Hydroxide Patents (Class 205/508)
  • Patent number: 11929480
    Abstract: The disclosure relates to the technical field of batteries, and proposes a battery and a battery apparatus. The battery includes: a housing; a cell, the cell disposed in the housing. A pole element is disposed on the housing. A heat sink is disposed on the housing.
    Type: Grant
    Filed: July 12, 2021
    Date of Patent: March 12, 2024
    Assignee: CALB Co., Ltd.
    Inventors: Chengkun Tang, Fangfang Pan
  • Patent number: 11629415
    Abstract: A process for electrochemical preparation of sodium alkoxide is performed in an electrolysis cell having three chambers, wherein the middle chamber is separated from the cathode chamber by a solid-state electrolyte permeable to sodium ions, and from the anode chamber by a diffusion barrier. The geometry of the electrolysis cell protects the solid-state electrolyte permeable to sodium ions from acidic destruction by the pH of the anolyte that falls in the course of electrolysis. The anolyte used in the process is a brine also comprising carbonates and/or hydrogencarbonates, as well as NaCl. The process solves the problem that CO2 from these carbonates and/or hydrogencarbonates forms in the electrolysis cell during the electrolysis of this brine obtained from pretreatment. The process prevents the formation of a gas bubble in the electrolysis cell that disrupts electrolysis and reduces the contamination of the chlorine with CO2.
    Type: Grant
    Filed: March 22, 2021
    Date of Patent: April 18, 2023
    Assignee: Evonik Functional Solutions GmbH
    Inventors: Michael Horn, Felix Gärtner, Philip Heinrich Reinsberg, Rüdiger Teufert
  • Patent number: 11434576
    Abstract: System for, and methods of, recovering precious metals from precious metals-containing solids are described herein. Methods for the recovery of precious metals from precious metals-containing solids heating a salt mixture to form a molten salt mixture, adding a precious metals-containing solid to the molten salt mixture to form a molten salt/precious metals-containing solids mixture, adding an oxidizing agent to the molten salt/precious metals-containing solids mixture, forming a liquid solution from molten salt/precious metals-containing solids mixture, the liquid solution comprising soluble precious metal salts, and subjecting the liquid solution to an electrodeposition process to form purified precious metals. Systems for, and methods of, recovery precious metals from precious metals-containing solids allow for the recovery of salt mixtures and reuse of the salt mixtures in subsequent precious metals recovery operations.
    Type: Grant
    Filed: August 11, 2017
    Date of Patent: September 6, 2022
    Assignee: CLEAN RESOURCES PTE. LTD
    Inventors: Abraham Fouad Jalbout, Hassan Elsentriecy
  • Patent number: 10884274
    Abstract: Disclosed is a plastic substrate, which includes a plastic film, a metal layer, and a resin layer having a conductive material dispersed therein and which is useful as a lower substrate of a transmissive electronic paper display device or a display device.
    Type: Grant
    Filed: July 7, 2017
    Date of Patent: January 5, 2021
    Assignee: KOLON INDUSTRIES, INC.
    Inventors: Hak Gee Jung, Jeong Han Kim, Hyo Jun Park
  • Patent number: 10662088
    Abstract: A salt cell chlorinator adapted to run a self-cleaning program by scraping off residual buildup, the salt cell chlorinator having: electrodes arranged a line within a housing, each electrode having: a round shape; a first face; and a second face; rotary wipers arranged within the line of the electrodes, such that each rotary wiper is adapted to make contact with at least one electrode of the electrodes, wherein each rotary wiper is adapted to rotate on the first face or the second face of the electrodes; a drive motor adapted to cause a rotation of the rotary wipers; a control panel adapted to customize the self-cleaning program to run at a predetermined time interval; wherein the rotation of the rotary wipers removes the residual buildup from the electrodes; and wherein the predetermined time interval occurs between occurrences of the chlorination program.
    Type: Grant
    Filed: April 24, 2019
    Date of Patent: May 26, 2020
    Inventors: Brian Rosser Rejniak, John Alan Rejniak
  • Patent number: 10604415
    Abstract: A basic oxygen furnace slag treatment method includes the steps of mixing basic oxygen furnace slag with an active aqueous solution and then keeping the mixture thus obtained under an enclosed environment for reaction and then employing a solid-liquid separation procedure to separate solid phase from liquid phase. Since basic oxygen furnace slag has strong alkaline, the method of the invention overcomes the problem that directly discharging basic oxygen furnace slag will cause environmental pollutions. The basic oxygen furnace slag treatment method avoids a secondary pollution, and can turn waste into treasure, bringing a number of economic benefits.
    Type: Grant
    Filed: March 9, 2017
    Date of Patent: March 31, 2020
    Inventor: Kun-Liang Hong
  • Patent number: 9302216
    Abstract: In the carbon dioxide gas fixation method and carbon dioxide gas fixation apparatus, seawater (7) is electrolyzed, anodic electrolyzed water (7a) and cathodic electrolyzed water (7b) produced by electrolysis of the seawater are separated, alkaline material is inputted into the anodic electrolyzed water to adjust pH, carbon dioxide gas is blown into the cathodic electrolyzed water to fix the carbon dioxide gas as carbonate, and the anodic electrolyzed water after pH adjustment and the cathodic electrolyzed water after carbonate fixation are intermixed, and discharged in a state where a pH of the intermixed water is identical to a pH of the seawater. As a result, it is possible to offer a carbon dioxide gas fixation method and a carbon dioxide gas fixation apparatus which fix carbon dioxide gas with little impact on the environment, and without risk of re-release.
    Type: Grant
    Filed: August 30, 2011
    Date of Patent: April 5, 2016
    Assignee: IHI CORPORATION
    Inventors: Tatsushi Iwamoto, Kenichi Akamine, Junichi Okuyama
  • Publication number: 20140262813
    Abstract: Both the reaction of hydride-forming compositions with hydrogen to form hydrides, and the decomposition of such hydrides to release hydrogen may be promoted electrochemically. These reactions may be conducted reversibly, and if performed in a suitable cell, the cell will serve as a hydrogen storage and release device.
    Type: Application
    Filed: May 27, 2014
    Publication date: September 18, 2014
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: John J. Vajo, Wen Li, Ping Liu, Frederick E. Pinkerton
  • Publication number: 20140234193
    Abstract: Systems are described for dissolving metal silicates to: produce metal hydroxide; remove carbon dioxide or other acid gases from the atmosphere or other gas mixture by reacting such gases with the metal hydroxide; penetrate or excavate metal silicates; extract metals or silicon-containing compounds from metal silicates; and produce hydrogen and oxygen or other gases.
    Type: Application
    Filed: January 18, 2011
    Publication date: August 21, 2014
    Applicant: Lawrence Livermore National Security, LLC
    Inventor: Gregory Hudson Rau
  • Patent number: 8764964
    Abstract: A system for forming metal hydroxide from a metal carbonate utilizes a water electrolysis cell having an acid-producing anode and a hydroxyl-producing cathode immersed in a water solution of sufficient ionic content to allow an electric current to pass between the hydroxyl-producing cathode and the acid-producing anode. A metal carbonate is placed in close proximity to the acid-producing anode. A direct current electrical voltage is provided across the acid-producing anode and the hydroxyl-producing cathode sufficient to generate acid at the acid-producing anode and hydroxyl ions at the hydroxyl-producing cathode. The acid dissolves at least part of the metal carbonate into metal and carbonate ions allowing the metal ions to travel toward the hydroxyl-producing cathode and to combine with the hydroxyl ions to form the metal hydroxide. The carbonate ions travel toward the acid-producing anode and form carbonic acid and/or water and carbon dioxide.
    Type: Grant
    Filed: December 13, 2011
    Date of Patent: July 1, 2014
    Assignee: Lawrence Livermore National Security, LLC.
    Inventor: Gregory Hudson Rau
  • Patent number: 8641874
    Abstract: This is an electrolytic apparatus and process for the production of Hypochlorous Acid (HClO) and Sodium Hydroxide (NaOH) in a closed-loop arrangement. A brine solution in an electrolyzer cell is subjected to an electric current, causing HClO and/or NaOH to be produced in water circulated through the cell. The produced solution is recirculated through the cell as its chemical properties are monitored by a sensor, connected by a controller which controls a recirculating pump and the electric current, until the sensor indicates that the concentration of the solution has reached a desired value, and the controller stops the process.
    Type: Grant
    Filed: January 18, 2011
    Date of Patent: February 4, 2014
    Assignee: Rayne Guest
    Inventor: John Kuiphoff
  • Publication number: 20130312500
    Abstract: An electrolytic CO2-removal device for anion analysis of a liquid sample. The device includes a basic chamber and CO2-permeable tubing in the basic chamber. Anion exchange membranes are disposed on opposite sides of the basic chamber, and electrodes are disposed outside the membranes. The device can be integral with a suppressor in an ion chromatography system and/or an aqueous stream purifier. Also, methods performed by the device.
    Type: Application
    Filed: August 1, 2013
    Publication date: November 28, 2013
    Inventor: John M. Riviello
  • Patent number: 8501129
    Abstract: The subject of the invention is a method for reduction of the CO2 content of flue and atmospheric gases and equipment for application of the method. The characteristic of the solution according to the invention is, that “hydroxide” ionized water containing (OH?) ions of alkaline characteristics is used as reaction medium for binding carbon dioxide (CO2) gas, and carbon dioxide (CO2) gas gets into reaction with alkaline ionized water, and during the reaction from the carbon dioxide (CO2) gas and water, carbonate ion (CO32?) and hydrogencarbonate/bicarbonate (2HCO3?) are formed, and they leave for the outside atmosphere and/or outside water with the bound CO2 content in stable gas or liquid form.
    Type: Grant
    Filed: January 14, 2010
    Date of Patent: August 6, 2013
    Inventor: Ferenc Meszaros
  • Publication number: 20130161200
    Abstract: In the magnesium recovery method and magnesium recovery apparatus, anode electrolyzed water (7a) and cathode electrolyzed water (7b) produced by electrolysis of seawater are separated, alkaline material is inputted into the anode electrolyzed water to adjust pH, magnesium is precipitated as magnesium hydroxide in the cathode electrolyzed water, and recovered, and the anode electrolyzed water after pH adjustment and cathode electrolyzed water after carbonate fixation are intermixed, and discharged in a state where a pH of the intermixed water is identical to a pH of the seawater. As a result, magnesium can be recovered from seawater while minimizing impact on the environment.
    Type: Application
    Filed: September 6, 2011
    Publication date: June 27, 2013
    Inventors: Tatsushi Iwamoto, Kenichi Akamine, Junichi Okuyama
  • Patent number: 8366974
    Abstract: An article of manufacture and methods of making same. In one embodiment, the article of manufacture has a plurality of zinc oxide layers substantially in parallel, wherein each zinc oxide layer has a thickness d1, and a plurality of organic molecule layers substantially in parallel, wherein each organic molecule layer has a thickness d2 and a plurality of molecules with a functional group that is bindable to zinc ions, wherein for every pair of neighboring zinc oxide layers, one of the plurality of organic molecule layers is positioned in between the pair of neighboring zinc oxide layers to allow the functional groups of the plurality of organic molecules to bind to zinc ions in the neighboring zinc oxide layers to form a lamellar hybrid structure with a geometric periodicity d1+d2, and wherein d1 and d2 satisfy the relationship of d1?d2?3d1.
    Type: Grant
    Filed: December 4, 2009
    Date of Patent: February 5, 2013
    Assignee: Northwestern University
    Inventors: Samuel I. Stupp, Josh Goldberger, Marina Sofos
  • Patent number: 8349165
    Abstract: Soluble nickel and tin contained in a coating layer are eluted into an aqueous solution by bringing a cathode coated with a nickel-tin alloy into contact with an aqueous solution of an alkali metal hydrogen carbonate such as sodium hydrogen carbonate, thereby reducing the amounts of these metals eluted during electrolysis.
    Type: Grant
    Filed: November 12, 2009
    Date of Patent: January 8, 2013
    Assignee: Tokuyama Corporation
    Inventors: Yasuyuki Tanaka, Kenji Aoki
  • Publication number: 20120292200
    Abstract: Methods and apparatus for separating aqueous solution of alkali aluminate into alkali hydroxide and aluminate hydroxide are disclosed. These methods are enabled by the use of alkali ion conductive membranes in electrolytic cells that are chemically stable and alkali ion selective. The alkali ion conductive membrane includes a chemically stable ionic-selective cation membrane.
    Type: Application
    Filed: July 31, 2012
    Publication date: November 22, 2012
    Inventors: Shekar Balagopal, Kean Duffey
  • Publication number: 20120247970
    Abstract: Methods and systems for electrochemical cell optimization, namely increasing cell efficiency and rate of chemical product, are disclosed. In particular, a device wherein air or an oxygen-containing gas is bubbled through an electrochemical cell and methods of use are disclosed to reduce the voltage demand and power usage of an electrochemical cell. The optimized electrochemical cell also achieves increased chemical generation from electrolysis for using in various settings, including for example, housekeeping applications.
    Type: Application
    Filed: March 31, 2011
    Publication date: October 4, 2012
    Applicant: ECOLAB USA INC.
    Inventors: Erik C. Olson, Kim R. Smith
  • Patent number: 8268159
    Abstract: An electrochemical process for the production of sodium hypochlorite is disclosed. The process may potentially be used to produce sodium hypochlorite from seawater or low purity un-softened or NaCl-based salt solutions. The process utilizes a sodium ion conductive ceramic membrane, such as membranes based on NASICON-type materials, in an electrolytic cell. In the process, water is reduced at a cathode to form hydroxyl ions and hydrogen gas. Chloride ions from a sodium chloride solution are oxidized in the anolyte compartment to produce chlorine gas which reacts with water to produce hypochlorous and hydrochloric acid. Sodium ions are transported from the anolyte compartment to the catholyte compartment across the sodium ion conductive ceramic membrane. Sodium hydroxide is transported from the catholyte compartment to the anolyte compartment to produce sodium hypochlorite within the anolyte compartment.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: September 18, 2012
    Assignee: Ceramatec, Inc.
    Inventors: Shekar Balagopal, Vinod Malhotra, Justin Pendleton, Kathy Jo Reid
  • Publication number: 20120183462
    Abstract: Systems are described for dissolving metal silicates to: produce metal hydroxide; remove carbon dioxide or other acid gases from the atmosphere or other gas mixture by reacting such gases with the metal hydroxide; penetrate or excavate metal silicates; extract metals or silicon-containing compounds from metal silicates; and produce hydrogen and oxygen or other gases.
    Type: Application
    Filed: January 18, 2011
    Publication date: July 19, 2012
    Applicant: Lawrence Livermore National Security, LLC
    Inventor: Gregory Hudson Rau
  • Publication number: 20120160701
    Abstract: An electrolytic cell that generates metal hydroxides from metallic anode material utilizing small metal particles or fines. Metal fines are impregnated in an open cell or reticulated foam material and rolled into a cylindrical shape having a fixed electrode in the center and on the outer surface of the cylinder. Basket cells with larger metal pieces disposed therein in a packed bed configuration may alternatively be utilized.
    Type: Application
    Filed: March 7, 2012
    Publication date: June 28, 2012
    Applicant: MEHL RESEARCH LABORATORIES, LLC
    Inventor: Ronald Charles Mehl
  • Publication number: 20120156126
    Abstract: An electric current is passed through an acidic solution containing one or more soluble metal salts in an electrolytic cell divided by an anion exchange membrane. The acidic solution is fed into the cathode compartment whereby the passage of electric current at sufficient voltage causes the generation of hydrogen at the cathode. This gives rise to a localized very highly polarized region at the cathode resulting in a localized effective high relative pH. This causes the metal cation species to precipitate as a hydroxide (or oxide) species and electroadsorption/electrocoagulation causes the finely precipitated hydroxide (or oxide) species to adhere to the cathode. Electrodialytic transport of the liberated acid anions across the anion exchange membrane selectively removes the acid anions. Oxygen and hydrogen ions are formed by hydrolysis as the counter-reaction at the anode. Hydrogen ions combine with the anions to regenerate sulfuric acid.
    Type: Application
    Filed: January 20, 2010
    Publication date: June 21, 2012
    Inventors: Adam Justin Blunn, Adam Daniel Longstaff
  • Publication number: 20120121491
    Abstract: A system for forming metal hydroxide from a metal carbonate utilizes a water electrolysis cell having an acid-producing anode and a hydroxyl-producing cathode immersed in a water solution of sufficient ionic content to allow an electric current to pass between the hydroxyl-producing cathode and the acid-producing anode. A metal carbonate is placed in close proximity to the acid-producing anode. A direct current electrical voltage is provided across the acid-producing anode and the hydroxyl-producing cathode sufficient to generate acid at the acid-producing anode and hydroxyl ions at the hydroxyl-producing cathode. The acid dissolves at least part of the metal carbonate into metal and carbonate ions allowing the metal ions to travel toward the hydroxyl-producing cathode and to combine with the hydroxyl ions to form the metal hydroxide. The carbonate ions travel toward the acid-producing anode and form carbonic acid and/or water and carbon dioxide.
    Type: Application
    Filed: December 13, 2011
    Publication date: May 17, 2012
    Applicant: Lawrence Livermore National Security, LLC
    Inventor: Gregory Hudson Rau
  • Publication number: 20120118757
    Abstract: An electrolytic cell that generates metal hydroxides from metallic anode material utilizing small metal particles or fines. Metal fines are impregnated in an open cell or reticulated foam material and rolled into a cylindrical shape having a fixed electrode in the center and on the outer surface of the cylinder. Basket cells with larger metal pieces disposed therein in a packed bed configuration may alternatively be utilized.
    Type: Application
    Filed: November 8, 2011
    Publication date: May 17, 2012
    Inventor: Ronald Charles Mehl
  • Patent number: 8177946
    Abstract: A system is described for forming metal hydroxide from a metal carbonate utilizing a water electrolysis cell having an acid-producing anode and a hydroxyl-producing cathode immersed in a water solution of sufficient ionic content to allow an electric current to pass between the hydroxyl-producing cathode and the acid-producing anode. A metal carbonate, in particular water-insoluble calcium carbonate or magnesium carbonate, is placed in close proximity to the acid-producing anode. A direct current electrical voltage is provided across the acid-producing anode and the hydroxyl-producing cathode sufficient to generate acid at the acid-producing anode and hydroxyl ions at the hydroxyl-producing cathode. The acid dissolves at least part of the metal carbonate into metal and carbonate ions allowing the metal ions to travel toward the hydroxyl-producing cathode and to combine with the hydroxyl ions to form the metal hydroxide.
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: May 15, 2012
    Assignee: Lawrence Livermore National Security, LLC
    Inventor: Gregory Hudson Rau
  • Patent number: 8012336
    Abstract: Proposed is a method for collecting valuable metal from an ITO scrap in which a mixture of indium hydroxide and tin hydroxide or metastannic acid is collected by subjecting the ITO scrap to electrolysis in pH-adjusted electrolyte, and roasting this mixture as needed to collect the result as a mixture of indium oxide and tin oxide. This method enables the efficient collection of indium hydroxide and tin hydroxide or metastannic acid, or indium oxide and tin oxide from an ITO scrap of an indium-tin oxide (ITO) sputtering target or an ITO scrap such as ITO mill ends arisen during the manufacture of such ITO sputtering target.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: September 6, 2011
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Yuichiro Shindo, Kouichi Takemoto
  • Publication number: 20110200508
    Abstract: The invention generally relates to methods of selectively removing lithium from various liquids, methods of producing high purity lithium carbonate, methods of producing high purity lithium hydroxide, and methods of regenerating resin.
    Type: Application
    Filed: February 17, 2011
    Publication date: August 18, 2011
    Applicant: Simbol Mining Corp.
    Inventors: Stephen Harrison, Robert Blanchet
  • Publication number: 20110147227
    Abstract: A method and system of separating an acid from an acid-salt solution produced in an electrochemical system using an ion exchange resin bed, by processing the acid-salt solution through the ion exchange resin bed such that the acid is retarded at the bottom of the bed and a de-acidified salt solution is recovered from the top of the bed. After removing the salt solution from the bed, the acid is recovered by back-flushing the resin bed with water.
    Type: Application
    Filed: February 4, 2011
    Publication date: June 23, 2011
    Inventors: Ryan J. Gilliam, Nigel Antony Knott, Michael Kostowskyj
  • Patent number: 7922890
    Abstract: Method and apparatus for a low maintenance, high reliability on-site electrolytic generator incorporating automatic cell monitoring for contaminant film buildup, as well as automatically removing or cleaning the contaminant film. This method and apparatus preferably does not require human intervention to clean.
    Type: Grant
    Filed: November 28, 2007
    Date of Patent: April 12, 2011
    Assignee: MIOX Corporation
    Inventors: Justin Sanchez, Rodney E. Herrington
  • Patent number: 7892447
    Abstract: Nanoplatelet forms of metal hydroxide and metal oxide are provided, as well as methods for preparing same. The nanoplatelets are suitable for use as fire retardants and as agents for chemical or biological decontamination.
    Type: Grant
    Filed: August 9, 2007
    Date of Patent: February 22, 2011
    Assignee: Aqua Resources Corporation
    Inventor: Orville Lee Maddan
  • Publication number: 20100155258
    Abstract: A low-energy method and system of forming hydroxide ions in an electrochemical cell. On applying a low voltage across the anode and cathode, hydroxide ions form in the electrolyte containing the cathode, protons form at the anode but a gas e.g. chlorine or oxygen does not form at the anode.
    Type: Application
    Filed: December 23, 2008
    Publication date: June 24, 2010
    Inventors: Donald W. Kirk, J. Douglas Way, Allen J. Bard, Ryan J. Gilliam, Kasra Farsad, Valentin Decker
  • Patent number: 7736485
    Abstract: Nanoplatelet forms of metal hydroxide and metal oxide are provided, as well as methods for preparing same. The nanoplatelets are suitable for use as fire retardants and as agents for chemical or biological decontamination.
    Type: Grant
    Filed: August 9, 2007
    Date of Patent: June 15, 2010
    Assignee: Aqua Resources Corporation
    Inventor: Orville Lee Maddan
  • Publication number: 20100143679
    Abstract: An article of manufacture and methods of making same. In one embodiment, the article of manufacture has a plurality of zinc oxide layers substantially in parallel, wherein each zinc oxide layer has a thickness d1, and a plurality of organic molecule layers substantially in parallel, wherein each organic molecule layer has a thickness d2 and a plurality of molecules with a functional group that is bindable to zinc ions, wherein for every pair of neighboring zinc oxide layers, one of the plurality of organic molecule layers is positioned in between the pair of neighboring zinc oxide layers to allow the functional groups of the plurality of organic molecules to bind to zinc ions in the neighboring zinc oxide layers to form a lamellar hybrid structure with a geometric periodicity d1+d2, and wherein d1 and d2 satisfy the relationship of d1?d2?3d1.
    Type: Application
    Filed: December 4, 2009
    Publication date: June 10, 2010
    Applicant: NORTHWESTERN UNIVERSITY
    Inventors: Samuel I. Stupp, Josh Goldberger, Marina Sofos
  • Patent number: 7727374
    Abstract: Apparatuses and methods for removing carbon dioxide and other pollutants from a gas stream are provided. The methods include obtaining hydroxide in an aqueous mixture, and mixing the hydroxide with the gas stream to produce carbonate and/or bicarbonate. Some of the apparatuses of the present invention comprise an electrolysis chamber for providing hydroxide and mixing equipment for mixing the hydroxide with a gas stream including carbon dioxide to form an admixture including carbonate and/or bicarbonate.
    Type: Grant
    Filed: September 22, 2005
    Date of Patent: June 1, 2010
    Assignee: Skyonic Corporation
    Inventor: Joe David Jones
  • Publication number: 20100101964
    Abstract: Proposed is a method of recovering valuable metal from scrap containing conductive oxide including the steps of using an insoluble electrode as either an anode or a cathode, using a scrap containing conductive oxide as the counter cathode or anode, performing electrolysis while periodically inverting the polarity, and recovering the scrap as hydroxide. With the foregoing method of recovering valuable metal from scrap containing conductive oxide, oxide system scrap is conductive oxide and a substance that can be reduced to metal or suboxide with hydrogen. This method enables the efficient recovery of valuable metal from sputtering target scrap containing conductive oxide or scrap such as mill ends of conductive oxide that arise during the production of such a sputtering target.
    Type: Application
    Filed: February 8, 2008
    Publication date: April 29, 2010
    Applicant: NIPPON MINING & METALS CO., LTD.
    Inventors: Yuichiro Shindo, Kouichi Takemoto
  • Publication number: 20100084279
    Abstract: Proposed is a method for collecting valuable metal from an ITO scrap in which a mixture of indium hydroxide and tin hydroxide or metastannic acid is collected by subjecting the ITO scrap to electrolysis in pH-adjusted electrolyte, and roasting this mixture as needed to collect the result as a mixture of indium oxide and tin oxide. This method enables the efficient collection of indium hydroxide and tin hydroxide or metastannic acid, or indium oxide and tin oxide from an ITO scrap of an indium-tin oxide (ITO) sputtering target or an ITO scrap such as ITO mill ends arisen during the manufacture of such ITO sputtering target.
    Type: Application
    Filed: June 27, 2007
    Publication date: April 8, 2010
    Applicant: NIPPON MINING & METALS CO., LTD.
    Inventors: Yuichiro Shindo, Kouichi Takemoto
  • Publication number: 20090038955
    Abstract: A system is described for forming metal hydroxide from a metal carbonate utilizing a water electrolysis cell having an acid-producing anode and a hydroxyl-producing cathode immersed in a water solution of sufficient ionic content to allow an electric current to pass between the hydroxyl-producing cathode and the acid-producing anode. A metal carbonate, in particular water-insoluble calcium carbonate or magnesium carbonate, is placed in close proximity to the acid-producing anode. A direct current electrical voltage is provided across the acid-producing anode and the hydroxyl-producing cathode sufficient to generate acid at the acid-producing anode and hydroxyl ions at the hydroxyl-producing cathode. The acid dissolves at least part of the metal carbonate into metal and carbonate ions allowing the metal ions to travel toward the hydroxyl-producing cathode and to combine with the hydroxyl ions to form the metal hydroxide.
    Type: Application
    Filed: August 1, 2008
    Publication date: February 12, 2009
    Inventor: Gregory Hudson Rau
  • Publication number: 20080269910
    Abstract: The invention relates to a medical prosthetic device having a metal material, such as titanium or an alloy thereof, where the surface parts of the metal material are coated with a layer of a corresponding hydroxide material, such as titanium hydroxide. Preferably, the hydroxide layer includes one or more biomolecule substances associated therewith. The invention also relates to an electrolytic process for the preparation of a medical prosthetic device.
    Type: Application
    Filed: July 1, 2008
    Publication date: October 30, 2008
    Inventors: Jan Eirik Ellingsen, Staale Petter Lyngstadaas
  • Publication number: 20080169201
    Abstract: Nanoplatelet forms of metal hydroxide and metal oxide are provided, as well as methods for preparing same. The nanoplatelets are suitable for use as fire retardants and as agents for chemical or biological decontamination.
    Type: Application
    Filed: August 9, 2007
    Publication date: July 17, 2008
    Applicant: AQUA RESOURCES CORPORATION
    Inventor: Orville Lee Maddan
  • Publication number: 20080171203
    Abstract: Nanoplatelet forms of metal hydroxide and metal oxide are provided, as well as methods for preparing same. The nanoplatelets are suitable for use as fire retardants and as agents for chemical or biological decontamination.
    Type: Application
    Filed: August 9, 2007
    Publication date: July 17, 2008
    Applicant: AQUA RESOURCES CORPORATION
    Inventor: Orville Lee Maddan
  • Publication number: 20080171158
    Abstract: Nanoplatelet forms of metal hydroxide and metal oxide are provided, as well as methods for preparing same. The nanoplatelets are suitable for use as fire retardants and as agents for chemical or biological decontamination.
    Type: Application
    Filed: August 9, 2007
    Publication date: July 17, 2008
    Applicant: AQUA RESOURCES CORPORATION
    Inventor: Orville Lee Maddan
  • Publication number: 20070151864
    Abstract: A pH adjusting apparatus includes an electrolytic chip receiving a solution, an electrolytic chip loading station receiving the electrolytic chip, an input unit inputting electrolysis conditions, a control unit receiving the electrolysis conditions and controlling electrolysis performed in the electrolytic chip, and a display unit displaying the electrolysis conditions and a progress of the electrolysis. Thus, the pH of a solution can be adjusted easily and accurately, by precisely controlling a constant current, a constant voltage, and current and voltage application times, thereby enabling useful application in various biological assays such as cell lysis. Furthermore, the pH adjusting apparatus has small size and weight and can be operated for a long time after charging once due to low power consumption.
    Type: Application
    Filed: November 15, 2006
    Publication date: July 5, 2007
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Hun-joo LEE, Jin-tae KIM, Sung-young JEONG, Joon-ho KIM, Hee-kyun LIM
  • Patent number: 7144493
    Abstract: Process for the electrochemical decomposition of precursors in powder form by introducing a powder batch between two electrodes of an electrolysis cell, electrodes being designed to be liquid-permeable, and the electrolyte flowing through the powder batch perpendicularly to the electrode surfaces, and electrolysis cell suitable therefor, which is essentially characterized in that at least one electrode has a structure which consists of a supporting pierced plate (5), an electrode plate (3) provided with perforations, and a filter cloth (4) arranged between the supporting pierced plate (5) and the electrode plate (3), and in that the cathode (6) is shielded from the cell by means of a liquid-permeable separator (7).
    Type: Grant
    Filed: April 15, 2003
    Date of Patent: December 5, 2006
    Assignee: H.C. Starck GmbH
    Inventors: Armin Olbrich, Juliane Meese-Marktscheffel, Gerhard Gille, Viktor Stoller, Wolfgang Mathy
  • Patent number: 7048843
    Abstract: The invention relates to a method for producing metal hydroxides or alkaline metal carbonates by anode dissolution of the corresponding metals and precipitation of the hydroxides or alkaline carbonates in an aqueous medium. The anode dissolution of the metal components is carried out in the anode compartment of a three-compartment electrolytic cell. An aqueous auxiliary salt solution is fed to an intermediate compartment that is disposed between the anode compartment and the cathode compartment and that is separated therefrom by a porous membrane. An at least not alkaline metal salt solution is continuously taken from the anode compartment while an alkaline auxiliary salt solution is continuously taken from the cathode compartment. The at least not alkaline metal salt solution and the alkaline auxiliary salt solution are combined outside the electrolytic cell for the purpose of precipitating metal hydroxides or alkaline metal carbonates.
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: May 23, 2006
    Assignee: H.C. Starck GmbH
    Inventors: Armin Olbrich, Astrid Görge, Frank Schrumpf, Juliane Meese-Marktscheffel, Viktor Stoller, Gerhard Gille, Josef Schmoll, Michael Kruft, Dirk Naumann
  • Publication number: 20040200730
    Abstract: The invention provides processes for recovering copper metal from sulphide minerals via basic copper sulphate which is produced by pressure oxidation in chloride spiked sulphate solutions. Chloride contaminants in the basic copper sulphate obtained from the pressure oxidation reaction are removed in a reaction with an alkali, such as CaO. Thereafter, the basic copper sulphate is leached with a weak acid, and the resultant pregnant copper solution contains chloride ions at low concentrations, which allow copper electrolysis to operate efficiently.
    Type: Application
    Filed: April 14, 2003
    Publication date: October 14, 2004
    Inventor: Kyo Jibiki
  • Patent number: 6752918
    Abstract: A process is described for the production of spherical nickel hydroxide by anodic dissolution of a nickel electrode and precipitation of nickel hydroxide in a completely intermixed electrolysis cell, wherein an electrolysis brine is used which has a content of 20 to 50 g/l of chloride ions and 1 to 7 g/l of ammonia with a pH value of 9.5 to 11.5 and a temperature of 45 to 60° C.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: June 22, 2004
    Assignee: H. C. Starck GmbH
    Inventors: Armin Olbrich, Viktor Stoller, Juliane Meese-Marktscheffel, Frank Schrumpf, Josef Schmoll, Gerhard Gille
  • Patent number: 6733639
    Abstract: The invention relates to a gas diffusion electrode (1) comprising a hydrophobic gas diffusion layer (3b), a reaction layer (3a), and a hydrophilic layer (5) arranged in the mentioned order wherein the reaction layer (3a) is arranged to a barrier layer (4), which barrier layer (4), on its opposite side, is arranged to the hydrophilic layer (5). The invention also relates to a method for manufacturing such a gas diffusion electrode (1), and to an electrolytic cell, and use thereof.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: May 11, 2004
    Assignee: Akzo Nobel N.V.
    Inventors: Bernd Busse, Lars-Erik Bergman
  • Patent number: 6726828
    Abstract: Using a solution mining procedure, an ore (10) is treated with a solution of acetic acid and hydrogen peroxide so as to form a leachate containing lead ions. Lead ions (and other metal ions such as zinc and manganese) are stripped (22, 24, 26) by solvent extraction from the leachate to form separate aqueous solutions. The aqueous solution containing lead ions is treated electrochemically in the anodic compartment of a separated electrochemical cell (42) to form a precipitate of lead oxide. Manganese dioxide can be produced similarly (72). A precipitate of zinc hydroxide can be formed in the cathode compartment of a separated electrochemical cell (56). In the cells (42, 72) extracting lead ions and manganese ions, the cathode compartment is used to generate hydrogen peroxide (for use in making the leachant), either directly or indirectly.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: April 27, 2004
    Assignee: Accentus plc
    Inventors: Andrew Derek Turner, Christopher Peter Jones
  • Patent number: 6685820
    Abstract: The present invention relates to a method for treating spent tin or tin/lead stripping solution used in the electronic industry, particularly in the manufacture of printed circuit boards or a lead frames. Said method comprises (i) electrolytically reducing copper ions in the solution to copper at a low temperature; (ii) electrolytically oxidizing Sn2+ and Pb2+ in the solution at a high temperature to form solid tin and lead oxides and hydroxides; (iii) separating solid tin and lead oxides and hydroxides from the solution; (iv) dissolving tin and lead oxides and hydroxides obtained in step (iii) in a strong alkali or acidic solution; and (v) electrolytically reducing the alkali or acidic solution obtained in step (iv) at a high temperature to recover metallic tin and lead. Also, the filtrate obtained in step (iii) above is useful for preparing fresh tin or tin/lead stripping solution.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: February 3, 2004
    Assignees: Amia Co., Ltd., Persee Chemical Co., Ltd.
    Inventors: Kuo-Chin Chen, Ching-Hwa Chang, Yu-Feng Lin, Tai-Sheng Yuan, Hung-Ming Wang, Jenn-Fang Wu, Huei-Yin Cheng
  • Patent number: 6528182
    Abstract: The invention concerns a steel plate coated with a metal layer based on zinc and a zinc hydroxysulphate layer, whereof the surface density of sulphur is more than 0.5 mg/m2. The invention also concerns a method for obtaining said plate by treating a zinc coated sheet metal: either in a highly alkaline sulphate solution under polarization; or in a sulphate solution containing Zn2+ ions without polarization. The hydroxysulphate deposit brings about a pre-lubricating effect applicable to operations for forming sheet metal.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: March 4, 2003
    Assignee: Sollac
    Inventors: Alain Bello, Sylviane Wajda, Jacques Petitjean, Armand Rossi