Nitrogen-heterocyclic Compound-containing Patents (Class 205/310)
  • Patent number: 11773534
    Abstract: The present invention provides a metal cord having better adhesion to rubber compared to a conventional one, as well as a metal cord-rubber composite and a conveyor belt, including the same. In a metal cord (10) composed of a plurality of metal filaments (11) twisted together, the surfaces of the metal filaments (11) constituting the outermost layer are each provided with a zinc plating layer (16), and the degrees of crystal orientation of the (002) plane and the (102) plane of the surface of the zinc plating layer (16) are less than 120.
    Type: Grant
    Filed: June 12, 2019
    Date of Patent: October 3, 2023
    Assignee: BRIDGESTONE CORPORATION
    Inventors: Naohiko Obana, Yoshiaki Oono
  • Patent number: 11578421
    Abstract: A method of fabricating and using a zinc negative electrode and systems thereof are described. A zinc electroplated electrode including a layer of zinc metal bonded to a surface of an electrically conductive current collector is fabricated by an electroplating process using a zinc electroplating system. The zinc electroplating system includes: a zinc metal anode, a cathode including the current collector for plating zinc thereon, and an electrolyte bath comprising zinc ions. The electroplating process bonds the zinc metal to the surface of the current collector to create the electroplated zinc electrode. The electroplated zinc electrode is used as a negative electrode in a zinc metal cell. The zinc metal cell may be a primary cell or a secondary cell.
    Type: Grant
    Filed: November 6, 2019
    Date of Patent: February 14, 2023
    Assignee: Salient Energy Inc.
    Inventors: Brian D. Adams, Marine B. Cuisinier, John Philip S. Lee
  • Patent number: 10590541
    Abstract: Stable electroless copper plating baths include di-cation viologen compounds to improve rate of copper deposition on substrates. The copper from the electroless plating baths can be plated at low temperatures and at high plating rates.
    Type: Grant
    Filed: June 15, 2018
    Date of Patent: March 17, 2020
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Alejo M. Lifschitz Arribio, Donald E. Cleary
  • Patent number: 9587320
    Abstract: An additive for an acid zinc alloy plating bath includes an aliphatic polyamine having not more than 12 carbon atoms. The acid zinc alloy plating bath includes a buffer including an acetic acid-containing material containing acetic acid and/or acetate ions. A method for producing a zinc alloy plated article including an article and a zinc alloy plated coating formed on a plating surface of the article includes forming the zinc alloy plated coating by electroplating using the acid zinc alloy plating bath.
    Type: Grant
    Filed: September 15, 2015
    Date of Patent: March 7, 2017
    Assignee: YUKEN INDUSTRY CO., LTD.
    Inventors: Yasunori Aoki, Takahiro Teramoto
  • Patent number: 9399618
    Abstract: Disclosed is a solution for an electrochemical process, the solution containing a sulfonic acid and having a low concentration of sulfur compounds, either low or high valence, that are susceptible to reduction and which is intended for use in electrodeposition, batteries, conductive polymers and descaling processes.
    Type: Grant
    Filed: March 23, 2011
    Date of Patent: July 26, 2016
    Assignee: Arkema Inc.
    Inventors: Nicholas M. Martyak, Martin Nosowitz, Gary S. Smith, Patrick Kendall Janney, Jean-Marie Ollivier
  • Patent number: 8735580
    Abstract: A process of making a polymeric phenazonium compound having the general formula: wherein R1, R2, R4, R5, R6, R8 and R9 are the same or different, and represent hydrogen, a low alkyl or a substituted aryl, R3 starts as NH2 and is diazotized followed by polymerization, R5 and R8 may alternatively represent monomeric or polymeric phenazonium radicals, R7 is a carbon in the aromatic ring, and wherein RX—N—RY represents a substituted amine, and RX and RY represent any combination of CH3, C2H5, and hydrogen, except that RX and RY cannot both be hydrogen, A is an acid radical, and n is an integer from 2 to 100. The polymeric phenazonium compound is usable in as an additive in a metal plating bath.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: May 27, 2014
    Inventors: Andrew M. Krol, Ernest Long, Lev Taytsas
  • Patent number: 8691987
    Abstract: A process of making a polymeric phenazonium compound having the general formula: wherein R1, R2, R4, R5, R6, R8 and R9 are the same or different, and represent hydrogen, a low alkyl or a substituted aryl, R3 starts with NH2 and is diazotized followed by polymerization, R5 and R8 may alternatively represent monomeric or polymeric phenazonium radicals, R7 with its substituent group is a substituted amine, with RX and RY representing any combination of CH3, C2H5, and hydrogen, except that RX and RY cannot both be hydrogen, A is an acid radical, and n is an integer from 2 to 100, preferably from 2 to 20 is described. The polymeric phenazonium compound is usable in as an additive in a metal plating bath.
    Type: Grant
    Filed: September 24, 2010
    Date of Patent: April 8, 2014
    Inventors: Andrew M. Krol, Ernest Long, Lev Taytsas
  • Publication number: 20130175179
    Abstract: A zinc electroplating bath includes zinc ions and a brightening agent. The brightening agent is a polyamine or a mixture of polyamines that include a quaternary ammonium group.
    Type: Application
    Filed: December 10, 2012
    Publication date: July 11, 2013
    Applicant: Coventya, Inc.
    Inventor: Coventya, Inc.
  • Publication number: 20120061250
    Abstract: Techniques for electrodepositing zinc (Zn)-containing films are provided. In one aspect, a method of preparing a Zn electroplating solution is provided. The method includes the following steps. The solution is formed from a mixture of at least one zinc salt, a sulfonic acid and a solvent. The sulfonic acid is quenched with a base. A pH of the solution is adjusted to be either less than about 3.5 or greater than about 8.0. The pH of the solution can be adjusted by adding additional sulfonic acid to the solution to adjust the pH of the solution to be less than about 3.5 or by adding a second base to the solution to adjust the pH of the solution to be greater than about 8.0. A Zn electroplating solution and an electroplating method are also provided.
    Type: Application
    Filed: September 9, 2010
    Publication date: March 15, 2012
    Applicant: International Business Machines Corporation
    Inventors: Shafaat Ahmed, Hariklia Deligianni
  • Publication number: 20110147224
    Abstract: A zinc electroplating bath includes zinc ions and a brightening agent. The brightening agent is a polyamine or a mixture of polyamines that include a quaternary ammonium group.
    Type: Application
    Filed: February 28, 2011
    Publication date: June 23, 2011
    Inventors: William E. Eckles, Thorsten Kuehler
  • Patent number: 7714285
    Abstract: A spectrometer (10) for sample surface analysis by irradiation of the surface by primary particles and a corresponding method of surface analysis spectroscopy. The spectrometer (10) provides sample viewing and secondary charged particle collection substantially normal to the sample surface. A collection chamber (22) comprises a secondary charged particle lens arrangement (20) to focus the emitted particles in a downstream direction along a first normal axis (24) and thereby to define a charged particle optical crossover location (25); and a light-reflecting optical element (50) downstream of the lens arrangement and arranged to receive image light (41) and reflect it away from a second normal axis (42) for providing a viewable image of the surface.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: May 11, 2010
    Assignee: Thermo Fisher Scientific Inc.
    Inventor: Bryan Robert Barnard
  • Patent number: 6652728
    Abstract: An aqueous alkaline cyanide-free bath for the galvanic deposition of zinc or zinc alloy coatings on substrate surfaces is described, which contains in addition to a source of zinc ions and optionally a source of further metal ions, also hydroxide ions and a polymer of the general formula A that is soluble in the bath as well as optionally conventional additives. The bath may furthermore contain a quaternary derivative of a pyridine-3-carboxylic acid of the formula B and/or a quaternary derivative of a pyridine-3-carboxylic acid of the formula C A process for the galvanic deposition of zinc coatings and zinc alloy coatings using the aforedescribed bath is also described. By using the baths according to the invention it is possible to produce coatings that exhibit a uniform layer thickness combined with a high gloss, and which do not exhibit any tendency to exfoliate.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: November 25, 2003
    Assignee: Atotech Deutschland GmbH
    Inventors: Birgit Sonntag, Udo Grieser, Barrie Sydney James
  • Patent number: 6468411
    Abstract: An alkaline zinc-nickel electroplating bath comprises zinc ions, nickel ions, a primary brightener which is an N-methylpyridinium compound substituted at the 3-position of the pyridine ring with a carboxylate group or a group hydrolyzable to a carboxylate group and a secondary brightener which is an aliphatic amine. An example of a preferred brightener is N-methylpyridinium-3-carboxylate or a salt thereof. A preferred polyamine is a polyethyleimine. By the present invention, a mirror bright zinc-nickel deposit can be obtained having more than 4% by weight nickel, without blistering or decomposition of the primary brightener.
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: October 22, 2002
    Assignee: Taskem Inc.
    Inventors: William E. Eckles, Becki A. Zinni-Kettering, Robert E. Frischauf
  • Patent number: 5435898
    Abstract: An aqueous bath for electrodepositing zinc and zinc alloys wherein the alloying metals are selected from the group consisting of iron, cobalt and nickel and containing an effective additive amount of a quaternary ammonium polymer to produce enhanced deposits. A process for electrodepositing zinc and zinc alloys using the baths of the invention is also disclosed.
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: July 25, 1995
    Assignee: Enthone-OMI Inc.
    Inventors: John H. Commander, Victor J. Waldman
  • Patent number: 5182006
    Abstract: A method for producing smooth metal coatings on zincated aluminum substrates using a specially formulated zincating bath containing an additive comprising a bath soluble cationic condensation polymer represented by the general formula: ##STR1## wherein: Z represents a group of atoms necessary to complete a heterocylic compound having a five or six membered ring containing at least 2 nitrogen atoms;R is nothing or the alkyl group of an alkylating agent;X is Cl, Br or I, andn is >1.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: January 26, 1993
    Assignee: Enthone-OMI Inc.
    Inventors: Juan Haydu, Vincent Paneccasio, Jr., Patricia A. Cacciatore