With Preliminary Treatment Of Feed Patents (Class 208/211)
  • Patent number: 6872752
    Abstract: The present invention relates to an olefinic naphtha and a process for producing lower olefinc from this naphtha. In the process of the present invention for producing lower olefins, preferably ethylene, at least a portion of a hydrocarbon asset is converted to synthesis gas and at least a portion of the synthesis gas is converted to an olefinic naphtha by a Fischer-Tropsch process. At least a portion of the olefinic naphtha is converted in a naphtha cracker to a product stream comprising lower olefins, and at least a portion of the lower olefins from the product stream of the cracker are recovered.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: March 29, 2005
    Assignee: Chevron U.S.A. Inc.
    Inventors: Dennis J. O'Rear, Guan Dao Lei
  • Patent number: 6858131
    Abstract: Feed oil is subject to atmospheric distillation, to thereby be separated into light oil or light distillate and atmospheric residue oil. The light distillate is catalytically contacted with pressurized hydrogen in the presence of a catalyst, resulting in a first hydrotreating step being executed. In this instance, various fractions of the light distillate produced in the atmospheric distillation are subject to hydrotreating in a lump. The atmospheric residue oil is then separated into a light matter and a heavy matter. The light matter is subject to second hydrotreating in the presence of a catalyst to produce refined oil (light matter), which is mixed with refined oil produced in the first hydrotreating to prepare a mixture. The mixture is used as gas turbine fuel oil.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: February 22, 2005
    Assignee: JGC Corporation
    Inventors: Tsuyoshi Okada, Yoshinori Mashiko, Shinichi Tokuda, Tomoyoshi Sasaki, Kozo Imura, Makoto Inomata, Toshio Tanuma
  • Patent number: 6855853
    Abstract: A process for the production of low benzene content gasoline is disclosed wherein a full boiling range naphtha is fractionated to produce a light naphtha, a medium naphtha and a heavy naphtha. The benzene is contained in the medium naphtha and this stream is subjected to hydrogenation to convert the benzene to cyclohexane which may be isomerized to improve the octane. The valuable olefins are removed in the light naphtha and the valuable heavier aromatics (toluene and xylenes) are removed in the heavy naphtha. In a preferred embodiment all of the reactions are carried out in distillation column reactors.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: February 15, 2005
    Assignee: Catalytic Distillation Technologies
    Inventors: Willibrord A. Groten, Kerry L. Rock
  • Patent number: 6843906
    Abstract: An integrated hydrotreating process which produces a high quality feed for the FCC to maintain sulfur in FCC gasoline to a level lower than 30 ppm from a high boiling feedstock and an ultra low sulfur diesel stream preferably less than 10 ppm from a cracked stock diesel boiling material. The high boiling feedstock is firstly hydrotreated to reduce the concentration of heterogeneous compounds which produces lower boiling hydrocarbonaceous compounds boiling in the diesel range. The resulting hydrocarbonaceous compounds boiling in the diesel range together with other cracked material in the diesel boiling range are further hydrotreated in a second hydrotreating zone to meet ultra low sulfur diesel specifications and high cetane index.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: January 18, 2005
    Assignee: UOP LLC
    Inventor: Odette T. Eng
  • Patent number: 6830678
    Abstract: The invention relates to a process of producing gasoline with a low sulphur content from a feedstock containing sulphur. This process comprises at least one step a1 of selectively hydrogenating the diolefins and acetylenic compounds, at least one separation of the gasoline (step b) obtained at step a1 into at least three fractions, at least one step c1 of treating the heavy gasoline separated at step b on a catalyst enabling the unsaturated sulphur compounds to be at least partially decomposed or hydrogenated and at least one step d to remove the sulphur and nitrogen from at least one intermediate fraction, followed by catalytic reforming.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: December 14, 2004
    Assignee: Institut Francais DuPetrole
    Inventors: Blaise Didillon, Denis Uzio, Quentin Debuisschert, Jean-Luc Nocca
  • Patent number: 6824676
    Abstract: A process for concurrently fractionating and treating a full range naphtha stream. The full boiling range naphtha stream is first subjected to simultaneous thioetherification and splitting into a light boiling range naphtha, an intermediate boiling range naphtha and a heavy boiling range naphtha. The intermediate boiling range naphtha containing thiophene and thiophene boiling range mercaptans is passed on to a polishing hydrodesulfurization reactor where a low sulfur, low olefin gas oil is concurrently fed to the polishing reactor to insure that a liquid phase is present.
    Type: Grant
    Filed: March 8, 2002
    Date of Patent: November 30, 2004
    Assignee: Catalytic Distillation Technologies
    Inventors: Gary G. Podrebarac, Willibrord A. Groten, Lawrence A. Smith, Jr.
  • Publication number: 20040232050
    Abstract: A process to continuously prepare a hydrocarbon product having a specified desired sulphur content lower than 0.05 wt %, starting from at least two or more high-sulphur hydrocarbon feedstocks having a sulphur content of above 0.
    Type: Application
    Filed: February 5, 2004
    Publication date: November 25, 2004
    Inventors: Bernard Martin, Jean-Luc Christian Rouby, Wouter Frederik Timmermans, Frederic Viel
  • Publication number: 20040222131
    Abstract: Processes for generating and removing oxidized sulfur species, and in particular sulfoxides, from crude oil and various fractions derived therefrom. Initially, the sulfur species present in the crude oil or fractions derived from the crude oil, is oxidized such that substantially all of the sulfur species are converted to sulfoxides and/or a combination of sulfoxides and sulfones. Thereafter, the fossil fuel containing the oxidized sulfur species are subjected to conventional hydrodesulfurization processes where substantially all of the sulfones are converted to hydrogen sulfide gas.
    Type: Application
    Filed: May 5, 2003
    Publication date: November 11, 2004
    Inventor: Mark Cullen
  • Publication number: 20040211705
    Abstract: A membrane process for the removal of sulfur species from a naphtha feed, in particular, a FCC light cat naphtha, without a substantial loss of olefin yield is disclosed. The process involves contacting a naphtha feed stream with a membrane having sufficient flux and selectivity to separate a sulfur deficient retentate fraction from a sulfur enriched permeate fraction, preferably, under pervaporation conditions. Sulfur deficient retentate fractions are useful directly into the gasoline pool. Sulfur-enriched permeate fractions are rich in sulfur containing aromatic and nonaromatic hydrocarbons and are further treated with conventional sulfur removal technologies, e.g. hydrotreating, to reduce sulfur content. The process of the invention provides high quality naphtha products having a reduced sulfur content and a high content of olefin compounds.
    Type: Application
    Filed: May 14, 2004
    Publication date: October 28, 2004
    Inventors: Lloyd Steven White, Richard Franklin Wormsbecher, Markus Lesemann
  • Publication number: 20040211706
    Abstract: A membrane process for the removal of sulfur species from a naphtha feed, in particular, a FCC light cat naphtha, without a substantial loss of olefin yield is disclosed. The process involves contacting a naphtha feed stream with a membrane having sufficient flux and selectivity to separate a sulfur deficient retentate fraction from a sulfur enriched permeate fraction, preferably, under pervaporation conditions. Sulfur deficient retentate fractions are useful directly into the gasoline pool. Sulfur-enriched permeate fractions are rich in sulfur containing aromatic and nonaromatic hydrocarbons and are further treated with conventional sulfur removal technologies, e.g. hydrotreating, to reduce sulfur content. The process of the invention provides high quality naphtha products having a reduced sulfur content and a high content of olefin compounds.
    Type: Application
    Filed: May 14, 2004
    Publication date: October 28, 2004
    Inventors: Lloyd Steven White, Richard Franklin Wormsbecher, Markus Lesemann
  • Publication number: 20040209771
    Abstract: The present invention pertains to a method for hydroprocessing a heavy hydrocarbon oil, comprising bringing a heavy hydrocarbon oil into contact with hydroprocessing catalyst I in the presence of hydrogen in a first stage, after which the effluent of the first stage is contacted in whole or in part with hydroprocessing catalyst II in the presence of hydrogen in a second stage. The method according to the invention combines efficient contaminant removal with high cracking rate and low sediment formation. The invention also pertains to the combination of catalysts.
    Type: Application
    Filed: May 21, 2004
    Publication date: October 21, 2004
    Inventors: Satoshi Abe, Katsuhisa Fujita
  • Publication number: 20040200759
    Abstract: Processes for generating and removing oxidized sulfur species, and in particular sulfones, from crude oil and various fractions derived therefrom. Initially, the sulfur species present in the crude oil or fractions derived from the crude oil, is oxidized such that substantially all of the sulfur species are converted to sulfones. Thereafter, the fossil fuel containing the oxidized sulfur species are subjected to conventional hydrodesulfurization processes where substantially all of the sulfones are converted to hydrogen sulfide gas.
    Type: Application
    Filed: April 11, 2003
    Publication date: October 14, 2004
    Inventor: Mark Cullen
  • Publication number: 20040195151
    Abstract: A process for concurrently fractionating and treating a full range naphtha stream. The full boiling range naphtha stream is first subjected to simultaneous thioetherification and splitting into a light boiling range naphtha, an intermediate boiling range naphtha and a heavy boiling range naphtha. The intermediate boiling range naphtha containing thiophene and thiophene boiling range mercaptans is passed on to a polishing hydrodesulfurization reactor where a low sulfur, low olefin gas oil is concurrently fed to the polishing reactor to insure that a liquid phase is present.
    Type: Application
    Filed: April 7, 2004
    Publication date: October 7, 2004
    Inventors: Gary G. Podrebarac, Willibrord A. Groten, Lawrence A. Smith
  • Publication number: 20040188327
    Abstract: A process for fractionating and treating of a full range naphtha stream. The full boiling range naphtha stream is first split into a light boiling range naphtha, an intermediate boiling range naphtha and a heavy boiling range naphtha. The bottoms are subjected to hydrodesulfurization and the effluent combined with the intermediate boiling range naphtha containing thiophene and thiophene boiling range mercaptans and subjected to a second hydrodesulfurization. The effluent from the polishing reactor may be combined with the light boiling range naphtha to produce a new full boiling range naphtha containing substantially less total sulfur than the original feed. The mercaptans in the light naphtha may be removed by thioetherification prior to splitting or by wet caustic wash afterwards. The object being to meet higher standards for sulfur removal, by treating the components of the naphtha feed with the process that preserves the olefinic while most expediently removing the sulfur compounds.
    Type: Application
    Filed: December 12, 2001
    Publication date: September 30, 2004
    Applicant: CATALYTIC DISTILLATION TECHNOLOGIES
    Inventor: Willibrord A. Groten
  • Patent number: 6793804
    Abstract: An integrated hydrotreating process which produces a high quality feed for the FCC to maintain sulfur in FCC gasoline to a level lower than 30 ppm from a high boiling feedstock and an ultra low sulfur diesel stream preferably less than 10 ppm from a cracked diesel boiling material. The high boiling feedstock is firstly hydrotreated to reduce the concentration of heterogeneous compounds which produces lower boiling hydrocarbonaceous compounds boiling in the diesel range and the resulting hydrotreated high boiling feedstock is separated in a high pressure stripper. The resulting hydrocarbonaceous compounds boiling in the diesel range together with other cracked and/or straight run material in the diesel boiling range are further hydrotreated in an integrated second hydrotreating zone to meet ultra low sulfur diesel specifications and a high cetane index.
    Type: Grant
    Filed: November 7, 2001
    Date of Patent: September 21, 2004
    Assignee: UOP LLC
    Inventors: David A. Lindsay, Gary R. Brierley, Tom N. Kalnes
  • Publication number: 20040178123
    Abstract: A process for the desulfurization of a full boiling range naphtha stream is disclosed in which a full boiling range naphtha is concurrently split in catalytic distillation column reactor into a light and a heavy naphtha and the light nahtha thioetherified. Only the heavy naphtha is treated to remove organic nitrogen catalyst poisons then hydrodesulfurized. Both the light and the light naphtha streams may be subject to a final hydrodesulfurization in polishing reactor.
    Type: Application
    Filed: March 2, 2004
    Publication date: September 16, 2004
    Applicant: CATALYTIC DISTILLATION TECHNOLOGIES
    Inventor: Gary G. Podrebarac
  • Patent number: 6790342
    Abstract: Processes are provided to produce a dilute ethylene stream and a dilute propylene stream from a cracked gas stream. One process comprises separating the cracked gas stream to produce a C3− stream and a C3+ stream; hydrogenating the C2− stream in a hydrogenation zone to remove a portion of the acetylene to produce the dilute ethylene stream and routing the C3+ stream to storage or other process unit. Another process comprises separating a cracked gas stream in a depropanizer zone to form a C3− stream and a C4+ stream; separating the C3− stream in a deethanizer zone to form a C2− and a C3 stream; hydrogenating a portion of the acetylene in the C2− stream in a hydrogenation zone to produce a dilute ethylene stream; and routing the C3 stream to storage or other process unit.
    Type: Grant
    Filed: February 27, 2002
    Date of Patent: September 14, 2004
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Rodney L. Porter, Anne M. Balinsky, Eric P. Weber
  • Publication number: 20040168956
    Abstract: A refined oil is obtained by using a heavy oil having a hydrogen content of 12 wt % or less as a feed oil, and after carrying out a solvent extraction process such that the hydrogen content increases by 0.2 wt % over that of the feed oil, hydrorefining process is carried out such that the hydrogen content increases by 0.5 wt % over the extracted oil. Thereby, an inexpensive heavy oil can be used as a feedstock, and using a simple and reliable method, refined oil can be produced.
    Type: Application
    Filed: March 18, 2004
    Publication date: September 2, 2004
    Inventors: Makoto Inomata, Tsuyoshi Okada, Akira Higashi, Hajime Sasaki, Susumu Kasahara, Yasushi Fujimura
  • Patent number: 6783659
    Abstract: A process is provided to produce a dilute ethylene stream and a dilute propylene stream to be used as feedstocks for producing olefin-based derivatives. Specifically, the dilute ethylene stream is used as a feedstock to produce ethylbenzene, and the dilute propylene stream is used as a feedstock to produce cumene, acrylic acid, propylene oxide and other propylene based derivatives.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: August 31, 2004
    Assignee: Chevron Phillips Chemical Company, L.P.
    Inventors: Rodney L. Porter, Anne M. Balinsky, Eric P. Weber
  • Publication number: 20040129606
    Abstract: A process for concurrently fractionating and hydrotreating a full range naphtha stream.
    Type: Application
    Filed: June 18, 2003
    Publication date: July 8, 2004
    Applicant: CATALYTIC DISTILLATION TECHNOLOGIES
    Inventors: Gary G. Podrebarac, Mario J. Maraschino, Montri Vichailak
  • Publication number: 20040118749
    Abstract: The present invention is directed to the removal of nitrogen and sulfur containing impurities from high molecular weight petroleum feedstock obtained from fluid cracking catalyst or distillation zone of a petroleum treatment plant. The present process comprises first treating C12 and higher hydrocarbon petroleum feedstock having nitrogen and sulfur containing compounds therein with a porous, particulate adsorbent comprising a silica matrix having an effective amount of metal atoms therein to cause the adsorbent to have Lewis acidity of at least 500 &mgr;mol/g and then treating the resultant feedstock to catalytic hydrodesulfurization to produce a hydrocarbon fuel having low sulfur and nitrogen content.
    Type: Application
    Filed: December 19, 2002
    Publication date: June 24, 2004
    Inventors: Markus Friedrich Manfred Lesemann, Constance Setzer
  • Publication number: 20040118748
    Abstract: The present invention is directed to the removal of nitrogen and sulfur containing impurities from high molecular weight petroleum feedstock obtained from fluid cracking catalyst or distillation zone of a petroleum treatment plant. The present process comprises first treating C12 and higher hydrocarbon petroleum feedstock having nitrogen and sulfur containing compounds therein with a porous, particulate adsorbent comprising a silica matrix having an effective amount of metal atoms therein to cause the adsorbent to have Lewis acidity of at least 500 &mgr;mol/g and then treating the resultant feedstock to catalytic hydrodesulfurization to produce a hydrocarbon fuel having low sulfur and nitrogen content.
    Type: Application
    Filed: December 19, 2002
    Publication date: June 24, 2004
    Inventors: Markus Friedrich Manfred Lesemann, Constanze Setzer
  • Publication number: 20040099574
    Abstract: A process for the treatment of a light cracked naphtha is disclosed wherein the light cracked naphtha is first subjected to thioetherification and fractionation into two boiling fractions. The lower boiling fraction is removed as overheads for later recombination with the product and the higher boiling fraction is combined with a heavy cracked naphtha and subjected to simultaneous hydrodesulfurization and fractionation to separate the higher boiling fraction from the heavy cracked naphtha which is recycled. The recycled heavy cracked naphtha is eventually desulfurized and hydrogenated to produce a clean solvent which washes the catalyst and extends catalyst life.
    Type: Application
    Filed: November 3, 2003
    Publication date: May 27, 2004
    Applicant: CATALYTIC DISTILLATION TECHNOLOGIES
    Inventors: Manoj Som, Gary G. Podrebarac, Scott W. Shorey
  • Publication number: 20040094455
    Abstract: For desulfurization of a hydrocarbon-containing feedstock, at least one stage for selective hydrogenation of diolefins present in the initial hydrocarbon feedstock, in the presence of a catalyst of group VIII of the period table, and a stage for extraction by a solvent of the resultant hydrogenated fraction under conditions that provide at least two fractions:
    Type: Application
    Filed: November 13, 2003
    Publication date: May 20, 2004
    Inventors: Florent Picard, Raphael Huyghe
  • Patent number: 6736961
    Abstract: A process for removing sulfur from a hydrocarbon employs a solid membrane. A feed stream is provided containing a feed liquid hydrocarbon and a feed sulfur species and a sweep stream is provided containing a sweep liquid hydrocarbon. A relatively large quantity of the feed stream is conveyed past one side of the solid membrane, while a relatively small quantity of the sweep stream is conveyed past the opposite side of the solid membrane. The feed sulfur species is transported in a permeate from the feed stream through the solid membrane to the sweep stream. As a result, the feed stream is converted to a relatively large quantity of a substantially sulfur-free reject stream containing a primary hydrocarbon product, while the sweep stream combines with the permeate to produce a relatively small quantity of a sulfur-enriched stream, which is amenable to further processing.
    Type: Grant
    Filed: January 30, 2001
    Date of Patent: May 18, 2004
    Assignee: Marathon Oil Company
    Inventors: Mark A. Plummer, Richard F. Bonelli, Jr.
  • Patent number: 6734472
    Abstract: A power and ground shield mesh to remove both capacitive and inductive signal coupling effects of routing in integrated circuit device. An embodiment describes the routing of a shield mesh of both power and ground lines to remove noise created by capacitive and inductive coupling. Relatively long signal lines are routed in between fully connected power and ground shield mesh which may be generated by a router during the signal routing phase or during power mesh routing phase. Leaving only the odd tracks or the even tracks for signal routing, power mesh (VDD) and ground mesh (VSS) are routed and fully interconnected leaving shorter segments and thereby reducing the RC effect of the circuit device. Another embodiment presents a technique where the signals are shielded using the power and ground mesh for a gridless routing. Another embodiment presents a multi-layer grid routing technique where signals are routed on even grid and the power and ground lines are routed on odd grid.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: May 11, 2004
    Assignee: Synplicity, Inc.
    Inventor: Iu-Meng Tom Ho
  • Publication number: 20040084351
    Abstract: The present invention relates to a method in which grades of oil are refined according to their object from a feed oil. This method has a solvent extraction process that obtains an extracted oil, and a hydrogenation process that subjects the obtained extracted oil to hydrogenation process in the presence of hydrogen and a catalyst to obtain a hydrorefined oil. The solvent extraction conditions are selected by using the poly-aromatic concentration as an index for calculating the concentration of heptane insolvent components in the residue of the extracted oil obtained by the solvent extraction process that cannot be fractionally distilled.
    Type: Application
    Filed: August 18, 2003
    Publication date: May 6, 2004
    Inventors: Yoshinori Mashiko, Akira Sugimoto, Tsuyoshi Okada
  • Patent number: 6726835
    Abstract: Savings in the processing of a naphtha boiling range feed containing a thiophene are achieved by fractionating the feed stream in a single dividing wall column to yield a C6-minus overhead stream, a side-draw containing the majority of the C6 and C7 paraffins and olefins, and a bottoms stream comprising C7 and heavier hydrocarbons. A dividing wall column provides better control of the concentration of both thiophene and toluene in the side-draw. Less of the valuable naphtha is lost and the amount of thiophene in the overhead product is minimized.
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: April 27, 2004
    Assignee: UOP LLC
    Inventors: Gavin P. Towler, Michael A. Schultz
  • Patent number: 6723230
    Abstract: A process to regenerate iron-based hydrogen sulfide sorbents using steam. The steam is preferably mixed with hydrogen-containing gas and/or an inert gas, such as nitrogen. In a preferred embodiment, the sorbent is first exposed to the steam and then exposed to a hydrogen-containing gas at regeneration conditions.
    Type: Grant
    Filed: July 21, 2000
    Date of Patent: April 20, 2004
    Assignee: ExxonMobil Research & Engineering Company
    Inventors: Jingguang G. Chen, Leo D. Brown, William C. Baird, Jr., Gary B. McVicker, Edward S. Ellis, Michele S. Touvelle, Darryl P. Klein, David E. W. Vaughan
  • Publication number: 20040069685
    Abstract: The oil refining method according to the present invention comprises the fractional distillation process 1 for distilling and separating the feed oil into the distillate M1 and the residue M2; the hydrorefining process 2 wherein at least a part of the distillate M1 is refined by hydrogenation and desulfurized thereby to obtain the hydrorefined oil M3; the solvent deasphalting process 3 wherein the residue M2 is deasphalted with a solvent thereby to obtain the deasphalted oil M4 as an extract and asphaltene (pitch) M5 as the residue; the hydrodemetalizating/desulfurizing process 4 wherein at least a part of the deasphalted oil M4 is demetalized and desulfurized by hydrogenation thereby to obtain the HDMS refined oil M6; and the first mixing process 5 wherein a part of the HDMS refined oil M6 and at least a part of the hydrorefined oil M3 are mixed thereby to produce oil products.
    Type: Application
    Filed: May 22, 2003
    Publication date: April 15, 2004
    Inventors: Makoto Inomata, Yasushi Fujimura, Tsuyoshi Okada, Kozo Imura, Hajime Sasaki
  • Publication number: 20040055934
    Abstract: The invention consists in a process for hydrotreating a heavy hydrocarbon fraction in a first hydrodemetallisation section, then in a second hydrodesulphurisation section into which the effluent from the first section is passed. The hydrodemetallisation section is preceded by at least one guard zone.
    Type: Application
    Filed: October 14, 2003
    Publication date: March 25, 2004
    Inventors: Pascal Tromeur, Stephane Kressmann
  • Publication number: 20040040889
    Abstract: A process for concurrently fractionating and hydrotreating of a full range naphtha stream. The full boiling range naphtha stream, for example which is derived from fluid catalytic cracking, is first subjected to simultaneous hydrogenation of the thiophene contained therein and thioetherification and fractionation to remove the mercaptans the light fraction and then to simultaneous hydrodesulfurization and splitting of the bottoms into an intermediate boiling range naphtha and a heavy boiling range naphtha. The three boiling range naphthas are treated separately according to the amount of sulfur in each cut and the end use of each fraction.
    Type: Application
    Filed: August 27, 2003
    Publication date: March 4, 2004
    Applicant: CATALYTIC DISTILLATION TECHNOLOGIES
    Inventor: Willibrord A. Groten
  • Publication number: 20040035752
    Abstract: A process for desulphurizing a gasoline feed comprising at least 150 ppm by weight of sulphur-containing compounds using a hydrodesulphurization catalyst is characterized in that said feed undergoes prior denitrogenation treatment under conditions such that the amount of nitrogen-containing compounds present in said feed when it is brought into contact with said hydrodesulphurization catalyst does not exceed 150 ppm by weight.
    Type: Application
    Filed: June 9, 2003
    Publication date: February 26, 2004
    Applicant: Institute Francais du Petrole
    Inventors: Nathalie Marchal-George, Florent Picard, Denis Uzio, Quentin Debuisschert, Jean-Luc Nocca
  • Patent number: 6692635
    Abstract: Process for the production of gasoline with a low sulfur content that comprises at least the following two stages: a) a hydrogenation stage of the unsaturated sulfur containing compounds, b) a decomposition stage of saturated sulfur containing compounds, and optionally a preliminary stage for pretreatment of the feedstock such as selective hydrogenation of dienes.
    Type: Grant
    Filed: February 23, 2000
    Date of Patent: February 17, 2004
    Assignee: Institut Francais du Petrole
    Inventors: Blaise Didillon, Denis Uzio, Nathalie Marchal
  • Patent number: 6676830
    Abstract: A process for the desulfurization of a light boiling range (C5-350° F.) fluid catalytically cracked naphtha, which may be first subjected to a thioetherification to react the diolefins with mercaptans contained in it to form sulfides, is fed to a high pressure (>250 psig) catalytic distillation hydrodesulfurization step along with hydrogen under conditions to react most of the organic sulfur compounds, including sulfides from the thioetherification to form H2S. The H2S and a light product stream (C5's and C6's) are removed as overheads. The bottoms from the catalytic distillation hydrodesulfurization step is fractionated and the bottoms from the fractionation contacted with hydrogen in a straight pass hydrogenation step in the presence of a hydrodesulfurization catalyst at pressure of >250 and temperature >400° F. to further reduce the sulfur content.
    Type: Grant
    Filed: September 17, 2001
    Date of Patent: January 13, 2004
    Assignee: Catalytic Distillation Technologies
    Inventors: Montri Vichailak, Bertrand Klussman, Mario J. Maraschino
  • Patent number: 6676829
    Abstract: A method is provided for removing sulfur from an effluent produced by hydrotreating a hydrocarbon feed, said effluent having a heavy fraction containing polyaromatic sulfur compounds and a lighter fraction, said method comprising contacting the effluent with a noble metal containing hydrodearomatization catalyst on a support under super-atmospheric hydrogen pressure and reaction conditions sufficient to hydrogenate at least one ring of said polyaromatic sulfur compounds and thereby produce a product with a reduced sulfur content.
    Type: Grant
    Filed: December 8, 1999
    Date of Patent: January 13, 2004
    Assignee: Mobil Oil Corporation
    Inventors: Philip J. Angevine, Anna B. Gorshteyn, Larry A. Green, Yuk Mui Louie, David A. Pappal, Peter J. Owens, Richard J. Quann, Jolie A. Rhinehart
  • Publication number: 20040000506
    Abstract: A light cracked naphtha is treated to convert mercaptans to sulfides and saturate dienes and then subjected to destructive hydrodesulfurization (HDS) to convert the organic sulfur compounds to hydrogen sulfide. The recombinant mercaptans formed by reaction of hydrogen sulfide and olefins at the outlet of the HDS are generally heavier than the light cracked naphtha is fractionated in admixture with a heavy cracked naphtha. A low sulfur content light cracked naphtha is produced as an overheads and the major portion of the mercaptans leave with heavy cracked naphtha as bottoms. It also advantageous to pass the heavy cracked naphtha through the HDS in admixture with the light cracked naphtha, since the recombinant mercaptans formed with the heavy cracked naphtha olefins (which displace some of the lower mercaptans which would form the light cracked naphtha olefins) will be even higher boiling and easier to separate by fractionation.
    Type: Application
    Filed: November 1, 2002
    Publication date: January 1, 2004
    Applicant: CATALYTIC DISTILLATION TECHNOLOGIES
    Inventors: Gary G. Podrebarac, Willibrord A. Groten, Manoj Som, Martinus J. Almering
  • Publication number: 20030188994
    Abstract: The invention relates to a process for forming a low-sulfur motor gasoline and the product made therefrom. In one embodiment, process involves separating a catalytically cracked naphtha into at least a light fraction boiling below about 165° F. and a heavy fraction boiling above about 165° F. The light fraction is treated to remove sulfur by a non-hydrotreating method, and the heavy fraction is hydrotreated to remove sulfur to a level of less than about 100 ppm.
    Type: Application
    Filed: January 15, 2003
    Publication date: October 9, 2003
    Inventors: Gordon F. Stuntz, Robert C. W. Welch, Thomas R. Halbert
  • Patent number: 6623627
    Abstract: A process for desulfurizing a gasoline stream while continuing to maintain the octane rating of the blend stock. A gasoline stream containing sulfur compounds and olefins is introduced into a fractionation zone to produce a low boiling fraction containing mercaptan sulfur compounds and olefins, a mid boiling fraction containing thiophene and olefins, and a high boiling fraction containing sulfur compounds. The low boiling fraction containing mercaptan sulfur compounds is contacted with an aqueous alkaline solution to selectively remove mercaptan sulfur compounds. The mid boiling fraction containing thiophene is extracted to produce a raffinate stream containing olefins and having a reduced sulfur content relative to the mid boiling fraction and a hydrocarbonaceous stream rich in thiophene.
    Type: Grant
    Filed: July 9, 2001
    Date of Patent: September 23, 2003
    Assignee: UOP LLC
    Inventor: Lubo Zhou
  • Publication number: 20030173252
    Abstract: The invention concerns a catalyst for the hydrogenation, hydroisomerisation, hydrocracking and/or hydrodesulfurisation, of hydrocarbon feedstocks, said catalyst consisting of a substantially binder free bead type support material obtained through a sol-gel method, and a catalytically active component selected from precious metals, the support comprising 5 to 50 wt. % of at least one molecular sieve material and 50 to 95 wt. % of silica-alumina.
    Type: Application
    Filed: February 5, 2003
    Publication date: September 18, 2003
    Inventor: Marius Vaarkamp
  • Publication number: 20030168380
    Abstract: Process for the production of gasoline with a low sulfur content that comprises at least the following two stages:
    Type: Application
    Filed: February 23, 2000
    Publication date: September 11, 2003
    Inventors: Blaise Didillon, Denis Uzio, Nathalie Marchal
  • Patent number: 6602405
    Abstract: A product of reduced sulfur content is produced from an olefin-containing hydrocarbon feedstock which includes sulfur-containing impurities. The feedstock is contacted with an olefin-modification catalyst in a reaction zone under conditions which are effective to produce an intermediate product which has a reduced amount of olefinic unsaturation relative to that of the feedstock as measured by bromine number. The intermediate product is then contacted with a hydrodesulfurization catalyst in the presence of hydrogen under conditions which are effective to convert at least a portion of its sulfur-containing impurities to hydrogen sulfide.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: August 5, 2003
    Assignee: BP Corporation North America Inc.
    Inventors: Vivek R. Pradhan, Ptoshia A. Burnett, George A. Huff
  • Patent number: 6599417
    Abstract: A product of reduced sulfur content is produced from an olefin-containing hydrocarbon feedstock which includes sulfur-containing impurities. The feedstock is contacted with an olefin-modification catalyst in a reaction zone under conditions which are effective to produce an intermediate product which has a reduced amount of olefinic unsaturation relative to that of the feedstock as measured by bromine number. The intermediate product is then separated into fractions of different volatility, and the lowest boiling fraction is contacted with a hydrodesulfurization catalyst in the presence of hydrogen under conditions which are effective to convert at least a portion of its sulfur-containing impurities to hydrogen sulfide.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: July 29, 2003
    Assignee: BP Corporation North America Inc.
    Inventors: Vivek R. Pradhan, Ptoshia A. Burnett, George A. Huff
  • Patent number: 6596157
    Abstract: The invention relates to a method and dual reactor system for hydrotreating a wide cut cat naphtha stream comprising heavy cat naphtha (HCN) and intermediate cat naphtha (ICN). Accordingly, a HCN fraction is hydrotreated under non-selective hydrotreating conditions and an ICN fraction is hydrotreated under selective hydrotreating conditions. The hydrotreated HCN and ICN effluents may be conducted to heat exchangers to pre-heat the ICN feed, obviating the need for a furnace.
    Type: Grant
    Filed: March 23, 2001
    Date of Patent: July 22, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Brij Gupta, John P. Greeley, Thomas R. Halbert
  • Patent number: 6596914
    Abstract: A multi-step process for desulfurizing liquid petroleum fuels that also removes nitrogen-containing compounds and aromatics. The process steps are: thiophene extraction; thiophene oxidation; thiophene-oxide and -dioxide extraction; raffinate solvent recovery and polishing; extract solvent recovery; and recycle-solvent purification. The thiophene oxidation is accomplished with hydrogen peroxide and the extraction solvent is acetic acid in combination with secondary solvents. The operating conditions in the process are relatively mild at near ambient pressure and less than 145° C. throughout the process, and the only chemical consumed in the process is hydrogen peroxide. The process design can be modified to accommodate a variety of liquid hydrocarbon feeds.
    Type: Grant
    Filed: August 25, 2001
    Date of Patent: July 22, 2003
    Inventors: Walter Gore, Steve Bonde, Geoffrey E. Dolbear, Ebbe R. Skov
  • Publication number: 20030116474
    Abstract: Savings in the processing of a naphtha boiling range feed containing a thiophene are achieved by fractionating the feed stream in a single dividing wall column to yield a C6-minus overhead stream, a side-draw containing the majority of the C6 and C7 paraffins and olefins, and a bottoms stream comprising C7 and heavier hydrocarbons. A dividing wall column provides better control of the concentration of both thiophene and toluene in the side-draw. Less of the valuable naphtha is lost and the amount of thiophene in the overhead product is minimized.
    Type: Application
    Filed: December 17, 2002
    Publication date: June 26, 2003
    Inventors: Gavin P. Towler, Michael A. Schultz
  • Patent number: 6569314
    Abstract: The present invention relates to a process for upgrading a liquid petroleum or chemical stream wherein said stream flows countercurrent to the flow of a treat gas, such as a hydrogen-containing gas, in at least one reaction zone. At least a fraction of up flowing vapor product is condensed to produce a condensate comprised of the heavier fraction of the vapor phase product stream and a lighter remaining vapor stream. The condensate and potentially the lighter remaining vapor stream are further hydroprocessed.
    Type: Grant
    Filed: December 7, 1999
    Date of Patent: May 27, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Larry L. Iaccino, Edward S. Ellis
  • Publication number: 20030094400
    Abstract: A process for removing sulfur from hydrocarbon streams is described. The organic sulfur compounds are first oxidized to create oxidized sulfur in the hydrocarbon stream and then processing the hydrocarbon stream with hydrogen at hydrodesulfurization conditions to reduce the sulfur to hydrogen sulfide, leaving a hydrocarbon gas stream substantially free of sulfur.
    Type: Application
    Filed: May 23, 2002
    Publication date: May 22, 2003
    Inventors: Robert Edward Levy, Alkis Stavros, Chakka Sudhakar, Vincent Paul Nero, Stephen Jude DeCanio
  • Patent number: 6554994
    Abstract: A reactor system and process for hydrotreating a heavy feedstock contaminated with metals sulfur and carbon residue using an upflow fixed bed reactor with at least two catalyst layers having different hydrogenation activity.
    Type: Grant
    Filed: April 13, 1999
    Date of Patent: April 29, 2003
    Assignee: Chevron U.S.A. Inc.
    Inventors: Bruce E. Reynolds, Fred W. Lam, Julie Chabot, Fernando J. Antezana, Robert Bachtel, Kirk R. Gibson, Richard Threlkel, Pak C. Leung
  • Patent number: 6554993
    Abstract: A membrane process for the removal of sulfur species from a naphtha feed, in particular, a FCC light cat naphtha, without a substantial loss of olefin yield is disclosed. The process involves contacting a naphtha feed stream with a membrane having sufficient flux and selectivity to separate a sulfur deficient retentate fraction from a sulfur enriched permeate fraction, preferably, under pervaporation conditions. Sulfur deficient retentate fractions are useful directly into the gasoline pool. Sulfur-enriched permeate fractions are rich in sulfur containing aromatic and nonaromatic hydrocarbons and are further treated with conventional sulfur removal technologies, e.g. hydrotreating, to reduce sulfur content. The process of the invention provides high quality naphtha products having a reduced sulfur content and a high content of olefin compounds.
    Type: Grant
    Filed: February 16, 2001
    Date of Patent: April 29, 2003
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Lloyd Steven White, Richard Franklin Wormsbecher, Markus Lesemann