Abstract: Stannous electrolytic tinplating baths utilized in flat-rolled steel tinplating operations contain non-filterable lead in solution at undesirable levels because of the lead content of commercially available tin anode materials. As taught herein, lead in the electrolyte is controllably incapacitated for deposition with the tin by chemical treatment of the bath which establishes, in solid phase, an insoluble bivalent metal compound having an affinity for lead which is adsorbed. In a preferred halogen-system embodiment, calcium fluoride presents an extended surface area for adhesion of lead and not only incapacitates lead in the bath for deposition purposes but also enables separation of such adsorbed lead from the plating bath as part of sludge removal.
Abstract: A process and apparatus for regenerating a plating bath comprising trivalent chromium cations (a trivalent chromium bath). The bath can be continuously, or more preferably, periodically with an ion exchange resin, preferably a cation exchange resin. A useful apparatus comprises a plating tank containing a trivalent chromium plating bath in communication with an ion exchange bed continuing ion exchange resin.
Abstract: The total organic content (TOC) of an aqueous composition is reduced to 200 ppm or less by subjecting the composition to electrolysis whereby the pH of the composition at the start of the electrolysis is about 1.8 to about 7 to thereby electrolytically decompose organic materials contained in the aqueous composition.
Type:
Grant
Filed:
July 22, 1991
Date of Patent:
July 27, 1993
Assignee:
International Business Machines Corporation
Inventors:
Francis J. Downes, Jr., Oscar A. Moreno, Cindy M. Reidsema, Joseph E. Varsik
Abstract: The present invention relates to a method of completely recovering nickel and zinc metal from multiple plating process waste streams by first separating the waste streams into a clean, relatively constant flow and/or concentration fraction and a dirty, variable flow and/or concentration fraction. Metal is recovered from the clean fraction by ion-exchange so as to concentrate the extracted metals for direct return to the plating bath. The effluent from the ion-exchange step is then blended with the dirty, variable flow and concentration fraction. This blended flow is first neutralized and then precipitated in a two-stage process using a sodium hydroxide solution. The resultant slurry containing the metal precipitate is filtered to yield a filter cake containing recovered nickel and zinc. This filter cake can then be further processed to recover the metal for reintroduction into the plating bath or for other uses.
Type:
Grant
Filed:
July 8, 1991
Date of Patent:
March 9, 1993
Assignee:
Bethlehem Steel Corporation
Inventors:
Charles R. Hughes, Stewart T. Herman, Richard N. Steinbicker