Lubricating Oils Patents (Class 208/18)
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Publication number: 20080073248Abstract: A heat transfer oil, comprising a base oil made from a waxy feed, wherein the base oil has a low pour point, low aromatics, and defined cycloparaffin composition. The heat transfer oil has high AIT and VI, and is an ISO viscosity grade. A process to prepare heat transfer oil, comprising: hydroisomerization of wax feed to make fraction(s) of base oil having low pour point, defined cycloparaffin composition, and high ratio of monocycloparaffins to multicycloparaffins; and blending the fractions with <0.2 wt % antifoam agent. A method to use heat transfer oil, comprising selecting heat transfer oil having high AIT and VI that is made with base oil having defined cycloparaffin composition, providing the heat transfer oil to mechanical system, and transferring heat from heat source to heat sink. Also, heat transfer oil comprising isomerized Fischer-Tropsch derived base oil with a low traction coefficient, and an antifoam agent.Type: ApplicationFiled: September 26, 2006Publication date: March 27, 2008Inventors: Ravindra Shah, John M. Rosenbaum, Nancy J. Bertrand
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Patent number: 7347928Abstract: A process to prepare a spindle oil, light machine oil and a medium machine oil base oil grade by: (a) performing a separate catalytic dewaxing on a spindle oil fraction, a light machine oil fraction and a medium machine oil fraction as obtained in a vacuum distillation of a bottoms fraction of a fuels hydrocracking process; (b) performing a separate hydrofinishing of the light and medium machine oil fractions obtained in step (a); (c) separating the low boiling compounds from the spindle oil, light machine oil and medium machine oil fractions as obtained in step (a) and (b) and obtaining the spindle oil, light machine oil and medium machine oil base oil grade; (d) wherein the vacuum distillation is performed by altematingly performing the distillation in two modes wherein the first mode (d1) the bottoms fraction is separated into a gas oil fraction, a spindle oil fraction, a medium machine oil fraction and a first rest fraction boiling between said spindle oil and medium machine oil fraction and in the seconType: GrantFiled: December 18, 2001Date of Patent: March 25, 2008Assignee: Shell Oil CompanyInventors: Johannes Van Beijnum, Arjen Peter Geukema, Kevin John Anthony Polder
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Publication number: 20080041762Abstract: A high solvency dispersive power (HSDP) crude oil is added to a blend of incompatible oils to proactively address the potential for fouling heat exchange equipment. The HSDP component dissolves asphaltene precipitates and maintains suspension of inorganic particulates before coking affects heat exchange surfaces. An HSDP oil is also flushed through heat exchange equipment to remove any deposits and/or precipitates on a regular maintenance schedule before coking can affect heat exchange surfaces.Type: ApplicationFiled: August 21, 2006Publication date: February 21, 2008Applicant: ExxonMobil Research and Engineering Company Law DepartmentInventors: Glen B. Brons, Chris A. Wright, George A. Lutz, Daniel P. Leta
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Patent number: 7332072Abstract: A process to prepare a waxy raffinate product by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch derived feed, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch derived feed have at least 30 carbon atoms; and, (b) isolating from the product of step (a) a waxy raffinate product having a T10 wt % boiling point of between 200° C. and 450° C. and a T90 wt % boiling point of between 400° C. and 650° C.Type: GrantFiled: March 5, 2002Date of Patent: February 19, 2008Assignee: Shell Oil CompanyInventors: Gilbert Robert Bernard Germaine, David John Wedlock
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Patent number: 7294253Abstract: This invention relates to process for producing middle distillates having good cold flow properties, such as the Cold Filter Plugging Point (CFPP) measured in accordance with the IP method 309, and a high Cetane number, as well as to a process for production of such distillates. More particularly, this invention relates to a process in which middle distillates are produced from a mainly paraffinic synthetic crude which is produced by the reaction of CO and H2, typically by the Fischer-Tropsch (FT) process. The middle distillates produced by the process of the invention are predominantly isoparaffinic, the isoparaffins being methyl, ethyl and/or propyl branched.Type: GrantFiled: November 12, 2003Date of Patent: November 13, 2007Assignee: Sasol Technology (Pty) Ltd.Inventors: Robert DeHaan, Luis Pablo Dancuart, Mark Jan Prins, Ewald Watermeyer DeWet
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Patent number: 7285206Abstract: A process to prepare a lubricating base oil and a gas oil by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch product, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2, and, wherein at least 30 wt % of compounds in the Fischer-Tropsch product have at least 30 carbon atoms; (b) separating the product of step (a) into one or more gas oil fractions, a base oil precursor fraction and a higher boiling fraction; and (c) performing a pour point reducing step to the base oil precursor fraction obtained in step (b).Type: GrantFiled: March 4, 2002Date of Patent: October 23, 2007Assignee: Shell Oil CompanyInventor: Gilbert Robert Bernard Germaine
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Patent number: 7282134Abstract: A process for manufacturing a lubricating base oil by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an is dimerized oil; and d) hydrofinishing said isomerized oil to produce a lubricating base oil having specific desired properties.Type: GrantFiled: December 23, 2003Date of Patent: October 16, 2007Assignee: Chevron USA, Inc.Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug
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Patent number: 7252753Abstract: Dielectric fluids comprising oil fractions derived from highly paraffinic wax are provided. Further provided are processes for making these dielectric fluids comprising oil fractions derived from highly paraffinic wax. The dielectric fluids are useful as insulating and cooling mediums in new and existing power and distribution electrical apparatus, such as transformers, regulators, circuit breakers, switchgear, underground electrical cables, and attendant equipment.Type: GrantFiled: December 1, 2004Date of Patent: August 7, 2007Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nadine L. Yenni, Joseph M. Pudlak
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Patent number: 7244350Abstract: A process to continuously prepare a hydrocarbon product having a specified desired sulphur content lower than 0.05 wt %, starting from at least two or more high-sulphur hydrocarbon feedstocks having a sulphur content of above 0.Type: GrantFiled: August 6, 2002Date of Patent: July 17, 2007Assignee: Shell Oil CompanyInventors: Bernard Martin, Jean-Luc Christian Rouby, Wouter Frederik Timmermans, Frederic Viel
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Patent number: 7241375Abstract: A heavy hydrocarbon composition with utility as a heavy hydrocarbon base stock comprising at least 95 wt % paraffin molecules, of which at least 90 wt % are isoparaffin, containing hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity, as measured by ASTM D-445, is above 8 cSt, has an initial boiling point of least 850° F. (454° C.) and an end boiling point of at least 1000° F. (538° C.), wherein the branching index (BI), as measured by the percentage of methyl hydrogens, and the branching proximity (CH2>4), as measured by the percentage of recurring methylene carbons which are four or more carbon atoms removed from an end group or branch, of said isoparaffinic hydrocarbon molecules, are such that: (a) BI?0.5(CH2>4)<15; and (b) BI+0.85(CH2>4)<45; as measured over the heavy hydrocarbon composition as a whole.Type: GrantFiled: August 29, 2003Date of Patent: July 10, 2007Assignee: ExxonMobil Research and Engineering CompanyInventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
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Patent number: 7217852Abstract: This invention relates to middle distillates having good cold flow properties, such as the Cold Filter Plugging Point (CFPP) measured in accordance with the IP method (309), and a high Cetane number, as well as to a process for production of such distillates. More particularly, this invention relates to middle distillates produced from a mainly paraffinic synthetic crude which is produced by the reaction of CO and H2, typically by the Fischer-Tropsch (FT) process. The middle distillates of the invention are predominantly isoparaffinic, the isoparaffins being methyl, ethyl and/or propyl branched. The invention also provides a diesel fuel composition including the middle distillates in accordance with the invention. A process for preparing the middle distillates is also included in the invention.Type: GrantFiled: September 17, 1999Date of Patent: May 15, 2007Assignee: Sasol Technology (PTY) Ltd.Inventors: Robert DeHaan, Luis Pablo Dancuart, Mark Jan Prins, Ewald Watermeyer DeWet
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Patent number: 7214307Abstract: A composition of white oil having a kinematic viscosity at 100° C. between about 1.5 cSt and 36 cSt, a viscosity index greater than an amount calculated by the equation: Viscosity Index=28×Ln(the Kinematic Viscosity at 100° C.)+105, less than 18 weight percent of molecules with cycloparaffin functionality, a pour point less than zero degrees C., and a Saybolt color of +20 or greater. Also, a composition of white oil having a kinematic viscosity at 100° C. between about 1.5 cSt and 36 cSt, a viscosity index greater than an amount calculated by the equation: Viscosity Index=28×Ln(the Kinematic Viscosity at 100° C.)+95, between 5 and less than 18 weight percent of molecules with cycloparaffin functionality, less than 1.2 weight percent molecules with multicycloparaffin functionality, a pour point less than zero degrees C., and a Saybolt color of +20 or greater.Type: GrantFiled: July 22, 2004Date of Patent: May 8, 2007Assignee: Chevron U.S.A. Inc.Inventors: Stephen J. Miller, Susan M. Abernathy, John M. Rosenbaum
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Patent number: 7195706Abstract: A process for manufacturing a finished lubricant by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an isomerized oil; and d) hydrofinishing said isomerized oil, whereby a lubricating base oil is produced having specific desired properties; and e) blending the lubricating base oil with at least one lubricant additive.Type: GrantFiled: December 23, 2003Date of Patent: March 27, 2007Assignee: Chevron U.S.A. Inc.Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug, James N. Ziemer, Robert J. Farina, Mark L. Sztenderowicz
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Patent number: 7144497Abstract: A process for producing a lubricating base oil blend which comprises (a) recovering a Fischer-Tropsch derived distillate fraction characterized by a kinematic viscosity of about 2 cSt or greater but less than 3 cSt at 100 degrees C.; and (b) blending the Fischer-Tropsch derived distillate fraction with a petroleum derived base oil selected from the group consisting of a Group I base oil, a Group II base oil, a Group III base oil, and a mixture of two or more of any of the foregoing conventional base oils in the proper proportion to produce a lubricating base oil blend characterized as having a viscosity of about 3 or greater; also the base oil blends, finished lubricants, and their use in internal combustion engines.Type: GrantFiled: November 20, 2002Date of Patent: December 5, 2006Assignee: Chevron U.S.A. Inc.Inventors: Brent K. Lok, David Kramer, John M. Rosenbaum, Joseph Pudlak
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Patent number: 7141157Abstract: A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with a Fischer-Tropsch derived bottoms fraction; lubricating base oil compositions having a viscosity between about 3 and about 10 cSt at 100 degrees C. and a TGA Noack volatility of less than about 45 weight percent; and finished lubricants using the aforesaid lubricating base oils.Type: GrantFiled: March 11, 2003Date of Patent: November 28, 2006Assignee: Chevron U.S.A. Inc.Inventors: John Rosenbaum, David Kramer, Joseph Pudlak
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Patent number: 7083713Abstract: A composition of lubricating base oil having a weight percent of all molecules with at least one aromatic function less than 0.30, a weight percent of all molecules with at least one cycloparaffin function greater than 10, and a ratio of weight percent of molecules with monocycloparaffins to weight percent of molecules with multicycloparaffins greater than 15.Type: GrantFiled: December 23, 2003Date of Patent: August 1, 2006Assignee: Chevron U.S.A. Inc.Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug
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Patent number: 7067049Abstract: The present invention relates to formulated lubricant oils derived from a highly paraffinic basestock. The lubricating oils of the present invention achieve the extremely stringent viscosity requirements of SAE “0W” crossgraded engine oils and demonstrate an excellent combination of low-temperature performance and biodegradability not achievable by other formulations derived from other classes of basestocks.Type: GrantFiled: February 4, 2000Date of Patent: June 27, 2006Assignee: Exxonmobil Oil CorporationInventors: David J. Baillargeon, Thomas R. Forbus, Jr., Kenneth R. Graziani, Gretchen R. Hall, Nancy M. Page, Richard F. Socha
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Patent number: 7045055Abstract: This invention is directed to a method of operating a wormgear drive at high energy efficiency comprising filling an oil reservoir with a wormgear lubricant comprising an isomerized Fischer-Tropsch derived distillate fraction having a low traction coefficient and operating the wormgear drive with the filled oil reservoir at an equilibrium temperature between 20 and 225 degrees C. This invention is also directed to a process for reducing the traction coefficient of a higher-traction coefficient lubricating base oil by blending it with an isomerized Fischer-Tropsch derived distillate fraction. This invention is also directed to a wormgear lubricant comprising an isomerized Fischer-Tropsch distillate fraction and between 2 and 50 weight percent thickener.Type: GrantFiled: April 29, 2004Date of Patent: May 16, 2006Assignee: Chevron U.S.A. Inc.Inventors: James N. Ziemer, Susan M. Abernathy, John M. Rosenbaum, Stephen J. Miller, Mark E. Okazaki
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Patent number: 7037955Abstract: Additives and methods for reducing or eliminating odor in oil based media. The additives comprise an essential oil, an essential oil component, or mixtures thereof.Type: GrantFiled: May 2, 2003Date of Patent: May 2, 2006Assignee: Odor Managements, Inc.Inventors: Charles Timcik, John Fergeus
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Patent number: 7015178Abstract: Disclosed is a lubricant base oil composition that comprises (a) from 80 to 98% by mass of a naphthenic synthetic lubricant base oil having a flash point of not lower than 140° C. and (b) from 2 to 20% by mass of an alcohol/fatty acid ester having a flash point of not lower than 150° C. of which the alcohol has a gem-type dimethyl structure, or comprises (a) from 85 to 99% by mass of a naphthenic synthetic lubricant base oil having a flash point of not lower than 140° C. and (c) from 1 to 15% by mass of a mineral oil having a kinematic viscosity at 40° C. of from 0.9 to 9.6 mm2/sec, a boiling point under normal pressure of from 150 to 400° C. and a % CA measured through ring analysis (in n-d-M process) of at most 10%. The lubricant base oil composition has a flash point of not lower than 150° C. and has a high traction coefficient at high temperatures, and its low-temperature flowability characteristic is good. The oil composition is favorable for traction drive fluid.Type: GrantFiled: May 24, 2002Date of Patent: March 21, 2006Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hidetoshi Koga, Hitoshi Hata, Toshiyuki Tsubouchi
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Patent number: 6872693Abstract: This invention relates to mineral oil based gear oils and transmission fluids which comprise a major amount of a mineral oil having an iodine number of less than 9 and where at least 55% of the saturates are aliphatic, and gear oil or transmission fluid additives. In one embodiment, the invention relates to a gear oil or transmission fluid composition comprising a major amount of lubricant basestock and at least one functional additive wherein a major amount of the lubricant basestock comprises a mineral oil having an iodine number of less than 9 and comprising at least 45% by weight of aliphatic saturates. These gear oils and transmission fluids have good viscosity and oxidation properties.Type: GrantFiled: May 24, 2000Date of Patent: March 29, 2005Assignee: The Lubrizol CorporationInventor: Robert W. Cain
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Patent number: 6872692Abstract: A synthetic lubricant base stock is provided having a kinematic viscosity at 100° C. of from 5 to about 300 cS and a VI greater than 100. The base stock comprises random co-oligomers of an alpha olefin or mixtures thereof and an olefinic substituted aromatic compound which co-oligomers are prepared in the presence of a Friedel-Crafts catalyst.Type: GrantFiled: September 10, 2002Date of Patent: March 29, 2005Assignee: ExxonMobil Research and Engineering CompanyInventors: Margaret May-Som Wu, Steven Edward Donnachie, James Thomas Carey, Walter David Vann, Norman Yang, Dilip Surana
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Patent number: 6841711Abstract: A process for making a lube base stock wherein an olefinic feedstock is contacted with an oligomerization catalyst in a catalytic distillation unit to produce a product having a higher number average molecular weight than the olefinic feedstock. That product is separated zone in the catalytic distillation unit into a light byproduct fraction and a heavy product fraction that includes hydrocarbons in a lube base stock range.Type: GrantFiled: January 11, 2001Date of Patent: January 11, 2005Assignee: Chevron U.S.A. Inc.Inventors: Russell R. Krug, Dennis J. O'Rear
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Patent number: 6833065Abstract: The invention provides methods for preparing a blended lube base oils comprising at least one highly paraffinic Fischer Tropsch lube base stocks and at least one base stock composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof. The use of base stocks composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof improves the yield of lube base oils from Fischer Tropsch facilities, as well as provides moderate improvements in physical properties including additive solubility. The invention provides processes for obtaining such blended lube base oils using the products of Fischer Tropsch processes.Type: GrantFiled: August 15, 2003Date of Patent: December 21, 2004Assignee: Chevron U.S.A. Inc.Inventor: Dennis J. O'Rear
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Patent number: 6821933Abstract: The invention relates to additives for improving the flowability of mineral oils, containing: A) 1-40 wt. % of at least one copolymer, which is oil-soluble and improves the cold flow properties of mineral oil, selected from A1) copolymers consisting of 80 to 96.5 mol % ethylene and 3.5-20 mol % vinyl esters of carboxylic acids with 1-20 C atoms and/or (meth)acrylic acid esters of alcohols with 1-8 C atoms, and A2) homopolymers or copolymers of esters, containing C10-C30 alkyl radicals, of ethylenically unsaturated carboxylic acids with up to 20 mol % of other olefinically unsaturated compounds, B) 20-80 wt. % of at least one poly-alpha-olefin with a molecular weight of 250-5000, derived from monoolefins with 3-5 C atoms, and C) 5-70 wt.Type: GrantFiled: December 13, 2002Date of Patent: November 23, 2004Assignee: Clariant International Ltd.Inventors: Michael Feustel, Matthias Krull, Hans-Jörg Oschmann
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Patent number: 6822126Abstract: Provided is a continuous process for converting waste or virgin plastics into lube oils. The plastic feed is maintained in a heater at preferred temperatures of 150° C.-350° C. The feed is continuously passed to a pyrolysis reactor preferably maintained at a temperature of 450° C.-700° C. and at atmospheric pressure. Relatively short residence times are employed. Optionally, the reactor effluent is processed in a hydrotreating unit. The effluent is fed to an isomerization dewaxing unit and fractionated to recover lube oil stocks. Preferably, the feed to the pyrolysis reactor can be a blend of waste plastic and waxy Fischer-Tropsch fractions.Type: GrantFiled: April 18, 2002Date of Patent: November 23, 2004Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller
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Patent number: 6803492Abstract: The invention relates to an additive for improving the cold-flow properties of crude and distillate oils, where the additive is obtainable by extraction of crude oil with supercritical gas.Type: GrantFiled: March 20, 2002Date of Patent: October 12, 2004Assignee: Clariant International Ltd.Inventors: Michael Feustel, Hans-Jörg Oschmann, Utha Kentschke
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Publication number: 20040178118Abstract: A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with a Fischer-Tropsch derived bottoms fraction; lubricating base oil compositions having a viscosity between about 3 and about 10 cSt at 100 degrees C. and a TGA Noack volatility of less than about 45 weight percent; and finished lubricants using the aforesaid lubricating base oils.Type: ApplicationFiled: March 11, 2003Publication date: September 16, 2004Inventors: John Rosenbaum, David Kramer, Joseph Pudlak
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Patent number: 6790386Abstract: A dielectric fluid comprises an isoparaffinic base oil and hydrogen donor compound. The base oil may be a hydroisomerized isoparaffinic oil, and the hydrogen donor may be a substituted, or partially saturated aromatic compound. The resulting dielectric fluid exhibits negative hydrogen gassing properties along with good oxidative stability and low temperature performance.Type: GrantFiled: April 2, 2002Date of Patent: September 14, 2004Assignee: Petro-CanadaInventors: Michael Fefer, Tomoki Ruo
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Patent number: 6787022Abstract: A process for the production of a winter diesel fuel from wax containing hydrocarbons produced by the Fischer-Tropsch hydrocarbon synthesis process. A 300° F.+ Fischer-Tropsch fraction is upgraded first by hydroisomerization followed by catalytic dewaxing resulting in a diesel fuel suitable for use as a winter diesel fuel having excellent cold flow properties and reduced emissions.Type: GrantFiled: May 2, 2000Date of Patent: September 7, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Paul Joseph Berlowitz, Daniel Francis Ryan, Robert Jay Wittenbrink, W. Berlin Genetti, Jack Wayne Johnson
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Publication number: 20040168955Abstract: The present invention relates to a process to increase extraction yields and improve dewaxing performance of a lube boiling range stream. More particularly, the present invention is a process to produce at least one base oil by contacting a light lube stream with a polar solvent in a solvent extraction zone, then mixing the resulting extract with a second, heavier lube stream, extracting the mixture with a polar solvent, and dewaxing the resultant raffinate.Type: ApplicationFiled: November 25, 2003Publication date: September 2, 2004Applicant: ExxonMobil Research and Engineering CompanyInventors: Heather A. Boucher Ashe, Ronald J. Taylor
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Publication number: 20040154957Abstract: This invention relates to lubricants comprising base stocks and base oils that exhibit an unexpected combination of high viscosity index (130 or greater) and a ratio of measured-to-theoretical high-shear/low-temperature viscosity at −30 C or lower and the methods of making them. Specifically, the present invention relates to novel high viscosity index, low-viscosity lubricants usable as wide-temperature lubricants, for example hyrdraulic oils, comprising novel low-viscosity base stocks, with improved performance in low-temperature viscosity, and methods to produce them.Type: ApplicationFiled: October 3, 2003Publication date: August 12, 2004Inventors: Angela J. Keeney, Eugenio Sanchez, Angela Stefana Galiano-Roth
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Publication number: 20040154958Abstract: This invention relates to base stocks and base oils that exhibit an unexpected combination of high viscosity index (130 or greater) and a ratio of measured-to-theoretical high-shear/low-temperature viscosity at −30 C. or lower and the methods of making them. Specifically, the present invention relates to low-viscosity base stocks and base oils as used in functional fluids. More specifically, the present invention relates to automatic transmission fluids showing surprising low temperature Brookfield viscosities and methods to produce them.Type: ApplicationFiled: October 3, 2003Publication date: August 12, 2004Inventors: Albert Gordon Alexander, Eugenio Sanchez, Kim Elizabeth Fyfe
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Patent number: 6773578Abstract: Lube base stocks and lube stock compositions, as well as a process for preparing lube base stocks and lube stock compositions, are disclosed. The lube oils preferably have a viscosity index above about 115. The process involves obtaining feedstocks that have a 95% point below 1150° F. and feedstocks that have 95% point above 1150° F. The feedstocks that have a 95% point below 1150° F. are catalytically dewaxed, and the feedstocks that have 95% point above 1150° F. are solvent dewaxed. The resulting products can optionally be blended, and the base stocks can be combined with various additives to form lube oil compositions. Hydrotreatment can optionally be performed on the lube base stocks to remove olefins, oxygenates and other impurities. In one embodiment, one or more of the fractions are obtained from Fischer-Tropsch synthesis.Type: GrantFiled: December 5, 2000Date of Patent: August 10, 2004Assignee: Chevron U.S.A. Inc.Inventors: Dennis J. O'Rear, Joseph A. Biscardi
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Patent number: 6774272Abstract: A process for converting a blend of plastic waste and a Fischer-Tropsch waxy fraction into high VI lube oils. A Fischer-Tropsch wax is separated into a 1000° F.+ fraction and a 1000° F.− fraction. The higher boiling fraction is combined with virgin or waste polyolefin and fed to a pyrolysis zone after being heated in a heating unit. The pyrolysis effluent is separated into at least a heavy fraction. Any light fraction recovered can be further processed into a feed for gasoline products. Any middle fraction recovered can be hydrotreated and isodewaxed to form diesel, diesel blending and jet fuel, or can be oligomerized, hydrotreated and isodewaxed to form high VI lubricating base oil. The heavy fraction is hydrotreated and isodewaxed to yield high VI lubricating base oil. The process can be conducted on a continuous basis.Type: GrantFiled: April 18, 2002Date of Patent: August 10, 2004Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller
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Publication number: 20040129603Abstract: This invention relates to base stocks and base oils that exhibit an unexpected combination of high viscosity index (130 or greater) and a ratio of measured-to-theoretical high-shear/low-temperature viscosity at −30C or lower and the methods of making them. Specifically, the present invention relates to low-volatility/low-viscosity lubricant base stocks, lubricant base stocks and base oils, formulated lubricant compositions or functional fluids comprising these base stocks and methods of making them. More particularly, this invention relates to lubricant compositions of low-temperature flow capability and low viscosity for passenger car motor lubricants of SAE 0W-XX grade (where XX=40 or lower), methods for optimizing fuel economy using the same, and methods or processes to produce them.Type: ApplicationFiled: October 3, 2003Publication date: July 8, 2004Inventors: Kim Elizabeth Fyfe, Eugenio Sanchez, David J. Baillargeon, James William Gleeson, Ian Alfred Cody, William John Murphy, Sylvain S. Hantzer, David W. Larkin, John E. Gallagher, Jeenok T. Kim
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Publication number: 20040118744Abstract: A lubricating base oil composition having at least 95 wt % saturates, of which saturates fraction between 10 and 30 wt % are cyclo-paraffins and the remainder being n- and iso-paraffins, having a viscosity index of above 120 and a pour point of below −15° C.Type: ApplicationFiled: January 9, 2004Publication date: June 24, 2004Inventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20040108245Abstract: The present invention relates to a process for converting wax with a heavy component to high quality lube basestocks using a unidimensional intermediate pore molecular sieve with near circular pore structures having an average diameter of 0.50 nm to 0.65 nm wherein the difference between the maximum diameter and the minimum is ≦0.05 nm followed by a molecular sieve Zeolite Beta catalyst. Both catalysts comprise one or more Group VIII metals. For example, a cascaded two-bed catalyst system consisting of a first bed Pt/ZSM-48 catalyst followed by a second bed Pt/Beta catalyst improves processing of heavy lubes.Type: ApplicationFiled: October 3, 2003Publication date: June 10, 2004Inventors: Zhaozhong Jiang, Randall D. Partridge
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Publication number: 20040104145Abstract: Process to prepare two or more base oil grades, which base oil grades having different kinematic viscosity's at 100° C. from a waxy paraffinic Fischer-Tropsch product having a content of non-cyclic iso-paraffins of more than 70 wt % by (a) obtaining from the waxy paraffinic Fischer-Tropsch product a distillate fraction having a viscosity corresponding to one of the desired base oil products, (b) performing a catalytic dewaxing step using the distillate fraction obtained in step (a) as feed, (c) separating the lower boiling compounds from the dewaxed product obtained in step (b) in order to obtain the desired base oil, and (d) repeating steps (a)-(c) for each base oil.Type: ApplicationFiled: September 4, 2003Publication date: June 3, 2004Inventor: Gilbert Robert Bernard Germaine
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Publication number: 20040094453Abstract: A process for producing a lubricating base oil blend which comprises (a) recovering a Fischer-Tropsch derived distillate fraction characterized by a kinematic viscosity of about 2 cSt or greater but less than 3 cSt at 100 degrees C.; and (b) blending the Fischer-Tropsch derived distillate fraction with a petroleum derived base oil selected from the group consisting of a Group I base oil, a Group II base oil, a Group III base oil, and a mixture of two or more of any of the foregoing conventional base oils in the proper proportion to produce a lubricating base oil blend characterized as having a viscosity of about 3 or greater; also the base oil blends, finished lubricants, and their use in internal combustion engines.Type: ApplicationFiled: November 20, 2002Publication date: May 20, 2004Inventors: Brent K. Lok, David Kramer, John M. Rosenbaum, Joseph Pudlak
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Publication number: 20040077505Abstract: A lubricant composition comprising a base oil and one or more additives wherein the lubricant composition has a kinematic viscosity at 100° C. of more than 5.6 cSt, a cold cranking simulated dynamic viscosity at −35° C. according to ASTM D 5293 of less than 62 centiPoise (cP) and a mini rotary viscosity test value of less than 60000 cP according to ASTM d 4684, wherein the base oil has been obtained from a waxy paraffinic Fischer-Tropsch synthesized hydrocarbons.Type: ApplicationFiled: August 13, 2003Publication date: April 22, 2004Inventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20040067856Abstract: A synthetic, isoparaffinic heavy hydrocarbon composition useful as a heavy lubricant base stock contains hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity is above 8 cSt and has respective initial and end boiling points of at least 850 and 1000° F. (454 and 538° C.).Type: ApplicationFiled: October 8, 2002Publication date: April 8, 2004Inventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
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Publication number: 20040065581Abstract: The present invention relates to a process for converting Fischer-Tropsch wax to high quality lube basestocks using a molecular sieve Beta catalyst followed by a unidimensional intermediate pore molecular sieve with near circular pore structures having an average diameter of 0.50 nm to 0.65 nm wherein the difference between the maximum diameter and the minimum is ≦0.05 nm. Both catalysts comprise one or more Group VIII metals. For example, a cascaded two-bed catalyst system consisting of a first bed Pt/Beta catalyst followed by a second bed Pt/ZSM-48 catalyst is highly selective for wax isomerization and lube hydrodewaxing with minimal gas formation.Type: ApplicationFiled: October 8, 2002Publication date: April 8, 2004Inventors: Zhaozhong Jiang, Terry Eugene Helton, Randall David Partridge, Larry E. Hoglen
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Patent number: 6713438Abstract: High performance engine oils and other liquid lubricants comprise a liquid lubricant basestock of low viscosity from 1.5 to 12 cSt (100C) with two dissolved polymer components of differing molecular weights. The basestock is preferably a single PAO or blend of PAOs with a co-basestock component which is preferably an ester or an alkylated aromatic of comparable viscosity. The lower molecular weight polymer is highly viscoelastic in character and is preferably an HVI-PAO; this component in the lubricant which provides unexpectedly high film thickness and unexpectedly good wear protection under conditions where the second, higher molecular weight polymer may lose some or all of its thickening power. The use of the highly viscoelastic low molecular weight polymer in combination with the higher molecular weight thickener enables the production of very widely cross-graded engine oils, especially oils with a low temperature grading of 0W or better.Type: GrantFiled: March 24, 1999Date of Patent: March 30, 2004Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Raymond J. Bergstra, Andrew Jackson, William L. Maxwell, G. James Johnston, Robert A. Pache
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Publication number: 20040055931Abstract: Process to prepare a spindle oil, light machine oil and a medium machine oil base oil grade by (a) performing a separate catalytic dewaxing on a spindle oil fraction, a light machine oil fraction and a medium machine oil fraction as obtained in a vacuum distillation of a bottoms fraction of a fuels hydrocracking process; (b) performing a separate hydrofinishing of the light and medium machine oil fractions obtained in step (a); (c) separating the low boiling compounds from the spindle oil, light machine oil and medium machine oil fractions as obtained in step (a) and (b) and obtaining the spindle oil, light machine oil and medium machine oil base oil grade; (e) wherein the vacuum distillation is performed by alternatingly performing the distillation in two modes wherein the first mode (d1) the bottoms fraction is separated into a gas oil fraction, a spindle oil fraction, a medium machine oil fraction and a first rest fraction boiling between said spindle oil and medium machine oil fraction and in the second mType: ApplicationFiled: June 18, 2003Publication date: March 25, 2004Inventors: Johannes Van Beijnum, Arjen Peter Geukema, Kevin John Anthony Polder
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Patent number: 6709569Abstract: Embodiments of the present invention are directed to methods for hydroprocessing Fischer-Tropsch products. The embodiments in particular are related to integrated methods for producing liquid fuels from a hydrocarbon stream provided by a Fischer-Tropsch synthesis process. The methods involves separating the Fischer-Tropsch products into a light fraction and a heavy fraction. The light fraction is pre-conditioned to remove contaminants such as CO2 prior to being subjected to hydroprocessing, either separately, or after having been being recombined with the heavy fraction. Any of the hydroprocessing steps may be accomplished in a single reactor.Type: GrantFiled: December 21, 2001Date of Patent: March 23, 2004Assignee: Chevron U.S.A. Inc.Inventors: Richard O. Moore, Jr., Paul D. Cambern
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Patent number: 6706936Abstract: A process for making a lube base stock wherein a highly paraffinic feedstock is dehydrogenated to produce an olefinic feedstock. That olefinic feedstock is contacted with an oligomerization catalyst in an oligomerization zone to produce a product having a higher number average molecular weight than the olefinic feedstock. The product is separated into a light byproduct fraction and a heavy product fraction. The heavy product fraction comprises a lube base stock.Type: GrantFiled: January 11, 2001Date of Patent: March 16, 2004Assignee: Chevron U.S.A. Inc.Inventors: Dennis J. O'Rear, Thomas V. Harris, Stephen J. Miller, Russell R. Krug, Brent K. Lok
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Publication number: 20040045868Abstract: A process to prepare a lubricating base oil and a gas oil byType: ApplicationFiled: September 4, 2003Publication date: March 11, 2004Inventor: Gilbert Robert Bernard Germaine
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Patent number: 6703353Abstract: A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with at least one additional Fischer-Tropsch derived distillate fraction having a viscosity of greater than 3.8 cSt at 100 degrees C.; lubricating base oil compositions having a viscosity between about 3 and about 10 cSt at 100 degrees C. and a TGA Noack volatility of less than about 35 weight percent; and finished lubricants using the aforesaid lubricating base oils.Type: GrantFiled: September 4, 2002Date of Patent: March 9, 2004Assignee: Chevron U.S.A. Inc.Inventors: Brent K. Lok, Russell R. Krug, John M. Rosenbaum, Joseph Pudlak, Stephen J. Miller
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Patent number: 6686511Abstract: A process for making a lube base stock wherein an olefinic feedstock is separated into a light olefin fraction and a medium olefin fraction. The light olefin fraction is contacted with a first oligomerization catalyst in a first oligomerization zone to produce a first product. Both the medium olefin fraction and the first product are contacted with a second oligomerization catalyst in a second oligomerization zone to produce a second product. The second product is separated into a light byproduct fraction and a heavy product fraction that includes hydrocarbons in the lube base stock range.Type: GrantFiled: January 11, 2001Date of Patent: February 3, 2004Assignee: Chevron U.S.A. Inc.Inventors: Stephen J. Miller, Dennis J. O'Rear, Thomas V. Harris, Russell R. Krug