Nitrogen-heterocyclic Compound-containing Patents (Class 205/310)
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Patent number: 11773534Abstract: The present invention provides a metal cord having better adhesion to rubber compared to a conventional one, as well as a metal cord-rubber composite and a conveyor belt, including the same. In a metal cord (10) composed of a plurality of metal filaments (11) twisted together, the surfaces of the metal filaments (11) constituting the outermost layer are each provided with a zinc plating layer (16), and the degrees of crystal orientation of the (002) plane and the (102) plane of the surface of the zinc plating layer (16) are less than 120.Type: GrantFiled: June 12, 2019Date of Patent: October 3, 2023Assignee: BRIDGESTONE CORPORATIONInventors: Naohiko Obana, Yoshiaki Oono
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Patent number: 11578421Abstract: A method of fabricating and using a zinc negative electrode and systems thereof are described. A zinc electroplated electrode including a layer of zinc metal bonded to a surface of an electrically conductive current collector is fabricated by an electroplating process using a zinc electroplating system. The zinc electroplating system includes: a zinc metal anode, a cathode including the current collector for plating zinc thereon, and an electrolyte bath comprising zinc ions. The electroplating process bonds the zinc metal to the surface of the current collector to create the electroplated zinc electrode. The electroplated zinc electrode is used as a negative electrode in a zinc metal cell. The zinc metal cell may be a primary cell or a secondary cell.Type: GrantFiled: November 6, 2019Date of Patent: February 14, 2023Assignee: Salient Energy Inc.Inventors: Brian D. Adams, Marine B. Cuisinier, John Philip S. Lee
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Patent number: 10590541Abstract: Stable electroless copper plating baths include di-cation viologen compounds to improve rate of copper deposition on substrates. The copper from the electroless plating baths can be plated at low temperatures and at high plating rates.Type: GrantFiled: June 15, 2018Date of Patent: March 17, 2020Assignee: Rohm and Haas Electronic Materials LLCInventors: Alejo M. Lifschitz Arribio, Donald E. Cleary
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Patent number: 9587320Abstract: An additive for an acid zinc alloy plating bath includes an aliphatic polyamine having not more than 12 carbon atoms. The acid zinc alloy plating bath includes a buffer including an acetic acid-containing material containing acetic acid and/or acetate ions. A method for producing a zinc alloy plated article including an article and a zinc alloy plated coating formed on a plating surface of the article includes forming the zinc alloy plated coating by electroplating using the acid zinc alloy plating bath.Type: GrantFiled: September 15, 2015Date of Patent: March 7, 2017Assignee: YUKEN INDUSTRY CO., LTD.Inventors: Yasunori Aoki, Takahiro Teramoto
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Patent number: 9399618Abstract: Disclosed is a solution for an electrochemical process, the solution containing a sulfonic acid and having a low concentration of sulfur compounds, either low or high valence, that are susceptible to reduction and which is intended for use in electrodeposition, batteries, conductive polymers and descaling processes.Type: GrantFiled: March 23, 2011Date of Patent: July 26, 2016Assignee: Arkema Inc.Inventors: Nicholas M. Martyak, Martin Nosowitz, Gary S. Smith, Patrick Kendall Janney, Jean-Marie Ollivier
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Patent number: 8735580Abstract: A process of making a polymeric phenazonium compound having the general formula: wherein R1, R2, R4, R5, R6, R8 and R9 are the same or different, and represent hydrogen, a low alkyl or a substituted aryl, R3 starts as NH2 and is diazotized followed by polymerization, R5 and R8 may alternatively represent monomeric or polymeric phenazonium radicals, R7 is a carbon in the aromatic ring, and wherein RX—N—RY represents a substituted amine, and RX and RY represent any combination of CH3, C2H5, and hydrogen, except that RX and RY cannot both be hydrogen, A is an acid radical, and n is an integer from 2 to 100. The polymeric phenazonium compound is usable in as an additive in a metal plating bath.Type: GrantFiled: September 21, 2011Date of Patent: May 27, 2014Inventors: Andrew M. Krol, Ernest Long, Lev Taytsas
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Patent number: 8691987Abstract: A process of making a polymeric phenazonium compound having the general formula: wherein R1, R2, R4, R5, R6, R8 and R9 are the same or different, and represent hydrogen, a low alkyl or a substituted aryl, R3 starts with NH2 and is diazotized followed by polymerization, R5 and R8 may alternatively represent monomeric or polymeric phenazonium radicals, R7 with its substituent group is a substituted amine, with RX and RY representing any combination of CH3, C2H5, and hydrogen, except that RX and RY cannot both be hydrogen, A is an acid radical, and n is an integer from 2 to 100, preferably from 2 to 20 is described. The polymeric phenazonium compound is usable in as an additive in a metal plating bath.Type: GrantFiled: September 24, 2010Date of Patent: April 8, 2014Inventors: Andrew M. Krol, Ernest Long, Lev Taytsas
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Publication number: 20130175179Abstract: A zinc electroplating bath includes zinc ions and a brightening agent. The brightening agent is a polyamine or a mixture of polyamines that include a quaternary ammonium group.Type: ApplicationFiled: December 10, 2012Publication date: July 11, 2013Applicant: Coventya, Inc.Inventor: Coventya, Inc.
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Publication number: 20120061250Abstract: Techniques for electrodepositing zinc (Zn)-containing films are provided. In one aspect, a method of preparing a Zn electroplating solution is provided. The method includes the following steps. The solution is formed from a mixture of at least one zinc salt, a sulfonic acid and a solvent. The sulfonic acid is quenched with a base. A pH of the solution is adjusted to be either less than about 3.5 or greater than about 8.0. The pH of the solution can be adjusted by adding additional sulfonic acid to the solution to adjust the pH of the solution to be less than about 3.5 or by adding a second base to the solution to adjust the pH of the solution to be greater than about 8.0. A Zn electroplating solution and an electroplating method are also provided.Type: ApplicationFiled: September 9, 2010Publication date: March 15, 2012Applicant: International Business Machines CorporationInventors: Shafaat Ahmed, Hariklia Deligianni
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Publication number: 20110147224Abstract: A zinc electroplating bath includes zinc ions and a brightening agent. The brightening agent is a polyamine or a mixture of polyamines that include a quaternary ammonium group.Type: ApplicationFiled: February 28, 2011Publication date: June 23, 2011Inventors: William E. Eckles, Thorsten Kuehler
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Patent number: 7714285Abstract: A spectrometer (10) for sample surface analysis by irradiation of the surface by primary particles and a corresponding method of surface analysis spectroscopy. The spectrometer (10) provides sample viewing and secondary charged particle collection substantially normal to the sample surface. A collection chamber (22) comprises a secondary charged particle lens arrangement (20) to focus the emitted particles in a downstream direction along a first normal axis (24) and thereby to define a charged particle optical crossover location (25); and a light-reflecting optical element (50) downstream of the lens arrangement and arranged to receive image light (41) and reflect it away from a second normal axis (42) for providing a viewable image of the surface.Type: GrantFiled: October 27, 2006Date of Patent: May 11, 2010Assignee: Thermo Fisher Scientific Inc.Inventor: Bryan Robert Barnard
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Patent number: 6652728Abstract: An aqueous alkaline cyanide-free bath for the galvanic deposition of zinc or zinc alloy coatings on substrate surfaces is described, which contains in addition to a source of zinc ions and optionally a source of further metal ions, also hydroxide ions and a polymer of the general formula A that is soluble in the bath as well as optionally conventional additives. The bath may furthermore contain a quaternary derivative of a pyridine-3-carboxylic acid of the formula B and/or a quaternary derivative of a pyridine-3-carboxylic acid of the formula C A process for the galvanic deposition of zinc coatings and zinc alloy coatings using the aforedescribed bath is also described. By using the baths according to the invention it is possible to produce coatings that exhibit a uniform layer thickness combined with a high gloss, and which do not exhibit any tendency to exfoliate.Type: GrantFiled: June 25, 2001Date of Patent: November 25, 2003Assignee: Atotech Deutschland GmbHInventors: Birgit Sonntag, Udo Grieser, Barrie Sydney James
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Patent number: 6468411Abstract: An alkaline zinc-nickel electroplating bath comprises zinc ions, nickel ions, a primary brightener which is an N-methylpyridinium compound substituted at the 3-position of the pyridine ring with a carboxylate group or a group hydrolyzable to a carboxylate group and a secondary brightener which is an aliphatic amine. An example of a preferred brightener is N-methylpyridinium-3-carboxylate or a salt thereof. A preferred polyamine is a polyethyleimine. By the present invention, a mirror bright zinc-nickel deposit can be obtained having more than 4% by weight nickel, without blistering or decomposition of the primary brightener.Type: GrantFiled: July 11, 2001Date of Patent: October 22, 2002Assignee: Taskem Inc.Inventors: William E. Eckles, Becki A. Zinni-Kettering, Robert E. Frischauf
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Patent number: 5435898Abstract: An aqueous bath for electrodepositing zinc and zinc alloys wherein the alloying metals are selected from the group consisting of iron, cobalt and nickel and containing an effective additive amount of a quaternary ammonium polymer to produce enhanced deposits. A process for electrodepositing zinc and zinc alloys using the baths of the invention is also disclosed.Type: GrantFiled: October 25, 1994Date of Patent: July 25, 1995Assignee: Enthone-OMI Inc.Inventors: John H. Commander, Victor J. Waldman
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Patent number: 5182006Abstract: A method for producing smooth metal coatings on zincated aluminum substrates using a specially formulated zincating bath containing an additive comprising a bath soluble cationic condensation polymer represented by the general formula: ##STR1## wherein: Z represents a group of atoms necessary to complete a heterocylic compound having a five or six membered ring containing at least 2 nitrogen atoms;R is nothing or the alkyl group of an alkylating agent;X is Cl, Br or I, andn is >1.Type: GrantFiled: February 4, 1991Date of Patent: January 26, 1993Assignee: Enthone-OMI Inc.Inventors: Juan Haydu, Vincent Paneccasio, Jr., Patricia A. Cacciatore