Utilizing Cell Having Three Or More Compartments Or Units Patents (Class 205/514)
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Patent number: 8795508Abstract: The present invention relates to carbon dioxide sequestration, including processes in which group-2 silicates are used to remove carbon dioxide from waste streams to form corresponding group-2 carbonates and silica.Type: GrantFiled: December 17, 2010Date of Patent: August 5, 2014Assignee: Skyonic CorporationInventor: Joe David Jones
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Patent number: 7993511Abstract: An electrochemical system comprising a cathode electrolyte comprising added carbon dioxide and contacting a cathode; and a first cation exchange membrane separating the cathode electrolyte from an anode electrolyte contacting an anode; and an electrochemical method comprising adding carbon dioxide into a cathode electrolyte separated from an anode electrolyte by a first cation exchange membrane; and producing an alkaline solution in the cathode electrolyte and an acid.Type: GrantFiled: November 12, 2009Date of Patent: August 9, 2011Assignee: Calera CorporationInventors: Ryan J. Gilliam, Valentin Decker, Nigel Antony Knott, Michael Kostowskyj, Bryan Boggs
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Patent number: 7875163Abstract: A low-voltage, low-energy electrochemical system and method of producing hydroxide ions and/or bicarbonate ions and/or carbonate ions utilizing significantly less than the typical 3V used across the conventional anode and cathode to produce the ions; consequently, carbon dioxide emissions attributable to the present system and method are significantly reduced.Type: GrantFiled: June 24, 2009Date of Patent: January 25, 2011Assignee: Calera CorporationInventors: Ryan J. Gilliam, Thomas A. Albrecht, Nikhil Jalani, Nigel Antony Knott, Valentin Decker, Michael Kostowskyj, Bryan Boggs, Kasra Farsad
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Patent number: 7790012Abstract: A low-energy method and system of forming hydroxide ions in an electrochemical cell. On applying a low voltage across the anode and cathode, hydroxide ions form in the electrolyte containing the cathode, protons form at the anode but a gas e.g. chlorine or oxygen does not form at the anode.Type: GrantFiled: December 23, 2008Date of Patent: September 7, 2010Assignee: Calera CorporationInventors: Donald W. Kirk, J. Douglas Way, Allen J. Bard, Ryan J. Gilliam, Kasra Farsad, Valentin Decker
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Patent number: 7048843Abstract: The invention relates to a method for producing metal hydroxides or alkaline metal carbonates by anode dissolution of the corresponding metals and precipitation of the hydroxides or alkaline carbonates in an aqueous medium. The anode dissolution of the metal components is carried out in the anode compartment of a three-compartment electrolytic cell. An aqueous auxiliary salt solution is fed to an intermediate compartment that is disposed between the anode compartment and the cathode compartment and that is separated therefrom by a porous membrane. An at least not alkaline metal salt solution is continuously taken from the anode compartment while an alkaline auxiliary salt solution is continuously taken from the cathode compartment. The at least not alkaline metal salt solution and the alkaline auxiliary salt solution are combined outside the electrolytic cell for the purpose of precipitating metal hydroxides or alkaline metal carbonates.Type: GrantFiled: June 6, 2001Date of Patent: May 23, 2006Assignee: H.C. Starck GmbHInventors: Armin Olbrich, Astrid Görge, Frank Schrumpf, Juliane Meese-Marktscheffel, Viktor Stoller, Gerhard Gille, Josef Schmoll, Michael Kruft, Dirk Naumann
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Publication number: 20030141199Abstract: The invention relates to a method for producing metal hydroxides or alkaline metal carbonates by anode dissolution of the corresponding metals and precipitation of the hydroxides or alkaline carbonates in an aqueous medium. The anode dissolution of the metal components is carried out in the anode compartment of a three-compartment electrolytic cell. An aqueous auxiliary salt solution is fed to an intermediate compartment that is disposed between the anode compartment and the cathode compartment and that is separated therefrom by a porous membrane. An at least not alkaline metal salt solution is continuously taken from the anode compartment while an alkaline auxiliary salt solution is continuously taken from the cathode compartment. The at least not alkaline metal salt solution and the alkaline auxiliary salt solution are combined outside the electrolytic cell for the purpose of precipitating metal hydroxides or alkaline metal carbonates.Type: ApplicationFiled: December 13, 2002Publication date: July 31, 2003Inventors: Armin Olbrich, Astrid Grge, Frank Schrumpf, Juliane Meese-Marktscheffel, Viktor Stoller, Gerhard Gille, Josef Schmoll, Michael Kruft, Dirk Naumann
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Patent number: 5888368Abstract: Process for manufacturing sodium hydroxide by the electrodialysis of sodium carbonate in an electrodialysis cell having three compartments, in which an aqueous sodium carbonate solution is introduced into a compartment of the cell which is bounded between two cationic membranes, an acid is introduced into a compartment which is bounded between one of the cationic membranes and a cationic face of a bipolar membrane, and an aqueous sodium hydroxide solution is removed from a compartment which is adjacent to an anionic face of the bipolar membrane.Type: GrantFiled: October 29, 1997Date of Patent: March 30, 1999Assignee: Solvay (Societe Anonyme)Inventor: Francesco Posar
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Patent number: 5855759Abstract: The present invention relates to an electrochemical cell and a process for producing a hydroxide solution, sulfuric acid and a halogen gas from a hydrogen halide and a sulfate solution. In particular, the sulfate solution may be an alkali metal sulfate solution, such as sodium or potassium sulfate solution, an alkaline earth metal sulfate solution or an ammonium sulfate solution. The cell and the process may use either an anhydrous or an aqueous hydrogen halide, namely, hydrogen chloride, hydrogen fluoride, hydrogen bromide and hydrogen iodide, to a respective dry halogen gas, such as chlorine, fluorine, bromine, or iodine, to produce hydrogen ions in order to split the alkali metal solution and form the sulfuric acid. The cell has two membrane-electrode assemblies, where an anode is disposed in contact with one membrane, and a cathode is disposed in contact with another membrane. The sulfate solution is fed in between the membrane-electrode assemblies.Type: GrantFiled: November 3, 1997Date of Patent: January 5, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Kenneth Bernard Keating, James Arthur Trainham, III, Clarence Garlan Law, Jr., John Scott Newman
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Patent number: 5776328Abstract: Electrolyzer for the electrolysis of a solution of a salt for the production of a solution containing an acid and a solution of a base, said electrolyzer comprising at least one elementary cell divided into three compartments by two cation-exchange membranes, the first of said compartments contains the first of said membranes and a cathode for hydrogen evolution and the production of the base, a central compartment is defined by said cation-exchange membranes and has an inlet for the solution of the salt and has an outlet for the withdrawal of the solution containing the acid, a third compartment contains the second of said cation exchange membranes and an anode, said anode comprises a porous electrocatalytic sheet for hydrogen ionization and a porous rigid current collector, said third compartment further has an inlet for a hydrogen-containing gaseous stream and an outlet for the venting of the rest of gas characterized in that said current collector has a multiplicity of contact points and said porous electType: GrantFiled: May 24, 1996Date of Patent: July 7, 1998Assignee: De Nora Permelec S.p.A.Inventors: Carlo Traini, Giuseppe Faita
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Patent number: 5622614Abstract: The present invention relates to an electrochemical cell and a process for using a halogen halide and splitting a sulfate solution and producing a hydroxide solution, sulfuric acid and a halogen gas. In particular, the sulfate solution may be an alkali metal sulfate solution, such as sodium or potassium sulfate solution, an alkaline earth metal sulfate solution or an ammonium sulfate solution. The cell and the process may use either an anhydrous or an aqueous hydrogen halide, namely, hydrogen chloride, hydrogen fluoride, hydrogen bromide and hydrogen iodide, to a respective dry halogen gas, such as chlorine, fluorine, bromine, or iodine, to produce hydrogen ions in order to split the sulfate solution and form the sulfuric acid. The cell has two membrane-electrode assemblies, where an anode is disposed in contact with one membrane, and a cathode is disposed in contact with another membrane. The sulfate solution is fed in between the membrane-electrode assemblies.Type: GrantFiled: May 1, 1995Date of Patent: April 22, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Kenneth B. Keating, James A. Trainham, III, Clarence G. Law, Jr., John S. Newman, Douglas J. Eames