Silver Patents (Class 205/263)
  • Patent number: 9637833
    Abstract: A copper plating solution which contains compounds with the structure —X—S—Y— where X and Y are, independently of each other, atoms selected from a group consisting of hydrogen, carbon, sulfur, nitrogen, and oxygen, and X and Y can be the same only if they are carbon atoms and aliphatic semialdehydes. By using this copper electroplating solution it is possible to form good filled vias without worsening the appearance of the plating.
    Type: Grant
    Filed: December 24, 2012
    Date of Patent: May 2, 2017
    Inventors: Matsuko Saito, Makoto Sakai, Shinjiro Hayashi
  • Patent number: 8986434
    Abstract: Compositions and methods for silver plating onto metal surfaces such as PWBs in electronics manufacture to produce a silver plating which is greater than 80 atomic % silver, tarnish resistant, and has good solderability.
    Type: Grant
    Filed: January 7, 2013
    Date of Patent: March 24, 2015
    Assignee: Enthone Inc.
    Inventors: Yung-Herng Yau, Thomas B. Richardson, Joseph A. Abys, Karl F. Wengenroth, Anthony Fiore, Chen Xu, Chonglun Fan, John Fudala
  • Publication number: 20150027899
    Abstract: Provided is an anode for electroplating which uses an aqueous solution as an electrolytic solution, and the anode which is low in potential when compared with a conventional anode, able to decrease an electrolytic voltage and an electric energy consumption rate and may also be used as an anode for electroplating various types of metals, and which is low in cost. Also provided is a method for electroplating which uses an aqueous solution as an electrolytic solution, in which the anode is low in potential and electrolytic voltage, thereby making it possible to decrease the electric energy consumption rate. The anode for electroplating of the present invention is an anode for electroplating which uses an aqueous solution as an electrolytic solution, in which a catalytic layer containing amorphous ruthenium oxide and amorphous tantalum oxide is formed on a conductive substrate.
    Type: Application
    Filed: August 31, 2012
    Publication date: January 29, 2015
    Applicant: THE DOSHISHA
    Inventor: Masatsugu Morimitsu
  • Publication number: 20150017554
    Abstract: A process for producing oxygen-consuming electrodes, in particular for use in chloralkali electrolysis, which display good transport capability and storage capability. In the process, a silver oxide-containing sheet-like structure as intermediate is electrochemically reduced. Also disclosed are methods of using these electrodes in chloralkali electrolysis or fuel cell technology or in metal-air batteries, and the fuel cells and metal-air batteries produced.
    Type: Application
    Filed: July 10, 2014
    Publication date: January 15, 2015
    Applicant: BAYER MATERIALSCIENCE AG
    Inventors: Andreas BULAN, Rainer WEBER, Michael STELTER, Hartmund BOMBACH, Katja PALM
  • Patent number: 8877630
    Abstract: The present disclosure provides a method for manufacturing a semiconductor structure. The method includes forming a conductive pad on a semiconductor die; forming a seed layer over the conductive pad; defining a first mask layer over the seed layer; and forming a silver alloy bump body in the first mask layer. The forming a silver alloy bump body in the first mask layer includes operations of preparing a first cyanide-based bath; controlling a pH value of the first cyanide-based bath to be within a range of from about 6 to about 8; immersing the semiconductor die into the first cyanide-based bath; and applying an electroplating current density of from about 0.1 ASD to about 0.5 ASD to the semiconductor die.
    Type: Grant
    Filed: November 12, 2013
    Date of Patent: November 4, 2014
    Assignee: ChipMos Technologies Inc.
    Inventors: Shih Jye Cheng, Tung Bao Lu
  • Patent number: 8608932
    Abstract: A cyanide-free silver electroplating solution may be used to electroplate mirror bright silver layers at high current density ranges and at high temperatures such as in reel-to-reel electroplating. The cyanide-free silver electroplating solution is environmentally friendly.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: December 17, 2013
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Margit Clauss, Wan Zhang-Beglinger
  • Publication number: 20130264215
    Abstract: The present invention relates to an anode system for conventional electrolysis cells, a process for the production thereof and its use for the deposition of electrolytic coatings. The anode system is characterized in that the anode (2) is in direct contact with a membrane (3) which completely separates the anode space from the cathode space. This anode system is therefore a direct-contact membrane anode.
    Type: Application
    Filed: December 8, 2011
    Publication date: October 10, 2013
    Applicant: UMICORE GALVANOTECHNIK GMBH
    Inventors: Bernd Weyhmueller, Franz Kohl, Uwe Manz, Klaus Bronder, Frank Oberst, Mario Tomazzoni
  • Publication number: 20130256145
    Abstract: Silver electroplating baths having certain sulfide compounds and methods of electrodepositing a silver-containing layer using these baths are disclosed. Such electroplating baths are useful to provide silver-containing solder deposits having reduced void formation and improved within-die uniformity.
    Type: Application
    Filed: March 30, 2012
    Publication date: October 3, 2013
    Applicants: Dow Global Technologies LLC, Rohm and Haas Electronic Materials LLC
    Inventors: Duane R. Romer, Elissei Iagodkine, Inho Lee
  • Patent number: 8524629
    Abstract: Presented are one or more aspects and/or one or more embodiments of catalysts, methods of preparation of catalyst, methods of deoxygenation, and methods of fuel production.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: September 3, 2013
    Assignee: Energia Technologies, Inc.
    Inventors: Thien Duyen Thi Nguyen, Krishniah Parimi
  • Patent number: 8507400
    Abstract: Presented are one or more aspects and/or one or more embodiments of catalysts, methods of preparation of catalyst, methods of deoxygenation, and methods of fuel production.
    Type: Grant
    Filed: March 1, 2012
    Date of Patent: August 13, 2013
    Assignee: Energia Technologies, Inc.
    Inventors: Thien Duyen Thi Nguyen, Krishniah Parimi
  • Publication number: 20130199936
    Abstract: Electrodeposition involving an electrolyte having a surface-smoothing additive can result in self-healing, instead of self-amplification, of initial protuberant tips that give rise to roughness and/or dendrite formation on the substrate and/or film surface. For electrodeposition of a first conductive material (C1) on a substrate from one or more reactants in an electrolyte solution, the electrolyte solution is characterized by a surface-smoothing additive containing cations of a second conductive material (C2), wherein cations of C2 have an effective electrochemical reduction potential in the solution lower than that of the reactants.
    Type: Application
    Filed: June 13, 2012
    Publication date: August 8, 2013
    Applicant: BATTELLE MEMORIAL INSTITUTE
    Inventors: Jiguang Zhang, Wu Xu, Gordon L. Graff, Xilin Chen, Fei Ding, Yuyan Shao
  • Patent number: 8449754
    Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.
    Type: Grant
    Filed: September 2, 2011
    Date of Patent: May 28, 2013
    Assignee: HNO Greenfuels, Inc.
    Inventor: Donald Wade Owens
  • Publication number: 20130022761
    Abstract: The present invention relates to a silver complex obtained by reacting at least one silver compound represented by the formula 2 below with at least one ammonium carbamate compound or ammonium carbonate compound represented by the formula 3, 4 or 5 below:
    Type: Application
    Filed: May 11, 2012
    Publication date: January 24, 2013
    Applicant: Inktec Co., Ltd.
    Inventors: Kwang-Choon Chung, Hyun-Nam Cho, Myoung-Seon Gong, Yi-Sup Han, Jeong-Bin Park, Dong-Hun Nam, Seong-Yong Uhm, Young-Kwan Seo
  • Patent number: 8337688
    Abstract: Disclosed are metal plating compositions for plating a metal on a substrate. The metal plating compositions include compounds which influence the leveling and throwing performance of the metal plating compositions. Also disclosed are methods of depositing metals on a substrate.
    Type: Grant
    Filed: August 15, 2011
    Date of Patent: December 25, 2012
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Erik Reddington, Gonzalo U. Desmaison, Zukra I. Niazimbetova, Donald E. Cleary, Mark Lefebvre
  • Patent number: 8329018
    Abstract: Disclosed are metal plating compositions and methods. The metal plating compositions provide good leveling performance and throwing power.
    Type: Grant
    Filed: September 6, 2011
    Date of Patent: December 11, 2012
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Erik Reddington, Gonzalo U. Desmaison, Zukra I. Niazimbetova, Donald E. Cleary, Mark Lefebvre
  • Publication number: 20120298519
    Abstract: An electrolytic composition for the deposition of a matt metal layer onto a substrate and deposition process where the composition comprises a source of metal from the group consisting of Cr, Mn, Fe, Co, Ni, Cu, Zn, Ru, Rh, Pd, Ag, In, Sn, Sb, Re, Pt, Au, Bi, and combinations thereof; a substituted or unsubstituted polyalkylene oxide or its derivative as an emulsion and/or dispersion former; and a compound comprising fluorated or perfluorated hydrophobic chains or which is a polyalkylene oxide substituted quaternary ammonium compound as wetting agent; wherein the electrolytic composition forms a microemulsion and/or dispersion.
    Type: Application
    Filed: June 4, 2012
    Publication date: November 29, 2012
    Applicant: ENTHONE INC.
    Inventors: Andreas Königshofen, Danica Elbick, Christoph Werner, Wolfgang Clauberg, Peter Pies, Andreas Möbius
  • Patent number: 8273465
    Abstract: A slide member including a base material; and an overlay that is formed over the base material and that consists of Ag or Ag alloy including crystal planes (hk1) represented by Miller indices; wherein a relative X-ray diffraction intensity of crystal plane (200) to a sum of X-ray diffraction intensities of crystal planes (200), (111), (220), (311), and (222) of the overlay ranges between 1%?(200)/{(200)+(111)+(220)+(311)+(222)}?20% and the relative X-ray diffraction intensity of the crystal plane (200) to the X-ray diffraction intensity of the crystal plane (111) ranges between 1%?(200)/(111)?30%.
    Type: Grant
    Filed: March 24, 2010
    Date of Patent: September 25, 2012
    Assignee: Daido Metal Company Ltd.
    Inventors: Manabu Izumida, Hideo Tsuji
  • Patent number: 8192606
    Abstract: A device and a method for metallic electrolytic coating of an object of electrically conductive material, wherein the object has at least two surface portions that are desired to be coated with layers of different thicknesses. The device includes an anode. The device is designed to receive the object in such a way that the object constitutes a cathode and that, upon receipt of the object, a space is formed for receiving a liquid-absorbing material and an electrolyte for coating the object. The body of the anode includes at least two surface portions) that have different electrical conductivity and that are arranged opposite to the surface portions of the received object.
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: June 5, 2012
    Assignee: ABB Technology Ltd.
    Inventor: Jan Haglund
  • Patent number: 8152914
    Abstract: Described is a new process for applying a metal coating to a non-conductive substrate comprising the steps of (a) contacting the substrate with an activator comprising a noble metal/group IVA metal sol to obtain a treated substrate, (b) contacting said treated substrate with a composition comprising a solution of: (i) a Cu(II), Ag, Au or Ni soluble metal salt or mixtures thereof, (ii) 0.05 to 5 mol/l of a group IA metal hydroxide and (iii) a complexing agent for an ion of the metal of said metal salt, wherein an iminosuccinic acid or a derivative thereof is used as said complexing agent.
    Type: Grant
    Filed: April 24, 2008
    Date of Patent: April 10, 2012
    Assignee: Atotech Deutschland GmbH
    Inventors: Sigrid Schadow, Brigitte Dyrbusch, Carl Christian Fels
  • Publication number: 20120067733
    Abstract: A silver electroplating solution is used to electroplate a mirror bright silver layer on a nickel or nickel alloy substrate. The silver electroplating solution is cyanide-free and environmentally friendly.
    Type: Application
    Filed: September 21, 2011
    Publication date: March 22, 2012
    Applicant: Rohm and Haas Electronic Materials LLC
    Inventors: Wan ZHANG-BEGLINGER, Edit SZÖCS, Margit CLAUSS
  • Publication number: 20120067735
    Abstract: A cyanide-free silver electroplating solution may be used to electroplate mirror bright silver layers at high current density ranges and at high temperatures such as in reel-to-reel electroplating. The cyanide-free silver electroplating solution is environmentally friendly.
    Type: Application
    Filed: September 21, 2011
    Publication date: March 22, 2012
    Applicant: Rohm and Haas Electronic Materials LLC
    Inventors: Margit Clauss, Wan Zhang-Berlinger
  • Publication number: 20120040202
    Abstract: The invention relates to the field of materials science and material physics and relates to a coated magnetic alloy material, which can be used, for example, as a magnetic cooling material for cooling purposes. The object of the present invention is to disclose a coated magnetic alloy material, which has improved mechanical and/or chemical properties. The object is attained with a magnetic alloy material with a NaZn13 type crystal structure and a composition according to the formula RaFe100-a-x-y-zTxMyLz and the surface of which is coated with a material composed of at least one element from the group Al, Si, C, Sn, Ti, V, Cd, Cr, Mn, W, Co, Ni, Cu, Zn, Pd, Ag, Pt, Au or combinations thereof The object is furthermore attained by a method in which the magnetic alloy material is coated by means of a method from the liquid phase.
    Type: Application
    Filed: December 10, 2009
    Publication date: February 16, 2012
    Inventors: Julia Lyubina, Mihaela Buschbeck, Oliver Gutfleisch
  • Patent number: 8062500
    Abstract: A method and apparatus for electrolytically producing oxidation reduction potential water from aqueous salt solutions for use in disinfection, sterilization, decontamination, wound cleansing. The apparatus includes an electrolysis unit having a three-compartment cell (22) comprising a cathode chamber (18), an anode chamber (16), and a saline solution chamber (20) interposed between the anode and cathode chambers. Two communicating (24, 26) membranes separate the three chambers. The center chamber includes a fluid flow inlet (21a) and outlet (21b) and contains insulative material that ensures direct voltage potential does not travel through the chamber. A supply of water flows through the cathode and anode chambers at the respective sides of the saline chamber. Saline solution flows through the center chamber, either by circulating a pre-prepared aqueous solution containing ionic species, or, alternatively, by circulating pure water or an aqueous solution of, e.g.
    Type: Grant
    Filed: December 5, 2002
    Date of Patent: November 22, 2011
    Assignee: Oculus Innovative Sciences, Inc.
    Inventor: Osao Sumita
  • Patent number: 8062765
    Abstract: The inventors have conducted vigorous studies, and discovered as a result that it is possible to form a silver layer having a high reflectance of about 90 to 99% in a visible light area by setting a grain size of an outermost surface of a silver plated layer within a range of 0.5 ?m or more to 30 ?m or less.
    Type: Grant
    Filed: July 5, 2007
    Date of Patent: November 22, 2011
    Assignee: Panasonic Electric Works, Ltd.
    Inventors: Youichiro Nakahara, Naoto Ikegawa
  • Patent number: 8048284
    Abstract: Disclosed are metal plating compositions for plating a metal on a substrate. The metal plating compositions include compounds which influence the leveling and throwing performance of the metal plating compositions. Also disclosed are methods of depositing metals on a substrate.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: November 1, 2011
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Erik Reddington, Gonzalo Urrutia Desmaison, Zukhra I. Niazimbetova, Donald E. Cleary, Mark Lefebvre
  • Patent number: 8048572
    Abstract: A lead acid electric storage battery uses conventional lead-acid secondary battery chemistry. The battery may be a sealed battery, an unsealed battery or a conventional multi-cellbattery. It has 12 to 25 cells in a single case. The case is less than 12 inches long and may be less than 6 inches long. The battery has a set of positive battery grids (plates) which are constructed with a core of thin titanium expanded metal having a thickness preferably, for start batteries etc. in the range 0.1 mm to 0.7 mm and most preferably 0.2 mm to 0.4 mm. The grid cores are of a titanium alloy containing a platinum group metal. The cores are coated with hot melt dip lead and are not lead electroplated. The grid cores expand and contract, with temperature changes, much less than conventional lead grids.
    Type: Grant
    Filed: May 3, 2010
    Date of Patent: November 1, 2011
    Inventor: Eliot Samuel Gerber
  • Publication number: 20110233065
    Abstract: This invention relates to an electrolyte as well as a method for the deposition of a matte metal layer on a substrate surface, where the matte metal layer is V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ru, Rh, Pd, Ag, In, Sn, Sb, Te, Re, Pt, Au, TI, Bi, or an alloy thereof, and there is a halogenide, sulphate, or sulfonate of an element of the group consisting of sodium, potassium, aluminum, magnesium, or boron to facilitate deposition of a smooth and even layer with much lower deposition metal requirements.
    Type: Application
    Filed: July 8, 2009
    Publication date: September 29, 2011
    Applicant: ENTHONE INC.
    Inventors: Andreas Königshofen, Danica Elbick, Helmut Starke
  • Patent number: 8012334
    Abstract: Disclosed are metal plating compositions and methods. The metal plating compositions provide good leveling performance and throwing power.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: September 6, 2011
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Erik Reddington, Gonzalo Urrutia Desmaison, Zukhra I. Niazimbetova, Donald E. Cleary, Mark Lefebvre
  • Patent number: 7988843
    Abstract: A method of electroplating conductive material on semiconductor wafers controls undesirable surface defects by reducing the electroplating current as the wafer is being initially immersed in a plating bath. Further defect reduction and improved bottom up plating of vias is achieved by applying a static charge on the wafer before it is immersed in the bath, in order to enhance bath accelerators used to control the plating rate. The static charge is applied to the wafer using a supplemental electrode disposed outside the plating bath.
    Type: Grant
    Filed: February 15, 2010
    Date of Patent: August 2, 2011
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Chung-Liang Chang, Shau-Lin Shue
  • Patent number: 7938948
    Abstract: To develop stable, non-cyanide silver and silver alloy plating baths. The present invention is a silver and silver alloy plating bath, comprises: (A) a soluble salt, comprising a silver salt or a mixture of a silver salt and a salt of a metal selected from the group consisting of tin, bismuth, cobalt, antimony, iridium, indium, lead, copper, iron, zinc, nickel, palladium, platinum, and gold; and (B) at least one aliphatic sulfide compound comprising a functionality selected from the group consisting of an ether oxygen atom, a 3-hydroxypropyl group, and a hydroxypropylene group, with the proviso that the aliphatic sulfide compound does not comprise a basic nitrogen atom.
    Type: Grant
    Filed: September 3, 2009
    Date of Patent: May 10, 2011
    Assignees: Ishihara Chemical Co., Ltd., Daiwa Fine Chemicals Co., Ltd.
    Inventors: Kiyotaka Tsuji, Tetsuji Nishikawa, Takao Takeuchi, Keigo Obata, Hidemi Nawafune
  • Publication number: 20110090621
    Abstract: A capacitor with an anode, a dielectric on the anode and a cathode on the dielectric. A blocking layer is on the cathode. A metal filled layer is on said blocking layer and a plated layer is on the metal filled layer.
    Type: Application
    Filed: December 20, 2010
    Publication date: April 21, 2011
    Inventors: Antony Chacko, Randy Hahn
  • Publication number: 20110062030
    Abstract: The electrolyte composition is used in a method of depositing metals, in particular, onto substrates, especially solar cells. The electrolyte composition is particularly suitable for the deposition of metals, in particular silver, onto solar cells. The electrolyte composition is preferably free of cyanides and contains at least one metal, preferably silver, and an iminodisuccinate derivative, preferably a sodium or postassium iminodisuccinate.
    Type: Application
    Filed: September 9, 2010
    Publication date: March 17, 2011
    Inventors: Lothar Lippert, Stefan Dauwe
  • Publication number: 20100294669
    Abstract: A method is provided for imparting corrosion resistance onto a surface of a substrate. The method comprises contacting the surface of the substrate with an electrolytic plating solution comprising (a) a source of deposition metal ions of a deposition metal selected from the group consisting of zinc, palladium, silver, nickel, copper, gold, platinum, rhodium, ruthenium, chrome, and alloys thereof, (b) a pre-mixed dispersion of non-metallic nano-particles, wherein the non-metallic particles have a pre-mix coating of surfactant molecules thereon; and applying an external source of electrons to the electrolytic plating solution to thereby electrolytically deposit a metal-based composite coating comprising the deposition metal and non-metallic nano-particles onto the surface.
    Type: Application
    Filed: December 10, 2008
    Publication date: November 25, 2010
    Applicant: ENTHONE INC.
    Inventors: Joseph A. Abys, Edward J. Kudrak, JR., Jingye Li, Chen Xu, Chonglun Fan
  • Patent number: 7781731
    Abstract: Disclosed herein is a method of qualitatively analyzing high-molecular additives in a metal plating solution, including: removing sulfate ions and metal ions from a metal plating solution; and qualitatively analyzing the metal plating solution, from which sulfate ions and metal ions are removed, using Matrix-Assisted Laser Desorption/Ionization Time-Of-Flight Mass Spectroscopy (MALDI-TOF MS). The method is advantageous in that the structure and molecular weight of high-molecular additives present in very small amounts in a plating solution can be accurately measured while maintaining the specific structure and molecular weight thereof without degrading the high-molecular additives.
    Type: Grant
    Filed: July 1, 2008
    Date of Patent: August 24, 2010
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Yun Hee Kim, Bae Kyun Kim, Dong Hyun Cho
  • Publication number: 20100187121
    Abstract: A process for the preparation of electrodes for use in a fuel cell comprising a membrane electrode assembly with a negative and a positive electrode is described, said process comprising the following steps: (i) providing an electrode substrate and (ii) coating said substrate electrolytically from a plating bath with a metal layer, said metal being selected from Ag, Au, Pd and its alloys.
    Type: Application
    Filed: April 2, 2008
    Publication date: July 29, 2010
    Applicant: Atotech Deutschland GmbH
    Inventors: Dieter Metzger, Sven Lamprecht
  • Patent number: 7763159
    Abstract: A method for preparation of nanocomposite solution, comprises preparing basic silica colloid aqueous solution; providing an electrolysis apparatus by installing a negative electrode containing aluminum and a positive electrode containing silver into the basic silica colloid aqueous solution; and forming nanocomposite by applying voltage to the respective electrodes of the electrolysis apparatus. With this configuration, the present invention provides a method of manufacturing solution dispersed with nanocomposite, further particularly to, a method of manufacturing nanocomposite solution having excellent storability and thermal stability and containing silver having antibacterial function, far infrared radiation function, deodorization function.
    Type: Grant
    Filed: December 26, 2003
    Date of Patent: July 27, 2010
    Inventors: Chul-sang Jeong, Moon-young Jeong, Byoung-chan Kim, Myung-soo Lee
  • Publication number: 20100135466
    Abstract: A bonded assembly includes a member, and a substrate comprising beryllium, the substrate configured to be bonded to the member. The bonded assembly includes a first barrier applied to a surface of the substrate, a second barrier applied to a surface of the first barrier, a bonding material disposed between the second barrier and the member, and wherein the second barrier is configured to prevent dissolution of the first barrier into the bonding material.
    Type: Application
    Filed: December 3, 2008
    Publication date: June 3, 2010
    Inventors: Gregory Alan Steinlage, Thomas C. Tiearney, Donald Robert Allen
  • Patent number: 7713388
    Abstract: A structure has at least one structure component formed of a first material residing on a substrate, such that the structure is out of a plane of the substrate. A first coating of a second material then coats the structure. A second coating of a non-oxidizing material coats the structure at a thickness less than a thickness of the second material.
    Type: Grant
    Filed: February 27, 2006
    Date of Patent: May 11, 2010
    Assignee: Palo Alto Research Center Incorporated
    Inventors: Christopher L. Chua, Thomas Hantschel, David K. Fork, Koenraad F. Van Schuylenbergh, Yan Yan Yang
  • Publication number: 20100044239
    Abstract: The invention relates to a cyanide-free electrolyte composition for depositing a silver or silver alloy layer on a substrate as well as a method for depositing such layers with the help of said cyanide-free electrolyte composition. The electrolyte composition according to the invention comprises at least one silver ion source, a sulfonic acid and/or a sulfonic acid derivative, a wetting agent and a hydantoin. The silver or silver alloy layers deposited from such an electrolyte composition by means of the method according to the invention are dull and ductile.
    Type: Application
    Filed: October 9, 2007
    Publication date: February 25, 2010
    Applicant: ENTHONE INC.
    Inventors: Stefan Schäfer, Thomas B. Richardson
  • Publication number: 20100044240
    Abstract: When depositing a metal or a compound of the metal from a liquid crystal phase comprising a metal compound, e.g. a metal salt, by electrochemical means, high concentrations of the salt may be employed by using an ionic surfactant in place of the commonly used non-ionic surfactant.
    Type: Application
    Filed: September 7, 2007
    Publication date: February 25, 2010
    Inventors: Jennifer Kimber, Daniel Peat
  • Publication number: 20090321269
    Abstract: To develop stable, non-cyanide silver and silver alloy plating baths. The present invention is a silver and silver alloy plating bath, comprises: (A) a soluble salt, comprising a silver salt or a mixture of a silver salt and a salt of a metal selected from the group consisting of tin, bismuth, cobalt, antimony, iridium, indium, lead, copper, iron, zinc, nickel, palladium, platinum, and gold; and (B) at least one aliphatic sulfide compound comprising a functionality selected from the group consisting of an ether oxygen atom, a 3-hydroxypropyl group, and a hydroxypropylene group, with the proviso that the aliphatic sulfide compound does not comprise a basic nitrogen atom.
    Type: Application
    Filed: September 3, 2009
    Publication date: December 31, 2009
    Applicants: ISHIHARA CHEMICAL CO., LTD., DAIWA FINE CHEMICALS CO., LTD.
    Inventors: Kiyotaka TSUJI, Tetsuji NISHIKAWA, Takao TAKEUCHI, Keigo OBATA, Hidemi NAWAFUNE
  • Publication number: 20090308756
    Abstract: The present invention is directed to structures having a plurality of discrete insulated elongated electrical conductors projecting from a support surface which are useful as probes for testing of electrical interconnections to electronic devices, such as integrated circuit devices and other electronic components and particularly for testing of integrated circuit devices with rigid interconnection pads and multi-chip module packages with high density interconnection pads and the apparatus for use thereof and to methods of fabrication thereof. Coaxial probe structures are fabricated by the methods described providing a high density coaxial probe.
    Type: Application
    Filed: August 21, 2009
    Publication date: December 17, 2009
    Inventors: Brian Samuel Beaman, Keith Edward Fogel, Paul Alfred Lauro, Yun-Hsin Liao, Daniel Peter Morris, Da-Yuan Shih
  • Patent number: 7628903
    Abstract: A silver and silver alloy plating bath, includes (A) a soluble salt, having a silver salt or a mixture of a silver salt and a salt of a metal such as tin, bismuth, indium, lead, and the like; and (B) a particular aliphatic sulfide compound, such as thiobis(diethyleneglycol), dithiobis(triglycerol), 3,3?-thiodipropanol, thiodiglycerin, 3,6-dithiooctane-1,8-diol, and the like, which contain at least one or more of an ether oxygen atom, a 1-hydroxypropyl group, a hydroxypropylene group, or two or more of a sulfide bond in the molecule, and not containing a basic nitrogen atom.
    Type: Grant
    Filed: May 2, 2000
    Date of Patent: December 8, 2009
    Assignees: Ishihara Chemical Co., Ltd., Daiwa Fine Chemicals Co., Ltd.
    Inventors: Kiyotaka Tsuji, Tetsuji Nishikawa, Takao Takeuchi, Keigo Obata, Hidemi Nawafune
  • Publication number: 20090283416
    Abstract: Disclosed is a method of treating the surface of an electrically conducting substrate surface wherein a tool comprising an ion-conducting solid material is brought into contact at least in some areas with the substrate surface, the tool is able to conduct the metal ions of the substrate and an electric potential is applied so that an electric potential gradient is applied between the substrate surface and the tool in such a manner that metal ions are drawn from the substrate surface or deposited onto the substrate surface by means of the tool.
    Type: Application
    Filed: April 20, 2007
    Publication date: November 19, 2009
    Inventors: Hans-Joachim Quenzer, Gerfried Zwicker
  • Publication number: 20090224422
    Abstract: Embodiments of a composite carbon nanotube structure comprising a number of carbon nanotubes disposed in a matrix comprised of a metal or a metal oxide. The composite carbon nanotube structures may be used as a thermal interface device in a packaged integrated circuit device.
    Type: Application
    Filed: January 9, 2009
    Publication date: September 10, 2009
    Inventor: Valery M. Dubin
  • Publication number: 20090223830
    Abstract: A surface treatment method of cladding a Sn or Sn alloy coating with one or more metals selected from among Mn, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Ga, In, Ti, Ge, Pb, Sb and Bi continuously or discontinuously in such a way as to make the Sn or Sn alloy coating partially exposed, which method makes it possible to inhibit the generation of whiskers in an Sn or Sn alloy coating formed on the surface of a substrate to which other member is pressure-welded or the joint surface to be soldered. Cladding an Sn or Sn alloy coating with a prescribed metal continuously or discontinuously in such a way as to make the coating partially exposed inhibits the generation of whiskers by contact pressure in pressure welding, and further inhibits the generation of whiskers without impairing the solder wettability of the coating even when the cladding is not followed by heat treatment or reflowing.
    Type: Application
    Filed: October 2, 2006
    Publication date: September 10, 2009
    Applicants: C. UYEMURA & CO., LTD., OSAKA UNIVERSITY
    Inventors: Masanobu Tsujimoto, Isamu Yanada, Katsuaki Suganuma, Keunsoo Kim
  • Patent number: 7575665
    Abstract: Described is a method of reducing corrosion of a silver-containing surface comprising electro-depositing a layer of an iodine-containing material on the silver-containing surface at a charge density of about 80 mA*s (milliamps second)/cm2 or less. Also described is an electrical contact also produced by the method.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: August 18, 2009
    Assignee: Delphi Technologies, Inc.
    Inventors: Charles R. Harrington, Neil R. Aukland
  • Patent number: RE45175
    Abstract: In PCB manufacture, the pads and/or through-holes of a bare board are protected prior to mounting of other components by a silver plating process. The silver plate is applied from a plating composition by a replacement process in which silver ions oxidized copper and deposit a layer of silver at the surface. In the aqueous plating composition the silver ions are maintained in solution by the incorporation of a multidentate complexing agent. The compositions may contain a silver tarnish inhibitor and are free of reducing agent capable of reducing silver ions to silver metal, halide ions and substantially free of non-aqueous solvent. Surface mounted components can be soldered direct to the silver coated contact using any commercially available solder. Silver does not deposit onto solder mask, but only onto metal which is less electropositive than silver.
    Type: Grant
    Filed: October 18, 2012
    Date of Patent: October 7, 2014
    Assignee: Fry's Metals, Inc.
    Inventors: Andrew McIntosh Soutar, Peter Thomas McGrath
  • Patent number: RE45279
    Abstract: In PCB manufacture, the pads and/or through-holes of a bare board are protected prior to mounting of other components by a silver plating process. The silver plate is applied from a plating composition by a replacement process in which silver ions oxidized copper and deposit a layer of silver at the surface. In the aqueous plating composition the silver ions are maintained in solution by the incorporation of a multidentate complexing agent. The compositions may contain a silver tarnish inhibitor and are free of reducing agent capable of reducing silver ions to silver metal, halide ions and substantially free of non-aqueous solvent. Surface mounted components can be soldered direct to the silver coated contact using any commercially available solder. Silver does not deposit onto solder mask, but only onto metal which is less electropositive than silver. REEXAMINATION RESULTS The questions raised in reexamination proceedings Nos. 90/012,336 and 90/009,934, filed Jun. 4, 2012 and Aug.
    Type: Grant
    Filed: May 14, 2012
    Date of Patent: December 9, 2014
    Assignee: Fry's Metals, Inc.
    Inventors: Andrew McIntosh Soutar, Peter Thomas McGrath
  • Patent number: RE45297
    Abstract: A method for enhancing the solderability of a metallic surface is disclosed where the metallic surface is plated with an immersion silver plate prior to soldering, which immersion silver plate is treated with an additive selected from the group consisting of fatty amines, fatty amides, quaternary salts, amphateric salts, resinous amines, resinous amides, fatty acids, resinous acids, ethoxylated derivatives of any of the foregoing, and mixtures of any of the foregoing. The immersion silver deposits created are resistant to electromigration.
    Type: Grant
    Filed: February 13, 2012
    Date of Patent: December 23, 2014
    Inventors: Ronald Redline, David Sawoska, Peter Kukanskis, Donald Ferrier, Eric Yakobson