length L0 less than half the maximum length Lmax.

Abstract: A microelectrode comprising a diamond layer formed from electrically non-conducting diamond and containing one or more pins or projections of electrically conducting diamond extending at least partially through the layer of non-conducting diamond and presenting areas of electrically conducting diamond.

Abstract: A method for producing a diamond electrode comprising synthetically produced and electrically conductive (doped) diamond particles, which are embedded into a support layer of electrically non-conductive material. The doped diamond particles are introduced as a single layer between two films that form the support layer, the films then being permanently connected to each other and the diamond particles being exposed on both sides of the support layer.

Abstract: The hydrogen-oxygen generating electrode plate using a carbon nano tube includes a carbon nano tube (CNT); a carbon (C); NiO; NaTaO3; and a catalyst. The method for manufacturing a hydrogen and oxygen generating electrode plate using a carbon nano tube, includes a step S1 for grinding into high-density powders; a step S2 for uniformly mixing carbon nano tube powder, carbon powder, NiO powder, NaTaO3 powder and catalyst and forming a mixture having a high distribution degree; a step S3 for inputting the mixture into a mold and pressing the same and forming a pressing forming object; and a step S4 for plasticity-forming the pressing forming object in a vacuum plasticity furnace.

Abstract: A gas diffusion substrate includes a non-woven network of carbon fibres, the carbon fibres are graphitised but the non-woven network has not been subjected to a graphitisation process. A mixture of graphitic particles and hydrophobic polymer is disposed within the network. The longest dimension of at least 90% of the graphitic particles is less than 100 ?m. A process for manufacturing gas diffusion substrates includes depositing a slurry of graphitised carbon fibres onto a porous bed forming a wet fibre network, preparing a suspension of graphitic particles and hydrophobic polymer, applying onto, and pulling the suspension into, the network, and drying and firing the network. Another process includes mixing a first slurry of graphitic particles and hydrophobic polymer with a second slurry of graphitised carbon fibres and liquid forming a third slurry, depositing the third slurry onto a porous bed forming a fibre-containing layer, and drying and firing the layer.

Abstract: In embodiments there are disclosed a substantially flat, flow through electrode, electrochemical cells comprising substantially flat flow through cathodes, and methods for electrochemically recovering a metal substantially liquid at room temperature.

Abstract: An electrode is described completely made of graphenes or containing high amounts of these compounds in mixture with nanostructured or non-nanostructured carbon-based materials. An electrooxidation process for the removal of contaminants from liquids, and a reactor for performing the process, based on the use of said electrodes, are also described.

Abstract: Microelectrode comprising a body formed from electrically non-conducting material and including at least one region of electrically conducting material and at least one passage extending through the body of non-conducting material and the region of conducting material, the electrically conducting region presenting an area of electrically conducting material to a fluid flowing through the passage in use. An electrochemical cell which includes such a microelectrode is also disclosed.

Abstract: The invention relates to novel compositions of disubstituted bipyridyl osmium complexes useful for the synthesis of labeled proteins, nucleic acids, and for the modification of electrodes.

Abstract: Nanostructured microelectrodes and biosensing devices incorporating the same are disclosed herein.

Abstract: The present invention relates to a carbon electrode having a conical or pyramidal tip, wherein the tip is surrounded on its side by a raised edge.

Abstract: The present invention provides a process for producing an electrode for electrochemical reaction, wherein a conductive diamond layer is formed on an electrode substrate in the electrode; and the electrode substrate on which the conductive diamond layer is formed is kept at a temperature of 400° C. or more and 1,000° C. or less in a water vapor, thereby forming a micropore in the conductive diamond layer. Also, the present invention provides an electrode for electrochemical reaction obtained by the foregoing production process.

Abstract: An electrode for electrochemical water treatment, the electrode including a nanodiamond and a conducting agent.

Abstract: Method for manufacturing anodes used for the production of aluminium by fused bath electrolysis, said anodes comprising an anode stem made of a conducting metal and at least one block made of carbonaceous material called an anode block, said method including at least the following steps: a) obtain an anode stem; b) obtain a new anode block; c) fix one end of the anode stem onto the anode block, so as to give good mechanical attachment and good electrical connection between said stem and said anode block; said method being characterised in that before, during or after step c), but before placement of said anode in the electrolytic cell, a protective layer with a controlled thickness, typically between 5 and 25 cm composed of a material resistant to temperature and corrosion by the medium above the electrolytic bath is at least partially deposited on the upper surface of said anode block.

Abstract: An electroactivated film that includes: a first electrode that is spaced apart from a second electrode, a water insoluble electrically conductive medium which is permeable to moisture and oxygen and which contacts both electrodes, an electrocatalyst which can be reversibly oxidized and reduced and which facilitates the production of a peroxide when an electrical potential is imposed across the electrodes, and optionally a peroxide-activating catalyst which converts the peroxide to an activated peroxide, wherein one or both electrodes have electrocatalyst immobilized thereupon.

Abstract: An auto-calibration system for diagnostic test strips is described for presenting data individually carried on each test strip readable by a diagnostic meter. The carried data may include an embedded code relating to data particular to that individual strip. The data is presented so as to be read by a meter associated with the diagnostic test strip in order to avoid manually inputting the information.

Abstract: A diamond electrode includes a conductive silicon substrate having a plurality of pores. The diamond electrode also includes a conductive diamond covering the conductive silicon substrate. The inner wall surfaces of the plurality of pores are at an angle of 60° to 85° with respect to a substrate of the conductive silicon substrate.

Abstract: The present invention relates to a process for activating a diamond-based electrode, which includes a step consisting in subjecting, in the presence of an aqueous solution containing an ionic electrolyte, said electrode to an alternately cathodic and anodic polarization potential, of increasing amplitude so as to obtain an anodic and cathodic current density of between 10 ?A/cm2 and 1 mA/cm2. The present invention also relates to a diamond-based electrode activated by said process and to the uses thereof.

Abstract: An electrolytic cell is provided that can include: a first electrode plate including a first surface that can include a graphite material; a second electrode plate including a second surface that can include a graphite material opposing the first surface; an electrolytic reaction zone between the first surface and the second surface; and an inlet to and an outlet from the electrolytic reaction zone. The first electrode plate and the second electrode plate can include resin-impregnated monolithic graphite plates. The first electrode plate and the second electrode plate can form opposite internal walls of a chamber for the electrolytic reaction and thus can be provided without a container for containing the electrode plates. Methods are also provided for flow-through-resin-impregnating porous, monolithic graphite plates to form electrode plates.

Abstract: A method of producing aluminium in a Hall-Héroult cell with prebaked anodes, as well as anodes for the same. The anodes are provided with slots in a wear (bottom) surface thereof for gas drainage. The slots are 2-8 millimeters wide, and preferably 3 millimeters.

Abstract: A cathodic material for use in an electrochemical sensor comprising: a carbonaceous material and an oxygen reduction catalyst associated with the carbonaceous material; and wherein the cathodic material does not materially exhibit catalytic activity for the oxidation of carbon monoxide. Associated electrochemical sensors may include an anode and cathode that are disposed upon the same or opposite sides of an ion exchange membrane and/or exposed to the same or different gaseous environments.