Soaking Patents (Class 208/131)
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Patent number: 5443717Abstract: A process for producing a delayed coker quench stream for use in the quench cycle of a delayed coking process wherein a waste stream containing water, organic compounds and solids is treated to produce a coker feed stream containing from about 5 to about 35% by weight solids, water and less than about 6% by weight mobile organics, the solids having a particle size distribution such that greater than about 70% of the total solids volume comprises solids having a particle size of less than about 15 microns.Type: GrantFiled: January 19, 1993Date of Patent: August 22, 1995Assignee: Scaltech, Inc.Inventors: Robert M. Scalliet, Craig A. Koopersmith, Walter A. Carter
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Patent number: 5431812Abstract: A feedstock composition comprising residuum fractions and deasphalter bottoms is formulated by use of a carbon residue characterization factor. It has been found in the feedstock composition that the character of carbon residue is determinative of the coke quality. The process is used to make coke having a sulfur concentration of 0.5 to 0.9 of the feedstock composition sulfur.Type: GrantFiled: March 7, 1994Date of Patent: July 11, 1995Assignee: Texaco Inc.Inventor: Ooriapadical C. Abraham
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Patent number: 5407560Abstract: A novel process is disclosed by which petroleum cokes and cracked oil can be produced by thermal cracking of a heavy petroleum oil to which a rare earth metal compound is added. The process produces petroleum cokes with an improved combustibility and promotes the yield of cracked oil at the same time.Type: GrantFiled: March 16, 1992Date of Patent: April 18, 1995Assignee: Japan Energy CorporationInventors: Shintaro Miyawaki, Kiyomi Ishii, Mamoru Yamane
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Patent number: 5389234Abstract: Waste refinery sludge having a high water content along with hydrocarbon liquids and solids is disposed of in a delayed coking process. The sludge is pretreated and heated to a coking temperature and then introduced into the top of a delayed coking drum.Type: GrantFiled: July 14, 1993Date of Patent: February 14, 1995Assignee: ABB Lummus Crest Inc.Inventors: Alok K. Bhargava, Wai Seung W. Louie, Arthur N. Stefani
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Patent number: 5350503Abstract: A consistent high quality coke is produced by feeding a balancing stream comprising hydrocarbons to a delayed coking drum in addition to the heavy hydrocarbonaceous coker feedstock. The process of this invention reduces the contaminant content of coke by coking contaminant-containing residua and a reduced contaminant hydrocarbon balancing stream. Preferably, the balancing stream is a contaminant diluent, such as unreduced crude. The balancing stream may be a crude which is different from the base crude processed in the refinery crude tower and is preferably selected as a sulfur and/or metals diluent having a lower concentration of sulfur-containing or metal-containing compounds than the heavy coker feedstock.Type: GrantFiled: July 29, 1992Date of Patent: September 27, 1994Assignee: Atlantic Richfield CompanyInventors: Douglas A. Freymeyer, Richard L. Holloway, Ronald J. Kiracofe, Vijay R. Sampath
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Patent number: 5340464Abstract: A process for disposing of filter media is provided, which process comprises (a) mixing a filter media with a hydrocarbonaceous mixing stream to form a media-hydrocarbon mixture and (b) feeding said media-hydrocarbon mixture to a coking vessel. Preferred coking vessels include delayed cokers, fluidized cokers, and coke calciners. An apparatus for disposing of filter media is provided, which apparatus comprises (a) a coking vessel; (b) a mixer to mix the filter media with a hydrocarbonaeous mixing fluid to form a media- hydrocarbonaeous fluid mixture; and, (c) a feed means to feed the media-hydrocarbonaeous fluid mixture to the coking vessel. Preferably, the apparatus comprises a size reduction means to reduce the size of the filter media to form a media staple comprising fiber clusters having a desired shape and size.Type: GrantFiled: September 8, 1992Date of Patent: August 23, 1994Assignee: Atlantic Richfield CompanyInventor: Anthony Mickas
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Patent number: 5316655Abstract: A process for making a light hydrocarbonaceous liquid in a delayed coker comprising:(A) providing a hydrocarbonaceous feed to the coke drum and heating the feed to a temperature of about 800.degree. F. to about 1200.degree. F. to provide an intermediate product; and(B) introducing said intermediate product into the coke drum, operating the coke drum to convert the intermediate product to a final comprising light liquid and coke, and separating the light liquid from the coke;step (A) being conducted in combination with either step (A) (i) or step (A) (ii);Step (A) (i) comprising maintaining the feed during step (A) in an enclosed space and subjecting the feed to a pressure that is at least about 500 psig and is sufficient to maintain the specific gravity of the contents of the enclosed space at least about 0.Type: GrantFiled: November 13, 1991Date of Patent: May 31, 1994Assignee: The Standard Oil CompanyInventors: Stephen C. Paspek, Christopher P. Eppig, Jeffrey B. Hauser, Carl Polisena
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Patent number: 5296132Abstract: Methods and compositions for controlling foam in high temperature hydrocarbons during processing vegetable oils, exemplified by jojoba oil, are added to the hydrocarbon to control foam.Type: GrantFiled: October 6, 1992Date of Patent: March 22, 1994Assignee: Betz Laboratories, Inc.Inventor: Paul R. Hart
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Patent number: 5286371Abstract: A process is provided for producing premium and super premium grade needle coke comprising the steps of passing a heavy resid feedstock to a resid hydrotreating reaction zone at resid hydrotreating conditions and producing light resid hydrotreated products and a heavy resid hydrotreated residual product, directing the heavy resid hydrotreated residual product and FCC decanted oil to a solvent extraction process reaction zone at solvent extraction process conditions and producing products comprising a solvent extracted oil and resin stream and a stream comprising asphaltenes, and conveying at least a portion of the solvent extracted oil and resin stream to a delayed coking process at delayed coking conditions and producing liquid products and premium grade coke.Type: GrantFiled: July 14, 1992Date of Patent: February 15, 1994Assignee: Amoco CorporationInventors: Shri K. Goval, Jeffrey J. Kolstad, F. W. Hauschildt, Dean G. Venardos, Cheryl L. M. Joval
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Patent number: 5258115Abstract: A refinery derived spent caustic is recycled by introducing the spent caustic to a delayed coking drum while conducting delayed coking of a hydrocarbon feedstock. The alkali metal containing material accelerates coking, induces production of shot coke, alleviates the problem of a hot drum and reduces drum cooling time.Type: GrantFiled: September 16, 1992Date of Patent: November 2, 1993Assignee: Mobil Oil CorporationInventors: Roland H. Heck, Tom Reischman, Gerald J. Teitman, Salvatore T. M. Viscontini
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Patent number: 5248410Abstract: A feedstock comprising 10 to 15 wt % used motor oil is subjected to delayed coking to yield coke and distillate fractions.Type: GrantFiled: November 29, 1991Date of Patent: September 28, 1993Assignee: Texaco Inc.Inventors: Glenn A. Clausen, Christopher A. Paul
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Patent number: 5223152Abstract: A process and apparatus for dewatering a recovered oil stream prior to the recovered oil stream being fed to a fractionator for reprocessing into product s rea s uses a blowdown drum controlled like a drstillatron tower so that the bottoms temperature of the blowdown drum is maintained at a temperature above the dewpoint temperature of the water in the blowdown drum by a reboiler. For refineries that contain a delayed coker unit and a coker fractionator which is used for fractionating light products from residual oil serving as coker feedstock, which coker fractionator is also used to fractionate recovered oil containing water and hydrocarbons, a coker blowdown drum is controlled to maintain an appropriate bottoms temperature to achieve separation in the blowdown drum of water from the hydrocarbons in the recovered oil stream, and the blowdown drum is thus used for dewatering the recovered oil before it is fed to the coker fractionator.Type: GrantFiled: October 8, 1991Date of Patent: June 29, 1993Assignee: Atlantic Richfield CompanyInventors: Douglas A. Freymeyer, J. Paul Love, Richard L. Holloway, Daniel L. Torres, Alfred G. Brosman
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Patent number: 5200061Abstract: During delayed coking, channels are formed in the solid coke bed to facilitate cooling of the hot coke drum. A distributor device injects a fluid, preferably steam, directly into the coke drum during delayed coking. The fluid travels through the coke bed and forms a channel which eliminates an impervious zone in the mass of solid coke. The channel allows more efficient cooling of the drum and eliminates the problem of a "hot drum" which can occur during delayed coking.Type: GrantFiled: September 20, 1991Date of Patent: April 6, 1993Assignee: Mobil Oil CorporationInventor: Salvatore T. M. Viscontini
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Patent number: 5174891Abstract: A nonair-blown low sulfur petroleum residual oil is combined with super finely divided particles of calcined premium coke, and the combination is subjected to delayed coking to produce isotropic coke containing reduced sulfur and having a low CTE ratio.Type: GrantFiled: October 29, 1991Date of Patent: December 29, 1992Assignee: Conoco Inc.Inventor: Lloyd G. Becraft
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Patent number: 5167796Abstract: A premium coke is produced from a decant oil resulting from the catalytic cracking of petroleum oil by selectively hydrodesulfurizing the decant oil and then subjecting the hydrodesulfurized decant oil to delayed coking.Type: GrantFiled: May 22, 1989Date of Patent: December 1, 1992Assignee: Ucar Carbon Technology CorporationInventors: Rostislav Didchenko, Irwin C. Lewis
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Patent number: 5160602Abstract: A non air-blown low sulfur heavy aromatic mineral oil which does not produce acceptable isotropic coke when subjected to delayed coking is combined with an inorganic additive which promotes pyrolysis and which vaporizes during calcining and the combination is subjected to delayed coking to produce isotropic coke having a low CTE ratio. The isotropic coke is further processed (including calcination) to produce graphite logs used in nuclear reactors.Type: GrantFiled: September 27, 1991Date of Patent: November 3, 1992Assignee: Conoco Inc.Inventors: Lloyd G. Becraft, Edward J. Nanni
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Patent number: 5158668Abstract: Recarburizer coke containing not more than 0.1 weight percent sulfur and not more than 0.1 weight percent nitrogen is prepared by the catalytic hydrogenation, thermal cracking, and delayed coking of a mixture of pyrolysis tar and petroleum distillate.Type: GrantFiled: January 6, 1992Date of Patent: October 27, 1992Assignee: Conoco Inc.Inventors: Bharat S. Chahar, John K. Shipley
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Patent number: 5143597Abstract: A used lubricant oil recycling process is disclosed in which a used lubricating oil is injected to a delayed coker downstream of the coker furnace whereby the used oil is thermally cracked into hydrocarbon fuel products which are low in metal contaminants, sulfur and nitrogen. The used lubricant can be preheated in an independent heater to avoid a quenching effect of the process stream when added in an amount greater than about 3% by volume based on the entire volume of the feed.Type: GrantFiled: January 10, 1991Date of Patent: September 1, 1992Assignee: Mobil Oil CorporationInventors: Steven W. Sparks, Gerald J. Teitman, Salvatore T. M. Viscontini
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Patent number: 5128026Abstract: More uniform premium coke is obtained in a delayed coking process by oxygenating the latter portion of the premium coking feed introduced to the coking drum.Type: GrantFiled: May 13, 1991Date of Patent: July 7, 1992Assignee: Conoco Inc.Inventors: Bruce A. Newman, Lloyd G. Becraft
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Patent number: 5114564Abstract: An improved delayed coking process is described in which sludge and oxygen contact hot coke during the quench cycle at conditions which cause at least a portion of the organics contained in the sludge to oxidize. Preferably, a portion of the sludge is combusted and the heat generated is used to help remove, during the quench cycle, entrapped liquids contained in the coke bed and to enhance thermal conversion of hazardous materials contained in the sludge to less harmful materials.Type: GrantFiled: June 18, 1991Date of Patent: May 19, 1992Assignee: Amoco CorporationInventor: Shri K. Goyal
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Patent number: 5110449Abstract: A process is disclosed for sludge addition to a coking zone in which the sludge is contacted with oxygen. The sludge is then contacted with feed, liquid derived from the feed, or vapor derived from the feed. Oxygen also contacts the feed, liquid derived from the feed, or vapor derived from the feed to help maintain reaction temperature in the coking zone.Type: GrantFiled: June 18, 1991Date of Patent: May 5, 1992Assignee: Amoco CorporationInventors: Dean G. Venardos, Shri K. Goyal
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Patent number: 5110448Abstract: Coker water from a delayed coking process is cooled and a water soluble, organic cationic surface active compound is introduced to produce a substantially water free oil stream and a substantially oil free coker water stream which can be returned to the coking process.Type: GrantFiled: March 12, 1991Date of Patent: May 5, 1992Inventors: Stephen P. Adams, William R. Morrison
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Patent number: 5104518Abstract: Carbonates, oxides, carbides or fluorides of alkaline earth metals are added to coal tar pitches before coking. After the coking, which is preferably carried out by the delayed coking process, this produces coal tar pitch cokes or coal tar pitch needle cokes which have no irreversible expansion or a strongly reduced irreversible expansion upon heating in the temperature range of 1400.degree. to 2000.degree. C.Type: GrantFiled: March 6, 1990Date of Patent: April 14, 1992Assignee: Sigri GmbHInventor: Hubert Jager
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Patent number: 5092982Abstract: Low sulfur isotropic coke is produced by the delayed coking of a mixture of a pyrolysis tar and a residual oil which has been solvent extracted to remove paraffinic components and then air-blown.Type: GrantFiled: December 14, 1990Date of Patent: March 3, 1992Assignee: Conoco, Inc.Inventor: Lloyd G. Becraft
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Patent number: 5078857Abstract: A process and apparatus are disclosed for heating a coking feedstock to a temperature sufficient to effect coking of the coking feedstock in a coking drum, said process and said apparatus being characterized by the fact that the heating is conducted in a double fired heater in which the coking feedstock is heated by flames located on opposite sides of the tubing through which the feedstock flows. The process and apparatus allow for increased coke production and extended operating periods.Type: GrantFiled: April 12, 1990Date of Patent: January 7, 1992Inventor: M. Shannon Melton
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Patent number: 5071515Abstract: The density and crush resistance of calcined coke are improved by depositing coker feedstock on green (uncalcined) coke, thereafter subjecting the coke to a heat soak and then calcining the coke.Type: GrantFiled: September 28, 1989Date of Patent: December 10, 1991Assignee: Conoco Inc.Inventors: Bruce A. Newman, Lynn J. Whitebay
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Patent number: 5068024Abstract: The present invention relates to a process and apparatus for injecting sludge into the vapor phase of a coking process to vaporize the sludge while minimizing the carryover of solids and coke to downstream equipment. The process and apparatus are applicable to use in both fluid and delayed coking operations and are useful on various sludges which can be found in refineries or petrochemical plants.Type: GrantFiled: August 3, 1990Date of Patent: November 26, 1991Assignee: Amoco CorporationInventors: Jon C. Moretta, Robert D. Gombas, Jr.
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Patent number: 5066385Abstract: Petroleum residual oil which has been contacted with an oxygen-containing gas to increase its softening point is combined with a pyrolysis tar and the combination is subjected to delayed coking to produce isotropic coke containing reduced sulfur and having a low CTE ratio.Type: GrantFiled: March 5, 1990Date of Patent: November 19, 1991Assignee: Conoco Inc.Inventor: Lloyd G. Becraft
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Patent number: 5059301Abstract: Recarburizer coke containing not more than 0.1 weight percent sulfur and not more than 0.1 weight percent nitrogen is prepared by severe catalytic hydrotreating, followed by thermal cracking, and delayed coking of vacuum gas oil obtained from the vacuum distillation of FCC decant oil.Type: GrantFiled: March 20, 1991Date of Patent: October 22, 1991Assignee: ConocoInventors: Keith M. Roussel, John K. Shigley
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Patent number: 5045177Abstract: An improvement has been found in the gas recovery section of a delayed coking process. In the improvement the compressor discharge is amine scrubbed to remove hydrogen sulfide. The compressor discharge is the entire vapor feed to the gas recovery section and contains about 90% of the hydrogen sulfide. This has been found to cause a significant drop in both the depropanizer and debutanizer pressure and allow a saving in the investment cost of the pressure vessel. Synergistically a reduced amount of hydrogen sulfide is present in the entire gas recovery section. The remaining 10% of the hydrogen sulfide is removed by amine scrubbing the fuel gas and propane/propylene fractions.Type: GrantFiled: August 15, 1990Date of Patent: September 3, 1991Assignee: Texaco Inc.Inventors: John C. Cooper, James H. Colvert
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Patent number: 5041207Abstract: A process is disclosed wherein at least two separate gaseous oxygen streams are passed into a coker transfer line to effect oxidation of a portion of the feed passing through the transfer line. Another aspect of the process is disclosed wherein gaseous oxygen is passed into a coking process and sludge is also passed into the coking process.Type: GrantFiled: December 15, 1988Date of Patent: August 20, 1991Assignee: Amoco CorporationInventors: Joseph A. Harrington, Ciro D. Sorrentino, Dean G. Venardos, Shri K. Goyal, Irwin Ginsburgh
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Patent number: 5034116Abstract: The coarse-grain CTE of premium coke is reduced by increasing the nominal velocity of the volatile coking by-products in the coking drum to a higher level than the preexisting nominal velocity.Type: GrantFiled: August 15, 1990Date of Patent: July 23, 1991Assignee: Conoco Inc.Inventor: Bruce A. Newman
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Patent number: 5028311Abstract: Premium coke having a low coefficient of thermal expansion and containing reduced fluff coke is obtained by subjecting an aromatic mineral oil to reduced temperature delayed coking, thereafter converting uncoked oil in the coke drum to coke under delayed coking conditions by continuing coking in the presence of a aromatic mineral oil capable forming coke admixed with a non-coking material circulated through the coke drum as a heating fluid. After termination of the heating fluid, the coke in the coke drum is subjected to a heat soak in the presence of a non-coking material at an elevated temperature preferably above the delayed coking conditions.Type: GrantFiled: April 12, 1990Date of Patent: July 2, 1991Assignee: Conoco Inc.Inventors: John K. Shigley, Keith M. Roussel, Steve D. Harris
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Patent number: 5024730Abstract: A system controls a delayed coker in which a heavy liquid hydrocarbon feedstock is thermally decomposed to a solid coke product in a cyclical process. When the coking portion of the cycle is completed, the coke in the drum is cooled by quench water, and the quench water is then passed from the coke drum through a manifold to a drain conduit. Hot vapor is passed through the coke drum, via the same manifold to warm the coke drum. A temperature controller, valve actuator and ball valve allow passage of vapor to the coker fractionator at a manifold temperature at which all water is in the vapor state. Manifold temperatures at which liquid water may exist causes the ball valve to close, preventing liquid water from flowing into the coker fractionator. Upset of the coker fractionator is prevented.Type: GrantFiled: June 7, 1990Date of Patent: June 18, 1991Assignee: Texaco Inc.Inventor: James H. Colvert
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Patent number: 5024752Abstract: Heavy resid oils are upgraded by a thermal treatment under liquid coking conditions to evolve two at least partially immiscible liquid phases. The lighter gas oil phase is then separated from the heavier liquid coke phase by decantation.Type: GrantFiled: September 18, 1989Date of Patent: June 18, 1991Assignee: Mobil Oil CorporationInventor: Tsoung Y. Yan
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Patent number: 5009767Abstract: Petroleum refinery waste stream sludges are recycled by segregating the sludges according to their oil content. Sludges of high oil content are developed and then injected into a delayed coking unit during the coking phase so that they are converted to coke and liquid coking products. High water content sludges are used to quench the coke during the quench phase of the coking cycle, with minimal increases in coke volatile matter. The process increases the capacity of the delayed coking unit to process and recycle refinery waste sludges and produce a coke of lower volatile content.Type: GrantFiled: September 21, 1989Date of Patent: April 23, 1991Assignee: Mobil Oil CorporationInventors: Mark P. Bartilucci, Grant G. Karsner, William J. Tracy, III
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Patent number: 5007987Abstract: The friability of green needle coke is reduced by heating the green needle coke to a temperature between about 875.degree. F. and about 1,200.degree. F. for a time sufficient to reduce the friability of the green needle coke.Type: GrantFiled: November 22, 1988Date of Patent: April 16, 1991Assignee: Union Oil Company of CaliforniaInventors: Michael J. Block, Arnold E. Kelley, Milan Skripek
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Patent number: 4983272Abstract: A process for producing coke from a combined feed. The combined feed is initially provided as a first portion which comprises easily cokable components and a second portion which is essentially free of easily cokable components. The first portion is heated to a temperature lower than that normally employed by a coking heater in a delayed coking process. The second portion is heated to a temperature at which a combination of the first and second portion provides combined feed at coking temperatures. The combined feed is then subjected to coking conditions.The first portion, in one embodiment, may be comprised of a fresh feed and the second portion may be comprised of a coker recycle. In another alternative, a fresh feed and a coker recycle are combined and fractionated to produce the first portion and the second portion. The first portion may include components which boil above a temperature of about 900.degree. F., and the second portion may be essentially free of easily cokable components.Type: GrantFiled: November 21, 1988Date of Patent: January 8, 1991Assignee: Lummus Crest, Inc.Inventor: Napoleon Stavropoulos
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Patent number: 4969988Abstract: A process for the conversion of a heavy hydrocarbon oil in the presence of hydrogen and a catalyst or additive is described. It is shown that conversion can be increased by injecting an anti-foaming agent or a solution of anti-foaming agent in light oil into the reactor. Significantly better results are obtained when the anti-foam or the solution of anti-foam is injected directly into the top section of the reactor.Type: GrantFiled: April 17, 1989Date of Patent: November 13, 1990Assignee: Petro-Canada Inc.Inventors: Anil K. Jain, Barry B. Pruden, Dennis Lambiris, Serge Rivard, Dirkson D. S. Liu
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Patent number: 4968407Abstract: Wet refinery sludges are disposed of by feeding them into a delayed coking process. The sludge is fed to the blowdown drum of the delayed coking process and mixed with oil condensed from the coke drum overhead, and the resulting sludge-oil mixture is fed to the coke drum where it is converted into coke. In order to remove the water from the sludge, a portion of the sludge-oil mixture is heated and recirculated to the blowdown drum where it provides the heat for drying and heating the sludge. The recirculating sludge-oil mixture is heated by a low level heat source, such as one of the fluid streams taken off from the fractionator.Type: GrantFiled: April 25, 1988Date of Patent: November 6, 1990Assignee: Foster Wheeler USA CorporationInventors: Michael J. McGrath, Rino L. Godino
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Patent number: 4961840Abstract: An improved delayed coking process using an improved method for adding antifoam materials to the delayed coking process. The process is directed to injecting a polysiloxane antifoam material in mixture with an inert gas in the absence or substantial absence of steam and wherein this mixture is heated and thereafter injected into a delayed coking drum. The process allows improved use of antifoam materials and prevents downstream contamination of process units with silica materials which can be broken down when the polysiloxane antifoam material is contacted with large quantities of steam within the coking drum.Type: GrantFiled: April 13, 1989Date of Patent: October 9, 1990Assignee: Amoco CorporationInventor: Shri K. Goyal
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Patent number: 4943367Abstract: High purity coke particularly suited to the production of anodes for aluminium smelting is produced by an integrated process that includes flash pryolysis and delayed coking. In the integrated process, flash pyrolysis of carbonaceous materials such as coal, oil shale or tar sand is operated under conditions that maximize the production of tar suitable for coking, and the delayed coking is operated under conditions that maximize the coke yield, and intermediate products may be recycled to enhance overall efficiency.Type: GrantFiled: June 21, 1989Date of Patent: July 24, 1990Assignees: Comalco Aluminum Limited, Alcoa of Australia Limited, Alcan Australia LimitedInventors: John C. Nixon, John A. Eady, Christopher G. Goodes
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Patent number: 4929339Abstract: A method for conditioning delayed coke includes allowing coke to form in a first chamber or coke drum, while simultaneously conditioning coke in a second coke drum by flowing through it a hydrocarbon conditioning fluid recirculated from another portion of the coking apparatus, said conditioning fluid having a temperature of more than 750.degree. F. and less than 1000.degree. F., and decoking a third coke drum. The coking, conditioning and decoding operations are sequentially switched among the coke drums.Type: GrantFiled: October 7, 1985Date of Patent: May 29, 1990Assignee: Foster Wheeler U.S.A. CorporationInventors: John D. Elliott, Jr., Robert DeBiase
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Patent number: 4927524Abstract: A process for producing metallurgical coke from a hydrocarbon residuum characterized by high vanadium and high sulphur contents comprises coking a hydrocarbon residuum in a coking drum in the presence of an additive selected from the group consisting of carbonates and hydroxides of sodium, potassium and calcium and mixtures thereof and an oxidizing agent selected from the group consisting of water, carbon dioxide and mixtures thereof.Type: GrantFiled: May 10, 1989Date of Patent: May 22, 1990Assignee: Intevep, S.A.Inventors: Domingo Rodriguez, Cebers Gomez
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Patent number: 4919793Abstract: This invention is an improvement of the prior art in that the properties, as well as the molecular structure of the coker heater charge material are altered by hydrogeneration under conidtions of pressure and temperature typically operated for a conventional delayed coking process. Hydrogeneation of the heater charge material is accomplished in a soaking pipe provided with static mixers for up to 90 minutes fluid residence time thereby improving the quality and yields of products from the process.Type: GrantFiled: August 15, 1988Date of Patent: April 24, 1990Inventor: Renato M. Mallari
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Patent number: 4894144Abstract: A virgin heavy oil is hydrotreated, separated into a light fraction and a heavy fraction which are separately delay coked to obtain (a) a coke product of low sulfur content suitable for use as recarburizer coke or for use in the manufacture of graphite electrodes used in the manufacture of steel and (b) a coke product of higher sulfur content suitable for use in electrodes employed in the manufacture of aluminum.Type: GrantFiled: November 23, 1988Date of Patent: January 16, 1990Assignee: Conoco Inc.Inventors: Bruce A. Newman, Bharat S. Chahar
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Patent number: 4874505Abstract: Petroleum refinery waste stream sludges are recycled by segregating the sludges according to their oil content. Sludges of high oil content are injected into a delayed coking unit during the coking phase so that they are converted to coke and liquid coking products. High water content sludges are used to quench the coke during the quench phase of the coking cycle, with minimal increases in coke volatile matter. The process increases the capacity of the delayed coking unit to process and recycle refinery waste sludges and produce a coke of lower volatile content.Type: GrantFiled: February 2, 1988Date of Patent: October 17, 1989Assignee: Mobil Oil CorporationInventors: Mark P. Bartilucci, Grant G. Karsner, William J. Tracy, III
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Patent number: 4853106Abstract: Delayed coking process in which improved liquid yield is achieved by varying the rate at which the heavy feedstock is fed to the coke drum. Tandem operation of two active coking drums is disclosed which permits feedrate variation without change of load on furnace.Type: GrantFiled: August 19, 1987Date of Patent: August 1, 1989Assignee: Mobil Oil CorporationInventors: J. Jay Grove, Grant G. Karsner
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Patent number: 4839021Abstract: A method of producing pyrolytic oils suitable for petroleum reprocessing is disclosed. According to the invention, petroleum derived organic sludges or oil residues in a solid/liquid phase are subjected to vacuum pyrolysis under temperature and sub-atmospheric pressure conditions such as to prevent gas and vapor phase secondary cracking reactions and to thereby increase the yield of pyrolytic oils to the detriment of hydrocarbon gases. About 97% of the organic matter content of the sludges and about 75% of the organic matter content of the oil residues can be converted into pyrolytic oils suitable for petroleum reprocessing.Type: GrantFiled: December 11, 1987Date of Patent: June 13, 1989Assignee: Recherche Carbovac Inc.Inventor: Christian Roy
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Patent number: RE33728Abstract: A process for converting residual oil comprising vacuum bottoms in the presence of a cracking catalyst of high surface area and comprising an ultrastable zeolite is described. More particularly, a conversion process particularly contributing to producing cycle oil and gasoline boiling range products with reduced carbon deposition in combination with a relatively high regeneration temperature operation of at least 1350.degree. F. and above, and a short contact time riser hydrocarbon conversion operation contributing to reducing slurry oil product in favor of lower boiling products is described. A fluid cracking catalyst comprising a special ultrastable crystalline zeolite of high silica to alumina ratio provides hydrothermal stability of acceptable tolerance in the environment employed.Type: GrantFiled: August 4, 1987Date of Patent: October 29, 1991Assignee: Total Engineering and Research CompanyInventors: Robert R. Dean, Warren S. Letzsch, Jean L. Mauleon