Lubricating Oils Patents (Class 208/18)
  • Publication number: 20080073248
    Abstract: A heat transfer oil, comprising a base oil made from a waxy feed, wherein the base oil has a low pour point, low aromatics, and defined cycloparaffin composition. The heat transfer oil has high AIT and VI, and is an ISO viscosity grade. A process to prepare heat transfer oil, comprising: hydroisomerization of wax feed to make fraction(s) of base oil having low pour point, defined cycloparaffin composition, and high ratio of monocycloparaffins to multicycloparaffins; and blending the fractions with <0.2 wt % antifoam agent. A method to use heat transfer oil, comprising selecting heat transfer oil having high AIT and VI that is made with base oil having defined cycloparaffin composition, providing the heat transfer oil to mechanical system, and transferring heat from heat source to heat sink. Also, heat transfer oil comprising isomerized Fischer-Tropsch derived base oil with a low traction coefficient, and an antifoam agent.
    Type: Application
    Filed: September 26, 2006
    Publication date: March 27, 2008
    Inventors: Ravindra Shah, John M. Rosenbaum, Nancy J. Bertrand
  • Patent number: 7347928
    Abstract: A process to prepare a spindle oil, light machine oil and a medium machine oil base oil grade by: (a) performing a separate catalytic dewaxing on a spindle oil fraction, a light machine oil fraction and a medium machine oil fraction as obtained in a vacuum distillation of a bottoms fraction of a fuels hydrocracking process; (b) performing a separate hydrofinishing of the light and medium machine oil fractions obtained in step (a); (c) separating the low boiling compounds from the spindle oil, light machine oil and medium machine oil fractions as obtained in step (a) and (b) and obtaining the spindle oil, light machine oil and medium machine oil base oil grade; (d) wherein the vacuum distillation is performed by altematingly performing the distillation in two modes wherein the first mode (d1) the bottoms fraction is separated into a gas oil fraction, a spindle oil fraction, a medium machine oil fraction and a first rest fraction boiling between said spindle oil and medium machine oil fraction and in the secon
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: March 25, 2008
    Assignee: Shell Oil Company
    Inventors: Johannes Van Beijnum, Arjen Peter Geukema, Kevin John Anthony Polder
  • Publication number: 20080041762
    Abstract: A high solvency dispersive power (HSDP) crude oil is added to a blend of incompatible oils to proactively address the potential for fouling heat exchange equipment. The HSDP component dissolves asphaltene precipitates and maintains suspension of inorganic particulates before coking affects heat exchange surfaces. An HSDP oil is also flushed through heat exchange equipment to remove any deposits and/or precipitates on a regular maintenance schedule before coking can affect heat exchange surfaces.
    Type: Application
    Filed: August 21, 2006
    Publication date: February 21, 2008
    Applicant: ExxonMobil Research and Engineering Company Law Department
    Inventors: Glen B. Brons, Chris A. Wright, George A. Lutz, Daniel P. Leta
  • Patent number: 7332072
    Abstract: A process to prepare a waxy raffinate product by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch derived feed, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch derived feed have at least 30 carbon atoms; and, (b) isolating from the product of step (a) a waxy raffinate product having a T10 wt % boiling point of between 200° C. and 450° C. and a T90 wt % boiling point of between 400° C. and 650° C.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: February 19, 2008
    Assignee: Shell Oil Company
    Inventors: Gilbert Robert Bernard Germaine, David John Wedlock
  • Patent number: 7294253
    Abstract: This invention relates to process for producing middle distillates having good cold flow properties, such as the Cold Filter Plugging Point (CFPP) measured in accordance with the IP method 309, and a high Cetane number, as well as to a process for production of such distillates. More particularly, this invention relates to a process in which middle distillates are produced from a mainly paraffinic synthetic crude which is produced by the reaction of CO and H2, typically by the Fischer-Tropsch (FT) process. The middle distillates produced by the process of the invention are predominantly isoparaffinic, the isoparaffins being methyl, ethyl and/or propyl branched.
    Type: Grant
    Filed: November 12, 2003
    Date of Patent: November 13, 2007
    Assignee: Sasol Technology (Pty) Ltd.
    Inventors: Robert DeHaan, Luis Pablo Dancuart, Mark Jan Prins, Ewald Watermeyer DeWet
  • Patent number: 7285206
    Abstract: A process to prepare a lubricating base oil and a gas oil by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch product, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2, and, wherein at least 30 wt % of compounds in the Fischer-Tropsch product have at least 30 carbon atoms; (b) separating the product of step (a) into one or more gas oil fractions, a base oil precursor fraction and a higher boiling fraction; and (c) performing a pour point reducing step to the base oil precursor fraction obtained in step (b).
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: October 23, 2007
    Assignee: Shell Oil Company
    Inventor: Gilbert Robert Bernard Germaine
  • Patent number: 7282134
    Abstract: A process for manufacturing a lubricating base oil by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an is dimerized oil; and d) hydrofinishing said isomerized oil to produce a lubricating base oil having specific desired properties.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: October 16, 2007
    Assignee: Chevron USA, Inc.
    Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug
  • Patent number: 7252753
    Abstract: Dielectric fluids comprising oil fractions derived from highly paraffinic wax are provided. Further provided are processes for making these dielectric fluids comprising oil fractions derived from highly paraffinic wax. The dielectric fluids are useful as insulating and cooling mediums in new and existing power and distribution electrical apparatus, such as transformers, regulators, circuit breakers, switchgear, underground electrical cables, and attendant equipment.
    Type: Grant
    Filed: December 1, 2004
    Date of Patent: August 7, 2007
    Assignee: Chevron U.S.A. Inc.
    Inventors: John M. Rosenbaum, Nadine L. Yenni, Joseph M. Pudlak
  • Patent number: 7244350
    Abstract: A process to continuously prepare a hydrocarbon product having a specified desired sulphur content lower than 0.05 wt %, starting from at least two or more high-sulphur hydrocarbon feedstocks having a sulphur content of above 0.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: July 17, 2007
    Assignee: Shell Oil Company
    Inventors: Bernard Martin, Jean-Luc Christian Rouby, Wouter Frederik Timmermans, Frederic Viel
  • Patent number: 7241375
    Abstract: A heavy hydrocarbon composition with utility as a heavy hydrocarbon base stock comprising at least 95 wt % paraffin molecules, of which at least 90 wt % are isoparaffin, containing hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity, as measured by ASTM D-445, is above 8 cSt, has an initial boiling point of least 850° F. (454° C.) and an end boiling point of at least 1000° F. (538° C.), wherein the branching index (BI), as measured by the percentage of methyl hydrogens, and the branching proximity (CH2>4), as measured by the percentage of recurring methylene carbons which are four or more carbon atoms removed from an end group or branch, of said isoparaffinic hydrocarbon molecules, are such that: (a) BI?0.5(CH2>4)<15; and (b) BI+0.85(CH2>4)<45; as measured over the heavy hydrocarbon composition as a whole.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: July 10, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
  • Patent number: 7217852
    Abstract: This invention relates to middle distillates having good cold flow properties, such as the Cold Filter Plugging Point (CFPP) measured in accordance with the IP method (309), and a high Cetane number, as well as to a process for production of such distillates. More particularly, this invention relates to middle distillates produced from a mainly paraffinic synthetic crude which is produced by the reaction of CO and H2, typically by the Fischer-Tropsch (FT) process. The middle distillates of the invention are predominantly isoparaffinic, the isoparaffins being methyl, ethyl and/or propyl branched. The invention also provides a diesel fuel composition including the middle distillates in accordance with the invention. A process for preparing the middle distillates is also included in the invention.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: May 15, 2007
    Assignee: Sasol Technology (PTY) Ltd.
    Inventors: Robert DeHaan, Luis Pablo Dancuart, Mark Jan Prins, Ewald Watermeyer DeWet
  • Patent number: 7214307
    Abstract: A composition of white oil having a kinematic viscosity at 100° C. between about 1.5 cSt and 36 cSt, a viscosity index greater than an amount calculated by the equation: Viscosity Index=28×Ln(the Kinematic Viscosity at 100° C.)+105, less than 18 weight percent of molecules with cycloparaffin functionality, a pour point less than zero degrees C., and a Saybolt color of +20 or greater. Also, a composition of white oil having a kinematic viscosity at 100° C. between about 1.5 cSt and 36 cSt, a viscosity index greater than an amount calculated by the equation: Viscosity Index=28×Ln(the Kinematic Viscosity at 100° C.)+95, between 5 and less than 18 weight percent of molecules with cycloparaffin functionality, less than 1.2 weight percent molecules with multicycloparaffin functionality, a pour point less than zero degrees C., and a Saybolt color of +20 or greater.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: May 8, 2007
    Assignee: Chevron U.S.A. Inc.
    Inventors: Stephen J. Miller, Susan M. Abernathy, John M. Rosenbaum
  • Patent number: 7195706
    Abstract: A process for manufacturing a finished lubricant by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an isomerized oil; and d) hydrofinishing said isomerized oil, whereby a lubricating base oil is produced having specific desired properties; and e) blending the lubricating base oil with at least one lubricant additive.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: March 27, 2007
    Assignee: Chevron U.S.A. Inc.
    Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug, James N. Ziemer, Robert J. Farina, Mark L. Sztenderowicz
  • Patent number: 7144497
    Abstract: A process for producing a lubricating base oil blend which comprises (a) recovering a Fischer-Tropsch derived distillate fraction characterized by a kinematic viscosity of about 2 cSt or greater but less than 3 cSt at 100 degrees C.; and (b) blending the Fischer-Tropsch derived distillate fraction with a petroleum derived base oil selected from the group consisting of a Group I base oil, a Group II base oil, a Group III base oil, and a mixture of two or more of any of the foregoing conventional base oils in the proper proportion to produce a lubricating base oil blend characterized as having a viscosity of about 3 or greater; also the base oil blends, finished lubricants, and their use in internal combustion engines.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: December 5, 2006
    Assignee: Chevron U.S.A. Inc.
    Inventors: Brent K. Lok, David Kramer, John M. Rosenbaum, Joseph Pudlak
  • Patent number: 7141157
    Abstract: A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with a Fischer-Tropsch derived bottoms fraction; lubricating base oil compositions having a viscosity between about 3 and about 10 cSt at 100 degrees C. and a TGA Noack volatility of less than about 45 weight percent; and finished lubricants using the aforesaid lubricating base oils.
    Type: Grant
    Filed: March 11, 2003
    Date of Patent: November 28, 2006
    Assignee: Chevron U.S.A. Inc.
    Inventors: John Rosenbaum, David Kramer, Joseph Pudlak
  • Patent number: 7083713
    Abstract: A composition of lubricating base oil having a weight percent of all molecules with at least one aromatic function less than 0.30, a weight percent of all molecules with at least one cycloparaffin function greater than 10, and a ratio of weight percent of molecules with monocycloparaffins to weight percent of molecules with multicycloparaffins greater than 15.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: August 1, 2006
    Assignee: Chevron U.S.A. Inc.
    Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug
  • Patent number: 7067049
    Abstract: The present invention relates to formulated lubricant oils derived from a highly paraffinic basestock. The lubricating oils of the present invention achieve the extremely stringent viscosity requirements of SAE “0W” crossgraded engine oils and demonstrate an excellent combination of low-temperature performance and biodegradability not achievable by other formulations derived from other classes of basestocks.
    Type: Grant
    Filed: February 4, 2000
    Date of Patent: June 27, 2006
    Assignee: Exxonmobil Oil Corporation
    Inventors: David J. Baillargeon, Thomas R. Forbus, Jr., Kenneth R. Graziani, Gretchen R. Hall, Nancy M. Page, Richard F. Socha
  • Patent number: 7045055
    Abstract: This invention is directed to a method of operating a wormgear drive at high energy efficiency comprising filling an oil reservoir with a wormgear lubricant comprising an isomerized Fischer-Tropsch derived distillate fraction having a low traction coefficient and operating the wormgear drive with the filled oil reservoir at an equilibrium temperature between 20 and 225 degrees C. This invention is also directed to a process for reducing the traction coefficient of a higher-traction coefficient lubricating base oil by blending it with an isomerized Fischer-Tropsch derived distillate fraction. This invention is also directed to a wormgear lubricant comprising an isomerized Fischer-Tropsch distillate fraction and between 2 and 50 weight percent thickener.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: May 16, 2006
    Assignee: Chevron U.S.A. Inc.
    Inventors: James N. Ziemer, Susan M. Abernathy, John M. Rosenbaum, Stephen J. Miller, Mark E. Okazaki
  • Patent number: 7037955
    Abstract: Additives and methods for reducing or eliminating odor in oil based media. The additives comprise an essential oil, an essential oil component, or mixtures thereof.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: May 2, 2006
    Assignee: Odor Managements, Inc.
    Inventors: Charles Timcik, John Fergeus
  • Patent number: 7015178
    Abstract: Disclosed is a lubricant base oil composition that comprises (a) from 80 to 98% by mass of a naphthenic synthetic lubricant base oil having a flash point of not lower than 140° C. and (b) from 2 to 20% by mass of an alcohol/fatty acid ester having a flash point of not lower than 150° C. of which the alcohol has a gem-type dimethyl structure, or comprises (a) from 85 to 99% by mass of a naphthenic synthetic lubricant base oil having a flash point of not lower than 140° C. and (c) from 1 to 15% by mass of a mineral oil having a kinematic viscosity at 40° C. of from 0.9 to 9.6 mm2/sec, a boiling point under normal pressure of from 150 to 400° C. and a % CA measured through ring analysis (in n-d-M process) of at most 10%. The lubricant base oil composition has a flash point of not lower than 150° C. and has a high traction coefficient at high temperatures, and its low-temperature flowability characteristic is good. The oil composition is favorable for traction drive fluid.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: March 21, 2006
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Hidetoshi Koga, Hitoshi Hata, Toshiyuki Tsubouchi
  • Patent number: 6872693
    Abstract: This invention relates to mineral oil based gear oils and transmission fluids which comprise a major amount of a mineral oil having an iodine number of less than 9 and where at least 55% of the saturates are aliphatic, and gear oil or transmission fluid additives. In one embodiment, the invention relates to a gear oil or transmission fluid composition comprising a major amount of lubricant basestock and at least one functional additive wherein a major amount of the lubricant basestock comprises a mineral oil having an iodine number of less than 9 and comprising at least 45% by weight of aliphatic saturates. These gear oils and transmission fluids have good viscosity and oxidation properties.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: March 29, 2005
    Assignee: The Lubrizol Corporation
    Inventor: Robert W. Cain
  • Patent number: 6872692
    Abstract: A synthetic lubricant base stock is provided having a kinematic viscosity at 100° C. of from 5 to about 300 cS and a VI greater than 100. The base stock comprises random co-oligomers of an alpha olefin or mixtures thereof and an olefinic substituted aromatic compound which co-oligomers are prepared in the presence of a Friedel-Crafts catalyst.
    Type: Grant
    Filed: September 10, 2002
    Date of Patent: March 29, 2005
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Margaret May-Som Wu, Steven Edward Donnachie, James Thomas Carey, Walter David Vann, Norman Yang, Dilip Surana
  • Patent number: 6841711
    Abstract: A process for making a lube base stock wherein an olefinic feedstock is contacted with an oligomerization catalyst in a catalytic distillation unit to produce a product having a higher number average molecular weight than the olefinic feedstock. That product is separated zone in the catalytic distillation unit into a light byproduct fraction and a heavy product fraction that includes hydrocarbons in a lube base stock range.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: January 11, 2005
    Assignee: Chevron U.S.A. Inc.
    Inventors: Russell R. Krug, Dennis J. O'Rear
  • Patent number: 6833065
    Abstract: The invention provides methods for preparing a blended lube base oils comprising at least one highly paraffinic Fischer Tropsch lube base stocks and at least one base stock composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof. The use of base stocks composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof improves the yield of lube base oils from Fischer Tropsch facilities, as well as provides moderate improvements in physical properties including additive solubility. The invention provides processes for obtaining such blended lube base oils using the products of Fischer Tropsch processes.
    Type: Grant
    Filed: August 15, 2003
    Date of Patent: December 21, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventor: Dennis J. O'Rear
  • Patent number: 6821933
    Abstract: The invention relates to additives for improving the flowability of mineral oils, containing: A) 1-40 wt. % of at least one copolymer, which is oil-soluble and improves the cold flow properties of mineral oil, selected from A1) copolymers consisting of 80 to 96.5 mol % ethylene and 3.5-20 mol % vinyl esters of carboxylic acids with 1-20 C atoms and/or (meth)acrylic acid esters of alcohols with 1-8 C atoms, and A2) homopolymers or copolymers of esters, containing C10-C30 alkyl radicals, of ethylenically unsaturated carboxylic acids with up to 20 mol % of other olefinically unsaturated compounds, B) 20-80 wt. % of at least one poly-alpha-olefin with a molecular weight of 250-5000, derived from monoolefins with 3-5 C atoms, and C) 5-70 wt.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: November 23, 2004
    Assignee: Clariant International Ltd.
    Inventors: Michael Feustel, Matthias Krull, Hans-Jörg Oschmann
  • Patent number: 6822126
    Abstract: Provided is a continuous process for converting waste or virgin plastics into lube oils. The plastic feed is maintained in a heater at preferred temperatures of 150° C.-350° C. The feed is continuously passed to a pyrolysis reactor preferably maintained at a temperature of 450° C.-700° C. and at atmospheric pressure. Relatively short residence times are employed. Optionally, the reactor effluent is processed in a hydrotreating unit. The effluent is fed to an isomerization dewaxing unit and fractionated to recover lube oil stocks. Preferably, the feed to the pyrolysis reactor can be a blend of waste plastic and waxy Fischer-Tropsch fractions.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: November 23, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen J. Miller
  • Patent number: 6803492
    Abstract: The invention relates to an additive for improving the cold-flow properties of crude and distillate oils, where the additive is obtainable by extraction of crude oil with supercritical gas.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: October 12, 2004
    Assignee: Clariant International Ltd.
    Inventors: Michael Feustel, Hans-Jörg Oschmann, Utha Kentschke
  • Publication number: 20040178118
    Abstract: A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with a Fischer-Tropsch derived bottoms fraction; lubricating base oil compositions having a viscosity between about 3 and about 10 cSt at 100 degrees C. and a TGA Noack volatility of less than about 45 weight percent; and finished lubricants using the aforesaid lubricating base oils.
    Type: Application
    Filed: March 11, 2003
    Publication date: September 16, 2004
    Inventors: John Rosenbaum, David Kramer, Joseph Pudlak
  • Patent number: 6790386
    Abstract: A dielectric fluid comprises an isoparaffinic base oil and hydrogen donor compound. The base oil may be a hydroisomerized isoparaffinic oil, and the hydrogen donor may be a substituted, or partially saturated aromatic compound. The resulting dielectric fluid exhibits negative hydrogen gassing properties along with good oxidative stability and low temperature performance.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: September 14, 2004
    Assignee: Petro-Canada
    Inventors: Michael Fefer, Tomoki Ruo
  • Patent number: 6787022
    Abstract: A process for the production of a winter diesel fuel from wax containing hydrocarbons produced by the Fischer-Tropsch hydrocarbon synthesis process. A 300° F.+ Fischer-Tropsch fraction is upgraded first by hydroisomerization followed by catalytic dewaxing resulting in a diesel fuel suitable for use as a winter diesel fuel having excellent cold flow properties and reduced emissions.
    Type: Grant
    Filed: May 2, 2000
    Date of Patent: September 7, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Paul Joseph Berlowitz, Daniel Francis Ryan, Robert Jay Wittenbrink, W. Berlin Genetti, Jack Wayne Johnson
  • Publication number: 20040168955
    Abstract: The present invention relates to a process to increase extraction yields and improve dewaxing performance of a lube boiling range stream. More particularly, the present invention is a process to produce at least one base oil by contacting a light lube stream with a polar solvent in a solvent extraction zone, then mixing the resulting extract with a second, heavier lube stream, extracting the mixture with a polar solvent, and dewaxing the resultant raffinate.
    Type: Application
    Filed: November 25, 2003
    Publication date: September 2, 2004
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Heather A. Boucher Ashe, Ronald J. Taylor
  • Publication number: 20040154957
    Abstract: This invention relates to lubricants comprising base stocks and base oils that exhibit an unexpected combination of high viscosity index (130 or greater) and a ratio of measured-to-theoretical high-shear/low-temperature viscosity at −30 C or lower and the methods of making them. Specifically, the present invention relates to novel high viscosity index, low-viscosity lubricants usable as wide-temperature lubricants, for example hyrdraulic oils, comprising novel low-viscosity base stocks, with improved performance in low-temperature viscosity, and methods to produce them.
    Type: Application
    Filed: October 3, 2003
    Publication date: August 12, 2004
    Inventors: Angela J. Keeney, Eugenio Sanchez, Angela Stefana Galiano-Roth
  • Publication number: 20040154958
    Abstract: This invention relates to base stocks and base oils that exhibit an unexpected combination of high viscosity index (130 or greater) and a ratio of measured-to-theoretical high-shear/low-temperature viscosity at −30 C. or lower and the methods of making them. Specifically, the present invention relates to low-viscosity base stocks and base oils as used in functional fluids. More specifically, the present invention relates to automatic transmission fluids showing surprising low temperature Brookfield viscosities and methods to produce them.
    Type: Application
    Filed: October 3, 2003
    Publication date: August 12, 2004
    Inventors: Albert Gordon Alexander, Eugenio Sanchez, Kim Elizabeth Fyfe
  • Patent number: 6773578
    Abstract: Lube base stocks and lube stock compositions, as well as a process for preparing lube base stocks and lube stock compositions, are disclosed. The lube oils preferably have a viscosity index above about 115. The process involves obtaining feedstocks that have a 95% point below 1150° F. and feedstocks that have 95% point above 1150° F. The feedstocks that have a 95% point below 1150° F. are catalytically dewaxed, and the feedstocks that have 95% point above 1150° F. are solvent dewaxed. The resulting products can optionally be blended, and the base stocks can be combined with various additives to form lube oil compositions. Hydrotreatment can optionally be performed on the lube base stocks to remove olefins, oxygenates and other impurities. In one embodiment, one or more of the fractions are obtained from Fischer-Tropsch synthesis.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: August 10, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventors: Dennis J. O'Rear, Joseph A. Biscardi
  • Patent number: 6774272
    Abstract: A process for converting a blend of plastic waste and a Fischer-Tropsch waxy fraction into high VI lube oils. A Fischer-Tropsch wax is separated into a 1000° F.+ fraction and a 1000° F.− fraction. The higher boiling fraction is combined with virgin or waste polyolefin and fed to a pyrolysis zone after being heated in a heating unit. The pyrolysis effluent is separated into at least a heavy fraction. Any light fraction recovered can be further processed into a feed for gasoline products. Any middle fraction recovered can be hydrotreated and isodewaxed to form diesel, diesel blending and jet fuel, or can be oligomerized, hydrotreated and isodewaxed to form high VI lubricating base oil. The heavy fraction is hydrotreated and isodewaxed to yield high VI lubricating base oil. The process can be conducted on a continuous basis.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: August 10, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen J. Miller
  • Publication number: 20040129603
    Abstract: This invention relates to base stocks and base oils that exhibit an unexpected combination of high viscosity index (130 or greater) and a ratio of measured-to-theoretical high-shear/low-temperature viscosity at −30C or lower and the methods of making them. Specifically, the present invention relates to low-volatility/low-viscosity lubricant base stocks, lubricant base stocks and base oils, formulated lubricant compositions or functional fluids comprising these base stocks and methods of making them. More particularly, this invention relates to lubricant compositions of low-temperature flow capability and low viscosity for passenger car motor lubricants of SAE 0W-XX grade (where XX=40 or lower), methods for optimizing fuel economy using the same, and methods or processes to produce them.
    Type: Application
    Filed: October 3, 2003
    Publication date: July 8, 2004
    Inventors: Kim Elizabeth Fyfe, Eugenio Sanchez, David J. Baillargeon, James William Gleeson, Ian Alfred Cody, William John Murphy, Sylvain S. Hantzer, David W. Larkin, John E. Gallagher, Jeenok T. Kim
  • Publication number: 20040118744
    Abstract: A lubricating base oil composition having at least 95 wt % saturates, of which saturates fraction between 10 and 30 wt % are cyclo-paraffins and the remainder being n- and iso-paraffins, having a viscosity index of above 120 and a pour point of below −15° C.
    Type: Application
    Filed: January 9, 2004
    Publication date: June 24, 2004
    Inventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
  • Publication number: 20040108245
    Abstract: The present invention relates to a process for converting wax with a heavy component to high quality lube basestocks using a unidimensional intermediate pore molecular sieve with near circular pore structures having an average diameter of 0.50 nm to 0.65 nm wherein the difference between the maximum diameter and the minimum is ≦0.05 nm followed by a molecular sieve Zeolite Beta catalyst. Both catalysts comprise one or more Group VIII metals. For example, a cascaded two-bed catalyst system consisting of a first bed Pt/ZSM-48 catalyst followed by a second bed Pt/Beta catalyst improves processing of heavy lubes.
    Type: Application
    Filed: October 3, 2003
    Publication date: June 10, 2004
    Inventors: Zhaozhong Jiang, Randall D. Partridge
  • Publication number: 20040104145
    Abstract: Process to prepare two or more base oil grades, which base oil grades having different kinematic viscosity's at 100° C. from a waxy paraffinic Fischer-Tropsch product having a content of non-cyclic iso-paraffins of more than 70 wt % by (a) obtaining from the waxy paraffinic Fischer-Tropsch product a distillate fraction having a viscosity corresponding to one of the desired base oil products, (b) performing a catalytic dewaxing step using the distillate fraction obtained in step (a) as feed, (c) separating the lower boiling compounds from the dewaxed product obtained in step (b) in order to obtain the desired base oil, and (d) repeating steps (a)-(c) for each base oil.
    Type: Application
    Filed: September 4, 2003
    Publication date: June 3, 2004
    Inventor: Gilbert Robert Bernard Germaine
  • Publication number: 20040094453
    Abstract: A process for producing a lubricating base oil blend which comprises (a) recovering a Fischer-Tropsch derived distillate fraction characterized by a kinematic viscosity of about 2 cSt or greater but less than 3 cSt at 100 degrees C.; and (b) blending the Fischer-Tropsch derived distillate fraction with a petroleum derived base oil selected from the group consisting of a Group I base oil, a Group II base oil, a Group III base oil, and a mixture of two or more of any of the foregoing conventional base oils in the proper proportion to produce a lubricating base oil blend characterized as having a viscosity of about 3 or greater; also the base oil blends, finished lubricants, and their use in internal combustion engines.
    Type: Application
    Filed: November 20, 2002
    Publication date: May 20, 2004
    Inventors: Brent K. Lok, David Kramer, John M. Rosenbaum, Joseph Pudlak
  • Publication number: 20040077505
    Abstract: A lubricant composition comprising a base oil and one or more additives wherein the lubricant composition has a kinematic viscosity at 100° C. of more than 5.6 cSt, a cold cranking simulated dynamic viscosity at −35° C. according to ASTM D 5293 of less than 62 centiPoise (cP) and a mini rotary viscosity test value of less than 60000 cP according to ASTM d 4684, wherein the base oil has been obtained from a waxy paraffinic Fischer-Tropsch synthesized hydrocarbons.
    Type: Application
    Filed: August 13, 2003
    Publication date: April 22, 2004
    Inventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
  • Publication number: 20040067856
    Abstract: A synthetic, isoparaffinic heavy hydrocarbon composition useful as a heavy lubricant base stock contains hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity is above 8 cSt and has respective initial and end boiling points of at least 850 and 1000° F. (454 and 538° C.).
    Type: Application
    Filed: October 8, 2002
    Publication date: April 8, 2004
    Inventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
  • Publication number: 20040065581
    Abstract: The present invention relates to a process for converting Fischer-Tropsch wax to high quality lube basestocks using a molecular sieve Beta catalyst followed by a unidimensional intermediate pore molecular sieve with near circular pore structures having an average diameter of 0.50 nm to 0.65 nm wherein the difference between the maximum diameter and the minimum is ≦0.05 nm. Both catalysts comprise one or more Group VIII metals. For example, a cascaded two-bed catalyst system consisting of a first bed Pt/Beta catalyst followed by a second bed Pt/ZSM-48 catalyst is highly selective for wax isomerization and lube hydrodewaxing with minimal gas formation.
    Type: Application
    Filed: October 8, 2002
    Publication date: April 8, 2004
    Inventors: Zhaozhong Jiang, Terry Eugene Helton, Randall David Partridge, Larry E. Hoglen
  • Patent number: 6713438
    Abstract: High performance engine oils and other liquid lubricants comprise a liquid lubricant basestock of low viscosity from 1.5 to 12 cSt (100C) with two dissolved polymer components of differing molecular weights. The basestock is preferably a single PAO or blend of PAOs with a co-basestock component which is preferably an ester or an alkylated aromatic of comparable viscosity. The lower molecular weight polymer is highly viscoelastic in character and is preferably an HVI-PAO; this component in the lubricant which provides unexpectedly high film thickness and unexpectedly good wear protection under conditions where the second, higher molecular weight polymer may lose some or all of its thickening power. The use of the highly viscoelastic low molecular weight polymer in combination with the higher molecular weight thickener enables the production of very widely cross-graded engine oils, especially oils with a low temperature grading of 0W or better.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: March 30, 2004
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Raymond J. Bergstra, Andrew Jackson, William L. Maxwell, G. James Johnston, Robert A. Pache
  • Publication number: 20040055931
    Abstract: Process to prepare a spindle oil, light machine oil and a medium machine oil base oil grade by (a) performing a separate catalytic dewaxing on a spindle oil fraction, a light machine oil fraction and a medium machine oil fraction as obtained in a vacuum distillation of a bottoms fraction of a fuels hydrocracking process; (b) performing a separate hydrofinishing of the light and medium machine oil fractions obtained in step (a); (c) separating the low boiling compounds from the spindle oil, light machine oil and medium machine oil fractions as obtained in step (a) and (b) and obtaining the spindle oil, light machine oil and medium machine oil base oil grade; (e) wherein the vacuum distillation is performed by alternatingly performing the distillation in two modes wherein the first mode (d1) the bottoms fraction is separated into a gas oil fraction, a spindle oil fraction, a medium machine oil fraction and a first rest fraction boiling between said spindle oil and medium machine oil fraction and in the second m
    Type: Application
    Filed: June 18, 2003
    Publication date: March 25, 2004
    Inventors: Johannes Van Beijnum, Arjen Peter Geukema, Kevin John Anthony Polder
  • Patent number: 6709569
    Abstract: Embodiments of the present invention are directed to methods for hydroprocessing Fischer-Tropsch products. The embodiments in particular are related to integrated methods for producing liquid fuels from a hydrocarbon stream provided by a Fischer-Tropsch synthesis process. The methods involves separating the Fischer-Tropsch products into a light fraction and a heavy fraction. The light fraction is pre-conditioned to remove contaminants such as CO2 prior to being subjected to hydroprocessing, either separately, or after having been being recombined with the heavy fraction. Any of the hydroprocessing steps may be accomplished in a single reactor.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: March 23, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventors: Richard O. Moore, Jr., Paul D. Cambern
  • Patent number: 6706936
    Abstract: A process for making a lube base stock wherein a highly paraffinic feedstock is dehydrogenated to produce an olefinic feedstock. That olefinic feedstock is contacted with an oligomerization catalyst in an oligomerization zone to produce a product having a higher number average molecular weight than the olefinic feedstock. The product is separated into a light byproduct fraction and a heavy product fraction. The heavy product fraction comprises a lube base stock.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: March 16, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventors: Dennis J. O'Rear, Thomas V. Harris, Stephen J. Miller, Russell R. Krug, Brent K. Lok
  • Publication number: 20040045868
    Abstract: A process to prepare a lubricating base oil and a gas oil by
    Type: Application
    Filed: September 4, 2003
    Publication date: March 11, 2004
    Inventor: Gilbert Robert Bernard Germaine
  • Patent number: 6703353
    Abstract: A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with at least one additional Fischer-Tropsch derived distillate fraction having a viscosity of greater than 3.8 cSt at 100 degrees C.; lubricating base oil compositions having a viscosity between about 3 and about 10 cSt at 100 degrees C. and a TGA Noack volatility of less than about 35 weight percent; and finished lubricants using the aforesaid lubricating base oils.
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: March 9, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventors: Brent K. Lok, Russell R. Krug, John M. Rosenbaum, Joseph Pudlak, Stephen J. Miller
  • Patent number: 6686511
    Abstract: A process for making a lube base stock wherein an olefinic feedstock is separated into a light olefin fraction and a medium olefin fraction. The light olefin fraction is contacted with a first oligomerization catalyst in a first oligomerization zone to produce a first product. Both the medium olefin fraction and the first product are contacted with a second oligomerization catalyst in a second oligomerization zone to produce a second product. The second product is separated into a light byproduct fraction and a heavy product fraction that includes hydrocarbons in the lube base stock range.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: February 3, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventors: Stephen J. Miller, Dennis J. O'Rear, Thomas V. Harris, Russell R. Krug