First Stage Is Hydrocracking (includes Hydro-desulfurization Under Cracking Conditions) Patents (Class 208/58)
  • Patent number: 8231776
    Abstract: A method for obtaining a petroleum distillate product is provided, the method includes subjecting an untreated light Fischer-Tropsch liquid to a two-step hydrogenation process, each step to be carried in the presence of a catalyst comprising an amorphous substrate having a metallic composition embedded therein. After the first step of hydrogenation, an intermediate hydrotreated light Fischer-Tropsch liquid is obtained, followed by the second step of hydrogenation thereof, obtaining the petroleum distillate product as a result. An apparatus for carrying out the method is also provided.
    Type: Grant
    Filed: March 24, 2010
    Date of Patent: July 31, 2012
    Assignee: UOP LLC
    Inventor: Peter Kokayeff
  • Publication number: 20120152803
    Abstract: The present invention relates to processes for increasing smoke point of a fuel. The process can be carried out using an upgrading catalyst that contains at least one noble metal supported on an inorganic, porous crystalline phase material. The catalyst is particularly effective in increasing smoke point, while minimizing reduction in total aromatics content, particularly naphthalene content.
    Type: Application
    Filed: December 16, 2011
    Publication date: June 21, 2012
    Applicant: ExxonMobil Research and Engineering Company
    Inventor: Stuart S. Shih
  • Patent number: 8177961
    Abstract: The present invention relates to new crystalline molecular sieve SSZ-75 prepared using a tetramethylene-1,4-bis-(N-methylpyrrolidinium) dication as a structure-directing agent, and its use in catalysts for hydrocarbon conversion reactions.
    Type: Grant
    Filed: January 14, 2010
    Date of Patent: May 15, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventors: Stacey Zones, Allen Burton, Theodorus Ludovicus Michael Maesen, Berend Smit, Edith Beerdsen
  • Patent number: 8158841
    Abstract: To provide a method for hydrotreating a synthetic hydrocarbon oil, which removes olefins and oxygen-containing compounds by hydrotreatment with the gasification rate restrained and can efficiently convert the synthetic hydrocarbon oil generated by the FT process to a liquid fuel suitable as a fuel for diesel-powered vehicles. A hydrotreating method is disclosed in which a synthetic hydrocarbon oil generated by FT synthesis is hydrotreated using a catalyst in which a definite catalytic metal is allowed to be carried on a support, under definite reaction conditions, with the gasification rate restrained to a definite value or less, thereby removing the olefins and the oxygen-containing compounds.
    Type: Grant
    Filed: September 22, 2005
    Date of Patent: April 17, 2012
    Assignees: Japan Oil, Gas and Metals National Corporation, Japan Petroleum Exploration Co., Ltd., Cosmo Oil Co., Ltd., Nippon Steel Engineering Corporation, Inpex Corporation
    Inventors: Hiroaki Hara, Toshio Shimizu, Yutaka Miyata
  • Patent number: 8147675
    Abstract: A process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues from crude oil or coming from catalytic treatment, visbreaker tars, thermal tars, bitumens from oil sands, liquids from coats of different origins and other high-boiling feedstocks of a hydrocarbon nature known as “black oils.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: April 3, 2012
    Assignee: ENI S.p.A.
    Inventors: Mario Marchionna, Salvatore Meli, Luigi Patron, Alberto Delbianco, Nicoletta Panariti
  • Publication number: 20120061291
    Abstract: A hydrocarbon feedstock upgrading method is provided. The method includes supplying the hydrocarbon feedstock, water and a pre-heated hydrogen donating composition to a hydrothermal reactor where the mixed stream is maintained at a temperature and pressure greater than the critical temperatures and pressure of water in the absence of catalyst for a residence time sufficient to convert the mixed stream into a modified stream. The hydrogen donating composition is pre-heated and maintained at a temperature of greater than about 50° C. for a period of at least about 10 minutes. The modified stream includes upgraded hydrocarbons relative to the hydrocarbon feedstock. The modified stream is then separated into a gas stream and a liquid stream and the liquid stream is separated into a water stream and an upgraded hydrocarbon product stream.
    Type: Application
    Filed: September 14, 2010
    Publication date: March 15, 2012
    Applicant: Saudi Arabian Oil Company
    Inventors: Ki-Hyouk Choi, Ashok K. Punetha, Mohammed R. Al-Dossary, Mohammad F. Aljishi
  • Patent number: 8133446
    Abstract: Slurry hydrocracking a heavy hydrocarbon feed produces a HVGO stream and a pitch stream. At least a portion of the pitch stream is subjected to SDA to prepare a DAO stream low in metals. The DAO is blended with at least a portion of the HVGO stream to provide turbine or marine fuel with acceptable properties for combustion in gas turbines or for marine fuel grades.
    Type: Grant
    Filed: December 11, 2009
    Date of Patent: March 13, 2012
    Assignee: UOP LLC
    Inventors: James F. McGehee, Lorenz J. Bauer
  • Patent number: 8110091
    Abstract: The invention relates to a process for the treatment of heavy petroleum feedstocks in order to produce a gas oil fraction having a sulphur content of less than 50 ppm and generally 10 ppm which comprises the following stages: e) mild hydrocracking in a catalyst fixed bed, f) separation of the hydrogen sulphide, of a distillate cut including a gas oil fraction and of a fraction which is heavier than the gas oil, g) hydrotreating, by contact with at least one catalyst, of at least a portion of the distillate cut obtained in stage b) including the gas oil fraction, as a mixture with a feedstock resulting from a crude or refined renewable source, h) separation of a gas oil cut comprising less than 50 ppm of sulphur. Advantageously, the heavy fraction is sent for catalytic cracking. Preferably, the process is carried out with makeup hydrogen introduced in stage c) and very advantageously all the makeup hydrogen for the process is introduced in stage c).
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: February 7, 2012
    Assignee: IFP Energies Nouvelles
    Inventors: Thierry Chapus, Karin Marchand
  • Patent number: 8057660
    Abstract: Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues from crude oil or catalytic treatment, “visbreaker tars”, “thermal tars”, bitumens from “oil sands” liquids from coals of different origins and other high boiling feedstocks of a hydrocarbon origin.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: November 15, 2011
    Assignee: ENI S.p.A.
    Inventors: Mario Marchionna, Salvatore Meli, Luigi Patron, Alberto Delbianco, Nicoletta Panariti
  • Patent number: 8034232
    Abstract: Methods and systems for hydrocracking a heavy oil feedstock using, a colloidally or molecularly dispersed catalyst (e.g., molybdenum sulfide) which provide for concentration of the colloidally dispersed catalyst within the lower quality materials requiring additional hydrocracking. In addition to increased catalyst concentration, the inventive systems and methods provide increased reactor throughput, increased reaction rate, and of course higher conversion of asphaltenes and lower quality materials. Increased conversion levels of asphaltenes and lower quality materials also reduces equipment fouling, enables the reactor to process a wider range of lower quality feedstocks, and can lead to more efficient use of a supported catalyst if used in combination with the colloidal or molecular catalyst.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: October 11, 2011
    Assignee: Headwaters Technology Innovation, LLC
    Inventors: Roger K. Lott, Yu-Hwa Chang
  • Patent number: 8034230
    Abstract: A reconstituted non-asphaltenic oil Pa comprising at least 28% by weight of naphtha N, having a ratio R of 1.5 or more and a gasoline potential, POTg, in the range 47 to 70, in which: R=(0.9 N+0.5 VGO+)/(MD+0.1 VGO+), POTg=0.9N+0.5 VGO+, with in % by weight: N=naphtha: [30° C./170° C.]; MD=middle distillates: ]170° C./360° C.] and VGO+=fraction boiling above 360° C. R indicates the relative gasoline potential of a non residual oil over middle distillates during its subsequent refining.
    Type: Grant
    Filed: September 14, 2006
    Date of Patent: October 11, 2011
    Assignee: IFP Energies Nouvelles
    Inventor: Eric Lenglet
  • Patent number: 8002970
    Abstract: The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10?10 m to 24.15×10?10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: August 23, 2011
    Assignee: IFP Energies Nouvelles
    Inventors: Patrick Euzen, Patrick Bourges, Christophe Gueret, Carole Bobin, Alexandra Chaumonnot, Hugues Dulot
  • Patent number: 7972498
    Abstract: The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is treated by hydroprocessing and visbreaking and then passed to a steam cracker to obtain a product comprising olefins.
    Type: Grant
    Filed: October 19, 2006
    Date of Patent: July 5, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: John S. Buchanan, Paul F Keusenkothen, Stephen H. Brown, Julian A. Wolfenbarger, James E. Graham, James N. McCoy
  • Publication number: 20110147264
    Abstract: Systems and processes for the hydroprocessing of a hydrocarbonaceous feed are provided that utilize a plurality of moving bed reactors. The reactors may be moving bed radial flow reactors. A hydrogen injection point can be provided prior to each reactor by providing a mixer that mixes hydrogen with a hydrocarbonaceous feed, or with the effluent stream from an upstream reactor, to produce a reactor feed stream. Catalyst can be provided from the reaction zone of one reactor to the reaction zone of a downstream reactor through catalyst transfer pipes, and can be regenerated after passing through the reaction zones of the reactors. The moving bed reactors can be stacked in one or more reactor stacks.
    Type: Application
    Filed: December 2, 2010
    Publication date: June 23, 2011
    Applicant: UOP LLC
    Inventors: Clayton C. Sadler, Mary Jo Wier, Laurence O. Stine, Christopher Naunheimer
  • Patent number: 7943036
    Abstract: A flexible once-through process for hydroprocessing heavy oil feedstock is disclosed. The process employs a plurality of contacting zones and at least a separation zone to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock.
    Type: Grant
    Filed: July 21, 2009
    Date of Patent: May 17, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Darush Farshid, Bruce Reynolds
  • Patent number: 7938953
    Abstract: An improved process for heavy oil conversion and upgrading and a combined method for heavy oil conversion and vacuum gas-oil treatment are described herein. The method utilizes the creation and recycle of a separate product from the vacuum still, which is thereafter recycled back to the heavy oil conversion reactor. The result is the production of a higher quality medium gas oil product relative to the overall vacuum gas oil product which is acceptable for use in a typical vacuum gas oil treatment process. Additionally, there is a higher diesel yield selectivity from the heavy oil conversion unit.
    Type: Grant
    Filed: May 20, 2008
    Date of Patent: May 10, 2011
    Assignee: Institute Francais du Petrole
    Inventors: James J. Colyar, John Duddy
  • Patent number: 7938954
    Abstract: Systems and methods for hydroprocessing a heavy oil feedstock with reduced heavy oil deposits, the system employs a plurality of contacting zones and separation zones zone under hydrocracking conditions to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock, forming upgraded products of lower boiling hydrocarbons. In the separation zones, upgraded products are removed overhead and optionally, further treated in an in-line hydrotreater. At least a portion of the non-volatile fractions recovered from at least one of the separation zones is recycled back to the first contacting zone in the system, in an amount ranging between 3 to 50 wt. % of the heavy oil feedstock.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: May 10, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Julie Chabot, Bo Kou, Vivion Andrew Brennan, Erin Maris, Shuwu Yang, Bruce Reynolds
  • Patent number: 7938952
    Abstract: This invention relates to a novel integrated hydroconversion process for converting heavy atmospheric or vacuum residue feeds and also converting and reducing impurities in the vacuum gas oil liquid product. This is accomplished by utilizing two residue hydroconversion reaction stages, two vapor-liquid separators, and at least two additional distillate ebullated-bed hydrocracking/hydrotreating reaction stages to provide a high conversion rate of the residue feedstocks.
    Type: Grant
    Filed: May 20, 2008
    Date of Patent: May 10, 2011
    Assignee: Institute Francais du Petrole
    Inventors: James J. Colyar, John Duddy
  • Patent number: 7935243
    Abstract: Systems and methods for hydroprocessing a heavy oil feedstock with reduced heavy oil deposits, the system employs a plurality of contacting zones and separation zones zone under hydrocracking conditions to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products, wherein the first contacting zone is operated at a temperature of at least 10° F. lower than a next contacting zone. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock, forming upgraded products of lower boiling hydrocarbons. In the separation zones, upgraded products are removed overhead and, optionally, further treated in an in-line hydrotreater. At least a portion of the non-volatile fractions recovered from at least one of the separation zones is recycled back to the first contacting zone in the system.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: May 3, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Julie Chabot, Bo Kou, Vivion Andrew Brennan, Erin Maris, Shuwu Yang
  • Patent number: 7931797
    Abstract: A process for hydroprocessing heavy oil feedstock is disclosed. The process operates in once-through mode, employing a plurality of contacting zones and at least a separation zone to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. In the once-through upgrade system, little if any of the unconverted material and slurry catalyst mixture is recycled back to the system for further upgrading. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock. The slurry catalyst feed comprises an active metal catalyst having an average particle size of at least 1 micron in a hydrocarbon oil diluent, at a concentration of greater than 500 wppm of active metal catalyst to heavy oil feedstock.
    Type: Grant
    Filed: July 21, 2009
    Date of Patent: April 26, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Julie Chabot, Shuwu Yang, Bruce Reynolds
  • Patent number: 7931796
    Abstract: Systems and methods for hydroprocessing a heavy oil feedstock, the system employs a plurality of contacting zones and separation zones with at least some of the fresh slurry catalyst being supplied to at least a contacting zone other than the first contacting zone. The contacting zones operate under hydrocracking conditions, employing the slurry catalyst for upgrading the heavy oil feedstock, forming upgraded products of lower boiling hydrocarbons. In the separation zones, upgraded products are removed overhead and optionally, further treated in an in-line hydrotreater. A least a portion of the non-volatile fractions recovered from the separation zones is recycled back to the first contacting zone in the system.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: April 26, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Julie Chabot, Kaidong Chen, Bruce Reynolds
  • Publication number: 20110079540
    Abstract: The invention provides for a process for dewaxing a waxy hydrocarbon feedstock to form a lubricant oil. The invention is also directed to a catalyst system comprising a hydrotreating catalyst upstream of a dewaxing catalyst, used in the dewaxing of a waxy hydrocarbon feedstock to form a lubricant oil. In particular, the invention is directed to a process and catalyst system designed to maintain yield of lubricant oil product. Specifically, the yield of lubricant oil does not decrease more than 2%, at a target pour point, over a dewaxing temperature range. The hydrotreating catalyst helps prevent aging of the dewaxing catalyst and maintains lubricant oil product yield at a target pour point over a wide temperature range. The hydrotreating catalyst comprises platinum, palladium, or combinations thereof on a low acidity inorganic oxide support where acidity is measured by a decalin conversion of less than 10% at 700° F.
    Type: Application
    Filed: October 6, 2009
    Publication date: April 7, 2011
    Inventors: Kamala R. Krishna, James N. Ziemer, Andrew Rainis, Joseph A. Biscardi, Thomas V. Harris
  • Publication number: 20110073522
    Abstract: The present invention concerns a catalyst comprising at least one amorphous material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said amorphous material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said spherical particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having amorphous and microporous walls with a thickness in the range 1.5 to 50 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
    Type: Application
    Filed: May 13, 2009
    Publication date: March 31, 2011
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Audrey Bonduelle, Alexandra Chaumonnot
  • Publication number: 20110067305
    Abstract: A hydrocarbon synthesizer system for the production of petroleum fractions from a feedstock. Methods of synthesizing hydrocarbons from a feedstock.
    Type: Application
    Filed: September 22, 2010
    Publication date: March 24, 2011
    Inventor: Martin Allan Morris
  • Patent number: 7906013
    Abstract: A process is provided to produce an ultra low sulfur diesel with less than about 10 ppm sulfur using a two-phase or liquid-phase continuous reaction zone to convert a diesel boiling range distillate preferably obtained from a mild hydrocracking unit. In one aspect, the diesel boiling range distillate is introduced once-through to the liquid-phase continuous reaction zone over-saturated with hydrogen in an amount effective so that the liquid phase remains substantially saturated with hydrogen throughout the reaction zone as the reactions proceed.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: March 15, 2011
    Assignee: UOP LLC
    Inventors: Peter Kokayeff, Laura E. Leonard, Michael R. Smith
  • Patent number: 7897036
    Abstract: Systems and methods for hydroprocessing a heavy oil feedstock with reduced heavy oil deposits, the system employs a plurality of contacting zones and separation zones zone under hydrocracking conditions to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products, wherein water and/or steam being injected into first contacting zone in an amount of 1 to 25 weight % on the weight of the heavy oil feedstock. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock, forming upgraded products of lower boiling hydrocarbons. In the separation zones, upgraded products are removed overhead and optionally, further treated in an in-line hydrotreater. At least a portion of the non-volatile fractions recovered from at least one of the separation zones is recycled back to the first contacting zone in the system.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: March 1, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Julie Chabot, Bo Kou, Vivion Andrew Brennan, Erin Maris, Shuwu Yang
  • Patent number: 7897035
    Abstract: Systems and methods for hydroprocessing a heavy oil feedstock, the system employs a plurality of contacting zones and separation zones with at least some of the heavy oil feedstock being supplied to at least a contacting zone other than the first contacting zone. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock, forming upgraded products of lower boiling boiling hydrocarbons. In the separation zones, upgraded products are removed overhead and optionally, further treated in an in-line hydrotreater. At least a portion of the non-volatile fractions recovered from at least one of the separation zones is recycled back to the first contacting zone in the system.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: March 1, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventor: Julie Chabot
  • Patent number: 7883882
    Abstract: Disclosed herein are methods of manufacturing renewable chemicals through the manufacture of novel triglyceride oils followed by chemical modification of the oils. Methods such as transesterification, hydrogenation, hydrocracking, deoxygenation, isomerization, interesterification, hydroxylation, hydrolysis and saponification are disclosed. Novel oils containing fatty acid chain lengths of C8, C10, C12 or C14 are also disclosed and are useful as feedstocks in the methods of the invention.
    Type: Grant
    Filed: November 30, 2009
    Date of Patent: February 8, 2011
    Assignee: Solazyme, Inc.
    Inventors: Scott Franklin, Aravind Somanchi, Karen Espina, George Rudenko, Penelope Chua
  • Patent number: 7846323
    Abstract: The present invention generally relates to a method for producing an isoparaffinic product useful as jet fuel from a renewable feedstock. The method may also include co-producing a jet fuel and a liquefied petroleum gas (LPG) fraction from a renewable feedstock. The method includes hydrotreating the renewable feedstock to produce a hydrotreating unit heavy fraction that includes n-paraffins and hydroisomerizing the hydrotreating unit heavy fraction to produce a hydroizomerizing unit heavy fraction that includes isoparaffins. The method also includes recycling the hydroisomerizing unit heavy fraction through the hydroisomerization unit to produce an isoparaffinic product that may be fractionated into a jet fuel and an LPG fraction. The present invention also relates to a jet fuel produced from a renewable feedstock having improved cold flow properties.
    Type: Grant
    Filed: April 4, 2008
    Date of Patent: December 7, 2010
    Assignee: Syntroleum Corporation
    Inventors: Ramin Abhari, Lynn Tomlinson, Peter Havlik, Nathan Jannasch
  • Patent number: 7837857
    Abstract: A method for obtaining jet fuel from diesel fuel is provided, the method comprising subjecting the diesel fuel to hydrocracking to convert at least a portion of the diesel fuel into a mixture of light hydrocarbons, kerosene, naphtha and a liquefied petroleum gas, isolating the kerosene, recovering jet fuel from the kerosene, subjecting at least a portion of the mixture of kerosene, naphtha and a liquefied petroleum gas to steam forming to obtain a synthesis gas containing hydrogen, and recycling hydrogen contained in the synthesis gas to the hydrocracking step. A modular system for performing the method is also provided.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: November 23, 2010
    Assignee: UOP LLC
    Inventors: Rajeev Gautam, William H. Keesom, Gavin P. Towler
  • Patent number: 7815789
    Abstract: A process to prepare a base oil having a viscosity index of above 80 and a saturates content of above 90 wt % from a crude derived feedstock by (a) contacting a crude derived feedstock in the presence of hydrogen with a catalyst having at least one Group VIB metal component and at least one non-noble Group VIII metal component supported on a refractory oxide carrier; (b) adding to the effluent of step (a) or part of the effluent of step (a) a Fischer-Tropsch derived fraction boiling at least partly in the base oil range in an amount effective to achieve the target viscosity index of the final base oil; and (c) dewaxing the mixture as obtained in step (b).
    Type: Grant
    Filed: June 21, 2004
    Date of Patent: October 19, 2010
    Assignee: Shell Oil Company
    Inventors: Peter James Wardle, William Leonard Alexander King
  • Patent number: 7803265
    Abstract: A process is disclosed for converting distillate to gasoline-range hydrocarbons using a two-stage catalyst system including a first catalyst containing platinum, palladium, or platinum and palladium, and an acidic support, and a second catalyst containing iridium and an inorganic oxide support, and optionally nickel.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: September 28, 2010
    Assignee: ConocoPhillips Company
    Inventors: Tushar V. Choudhary, Paul F. Meier, Edward L. Sughrue, II, Walter E. Alvarez
  • Patent number: 7799207
    Abstract: The instant invention is directed to a process wherein a heavy oil feedstock upgrader alters its mode of operation of its full conversion hydroprocessing unit to create a custom tailored synthetic crude feedstock based upon data communicated from a target refinery and data communicated from the heavy oil feedstock upgrader. The data from the target refinery is data that represents refining process data and linear program modeling along with analysis by a refining planner to calculate the optimum “synthetic trim crude” that will optimize the effective use of the target refinery's capacity and equipment.
    Type: Grant
    Filed: March 10, 2006
    Date of Patent: September 21, 2010
    Assignee: Chevron U.S.A. Inc.
    Inventors: Paul A. Allinson, Curtis Munson
  • Patent number: 7790019
    Abstract: The invention relates to a catalyst including at least one hydro-dehydrogenating element chosen from the group formed by the group VIB and group VIII elements of the periodic table and a substrate based on a silica-alumina matrix with a reduced content of macropores containing a quantity greater than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and based on at least one zeolite. The invention also relates to a substrate based on a silica-alumina matrix with a reduced content of macropores containing a quantity greater than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and based on at least one zeolite. The invention also relates to hydrocracking and/or hydroconversion processes and hydrotreating processes utilizing a catalyst according to the invention.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: September 7, 2010
    Assignee: IFP Energies Nouvelles
    Inventors: Patrick Euzen, Patrick Bourges, Hugues Dulot, Christophe Gueret
  • Patent number: 7781629
    Abstract: A hydrotreating method uses two catalyst beds with the introduction, on the last catalyst bed, of oils of animal or vegetable origin for co-treating a mixture made up of oils of vegetable or animal origin and of petroleum cuts (gas oil cuts (GO) and middle distillates) in order to produce gas oil effluents meeting specifications with an improved cetane number. The first catalyst bed is dedicated to only the deep desulfurization reactions (HDS1) of a petroleum type feed. The effluents of the first catalyst bed having an effluent sulfur content below or equal to 50 mg/kg are separated into two streams. The first stream, which is predominant, is sent to the gas oil pool. The second stream is mixed with oils of vegetable or animal origin. The resultant oil-petroleum cut mixture is then subjected to a milder hydrotreatment (HDT2). The effluents obtained at the outlet of the second catalyst bed can optionally be mixed with the predominant stream from the first bed.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: August 24, 2010
    Assignee: Institut Francais du Petrole
    Inventors: Karin Marchand, Fabrice Bertoncini
  • Publication number: 20100187155
    Abstract: An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants. The integrated process includes an initial hydrotreatment, hydrocracking, catalytic dewaxing of the hydrocracking effluent, and an option final hydrotreatment.
    Type: Application
    Filed: December 23, 2009
    Publication date: July 29, 2010
    Inventors: Stephen J. McCarthy, Gary Paul Schleicher, Krista Marie Prentice, Michel Daage, Christopher Gordon Oliveri, Thomas Francis Degnan, Jose Guadalupe Santiesteban, Ajit Bhaskar Dandekar, William Joseph Novak, Wenyih F. Lai
  • Patent number: 7763163
    Abstract: A feedstream to a hydrocracking unit is treated to remove or reduce the content of polynuclear aromatics and nitrogen-containing compounds by contacting the feedstream with an adsorbent compound selected from attapulgus clay, alumina, silica gel and activated carbon in a fixed bed or slurry column and separating the treated feedstream that is lower in the undesired compounds from the adsorbent material. The adsorbent can be mixed with a solvent for the undesired compounds and stripped for re-use.
    Type: Grant
    Filed: November 6, 2006
    Date of Patent: July 27, 2010
    Assignee: Saudi Arabian Oil Company
    Inventor: Omer Refa Koseoglu
  • Publication number: 20100163454
    Abstract: Methods are disclosed for hydrocracking processes that convert a significant portion of a heavy hydrocarbon feedstock such as vacuum gas oil (VGO) to lower molecular weight, lower boiling hydrocarbons. In addition to molecular weight reduction, the processes also substantially reduce the pour point of a recovered higher boiling fraction or unconverted oil, all or a portion of which may be used as a lube base stock, optionally after one or more further treatment steps such as hydrofinishing. The ability to reduce the pour point, through hydroisomerization, of the higher boiling fraction greatly improves the quality of this fraction, or unconverted oil, for use in lube base stock preparation. Advantageously, separate, conventional hydroisomerization and/or dewaxing steps, often requiring a noble metal catalyst, may be avoided in particular embodiments disclosed herein.
    Type: Application
    Filed: December 31, 2008
    Publication date: July 1, 2010
    Inventor: Hemant B. GALA
  • Patent number: 7727379
    Abstract: Process to prepare simultaneously two or more base oil grades and middle distillates from a mineral crude derived feed, in particular a de-asphalted oil or a vacuum distillate feed or their mixtures, by performing the following steps: (a) hydrocracking the mineral crude derived feed, thereby obtaining an effluent; (b) distillation of the effluent as obtained in step (a) into one or more middle distillates and a full range residue boiling substantially above 340° C., (c) catalytically dewaxing the full range residue by contacting the residue with a dewaxing catalyst comprising a zeolite of the MTW type and a Group VIII metal, thereby obtaining a dewaxed oil; (d) isolating by means of distillation two or more base oil grades from the dewaxed oil obtained in step (c); and (e) isolating a dewaxed gas oil from the dewaxed-oil obtained in step (c); wherein the dewaxed oil as obtained in step (c) comprises between 10 and 40 wt % of a dewaxed heavy gas oil boiling for more than 70 wt % between 370 and 400° C.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: June 1, 2010
    Assignee: Shell Oil Company
    Inventors: Nicholas James Adams, Harmannus Julius Hegge, Laurent Georges Huve, Kevin John Anthony Polder, Wiecher Derk Evert Steenge
  • Patent number: 7718050
    Abstract: The invention relates to a process for FCC pretreatment by mild hydrocracking of a hydrocarbon feedstock that comprises a vacuum distillate fraction or a deasphalted oil or else a mixture of these two fractions, said primary feedstock, to produce gas oil and an effluent having an initial boiling point of more than 320° C., said effluent (FCC feedstock) then being subjected to a catalytic cracking, process in which at least 85% by weight of said primary feedstock ends above 375° C. and at least 95% by weight of said primary feedstock ends below 650° C., whereby the mild hydrocracking is performed under an absolute pressure of 2 to 12 MPa and at a temperature of between 300 and 500° C., characterized in that the hydrocarbon feedstock also comprises a lighter hydrocarbon fraction, a so-called secondary feedstock, of which at least 50% by weight ends below 375° C. and at least 80% ends above 200° C.
    Type: Grant
    Filed: June 9, 2006
    Date of Patent: May 18, 2010
    Assignee: Institut Francais du Petrole
    Inventors: Christophe Gueret, Thierry Chapus, Damien Hudebine
  • Patent number: 7713407
    Abstract: A hydrocracking process for converting a petroleum feedstock to higher gravity, lower sulfur products, especially ultra low sulfur road diesel fuel. The process may be operated as a single-stage or two-stage hydrocracking. In each case, a hydrocracking step is followed directly by a post-treat hydrodesulfurization zone using a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least two Group VIB metals with a ratio of Group VIB metal to Group VIII non-noble metal is from about 10:1 to about 1:10. In the two-stage option with interstage ammonia removal, the initial hydrocracking step may be followed by hydrodesulfurization using the bulk multimetallic catalyst prior to the ammonia removal which is followed by the second hydrocracking step. A final hydrodesulfurization over the bulk multimetallic catalyst may follow. The hydrodesulfurization over the bulk multimetallic catalyst is carried out at a pressure of at least 25 barg and preferably at least 40 barg.
    Type: Grant
    Filed: June 2, 2006
    Date of Patent: May 11, 2010
    Assignee: ExxonMobil Research & Engineering Company
    Inventors: William J. Tracy, III, Chuansheng Bai, Robert A. Bradway, William E. Lewis, Randolph J. Smiley
  • Publication number: 20100108568
    Abstract: The invention provides a Fischer-Tropsch jet fuel refining process which has a jet fuel yield in excess of 60% by mass, said process including at least four of the following five conversion processes: a. hydrocracking one or more of a FT kerosene and heavier material fraction and a C9 and heavier FT syncrude fraction; b. oligomerising an FT syncrude fraction including hydrocarbons in the range C2 to C8; c. hydrotreating one or more of an FT syncrude fraction, a product from process b., and an alkylated FT syncrude fraction; d. aromatizing one or more of an FT syncrude fraction including hydrocarbons in the range C2 to C8, a product from process a., a product from process b, a product from process c., and a product from an aromatic alkylation process; and e. alkylating one or more of an FT syncrude fraction including hydrocarbons in the C2 to C6 range, a product from process b., and a product from process d.
    Type: Application
    Filed: April 10, 2008
    Publication date: May 6, 2010
    Applicant: Sasol Technology (Pty) Ltd
    Inventor: Arno De Klerk
  • Patent number: 7708877
    Abstract: A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the converted oil while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. Fully converted oil is subsequently hydrofinished for the nearly complete removal of hetoroatoms such as sulfur and nitrogen.
    Type: Grant
    Filed: April 24, 2006
    Date of Patent: May 4, 2010
    Assignee: Chevron USA Inc.
    Inventors: Darush Farshid, Bruce Reynolds
  • Patent number: 7686941
    Abstract: A process for simultaneously hydrocracking multiple feedstocks wherein a first feedstock is hydrotreated in a hydrotreating zone to produce a hydrotreating zone effluent which is separated to provide a first vaporous hydrocarbonaceous stream and a first liquid hydrocarbonaceous stream. The second feedstock and the first vaporous hydrocarbonaceous stream are hydroprocessed in a hydroprocessing zone to produce a hydroprocessing zone effluent. A third feedstock and the first liquid hydrocarbonaceous stream are hydrocracked in a hydrocracking zone to produce a hydrocracking zone effluent. The hydrocracking zone effluent and the hydroprocessing zone effluent are separated to recover hydrocracked hydrocarbons.
    Type: Grant
    Filed: September 11, 2006
    Date of Patent: March 30, 2010
    Assignee: UOP LLC
    Inventors: Gary R. Brierley, Vasant P. Thakkar, Milan Skripek
  • Patent number: 7686945
    Abstract: Process to prepare a water-white lubricating base oil having a saturates content of more than 90 wt %, a sulphur content of less than 0.03 wt % and a viscosity index of between 80-120 by subjecting a non-water-white hydrocarbon feed having a lower saturates content than the desired saturates content to a hydrogenation step, the hydrogenation step comprising contacting the feed with hydrogen in the presence of a hydrogenation catalyst, wherein the contacting is performed in two steps: (a) contacting the hydrocarbon feed with hydrogen in the presence of a hydrogenation catalyst at a temperature of above 300° C. and at a WSHV of between 0.3 and 2 kg of oil per litre of catalyst per hour, and (b) contacting the intermediate product obtained in step (a) with hydrogen in the presence of a hydrogenation catalyst at a temperature of below 280° C.
    Type: Grant
    Filed: July 10, 2001
    Date of Patent: March 30, 2010
    Assignee: Shell Oil Company
    Inventors: Gerard Benard, Patrick Moureaux
  • Patent number: 7682500
    Abstract: A process for the conversion of a feedstock containing light cycle oil and vacuum gas oil to produce naphtha boiling range hydrocarbons and a higher boiling range hydrocarbonaceous stream having a reduced concentration of sulfur.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: March 23, 2010
    Assignee: UOP LLC
    Inventor: Tom N. Kalnes
  • Patent number: 7678262
    Abstract: The invention concerns an improved hydrocracking process with a recycle having a step for eliminating polyaromatic compounds from at least a portion of the recycled fraction by adsorption on a particular adsorbent based on alumina-silica with a controlled macropore content.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: March 16, 2010
    Assignee: Institut Francais du Petrole
    Inventors: Karin Barthelet, Patrick Euzen, Hugues Dulot, Patrick Bourges
  • Patent number: 7674363
    Abstract: Process to prepare a haze free base oil having a cloud point of below 0° C. and a kinematic viscosity at 100° C. of greater than 10 cSt by performing the following steps: (a) hydroisomerisation of a Fischer-Tropsch synthesis product, (b) isolating one or more fuel products and a distillation residue, (c) reducing the wax content of the residue by contacting the feed with a hydroisomerization catalyst under hydroisomerization conditions, and (d) solvent dewaxing the product of step (c) to obtain the haze free base oil.
    Type: Grant
    Filed: December 21, 2004
    Date of Patent: March 9, 2010
    Assignee: Shell Oil Company
    Inventors: Nicholas James Adams, Gilbert Robert Bernard Germaine
  • Patent number: 7658836
    Abstract: The process of producing middle distillates from effluents obtained by a Fischer-Tropsch synthesis, comprises a step for hydro-treatment and purification and/or decontamination by passage over a multi-functional guard bed prior to a step of hydrocracking/hydroisomerization. The guard bed reduces the amount of unsaturated compounds, oxygen-containing compounds, particulate mineral solids, and organometallic compounds.
    Type: Grant
    Filed: July 17, 2006
    Date of Patent: February 9, 2010
    Assignees: Institut Francais du Petrole, ENI S.p.A.
    Inventors: Patrick Euzen, Vincenzo Calemma
  • Patent number: 7655135
    Abstract: The invention relates to a method of removing contaminants from a hydroprocessing feed stream. More specifically, the invention relates to a method of removing contaminants from a hydroprocessing feed stream which originates in a Fischer-Tropsch reactor using a guard bed that employs a temperature profile.
    Type: Grant
    Filed: March 14, 2006
    Date of Patent: February 2, 2010
    Assignee: Syntroleum Corporation
    Inventors: Peter Z. Havlik, Nathan Jannasch, Paul Ahner, H. Lynn Tomlinson