Admixtures Patents (Class 208/19)
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Patent number: 7972496Abstract: The present invention is related to a process oil using as a raw material a deasphalted oil obtained by deasphalting a vacuum residual oil of a crude oil and a manufacturing method of the process oil, the process oil having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (b) a viscosity (100° C.) of 40 to 70 mm2/s; (c) an aniline point of 85 to 100° C.; (d) a flash point of 250° C. or higher; (e) an aromatic hydrocarbon content of 40 to 55 mass %; and (f) a polar substance content of 10 to 15 mass %. The present invention is also related to a process oil and a manufacturing method of the process oil, the process oil obtained by mixing: an extract obtained by deasphalting and solvent-extracting a vacuum residual oil of a crude oil; and a lubricant base oil having a polycyclic aromatics (PCA) content of less than 3 mass %, and having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (i) a viscosity (100° C.Type: GrantFiled: May 29, 2006Date of Patent: July 5, 2011Assignee: Idemitsu Kosan Co., Ltd.Inventors: Meishi Tanaka, Masashi Nakamura, Kazuhiro Teshima, Akihito Abe, Masami Takasaki
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Patent number: 7956018Abstract: A lubricant composition includes a base oil having a consecutive number of carbon atoms and a viscosity index greater than a Viscosity Index Factor calculated by the following equation: 28×Ln(Kinematic Viscosity at 100° C.)+95. The lubricant composition also includes greater than 15 weight % detergent inhibitor (DI) additive package. The lubricant composition has a dynamic viscosity at ?35° C. of less than 6200 mPa·s, a Mini-Rotary Viscosity (MRV) at ?40° C. of less than 60,000 mPa·s, and a Cold Cranking Simulator (CCS) Viscosity at ?35° C. of less than 6200 mPa·s.Type: GrantFiled: December 10, 2007Date of Patent: June 7, 2011Assignee: Chevron U.S.A. Inc.Inventor: James A. McGeehan
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Patent number: 7951340Abstract: Atmospheric and/or vacuum resid fractions of a high solvency dispersive power (HSDP) crude oil are added to a blend of crude oil to prevent fouling of crude oil refinery equipment and to perform on-line cleaning of fouled refinery equipment. The HSDP resid fractions dissolve asphaltene precipitates and maintain suspension of inorganic particulates before coking affects heat exchange surfaces.Type: GrantFiled: October 12, 2010Date of Patent: May 31, 2011Assignee: ExxonMobil Research & Engineering CompanyInventors: Glen B. Brons, Chris A. Wright, George A. Lutz, Mark A. Greaney
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Publication number: 20110114537Abstract: A lubricating oil composition having a wide variety of uses consists of a dearomatized hydrocarbon distillate (petroleum), a post lubricant petroleum hydrocarbon, and white mineral oil. In one embodiment, the dearomatized hydrocarbon distillate is present in an amount from 15 to 25%, the post lubricant petroleum hydrocarbon is present in an amount from 5 to 15%, and the balance is the white mineral oil.Type: ApplicationFiled: November 18, 2009Publication date: May 19, 2011Applicant: LIQUIFIXInventor: D. Matthew Lacerenza
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Patent number: 7922892Abstract: A method for improving the lubricating properties of a distillate base oil characterized by a pour point of 0 degrees C. or less and a boiling range having the 10 percent point falling between about 625 degrees F. and about 790 degrees F. and the 90 percent point falling between about 725 degrees F. and about 950 degrees F., the method comprises blending with said distillate base oil a sufficient amount of a pour point depressing base oil blending component to reduce the pour point of the resulting base oil blend at least 3 degrees C. below the pour point of the distillate base oil, wherein the pour point depressing base oil blending component is an isomerized Fischer-Tropsch derived bottoms product having a pour point that is at least 3 degrees C. higher than the pour point of the distillate base oil.Type: GrantFiled: November 21, 2005Date of Patent: April 12, 2011Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller
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High-solvency-dispersive-power (HSDP) crude oil blending for fouling mitigation and on-line cleaning
Patent number: 7919058Abstract: A high solvency dispersive power (HSDP) crude oil is added to a blend of incompatible and/or near-incompatible oils to proactively address the potential for fouling heat exchange equipment. The HSDP component dissolves asphaltene precipitates and maintains suspension of inorganic particulates before coking affects heat exchange surfaces. HSDP co-blending for fouling mitigation and on-line cleaning can be affected using different concentrations of top-performing and moderate-performing HSDP crude oils.Type: GrantFiled: October 8, 2010Date of Patent: April 5, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Glen B. Brons, Chris A. Wright -
Patent number: 7910528Abstract: There is provided a finished lubricant, comprising: a) a major amount of hydroisomerized Fischer-Tropsch wax, Fischer-Tropsch oligomerized olefins, or mixture thereof; and b) between about 0.10 and about 5 wt % of a solubility improver having an aniline point less than 10° C.; wherein the finished lubricant passes the 4 hour TORT B rust test.Type: GrantFiled: September 24, 2009Date of Patent: March 22, 2011Assignee: Chevron U.S.A. Inc.Inventor: Mark E. Okazaki
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Patent number: 7906465Abstract: A lubricant composition comprising a detergent and a base oil comprising less than about 3% by weight of tetracycloparaffins is disclosed. Methods of making and using the composition are also disclosed.Type: GrantFiled: July 14, 2006Date of Patent: March 15, 2011Assignee: Afton Chemical Corp.Inventors: Mark T. Devlin, Tze-chi Jao
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Patent number: 7906466Abstract: A finished lubricant having a kinematic viscosity at 40° C. between about 90 and 1700 cSt that passes the 4 hour TORT B rust test, comprising: a) greater than 65 weight percent API Group III base oil, API Group IV base oil, polyinternal olefin base oil, or mixtures thereof; and b) between about 0.10 wt % and about 5 wt % solubility improver. The solubility improver has an aniline point less than 50° C., or even lower. The finished lubricant can additionally comprise a mixture of amine phosphates.Type: GrantFiled: December 30, 2009Date of Patent: March 15, 2011Assignee: Chevron U.S.A. Inc.Inventor: Mark E. Okazaki
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Patent number: 7901564Abstract: Atmospheric and/or vacuum resid fractions of a high solvency dispersive power (HSDP) crude oil are added to a blend of crude oil to prevent fouling of crude oil refinery equipment and to perform on-line cleaning of fouled refinery equipment. The HSDP resid fractions dissolve asphaltene precipitates and maintain suspension of inorganic particulates before coking affects heat exchange surfaces.Type: GrantFiled: August 15, 2008Date of Patent: March 8, 2011Assignee: ExxonMobil Research & Engineering CompanyInventors: Glen B. Brons, Chris A. Wright, George A. Lutz, Mark A. Greaney
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Patent number: 7879775Abstract: A lubricant composition comprising a phosphorus-containing compound and a base oil comprising less than about 3% by weight of tetracycloparaffins is disclosed. Methods of making and using the lubricant composition are also disclosed.Type: GrantFiled: July 14, 2006Date of Patent: February 1, 2011Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Tze-chi Jao, John T. Loper, Roger M. Sheets, Gregory H. Guinther
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Patent number: 7846880Abstract: A lubricant, comprising a light base oil fraction having a wt % Noack volatility between 0 and 100 and additionally less than a Noack Volatility Factor (NVF), wherein the Noack Volatility Factor is defined by the equation; 900×(Kinematic Viscosity at 100° C.)?2.8?15, and optionally one or more additional additives. A process to make the light base oil fraction, comprising hydroisomerization dewaxing a waxy feed in a series of two or more reactors, and recovering the light base oil fraction having a low wt % Noack volatility. Also, a light base oil fraction having a wt % Noack volatility between 0 and 100 and additionally less than the NVF, made by the process of hydroisomerization dewaxing a waxy feed in a series of reactors.Type: GrantFiled: December 20, 2006Date of Patent: December 7, 2010Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott C. Deskin, Brent K. Lok, Shuibo Xie, Stephen J. Miller
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Patent number: 7846882Abstract: Electrical oil formulation comprising a base oil component and an additive, wherein (i) at least 80 wt % of the base oil component is a paraffin base oil having a paraffin content of greater than 80 wt % paraffins and a saturates content of greater than 98 wt % and comprising a series of iso-paraffins having n, n+1, n+2, n+3 and n+4 carbon atoms and wherein n is between 20 and 35; and (ii) an anti-oxidant additive; wherein the base oil component has a flash point of at least 170° C., as determined by ISO 2592.Type: GrantFiled: June 22, 2006Date of Patent: December 7, 2010Assignee: Shell Oil CompanyInventors: Andree Hilker, Volker Klaus Null
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Patent number: 7837853Abstract: Process to blend a mineral derived hydrocarbon product and a Fischer-Tropsch derived hydrocarbon product by providing in a storage vessel of a marine vessel a quantity of mineral derived hydrocarbon product and Fischer-Tropsch derived hydrocarbon product such that initially the mineral derived hydrocarbon product is located substantially above the Fischer-Tropsch derived hydrocarbon product, transporting the combined products in the marine vessel from one location to another location, also referred to as the destination, and obtaining a blended product at arrival of the marine vessel at its destination.Type: GrantFiled: April 11, 2006Date of Patent: November 23, 2010Assignee: Shell Oil CompanyInventors: Claire Ansell, Richard Hugh Clark, Richard John Heins
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High-solvency-dispersive-power (HSDP) crude oil blending for fouling mitigation and on-line cleaning
Patent number: 7837855Abstract: A high solvency dispersive power (HSDP) crude oil is added to a blend of incompatible and/or near-incompatible oils to proactively address the potential for fouling heat exchange equipment. The HSDP component dissolves asphaltene precipitates and maintains suspension of inorganic particulates before coking affects heat exchange surfaces. HSDP co-blending for fouling mitigation and on-line cleaning can be affected using different concentrations of top-performing and moderate-performing HSDP crude oils.Type: GrantFiled: August 15, 2008Date of Patent: November 23, 2010Assignee: ExxonMobil Research & Engineering CompanyInventors: Glen B. Brons, Chris A. Wright -
Patent number: 7833952Abstract: A lubricant composition comprising a detergent and a base oil comprising more than about 1.6% by weight of tetracycloparaffins is disclosed. Methods of making and using the composition are also disclosed.Type: GrantFiled: August 28, 2006Date of Patent: November 16, 2010Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Tze-chi Jao
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Patent number: 7833953Abstract: A lubricant composition comprising a dispersant and a base oil comprising more than about 1.6% by weight of tetracycloparaffins is disclosed. Methods of making and using the lubricant composition are also disclosed.Type: GrantFiled: August 28, 2006Date of Patent: November 16, 2010Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Tze-chi Jao
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Patent number: 7820076Abstract: The invention relates to an oleaginous mildew and corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion and mildew. The composition comprises, in parts by weight, from about 20 to 60 parts of an oleaginous material such as a lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.0 to 5.0 parts of a water-displacing compound, an effective amount of a mildew-inhibiting compound, and from 0.0 to 1.0 part of a heterocyclic metal deactivator.Type: GrantFiled: December 20, 2005Date of Patent: October 26, 2010Assignee: The United States of America as represented by the Secretary of the NavyInventors: El Sayed S. Arafat, Craig A. Matzdorf, James A. Whitfield
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Patent number: 7815789Abstract: A process to prepare a base oil having a viscosity index of above 80 and a saturates content of above 90 wt % from a crude derived feedstock by (a) contacting a crude derived feedstock in the presence of hydrogen with a catalyst having at least one Group VIB metal component and at least one non-noble Group VIII metal component supported on a refractory oxide carrier; (b) adding to the effluent of step (a) or part of the effluent of step (a) a Fischer-Tropsch derived fraction boiling at least partly in the base oil range in an amount effective to achieve the target viscosity index of the final base oil; and (c) dewaxing the mixture as obtained in step (b).Type: GrantFiled: June 21, 2004Date of Patent: October 19, 2010Assignee: Shell Oil CompanyInventors: Peter James Wardle, William Leonard Alexander King
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Patent number: 7795365Abstract: The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C. The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.Type: GrantFiled: October 1, 2003Date of Patent: September 14, 2010Assignee: Dow Global Technologies Inc.Inventors: Teresa P. Karjala, Selim Yalvac, Thomas Karjala, Daniel D. Vanderlende, Brian W. Kolthammer, James C. Stevens, Charles F. Diehl
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Patent number: 7776111Abstract: The invention provides compositions comprising at least one alkylphenol-aldehyde resin (constituent I) and, based on the alkylphenol resin, from 0.005 to 10% by weight of at least one oil-soluble organic ammonium sulfonate (constituent II).Type: GrantFiled: July 20, 2005Date of Patent: August 17, 2010Assignee: Clariant Produkte (Deutschland) GmbHInventors: Matthias Krull, Carsten Cohrs, Hildegard Freundl, Stefan Lorenz
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Patent number: 7776233Abstract: The invention relates to an oleaginous corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion. The composition comprises, in parts by weight, from about 20 to 60 parts of lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.1 to 5.0 parts of a water-displacing compound and from 0.0 to 1.0 part of a metal deactivator.Type: GrantFiled: October 27, 2005Date of Patent: August 17, 2010Assignee: The United States of America as represented by the Secretary of the NavyInventors: El Sayed Arafat, Judy Butler-Kowalik, Kenneth Clark, David L. Gauntt
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Patent number: 7763161Abstract: A process for manufacturing a lubricating base oil, comprising dewaxing a substantially paraffinic wax feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve under hydroisomerization conditions including a hydrogen to feed ratio from about 712.4 to about 3562 liter H2/liter oil, whereby a lubricating base oil is produced having a) a total weight percent of molecules with cycloparaffinic functionality greater than 10, and b) a ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality greater than 30. Also a method for producing a base oil having a high ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality by hydroisomerization dewaxing a selected Fischer-Tropsch wax under hydroisomerization conditions including a hydrogen to feed ratio from about 712.4 to about 3562 liter H2/liter oil.Type: GrantFiled: May 19, 2006Date of Patent: July 27, 2010Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott Deskin, Kamala Krishna, Stephen J. Miller, Susan M. Abernathy
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Patent number: 7732391Abstract: A manual transmission fluid having a VI greater than 160 and a Brookfield viscosity at ?40° C. less than 30,000 cP. It comprises: 1) a base oil (made from a waxy feed) having less than 0.06 wt % aromatics, greater than 5 wt % total molecules with cycloparaffinic functionality, and a ratio of molecules with monocycloparaffinic functionality to molecules with multicycloparaffinic functionality greater than 20; and a manual transmission fluid additive package. In another embodiment, the manual transmission fluid comprises: 1) a base oil having a high VI and a kinematic viscosity at 100° C. greater than 5.5 cSt, 2) less than 0.01 wt % pour point depressant, and 3) a manual transmission fluid additive package. This invention is also directed to a process to make the manual transmission fluid, comprising the steps of hydroisomerization dewaxing, selecting base oil fractions having a high VI, and blending the fractions with an additive package.Type: GrantFiled: December 7, 2005Date of Patent: June 8, 2010Assignee: Chevron U.S.A. Inc.Inventors: John Rosenbaum, Marc J. De Weerdt, Thomas Plaetinck, Nancy J. Bertrand
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Patent number: 7727379Abstract: Process to prepare simultaneously two or more base oil grades and middle distillates from a mineral crude derived feed, in particular a de-asphalted oil or a vacuum distillate feed or their mixtures, by performing the following steps: (a) hydrocracking the mineral crude derived feed, thereby obtaining an effluent; (b) distillation of the effluent as obtained in step (a) into one or more middle distillates and a full range residue boiling substantially above 340° C., (c) catalytically dewaxing the full range residue by contacting the residue with a dewaxing catalyst comprising a zeolite of the MTW type and a Group VIII metal, thereby obtaining a dewaxed oil; (d) isolating by means of distillation two or more base oil grades from the dewaxed oil obtained in step (c); and (e) isolating a dewaxed gas oil from the dewaxed-oil obtained in step (c); wherein the dewaxed oil as obtained in step (c) comprises between 10 and 40 wt % of a dewaxed heavy gas oil boiling for more than 70 wt % between 370 and 400° C.Type: GrantFiled: March 1, 2005Date of Patent: June 1, 2010Assignee: Shell Oil CompanyInventors: Nicholas James Adams, Harmannus Julius Hegge, Laurent Georges Huve, Kevin John Anthony Polder, Wiecher Derk Evert Steenge
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Patent number: 7727378Abstract: A process to prepare a waxy raffinate product by performing the following steps: (a) subjecting a Fischer-Tropsch derived product having a weight ratio of compounds boiling above 540° C. and compounds boiling between 370 and 540° C. of greater than 2 to a hydroconversion step and (b) fractionating the effluent of step (a) to obtain products boiling in the fuels range and a waxy raffinate product boiling between 350 and 600° C.Type: GrantFiled: July 2, 2004Date of Patent: June 1, 2010Assignee: Shell Oil CompanyInventors: Jan Lodewijk Maria Dierickx, Arend Hoek, Lip Piang Kueh
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Patent number: 7708878Abstract: A process for producing a product slate, which includes at least three base oil grades having kinematic viscosities at 100° C. within the range between about 1.8 cSt and 30 cSt, from a waxy feed having an initial boiling point of about 340° C. or less and a final boiling point of about 560° C. or higher, said process comprising (a) isomerizing at least a portion of the waxy feed, whereby the amount of isoparaffins present are increased; (b) distilling a first portion of the isomerized waxy feed in light block mode operation into at least three base oil fractions having different boiling ranges; (c) distilling a second portion of the isomerized waxy feed in medium block mode operation into at least three base oil fractions having different boiling ranges; and (d) blending at least one base oil fraction produced from light block mode with at least one base oil fraction produced from medium block mode to produce a lubricating base oil blend meeting a target value for at least one pre-selected property.Type: GrantFiled: March 10, 2005Date of Patent: May 4, 2010Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Brent K. Lok, Philip E. Quinnett, Christopher Allen Simmons
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Patent number: 7682499Abstract: The invention provides for a mineral insulating oil having a naphthenic base oil and a paraffinic base oil wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1. The invention also provides for a mineral insulating oil having a naphthenic base oil, a paraffinic base oil, and an antioxidant agent wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1. The invention also provides for a process for producing a mineral insulating oil including contacting a naphthenic base oil and a paraffinic base oil wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1. The invention also provides for a process for producing a mineral insulating oil including contacting a naphthenic base oil, a paraffinic base oil, and an antioxidant agent wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1.Type: GrantFiled: August 24, 2006Date of Patent: March 23, 2010Assignee: Shell Oil CompanyInventors: Steven Allen Holmes, Ronald Wayne Dever
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Patent number: 7674364Abstract: A hydraulic fluid composition having excellent seal compatibility is prepared from an isomerized base oil is provided. The composition comprising (i) 80 to 99.999 wt. % of a lubricating base oil having consecutive numbers of carbon atoms, less than 10 wt % naphthenic carbon by n-d-M, less than 0.10 wt. % olefins and less than 0.05 wt. % aromatics, a molecular weight of greater than 600 by ASTM D 2503-92 (Reapproved 2002), a wt % total molecules with cycloparaffinic functionality greater than 25 and a ratio of molecules with monocycloparaffinic functionality to molecules with multicycloparaffinic functionality greater than 10; and (ii) optionally from 0.001 to 6 wt % of a viscosity modifier; and (iii) 0-10 wt % of at least an additive package. When used in operations, the composition results in an average volume change in a rubber seal of less than 3% and an average hardness change in the rubber seal of less than 1 pts. when tested under ASTM D 471-06 (SRE NBR1 at 100° C., 168 hours).Type: GrantFiled: August 28, 2007Date of Patent: March 9, 2010Assignee: Chevron U.S.A. Inc.Inventors: William Loh, John M. Rosenbaum, Nancy J. Bertrand, Patricia V. Lemay
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Publication number: 20100048434Abstract: A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.Type: ApplicationFiled: October 28, 2009Publication date: February 25, 2010Inventors: Mark Paul Hagemeister, Thomas R. Forbus, JR.
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Patent number: 7666295Abstract: An uninhibited electrical insulating oil is prepared by blending a severely hydrotreated naphthenic distillate base oil having a viscosity of from about 50 to about 80 SSU at 38° C. and an aniline point from about 63° to about 84° C. with a solvent extracted, non-hydrogenated paraffinic distillate having at least 9.0 wt. % aromatic content.Type: GrantFiled: October 20, 2005Date of Patent: February 23, 2010Assignee: Ergon Refining, Inc.Inventors: John Kristopher Patrick, Lance A. Puckett, Jimmy M. Rasco, H. Don Davis
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Publication number: 20100041572Abstract: The present invention provides a lubricating base oil comprising saturated components of 90% by mass or greater, wherein the proportion of cyclic saturated components among the saturated components is not greater than 40% by mass, and by having a viscosity index of 110 or higher and an iodine value of not greater than 2.5. The lubricating base oil of the invention exhibits excellent viscosity-temperature characteristics and heat and oxidation stability while also allowing additives to exhibit a higher level of function when additives are included. The lubricating base oil of the invention is suitable for use in various lubricating oil fields, and is especially useful for reducing energy loss and achieving energy savings in devices in which the lubricating base oil is applied.Type: ApplicationFiled: March 28, 2007Publication date: February 18, 2010Inventors: Takashi Sano, Shinichi Shirahama, Kazuo Tagawa, Kenichi Komiya, Shigeki Matsui, Osamu Kurosawa
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Patent number: 7662271Abstract: A lubricating oil (made from Group III base oil having a sequential number of carbon atoms) having a VI between 155 and 300, a RPVOT greater than 680 minutes, and a kinematic viscosity at 40° C. from 19.8 cSt to 748 cSt. A lubricating oil having a high VI and high RPVOT comprising: a) a Group III base oil with a sequential number of carbon atoms, and defined cycloparaffin composition or low traction coefficient, b) an antioxidant additive concentrate and c) no VI improver. A process comprising: a) hydroisomerization dewaxing of a waxy feed, b) fractionating the produced base oil, c) selecting a fraction having a VI greater than 150, and a high level of molecules with cycloparaffinic functionality or a low traction coefficient, and d) blending the fraction with an antioxidant additive concentrate. Also, a method of improving the oxidation stability of a lubricating oil.Type: GrantFiled: December 21, 2005Date of Patent: February 16, 2010Assignee: Chevron U.S.A. Inc.Inventors: William Loh, John Rosenbaum, Nancy J. Bertrand, Patricia Lemay, Rawls Frazier, Mark E. Okazaki
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Patent number: 7655133Abstract: An ashless lubricating oil, comprising a base oil having greater than 90 wt % saturates, less than 10 wt % aromatics, a viscosity index greater than 130, low sulfur, and a sequential number of carbon atoms. The lubricating oil has a VI between 155 and 300, greater than 680 minutes in a rotary pressure vessel oxidation test, and a kinematic viscosity at 40° C. from 19.8 to 748 cSt. An ashless paper machine oil, comprising a base oil having a sequential number of carbon atoms, wherein the oil has a defined viscosity index and high oxidation stability. Also, an ashless lubricating oil, comprising a base oil having a viscosity index greater than 150, wherein the base oil is made from a blend of petroleum-based wax and Fischer-Tropsch derived wax.Type: GrantFiled: November 25, 2008Date of Patent: February 2, 2010Assignee: Chevron U.S.A. Inc.Inventors: William Loh, John M. Rosenbaum, Nancy J. Bertrand, Patricia LeMay, Rawls H. Frazier, Mark E. Okazaki
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Patent number: 7655132Abstract: A method for improving the lubricating properties of a isomerized distillate base oil having a kinematic viscosity at 100 degrees C. between about 2.5 cSt and about 8 cSt, the method comprising blending with said isomerized distillate base oil a sufficient amount of a pour point depressing base oil blending component to reduce the pour point of the resulting base oil blend at least 3 degrees C. below the pour point of the distillate base oil wherein the pour point depressing base oil blending component is an isomerized petroleum derived base oil containing material having a boiling range above about 1050 degrees F.; also lubricating base oil blends prepared according to the process; and the pour point depressing base oil blending component.Type: GrantFiled: May 4, 2004Date of Patent: February 2, 2010Assignee: Chevron U.S.A. Inc.Inventors: Stephen J. Miller, John M. Rosenbaum
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Patent number: 7655605Abstract: The present invention relates to an extra light hydrocarbon liquid derived from highly paraffinic wax. This extra light hydrocarbon liquid is suitable for use as a lubricant additive diluent oil in oil soluble additive concentrates. This extra light hydrocarbon liquid derived from highly paraffinic wax has a viscosity of between about 1.0 and 3.5 cSt at 100° C. and a Noack volatility of less than 50 weight % and comprises greater than 3 weight % molecules with cycloparaffinic functionality and less than 0.30 weight percent aromatics. The extra light hydrocarbon liquid makes an excellent lubricant additive diluent oil because it has low volatility, low viscosity, good additive solubility, and excellent solubility in lubricant base oil stocks. The present invention also relates to finished lubricants comprising the oil soluble additive concentrates made with the extra light hydrocarbon liquid and finished lubricants comprising the oil soluble additive concentrates.Type: GrantFiled: February 14, 2006Date of Patent: February 2, 2010Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Brent K. Lok, Joseph M. Pudlak
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Patent number: 7651985Abstract: A method for improving the oxidation stability of an ashless hydraulic fluid or an ashless paper machine oil, comprising: a. selecting a base oil having greater than 90 wt % saturates, less than 10 wt % aromatics, a base oil viscosity index greater than 120, less than 0.03 wt % sulfur, a sequential number of carbon atoms, greater than 35 wt % total molecules with cycloparaffinic functionality, and a ratio of molecules with monocycloparaffinic functionality to molecules with multicycloparaffinic functionality greater than 2.1; and b. replacing a portion of an original base oil in the ashless oil with the selected base oil to produce an improved ashless lubricating oil; wherein the improved ashless lubricating oil has a result in the rotary pressure vessel oxidation test that is at least 50 minutes greater than the result in the rotary pressure oxidation test of the ashless hydraulic fluid or ashless paper machine oil.Type: GrantFiled: August 6, 2008Date of Patent: January 26, 2010Assignee: Chevron U.S.A. Inc.Inventors: William Loh, John M. Rosenbaum, Nancy J. Bertrand, Patricia LeMay, Rawls Frazier, Mark E. Okazaki
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Publication number: 20100016195Abstract: The lubricating base oil of the invention satisfies at least one of conditions (a) or (b) below. The lubricating oil composition for an internal combustion engine according to the invention comprises the lubricating base oil of the invention, an ashless antioxidant containing essentially no sulfur as a constituent element, and at least one compound selected from among ashless antioxidants containing sulfur as a constituent element and organic molybdenum compounds. Also, a lubricating oil composition for a power train device according to the invention comprises the lubricating base oil of the invention, a poly(meth)acrylate-based viscosity index improver and a phosphorus-containing compound. (a) The saturated component content is 90% by mass or greater, and the proportion of cyclic saturated components among the saturated components is 10-40% by mass. (b) The condition represented by the following formula (1) is satisfied. 1.440?n20?0.002×kv100?1.453 (1) [wherein n20 represents the 20° C.Type: ApplicationFiled: March 14, 2007Publication date: January 21, 2010Inventors: Shinichi Shirahama, Masahiro Taguchi, Kazuo Tagawa, Takashi Sano, Shozaburo Konishi, Shigeki Matsui, Osamu Kurosawa
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Patent number: 7601253Abstract: A process oil comprising a 95/5 to 5/95 by weight mixture of: an extract having a DMSO extractable content less than 3 wt % obtained by solvent-extracting an oil obtained by deasphalting a vacuum distillation bottom; and either a mineral oil base having a DMSO extractable content less than 3 wt % which is a raffinate obtained by the solvent refining of a vacuum distillate or a mineral oil base having a DMSO extractable content less than 3 wt % obtained by subjecting a raffinate obtained by the solvent refining of a vacuum distillate to hydrorefining and/or dewaxing. The process oil has a kinematic viscosity at 100° C. of less than 32 mm2/s, % CA of 15 to 30, aniline point of 100° C. or lower, weight change through evaporation of 0.5% or less, and mutagenicity index of less than 1.Type: GrantFiled: September 30, 2002Date of Patent: October 13, 2009Assignee: Japan Energy CorporationInventors: Takashi Kaimai, Yoshiyuki Morishima, Kenji Fujino
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Patent number: 7592495Abstract: Compositions including blends of Group II and/or Group III base oils and alkkylated fused and/or polyfused aromatic compositions, such as alkylated naphthalenes are provided. The use of such compositions, which exhibit excellent additive solvency, thermo-oxidative stability, hydrolytic stability, and seal swell characteristics, as lubricants is disclosed.Type: GrantFiled: July 3, 2001Date of Patent: September 22, 2009Assignee: King IndustriesInventors: Edward T. Hessell, Richard A. Abramshe, Lawrence V. Gallacher
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Patent number: 7582591Abstract: Gear lubricant with a low Brookfield Ratio, comprising: a base oil having sequential carbon atoms, low aromatics, greater than 20 wt % molecules with cycloparaffins and a high ratio of monocycloparaffins to multicycloparaffins; less than 22 wt % of a second base oil having less than 40 wt % molecules with cycloparaffins and a lower ratio of monocycloparaffins to multicycloparaffins; a pour point depressant, an EP additive; and less than 10 wt % VI improver. Gear lubricant with a low Brookfield Ratio, comprising a first base oil having low aromatics and high VI; less than 22 wt % of a second base oil with a lower VI; a pour point depressant; and an EP additive. Gear lubricant having a low Brookfield Ratio comprising: an FT derived base oil; a pour point depressing base oil blending component; and an EP additive. Processes for making gear lubricants with low Brookfield Ratios. Method for reducing Brookfield Ratio.Type: GrantFiled: April 7, 2006Date of Patent: September 1, 2009Assignee: Chevron U.S.A. Inc.Inventors: Michael J. Haire, John A. Zakarian, John M. Rosenbaum, Nancy J. Bertrand, Stephen J. Miller
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Patent number: 7582200Abstract: A method of operating a hydraulic pump, comprising: a. filling a hydraulic system oil reservoir with a hydraulic oil comprising: i. a lubricant base oil having defined properties: and ii. an antiwear hydraulic oil additive package; wherein the hydraulic oil has an air release at 50° C. less than 0.8 minutes; and b. operating the hydraulic pump without pump cavitation. A hydraulic system, comprising a hydraulic system oil reservoir holding a hydraulic oil comprising: i. a lubricant base oil, optionally having defined properties; and b. an antiwear hydraulic oil additive package; wherein the hydraulic oil has an air release at 50° C. less than 0.8 minutes. In one embodiment the hydraulic oil additionally has low foam tendency and good demulsibility.Type: GrantFiled: June 30, 2008Date of Patent: September 1, 2009Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Susan M. Abernathy, Nancy J. Bertrand
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Patent number: 7578372Abstract: An aerosol container containing a propellant and a highly hydrogenated mineral oil lubricant for the lubrication of gaskets in pipe segments. Preferred propellants are normally gaseous hydrocarbons. The preferred lubricant is the compound identified by the Chemical Abstracts Registry No. 8042-47-5. Preferred gaskets are those made of SBR, BR, EPM. And EPDM. A preferred actuating valve is an omnidirectional valve.Type: GrantFiled: June 17, 2002Date of Patent: August 25, 2009Inventor: Ronald D. Green
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Publication number: 20090203835Abstract: The invention relates to a process to prepare an oil blend comprising: (i) de-asphalting a mineral-derived vacuum residue to obtain a de-asphalted oil, (ii) optionally extracting from the de-asphalted oil an aromatic extract by solvent extraction process; and (iii) blending the de-asphalted oil obtained in (i) or the aromatic extract obtained in (ii) with a paraffin base oil. The invention further relates to the oil blends obtainable by the process, and their uses.Type: ApplicationFiled: July 3, 2006Publication date: August 13, 2009Inventors: Volker Klaus Null, David John Wedlock
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Patent number: 7572361Abstract: Lubricant blends and finished gear oils comprising a lubricant base oil fraction derived from highly paraffinic wax, a petroleum derived base oil, and a pour point depressant are provided. The lubricant base oil fraction derived from highly paraffinic wax comprises less than 0.30 weight percent aromatics, greater than 5 weight percent molecules with cycloparaffinic functionality, and a ratio of weight percent of molecules with monocycloparaffinic functionality to weight percent of molecules with multicycloparaffinic functionality greater than 15. The petroleum derived base oils comprises greater than 90 weight percent saturates and less than 300 ppm sulfur and is preferably selected from the group consisting of a Group II base oil, a Group III base oil, and mixtures thereof. These lubricant blends have surprising low Brookfield viscosities at ?40° C.Type: GrantFiled: December 2, 2004Date of Patent: August 11, 2009Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Stephen J. Miller, Joseph M. Pudlak
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Patent number: 7569524Abstract: A process for making an ashless hydraulic fluid or paper machine oil comprising a) hydroisomerization dewaxing, b) fractionating, c) selecting a fraction having a very high VI, and a high level of molecules with cycloparaffinic functionality, and d) blending the fraction with an ashless antioxidant. A process for making ashless paper machine oil, comprising: a. selecting two lubricating base oils both having a consecutive number of carbon atoms, greater than 35 wt % total molecules with cycloparaffinic functionality, and a viscosity index greater than 150; b. blending the two lubricating base oils with an ashless antioxidant additive concentrate and no viscosity index improver to make an ashless paper machine oil; wherein the ashless paper machine oil has a result of greater than 680 minutes in the rotary pressure vessel oxidation test.Type: GrantFiled: August 6, 2008Date of Patent: August 4, 2009Assignee: Chevron U.S.A. Inc.Inventors: William Loh, John M. Rosenbaum, Nancy J. Bertrand, Patricia LeMay, Rawls Frazier, Mark E. Okazaki
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Patent number: 7547666Abstract: An ashless hydraulic fluid or paper machine oil having a VI between 155 and 300, a RPVOT greater than 680 minutes, and a kinematic viscosity at 40° C. from 19.8 cSt to 748 cSt. An ashless hydraulic fluid or paper machine oil having a high VI and high RPVOT comprising: a) a Group III base oil with a sequential number of carbon atoms, and defined cycloparaffin composition or low traction coefficient, b) an ashless antioxidant additive concentrate, and c) low amount of VI improver. A process for making an ashless hydraulic fluid or paper machine oil comprising a) hydroisomerization dewaxing, b) fractionating, c) selecting a fraction having a very high VI, and a high level of molecules with cycloparaffinic functionality or a low traction coefficient, and d) blending the fraction with an ashless antioxidant. Also, a method of improving the oxidation stability of an ashless hydraulic fluid or paper machine oil.Type: GrantFiled: December 21, 2005Date of Patent: June 16, 2009Assignee: Chevron U.S.A. Inc.Inventors: William Loh, John Rosenbaum, Nancy J. Bertrand, Patricia LeMay, Rawls Frazier, Mark E. Okazaki
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Patent number: 7531083Abstract: Cycloalkane base oil, methods of making cycloalkane base oil, and dielectric liquid comprising cycloalkane base oil, the cycloalkane base oil comprising a quantity of isoparaffins and from 50 wt. % to 70 wt. % cycloalkanes having the formula CnH2n wherein n is from 15 to 30, said quantity of isoparaffins being less than 50 wt. % of said cycloalkane base oil.Type: GrantFiled: June 15, 2005Date of Patent: May 12, 2009Assignee: Shell Oil CompanyInventors: Steven Allen Holmes, John Robert Powers, Michael Phillip Smith, Abraham Robert Dekraker
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Patent number: 7531081Abstract: A lubricating base oil composition having at least 95 wt % saturates, of which saturates fraction between 10 and 30 wt % are cyclo-paraffins and the remainder being n- and iso-paraffins, having a viscosity index of above 120 and a pour point of below ?15° C.Type: GrantFiled: February 13, 2002Date of Patent: May 12, 2009Assignee: Shell Oil CompanyInventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20090111936Abstract: The invention relates to a bright stock base oil blend comprising of a paraffinic base oil component having a viscosity at 100° C. of from 8 to 25 mm?/sec and a residual and de-asphalted oil component, and the use of said blend as part of a gear oil or a cylinder oil formulation, and other uses.Type: ApplicationFiled: July 3, 2006Publication date: April 30, 2009Inventor: David John Wedlock