Admixtures Patents (Class 208/19)
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Patent number: 7520976Abstract: A multigrade engine oil meeting the specifications for SAE J300 revised June 2001 requirements and a process for preparing it, said engine oil comprising (a) between about 15 to about 94.5 wt % of a hydroisomerized distillate Fischer-Tropsch base oil characterized by (i) a kinematic viscosity between about 2.5 and about 8 cSt at 100° C., (ii) at least about 3 wt % of the molecules having cycloparaffin functionality, and (iii) a ratio of weight percent molecules with monocycloparaffin functionality to weight percent of molecules with multicycloparaffin functionality greater than about 15; (b) between about 0.5 to about 20 wt % of a pour point depressing base oil blending component prepared from an hydroisomerized bottoms material having an average degree of branching in the molecules between about 5 and 9 alkyl-branches per 100 carbon atoms and wherein not more than 10 wt % boils below about 900° F.Type: GrantFiled: September 23, 2004Date of Patent: April 21, 2009Assignee: Chevron U.S.A. Inc.Inventors: Stephen J. Miller, John M. Rosenbaum, Susan M. Abernathy
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Patent number: 7510674Abstract: Dielectric fluids comprising oil fractions derived from highly paraffinic wax are provided. Further provided are processes for making these dielectric fluids comprising oil fractions derived from highly paraffinic wax. The dielectric fluids are useful as insulating and cooling mediums in new and existing power and distribution electrical apparatus, such as transformers, regulators, circuit breakers, switchgear, underground electrical cables, and attendant equipment.Type: GrantFiled: December 1, 2004Date of Patent: March 31, 2009Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nadine L. Yenni, Joseph M. Pudlak
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Patent number: 7501019Abstract: A granular solid wax particle comprising a highly paraffinic wax having a low T10 boiling point less than 427° C. and an inorganic powder coating; optionally with a layer of higher boiling wax over the highly paraffinic wax having a low T10 boiling point, and an inorganic powder coating over the layer of higher boiling wax. In separate embodiments, a highly paraffinic wax having a T10 boiling point less than 427° C. or a highly paraffinic wax having a needle penetration greater than 3 mm/10 at 25° C. is coated with a powder that adsorbs the wax without being encapsulated by the wax in a hot drop wax test. Also, a process for transporting highly paraffinic wax having a T10 boiling point less than 427° C. as granular solid wax particles. And, a method of making base oil from granular solid wax particles transported from a distant location.Type: GrantFiled: March 31, 2005Date of Patent: March 10, 2009Assignee: Chevron U.S.A., Inc.Inventors: Gunther H. Dieckmann, Dennis J. O'Rear
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Patent number: 7479216Abstract: The present invention relates to transportable product for the transportation of paraffinic wax and methods of transporting using this transportable product. The transportable product comprises 90 to 20 weight % of a liquid comprising >50 weight % alcohol and having a true vapor pressure of ?14.7 psia when measured at 20° C., and 10 to 80 weight % of wax particles, wherein the wax particles comprise ?75 weight % of wax particles larger than 0.1 mm. The transportable product and methods of transporting according to the present invention are able to accommodate a relatively high weight % of paraffinic wax particles in the transportable product while avoiding interparticle adhesion and clumping by ensuring that the wax particles are not too small and the amount of small wax particles is not excessive.Type: GrantFiled: September 28, 2004Date of Patent: January 20, 2009Assignee: Chevron U.S.A. Inc.Inventors: Gunther H. Dieckmann, Mark R. Buetzow, Dennis J. O'Rear
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Patent number: 7476645Abstract: Blended lubricant base oils and blended finished lubricants comprising ?70 weight percent Fischer-Tropsch derived lubricant base oils comprising ?6 weight % molecules with monocycloparaffinic functionality and less than 0.05 weight % molecules with aromatic functionality; at least one polyalphaolefin lubricant base oil with a kinematic viscosity at 100° C. greater than about 30 cSt and less than 150 cSt are provided. These blended lubricant base oils and blended finished lubricants exhibit superior friction and wear properties, in addition to other highly desired properties. Also provided are processes for making these blended lubricant base oils and blended finished lubricants.Type: GrantFiled: March 3, 2005Date of Patent: January 13, 2009Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Brent K. Lok, Joseph M. Pudlak, James N. Ziemer, Robert J. Farina
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Patent number: 7473345Abstract: Lubricant blends and finished gear oils comprising a lubricant base oil fraction derived from highly paraffinic wax, a petroleum derived base oil, and a pour point depressant are provided. The lubricant base oil fraction derived from highly paraffinic wax comprises less than 0.30 weight percent aromatics, greater than 5 weight percent molecules with cycloparaffinic functionality, and a ratio of weight percent of molecules with monocycloparaffinic functionality to weight percent of molecules with multicycloparaffinic functionality greater than 15. The petroleum derived base oils comprises greater than 90 weight percent saturates and less than 300 ppm sulfur and is preferably selected from the group consisting of a Group II base oil, a Group III base oil, and mixtures thereof. These lubricant blends have surprising low Brookfield viscosities at ?40° C.Type: GrantFiled: December 2, 2004Date of Patent: January 6, 2009Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Stephen J. Miller, Joseph M. Pudlak
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Patent number: 7429318Abstract: A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreated feedstock is hydrodewaxed using a dewaxing catalyst that has been selectively activated by oxygenate treatment. The hydrodewaxed product may then be hydrofinished.Type: GrantFiled: May 18, 2006Date of Patent: September 30, 2008Assignee: ExxonMobil Research and Engineering CompanyInventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer, David W. Larkin, John E. Gallagher, Jr., Jeenok T. Kim
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Patent number: 7407917Abstract: An additive compound comprising a non-borated and/or borated reaction product, in which the reaction product is obtained by reacting a linear or branched, saturated or unsaturated monovalent aliphatic acid having 8 to 22 carbon atoms, urea, and polyalkylenepolyamine, when employed in a lubricating oil composition is favorably employable as an automatic transmission fluid of internal combustion engines.Type: GrantFiled: November 16, 2004Date of Patent: August 5, 2008Assignee: Chevron Oronite Company LLCInventors: Michio Shiga, Tomotusgu Shiroi
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Patent number: 7404888Abstract: A process for reducing the metal corrosion of a hydrocarbonaceous liquid which causes corrosion as measured by NACE Standard TM0172-2001, said process comprising blending with the hydrocarbonaceous liquid at least 0.1 weight percent of an acidic Fischer-Tropsch product in sufficient proportion to produce a hydrocarbonaceous blend displaying reduced metal corrosion as measured by NACE Standard TM0172-2001 when compared to the hydrocarbonaceous liquid and a hydrocarbonaceous blend prepared by the process.Type: GrantFiled: July 7, 2004Date of Patent: July 29, 2008Assignee: Chevron U.S.A. Inc.Inventors: Dennis J. O'Rear, Greg Hemighaus, Gunther H. Dieckmann
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Publication number: 20080156691Abstract: The present invention relates to a metal working fluid comprising abase oil having a viscosity index of more than 110 according to ASTM D 2270 and a pour point of less than ?40° C. according to ASTM D 97. Preferably the base oil is a Fischer-Tropsch derived oil. Preferably, the base oil has a kinematic viscosity at 100° C. of between 2 and 3 mm2/s, according to ASTM D 445. Further, the base oil preferably has a flash point of more than 170° C., preferably more than 175° C., most preferably more than 180° C., according to ASTM D 92.Type: ApplicationFiled: December 6, 2005Publication date: July 3, 2008Inventor: Didier Busatto
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Publication number: 20080149529Abstract: A lubricant base oil blend having a wt % Noack volatility less than 29, comprising a) a light base oil fraction having a kinematic viscosity at 100° C. between 1.5 and 3.6, and a wt % Noack volatility both between 0 and 100 and less than a Noack Volatility Factor, and b) a petroleum-derived base oil fraction. A process to make the lubricant base oil blend having a wt % Noack volatility less than 29. Also, a pour point depressed lubricant base oil blend having a Brookfield viscosity at ?40° C. of less than 18,000 cP, comprising the light base oil fraction, a petroleum-derived base oil fraction, and a pour point depressant.Type: ApplicationFiled: December 20, 2006Publication date: June 26, 2008Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott C. Deskin, Brent K. Lok, Shuibo Xie, Stephen J. Miller
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Patent number: 7384536Abstract: Lubricant blends and finished gear oils comprising a Fischer-Tropsch derived lubricant base oil fraction, a petroleum derived base oil, and a pour point depressant are provided. The Fischer-Tropsch derived lubricant base oil fraction comprises less than 0.30 weight percent aromatics, greater than 5 weight percent molecules with cycloparaffinic functionality, and a ratio of weight percent of molecules with monocycloparaffinic functionality to weight percent of molecules with multicycloparaffinic functionality greater than 15. The petroleum derived base oils comprises greater than 90 weight percent saturates and less than 300 ppm sulfur and is preferably selected from the group consisting of a Group II base oil, a Group III base oil, and mixtures thereof. These lubricant blends have surprising low Brookfield viscosities at ?40° C.Type: GrantFiled: May 19, 2004Date of Patent: June 10, 2008Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Stephen J. Miller, Joseph M. Pudlak
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Publication number: 20080128322Abstract: The present invention is directed to a traction coefficient reducing lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity comprising a blend of two or more isomerized Fischer-Tropsch derived base oils wherein the kinematic viscosity of the blend is in a range from about 2 to about 14 centistokes at 100° C., and (b) one or more lubricating oil additives wherein the lubricating oil composition is essentially free of friction modifiers. The present invention is also directed to a method for reducing the traction coefficient in internal combustion engines comprising lubricating the internal combustion engines with a lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity comprising a blend of two or more isomerized Fischer-Tropsch derived base oils wherein the kinematic viscosity of the blend is in a range from about 2 to about 14 centistokes at 100° C.Type: ApplicationFiled: November 30, 2006Publication date: June 5, 2008Applicant: CHEVRON ORONITE COMPANY LLCInventors: WILLEM VAN DAM, JAMES ZIEMER
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Publication number: 20080110799Abstract: The present invention provide a lubricating oil composition suitable for internal combustion engines, which composition is excellent in thermal/oxidation stability and can inhibit the increases of the viscosity and acid number even in the presence of NOx and can be used for a long period of time or provide a lubricating oil composition particularly suitable for diesel or direct injection engines equipped with an exhaust-gas after-treatment device such as DPF or various catalysts, which composition is excellent in high-temperature detergency and base number retention properties and further can achieve the effect of inhibit wear caused by soot contamination in the oil occurring significantly when the content of phosphorus compounds such as ZnDTP is decreased, at a high level and can inhibit the exhaust-gas after-treatment device from being adversely affected.Type: ApplicationFiled: November 1, 2007Publication date: May 15, 2008Applicant: NIPPON OIL CORPORATIONInventors: Shigeki MATSUI, Koji HOSHINO, Shigeki TAKESHIMA
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Patent number: 7347928Abstract: A process to prepare a spindle oil, light machine oil and a medium machine oil base oil grade by: (a) performing a separate catalytic dewaxing on a spindle oil fraction, a light machine oil fraction and a medium machine oil fraction as obtained in a vacuum distillation of a bottoms fraction of a fuels hydrocracking process; (b) performing a separate hydrofinishing of the light and medium machine oil fractions obtained in step (a); (c) separating the low boiling compounds from the spindle oil, light machine oil and medium machine oil fractions as obtained in step (a) and (b) and obtaining the spindle oil, light machine oil and medium machine oil base oil grade; (d) wherein the vacuum distillation is performed by altematingly performing the distillation in two modes wherein the first mode (d1) the bottoms fraction is separated into a gas oil fraction, a spindle oil fraction, a medium machine oil fraction and a first rest fraction boiling between said spindle oil and medium machine oil fraction and in the seconType: GrantFiled: December 18, 2001Date of Patent: March 25, 2008Assignee: Shell Oil CompanyInventors: Johannes Van Beijnum, Arjen Peter Geukema, Kevin John Anthony Polder
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Patent number: 7347927Abstract: A heat treatment oil composition comprising a mixed base oil containing 50-95 weight % of (A) a low viscosity base oil with kinematic viscosity of 5-60 mm2/s at 40° C., and 50-5 weight % of (B) a high viscosity base oil with kinematic viscosity of more than 300 mm2/s at 40° C. is proposed. By the use of this heat treatment oil composition for hardening of metallic material, it enables to generate little cooling unevenness, to assure the hardness of hardening processed product, and to reduce quenching distortion.Type: GrantFiled: April 26, 2002Date of Patent: March 25, 2008Assignee: Idemitsu Kosan Co., Ltd.Inventors: Katsumi Ichitani, Makoto Takeishi
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Publication number: 20080060257Abstract: A method for obtaining heavy oil is disclosed. The method includes mixing a material including heavy oil (e.g., oil sand) with a solvent including biodiesel to form a mixture and separating the mixture into a oil-enriched solvent phase and a residual sand phase. The method also can include introducing a solvent including biodiesel into an in-situ geological formation including heavy oil and collecting a mixture including biodiesel and heavy oil from the formation. For example, the mixture can be collected after the solvent travels through at least a portion of the formation by gravity. A method for producing biodiesel also is disclosed. The method includes microbially digesting asphaltenes to form a liquor including a fatty acid and reacting the fatty acid with an alcohol to produce biodiesel. This method can be used to convert petroleum asphaltenes and/or coal asphaltenes into biodiesel.Type: ApplicationFiled: September 8, 2006Publication date: March 13, 2008Inventor: Willem P. C. Duyvesteyn
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Patent number: 7332072Abstract: A process to prepare a waxy raffinate product by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch derived feed, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch derived feed have at least 30 carbon atoms; and, (b) isolating from the product of step (a) a waxy raffinate product having a T10 wt % boiling point of between 200° C. and 450° C. and a T90 wt % boiling point of between 400° C. and 650° C.Type: GrantFiled: March 5, 2002Date of Patent: February 19, 2008Assignee: Shell Oil CompanyInventors: Gilbert Robert Bernard Germaine, David John Wedlock
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Patent number: 7282134Abstract: A process for manufacturing a lubricating base oil by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an is dimerized oil; and d) hydrofinishing said isomerized oil to produce a lubricating base oil having specific desired properties.Type: GrantFiled: December 23, 2003Date of Patent: October 16, 2007Assignee: Chevron USA, Inc.Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug
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Patent number: 7241375Abstract: A heavy hydrocarbon composition with utility as a heavy hydrocarbon base stock comprising at least 95 wt % paraffin molecules, of which at least 90 wt % are isoparaffin, containing hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity, as measured by ASTM D-445, is above 8 cSt, has an initial boiling point of least 850° F. (454° C.) and an end boiling point of at least 1000° F. (538° C.), wherein the branching index (BI), as measured by the percentage of methyl hydrogens, and the branching proximity (CH2>4), as measured by the percentage of recurring methylene carbons which are four or more carbon atoms removed from an end group or branch, of said isoparaffinic hydrocarbon molecules, are such that: (a) BI?0.5(CH2>4)<15; and (b) BI+0.85(CH2>4)<45; as measured over the heavy hydrocarbon composition as a whole.Type: GrantFiled: August 29, 2003Date of Patent: July 10, 2007Assignee: ExxonMobil Research and Engineering CompanyInventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
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Patent number: 7217373Abstract: The present invention relates to refrigerant compositions comprising a fluorocarbon, an oxygenated lubricant, a non-oxygenated lubricant, and a compatibilizer.Type: GrantFiled: April 18, 2005Date of Patent: May 15, 2007Assignee: E.I. du Pont de Nemours and CompanyInventor: Barbara Haviland Minor
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Patent number: 7195706Abstract: A process for manufacturing a finished lubricant by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an isomerized oil; and d) hydrofinishing said isomerized oil, whereby a lubricating base oil is produced having specific desired properties; and e) blending the lubricating base oil with at least one lubricant additive.Type: GrantFiled: December 23, 2003Date of Patent: March 27, 2007Assignee: Chevron U.S.A. Inc.Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug, James N. Ziemer, Robert J. Farina, Mark L. Sztenderowicz
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Patent number: 7144497Abstract: A process for producing a lubricating base oil blend which comprises (a) recovering a Fischer-Tropsch derived distillate fraction characterized by a kinematic viscosity of about 2 cSt or greater but less than 3 cSt at 100 degrees C.; and (b) blending the Fischer-Tropsch derived distillate fraction with a petroleum derived base oil selected from the group consisting of a Group I base oil, a Group II base oil, a Group III base oil, and a mixture of two or more of any of the foregoing conventional base oils in the proper proportion to produce a lubricating base oil blend characterized as having a viscosity of about 3 or greater; also the base oil blends, finished lubricants, and their use in internal combustion engines.Type: GrantFiled: November 20, 2002Date of Patent: December 5, 2006Assignee: Chevron U.S.A. Inc.Inventors: Brent K. Lok, David Kramer, John M. Rosenbaum, Joseph Pudlak
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Patent number: 7141157Abstract: A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with a Fischer-Tropsch derived bottoms fraction; lubricating base oil compositions having a viscosity between about 3 and about 10 cSt at 100 degrees C. and a TGA Noack volatility of less than about 45 weight percent; and finished lubricants using the aforesaid lubricating base oils.Type: GrantFiled: March 11, 2003Date of Patent: November 28, 2006Assignee: Chevron U.S.A. Inc.Inventors: John Rosenbaum, David Kramer, Joseph Pudlak
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Patent number: 7083713Abstract: A composition of lubricating base oil having a weight percent of all molecules with at least one aromatic function less than 0.30, a weight percent of all molecules with at least one cycloparaffin function greater than 10, and a ratio of weight percent of molecules with monocycloparaffins to weight percent of molecules with multicycloparaffins greater than 15.Type: GrantFiled: December 23, 2003Date of Patent: August 1, 2006Assignee: Chevron U.S.A. Inc.Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug
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Patent number: 7053254Abstract: A method for improving the lubricating properties of a distillate base oil characterized by a pour point of 0 degrees C. or less and a boiling range having the 10 percent point falling between about 625 degrees F. and about 790 degrees F. and the 90 percent point falling between about 725 degrees F. and about 950 degrees F., the method comprises blending with said distillate base oil a sufficient amount of a pour point depressing base oil blending component to reduce the pour point of the resulting base oil blend at least 3 degrees C. below the pour point of the distillate base oil, wherein the pour point depressing base oil blending component is an isomerized Fischer-Tropsch derived bottoms product having a pour point that is at least 3 degrees C. higher than the pour point of the distillate base oil.Type: GrantFiled: November 7, 2003Date of Patent: May 30, 2006Assignee: Chevron U.S.A, Inc.Inventor: Stephen J. Miller
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Patent number: 7045055Abstract: This invention is directed to a method of operating a wormgear drive at high energy efficiency comprising filling an oil reservoir with a wormgear lubricant comprising an isomerized Fischer-Tropsch derived distillate fraction having a low traction coefficient and operating the wormgear drive with the filled oil reservoir at an equilibrium temperature between 20 and 225 degrees C. This invention is also directed to a process for reducing the traction coefficient of a higher-traction coefficient lubricating base oil by blending it with an isomerized Fischer-Tropsch derived distillate fraction. This invention is also directed to a wormgear lubricant comprising an isomerized Fischer-Tropsch distillate fraction and between 2 and 50 weight percent thickener.Type: GrantFiled: April 29, 2004Date of Patent: May 16, 2006Assignee: Chevron U.S.A. Inc.Inventors: James N. Ziemer, Susan M. Abernathy, John M. Rosenbaum, Stephen J. Miller, Mark E. Okazaki
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Patent number: 7015178Abstract: Disclosed is a lubricant base oil composition that comprises (a) from 80 to 98% by mass of a naphthenic synthetic lubricant base oil having a flash point of not lower than 140° C. and (b) from 2 to 20% by mass of an alcohol/fatty acid ester having a flash point of not lower than 150° C. of which the alcohol has a gem-type dimethyl structure, or comprises (a) from 85 to 99% by mass of a naphthenic synthetic lubricant base oil having a flash point of not lower than 140° C. and (c) from 1 to 15% by mass of a mineral oil having a kinematic viscosity at 40° C. of from 0.9 to 9.6 mm2/sec, a boiling point under normal pressure of from 150 to 400° C. and a % CA measured through ring analysis (in n-d-M process) of at most 10%. The lubricant base oil composition has a flash point of not lower than 150° C. and has a high traction coefficient at high temperatures, and its low-temperature flowability characteristic is good. The oil composition is favorable for traction drive fluid.Type: GrantFiled: May 24, 2002Date of Patent: March 21, 2006Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hidetoshi Koga, Hitoshi Hata, Toshiyuki Tsubouchi
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Patent number: 6872693Abstract: This invention relates to mineral oil based gear oils and transmission fluids which comprise a major amount of a mineral oil having an iodine number of less than 9 and where at least 55% of the saturates are aliphatic, and gear oil or transmission fluid additives. In one embodiment, the invention relates to a gear oil or transmission fluid composition comprising a major amount of lubricant basestock and at least one functional additive wherein a major amount of the lubricant basestock comprises a mineral oil having an iodine number of less than 9 and comprising at least 45% by weight of aliphatic saturates. These gear oils and transmission fluids have good viscosity and oxidation properties.Type: GrantFiled: May 24, 2000Date of Patent: March 29, 2005Assignee: The Lubrizol CorporationInventor: Robert W. Cain
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Patent number: 6869917Abstract: The present invention relates to a fully formulated lubicants comprising poly ?-olefins (PAOs), prepared from a mixed ?-olefin feed, which exhibit superior Noack volatility at low pour points, and methods for preparing the fully formulated lubricants. The fully formulated lubricants include PAOs that include mixtures of 1-decene and 1-dodecene. The PAOs may be prepared by polymerization/oligomerization using an alcohol promoted BF3 in conjunction with a combination of co-catalysts.Type: GrantFiled: August 16, 2002Date of Patent: March 22, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventors: Douglas E. Deckman, Mark D. Winemiller, William L. Maxwell, David J. Baillargeon, Norman Yang, Maria Caridad B. Goze
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Patent number: 6833484Abstract: The present invention relates blended hydrocarbonaceous products comprising Fischer Tropsch derived products that resist oxidation and to methods of inhibiting oxidation in Fischer Tropsch products. The present invention also relates to Fischer Tropsch products containing an effective amount of a petroleum-derived hydrocarbonaceous product such that the Fischer Tropsch product resists oxidation.Type: GrantFiled: June 15, 2001Date of Patent: December 21, 2004Assignee: Chevron U.S.A. Inc.Inventor: Dennis J. O'Rear
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Patent number: 6833065Abstract: The invention provides methods for preparing a blended lube base oils comprising at least one highly paraffinic Fischer Tropsch lube base stocks and at least one base stock composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof. The use of base stocks composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof improves the yield of lube base oils from Fischer Tropsch facilities, as well as provides moderate improvements in physical properties including additive solubility. The invention provides processes for obtaining such blended lube base oils using the products of Fischer Tropsch processes.Type: GrantFiled: August 15, 2003Date of Patent: December 21, 2004Assignee: Chevron U.S.A. Inc.Inventor: Dennis J. O'Rear
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Patent number: 6824671Abstract: The present invention relates to poly &agr;-olefins (PAO's) which exhibit superior Noack volatility at low pour points. Mixtures of 1-decene and 1-dodecene are polymerized using an alcohol promoted BF3 in conjunction with a combination of cocatalysts. The reaction mixture is distilled to remove the unreacted monomeric and dimeric species. The resulting product is then hydrogenated to saturate the oliogomers to provide a hydrogenated product which has a viscosity of 5 cSt. This product is distilled to provide PAO's of varying viscosity grades. The 4 cSt PAO is comprised mostly of trimers and tetramers while the 6 cSt product is comprised of trimers, tetramers, and pentamers.Type: GrantFiled: May 17, 2001Date of Patent: November 30, 2004Assignee: ExxonMobil Chemical Patents Inc.Inventors: Maria Caridad B. Goze, Norman Yang
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Patent number: 6821933Abstract: The invention relates to additives for improving the flowability of mineral oils, containing: A) 1-40 wt. % of at least one copolymer, which is oil-soluble and improves the cold flow properties of mineral oil, selected from A1) copolymers consisting of 80 to 96.5 mol % ethylene and 3.5-20 mol % vinyl esters of carboxylic acids with 1-20 C atoms and/or (meth)acrylic acid esters of alcohols with 1-8 C atoms, and A2) homopolymers or copolymers of esters, containing C10-C30 alkyl radicals, of ethylenically unsaturated carboxylic acids with up to 20 mol % of other olefinically unsaturated compounds, B) 20-80 wt. % of at least one poly-alpha-olefin with a molecular weight of 250-5000, derived from monoolefins with 3-5 C atoms, and C) 5-70 wt.Type: GrantFiled: December 13, 2002Date of Patent: November 23, 2004Assignee: Clariant International Ltd.Inventors: Michael Feustel, Matthias Krull, Hans-Jörg Oschmann
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Publication number: 20040224860Abstract: A lubricating oil composition comprising lubricating oil base oil is provided wherein such composition has a kinematic viscosity at 40° C. of from 18 to 60 mm2/s, a viscosity index of from 130 to 150 and a density at 15° C. of from 0.80 to 0.84 g.cm−3.Type: ApplicationFiled: February 18, 2004Publication date: November 11, 2004Inventors: Yoshiharu Baba, Keiichi Moriki, Mitsuhiro Nagakari, Minoru Saitou
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Patent number: 6806237Abstract: A lube base oil comprising a synthetic lube base oil, such as a Fischer Tropsch-derived component, and a non-synthetic lube base oil is defined that has improved stability to oxidation both during storage and during use in engines or other applications, even in the substantial absence of anti-oxidant additives and oxidation promoters.Type: GrantFiled: September 27, 2001Date of Patent: October 19, 2004Assignee: Chevron U.S.A. Inc.Inventor: Dennis J. O'Rear
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Publication number: 20040178118Abstract: A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with a Fischer-Tropsch derived bottoms fraction; lubricating base oil compositions having a viscosity between about 3 and about 10 cSt at 100 degrees C. and a TGA Noack volatility of less than about 45 weight percent; and finished lubricants using the aforesaid lubricating base oils.Type: ApplicationFiled: March 11, 2003Publication date: September 16, 2004Inventors: John Rosenbaum, David Kramer, Joseph Pudlak
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Patent number: 6787022Abstract: A process for the production of a winter diesel fuel from wax containing hydrocarbons produced by the Fischer-Tropsch hydrocarbon synthesis process. A 300° F.+ Fischer-Tropsch fraction is upgraded first by hydroisomerization followed by catalytic dewaxing resulting in a diesel fuel suitable for use as a winter diesel fuel having excellent cold flow properties and reduced emissions.Type: GrantFiled: May 2, 2000Date of Patent: September 7, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Paul Joseph Berlowitz, Daniel Francis Ryan, Robert Jay Wittenbrink, W. Berlin Genetti, Jack Wayne Johnson
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Publication number: 20040154958Abstract: This invention relates to base stocks and base oils that exhibit an unexpected combination of high viscosity index (130 or greater) and a ratio of measured-to-theoretical high-shear/low-temperature viscosity at −30 C. or lower and the methods of making them. Specifically, the present invention relates to low-viscosity base stocks and base oils as used in functional fluids. More specifically, the present invention relates to automatic transmission fluids showing surprising low temperature Brookfield viscosities and methods to produce them.Type: ApplicationFiled: October 3, 2003Publication date: August 12, 2004Inventors: Albert Gordon Alexander, Eugenio Sanchez, Kim Elizabeth Fyfe
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Publication number: 20040154957Abstract: This invention relates to lubricants comprising base stocks and base oils that exhibit an unexpected combination of high viscosity index (130 or greater) and a ratio of measured-to-theoretical high-shear/low-temperature viscosity at −30 C or lower and the methods of making them. Specifically, the present invention relates to novel high viscosity index, low-viscosity lubricants usable as wide-temperature lubricants, for example hyrdraulic oils, comprising novel low-viscosity base stocks, with improved performance in low-temperature viscosity, and methods to produce them.Type: ApplicationFiled: October 3, 2003Publication date: August 12, 2004Inventors: Angela J. Keeney, Eugenio Sanchez, Angela Stefana Galiano-Roth
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Publication number: 20040129603Abstract: This invention relates to base stocks and base oils that exhibit an unexpected combination of high viscosity index (130 or greater) and a ratio of measured-to-theoretical high-shear/low-temperature viscosity at −30C or lower and the methods of making them. Specifically, the present invention relates to low-volatility/low-viscosity lubricant base stocks, lubricant base stocks and base oils, formulated lubricant compositions or functional fluids comprising these base stocks and methods of making them. More particularly, this invention relates to lubricant compositions of low-temperature flow capability and low viscosity for passenger car motor lubricants of SAE 0W-XX grade (where XX=40 or lower), methods for optimizing fuel economy using the same, and methods or processes to produce them.Type: ApplicationFiled: October 3, 2003Publication date: July 8, 2004Inventors: Kim Elizabeth Fyfe, Eugenio Sanchez, David J. Baillargeon, James William Gleeson, Ian Alfred Cody, William John Murphy, Sylvain S. Hantzer, David W. Larkin, John E. Gallagher, Jeenok T. Kim
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Publication number: 20040118744Abstract: A lubricating base oil composition having at least 95 wt % saturates, of which saturates fraction between 10 and 30 wt % are cyclo-paraffins and the remainder being n- and iso-paraffins, having a viscosity index of above 120 and a pour point of below −15° C.Type: ApplicationFiled: January 9, 2004Publication date: June 24, 2004Inventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
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Publication number: 20040094453Abstract: A process for producing a lubricating base oil blend which comprises (a) recovering a Fischer-Tropsch derived distillate fraction characterized by a kinematic viscosity of about 2 cSt or greater but less than 3 cSt at 100 degrees C.; and (b) blending the Fischer-Tropsch derived distillate fraction with a petroleum derived base oil selected from the group consisting of a Group I base oil, a Group II base oil, a Group III base oil, and a mixture of two or more of any of the foregoing conventional base oils in the proper proportion to produce a lubricating base oil blend characterized as having a viscosity of about 3 or greater; also the base oil blends, finished lubricants, and their use in internal combustion engines.Type: ApplicationFiled: November 20, 2002Publication date: May 20, 2004Inventors: Brent K. Lok, David Kramer, John M. Rosenbaum, Joseph Pudlak
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Publication number: 20040079675Abstract: Automatic transmission fluid having a kinematic viscosity at 100° C. of between more than 4 cSt and 10 cSt, a dynamic viscosity at −40° C. of less than 10000 mPas comprising an additive package and a base oil, wherein the base oil fraction has at least 98 wt % saturates, of which saturates fraction the content of cyclo-paraffins is between 10 wt and 40 wt % and wherein the pour point of the base oil is less than −25° C.Type: ApplicationFiled: September 4, 2003Publication date: April 29, 2004Inventors: Gilbert Robert Bernard Germaine, Hans Dieter Mueller, David John Wedlock
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Publication number: 20040065581Abstract: The present invention relates to a process for converting Fischer-Tropsch wax to high quality lube basestocks using a molecular sieve Beta catalyst followed by a unidimensional intermediate pore molecular sieve with near circular pore structures having an average diameter of 0.50 nm to 0.65 nm wherein the difference between the maximum diameter and the minimum is ≦0.05 nm. Both catalysts comprise one or more Group VIII metals. For example, a cascaded two-bed catalyst system consisting of a first bed Pt/Beta catalyst followed by a second bed Pt/ZSM-48 catalyst is highly selective for wax isomerization and lube hydrodewaxing with minimal gas formation.Type: ApplicationFiled: October 8, 2002Publication date: April 8, 2004Inventors: Zhaozhong Jiang, Terry Eugene Helton, Randall David Partridge, Larry E. Hoglen
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Publication number: 20040067856Abstract: A synthetic, isoparaffinic heavy hydrocarbon composition useful as a heavy lubricant base stock contains hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity is above 8 cSt and has respective initial and end boiling points of at least 850 and 1000° F. (454 and 538° C.).Type: ApplicationFiled: October 8, 2002Publication date: April 8, 2004Inventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
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Patent number: 6713438Abstract: High performance engine oils and other liquid lubricants comprise a liquid lubricant basestock of low viscosity from 1.5 to 12 cSt (100C) with two dissolved polymer components of differing molecular weights. The basestock is preferably a single PAO or blend of PAOs with a co-basestock component which is preferably an ester or an alkylated aromatic of comparable viscosity. The lower molecular weight polymer is highly viscoelastic in character and is preferably an HVI-PAO; this component in the lubricant which provides unexpectedly high film thickness and unexpectedly good wear protection under conditions where the second, higher molecular weight polymer may lose some or all of its thickening power. The use of the highly viscoelastic low molecular weight polymer in combination with the higher molecular weight thickener enables the production of very widely cross-graded engine oils, especially oils with a low temperature grading of 0W or better.Type: GrantFiled: March 24, 1999Date of Patent: March 30, 2004Assignee: Mobil Oil CorporationInventors: David J. Baillargeon, Raymond J. Bergstra, Andrew Jackson, William L. Maxwell, G. James Johnston, Robert A. Pache
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Publication number: 20040055931Abstract: Process to prepare a spindle oil, light machine oil and a medium machine oil base oil grade by (a) performing a separate catalytic dewaxing on a spindle oil fraction, a light machine oil fraction and a medium machine oil fraction as obtained in a vacuum distillation of a bottoms fraction of a fuels hydrocracking process; (b) performing a separate hydrofinishing of the light and medium machine oil fractions obtained in step (a); (c) separating the low boiling compounds from the spindle oil, light machine oil and medium machine oil fractions as obtained in step (a) and (b) and obtaining the spindle oil, light machine oil and medium machine oil base oil grade; (e) wherein the vacuum distillation is performed by alternatingly performing the distillation in two modes wherein the first mode (d1) the bottoms fraction is separated into a gas oil fraction, a spindle oil fraction, a medium machine oil fraction and a first rest fraction boiling between said spindle oil and medium machine oil fraction and in the second mType: ApplicationFiled: June 18, 2003Publication date: March 25, 2004Inventors: Johannes Van Beijnum, Arjen Peter Geukema, Kevin John Anthony Polder
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Patent number: 6703353Abstract: A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with at least one additional Fischer-Tropsch derived distillate fraction having a viscosity of greater than 3.8 cSt at 100 degrees C.; lubricating base oil compositions having a viscosity between about 3 and about 10 cSt at 100 degrees C. and a TGA Noack volatility of less than about 35 weight percent; and finished lubricants using the aforesaid lubricating base oils.Type: GrantFiled: September 4, 2002Date of Patent: March 9, 2004Assignee: Chevron U.S.A. Inc.Inventors: Brent K. Lok, Russell R. Krug, John M. Rosenbaum, Joseph Pudlak, Stephen J. Miller
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Publication number: 20040033908Abstract: The present invention relates to a fully formulated lubicants comprising poly &agr;-olefins (PAOs), prepared from a mixed &agr;-olefin feed, which exhibit superior Noack volatility at low pour points, and methods for preparing the fully formulated lubricants. The fully formulated lubricants include PAOs that include mixtures of 1-decene and 1-dodecene. The PAOs may be prepared by polymerization/oligomerization using an alcohol promoted BF3 in conjunction with a combination of co-catalysts.Type: ApplicationFiled: August 16, 2002Publication date: February 19, 2004Inventors: Douglas E. Deckman, Mark D. Winemiller, William L. Maxwell, David J. Baillargeon, Norman Yang, Maria Caridad B. Goze