Admixtures Patents (Class 208/19)
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Patent number: 12247178Abstract: The application concerns the use of a lubricant composition of grade 0W-8 according to the SAEJ300 classification, comprising at least one base oil, from 1 to 1000 ppm of at least one friction modifying additive and from 0.1 to 10% by weight of at least one polymer improving the viscosity index, said lubricant composition having kinematic viscosity measured at 40° C. according to standard ASTM D445 lower than or equal to 20 mm2/s, kinematic viscosity measured at 100° C. according to standard ASTM D445 lower than 5 mm2/s, and Noack volatility measured at 250° C. according to standard CEC-L-40-A-93 of between 10 and 85%, preferably between 25 and 85%, more preferably between 60 and 85%, for the lubrication of a rechargeable hybrid vehicle engine or a hybrid vehicle engine comprising a range extender.Type: GrantFiled: March 30, 2022Date of Patent: March 11, 2025Assignee: TotalEnergies OneTechInventors: Gautier Burette, Mickael Debord, David Senard
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Patent number: 11987767Abstract: The present invention describes a pipe sealing compound/adjunct lubricant used to prevent gas or liquid leaks when applied to pipe threads and other connections of the same. The compound relies on silicone oil lubricant(s) and one or more friction modifier(s), viscosity builder(s) and filler material(s). The compound contains a viscoelastic liquid that does not have a curing phase and is resistant to hardening and/or drying. The compound is chemically resistant to a wide variety of liquids and gases, is food safe and can withstand extreme high or low temperatures and precipitous temperature fluctuations. The compound has been found to exhibit an inverse pressure to leak rate phenomena.Type: GrantFiled: May 5, 2023Date of Patent: May 21, 2024Inventors: John Pastorello, Michael Pastorello
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Patent number: 11643616Abstract: A process is disclosed for producing renewable products, such as a renewable base oil, from a feedstock of biological origin. The process includes subjecting a feedstock containing free fatty acids and fatty acid glycerides, wherein at least one hydrocarbon chain is unsaturated, to esterification reaction in the presence of an alcohol. An ester stream thereby obtained is then subjected to metathesis conditions in the presence of a renewable alkene to obtain a metathesis product. Separation of the metathesis product includes recovery of a fraction containing or consisting essentially of C16 fatty acid esters, which is subjected to ketonisation reaction conditions to produce long chain ketones, which after hydrotreatment meet requirements for a renewable base oil. Ketonisation reaction produces renewable alkene usable in metathesis reaction.Type: GrantFiled: September 25, 2020Date of Patent: May 9, 2023Assignee: NESTE OYJInventors: Jukka Myllyoja, Jukka Hietala
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Patent number: 11499117Abstract: A lubricating composition comprising a base oil and one or more additives, wherein the composition has: a sulphated ash content (according to ASTM D 874) of at least 0.4 wt % and at most 1.0 wt. %, by weight of the lubricating composition; a total base number (TBN) value (according to ASTM D 2896) of at least 4.0 mg KOH/g and at most 12 mg KOH/g; a total aromatics content contributed by the base oil in the range from 1 wt % to 30 wt %, by weight of the lubricating composition; and a sulphur content contributed by the base oil of 0.4 wt % or less, by weight of the lubricating composition; and wherein the base oil comprises a blend of (i) a first base oil which is a mineral base oil selected from an API Group I mineral base oil and an API Group II mineral base oil, and mixtures thereof, and (ii) a second base oil selected from an API Group II base oil and an API Group III base oil, preferably wherein the first base oil belongs to a different API group to that of the second base oil.Type: GrantFiled: July 11, 2019Date of Patent: November 15, 2022Assignee: SHELL USA, INC.Inventors: Jose Luis Garcia, Seung Min Yeo, Jörg Reher
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Patent number: 11186787Abstract: A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by ultra violet (UV) spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.015 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 4 and 6 cSt. A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by UV spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.020 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 10 and 14 cSt. A lubricating oil having the base stock as a major component, and one or more additives as a minor component. Methods for improving oxidation performance and low temperature performance of formulated lubricant compositions through the compositionally advantaged base stock.Type: GrantFiled: July 31, 2019Date of Patent: November 30, 2021Assignee: ExxonMobil Research and Engineering CompanyInventors: Rugved P. Pathare, Lisa I-Ching Yeh, Yogi V. Shukla, Charles L. Baker, Jr., Bryan E. Hagee, Debra A. Sysyn, Kendall S. Fruchey
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Patent number: 11041132Abstract: Provided is a lubricating oil composition containing a base oil (A) containing a mineral oil (A1) having a complex viscosity ?* at ?35° C. of 150 Pa·s or less as measured with a rotary rheometer under conditions at an angular velocity of 6.3 rad/s and a strain amount of 0.1%; a viscosity index improver (B) containing a comb-shaped polymer (B1); and a molybdenum-based friction modifier (C), wherein the content of the molybdenum-based friction modifier (C) in terms of a molybdenum atom is more than 500 ppm by mass and less than 900 ppm by mass on the basis of the whole amount of the lubricating oil composition, and a NOACK value is 10% by mass or less.Type: GrantFiled: March 23, 2017Date of Patent: June 22, 2021Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Hiroshi Oki, Motoharu Ishikawa
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Patent number: 10920159Abstract: A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by ultra violet (UV) spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.015 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 4 and 6 cSt. A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by UV spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.020 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 10 and 14 cSt. A lubricating oil having the base stock as a major component, and one or more additives as a minor component. Methods for improving oxidation performance and low temperature performance of formulated lubricant compositions through the compositionally advantaged base stock.Type: GrantFiled: July 31, 2019Date of Patent: February 16, 2021Assignee: ExxonMobil Research and Engineering CompanyInventors: Rugved P. Pathare, Lisa I-Ching Yeh, Yogi V. Shukla, Charles L. Baker, Jr., Bryan E. Hagee, Debra A. Sysyn, Kendall S. Fruchey
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Patent number: 10723881Abstract: The present invention provides a paraffin wax having a congealing point according to ASTM D938 of at least 100° C. and a Saybolt colour according to ASTM D156 of at least 25 cm.Type: GrantFiled: December 29, 2015Date of Patent: July 28, 2020Assignee: SHELL OIL COMPANYInventors: Arend Hoek, Antonius Adrianus Maria Roovers, Kaushik Majumder
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Patent number: 10717944Abstract: A lubricating oil composition for automotive transmissions is disclosed. It offers an automotive transmission (especially a fuel-saving type) which satisfies all requirements as regards the properties of resistance to churning, maintenance of the oil film and low-temperature viscosity. It comprises a GTL low viscosity base oil and a Group 1 high viscosity base oil.Type: GrantFiled: September 28, 2015Date of Patent: July 21, 2020Assignee: SHELL OIL COMPANYInventors: Noriaki Shinoda, Ryuji Maruyama, Katsuji Okami
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Patent number: 10647937Abstract: Provided is a mineral base oil having a kinematic viscosity at 40° C. of 4.0 mm2/s or more and less than 6.0 mm2/s, a kinematic viscosity at 100° C. of 1.0 mm2/s or more and less than 2.0 mm2/s, and a flash point of 140° C. or higher. A lubricating oil composition containing the mineral base oil has a high flash point while having a low viscosity and thus having excellent fuel-saving performance when used as a driving system oil and the like.Type: GrantFiled: February 3, 2017Date of Patent: May 12, 2020Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Norihiro Kuroda, Hisao Anzai, Kenji Goto
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Patent number: 10640721Abstract: The present invention provides a fuel comprising a renewable middle distillate composition obtainable by hydrodeoxygenation of a feedstock comprising levulinic acid dimers/oligomers and fractionated distillation. The renewable middle distillate composition contains less than 10.0 wt.-% aromatics.Type: GrantFiled: December 28, 2016Date of Patent: May 5, 2020Assignee: NESTE OYJInventors: Kati Sandberg, Ulla Kiiski, Marina Lindblad, Jukka Myllyoja
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Patent number: 10584750Abstract: Provided is a grease composition for a wheel bearing, containing (a) a base oil consisting of a mineral oil and a synthetic hydrocarbon oil, wherein the ratio of the synthetic hydrocarbon oil to the total amount of the mineral oil and the synthetic hydrocarbon oil is 40 to 60 mass %, and the base oil has a kinematic viscosity at 40° C. of 40 to 65 mm2/s; (b) a thickener of formula (A) wherein R2 is diphenylmethane, and R1 and R3, which may be the same or different from each other, each represent cyclohexyl group or a straight-chain or branched alkyl group having 16 to 20 carbon atoms, with a molar ratio of the cyclohexyl group to the total number of moles of the cyclohexyl group and the alkyl group being 50 to 90 mol %; (c) an amine type antioxidant; and (d) an amine phosphate type antiwear agent.Type: GrantFiled: March 12, 2015Date of Patent: March 10, 2020Assignees: KYODO YUSHI CO., LTD., NTN CORPORATIONInventors: Yuta Sato, Daisuke Tsutsui, Junichi Imai, Shinsuke Hirano
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Patent number: 10414995Abstract: A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by ultra violet (UV) spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.015 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 4 and 6 cSt. A base stock having at least 90 wt. % saturates, an amount and distribution of aromatics, as determined by UV spectroscopy, including an absorptivity between 280 and 320 nm of less than 0.020 l/gm-cm, a viscosity index (VI) from 80 to 120, and having a cycloparaffin performance ratio greater than 1.05 and a kinematic viscosity at 100° C. between 10 and 14 cSt. A lubricating oil having the base stock as a major component, and one or more additives as a minor component. Methods for improving oxidation performance and low temperature performance of formulated lubricant compositions through the compositionally advantaged base stock.Type: GrantFiled: March 24, 2017Date of Patent: September 17, 2019Assignee: ExxonMobil Research and Engineering CompanyInventors: Rugved P. Pathare, Lisa I-Ching Yeh, Yogi V. Shukla, Charles L. Baker, Jr., Bryan E. Hagee, Debra A. Sysyn, Kendall S. Fruchey
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Patent number: 10011787Abstract: Methods are provided for producing Group II and Group III base stocks with a controlled or consistent aromatics content. An aromatics-rich base stock, such as a Group I base stock or an alkylated aromatic base stock, can be added to the catalytically treated base stock in a minimal amount after the final catalytic treatment step but prior to fractionation. At the beginning of a processing run for forming lubricant base stock products, about 0.25 wt % to about 1.25 wt % of the Group I base stock can be added to a catalytically processed feed after the final catalytic processing stage but prior to fractionation to form the Group II and/or Group III base stock. During the course of the processing run, the amount of Group I base stock added can be reduced roughly in correspondence with the increase in aromatics caused by catalyst deactivation.Type: GrantFiled: November 13, 2015Date of Patent: July 3, 2018Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Kristen S. Lyon, Eric D. Joseck, Gary P. Schleicher, Richard C. Dougherty, Angela Horton
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Patent number: 9932538Abstract: A universal synthetic water displacement multi-purpose penetrating lubricant product-by-process with the capacity to protect metal surfaces against corrosion, with galvanic and electrolysis protection, while providing excellent lubrication properties. The lubricant actively penetrates the crystalline surface of the metal while exhibiting extreme pressure lubrication, non-migrating with lasting protection. The lubricant exhibits dielectric strength of over 14,000 volts, at the same time cleaning electrical contacts while reducing resistance and associated heat. A preferred embodiment comprises polymerized alpha-olefins, K-1 kerosene, and at least one base oil selected from the base oil group consisting of hydroisomerized high base oils and HT severe hydro-cracked base oils. Various combinations of other optional ingredients are also disclosed.Type: GrantFiled: April 5, 2016Date of Patent: April 3, 2018Assignee: Bestline International Research, Inc.Inventor: Ronald J. Sloan
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Patent number: 9528060Abstract: The present invention relates to a system oil composition for crosshead diesel engines, the system oil composition having excellent heat resistance and being effective for improvement of fuel efficiency. More specifically, the present invention relates to a system oil composition for crosshead diesel engines in which the system oil composition includes a mineral oil and/or a synthetic oil as a base oil (A) and has a kinematic viscosity of at least 35 mm2/s at 50° C., a high-shear viscosity of at most 45 mPa·s at 50° C., and a high-shear viscosity of at least 15 mPa·s at 70° C.Type: GrantFiled: March 8, 2012Date of Patent: December 27, 2016Assignee: JX Nippon Oil & Energy CorporationInventors: Shigeki Takeshima, Naozumi Arimoto
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Patent number: 9096811Abstract: A functional fluid composition comprising a naphthenic bright stock base oil and a Fischer-Tropsch derived base oil, wherein the functional fluid composition has a Viscosity Index (according to ASTM D 2270) of above 95.Type: GrantFiled: November 4, 2010Date of Patent: August 4, 2015Assignee: Shell Oil CompanyInventors: Janet Marian Smithers, David John Wedlock
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Patent number: 9023190Abstract: A lubricating oil composition for an internal combustion engine contains: a base oil including a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPa·s or less and a NOACK of 12 mass % or less and a component (B) of a mineral oil having a viscosity index of 120 or more; and polyisobutylene having a mass average molecular weight of 500,000 or more. A content of the composition (A) is 25 mass % or more of a total amount of a lubricating oil.Type: GrantFiled: March 31, 2011Date of Patent: May 5, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Patent number: 9023191Abstract: A lubricating oil composition for an internal combustion engine contains a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPA·s or less and a NOACK of 12 mass % or less, and a component (B) of a mineral oil having a viscosity index of 120 or more. The component (A) is contained at a content of 10 mass % or more of a total amount of the composition.Type: GrantFiled: March 31, 2011Date of Patent: May 5, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Publication number: 20150099675Abstract: A method for improving varnish control in a mechanical device requiring hydraulic fluids, turbine oils, industrial fluids, circulating oils, or combinations thereof. The method involves supplying the mechanical device with a lubricating composition including a Group III lubricating oil base stock. The Group III lubricating oil base stock has a viscosity from 3.8 to 8.5 mm2/s at 100° C., a viscosity index greater than 120, a sulfur content less than 0.0003 weight percent, and an aromatic hydrocarbon content less than 0.2 weight percent, based on the total weight of the Group III lubricating oil base stock. Varnish reduction properties are improved as compared to varnish reduction properties achieved using a lubricating composition containing a different Group III lubricating oil base stock. The disclosure also provides lubricating compositions used in the method.Type: ApplicationFiled: September 4, 2014Publication date: April 9, 2015Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: William Hum, David G.L. Holt, Michael L. Blumenfeld, Angela S. Galiano-Roth
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Patent number: 8992763Abstract: A lubricating oil composition for an internal combustion engine contains a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPA·s or less and a NOACK of 12 mass % or less, and a component (B) of a mineral oil having a viscosity index of 120 or more. The component (A) is contained at a content of 10 mass % or more of a total amount of the composition.Type: GrantFiled: March 31, 2011Date of Patent: March 31, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Patent number: 8992762Abstract: A lubricating oil composition for an internal combustion engine contains: a base oil including a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPa·s or less and a NOACK of 12 mass % or less and a component (B) of a mineral oil having a viscosity index of 120 or more; and polyisobutylene having a mass average molecular weight of 500,000 or more. A content of the composition (A) is 25 mass % or more of a total amount of a lubricating oil.Type: GrantFiled: March 31, 2011Date of Patent: March 31, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Publication number: 20150060329Abstract: The present invention provides a process to prepare a residual base oil, which process at least comprises the following steps: (a) providing a mineral bright stock waxy raffinate; (b) combining the mineral bright stock waxy raffinate provided in step (a) with a catalytically dewaxed residual Fischer-Tropsch derived base oil to obtain a mixture; and (c) solvent dewaxing the mixture obtained in (b) to obtain a residual base oil, wherein the weight ratio of the mineral bright stock waxy raffinate to the catalytically dewaxed residual Fischer-Tropsch derived base oil in step (b) is in the range of from 75:25 to 35:65. In another aspect the present invention provides a residual base oil obtainable by the process.Type: ApplicationFiled: April 4, 2013Publication date: March 5, 2015Inventor: David John Wedlock
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Publication number: 20150051124Abstract: Provided by the present invention is a lubricating oil composition having a low friction coefficient (traction coefficient) and a superior fluidity at low temperature, suitable as a transmission oil including an automatic transmission oil, by using a base oil which contains a mineral oil satisfying the conditions that (1) kinetic viscosity at 100° C. is in the range of 5 mm2/s or more to 8 mm2/s or less, (2) viscosity index is 130 or more, and (3) % CP by a ring analysis (n-d-M method) is 80 or more.Type: ApplicationFiled: March 29, 2013Publication date: February 19, 2015Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Daisuke Takekawa
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Patent number: 8933003Abstract: A multifunctional, high-performance hydrocarbon composition is demanded.Type: GrantFiled: September 29, 2008Date of Patent: January 13, 2015Assignee: Nippon Oil CorporationInventors: Junichi Shibata, Hiroshi Kametsuka, Masahiro Hata, Satoshi Suda, Masanori Ibi, Tadaaki Motoyama
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Patent number: 8882989Abstract: A lubricating base oil manufacturing plant comprising a means for hydroisomerization dewaxing a wax at a specified hydrogen to feed ratio and a means for hydrofinishing the hydroisomerized wax to produce one or more base oils having greater than 10 weight percent total molecules with cycloparaffinic functionality and less than 0.5 weight percent molecules with multicycloparaffinic functionality.Type: GrantFiled: June 26, 2009Date of Patent: November 11, 2014Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott C. Deskin, Kamala Krishna, Stephen J. Miller, Susan M. Abernathy
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Patent number: 8864981Abstract: Deasphalted residual oil (DAO) and the aromatics-rich extract that is derived from DAO have low polycyclic aromatics contents, relatively low aniline points, and high flash points. They form blending stocks that improve properties of mixed feedstocks to consistently produce environmentally qualified rubber processing oil (RPO) by extraction under low solvent-to-oil ratios and moderate extraction temperatures. Distilling a petroleum crude oil under atmospheric pressure generates a bottom residual oil which is then subject to vacuum distillation to yield a bottom residual oil. DAO is produced by removing the asphalt from the vacuum bottom residual oil through extraction with light paraffinic solvent. The extract of DAO is a co-product in the production of the bright stock of the lubricating oil through extraction. The feedstock is mixed with the extract from a petroleum fraction boiling in lube oil range.Type: GrantFiled: January 14, 2011Date of Patent: October 21, 2014Assignee: CPC Corporation, TaiwanInventors: Chih-Cheng Chang, Jung-Huang Wu, Cheng-Tsung Hong, Jin-Shang Liou, Kuo-Min Wei, Hung-Chung Shen, Fu-Ming Lee
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Patent number: 8846991Abstract: The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C. The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.Type: GrantFiled: June 17, 2010Date of Patent: September 30, 2014Assignee: Dow Global Technologies LLCInventors: Teresa P. Karjala, Selim Yalvac, Thomas Karjala, Daniel D. VanderLende, Brian W. Kolthammer, James C. Stevens, Charles F. Diehl
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Publication number: 20140274827Abstract: Provided for are lubricant base stocks with improved filterability. The lubricant base stock includes a bright stock and an effective amount of a heavy neutral. The filterability of the base stock as measured by the Membrane Filtration Method is less than or equal to 400 seconds. Also provided for are lubricating oils with improved filterability and methods of improving the filterability of lubricant base stocks.Type: ApplicationFiled: March 12, 2013Publication date: September 18, 2014Inventors: Kristen Amanda Lyon, Charles L. Baker, JR., Serge Riffard
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Patent number: 8834705Abstract: A novel lubricant composition is disclosed. In one embodiment the lubricant composition comprises in admixture: a first base stock component comprising one or more base stocks each having a viscosity of at least 40 cSt, Kv100° C. and a molecular weight distribution (MWD) as a function of viscosity at least 10 percent less than algorithm: MWD=0.2223+1.0232*log (Kv at 100° C. in cSt); and a second base stock component comprising one or more base stocks each having a viscosity less than 10 cSt, Kv100° C.Type: GrantFiled: June 14, 2012Date of Patent: September 16, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Willie A. Givens, Angela S. Galiano-Roth, Margaret M. Wu, James T. Carey
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Patent number: 8784642Abstract: A lubricating oil composition of SAE viscosity grade 0W20 which comprises a base oil and additive components comprising a nitrogen-containing ashless dispersant, an alkaline earth metal-containing detergent, a phosphorus-containing wear inhibitor, an oxidation inhibitor and a viscosity index improver and which shows a viscosity index of 200-240, a HTHS viscosity of not less than 2.9 mPa·s s at 150° C. and a Noack evaporation loss of not more than 13% favorably gives a high fuel economy and high wear inhibition to a four cycle gasoline engine of motorcycles and a diesel engine mounted on motor cars equipped with an exhaust gas post-processing apparatus.Type: GrantFiled: November 11, 2011Date of Patent: July 22, 2014Assignee: Chevron Japan Ltd.Inventors: Hiroki Andoh, Morikuni Nakazato
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Patent number: 8784643Abstract: We provide a base stock comprising hydrocarbons with consecutive numbers of carbon atoms, wherein the base stock has a boiling range from 388 to 538° C., a VI from 105 to less than 130, and a Noack volatility from 5 to 11.5 wt % or a CCS VIS at ?25° C. from 2000 to 4000 mPa·s. We also provide a base stock slate comprising the base stock and an additional base stock having an additional boiling range from 371 to 496° C., and other properties.Type: GrantFiled: November 30, 2012Date of Patent: July 22, 2014Assignee: Chevron U.S.A. Inc.Inventors: John Michael Rosenbaum, Brent K Lok, Kathy Ann Helling, Steven Lee, Ryan Joseph Schexnaydre, Susan Marjorie Abernathy
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Patent number: 8765823Abstract: A method for starting up a bubble column slurry bed reactor of the present invention includes, when restarting operation of a bubble column slurry bed reactor for producing hydrocarbons by the Fischer-Tropsch synthesis reaction, feeding a hydroprocessed oil produced in the bubble column slurry bed reactor and hydroprocessed that contains 40% by mass or more of paraffin hydrocarbons having carbon number of 21 or more and that has a peroxide value of 1 ppm or less, to the bubble column slurry bed reactor.Type: GrantFiled: March 26, 2012Date of Patent: July 1, 2014Assignees: Japan Oil, Gas and Metals National Corporation, Inpex Corporation, JX Nippon Oil & Energy Corporation, Japan Petroleum Exploration Co., Ltd., Cosmo Oil Co., Ltd., Nippon Steel & Sumikin Engineering Co., Ltd.Inventor: Yoshiyuki Nagayasu
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Patent number: 8759267Abstract: The present invention is directed to a method for improving the fuel efficiency of low and medium speed engine oil compositions by reducing the traction coefficient of the oil by formulating the oil using at least two base stocks of different kinematic viscosity wherein the differences in kinematic viscosity between the base stocks is at least 30 mm2/s.Type: GrantFiled: January 28, 2011Date of Patent: June 24, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Kathleen H. Tellier, Vincent M. Carey, Kevin L. Crouthamel
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Patent number: 8758595Abstract: The present invention is related to a process oil using as a raw material a deasphalted oil obtained by deasphalting a vacuum residual oil of a crude oil and a manufacturing method of the process oil, the process oil having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (b) a viscosity (100° C.) of 40 to 70 mm2/s; (c) an aniline point of 85 to 100° C.; (d) a flash point of 250° C. or higher; (e) an aromatic hydrocarbon content of 40 to 55 mass %; and (f) a polar substance content of 10 to 15 mass %. The present invention is also related to a process oil and a manufacturing method of the process oil, the process oil obtained by mixing: an extract obtained by deasphalting and solvent-extracting a vacuum residual oil of a crude oil; and a lubricant base oil having a polycyclic aromatics (PCA) content of less than 3 mass %, and having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (i) a viscosity (100° C.Type: GrantFiled: April 28, 2011Date of Patent: June 24, 2014Assignee: Idemitsu Kosan Co., Ltd.Inventors: Meishi Tanaka, Masashi Nakamura, Kazuhiro Teshima, Akihito Abe, Masami Takasaki
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Patent number: 8747650Abstract: Provided are formulations, methods of making, and methods of using one or more Fischer-Tropsch Base Oils of the present invention in a low sulfur, low sulfated ash, and low phosphorus engine lubricant to enhance thermal stability of the lubricant as well as the high-temperature performance of an engine housing the lubricant.Type: GrantFiled: December 21, 2006Date of Patent: June 10, 2014Assignee: Chevron Oronite Technology B.V.Inventors: Jeroen Van Leeuwen, Peter Kleijwegt
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Patent number: 8734725Abstract: A system for producing enhanced wax alternatives, including a high shear device comprising a rotor and a stator, and configured to process petroleum wax and base oil with a hydrogen-containing gas under shearing conditions to form a feedstock, wherein at least one of the rotor and the stator comprises a toothed surface; and a reactor comprising a reactor inlet and a reactor outlet, and configured for hydrogenation of the feedstock for a time sufficient to produce enhanced hydrogenated products, wherein the high shear device is in fluid communication with the reactor, whereby the feedstock is transferable therebetween.Type: GrantFiled: May 1, 2013Date of Patent: May 27, 2014Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Patent number: 8702968Abstract: Disclosed herein are marine cylinder lubricants which comprise a major amount of basestock selected from the group consisting of a Group II basestock, a Group III basestock and mixtures thereof, wherein the marine cylinder lubricant has a kinematic viscosity at 100° C. of from 13 to about 16.2 cSt; and contains less than about 10 wt. % bright stock. Also disclosed are marine cylinder lubricants which comprise a major amount of basestock selected from the group consisting of a Group II basestock, a Group III basestock and mixtures thereof, wherein the marine cylinder lubricant has a kinematic viscosity at 100° C. of between about 13 and about 16.2 cSt; and a total base number of 5 to about 70, and further wherein the marine cylinder lubricant contains less than about 10 wt. % bright stock.Type: GrantFiled: April 4, 2012Date of Patent: April 22, 2014Assignee: Chevron Oronite Technology B.V.Inventor: Cornelis Hendrikus Maria Boons
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Patent number: 8703663Abstract: The hydrocarbon-based lubricating base oil of the invention has a urea adduct value of not greater than 4% by mass, a viscosity index of 100 or greater, and a cycloparaffin content of 30-60% by mass based on the total amount of the saturated components, as measured by field desorption/ionization mass spectrometry. The hydrocarbon-based lubricating base oil of the invention allows high levels of both viscosity-temperature characteristic and low-temperature viscosity characteristic to be obtained, and exhibits excellence in terms of evaporation property and energy efficiency.Type: GrantFiled: October 1, 2009Date of Patent: April 22, 2014Assignee: JX Nippon Oil & Energy CorporationInventor: Kazuo Tagawa
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Patent number: 8663454Abstract: It has been determined that sealant fluid formulations comprising a lubricant oil derived from Fischer-Tropsch waxes demonstrate performance comparable to sealant fluid comprising lubricants derived from polyalphaolefins (PAO's). The sealant fluids of the current invention can provide excellent performance properties similar to those provided by PAO based sealant fluids, but at lower cost.Type: GrantFiled: October 23, 2009Date of Patent: March 4, 2014Assignee: Chevron U.S.A. Inc.Inventor: Ravindra R. Shah
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Patent number: 8658018Abstract: A lubricant base oil blend having a wt % Noack volatility less than 29, comprising a) a light base oil fraction having a kinematic viscosity at 100° C. between 1.5 and 3.6, and a wt % Noack volatility both between 0 and 100 and less than a Noack Volatility Factor, and b) a petroleum-derived base oil fraction. A process to make the lubricant base oil blend having a wt % Noack volatility less than 29. Also, a pour point depressed lubricant base oil blend having a Brookfield viscosity at ?40° C. of less than 18,000 cP, comprising the light base oil fraction, a petroleum-derived base oil fraction, and a pour point depressant.Type: GrantFiled: December 20, 2006Date of Patent: February 25, 2014Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott C. Deskin, Brent K. Lok, Shuibo Xie, Stephen J. Miller
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Patent number: 8648021Abstract: A hydrocarbon-based lubricating base oil wherein a urea adduct value is not greater than 4% by mass, a viscosity index is 100 or higher, an average of carbon atoms number is 23-31 as determined by gas chromatography distillation, a value obtained by dividing an integral value of a peak in 30 ppm by an integral value of total peaks in the range of from 0 ppm to 50 ppm for the 13C-NMR spectrum is 0.1-0.2, and a product of a value obtained by dividing an integral value of peaks attributed to tertiary carbon atoms by an integral value of total peaks in the range of from 0 ppm to 50 ppm for the 13C-NMR spectrum, and the average of carbon atoms number, is 1.8-2.5.Type: GrantFiled: October 7, 2009Date of Patent: February 11, 2014Assignee: JX Nippon Oil & Energy CorporationInventors: Kazuo Tagawa, Shigeki Matsui
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Patent number: 8642523Abstract: The present invention is directed to a method for improving the fuel efficiency of engine oil compositions by reducing the traction coefficient of the oil by formulating the oil using a blend of one or more first base stock(s) selected from Group II base stock, Group III base stock and Group IV base stock and a second base stock selected from polyisobutylene (PIB) and, preferably, additized with a detergent.Type: GrantFiled: January 28, 2011Date of Patent: February 4, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Kevin L. Crouthamel, Vincent M. Carey
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Patent number: 8642524Abstract: The present invention is directed to a method for controlling soot induced viscosity increase in diesel engines, by using as the diesel engine lubricant an oil formulation comprising a base oil containing about 10 to 80 wt % GTL base stock and/or base oil and/or hydrodewaxed or hydroisomerized/catalytic (or solvent) dewaxed base stock and/or base oil in combination with 20 to 90 wt % conventional Group I petroleum derived base oil, said base oil being further combined with a polymeric viscosity modifier, and to the lubricating oil which effects such control over soot induced viscosity increase.Type: GrantFiled: October 11, 2012Date of Patent: February 4, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Heather M. Haigh, Brandon Thomas Weldon, Jason Zhisheng Gao
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Patent number: 8637438Abstract: A lubricating oil composition for internal combustion engines comprising a base oil containing at least one component selected from an ?-olefin oligomer having 16 to 40 carbon atoms obtained by oligomerizing ?-olefin(s) having 2 to 20 carbon atoms using a metallocene catalyst, and the hydrogenated derivative thereof; an ?-olefin oligomer having 16 to 40 carbon atoms derived from an ?-olefin dimer obtained using a metallocene catalyst, and the hydrogenated derivative thereof; and the like. The lubricating oil composition has an excellent low-temperature fluidity, a low evaporativity, and a good oxidation stability.Type: GrantFiled: November 14, 2006Date of Patent: January 28, 2014Assignee: Idemitsu Kosan Co., Ltd.Inventor: Ryou Yamada
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Publication number: 20130333654Abstract: A lubricating composition comprising a base oil blend and one or more additives wherein the base oil blend comprises: a distillate naphthenic base oil having a saturates content as measured by IP368 of greater than 92 wt % and comprising less than 10 ppm of sulphur; and a Fischer-Tropsch derived base oil. The lubricating composition of the present invention exhibits improved detergency and engine cleanliness properties.Type: ApplicationFiled: December 15, 2011Publication date: December 19, 2013Applicant: Shell Internationale Research Maatschappij B.V.Inventor: David Wedlock
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Patent number: 8609429Abstract: Methods for determining the fouling propensity of a hydrocarbon stream and for reducing fouling are provided. In one method, the fouling propensity of a hydrocarbon stream is determined by obtaining a parameter value indicative of the fouling propensity at no less than two different temperatures, and an activation energy of fouling by the hydrocarbon stream is derived therefrom. In another method, the thus obtained parameter value at no less than two different temperatures and the activation energy are used to select proper heating fluids and operating temperature and to determine whether to add an antifoulant to the hydrocarbon stream to reduce fouling at a given temperature.Type: GrantFiled: November 17, 2011Date of Patent: December 17, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Teh C. Ho, Glen B. Brons, Limin Song, Tahmid I. Mizan
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Publication number: 20130313160Abstract: Disclosed herein are methods for isolating heavy saturated hydrocarbons from a subsurface shale formation comprising kerogen and an extractible organics component. These methods can be used to provide a bright stock product. The process comprises extracting an extractible organics component from subsurface shale formations comprising kerogen and the extractible organics component in an inorganic matrix and isolating a heavy hydrocarbon fraction comprising saturated beta-carotene. The methods utilize a hydrocarbon solvent to at least partially solubilize the extractible organics component. Among other factors, these processes are based on the discovery that the extractible organics is composed of a heavy hydrocarbon component containing saturated beta-carotene. The saturated beta-carotene product is a valuable commercial product. The presently disclosed processes are more environmentally benign, more economical, and more efficient in producing commercial products and in providing access to kerogen.Type: ApplicationFiled: May 25, 2012Publication date: November 28, 2013Applicant: CHEVRON U.S.A. INC.Inventors: Marcus Oliver Wigand, Saleh Elomari, Robert Martin Carlson
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Patent number: 8563486Abstract: A lubricating oil composition comprising: a lubricating base oil comprising a first lubricating base oil component having a urea adduct value of not greater than 4% by mass, a kinematic viscosity at 40° C. of 14-25 mm2/s and a viscosity index of 120 or higher and a second lubricating base oil component having a kinematic viscosity at 40° C. of less than 14 mm2/s, wherein the content of the first lubricating base oil component is 10-99% by mass and the content of the second lubricating base oil component is 1-50% by mass, based on the total amount of the lubricating base oil; and a viscosity index improver, the lubricating oil composition having a kinematic viscosity at 100° C. of 4-12 mm2/s and a viscosity index of 200-350.Type: GrantFiled: October 7, 2009Date of Patent: October 22, 2013Assignee: JX Nippon Oil & Energy CorporationInventors: Teppei Tsujimoto, Shigeki Matsui, Kazuo Tagawa
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Publication number: 20130264246Abstract: Provided are high viscosity high quality Group II lube base stocks with improved properties produced by an integrated hydrocracking and dewaxing process. In one form, the Group II lube base stock includes greater than or equal to 90 wt. % saturates, and less than 10 wt. % aromatics, and has an aromatic performance ratio between 1.0 and 5.0. Also provided are lubricant formulations including the high viscosity high quality Group II lube base stock.Type: ApplicationFiled: March 14, 2013Publication date: October 10, 2013Applicant: ExxonMobil Research and Engineering CompanyInventors: Gretchen L. Holtzer, Ajit B. Dandekar, Charles L. Baker, Bradley R. Fingland, Bryan E. Hagee, Cathleen Yung, Frank C. Wang, Eugenio Sanchez, Rugved Prakash Pathare