With Hydrogen Patents (Class 208/209)
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Patent number: 11795426Abstract: A fixed-bed bioreactor system is provided that includes a vessel with a media inlet, a media outlet, and an interior cavity disposed between and in fluid communication with the media inlet and media outlet. The vessel further includes a cell culture substrate disposed in the interior cavity between the media inlet and the media outlet in a packed-bed configuration, the cell culture substrate including a plurality of porous disks in a stacked arrangement. The interior cavity includes a cell culture section and a spacer section, the cell culture substrate defining the cell culture section and the spacer section being disposed between the cell culture section and the media outlet, and each of the plurality of porous disks has a surface configured to culture cells thereon.Type: GrantFiled: August 13, 2021Date of Patent: October 24, 2023Assignee: CORNING INCORPORATEDInventors: Ann MeeJin Ferrie, Vasiliy Nikolaevich Goral
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Patent number: 10864508Abstract: Described are catalytic articles comprising a substrate having a washcoat on the substrate, the washcoat containing a catalytic component having a first average (D50) particle size and a functional binder component having a second average (D50) particle size in the range of about 10 nm to about 1000 nm, wherein the ratio of the first average (D50) particle size to the second average (D50) particle size is greater than about 10:1. The catalytic articles are useful in methods and systems to purify exhaust gas streams from an engine.Type: GrantFiled: January 15, 2016Date of Patent: December 15, 2020Assignee: BASF CorporationInventors: Gary A. Gramiccioni, Jaya L. Mohanan, John K. Hochmuth, Kenneth R. Brown, Brian Todd Jones
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Patent number: 10822555Abstract: A process reducing sulfides R1-S-R2, with R1 and R2 methyl or ethyl, in a gasoline containing diolefins, mono-olefins and sulphur: A) contacting gasoline in mixture with a light gasoline cut recycled from C) and hydrogen in a reactor with catalyst A at least one VIb metal and at least one non noble group VIII metal on a support, producing effluent having diolefins and sulfides R1-S-R2, with R1 and R2 methyl or ethyl radicals lower than that that of the starting gasoline; B) the effluent from A) is sent into a fractionating column separating at the top a light gasoline cut containing hydrocarbons having less than 6 carbon atoms per molecule and at the bottom a heavy gasoline cut containing hydrocarbons having 6 and more than 6 carbon atoms per molecule; C) recycling a part of the light gasoline from B) to the reactor of A) with a recycle ratio 0.1 to 0.7.Type: GrantFiled: February 17, 2016Date of Patent: November 3, 2020Assignee: IFP Energies nouvellesInventors: Philibert Leflaive, Clementina Lopez Garcia, Julien Gornay, Annick Pucci, Diamantis Asteris, Marie Godard-Pithon
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Patent number: 10793788Abstract: The present invention relates to a method for treating a pyrolysis gasoline C5+ containing monoolefinic, diolefinic and sulfur hydrocarbons, comprising at least, and in any order: a) a step of hydrotreating the pyrolysis gasoline or a hydrocarbon fraction C6+ originating from the pyrolysis gasoline, in the presence of hydrogen and at least one hydrotreatment catalyst at a temperature ranging between 220 and 380° C. so as to produce a hydrotreated effluent; b) a step of separating the pyrolysis gasoline or the hydrotreated effluent originating from step a) when said step is completed before step b), into a separation column for separating into a top hydrocarbon fraction C5? and a bottom hydrocarbon fraction C6+, said separation column comprising a reboiling section including two heat exchangers, at least one of the two exchangers being configured to perform a heat exchange with a portion of the bottom fraction that is recycled in the column via the reboiling section.Type: GrantFiled: September 1, 2017Date of Patent: October 6, 2020Assignee: IFP Energies NouvellesInventor: Adrien Gomez
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Patent number: 10377956Abstract: A process for the treatment of a gasoline containing sulphur-containing compounds, olefins and diolefins: a) fractionating the gasoline into at least: a light gasoline cut LCN; a primary intermediate gasoline cut, MCN; and a primary heavy gasoline cut HHCN; b) desulphurizing the primary intermediate gasoline cut MCN alone producing an at least partially desulphurized primary intermediate gasoline cut MCN; c) desulphurizing the primary heavy gasoline cut HHCN alone producing an at least partially desulphurized primary heavy gasoline cut HHCN; d) sending, as a mixture, the partially desulphurized primary intermediate gasoline cut MCN and the partially desulphurized primary heavy gasoline cut HHCN to a separation column separating a gaseous stream containing hydrogen and H2S, a secondary intermediate gasoline cut MCN with low sulphur and mercaptans contents and a secondary heavy gasoline cut HHCN containing sulphur-containing compounds including recombinant mercaptans; e) desulphurizing the secondary heavy gType: GrantFiled: October 19, 2017Date of Patent: August 13, 2019Assignee: IFP Energies nouvellesInventors: Adrien Gomez, Philibert Leflaive, Clementina Lopez Garcia, Annick Pucci, Marie Godard-Pithon, Jean-Luc Nocca, Guobing Zhang
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Patent number: 10377957Abstract: A process for the treatment of a gasoline containing sulphur-containing compounds, olefins and diolefins, comprising the following steps: a) fractionating the gasoline in a manner such as to recover at least one intermediate gasoline cut, MCN, comprising hydrocarbons and wherein the temperature difference (?T) between the 5% and 95% by weight distillation points is less than 60° C.; b) desulphurizing the intermediate gasoline cut MCN alone and in the presence of a hydrodesulphurization catalyst and hydrogen in a manner such as to produce a partially desulphurized intermediate gasoline cut MCN; and c) fractionating, in a splitter, the at least partially desulphurized intermediate gasoline cut MCN which has not undergone catalytic treatment subsequent to step b), in a manner such as to recover an intermediate gasoline with low sulphur and mercaptans contents from the column head and a cut of hydrocarbons containing sulphur-containing compounds including mercaptans from the column bottom.Type: GrantFiled: April 5, 2017Date of Patent: August 13, 2019Assignee: IFP Energies nouvellesInventors: Clementina Lopez Garcia, Philibert Leflaive, Annick Pucci, Jean-Luc Nocca
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Patent number: 10253271Abstract: Systems and methods for refining conventional crude and heavy, corrosive, contaminant-laden carbonaceous crude (Opportunity Crude) in partially or totally separated streams or trains.Type: GrantFiled: January 23, 2018Date of Patent: April 9, 2019Assignee: Bechtel Hydrocarbon Technology Solutions, Inc.Inventors: Benjamin Klein, Odette Eng
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Patent number: 9982204Abstract: One exemplary embodiment can be a process for producing a chemical feedstock. The process can include passing a feed to a hydrotreatment zone, passing an effluent from the hydrotreatment zone to a fractionation zone, passing a stream including one or more C5-C25 hydrocarbons from the fractionation zone to a fluid catalytic cracking zone to obtain an another stream including one or more C6-C10 hydrocarbons, and passing the another stream to an adsorption zone for removing at least one heteroatom compound having a sulfur or a nitrogen atom.Type: GrantFiled: May 14, 2014Date of Patent: May 29, 2018Assignee: UOP LLCInventors: Christopher D. Gosling, Gavin P. Towler
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Patent number: 9914891Abstract: Methods of maximizing diesel production are describes. The methods include providing a stream of heavy heavy naphtha; and blending the stream of heavy heavy naphtha with a diesel stream from the crude distillation zone to increase diesel production while maintaining the blended diesel stream within a specification for diesel. Various apparatus for maximizing diesel production are also described.Type: GrantFiled: November 24, 2014Date of Patent: March 13, 2018Assignee: UOP LLCInventors: Jeffrey M. Bray, James P. Glavin, Daniel J. Pintar, Xin X. Zhu
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Patent number: 9909075Abstract: Systems and methods for refining conventional crude and heavy, corrosive, contaminant-laden carbonaceous crude (Opportunity Crude) in partially or totally separated streams or trains.Type: GrantFiled: September 30, 2014Date of Patent: March 6, 2018Assignee: Bechtel Hydrocarbon Technology Solutions, Inc.Inventors: Benjamin Klein, Odette Eng
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Patent number: 9478817Abstract: A fuel cell system includes: a reformer operative to generate a reformed gas by using a raw material gas; a fuel cell operative to generate electric power by using the reformed gas from the reformer and air; a desulfurizer operative to perform hydrodesulfurization of the raw material gas; a recycled gas passage through which a part of the reformed gas is supplied as a recycled gas to a raw material gas passage provided upstream of the desulfurizer; and a heat exchanger operative to cause the recycled gas flowing through the recycled gas passage to perform heat exchange with one of the raw material gas and the air.Type: GrantFiled: November 14, 2013Date of Patent: October 25, 2016Assignee: Panasonic Intellectual Property Management Co., Ltd.Inventors: Toru Sukawa, Noboru Taniguchi
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Patent number: 9453168Abstract: A method and a product made by treating a sulfur-containing hydrocarbon heavy feed, e.g., heavy crude asphaltene reduction is disposed herein. The method comprises the steps of: mixing the sulfur-containing hydrocarbon heavy feed with a hydrogen donor solvent and an addled silica to form a mixture and oxidizing the sulfur in the mixture at a temperature between 50° C. and 210° C. wherein the oxidation lowers the amount sulfur in the sulfur-containing hydrocarbon heavy feed by at least 90%.Type: GrantFiled: December 2, 2014Date of Patent: September 27, 2016Assignee: Board of Regents, The University of Texas SystemInventors: Karina Castillo, Jason Parsons, Russell R. Chianelli
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Patent number: 9359917Abstract: A cost-effective solution for the disposal of heavy residue bottoms recovered from a slurry hydrocracking process that include solid heterogeneous catalyst particles is provided by their introduction into a membrane wall gasification reactor in the form of a flowable slurry to produce a synthesis gas and, optionally, subjecting the synthesis gas to a water-gas shift reaction to produce a more hydrogen-rich product stream. Process steam and electricity are produced by recovering the sensible heat values from the hot synthesis gas.Type: GrantFiled: June 15, 2015Date of Patent: June 7, 2016Assignee: Saudi Arabian Oil CompanyInventors: Omer Refa Koseoglu, Jean-Pierre Ballaguet
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Patent number: 9017547Abstract: The recycle gas stream containing hydrogen that is part of the feedstream to a hydroprocessing reactor is mixed with the low purity make-up hydrogen and the sour flash gases upstream of the recycle gas compressor and compressed by the recycle gas compressor. The compressed gases pass through a methane and higher (C1+) absorber to produce a sweet hydrogen recycle gas stream that is delivered to the hydroprocessing reactor at 96-98 mol % hydrogen. The process can be used to advantage in existing process facilities to increase the hydrogen partial pressure in the feedstream to the hydroprocessor where the existing recycle gas compressor is not designed for compressing the high purity hydrogen.Type: GrantFiled: July 20, 2005Date of Patent: April 28, 2015Assignee: Saudi Arabian Oil CompanyInventors: Yuv R. Mehra, Ali H. Al-Abdulai
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Patent number: 9005430Abstract: The invention relates to the integration of a process for hydrotreatment of distillates (light and/or middle), that operates under a hydrogen partial pressure of 0.5 to 6.0 MPa, with a process for hydrotreatment/hydroconversion of middle and/or heavy distillates that operates at a hydrogen partial pressure that is at least 4.0 MPa higher than the hydrogen partial pressure of the process for hydrotreatment of distillates (light and/or middle). The integration resides in the use of the hydrogen-rich gas, obtained from the hydrotreatment/hydroconversion effluents, in the process for hydrotreatment of distillates (light and/or middle) and in the adjustment of the pressure level of this hydrogen-rich gas removed from the hydrotreatment/hydroconversion. This invention makes it possible to considerably reduce the net consumption of make-up hydrogen in the process for hydrotreatment of distillates (light and/or middle).Type: GrantFiled: December 10, 2009Date of Patent: April 14, 2015Assignee: IFP Energies NouvellesInventors: Antoine Fournier, Jean Luc Nocca
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Patent number: 8974660Abstract: There is provided a method for upgrading hydrocarbon compounds, in which hydrocarbon compounds synthesized in a Fisher-Tropsch synthesis reaction are fractionally distillated, and the fractionally distillated hydrocarbon compounds are hydrotreated to produce liquid fuel products. The method includes fractionally distilling heavy hydrocarbon compounds synthesized in the Fisher-Tropsch synthesis reaction as a liquid into a first middle distillate and a wax fraction, and fractionally distilling light hydrocarbon compounds synthesized in the Fisher-Tropsch synthesis reaction as a gas into a second middle distillate and a light gas fraction.Type: GrantFiled: February 26, 2010Date of Patent: March 10, 2015Assignees: Japan Oil, Gas and Metals National Corporation, Inpex Corporation, JX Nippon Oil & Energy Corporation, Japan Petroleum Exploration Co., Ltd., Cosmo Oil Co., Ltd., Nippon Steel Engineering Co., Ltd.Inventors: Yuichi Tanaka, Yasumasa Morita, Kenichi Kawazuishi
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Patent number: 8968552Abstract: An intermediate hydrogen separation and purification system is integrated with a hydrotreating and an aromatic saturation process for the production of relatively lower molecular weight products from a relatively heavy feedstock including sulfur-containing and aromatic-containing hydrocarbon compounds. The integrated process allows the processing of heavy hydrocarbon feedstock having high aromatic and high sulfur contents in a single-stage configuration and the using of noble metal catalyst in the aromatic saturation zone. The integrated process increases the overall catalytic activity and hydrogenation capability to produce superior distillate products.Type: GrantFiled: November 2, 2012Date of Patent: March 3, 2015Assignee: Saudi Arabian Oil CompanyInventors: Vinod Ramaseshan, Ali Hasan Al-Abdulal, Yuv Raj Mehra
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Patent number: 8936714Abstract: A process is disclosed for hydrocracking a primary hydrocarbon feed and a diesel co-feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The diesel stream fed through the hydrocracking unit is pretreated to reduce sulfur and ammonia and can be upgraded with noble metal catalyst.Type: GrantFiled: November 28, 2012Date of Patent: January 20, 2015Assignee: UOP LLCInventors: Peter Kokayeff, Paul R. Zimmerman
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Patent number: 8936716Abstract: A process is disclosed for recovering hydroprocessing effluent from a hydroprocessing unit utilizing a hot stripper and a cold stripper. A net overhead stream from the hot stripper is forwarded to the cold stripper for further stripping. The invention is particularly suitable for hydrotreating residue feed streams. The hot stripped stream may be subjected to fluid catalytic cracking. The apparatus and process eliminates the need for a fired heater in the product recovery unit.Type: GrantFiled: August 19, 2011Date of Patent: January 20, 2015Assignee: UOP LLCInventors: Richard K. Hoehn, Vedula K. Murty
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Patent number: 8932453Abstract: This invention relates to a hydroprocessing process with improved catalyst activity when hydroprocessing petroleum based feedstock or an oxygen containing feedstock. This invention also relates to a hydrotreating process with improved hydrodesulfurization (HDS) activity of a hydrotreating catalyst such as Co/Mo by co-feeding carbon monoxide or its precursors. Such inventive process confirms that adding a small amount of CO to H2 in a hydrotreater for a few days leads to an increase in product sulfur due to the inhibition of CO on the hydrotreating catalyst such as Co/Mo. However, it has been unexpectedly found that after the CO was removed from the hydrogen stream, product sulfur levels decreased to values below they were before CO addition which means the activity of the hydrotreating catalyst increased after the CO treatment.Type: GrantFiled: June 1, 2011Date of Patent: January 13, 2015Assignee: Phillips 66 CompanyInventors: Jianhua Yao, Dhananjay B. Ghonasgi, Xiaochun Xu, Larry D. Swinney
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Patent number: 8926825Abstract: Methods for removing sulfur from hydrocarbon streams using the sequential application of hydrodesulfurization, fractionation and oxidation. The hydrodesulfurization step is operative to remove easily-hydrogenated sulfur species, such as sulfides, disulfides and mercaptans. The resultant stream is then fractionated at a select temperature range to generate a sub-stream that is sulfur-rich with the sulfur species resistant to removal by hydrodesulfurization. The sub-stream is then isolated and subjected to an oxidative process operative to oxidize the sulfur species to sulfones or sulfoxides, which may then be removed by a variety of conventional methods, such as absorption. Alternatively, the methods may comprise using the sequential application of fractionation to generate a sulfur-rich sub-stream followed by oxidation and subsequent removal of the sulfur species present in the sub-fraction. The latter methods are ideally suited for transmix applications.Type: GrantFiled: March 17, 2011Date of Patent: January 6, 2015Inventor: Mark Cullen
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Patent number: 8920631Abstract: The invention relates to a method for removing sulfur from crude oils using a catalytic hydrotreating process operating at moderate temperature and pressure and reduced hydrogen consumption. The process produces sweet crude oil having a sulfur content of between about 0.1 and 1.0 wt % in addition to reduced crude density. The method employs least two reactors in series, wherein the first reactor includes a hydroconversion catalyst and the second reactor includes a desulfurization catalyst.Type: GrantFiled: November 8, 2012Date of Patent: December 30, 2014Assignee: Saudi Arabian Oil CompanyInventors: Stephane Cyrille Kressmann, Raheel Shafi, Ali Hussain Alzaid, Esam Z. Hamad
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Patent number: 8894844Abstract: The invention includes a hydrotreating method for increased CO content comprising: contacting an olefinic naphtha feedstream with a hydrogen-containing treat gas stream and a hydrotreating catalyst in a reactor under hydrotreating conditions sufficient to at least partially hydrodesulfurize and/or hydrodenitrogenate the feedstream, wherein the feedstream and the hydrogen-containing treat gas stream collectively have greater than 10 vppm CO content and/or wherein the reactor inlet sees an average CO concentration of greater than 10 vppm, wherein the hydrotreating catalyst comprises a catalyst having cobalt and molybdenum disposed on a silica-based support, and wherein the hydrotreating conditions are selected such that the catalyst has a relative HDS activity at least 10% greater than an identical catalyst under identical conditions except for a collective CO content of the feedstream and/or hydrogen-containing treat gas being <10 vppm and/or a reactor inlet CO content <10 vppm.Type: GrantFiled: March 20, 2012Date of Patent: November 25, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: April D. Ross, Thomas R. Halbert, William J. Novak, John P. Greeley
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Patent number: 8888990Abstract: A process and apparatus are disclosed for hydrotreating a hydrocarbon feed in a hydrotreating unit and hydrocracking a second hydrocarbon stream in a hydrocracking unit. The hydrocracking unit and the hydrotreating unit may share the same recycle gas compressor. A make-up hydrogen stream may also be compressed in the recycle gas compressor. The second hydrocarbon stream may be a diesel stream from the hydrotreating unit. The diesel stream may be a diesel and heavier stream from a bottom of a hydrotreating fractionation column.Type: GrantFiled: March 29, 2012Date of Patent: November 18, 2014Assignee: UOP LLCInventors: Paul R. Zimmerman, Peter Kokayeff
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Patent number: 8877039Abstract: One exemplary embodiment can be a process for hydrocarbon conversion. The process can include providing a feed to a slurry hydrocracking zone, obtaining a hydrocarbon stream including one or more C16-C45 hydrocarbons from the at least one separator, providing another feed to a hydrocracking zone, and providing hydrogen from a three-stage compressor to the slurry hydrocracking zone and the hydrocracking zone. Moreover, the slurry hydrocracking zone may include a slurry hydrocracking reactor and at least one separator.Type: GrantFiled: March 28, 2012Date of Patent: November 4, 2014Assignee: UOP LLCInventors: Mark Van Wees, Robert Haizmann
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Patent number: 8871082Abstract: A process and apparatus are disclosed for hydrotreating a hydrocarbon feed in a hydrotreating unit and hydrocracking a second hydrocarbon stream in a hydrocracking unit. The hydrocracking unit and the hydrotreating unit may share the same recycle gas compressor. A make-up hydrogen stream may also be compressed in the recycle gas compressor. A hydrocracking separator separates recycle gas and hydrocarbons from the hydrocracking unit to be processed with effluent from the hydrotreating unit.Type: GrantFiled: March 29, 2012Date of Patent: October 28, 2014Assignee: UOP LLCInventors: Paul R. Zimmerman, Peter Kokayeff
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Patent number: 8864980Abstract: A process for hydrotreating a first aromatics- and sulfur-containing hydrocarbon feed using a fresh supported CoMo catalyst, includes treating the fresh catalyst under first hydrotreating conditions with a second hydrocarbon feed having a lower aromatics content than the first feed.Type: GrantFiled: February 21, 2011Date of Patent: October 21, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Iulian Nistor, John Zengel, Sabato Miseo, Roman Krycak, Teh C. Ho
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Patent number: 8846564Abstract: A process for the sulfidation of a sour gas shift catalyst, wherein the temperature of the sulfidation feed stream is coordinated with the sulfur/hydrogen molar ratio in that feed stream to obtain enhanced performance of the sour gas shift catalyst. In the sulfidation process to produce a sour gas shift catalyst, the lower the sulfur to hydrogen molar ratio of the sulfidation feed stream, the lower the required temperature of the sulfidation feed stream. The sulfidation reaction can be further enhanced by increasing the pressure on the sulfidation feed stream.Type: GrantFiled: September 25, 2009Date of Patent: September 30, 2014Assignee: Clariant CorporationInventors: Justin X. Wang, Yeping Cai
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Patent number: 8828218Abstract: This invention provides methods for multi-stage hydroprocessing treatment of FCC naphthas for improving the overall production quantity of naphtha boiling-range materials during naphtha production for low sulfur gasolines. Of particular benefit of the present processes is the selective treating of cat naphthas to remove gums instead of undercutting the overall naphtha pool by lowering the end cutpoints of the cat naphtha fraction. This maximizes the amount of refinery cat naphtha that can be directed to the gasoline blending pool while eliminating existing processing problems in hydrodesulfurization units. The processes disclosed herein have the additional benefit of minimizing octane losses in the increased naphtha pool volume.Type: GrantFiled: October 19, 2012Date of Patent: September 9, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: John Peter Greeley, Timothy Lee Hilbert, William Joseph Novak, Rohit Garg
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Patent number: 8821715Abstract: An electrochemical catalytic method for the hydrodesulfurization of a petroleum-based hydrocarbon stream is described involving a hydrogen-containing gas in an electrochemical cell employing Non Faradic Electrochemical Modification of Electrochemical Activity.Type: GrantFiled: May 24, 2011Date of Patent: September 2, 2014Assignee: Saudi Arabian Oil CompanyInventors: Ahmad D. Hammad, Esam Zaki Hamad, Mohamed Saber Mohamed Elanany
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Patent number: 8822742Abstract: This invention relates to process for increasing color quality and thermal stability of fuel. Fuel that is provided as a feedstock is contacted or treated with an acidic, ion-exchange resin to increase the color quality and stability of the fuel. The process provides the benefit of substantially increasing the long term quality of both color and oxidation (JFTOT) stability.Type: GrantFiled: November 15, 2010Date of Patent: September 2, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Marc-Andre Poirier, Ashok Uppal
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Patent number: 8815081Abstract: A continuous process to upgrade heavy crude oil for producing more valuable crude feedstock having high API gravity, low asphaltene content, and high middle distillate yield, low sulfur content, low nitrogen content, and low metal co teat without external supply of hydrogen and/or catalyst. Heavy crude oil having substantial amount of asphaltene and heavy components is mixed with highly waxy crude oil having large amount of paraffinic components and water to decompose asphaltene compounds and remove sulfur, nitrogen, and metal containing substances under supercritical conditions. Product has higher API gravity, lower asphaltene content, high middle distillate yield, lower sulfur content, lower nitrogen content, and lower metal content to be suitable for conventional petroleum refining process.Type: GrantFiled: November 24, 2008Date of Patent: August 26, 2014Assignee: Saudi Arabian Oil CompanyInventor: Ki-Hyouk Choi
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Patent number: 8807214Abstract: Heavy crude oils having high sulfur content and viscosities are upgraded by a hydrodesulfurization (HDS) process that includes microwave irradiation of a mixture of the sour heavy crude oil with at least one catalyst and optionally, one or more sensitizers, and irradiation in the presence of hydrogen. The process is also adapted to microwave treatment of hard to break emulsions, either above ground or below ground where water-in-oil emulsions are initially formed, followed by the catalytic hydrodesulfurization promoted by application of further microwave energy to the demulsified crude oil stream.Type: GrantFiled: March 22, 2013Date of Patent: August 19, 2014Assignee: Saudi Arabian Oil CompanyInventors: M. Rashid Khan, Emad Naji Al-Shafei
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Patent number: 8795514Abstract: The present invention relates to a regenerated hydrotreatment catalyst regenerated from a hydrotreatment catalyst for treating a petroleum fraction, the hydrotreatment catalyst being prepared by supporting molybdenum and at least one species selected from metals of Groups 8 to 10 of the Periodic Table on an inorganic carrier containing an aluminum oxide, wherein a residual carbon content is in the range of 0.15 mass % to 3.0 mass %, a peak intensity of a molybdenum composite metal oxide with respect to an intensity of a base peak is in the range of 0.60 to 1.10 in an X-Ray diffraction spectrum, and a peak intensity of a Mo—S bond derived from a residual sulfur peak with respect to an intensity of a base peak is in the range of 0.10 to 0.60 in a radial distribution curve obtained from an extended X-ray absorption fine structure spectrum of an X-ray absorption fine structure analysis.Type: GrantFiled: November 8, 2010Date of Patent: August 5, 2014Assignees: JX Nippon Oil & Energy Corporation, Japan Petroleum Energy CenterInventors: Nobuharu Kimura, Yoshimu Iwanami, Wataru Sahara, Souichirou Konno
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Publication number: 20140209509Abstract: Herein disclosed is a method for hydrogenation comprising: supersaturating a hydrocarbonaceous liquid or slurry stream in a high shear device with a gas stream comprising hydrogen and optionally one or more C1-C6 hydrocarbons to form a supersaturated dispersion; and introducing the supersaturated dispersion into a reactor in the presence of a hydrogenation catalyst to generate a product stream. In some embodiments, the catalyst is present as a slurry or a fluidized or fixed bed of catalyst. In some embodiments, the hydrogenation catalyst is mixed with the hydrocarbonaceous liquid or slurry stream and the gas stream in the high shear device. In some embodiments, the method further comprises recycling at least a portion of an off gas from the reactor, recycling at least a portion of the product stream from the reactor, or both. Also disclosed herein is a system for hydrogenation.Type: ApplicationFiled: March 8, 2013Publication date: July 31, 2014Applicant: H R D CorporationInventors: Abbas Hassan, Aziz Hassan, Rayford G. Anthony, Gregory G. Borsinger
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Patent number: 8784646Abstract: For conversion of crude oil or a heavy hydrocarbon fraction having an initial boiling point of at least 300° C., conducting a catalytic hydroconversion in a three-phase reactor operating in a boiling bed with an upward flow of liquid and gas, separating resultant effluent into a light liquid fraction boiling at less than 300° C. and a heavy liquid fraction boiling above 300° C., deasphalting the heavy liquid fraction to obtain a deasphalted hydrocarbon fraction and residual asphalt, and recycling at least one portion of the deasphalted hydrocarbon fraction upstream of the hydroconversion stage.Type: GrantFiled: September 7, 2011Date of Patent: July 22, 2014Assignee: IFP Energies NouvellesInventors: Eric Sanchez, Jan Verstraete
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Patent number: 8778169Abstract: Conversion of a heavy hydrocarbon fraction that is obtained either from a crude oil or from the distillation of a crude oil and that has an initial boiling point of at least 300° C. by hydroconversion of at least one portion of heavy hydrocarbon fraction in the presence of hydrogen in at least one three-phase reactor containing at least one hydroconversion catalyst, separation of the effluent to obtain a light liquid fraction that boils at a temperature that is less than 300° C. and a heavy liquid fraction that boils at a temperature that is greater than 300° C., and a deasphalting of at least one portion of the heavy liquid fraction that boils at a temperature that is greater than 300° C.Type: GrantFiled: September 7, 2011Date of Patent: July 15, 2014Assignee: IFP Energies NouvellesInventors: Eric Sanchez, Jan Verstraete
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Patent number: 8764970Abstract: The present invention relates to quenching, during hydroprocessing of a hydrocarbon feed stream. More particularly, the present invention provides for quenching in hydroprocessing of a hydrocarbon feed stream through a hydroprocessing vessel. Liquid quenches (from high pressure hot separator) were installed to assist in cooling the reactor inter-bed, and to maintain good liquid irrigation of the catalyst. The soluble hydrogen in the stream, kinetically active and available for immediate reaction, is the final piece of the puzzle for why this unit runs so well.Type: GrantFiled: September 10, 2008Date of Patent: July 1, 2014Assignee: Marathon Petroleum Company LPInventor: Howard F. Moore
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Publication number: 20140174987Abstract: The present invention relates to a process for handling product fluid streams which are obtained in the catalytic hydrogenation of liquid feeds in laboratory catalysis apparatuses. The liquid feeds are preferably hydrocarbons comprising sulfur- and nitrogen-comprising compounds as impurities. The hydrogenation serves to convert the impurities into hydrogen sulfide and ammonia which in this form can be readily separated off from the other constituents of the liquid feed. The product fluid streams are contacted with an inert gas stream, with the flow rate of the inert gas being a multiple of the flow rate of the product fluid stream. The formation of deposits in lines of the region on the outlet side of the reaction space can be effectively prevented by means of the process of the invention.Type: ApplicationFiled: July 30, 2012Publication date: June 26, 2014Applicant: hte Aktiengesellschaft the high throughput experimentation companyInventors: Josef Find, Alfred Haas, Armin Brenner
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Publication number: 20140174983Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 A.Type: ApplicationFiled: August 3, 2012Publication date: June 26, 2014Applicant: ADVANCED REFINING TECHNOLOGIES LLCInventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
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Patent number: 8753501Abstract: A process and apparatus are disclosed for hydrocracking hydrocarbon feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The hydrocracking unit and the hydrotreating unit share the same recycle gas compressor. A make-up hydrogen stream may also be compressed in the recycle gas compressor. A warm separator separates recycle gas and hydrocarbons from diesel in the hydrotreating effluent, so fraction of the diesel is relatively simple. The warm separator also keeps the diesel product separate from the more sulfurous diesel in the hydrocracking effluent, and still retains heat needed for fractionation of lighter components from the low sulfur diesel product.Type: GrantFiled: December 13, 2011Date of Patent: June 17, 2014Assignee: UOP LLCInventors: Paul R. Zimmerman, Andrew P. Wieber
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Patent number: 8753504Abstract: A system and process are disclosed for removing elemental sulfur compounds from hydro-desulfurization (HDS) treated hydrocarbon products including liquid hydrocarbon fuels. Low (sub-ppm) concentrations of sulfur remain in the hydrocarbons, providing, e.g., fuel products suitable for use in various modalities including, e.g., jet fuels and fuel cell Auxiliary Power Units (APUs).Type: GrantFiled: April 28, 2011Date of Patent: June 17, 2014Assignee: Battelle Memorial InstituteInventors: Gregory A. Whyatt, Liyu Li
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Patent number: 8747656Abstract: This invention relates to a process for conducting a hydrocracking or a hydrotreating process in a microchannel reactor. This invention also relates to a process and apparatus for flowing a vapor and liquid into a plurality of microchannels in a microchannel processing unit.Type: GrantFiled: October 9, 2009Date of Patent: June 10, 2014Assignee: Velocys, Inc.Inventors: Anna Lee Tonkovich, Ravi Arora, John Brophy, Francis P. Daly, Soumitra Deshmukh, Maddalena Fanelli, Kai Tod Paul Jarosch, Timothy J. LaPlante, Richard Q. Long, Terry Mazanec, Daniel Francis Ryan, Laura J. Silva, Wayne W. Simmons, Bruce Stangeland, Yong Wang, Thomas Yuschak, Steven T. Perry, Jeffrey Dale Marco, Michael Alan Marchiando, Robert Dwayne Litt
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Patent number: 8747653Abstract: A process is disclosed for hydroprocessing two hydrocarbon streams at two different pressures. A hydrogen stream is compressed and split. A first split compressed stream is further compressed to feed a first hydroprocessing unit that requires higher pressure for operation. A second split compressed stream is fed to a second hydroprocessing unit that requires lower pressure. Recycle hydrogen from the second hydroprocessing unit is recycled back to the compression section.Type: GrantFiled: March 31, 2011Date of Patent: June 10, 2014Assignee: UOP LLCInventor: Andrew P. Wieber
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Publication number: 20140148628Abstract: A process is disclosed for treating a hydrocarbon stream including flowing the hydrocarbon stream through a hydrocarbon treating vessel, heating a portion of the hydrocarbon treating vessel to a predetermined temperature and for a predetermined amount of time and controlling sensitization of the portion of the interior surface of the hydrocarbon treating vessel.Type: ApplicationFiled: September 30, 2011Publication date: May 29, 2014Inventors: Steven A. Bradley, Benjamin L. Tiemens, Mark W. Mucek, Shixue Wen
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Patent number: 8709238Abstract: Crude tall oil is subjected to a distillation process that substantially removes impurities. The process produces a combined pitch and a distillate of free fatty acids and rosin acids from two vacuum columns. The distillate stream is amenable to further downstream hydroprocessing.Type: GrantFiled: May 18, 2012Date of Patent: April 29, 2014Assignee: UOP LLCInventor: John A. Petri
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Patent number: 8702973Abstract: One exemplary embodiment can be a process for upgrading one or more hydrocarbons boiling in a naphtha range including less than about 5%, by weight, one or more alkenes and about 2,000-about 5,000 wppm, S, comprised in one or more sulfur-containing compounds, based on the weight of the one or more hydrocarbons. The process can include contacting the one or more hydrocarbons with a catalyst. The catalyst may include about 0.1-about 10%, by weight, NiO, about 5-about 50%, by weight, MoO3, and about 0.1-about 10%, by weight, P, with the balance of the catalyst comprising Al2O3. The process can obtain an upgraded one or more hydrocarbons having a thiol concentration of no more than about 20 wppm, S, based on the sulfur comprised in one or more thiol compounds divided by the weight of the upgraded one or more hydrocarbons.Type: GrantFiled: March 15, 2011Date of Patent: April 22, 2014Assignee: UOP LLCInventors: Colleen Costello, Suheil F. Abdo, Keith Adrian Holder, Ashley James Austin, Willie J. Morrissette, Jr.
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Patent number: 8696885Abstract: A process is disclosed for hydrocracking hydrocarbon feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The hydrocracking unit and the hydrotreating unit shares the same recycle gas compressor. A warm separator separates recycle gas and hydrocarbons from diesel in the hydrotreating effluent, so fraction of the diesel is relatively simple. The warm separator also keeps the diesel product separate from the more sulfurous diesel in the hydrocracking effluent, and still retains heat needed for fractionation of lighter components from the low sulfur diesel product.Type: GrantFiled: March 31, 2011Date of Patent: April 15, 2014Assignee: UOP LLCInventors: Andrew P. Wieber, Paul R. Zimmerman
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Patent number: 8691082Abstract: Two-stage hydroprocessing uses a common dividing wall fractionator. Hydroprocessed effluents from both stages of hydroprocessing are fed to opposite sides of the dividing wall.Type: GrantFiled: September 30, 2010Date of Patent: April 8, 2014Assignee: UOP LLCInventors: John A. Petri, Vedula K. Murty, Peter Kokayeff
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Patent number: 8691078Abstract: An apparatus and process is disclosed for hydroprocessing hydrocarbon feed in a hydroprocessing unit and hydrotreating a second hydrocarbon. A warm separator sends vaporous hydrotreating effluent to be flashed with liquid hydroprocessing effluent to produce a vapor flash overhead that can be recycled to the hydrotreating unit to provide hydrogen requirements.Type: GrantFiled: June 24, 2011Date of Patent: April 8, 2014Assignee: UOP LLCInventors: Andrew P. Wieber, Joao J. da Silva Ferreira Alves