Lubricating Oils Patents (Class 208/18)
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Patent number: 12203043Abstract: The present invention provides a lubricating oil composition used in the reduction gearbox or transmission of an electric vehicle or a hybrid vehicle, wherein the lubricating oil contains a base oil, and the aromatic ring content of the base oil is from 3,500 to 15,000 ppm in terms of the mass of the base oil.Type: GrantFiled: March 16, 2022Date of Patent: January 21, 2025Assignee: Shell USA, Inc.Inventor: Kengo Suzuki
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Patent number: 11845900Abstract: The present invention relates to a process for the preparation of a C20 to C60 wax from the thermal decomposition of plastic polymer. The present invention provides a vacuum pyrolysis process for preparing a C20 to C60 wax from the thermal decomposition of plastic polyolefin polymer, the method comprising the steps of: i) introducing plastic polyolefin polymer into a thermal reaction zone of a vacuum pyrolysis reactor; ii) heating the plastic polyolefin polymer at sub-atmospheric pressure, wherein the temperature in the thermal reaction zone of the reactor is from 500° C. to 750° C., to induce thermal decomposition of the plastic polyolefin polymer and to form a thermal decomposition product effluent which comprises a major portion by weight of a C20 to C60 wax fraction; and iii) condensing a vapour component of the thermal decomposition product effluent from the vacuum pyrolysis reactor in a multistage condensation comprising a plurality of condensation stages connected in series.Type: GrantFiled: March 30, 2017Date of Patent: December 19, 2023Assignee: H&R Internationale Beteiligung GmbHInventors: Martin P. Atkins, Fergal Coleman
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Patent number: 11807813Abstract: An installation for the production of oil, gas and char for carbon black, from elastomers, characterized in that, it has a screw dispenser (3) with a shaft (1), which from the loading side is closed hydraulically with a lock (2) by a nitrogen, a reactor (4), which is divided into zones A, B, C, corresponding to the subsequent stages of the pyrolysis process: zone A—the beginning of depolymerization (350° C.), zone B—carbonization (350-400° C.) and zone C—aromatic compounds cracking (400-650° C.), while a bubbler (5) hydraulically closed with a siphon (6) and a separator (7) with a hydraulic closure (8) and an oil separator (9) equipped with a transport screw (10) and an afterburner chamber (20) are installed outside the reactor (4), wherein the oil separator (9) is closed at the outlet by an accumulation shaft (12) and from the side of receiving a solid product—with a shaft (13), which is connected by an U-shaped screw conveyor (14) with economizers (11) and (15).Type: GrantFiled: September 29, 2020Date of Patent: November 7, 2023Assignee: REOIL SP. Z O.O.Inventors: Michal Mikuskiewicz, Pawel Mikuskiewicz, Sebastian Zygmunt, Bronislaw Rolnik
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Patent number: 11441085Abstract: Provided in one embodiment is an improved and more flexible process for preparing a finished base oil or a white oil product comprising passing a dewaxed base oil product to a distillation column and separating the dewaxed base oil product into fuel and base oil product streams. The base oil product streams are tested to determine if they meet desired specifications. Base oil product streams that meet the desired minimum base oil specifications are passed to a hydrofinishing reactor to prepare a white oil product, or passed to direct sale.Type: GrantFiled: December 30, 2020Date of Patent: September 13, 2022Assignee: Chevron U.S.A. Inc.Inventors: Kenny Peinado, Jay Parekh, Jifei Jia, Yihua Zhang, Guan-Dao Lei, Guang Zhang
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Patent number: 11225616Abstract: Disclosed is a method of producing a lubricating base oil, including providing a feedstock including a diesel fraction, subjecting the feedstock to catalytic dewaxing, and recovering a lubricating base oil from a product of the catalytic dewaxing. A lubricating base oil produced thereby and a lubricant product including the lubricating base oil are also provided.Type: GrantFiled: July 6, 2020Date of Patent: January 18, 2022Assignees: SK INNOVATION CO., LTD, SK LUBRICANTS CO., LTD.Inventors: Seung Eon Lee, Hak Mook Kim, Jin Hee Ok
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Patent number: 11155767Abstract: Provided is a vacuum pump oil which contains a mineral oil (A) having a temperature gradient ?|?*| of complex viscosity between two points of t(° C.) and t?10(° C.) (where ?15?t??10), as measured using a rotary rheometer at an angular velocity of 6.3 rad/s, of 10 Pa·s/° C. or less, and one or more compounds selected from a phenol-based compound (B) and an amine-based compound (C), and which has a viscosity index of less than 160. The vacuum pump oil has a good ultimate vacuum degree and is excellent in water separability, oxidation stability and shear stability, and is therefore applicable to various applications.Type: GrantFiled: August 28, 2017Date of Patent: October 26, 2021Assignee: IDEMITSU KOSAN CO., LTD.Inventor: Tokue Sato
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Patent number: 11149206Abstract: A number of different branched hydrocarbon compounds (formula I) having a star-like configuration (S) are prepared from renewable oils containing fatty acids or derivatives containing fatty acids. The branched hydrocarbon compounds may be isolated individually or in mixtures, and may be used as part of base oils, such as renewable base oils (RBOs). A process for preparing the branched hydrocarbon compounds of formula I involve conditions that favour a trimerisation reaction followed by hydrotreating conditions. The compounds of formula I may be made by catalytically treating renewable material in a process, and the compounds have desirable qualities relating to lubrication, cold flow as well as having a low Noack volatility.Type: GrantFiled: June 15, 2018Date of Patent: October 19, 2021Assignee: NESTE OYJInventors: Jukka Myllyoja, Mika Kettunen, Rami Piilola
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Patent number: 11130926Abstract: The present invention provides a lubricating oil composition for automatic transmissions which comprises: 55 to 85 mass % of a Fischer-Tropsch synthetic oil with a kinematic viscosity at 100° C. of 2 to 4 mm2/s as a low-viscosity base oil; 1 to 10 mass % of an olefin copolymer 5 with a kinematic viscosity at 100° C. of 150 to 1,000 mm2/s as a high-viscosity base oil; and a polymethacrylate with a weight-average molecular weight of 10,000 to 50,000. This lubricating oil composition is such that the viscosity index of the composition is not 10 less than 190, the Brookfield viscosity is not more than 6,000 mPa·s at low temperature (?40° C.), the kinematic viscosity at 100° C. is 6 to 7 mm2/s, and the rate of reduction of the kinematic viscosity after a KRL shear stability test (60° C., 20 hr) is kept to within not more 15 than 3%.Type: GrantFiled: December 27, 2016Date of Patent: September 28, 2021Assignee: SHELL OIL COMPANYInventors: Genki Kamei, Ryuji Maruyama
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Patent number: 11124730Abstract: Provided is a vacuum pump oil which contains a mineral oil (A) having a temperature gradient ?|?*| of complex viscosity between two points of t(° C.) and t?10(° C.) (where ?15?t??10), as measured using a rotary rheometer at an angular velocity of 6.3 rad/s, of 10 Pa·s/° C. or less, and one or more compounds selected from a phenol-based compound (B) and an amine-based compound (C), and which has a viscosity index of less than 160. The vacuum pump oil has a good ultimate vacuum degree and is excellent in water separability, oxidation stability and shear stability, and is therefore applicable to various applications.Type: GrantFiled: August 28, 2017Date of Patent: September 21, 2021Assignee: IDEMITSU KOSAN CO., LTD.Inventor: Tokue Sato
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Patent number: 11111455Abstract: The invention provides a lubricating oil composition for automatic transmissions is made such that it comprises proportionately as its main constituents: 60 to 98 mass % as low viscosity base oils being base oils belonging to Groups 2 to 4 of the API (American Petroleum Institute) base oil categories wherein the kinematic viscosity at 100° C. is 2 to 5 mm2/s (Fischer-Tropsch synthetic oil comprising at least 45 to 80 mass %); 1 to 20 mass % as high-viscosity base oils being metallocene/poly-?-olefins with a kinematic viscosity at 100° C. of 100 to 600 mm2/s; and 1 to 20 mass % being a polymethacrylate with a weight-average molecular weight of 10,000 to 50,000. The viscosity index of this composition is not less than 190, the Brookfield viscosity at ?40° C. is not more than 5000 mPa·s, the 100° C. kinematic viscosity is 5 to 7 mm2/s, and the rate of reduction of the 100° C. kinematic viscosity after a KRL shear stability test (60° C., 20 hr) is not more than 3%.Type: GrantFiled: September 7, 2017Date of Patent: September 7, 2021Assignee: SHELL OIL COMPANYInventors: Ryuji Maruyama, Genki Kamei
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Patent number: 10961167Abstract: Provided herein is a unique process that prepares a saturated hydrocarbon mixture with well-controlled structural characteristics that address the performance requirements driven by the stricter environmental and fuel economy regulations for automotive engine oils. The process allows for the branching characteristics of the hydrocarbon molecules to be controlled so as to consistently provide a composition that has a surprising CCS viscosity at ?35° C. (ASTM D5329) and Noack volatility (ASTM D5800) relationship. The process comprises providing a specific olefinic feedstock, oligomerizing in the presence of a BF3 catalyst, and hydroisomerizing in the presence of a noble-metal impregnated, 10-member ring zeolite catalyst.Type: GrantFiled: April 30, 2019Date of Patent: March 30, 2021Assignees: Novvi LLC, Chevron U.S.A. Inc.Inventors: Eduardo Baralt, Cong Yan Chen, Yalin Hao, Liwenny Ho, Willbe Ho, Ajit Pradhan, Jason Rosalli, Benton Thomas, Jason Wells
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Patent number: 10947460Abstract: Systems and methods are provided for producing upgraded raffinate and extract products from lubricant boiling range feeds and/or other feeds having a boiling range of 400° F. (204° C.) to 1500° F. (816° C.) or more. The upgraded raffinate and/or extract products can have a reduced or minimized concentration of sulfur, nitrogen, metals, or a combination thereof. The reduced or minimized concentration of sulfur, nitrogen, and/or metals can be achieved by hydrotreating a suitable feed under hydrotreatment conditions corresponding to relatively low levels of feed conversion. Optionally, the feed can also dewaxed, such as by catalytic dewaxing or by solvent dewaxing. Because excessive aromatic saturation is not desired, the pressure for hydrotreatment (and optional dewaxing) can be 500 psig (˜3.4 MPa) to 1200 psig (˜8.2 MPa).Type: GrantFiled: September 11, 2019Date of Patent: March 16, 2021Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Benjamin S. Umansky, Keith K. Aldous, James W. Gleeson, Edward J. Blok, Richard A. Demmin
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Patent number: 10808185Abstract: Methods are provided for forming lubricant base stocks from feeds such as vacuum resid or other 510° C.+ feeds. A feed can be deasphalted and then catalytically and/or solvent processed to form lubricant base stocks, including bright stocks that are resistant to haze formation.Type: GrantFiled: December 27, 2016Date of Patent: October 20, 2020Assignee: ExxonMobil Research and Engineering CompanyInventors: Timothy L. Hilbert, Michael B. Carroll, Ajit B. Dandekar, Sara L. Yohe, Stephen H. Brown, Tracie L. Owens, April D. Ross, Eric B. Senzer, Steven Pyl, Rugved P. Pathare, Lisa I-Ching Yeh, Bradley R. Fingland, Keith K. Aldous, Anjaneya S. Kovvali, Kendall S. Fruchey, Sara K. Green, Camden N. Henderson
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Patent number: 10767125Abstract: Disclosed are Group III base stocks comprising greater than or equal to about 90 wt. % saturated hydrocarbons (saturates); a viscosity index from 120 to 145; a unique ratio of molecules with multi-ring naphthenes to single ring naphthenes (2R+N/1RN); a unique ratio of branched carbons to straight chain carbons (BC/SC); a unique ratio of branched carbons to terminal carbons (BC/TC); and unique MRV behavior as a function of base stock naphthene ratio (2R+N/1RN). A method for preparing the base stocks is also disclosed. Also disclosed is a lubricating oil having the base stock as a major component, and an additive as a minor component.Type: GrantFiled: August 14, 2019Date of Patent: September 8, 2020Assignee: EXXONMOBLE RESEARCH AND ENGINEERING COMPANYInventors: Daniel J. Eichelsdoerfer, Richard C. Dougherty, Charles L. Baker, Jr., Debra A. Sysyn
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Patent number: 10704734Abstract: An apparatus and method for determining lubrication contamination or deterioration in an engine or a lubricant system of an engine can include at least one sensor provided in the lubricant system. The sensor can sense an aroma of a lubricant or the air around the lubricant to measure a chemical composition or an aromatic. The sensed chemical composition or aromatic can be compared to a baseline or threshold to determine a particular contamination type or deterioration level of the lubricant.Type: GrantFiled: August 22, 2017Date of Patent: July 7, 2020Assignee: General Electric CompanyInventors: Ravindra Shankar Ganiger, Anand Madihalli Srinivasan, Uma Maheshwar Domala, Thomas DeWitt Woodrow
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Patent number: 10647627Abstract: The present disclosure relates to a method for upgrading hydrocarbon using C4, C5 and C6 streams, and more specifically, to a method for upgrading hydrocarbons using C4, C5 and C6 streams. The method includes the steps of: preparing C4, C5 and C6 streams, which are the products of naphtha catalytic cracking (NCC) process, heavy oil upgrading process, thermal cracking process, or fluidized catalytic cracking (FCC or RFCC) process; oligomerizing the C4, C5 and C6 streams with a catalyst to produce branched unsaturated hydrocarbons; and fractional distillating the branched unsaturated hydrocarbons to separate into C14-18 products or C32-40 products.Type: GrantFiled: October 20, 2015Date of Patent: May 12, 2020Assignees: SK Innovation Co., Ltd., SK Energy Co., Ltd.Inventors: Hee-Jung Jeon, Yong-Woo Kim
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Patent number: 10557093Abstract: A process for producing naphthenic base oils from low quality naphthenic crude feedstocks. The naphthenic base oils produced by the process have improved low temperature properties at high yields based on feedstock.Type: GrantFiled: September 19, 2018Date of Patent: February 11, 2020Assignee: ERGON, INC.Inventors: John K. Patrick, Howard Don Davis, Edward William Casserly
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Patent number: 10479949Abstract: A process for producing naphthenic bright stocks from low quality naphthenic crude feedstocks. The naphthenic bright stocks produced by the process have improved low temperature properties at high yields based on feedstock.Type: GrantFiled: September 17, 2015Date of Patent: November 19, 2019Assignee: ERGON, INC.Inventors: John K. Patrick, Howard Don Davis, Edward William Casserly
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Patent number: 10435634Abstract: The invention provides for a process for preparing a fluid having a boiling point in the range of from 100 to 400° C. and comprising more than 95% isoparaffins and containing less than 100 ppm aromatic, comprising the step of catalytically hydrogenating a feed comprising more than 95% by weight of a hydrodeoxygenated isomerized hydrocarbon biomass feedstock, at a temperature from 80 to 180° C. and at a pressure from 50 to 60 bars. The invention also provides for a fluid having a boiling point in the range of from 100 to 400° C. and a boiling range below 80° C., said fluid comprising more than 95% isoparaffins and less than 3% of naphthens by weight and having a ratio of iso-paraffins to n-paraffins of at least 12:1, a biodegradability at 28 days of at least 60%, as measured according to the OECD 306 standard, a biocarbon content of at least 95% by weight, containing less than 100 ppm aromatics by weight, and comprising carbon expressed as CH3 sat less than 30%.Type: GrantFiled: May 20, 2016Date of Patent: October 8, 2019Assignee: TOTAL MARKETING SERVICESInventors: Laurent Germanaud, Clarisse Doucet
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Patent number: 10294440Abstract: The present invention discloses a catalytic system for preparing highly branched alkane from olefin, which contains novel nickel or palladium complexes. In the presence of the catalytic system, highly branched oily alkane mixture can be efficiently obtained from olefins (such as ethylene) under mild conditions. The alkane mixture has a low bromine number, and can be used as a processing aid(s) and lubricant base oil with high-performance. Provides also was a method for preparing the catalyst and a method for preparing an oily olefin polymer.Type: GrantFiled: March 23, 2016Date of Patent: May 21, 2019Assignee: Shanghai Chemrun Co., Ltd.Inventors: Yong Tang, Wenjie Tao, Xiuli Sun, Junfang Li, Zheng Wang
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Patent number: 10227542Abstract: Disclosed is an oil composition with improved fuel economy and durability. The oil composition may be effective in improving fuel economy by reduction of friction on sliding parts of vehicle engines and in preventing abrasion of the engines by effective dispersion of soot in respective parts of the engines. The oil composition comprises a detergent dispersant, a friction reducer and a viscosity controller, which are suitably optimized at a mix ratio of those components.Type: GrantFiled: August 11, 2016Date of Patent: March 12, 2019Assignee: Hyundai Motor CompanyInventor: Jung Joon Oh
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Patent number: 10221367Abstract: Methods are provided for upgrading disadvantaged feeds for use in lubricant base stock production. A disadvantaged feed can be upgraded by hydroprocessing the feed to form a hydroprocessed bottoms fraction. The hydroprocessed bottoms fraction can then be used as a feed for forming Group I and/or Group II lubricant base stocks, optionally in combination with a conventional feed for lubricant production. The remaining portions of the hydroprocessing effluent can optionally be used for FCC processing and/or for other conventional applications of naphtha and distillate fractions.Type: GrantFiled: December 16, 2016Date of Patent: March 5, 2019Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Corry S. Powers, Liezhong Gong, Nicole D. Vaughn, Beatrice M. Gooding, Kendall S. Fruchey, Eric D. Joseck, Marc Sonnentrucker
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Patent number: 10087379Abstract: A process for producing naphthenic base oils from low quality naphthenic crude feedstocks. The naphthenic base oils produced by the process have improved low temperature properties at high yields based on feedstock.Type: GrantFiled: September 17, 2015Date of Patent: October 2, 2018Assignee: ERGON, INC.Inventors: John K. Patrick, Howard Don Davis, Edward William Casserly
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Patent number: 9868912Abstract: A method for producing a lubricating base oil, comprising: performing a 13C-NMR analysis regarding an oil to be treated and selecting the oil based on a value for dividing an integrated value of a peak for a tertiary carbon atom by an integrated value of all peaks at 0 to 50 ppm, a value for dividing an integrated value of a peak for a carbon atom constituting a main chain by the integrated value of all peaks at 0 to 50 ppm, and a value for dividing an integrated value of a peak for a branched CH3 bonded to a fifth or the following carbon atom from a terminal carbon atom in the main chain by an integrated value of all peaks at 10 to 25 ppm, and obtaining a dewaxed oil by isomerization dewaxing of the oil selected in the first step, is disclosed.Type: GrantFiled: March 26, 2014Date of Patent: January 16, 2018Assignee: JX NIPPON OIL & ENERGY CORPORATIONInventors: Kazuaki Hayasaka, Yasushi Wada, Marie Iwama, Koshi Takahama
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Patent number: 9809760Abstract: A method for producing a base oil having a high ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality by hydroisomerization dewaxing a selected Fischer-Tropsch wax under hydroisomerization conditions including a hydrogen to feed ratio from about 712.4 to about 3562 liter H2/liter oil.Type: GrantFiled: June 26, 2009Date of Patent: November 7, 2017Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott C. Deskin, Kamala Krishna, Stephen J. Miller, Susan M. Abernathy
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Patent number: 9796936Abstract: A process for heavy base oil production, comprising: a. performing an aromatic extraction of a first hydrocarbon feed to produce an aromatic extract, and a waxy raffinate; b. mixing the aromatic extract with a second hydrocarbon feed to make a mixed feed having greater than 2,000 wt ppm sulfur; c. feeding the mixed feed to a hydroprocessing unit to produce a heavy API Group II base oil having a kinematic viscosity at 70° C. from 22.6 to 100 mm2/s. An integrated refinery process unit for making heavy base oils, comprising: a. an aromatic extraction unit fluidly connected to a solvent dewaxing unit and a hydroprocessing unit; b. a first line from the aromatic extraction unit, that feeds an aromatic extract to a second hydrocarbon feed to make a mixed feed having greater than 2,000 wt ppm sulfur; and c. a connection that feeds the mixed feed to the hydroprocessing unit.Type: GrantFiled: September 9, 2015Date of Patent: October 24, 2017Assignee: Chevron U.S.A. Inc.Inventors: Guan-Dao Lei, Subhasis Bhattacharya, Axel Brait
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Patent number: 9732287Abstract: We provide a process to manufacture a base stock, comprising hydrocracking, separating, and dewaxing, wherein the base stock has a ratio of Noack volatility to CCS VIS at ?25° C. multiplied by 100 from 0.15 to 0.40. We also provide a base stock made by a process, and a base oil manufacturing plant that produces the base stock.Type: GrantFiled: March 24, 2014Date of Patent: August 15, 2017Assignee: Chevron U.S.A. Inc.Inventors: John Michael Rosenbaum, Brent K. Lok, Kathy A. Helling, Steven K. Lee, Ryan Joseph Schexnaydre
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Patent number: 9688923Abstract: Methods are provided for extracting heterocyclic compounds, organometallic compounds, and polynuclear aromatic hydrocarbons from a hydrocarbon feedstock such as crude oil or a crude fraction. The heterocyclic compounds and organometallic compounds are removed from the hydrocarbon feedstock through one or more successive extractions to form a first raffinate. The extractions use a first solvent system containing an ionic liquid formed from carbon dioxide and water. The polynuclear aromatic hydrocarbons are removed from the first raffinate using a second solvent system containing an aprotic solvent such as NMP, DMSO, aromatics, or combinations thereof. The extracted compounds remain chemically intact and may be fractionated for further applications. Further methods are provided for producing a hydrocarbon raffinate having reduced levels of heterocyclic compounds, organometallic compounds, and 2-4 cycle polynuclear aromatic hydrocarbons.Type: GrantFiled: June 10, 2014Date of Patent: June 27, 2017Assignee: Saudi Arabian Oil CompanyInventors: Zaki Yusuf, Alberto Lozano Ballesteros
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Patent number: 9605218Abstract: Improved yields of fuels and/or lubricants from a resid or other heavy oil feed can be achieved using slurry hydroconversion to convert at least about 90 wt % of the feed. The converted portion of the feed can then be passed into one or more hydroprocessing stages. An initial processing stage can be a hydrotreatment stage for additional removal of contaminants and for passivation of high activity functional groups that may be created during slurry hydroconversion. The hydrotreatment effluent can then be fractionated to separate naphtha boiling range fractions from distillate fuel boiling range fractions and lubricant boiling range fractions. At least the lubricant boiling range fraction can then be hydrocracked to improve the viscosity properties. The hydrocracking effluent can also be dewaxed to improve the cold flow properties. The hydrocracked and/or dewaxed product can then be optionally hydrofinished.Type: GrantFiled: June 19, 2014Date of Patent: March 28, 2017Assignee: ExxonMobil Research and Engineering CompanyInventors: Randolph J. Smiley, Ajit Bhaskar Dandekar, Ramanathan Sundararaman, Rustom Merwan Billimoria, Thomas Francis Degnan, Jr.
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Patent number: 9598344Abstract: The present invention relates generally to the field of chemical synthesis. Specifically, the present invention relates to a method for purification of ?-hydroxyl-?-methyl butyrate comprising (1) neutralizing a crude ?-hydroxyl-?-methyl butyrate; (2) cooling and crystallizing the crude ?-hydroxyl-?-methyl butyrate solution to create a ?-hydroxyl-?-methyl butyrate salt; (3) dissolving and acidifying the salt; and (4) extracting the resultant high purity ?-hydroxyl-?-methyl butyrate. Additionally, the present invention relates to a method of obtaining high purity ?-hydroxyl-?-methyl butyrate at normal temperature and vacuum conditions.Type: GrantFiled: December 6, 2013Date of Patent: March 21, 2017Inventors: Ling Long, Yongehun Tang
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Patent number: 9587184Abstract: Methods are provided for producing a plurality of lubricant base oil products with an increased overall yield. Prior to the final hydrocracking stage for viscosity index uplift, a feed for making a lubricant base oil is fractionated in order to form at least a feed for making a lighter lubricant base oil and a feed for making a heavier lubricant base oil. The fractionation cut points are selected to so that the feed fraction for forming a light lubricant base oil has a higher Noack volatility and a lower viscosity than the desired targets for the lighter lubricant base oil. The feed fractions are then hydroprocessed separately to achieve desired properties. After hydroprocessing, a portion of the heavier base oil is blended into the light lubricant base oil to produce a blended base oil product. This returns the volatility and the viscosity of the blended base oil to the desired specifications.Type: GrantFiled: September 21, 2011Date of Patent: March 7, 2017Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Eric D. Joseck, Michael Brian Carroll, David Mentzer, Sara M. Berberich, Yogi V. Shukla
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Patent number: 9562200Abstract: A method for producing a lubricant base oil, the method comprising a first step of fractionating, from a hydrocarbon oil containing a base oil fraction and a heavy fraction that is heavier than the base oil fraction, the base oil fraction and the heavy fraction, and a second step of obtaining a dewaxed oil by isomerization and dewaxing of the base oil fraction fractionated in the first step, wherein a hydrocracked oil obtained by hydrocracking the heavy fraction fractionated in the first step is returned to the first step.Type: GrantFiled: March 29, 2013Date of Patent: February 7, 2017Assignee: JX NIPPON OIL & ENERGY CORPORATIONInventors: Marie Iwama, Kazuaki Hayasaka, Yoshiyuki Nagayasu, Koshi Takahama
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Patent number: 9533291Abstract: The present invention provides a method for increasing hydrocarbon chain length. The method comprises providing a feedstock comprising fatty acids and/or fatty acid esters with hydrocarbon chain length below C23 into a reaction zone in which ketonization is conducted in the presence of a hydrotreatment catalyst under hydrogen pressure. The obtained ketones have a hydrocarbon chain length of from C24 to C43. The present invention further provides a method for simultaneous production of base oil components and fuel components.Type: GrantFiled: November 1, 2012Date of Patent: January 3, 2017Assignee: Neste OyjInventors: Jukka Myllyoja, Pekka Aalto, Rami Piilola
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Patent number: 9458402Abstract: Provided by the present invention is a lubricating oil composition having a low friction coefficient (traction coefficient) and a superior fluidity at low temperature, suitable as a transmission oil including an automatic transmission oil, by using a base oil which contains a mineral oil satisfying the conditions that (1) kinetic viscosity at 100° C. is in the range of 5 mm2/s or more to 8 mm2/s or less, (2) viscosity index is 130 or more, and (3) % CP by a ring analysis (n-d-M method) is 80 or more.Type: GrantFiled: March 29, 2013Date of Patent: October 4, 2016Assignee: IDEMITSU KOSAN CO., LTD.Inventor: Daisuke Takekawa
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Patent number: 9453166Abstract: This invention relates to compositions and methods for fluid hydrocarbon product, and more specifically, to compositions and methods for fluid hydrocarbon product via catalytic pyrolysis. Some embodiments relate to methods for the production of specific aromatic products (e.g., benzene, toluene, naphthalene, xylene, etc.) via catalytic pyrolysis. Some such methods may involve the use of a composition comprising a mixture of a solid hydrocarbonaceous material and a heterogeneous pyrolytic catalyst component. In some embodiments, an olefin compound may be co-fed to the reactor and/or separated from a product stream and recycled to the reactor to improve yield and/or selectivity of certain products. The methods described herein may also involve the use of specialized catalysts. For example, in some cases, zeolite catalysts may be used. In some instances, the catalysts are characterized by particle sizes in certain identified ranges that can lead to improve yield and/or selectivity of certain products.Type: GrantFiled: September 29, 2015Date of Patent: September 27, 2016Assignee: University of MassachusettsInventors: George H. Huber, Anne Mae Gaffney, Jungho Jae, Yu-Ting Cheng
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Patent number: 9404060Abstract: Disclosed is a novel diesel engine oil composition for fuel efficiency and endurance performance. The diesel engine oil composition may maximize frictional resistance and wear resistance by facilitating the formation of a lubricating film on a metal surface, extend an oil change cycle with excellent engine protection ability, and improve fuel efficiency due to friction reduction. The diesel engine oil composition include: base oil; a calcium-based or magnesium-based sulfonate detergent dispersant; a viscosity index improver selected from the group consisting of a diene copolymer, a polystyrene-diene copolymer and a hydrogenated polystyrene-diene copolymer; and a low friction agent including molybdenum dithiocarbamate (MoDTC) and glycerol monooleate (GMO).Type: GrantFiled: December 15, 2014Date of Patent: August 2, 2016Assignee: Hyundai Motor CompanyInventor: Jung Joon Oh
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Patent number: 9394494Abstract: Methods are provided for producing multiple lubricating oil basestocks from a feedstock. Prior to dewaxing, various fractions of the feedstock are exposed to hydrocracking conditions of different severity to produce a higher overall yield of basestocks. The hydrocracking conditions of different severity can represent exposing fractions of a feedstock to different processing conditions, exposing fractions of a feedstock to different amounts of hydrocracking catalyst, or a combination thereof.Type: GrantFiled: July 12, 2012Date of Patent: July 19, 2016Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Eric D. Joseck, Michael Brian Carroll, David Mentzer, Teck-Mui Hoo, Michel Daage, Ajit Bhaskar Dandekar
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Patent number: 9023191Abstract: A lubricating oil composition for an internal combustion engine contains a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPA·s or less and a NOACK of 12 mass % or less, and a component (B) of a mineral oil having a viscosity index of 120 or more. The component (A) is contained at a content of 10 mass % or more of a total amount of the composition.Type: GrantFiled: March 31, 2011Date of Patent: May 5, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Patent number: 9023190Abstract: A lubricating oil composition for an internal combustion engine contains: a base oil including a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPa·s or less and a NOACK of 12 mass % or less and a component (B) of a mineral oil having a viscosity index of 120 or more; and polyisobutylene having a mass average molecular weight of 500,000 or more. A content of the composition (A) is 25 mass % or more of a total amount of a lubricating oil.Type: GrantFiled: March 31, 2011Date of Patent: May 5, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Publication number: 20150099675Abstract: A method for improving varnish control in a mechanical device requiring hydraulic fluids, turbine oils, industrial fluids, circulating oils, or combinations thereof. The method involves supplying the mechanical device with a lubricating composition including a Group III lubricating oil base stock. The Group III lubricating oil base stock has a viscosity from 3.8 to 8.5 mm2/s at 100° C., a viscosity index greater than 120, a sulfur content less than 0.0003 weight percent, and an aromatic hydrocarbon content less than 0.2 weight percent, based on the total weight of the Group III lubricating oil base stock. Varnish reduction properties are improved as compared to varnish reduction properties achieved using a lubricating composition containing a different Group III lubricating oil base stock. The disclosure also provides lubricating compositions used in the method.Type: ApplicationFiled: September 4, 2014Publication date: April 9, 2015Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: William Hum, David G.L. Holt, Michael L. Blumenfeld, Angela S. Galiano-Roth
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Patent number: 8999901Abstract: Provided for are lubricant base stocks with improved filterability. The lubricant base stock includes a bright stock and an effective amount of a heavy neutral. The filterability of the base stock as measured by the Membrane Filtration Method is less than or equal to 400 seconds. Also provided for are lubricating oils with improved filterability and methods of improving the filterability of lubricant base stocks.Type: GrantFiled: March 12, 2013Date of Patent: April 7, 2015Assignee: ExxonMobil Research and Engineering CompanyInventors: Kristen Amanda Lyon, Charles L. Baker, Jr., Serge Riffard
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Patent number: 8992762Abstract: A lubricating oil composition for an internal combustion engine contains: a base oil including a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPa·s or less and a NOACK of 12 mass % or less and a component (B) of a mineral oil having a viscosity index of 120 or more; and polyisobutylene having a mass average molecular weight of 500,000 or more. A content of the composition (A) is 25 mass % or more of a total amount of a lubricating oil.Type: GrantFiled: March 31, 2011Date of Patent: March 31, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Patent number: 8992763Abstract: A lubricating oil composition for an internal combustion engine contains a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPA·s or less and a NOACK of 12 mass % or less, and a component (B) of a mineral oil having a viscosity index of 120 or more. The component (A) is contained at a content of 10 mass % or more of a total amount of the composition.Type: GrantFiled: March 31, 2011Date of Patent: March 31, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Patent number: 8980803Abstract: Provided for are lubricant base stocks with improved filterability. The lubricant base stock includes a bright stock or a heavy neutral and an effective amount of a pour point depressant. The filterability of the base stock as measured by the Membrane Filtration Method is less than or equal to 400 seconds. Also provided for are lubricating oils with improved filterability and methods of improving the filterability of lubricant base stocks.Type: GrantFiled: March 12, 2013Date of Patent: March 17, 2015Assignee: ExxonMobil Research and Engineering CompanyInventors: Kristen Amanda Lyon, Charles L. Baker, Jr., Serge Riffard
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Publication number: 20150060327Abstract: A lubricant base oil that is a hydrocarbon oil having a kinematic viscosity at 100° C. of 2.0 to 9 mm2/s, a viscosity index of 130 or more, a freezing point of ?30 to ?5° C., and an SBV viscosity at ?20° C. of 1,000 to 60,000 mPa·s, in which the freezing point of the lubricant base oil is higher by 10° C. or more than a freezing point of raffinate obtained by bringing the lubricant base oil into contact with urea and removing paraffin that can be included in the urea.Type: ApplicationFiled: April 1, 2013Publication date: March 5, 2015Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Kazuo Tagawa, Kazuaki Hayasaka
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Publication number: 20150060328Abstract: A lubricant base oil that is a hydrocarbon oil that satisfies any of the following conditions (i), (ii) and (iii): (i) a hydrocarbon oil having a kinematic viscosity at 100° C. of 3.0 to 5.0 mm2/s, a viscosity index of 145 or more, and an SBV viscosity at ?20° C. of 3,000 to 60,000 mPa·s, (ii) a hydrocarbon oil having a kinematic viscosity at 100° C. of 5 to 9 mm2/s, a viscosity index of 155 or more, and an SBV viscosity at ?20° C. of 3,000 to 30,000 mPa·s, and (iii) a hydrocarbon oil having a kinematic viscosity at 100° C. of 2.0 to 3.0 mm2/s, a viscosity index of 130 or more, and an SBV viscosity at ?30° C. of 1,000 to 30,000 mPa·s.Type: ApplicationFiled: April 1, 2013Publication date: March 5, 2015Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Kazuo Tagawa, Kazuaki Hayasaka
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Publication number: 20150057202Abstract: The present invention provides a lubricating oil composition for transmissions which is improved in fuel saving properties and has excellent metal fatigue prevention properties and heat resistance. The lubricating oil composition comprises (A) a mineral base oil having a 100° C. kinematic viscosity of 1.5 mm2/s or higher and 3.5 mm2/s or lower, a pour point of ?25° C. or lower, a viscosity index of 110 or greater, a % CN of 2 or greater and 20 or less and a % CA of 3 or less, the lubricating oil composition having a 100° C. kinematic viscosity of 2.5 mm2/s or higher and 3.8 mm2/s or lower.Type: ApplicationFiled: November 9, 2012Publication date: February 26, 2015Inventors: Hajime Nakao, Hitoshi Komatsubara
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Publication number: 20150051124Abstract: Provided by the present invention is a lubricating oil composition having a low friction coefficient (traction coefficient) and a superior fluidity at low temperature, suitable as a transmission oil including an automatic transmission oil, by using a base oil which contains a mineral oil satisfying the conditions that (1) kinetic viscosity at 100° C. is in the range of 5 mm2/s or more to 8 mm2/s or less, (2) viscosity index is 130 or more, and (3) % CP by a ring analysis (n-d-M method) is 80 or more.Type: ApplicationFiled: March 29, 2013Publication date: February 19, 2015Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Daisuke Takekawa
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Patent number: 8933003Abstract: A multifunctional, high-performance hydrocarbon composition is demanded.Type: GrantFiled: September 29, 2008Date of Patent: January 13, 2015Assignee: Nippon Oil CorporationInventors: Junichi Shibata, Hiroshi Kametsuka, Masahiro Hata, Satoshi Suda, Masanori Ibi, Tadaaki Motoyama
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Patent number: 8882989Abstract: A lubricating base oil manufacturing plant comprising a means for hydroisomerization dewaxing a wax at a specified hydrogen to feed ratio and a means for hydrofinishing the hydroisomerized wax to produce one or more base oils having greater than 10 weight percent total molecules with cycloparaffinic functionality and less than 0.5 weight percent molecules with multicycloparaffinic functionality.Type: GrantFiled: June 26, 2009Date of Patent: November 11, 2014Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott C. Deskin, Kamala Krishna, Stephen J. Miller, Susan M. Abernathy