Predominantly Iron Or Steel Substrate Patents (Class 205/320)
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Patent number: 11319632Abstract: Disclosed is a surface anti-corrosion treatment method for stainless steel. The method comprises the following steps: (1) performing chemical de-oiling and alkaline corrosion treatments on the surface of stainless steel by using a sodium hydroxide solution and a solution containing an alkaline corrosion active agent, and then washing with water; (2) performing, by using an oxidation solution, an oxidation treatment on the surface of the stainless steel treated in step (1), and then washing with water; (3) using the surface of the stainless steel treated in step (2) as a cathode and soaking same in an electrolyte for electrolysis, and then washing with water; and (4) placing the surface of the stainless steel treated in step (3) at a temperature of 50° C.-60° C. under a humidity of 60%-70%, and performing a hardening treatment. Also disclosed are the use of the treatment method in the treatment of a stainless steel part and a stainless steel part obtained after the treatment by means of the treatment method.Type: GrantFiled: August 16, 2017Date of Patent: May 3, 2022Assignee: SHENZHEN CANDORTECH INCORPORATED COMPANYInventor: Chao Chen
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Patent number: 9653738Abstract: A stainless steel for use in a fuel cell separator is produced by subjecting stainless steel containing 16 mass % or more of Cr to electrolytic treatment and thereafter to immersion treatment in a solution containing fluorine. The electrolytic treatment is carried out by anodic electrolyzation or by a combination of anodic electrolyzation and cathodic electrolyzation, and an anodic electrolytic quantity Qa and a cathodic electrolytic quantity Qc preferably satisfy Qa?Qc. The solution containing fluorine preferably has a temperature of 40° C. or higher, and hydrofluoric acid concentration [HF] (mass %) and nitric acid concentration [HNO3] (mass %) satisfying [HF]?0.8×[HNO3].Type: GrantFiled: January 19, 2011Date of Patent: May 16, 2017Assignee: JFE Steel CorporationInventors: Shinsuke Ide, Tomohiro Ishii, Shin Ishikawa, Yasushi Kato
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Patent number: 9458549Abstract: The invention concerns a method for manufacturing of an object having phosphorescent properties, comprising the steps of providing an object having a surface made from aluminum or from an aluminum-based alloy and forming a layer of porous aluminum (hydr)oxide at said surface. The invention is characterized in that the method comprises the step of contacting the layer of porous aluminum (hydr)oxide with one or several solutions containing metal dopant ions such as to allow the metal dopant ions to bind to the layer of porous aluminum (hydr)oxide, wherein at least one of said solutions contains ions of at least one element selected from a first group consisting of calcium (Ca), magnesium (Mg), strontium (Sr) and barium (Ba), and wherein at least one of said solutions contains ions of europium (Eu). The invention also concerns an object obtainable by the above method.Type: GrantFiled: April 12, 2011Date of Patent: October 4, 2016Assignee: Alusera ABInventors: Knut Irgum, Erika Wikberg
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Patent number: 9187830Abstract: A non-oriented electrical steel sheet includes: a base iron (1); and a tension applying type insulating film (2) of not less than 1 g/m2 nor more than 6 g/m2 on a surface of the base iron (1). An oxide layer (3) containing at least one type of oxide selected from the group consisting of Si, Al, and Cr and having a thickness of not less than 0.01 ?m nor more than 0.5 ?m is formed on the surface of the base iron (1).Type: GrantFiled: February 15, 2011Date of Patent: November 17, 2015Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Shuichi Yamazaki, Takeshi Kubota, Yousuke Kurosaki, Masahiro Fujikura, Takahide Shimazu
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Publication number: 20150129453Abstract: A surface treatment agent composition for non-chromium steel sheets for removing iron ions without reducing the amount of aluminum ions when subjecting the steel sheet to surface treatment by means of cathodic electrolysis using a surface treatment agent containing aluminum ions as the main component; and a method for producing a surface-treated steel sheet using the composition. A surface-treated steel sheet exhibiting high corrosion resistance, a surface-treated steel sheet with an organic coating, and a can lid, can body and seamless can produced using the surface-treated steel sheets. A surface treatment agent composition for steel sheets contains aluminum ions, fluorine ions and polycarboxylic acid and is used as the surface treatment bath used for forming a surface treatment coating film on the surface of the steel sheet by cathodic electrolysis.Type: ApplicationFiled: March 22, 2012Publication date: May 14, 2015Applicants: Nippon Paint Co., Ltd., Toyo Kohan Co., Ltd., Toyo Seikan Kaisha, Ltd.Inventors: Miwa Uchikawa, Masahiko Matsukawa, Tomio Hirano, Wataru Kurokawa, Munemitsu Hirotsu, Seitaro Kanazawa, Kunihiro Yoshimura, Shinichi Taya, Naomi Taguchi
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Publication number: 20150132602Abstract: A method for coating a component for use in a semiconductor chamber for plasma etching includes providing a component for use in a semiconductor manufacturing chamber, loading the component into a deposition chamber, cold spray coating a metal powder onto the component to form a coating on the component, and anodizing the coating to form an anodization layer.Type: ApplicationFiled: November 13, 2013Publication date: May 14, 2015Applicant: Applied Materials, Inc.Inventors: Jennifer Y. Sun, Vahid Firouzdor
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Patent number: 9011667Abstract: One embodiment of the invention includes an assembly of metal oxide comprising valve metal oxide nanotubes.Type: GrantFiled: September 27, 2007Date of Patent: April 21, 2015Assignee: GM Global Technology Operations LLCInventors: Mahmoud H. Abd Elhamid, Gayatri Vyas Dadheech, Curtis A. Wong, Youssef M. Mikhail, Michael J. Lukitsch
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Publication number: 20150021192Abstract: The purpose of the present invention is to provide a replenisher which is capable of supplying Zr ions to a metal surface treatment solution, while suppressing an increase in the HF concentration in the metal surface treatment solution, so that a chemical conversion coating film can be continuously formed on a steel sheet by electrolysis. A replenisher of the present invention is a replenisher which is used for the purpose of supplying zirconium ions to a metal surface treatment solution that contains zirconium ions and fluorine ions, and the replenisher contains (A) zirconium hydrofluoric acid or a salt thereof and/or (B) hydrofluoric acid or a salt thereof and (C) a fluorine-free zirconium compound.Type: ApplicationFiled: November 30, 2011Publication date: January 22, 2015Inventors: Yuta Yoshida, Hiroki Sunada, Shigeki Yamamoto, Hidehiro Yamaguchi
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Publication number: 20140377581Abstract: A surface treatment agent composition which contains aluminum as the coating film formation component and exhibits excellent properties for removing tin ions within a treatment bath when subjecting a tin-plated steel to electrolytic surface treatment, thereby forming a coating film exhibiting excellent corrosion resistance and yellowing resistance. This surface treatment agent composition is used for subjecting a tin-plated steel or a tin-based alloy-plated steel to electrolytic surface treatment and contains aluminum ions, fluorine ions, and polycarboxylic acid. The tin ions that eluted from the tin-plated steel are precipitated within and removed from the treatment bath by using this surface treatment agent composition.Type: ApplicationFiled: March 22, 2012Publication date: December 25, 2014Applicant: NIPPON PAINT CO., LTD.Inventors: Miwa Uchikawa, Masahiko Matsukawa, Tomio Hirano
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Publication number: 20140272414Abstract: Disclosed is a method of producing metal oxides, comprising electrodepositing a metal oxide from an electrolyte solution onto a substrate to coat at least a portion of the substrate, whereby metal oxide seed particles are released into the solution, and precipitating metal oxide particles from the solution. The precipitated metal oxide particles have a maximum particle size of less than 1 micron.Type: ApplicationFiled: March 14, 2013Publication date: September 18, 2014Applicant: PPG Industries Ohio, Inc.Inventors: Robin Peffer, Michael J. Pawlik, Jane Valenta
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Publication number: 20140238867Abstract: A coated overhead conductor having an assembly including one or more conductive wires, such that the assembly includes an outer surface coated with an electrochemical deposition coating forming an outer layer, wherein the electrochemical deposition coating includes a first metal oxide, such that the first metal oxide is not aluminum oxide. Methods for making the overhead conductor are also provided.Type: ApplicationFiled: February 20, 2014Publication date: August 28, 2014Applicant: GENERAL CABLETECHNOLOGIES CORPORATIONInventors: Sathish K. RANGANATHAN, Vijay MHETAR, Cody R. DAVIS, Srinivas SIRIPURAPU
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Patent number: 8574414Abstract: A method includes (a) contacting at least a portion of a substrate material with a solution comprising a source of copper, wherein the solution is essentially free of a source of a group IIIB metal and a source of a group IVB metal; and (b) after step (a), contacting at least a portion of the substrate with an electrodepositable coating composition comprising (i) a film-forming resin and (ii) a source of yttrium.Type: GrantFiled: July 14, 2010Date of Patent: November 5, 2013Assignee: PPG Industries Ohio, IncInventors: Terri Ziegler, Mark McMillen
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Patent number: 8551317Abstract: Disclosed are a method and an apparatus for forming an oxide coating film with excellent corrosion resistance and adhesiveness on a cathode made of a metal plate by a simple process at low cost. A direct current voltage is applied between an anode (12) and a cathode (13) in an electrolyte solution which cathode (13) is made of a metal plate to be coated with oxide and arranged opposite to the anode (12), while supplying oxygen or a gas containing oxygen into the electrolyte solution, so that the metal plate cathode (13) is coated with oxide, thereby being formed into a oxide-coated metal plate.Type: GrantFiled: November 9, 2004Date of Patent: October 8, 2013Assignees: Toyo Seikan Kaisha, Ltd., Toyo Kohan Co., Ltd.Inventors: Wataru Kurokawa, Hiroshi Matsubayashi, Mitsuhide Aihara, Masanobu Matsubara, Masatoki Ishida, Norimasa Maida
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Patent number: 8486538Abstract: An electrodepositable coating composition comprising (i) a film-forming polymer, (ii) a corrosion inhibitor, and (iii) a silane that does not contain an ethylenically unsaturated double bond.Type: GrantFiled: January 26, 2010Date of Patent: July 16, 2013Assignee: PPG Industries Ohio, IncInventors: Thor G. Lingenfelter, Amanda Foley, Edward G. Rakiewicz, Richard F. Karabin, William J. Vanooij
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Publication number: 20130052478Abstract: [Problems] To provide a bath for surface treatment capable of forming a surface-treating film having excellent corrosion resistance by a high-speed electrolytic treatment, and a method of producing a surface-treated steel plate having excellent corrosion resistance and closely adhering property to the coating maintaining good productivity. [Means for Solution] A bath for surface treatment used for forming a surface-treating film on the surface of a steel plate by cathodic electrolysis, the bath for surface treatment containing Zr and/or Ti, and a polycarboxylic acid.Type: ApplicationFiled: May 27, 2011Publication date: February 28, 2013Applicants: TOYO SEIKAN KAISHA, LTD., TOYO KOHAN CO., LTD., NIPPON PAINT CO., LTD.Inventors: Wataru Kurokawa, Seitaro Kanazawa, Shinichi Taya, Kunihiro Yoshimura, Naomi Iida, Miwa Iida, Masahiko Matsukawa
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Publication number: 20130011492Abstract: A method of electrochemical deposition includes submerging a stainless steel surface of an object in a chitosan solution and applying a first electric potential between the submerged stainless steel surface and the chitosan solution for a predetermined time to form a chitosan surface coating. After rinsing and dehydrating, the chitosan coated surface is submerged in a solution having a predetermined concentration of a noble metal nitrate and a second electric potential is applied between the chitosan coated surface and the solution of the noble metal nitrate to deposit noble metal particles on the chitosan surface coating.Type: ApplicationFiled: August 24, 2012Publication date: January 10, 2013Applicant: The Research Foundation of State University of New YorkInventors: Gary HALADA, Michael A. CUIFFO, Prashant JHA
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Publication number: 20120325673Abstract: Electrochemical nitridation of metals and the produced metals are disclosed. An exemplary method of electrochemical nitridation of metals comprises providing an electrochemical solution at low temperature. The method also comprises providing a three-electrode potentiostat system. The method also comprises stabilizing the three-electrode potentiostat system at open circuit potential. The method also comprises applying a cathodic potential to a metal.Type: ApplicationFiled: March 3, 2010Publication date: December 27, 2012Applicant: ALLIANCE FOR SUSTAINABLE ENERGY, LLCInventors: Heli Wang, John A. Turner
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Publication number: 20120292500Abstract: A mass spectrometer includes an ion source, which includes a coating or surface formed of a metallic carbide, a metallic boride, a ceramic or DLC, or an ion-implanted transition metal.Type: ApplicationFiled: November 11, 2011Publication date: November 22, 2012Applicant: MICROMASS UK LIMITEDInventors: Gordon A. Jones, David S. Douce, Amir Farooq
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Publication number: 20120183753Abstract: A surface-treated steel sheet for a container, comprising: a steel sheet, and a Zr compound film disposed on the steel sheet, wherein the Zr compound film being formed by a dipping or electrolytic treatment in a solution containing Zr ion, F ion, ammonium ion and nitrate ion; and the coating weight of the Zr compound film is 1 to 100 mg/m2 in terms of the amount of metallic Zr, and 0.1 mg/m2 or less in terms of the F amount. There is provided a steel sheet for container, which has an excellent processability in the can manufacturing, and at the same time, is excellent in drawing and ironing processability, weldability, corrosion resistance, adherence thereof to a coating material and adherence thereof to a film, and a process for producing such a steel sheet for container.Type: ApplicationFiled: January 18, 2011Publication date: July 19, 2012Inventors: Shigeru Hirano, Akira Tachiki, Hirokazu Yokoya
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Publication number: 20110259756Abstract: A method of production of a chemically treated steel sheet using cathode electrolysis to form a chemically treated coating which stably resupplies Zr ions in a treatment solution and uses an insoluble anode to continuously and stably treat a steel strip by cathode electrolysis in a treatment solution containing Zr ions and fluorine ions, characterized by using two or more types of zirconium compounds selected from predetermined Zr compounds to resupply zirconium ions in a plating solution consumed by the cathode electrolysis during the cathode electrolysis and maintaining a content of ions in the plating solution at zirconium ions: 0.05 to 30 g/liter, fluorine ions: 0.5 to 10 times the content of the zirconium ions, and ions derived from said two or more types of zirconium compounds other than zirconium ions and fluorine ions: not more than 10 times the content of the zirconium ions in performing the cathode electrolysis.Type: ApplicationFiled: April 22, 2010Publication date: October 27, 2011Inventors: Shigeru Hirano, Akira Tachiki
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Publication number: 20110076505Abstract: A metallic material is provided that is superior to an iron-based metallic material in all of adhesion, heat resistance, electrical conductivity, and corrosion resistance, and a method of manufacturing the metallic material is also provided. A metallic material is provided that includes an iron-based metallic material and an oxide layer formed on the surface of the iron-based metallic material. The oxide layer includes Fe and at least one kind of metal (A) selected from a group consisting of Zr, Ti, and Hf. There is also provided a method of manufacturing the metallic material.Type: ApplicationFiled: August 26, 2010Publication date: March 31, 2011Applicant: Henkel AG & Co., KGaAInventors: Hitoshi Ishii, Yasuhiko Nagashima, Ryosuke Kawagoshi
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Patent number: 7883616Abstract: A method for production of a metal oxide and/or metal hydroxide coated metal material comprises immersing a metal material or electrolyzing a conductive material in an aqueous treatment solution at pH 2-7 containing metal ion and fluorine ion in a 4-fold or more molar ratio with respect to the metal ion, and/or containing a complex ion comprising at least a metal and fluorine in a 4-fold or more molar ratio with respect to the metal, to form on the surface of the metal material a metal oxide and/or metal hydroxide coating containing the metal ion and/or the metal, as well as a metal oxide and/or metal hydroxide coated metal material having a metal oxide and/or metal hydroxide coating produced by the method.Type: GrantFiled: December 3, 2002Date of Patent: February 8, 2011Assignee: Nippon Steel CorporationInventors: Hiromasa Shoji, Tsutomu Sugiura
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Publication number: 20100044234Abstract: The invention relates to a superficial treatment method by electrolysis of ferrous surfaces to enhance friction or tread and seizing resistance features, wherein the surfaces provide the electrolysis anode, the electrolysis bath includes a sulphur species, primarily contains water and also contains a chloride salt and a nitrogen species in quantities which facilitates the sulphuration reaction of the surfaces.Type: ApplicationFiled: November 16, 2007Publication date: February 25, 2010Applicant: H.E.F.Inventors: Philippe Maurin-Perrier, Herve Chavanne, Smail Aaziz
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Publication number: 20090181240Abstract: In one embodiment, a functionalized particle includes a n inorganic particle with diazonium functional group attached. In some embodiments, the largest dimension of the inorganic particle ranges between about 10 nm and 1000 ?m. In another embodiment, a substrate with a hydrophobic surface includes a substrate, and a first plurality of inorganic particles with at least one diazonium functional group attached to the substrate. The largest dimension of the first plurality of inorganic particles ranges between about 10 nm and 1000 ?m. One embodiment includes a second plurality of particles with at least one phenol functional group attached to the inorganic particle. In a further embodiment, a fluorinated functional group is attached to the second plurality of particles. In some embodiments, the material has a hydrophobic surface with a water contact angle greater than about 150°.Type: ApplicationFiled: December 8, 2008Publication date: July 16, 2009Applicant: Tenaris Connections AGInventors: Federico Jose Williams, Maria Joselevich
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Publication number: 20090087716Abstract: One embodiment of the invention includes an assembly of metal oxide comprising valve metal oxide nanotubes.Type: ApplicationFiled: September 27, 2007Publication date: April 2, 2009Applicant: GM Global Technology Operations, Inc.Inventors: Mahmoud H. Abd Elhamid, Gayatri Vyas Dadheech, Curtis A. Wong, Youssef M. Mikhail, Michael J. Lukitsch
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Patent number: 7494716Abstract: Process for the anodic electro-dipcoating of conducting surfaces by dipping in an aqueous anodic electro-dipcoating bath and connecting up as the anode, in which an aqueous anodic electro-dipcoating bath is used that contains 1 to 15 wt. %, referred to the binder solids of the electro-dipcoating bath, of one or more phosphoric acid epoxy esters and/or phosphonic acid epoxy esters that have been produced in the presence of alcohols.Type: GrantFiled: December 13, 2000Date of Patent: February 24, 2009Assignee: E. I. du Pont de Nemours and CompanyInventors: Eduard Ehmann, Manfred Evers, Andreas Fieberg, Konstadinos Markou, Bettina Vogt-Birnbrich
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Patent number: 7422629Abstract: Electrolysis using a suitable electrolyte provides a completely nonsludging zinc phosphate conversion coating process that produces a high quality conversion coating in a very short time. The suitable electrolyte contains at least water, dissolved nitric acid, and dissolved zinc cations and optionally also contains m chemically distinct species of cations other than zinc and n chemically distinct species of anions other than anions derivable by ionization of phosphoric and nitric acids, each of m and n independently being zero or a positive integer.Type: GrantFiled: March 2, 2000Date of Patent: September 9, 2008Assignee: Henkel Kommanditgesellschaft Auf AktienInventors: Jun Kawaguchi, Kazuhiro Ishikura, Tomoyuki Manmi
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Publication number: 20080169200Abstract: A method of anodizing steel, wherein a steel object is connected to a positive terminal of a power supply, a counter electrode is connected to a negative terminal of the power supply, the steel object and counter electrode are placed into a solution of KOH or NaOH, and a voltage is applied across the terminals to anodize the steel object by forming a adherent blue-black or semi-adherent dichroic colored oxide coating thereon.Type: ApplicationFiled: January 17, 2007Publication date: July 17, 2008Inventors: Thomas David Burleigh, Taylor Chase Dotson, Keenan Thomas Dotson
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Patent number: 7297406Abstract: The present invention relates to a cationic electrodeposition coating composition substantially free of lead compounds, which is excellent in curability and can be finish-coated with a splendid appearance, and an article coated with the composition. The invention provides a lead-free electrodeposition coating composition excellent in curability and a coated article, the composition being capable of forming a coating film, which emits less tin compounds to have no influence on appearance of a finish coating film and film performances.Type: GrantFiled: March 3, 2004Date of Patent: November 20, 2007Assignees: Honda Motor Co., Ltd., Nippon Paint Co., Ltd.Inventors: Hiroyuki Morishita, Katsuyoshi Kaneko, Fumiaki Niisato, Toshiyuki Ishii, Kageki Fujimoto
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Patent number: 7294410Abstract: The present invention relates to a cationic electrodeposition coating composition substantially free of lead compounds, and more specifically to a method of coating an alloyed hot-dip galvanized steel plate with the composition and a coated article obtained by the method having edge portions and general surfaces excellent in corrosion resistance. The invention provides a method of coating an alloyed hotdip galvanized steel plate with a lead-free cationic electrodeposition coating composition containing a rust preventive pigment to form an electrodeposition coating film excellent in corrosion resistance, and a coated article obtained by the electrodeposition.Type: GrantFiled: March 3, 2004Date of Patent: November 13, 2007Assignees: Honda Motor Co., Ltd., Nippon Paint Co., Ltd.Inventors: Hiroyuki Morishita, Katsuyoshi Kaneko, Fumiaki Niisato, Toshiyuki Ishii
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Patent number: 7204925Abstract: A structure and a method of preventing electrolytic corrosion for a magnesium alloy member (20), the structure wherein a first coated layer (11) formed by electro deposition and a second coated layer (12) formed by distributing PTFE particles on the first coated layer (11) are covered on the surface of a tightening member (1) at least on a surface coming into contact with the magnesium alloy member (20), whereby, the electrolytic corrosion of the magnesium alloy member can be prevented at a low cost by insulating a tightening member such as a steel bolt and a washer from the magnesium alloy member, and an adhesiveness therebetween can be sufficiently assured.Type: GrantFiled: August 20, 2002Date of Patent: April 17, 2007Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Sadaharu Matsumura, Tsuyoshi Kawabe, Tetsuya Saito, Katsumi Sakamoto, Ryosuke Kamegamori
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Patent number: 7186327Abstract: A method and apparatus wherein an electrically conductive element is placed inside a previously installed metallic water vessel such as a supply pipe or well. A direct current voltage is then applied between the element and the conductive wall of the vessel. The conductive element can be a partially insulated wire. For causing deposition on the vessel, the voltage applied to the conductive element is of an amount sufficient to cause the potential of the metallic vessel to be lowered below the potential of the element by at least ?0.3 volts, and more adequately ?1.3 volts. An alternative embodiment involves reversing the polarity of the voltage applied between the conductive element and the vessel, causing the oxidation/reduction reaction to reverse, resulting in calcium carbonate being removed from the vessel by the production of acid at the surface of the vessel.Type: GrantFiled: July 18, 2002Date of Patent: March 6, 2007Inventor: Larry L. Russell
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Patent number: 7144492Abstract: The application of anti-corrosion base coating by cataphoretic painting (KTL) is well known in manufacturing automobile body parts. However the cataphoretic paint can penetrate only incompletely or possibly not at all into the gap in the contact areas of the components joined to each other. This type of gap is conventionally scaled following cataphoretic painting, in order to ensure corrosion protection for the entire assembly. The present invention makes it possible to dispense with the sealing in the production of an assembly of joined conductive components and nevertheless to ensure a sufficient corrosion protection. By introducing topographic changes in the components projecting from their surface in the known contact areas and then joining these components, they are spaced apart by the projecting topographic changes in such a manner that during cataphoretic painting the paint wets the entire surface of the assembly.Type: GrantFiled: May 27, 2005Date of Patent: December 5, 2006Assignee: DaimlerChrysler AGInventors: Wolfgang Becker, Alfred Fuchs, Klaus Goth, Markus Knoeller, Dirk Lindenau, Claus-Dieter Reiniger, Daniel Zauner
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Patent number: 7005056Abstract: A method for inhibiting corrosion, e.g., pitting corrosion, of alloys is provided. Particularly, the method comprises contacting at least a portion of a surface of the alloy with an aqueous solution comprising a salt of one or more rare earth elements selected from the group consisting of yttrium, gadolinium, cerium, europium, terbium, samarium, neodymium, praseodymium, lanthanum, holmium, ytterbium, dysprosium and erbium; and establishing a voltage differential between an anode comprising the alloy and a cathode in the solution at an effective level and for a sufficient period of time wherein a rare earth element oxide-containing coating is formed on the surface of the alloy to inhibit corrosion thereof.Type: GrantFiled: October 2, 2001Date of Patent: February 28, 2006Assignee: The Johns Hopkins UniversityInventors: Rengaswamy Srinivasan, Hassan M. Saffarian, Stuart A. Fogel
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Patent number: 6994779Abstract: The disclosure relates to a process for forming a deposit on the surface of a metallic or conductive surface. The process employs an energy enhanced process to deposit a silicate containing coating or film upon a metallic or conductive surface.Type: GrantFiled: March 3, 2003Date of Patent: February 7, 2006Assignee: Elisha Holding LLCInventors: Robert L Heimann, William M. Dalton, John Hahn, David M. Price, Wayne L. Soucie, Ravi Chandran
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Patent number: 6764769Abstract: The invention relates to a novel apatite-coated metallic material having improved surface quality and biocompatibility, a process for its preparation, and the use of the material for bone implants, in particular dental implants, artificial joints and fixative material for accident surgery (osteosynthesis material). The coating in this case consists of a thick covering of hydroxyapatite crystals and/or amorphous calcium phosphate spheres having a specific surface area of less than 15 m2/g.Type: GrantFiled: June 6, 2002Date of Patent: July 20, 2004Assignee: Biomet Merck GmbHInventors: Bernd Kotte, Jürgen Hofinger, Tanja Hebold
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Patent number: 6733650Abstract: Disclosed are a process for producing a zinc oxide film comprising the steps of transporting a conductive long substrate via above at least one electrode comprised of zinc in an electrodeposition bath held in an electrodeposition tank and applying an electric field between the electrode and the conductive long substrate, thereby forming a zinc oxide film on the conductive long substrate, the process comprising a first step of forming the zinc oxide film on a part of the conductive long substrate; a second step of stopping the application of the electric field and the transportation; and a third step of bringing at least a region of a part of the conductive long substrate being in contact with the electrodeposition bath in the second step into non-contact with the electrodeposition bath, and an apparatus suitably used for the process. The process and apparatus enables high-quality zinc oxide films to be produced.Type: GrantFiled: July 3, 2001Date of Patent: May 11, 2004Assignee: Canon Kabushiki KaishaInventors: Yuichi Sonoda, Kozo Arao, Noboru Toyama, Yusuke Miyamoto
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Publication number: 20040011659Abstract: A method for inhibiting corrosion, e.g., pitting corrosion, of alloys is provided. Particularly, the method comprises contacting at least a portion of a surface of the alloy with an aqueous solution comprising a salt of one or more rare earth elements selected from the group consisting of yttrium, gadolinium, cerium, europium, terbium, samarium, neodymium, praseodymium, lanthanum, holmium, ytterbium, dysprosium and erbium; and establishing a voltage differential between an anode comprising the alloy and a cathode in the solution at an effective level and for a sufficient period of time wherein a rare earth element oxide-containing coating is formed on the surface of the alloy to inhibit corrosion thereof.Type: ApplicationFiled: February 4, 2003Publication date: January 22, 2004Inventors: Rengaswamy Srinivasan, Hassan M. Saffarian, Stuart A. Fogel
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Publication number: 20040000492Abstract: A sliding member having excellent seizure resistance comprising a metallic member provided with a sulfide-based solid lubricating layer on the sliding surface thereof is provided, characterized in that the interface of the metallic member in contact with said solid lubricating layer is provided with a surface roughness Rmax of 1 &mgr;m or higher. The sliding member above is obtained by preparing an aqueous solution dissolved therein one or two types or more of thiocyanates or thiosulfates of alkali metals or alkaline earth metals, and by performing electrolytic treatment in which a steel member the surface roughness thereof is controlled is used as the anode. In this manner, an iron sulfide based layer is formed on the surface of the steel member by using the Fe component derived from the steel and the S component from the solution as the reacting agents.Type: ApplicationFiled: July 1, 2003Publication date: January 1, 2004Applicant: DOWA MINING CO., LTD.Inventors: Osamu Ogawa, Motoyoshi Yamauchi, Toshiki Kasamatsu
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Patent number: 6660152Abstract: According to the invention, silicon nanoparticles are applied to a substrate using an electrochemical plating processes, analogous to metal plating. An electrolysis tank of an aqueous or non-aqueous solution, such as alcohol, ether, or other solvents in which the particles are dissolved operates at a current flow between the electrodes. In applying silicon nanoparticles to a silicon, metal, or non-conducting substrate, a selective area plating may be accomplished by defining areas of different conductivity on the substrate. Silicon nanoparticle composite platings and stacked alternating material platings are also possible. The addition of metal ions into the silicon nanoparticle solution produces a composite material plating. Either composite silicon nanoparticle platings or pure silicon nanoparticle platings may be stacked with each other or with convention metal platings.Type: GrantFiled: November 15, 2001Date of Patent: December 9, 2003Assignee: The Board of Trustees of the University of IllinoisInventors: Munir H. Nayfeh, Gennadiy Belomoin, Adam Smith, Taysir Nayfeh
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Patent number: 6641711Abstract: An electrodeposition coating composition that is excellent in bath stability and that can give a cured film enhanced in hardness and an electrodeposition coating process is provided. An electrodeposition coating composition to be used in an electrodeposition coating process which comprises the electrodeposition step of immersing a substrate in an electrodeposition coating composition and applying a voltage between the substrate as an anode or cathode and a counter electrode to thereby form a film of said electrodeposition coating composition on the surface of the substrate, and the heating step of heating said film obtained in the above electrodeposition step, and said electrodeposition coating composition comprising having electrodeposition potentiality against the curing reaction of said film.Type: GrantFiled: August 16, 2001Date of Patent: November 4, 2003Assignee: Nippon Paint Co., Ltd.Inventors: Hiroyuki Sakamoto, Ichiro Kawakami, Koji Izumiya, Takao Saito, Masahiro Nishio
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Patent number: 6589412Abstract: A sliding member having excellent seizure resistance comprising a metallic member provided with a sulfide-based solid lubricating layer on the sliding surface thereof is provided, characterized in that the interface of the metallic member in contact with said solid lubricating layer is provided with a surface roughness Rmax of 1 &mgr;m or higher. The sliding member above is obtained by preparing an aqueous solution dissolved therein one or two types or more of thiocyanates or thiosulfates of alkali metals or alkaline earth metals, and by performing electrolytic treatment in which a steel member the surface roughness thereof is controlled is used as the anode. In this manner, an iron sulfide based layer is formed on the surface of the steel member by using the Fe component derived from the steel and the S component from the solution as the reacting agents.Type: GrantFiled: October 10, 2000Date of Patent: July 8, 2003Assignee: Dowa Mining Co., Ltd.Inventors: Osamu Ogawa, Motoyoshi Yamauchi, Toshiki Kasamatsu
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Patent number: 6572756Abstract: The disclosure relates to a process for forming a deposit on the surface of a metallic or conductive surface. The process employs an electrolytic process to deposit a mineral containing coating or film upon a metallic or conductive surface.Type: GrantFiled: March 23, 2001Date of Patent: June 3, 2003Assignee: Elisha Holding LLCInventors: Robert L. Heimann, William M. Dalton, John Hahn, David M. Price, Wayne L. Soucie
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Patent number: 6346186Abstract: A method for electrochemical phosphating of metal surfaces, particularly stainless steel, in connection with cold forming of metal workpieces, which method provides the cold formed workpiece with a lubricant after phosphating, involves an electrochemical phosphating through a cathodic process applying an aqueous phosphating solution containing 0.5 to 100 g Ca2+/l 0.5 to 100 g Zn2+/l 5 to 100 g PO43−/l 0 to 100 g NO3−/l 0 to 100 g ClO3−/l and 0 to 50 g F− or Cl−/l by which the temperature of the solution is between 0 and 95° C., the pH-value of the solution is between 0.5 and 5, and the current density is between 0.1 and 250 mA/cm2. This gives a good lubrication effect, a good adhesion to the metal surface, particularly stainless steel, and a more expedient texture than ordinary phosphating.Type: GrantFiled: August 7, 2000Date of Patent: February 12, 2002Assignee: Danfoss A/SInventors: Niels Janniksen Bjerrum, Erik Christensen, Thomas Steenberg
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Publication number: 20020012804Abstract: The disclosure relates to a process for forming a deposit on the surface of a metallic or conductive surface. The process employs an electrolytic process to deposit a silicate containing coating or film upon a metallic or conductive surface.Type: ApplicationFiled: February 1, 2001Publication date: January 31, 2002Inventors: Robert L. Heimann, William M. Dalton, John Hahn, David M. Price, Wayne L. Soucie, Ravi Chandran
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Patent number: 6328873Abstract: Cathodic electrodeposition coating compositions containing, in addition to conventional self-cross-linking or external cross-linking film-forming binders as well as optionally cross-linking agents, pigments, extenders, additives conventionally used in coating agents and solvents, from 0.1 to 5 wt-%, based on the resin solids content of the coating compositions, of one or more sulphonamides, when coated on a galvanized surface, produce coatings that are substantially free of pinholes.Type: GrantFiled: March 30, 2000Date of Patent: December 11, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Klausjoerg Klein, Norbert David, Heinz-Peter Katzmann
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Patent number: 6322688Abstract: In order to improve the adhesion property of an electrical steel sheet with no film of inorganic mineral matter on its surface, especially with respect to a tension-imparting insulating film, anodic electrolysis in an aqueous solution of silicate is carried out before insulating film formation to form a silicic film excellent in adhesion property with respect to the insulating film in a thin and strongly attached condition on the steel sheet surface. By this, a tension-imparting insulating film can be formed on a grain-oriented electrical steel sheet with excellent adhesion property to reduce the iron loss of the oriented electrical steel sheet. Also in the case of an insulating film that is not of the tension-imparting type, enhancement of film heat resistance and improvement of insulating property by increasing a film thickness are possible.Type: GrantFiled: June 1, 1999Date of Patent: November 27, 2001Assignee: Nippon Steel CorporationInventors: Shuichi Yamazaki, Masao Kurosaki, Kenichi Murakami, Yoshiyuki Ushigami
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Patent number: 6322687Abstract: The disclosure relates to a process for forming a deposit on the surface of a metallic or conductive surface. The process employs an electrolytic process to deposit a mineral containing coating or film upon a metallic or conductive surface.Type: GrantFiled: March 22, 2000Date of Patent: November 27, 2001Assignee: Elisha Technologies Co LLCInventors: Robert L. Heimann, William M. Dalton, John Hahn, David M. Price, Wayne L. Soucie
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Patent number: 6280852Abstract: A laminated steel sheet of the present invention has a surface-treated steel sheet with an outermost chromium oxide having specific surface area of 1.08 to 1.35 as a base sheet, and a plastic film is laminated on at least one side of the base sheet, and has excellent in tenacious adhesion to the plastic film after forming.Type: GrantFiled: September 21, 1998Date of Patent: August 28, 2001Assignee: Toyo Kohan Co., Ltd.Inventors: Nobuyoshi Shimizu, Masao Komai, Ayumu Taniguchi
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Patent number: 6258243Abstract: The disclosure relates to a process for forming a deposit on the surface of a metallic or conductive surface. The process employs an electrolytic process to deposit a mineral containing coating or film upon a metallic or conductive surface.Type: GrantFiled: July 24, 1998Date of Patent: July 10, 2001Assignee: Elisha Technologies Co LLCInventors: Robert L. Heimann, William M. Dalton, John Hahn, David M. Price