Catalytic Patents (Class 208/66)
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Patent number: 11939538Abstract: In accordance with one or more embodiments of the present disclosure, a method for producing aromatic compounds from pyrolysis gasoline comprising C5-C6 non-aromatic hydrocarbons includes aromatizing the pyrolysis gasoline in an aromatization unit, thereby converting the C5-C6 non-aromatic hydrocarbons to a first stream comprising benzene-toluene-xylenes (BTX); hydrotreating the first stream comprising BTX in a selective hydrotreatment unit, thereby producing a de-olefinated stream comprising BTX hydrodealkylating and transalkylating the de-olefinated stream comprising BTX in a hydrodealkylation-transalkylation unit, thereby producing a second stream comprising BTX, the second stream comprising BTX having a greater amount of benzene and xylenes than the first stream comprising BTX; and processing the second stream comprising BTX in an aromatics recovery complex, thereby producing the aromatic compounds from the pyrolysis gasoline, the aromatic compounds comprising benzene, toluene, and xylenes.Type: GrantFiled: February 28, 2023Date of Patent: March 26, 2024Assignee: SAUDI ARABIAN OIL COMPANYInventors: Noor Nasser Al-Mana, Zhonglin Zhang, Omer Refa Koseoglu, Sohel Shaikh
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Patent number: 11905472Abstract: A system and process for generating, on-site, a sustained C6+C7 aromatic rich solvent stream for tar solvation within the olefin plant employing a two-fuel oil tower system receiving a hydrocarbon feed from a quench water separator drum, where the two-fuel oil tower system is configured to make a sufficient solvent stream containing C6+C7 aromatic rich hydrocarbons that is recycled and mixed with quench water going to the quench water separator drum to assist in removing tar molecules out of the quench water.Type: GrantFiled: April 26, 2022Date of Patent: February 20, 2024Assignee: KELLOGG BROWN & ROOT LLCInventors: David Sellinger, Rian Reyneke, Alok Srivastava, Kristine E. Hamilton, Michael A. Radzicki, Larry J. Shulik, James R. Arnold, Quo-Chen Yeh
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Patent number: 11492563Abstract: Provided is a conversion process for an inferior oil, relating to the field of biomass utilization, energy and chemical industry. The conversion process is carried out in presence of a catalyst selected from the group consisting of an iron oxide compound, a desulfurization waste agent resulting from use of an iron oxide compound as desulfurizer, and a regeneration product of the desulfurization waste agent, under a controlled molar ratio of iron element to sulfur element. It is found that free radical condensation polymerization of inferior oil during cracking process can be blocked effectively by using carbonylation, and hydrogenation is achieved with active hydrogen produced from the conversion of CO and water. In the conversion process, inferior oil can be, directly converted, thereby increasing liquefaction yield and calorific value of the obtained oils. No large amount of waste water is generated after completion of the conversion.Type: GrantFiled: May 30, 2019Date of Patent: November 8, 2022Inventors: Ke Lin, Lixin Guo, Yongjun Cui
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Patent number: 11479730Abstract: A process increases the concentration of non normal paraffins in a feed stream comprising separating a naphtha feed stream into a normal paraffin rich stream and a non-normal paraffin rich stream. The non-normal paraffin rich stream is isomerized over an isomerization catalyst to convert non-normal paraffins to normal paraffins, hydrocrack C5+ hydrocarbon to C2-C4 paraffins and produce an isomerization effluent stream. The isomerization effluent stream is separated into a C3? off gas, C4 rich stream and C5+ stream that is recycled to the naphtha feed stream. A depentanizer column may be positioned to either remove C6+ from the naphtha feed stream or from a bottoms stream from a stabilizer column. The amount of C2-C4 paraffins that are provided is increased from about 55% to as much as 77% and even more with further modifications including operating at higher temperatures or increasing the volume of catalyst.Type: GrantFiled: April 11, 2022Date of Patent: October 25, 2022Assignee: UOP LLCInventors: Manoj Kumar, Mark P. Lapinski
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Patent number: 10844296Abstract: A system includes a hydroprocessing zone configured to remove impurities from crude oil; a first separation unit configured to separate a liquid output from the hydroprocessing zone into a light fraction and a heavy fraction; an aromatic extraction subsystem configured to extract aromatic petrochemicals from the light fraction; and a pyrolysis section configured to crack the heavy fraction into multiple olefinic products.Type: GrantFiled: December 18, 2017Date of Patent: November 24, 2020Assignee: Saudi Arabian Oil CompanyInventors: Raed Abudawoud, Thamer Mohammad, Alberto Lozano Ballesteros, Essam Al Sayed
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Patent number: 10144885Abstract: This present disclosure relates to processes and apparatuses for transforming feedstock with high levels of benzene into a low-benzene content product that is suitable for gasoline blending. The benzene rich reformate stream is split in a reformate splitter and the benzene in the benzene rich reformate is saturated in a benzene saturation unit and the gases like hydrogen and LPG are recovered.Type: GrantFiled: May 17, 2017Date of Patent: December 4, 2018Assignee: UOP LLCInventors: Pankaj Kumar Singh, Alexander V. Sabitov, David J. Shecterle, Mohamed S. M. Shakur, Rajaraman Panchapakesan
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Patent number: 9334451Abstract: A hydrocarbon feedstock is hydrocracked in a hydrocracking zone and the effluent is fractioned to recover a light fraction, a middle fraction containing aromatic compounds and a heavy fraction. The heavy fraction is recycled to the hydrocracking zone for further hydrocracking. The middle fraction is introduced to an aromatic separation zone. A product stream is recovered from the aromatic separation zone comprising a middle fraction having a reduced content of aromatic compounds as compared to the middle fraction recovered from the fractionator. Aromatics from the aromatic separation zone are recycled to the hydrocracking zone for further hydrogenation and cracking.Type: GrantFiled: March 15, 2010Date of Patent: May 10, 2016Assignee: Saudi Arabian Oil CompanyInventors: Omer Refa Koseoglu, Adnan Al-Hajji, Ali Mahmood Al-Somali, Hendrik Muller, Mohammed Abdullah Al-Ghamdi
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Patent number: 9260670Abstract: Disclosed is a process for the selective hydrogenation of diolefins and sulfur compounds that are contained in a pyrolysis gasoline feedstream. The process includes utilizing a single hydrotreating reaction stage by introducing the pyrolysis gasoline feedstock that includes a diolefin concentration and an organic sulfur concentration into a reactor that is loaded with a high activity hydrotreating catalyst and which is operated under selective hydrogenation conditions. A reactor effluent having a reduced diolefin concentration and a reduced organic sulfur concentration is yielded from the reactor and is separated into a portion that is recycled as a reactor feed. The remaining portion of the reactor effluent is passed downstream for further processing or handling.Type: GrantFiled: June 9, 2010Date of Patent: February 16, 2016Assignee: Shell Oil CompanyInventors: Dane Clark Grenoble, Paul Benjerman Himelfarb, Michael Norris Treybig, Brian Scott Vanderwilp
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Patent number: 9221728Abstract: Embodiments of apparatuses and methods for reforming of hydrocarbons including recovery of products are provided. In one example, a method comprises separating a reforming-zone effluent into a H2, C6? hydrocarbon-containing gas phase and a C5+ hydrocarbon-containing liquid phase. The H2, (C1-C11) hydrocarbon-containing gas phase is partially condensed and separated to form a H2, C6? hydrocarbon-containing net gas stream and a C3+ hydrocarbon-containing liquid stream. The C5+ hydrocarbon-containing liquid phase, the C3+ hydrocarbon-containing liquid stream, and at least a portion of the H2, C6+ hydrocarbon-containing net gas stream are introduced to a re-contacting recovery zone for forming a H2-rich stream, a C3/C4 hydrocarbon-rich LPG stream, and a C5+ hydrocarbon-rich reformate stream.Type: GrantFiled: March 5, 2015Date of Patent: December 29, 2015Assignee: UOP LLCInventors: Laxmikant Bharuka, Sudipta Ghosh, Ashutosh Sharma, Kenneth David Peters
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Patent number: 9127217Abstract: A process of upgrading a highly aromatic hydrocarbon feedstream comprising (a) contacting a highly aromatic hydrocarbon feedstream, having a normal paraffin content of greater than at least about 5 wt %, wherein a major portion of the feedstream has a boiling range of from about 300° F. to about 800° F. under catalytic conditions with a catalyst system, containing a hydrotreating catalyst, a hydrogenation/hydrocracking catalyst, and a dewaxing catalyst in a single stage reactor system, wherein the active metals in the hydrogenation/hydrocracking catalyst comprises from about 5%-30% by weight of nickel and from about 5%-30% by weight tungsten; and (b) wherein at least a portion of the highly aromatic hydrocarbon feedstream is converted to a product stream having a boiling range within jet or diesel boiling ranges.Type: GrantFiled: December 18, 2008Date of Patent: September 8, 2015Assignee: Chevron U.S.A. Inc.Inventors: Jaime Lopez, Janine Lichtenberger
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Patent number: 9005429Abstract: The present invention relates to hydrocarbons and particularly to the manufacture of hydrocarbon components suitable as aviation fuels or jet fuels and as blending stocks for aviation fuels. The process comprises the stages, wherein in the first stage an oil feed of biological origin and hydrogen gas are subjected to conditions sufficient to effect hydrodeoxygenation in the presence of a hydrodeoxygenation catalyst to yield n-paraffins; in the second stage the n-paraffins and hydrogen gas are subjected to conditions sufficient to effect isomerization in the presence of an isomerization catalyst to yield isoparaffins and separating fractions; and recycling the fraction boiling at a temperature above 200° C. under atmospheric pressure obtained from the second stage to reisomerization, where isomerization is effected in the presence of an isomerization catalyst.Type: GrantFiled: June 30, 2009Date of Patent: April 14, 2015Assignee: Neste Oil OyjInventors: Varpu Markkanen, Petri Lindqvist, Elina Harlin, Pekka Aalto, Jukka Myllyoja, Ville Alopaeus
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Patent number: 8940950Abstract: The process relates to the use of any naphtha-range stream containing a portion of C8+ aromatics combined with benzene, toluene, and other non-aromatics in the same boiling range to produce toluene. By feeding the A8+ containing stream to a dealkylation/transalkylation/cracking reactor to increase the concentration of toluene in the stream, a more suitable feedstock for the methylation reaction can be produced. This stream can be obtained from a variety of sources, including the pygas stream from a steam cracker, “cat naphtha” from a fluid catalytic cracker, or the heavier portion of reformate.Type: GrantFiled: November 23, 2011Date of Patent: January 27, 2015Assignee: ExxonMobil Chemical Patents Inc.Inventors: Justin M. Ellrich, Robert D. Strack, John W. Rebeck, Allen S. Gawlik, Larry L. Iaccino, Glenn C. Wood, Stephen H. Brown, Timothy Paul Bender
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Publication number: 20140299515Abstract: Process for conversion of petroleum feed for production of low sulphur content fuel comprising the following steps: a step of ebullated bed hydroconversion of the feed in the presence of a supported catalyst, a separation step allowing a residual fraction to be obtained, a step of fixed bed hydrotreatment of the residual fraction using an upstream system of permutable reactors.Type: ApplicationFiled: September 28, 2012Publication date: October 9, 2014Applicant: IFP Energies nouvellesInventors: Wilfried Weiss, Jerome Majcher
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Patent number: 8846995Abstract: A method for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 380° C., the method including: a cracking and reforming reaction step of obtaining a product containing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from the feedstock oil, a refining and collection step of refining and collecting monocyclic aromatic hydrocarbons of 6 to 8 carbon number that have been separated from the product, a hydrogenation reaction step of hydrogenating a heavy fraction of 9 or more carbon number separated from the product, and a recycling step of returning the heavy fraction hydrogenation reaction product obtained in the hydrogenation reaction step to the cracking and reforming reaction step.Type: GrantFiled: March 25, 2011Date of Patent: September 30, 2014Assignee: JX Nippon Oil & Energy CorporationInventors: Shinichiro Yanagawa, Masahide Kobayashi
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Patent number: 8801920Abstract: A catalytic reforming process for producing gasoline of reduced benzene content includes the steps of reforming a reformer feedstock that includes a naphtha stream to produce a gasoline reformate product stream; splitting the gasoline reformate product stream into one or more relatively benzene-rich fractions and one or more relatively benzene-lean fractions; and hydrogenating the one or more relatively benzene-rich fractions to produce a cyclohexane-rich effluent, at least a portion of which cyclohexane-rich effluent is recycled to constitute a portion of the reformer feedstock.Type: GrantFiled: July 11, 2012Date of Patent: August 12, 2014Assignee: Saudi Arabian Oil CompanyInventors: Abdennour Bourane, Omer Koseoglu
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Patent number: 8754276Abstract: A reverse flow regenerative reactor having first and second zones, each having first and second ends, the first zone having a plurality of channels capable of separately conveying at least two components of a combustible gas mixture, a gas distributor configured for injecting the components of the combustible gas mixture into first zone, a combustion zone including a selective combustion catalyst disposed at or downstream of the second end of said channels for catalyzing combustion, wherein the second zone is positioned and situated to receive a combusted gas mixture. Processes usefully conducted in the reactor are also disclosed.Type: GrantFiled: August 10, 2012Date of Patent: June 17, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: John Scott Buchanan, Stephen Mark Davis, Frank Hershkowitz, John Slocum Coleman, Seth McConkie Washburn
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Patent number: 8753503Abstract: One exemplary embodiment can be a process for producing a reformate by combining a stream having an effective amount of isopentane and a stream having an effective amount of naphtha for reforming. Generally, the naphtha has not less than about 95%, by weight, of one or more compounds having a boiling point of about 38-about 260° C. as determined by ASTM D86-07. The process may include introducing the combined stream to a reforming reaction zone. The combined stream can have an isopentane:naphtha mass ratio of about 0.10:1.00-about 1.00:1.00.Type: GrantFiled: July 24, 2008Date of Patent: June 17, 2014Assignee: UOP LLCInventors: Steven L. Krupa, Mark P. Lapinski, Clayton C. Sadler
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Publication number: 20140144809Abstract: A process is disclosed for hydrocracking a primary hydrocarbon feed and a diesel co-feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The diesel stream fed through the hydrocracking unit is pretreated to reduce sulfur and ammonia and can be upgraded with noble metal catalyst.Type: ApplicationFiled: November 28, 2012Publication date: May 29, 2014Applicant: UOP LLCInventors: Peter Kokayeff, Paul R. Zimmerman
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Patent number: 8715486Abstract: The invention relates to a process for producing a new type of high-quality hydrocarbon base oil of biological origin. The process of the invention comprises ketonization, hydrodeoxygenation, and isomerization steps. Fatty acids and/or fatty acid esters based on a biological raw material are preferably used as the feedstock.Type: GrantFiled: February 1, 2013Date of Patent: May 6, 2014Assignee: Neste Oil OyjInventors: Jukka Myllyoja, Juha Jakkula, Pekka Aalto, Eija Koivusalmi, Juha Moilanen
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Patent number: 8702969Abstract: A hydrocracking process that includes a wax fraction hydrocracking step of hydrocracking the wax fraction contained within a Fischer-Tropsch synthetic oil to obtain a hydrocracked product, a gas-liquid separation step of using a multi-stage gas-liquid separator to separate the hydrocracked product into a gas component, a heavy oil component and a light oil component, a specific component content estimation step of determining the flow rate ratio between the heavy oil component and the light oil component, and using this flow rate ratio to determine an estimated value for the content of a specific hydrocarbon component contained within the hydrocracked product, and a control step of controlling the operation of the wax fraction hydrocracking step on the basis of this estimated value, so that the content of the specific hydrocarbon component falls within a predetermined range.Type: GrantFiled: September 14, 2010Date of Patent: April 22, 2014Assignees: Japan Oil, Gas and Metals National Corporation, Inpex Corporation, JX Nippon Oil & Energy Corporation, Japan Petroleum Exploration Co., Ltd., Cosmo Oil Co., Ltd., Nippon Steel Engineering Co., Ltd.Inventors: Kazuhiko Tasaka, Yuichi Tanaka, Marie Iwama
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Patent number: 8696888Abstract: The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is severely hydrotreated and passed to a steam cracker to obtain an olefins product.Type: GrantFiled: October 17, 2006Date of Patent: April 15, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Paul F. Keusenkothen, Megan L. Renstrom, Julian A. Wolfenbarger, Stephen H. Brown, John S. Buchanan
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Patent number: 8628655Abstract: A hydrocracking process that includes a wax fraction hydrocracking step of hydrocracking the wax fraction contained within a Fischer-Tropsch synthetic oil to obtain a hydrocracked product, a gas-liquid separation step of using a multi-stage gas-liquid separator to separate the hydrocracked product into a gas component, a heavy oil component and a light oil component, a specific component content estimation step of determining the flow rate ratio between the heavy oil component and the light oil component, and using this flow rate ratio to determine an estimated value for the content of a specific hydrocarbon component contained within the hydrocracked product, and a control step of controlling the operation of the wax fraction hydrocracking step on the basis of this estimated value, so that the content of the specific hydrocarbon component falls within a predetermined range.Type: GrantFiled: September 14, 2010Date of Patent: January 14, 2014Assignees: Japan Oil, Gas and Metals National Corporation, Inpex Corporation, JX Nippon Oil & Energy Corporation, Japan Petroleum Exploration Co., Ltd., Cosmo Oil Co., Ltd., Nippon Steel Engineering Co., Ltd.Inventors: Kazuhiko Tasaka, Yuichi Tanaka, Marie Iwama
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Publication number: 20130313161Abstract: A process of hydroprocessing a hydrocarbon in a down flow reactor comprising one or more hydroprocessing-catalyst beds. The hydrocarbon feed is mixed with hydrogen and optionally diluent to form a liquid feed mixture wherein hydrogen is dissolved in the mixture, and the liquid feed mixture is introduced into the down flow reactor under hydroprocessing conditions. The hydroprocessing-catalyst bed(s) are liquid-full and the feed reacts by contact with the catalyst. Hydrogen gas is injected into at least one of the hydroprocessing-catalyst beds such that at least part of the hydrogen consumed in that bed is replenished and the liquid-full condition is maintained. In a multi-bed reactor, hydrogen gas may be injected into more than one or all of the hydroprocessing-catalyst beds.Type: ApplicationFiled: May 25, 2012Publication date: November 28, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: Hasan Dindi
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Publication number: 20130264246Abstract: Provided are high viscosity high quality Group II lube base stocks with improved properties produced by an integrated hydrocracking and dewaxing process. In one form, the Group II lube base stock includes greater than or equal to 90 wt. % saturates, and less than 10 wt. % aromatics, and has an aromatic performance ratio between 1.0 and 5.0. Also provided are lubricant formulations including the high viscosity high quality Group II lube base stock.Type: ApplicationFiled: March 14, 2013Publication date: October 10, 2013Applicant: ExxonMobil Research and Engineering CompanyInventors: Gretchen L. Holtzer, Ajit B. Dandekar, Charles L. Baker, Bradley R. Fingland, Bryan E. Hagee, Cathleen Yung, Frank C. Wang, Eugenio Sanchez, Rugved Prakash Pathare
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Publication number: 20130193034Abstract: A catalytic reforming process for producing gasoline of reduced benzene content includes the steps of reforming a reformer feedstock that includes a naphtha stream to produce a gasoline reformate product stream; splitting the gasoline reformate product stream into one or more relatively benzene-rich fractions and one or more relatively benzene-lean fractions; and hydrogenating the one or more relatively benzene-rich fractions to produce a cyclohexane-rich effluent, at least a portion of which cyclohexane-rich effluent is recycled to constitute a portion of the reformer feedstock.Type: ApplicationFiled: July 11, 2012Publication date: August 1, 2013Inventors: Abdennour Bourane, Omer Koseoglu
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Patent number: 8470165Abstract: Process for the production of high-quality kerosene and diesel fuels and for the coproduction of hydrogen from a so-called light naphtha cut to which any quantity of LPG cut can be added where the steps of the process include: separating normal and iso-paraffins, dehydrogenation of the paraffins, oligomerization of the olefins and hydrogenation of the oligomerized olefins, the process permitting the production of kerosene and diesel fuels meeting market specifications, or even improved relative to the latter.Type: GrantFiled: November 12, 2010Date of Patent: June 25, 2013Assignee: IFP Energies NouvellesInventors: Jean Cosyns, Annick Pucci, Quentin Debuisschert, Fabienne Le Peltier
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Patent number: 8455708Abstract: A process for producing hydrocarbon products, comprising: a) operating a process unit in an alkylate mode wherein greater than 50 wt % of a C5+ hydrocarbon stream from the process unit boils at 137.8° C. or below, b) adjusting one or more process conditions in the process unit, and c) after the adjusting step, operating the process unit in a distillate mode wherein greater than 50 wt % of the C5+ hydrocarbon stream from the process unit boils above 137.8° C. Also, a process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in the alkylate mode and in the distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.Type: GrantFiled: March 17, 2010Date of Patent: June 4, 2013Assignee: Chevron U.S.A. Inc.Inventors: Hye-Kyung Timken, Shawn Winter, Howard S. Lacheen, Sven Ivar Hommeltoft
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Patent number: 8431014Abstract: The invention provides for a process for dewaxing a waxy hydrocarbon feedstock to form a lubricant oil. The invention is also directed to a catalyst system comprising a hydrotreating catalyst upstream of a dewaxing catalyst, used in the dewaxing of a waxy hydrocarbon feedstock to form a lubricant oil. In particular, the invention is directed to a process and catalyst system designed to maintain yield of lubricant oil product. Specifically, the yield of lubricant oil does not decrease more than 2%, at a target pour point, over a dewaxing temperature range. The hydrotreating catalyst helps prevent aging of the dewaxing catalyst and maintains lubricant oil product yield at a target pour point over a wide temperature range. The hydrotreating catalyst comprises platinum, palladium, or combinations thereof on a low acidity inorganic oxide support where acidity is measured by a decalin conversion of less than 10% at 700° F.Type: GrantFiled: October 6, 2009Date of Patent: April 30, 2013Assignee: Chevron U.S.A. Inc.Inventors: Kamala R. Krishna, James N. Ziemer, Andrew Rainis, Joseph A. Biscardi, Thomas V. Harris
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Patent number: 8377386Abstract: Flow deflector that is capable of changing the flow direction of a fluid during passage through a duct. The duct is formed by an inner and outer duct, which creates an annular region in the duct. The flow deflector forces the fluid passing through the annular region of the duct to flow inside the inner duct, while the fluid passing through the inner duct is forced to flow through the annular region. Reactor tubes for catalytic reactors are formed by assembling tubes comprising said flow deflector and having a catalyst arranged in the inner tube.Type: GrantFiled: March 5, 2009Date of Patent: February 19, 2013Assignee: Haldor Topsoe A/SInventors: Jesper Norsk, Esben Lauge Sørensen, Niklas Jakobsson
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Publication number: 20130020233Abstract: Disclosed herein is a process for catalytically reforming naphtha, comprising, in the presence of hydrogen gas, contacting naphtha with at least one reforming catalyst under the conditions of a pressure ranging from 0.15 to 3.0 MPa, a temperature ranging from 300 to 540° C., a volume space velocity ranging from 2.1 to 50 h?1, to carry out a shallow catalytic reforming reaction so as to achieve a naphthene conversion ratio of greater than 85 mass %, and a conversion ratio of paraffins to arenes and C4? hydrocarbons of less than 30 mass %.Type: ApplicationFiled: May 25, 2012Publication date: January 24, 2013Inventors: Aizeng MA, Jieguang Wang, Jincheng Pan
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Patent number: 8318003Abstract: The invention provides a low aromatic producing process for catalytical conversion of Fisher-Tropsch derived olefins to distillates (COD), which process includes the step of contacting Fisher-Tropsch derived olefins with a zeolite type catalyst at pressures of more than 50 barg.Type: GrantFiled: August 6, 2009Date of Patent: November 27, 2012Assignee: The Petroleum Oil and Gas Corporation of South Africa (Pty) Ltd.Inventors: Cyril David Knottenbelt, Carl Dunlop, Kholekile Zono, Maxwell Thomas
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Publication number: 20120205284Abstract: An effective method for producing high density fuel candidates from pinenes is provided. MMT-K10 is an efficient catalyst for the reaction, although significant amounts of p-cymene and camphene produced as byproducts limit the overall yield to about 80%. Nafion is also an excellent catalyst for pinene dimerization and was capable of producing dimers in up to 90% yield. Pinene dimers synthesized with these heterogenous catalysts have a density and net heat of combustion comparable to JP-10. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.Type: ApplicationFiled: August 31, 2009Publication date: August 16, 2012Inventors: Benjamin G. Harvey, Michael E. Wright, Roxanne L. Quintana
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Patent number: 8148288Abstract: The invention relates to a catalyst that comprises a metal M from the group of platinum, at least one promoter X1 that is selected from the group that consists of tin, germanium, and lead, and optionally at least one promoter X2 that is selected from the group that consists of gallium, indium and thallium, a halogenated compound and a porous substrate, in which the atomic ratio X1/M and optionally X2/M is between 0.3 and 8, the Hir/M ratio that is measured by hydrogen adsorption is greater than 0.40, and the bimetallicity index BMI that is measured by hydrogen/oxygen titration is greater than 108. The invention also relates to the process for the preparation of this catalyst and a reforming process using said catalyst.Type: GrantFiled: December 7, 2007Date of Patent: April 3, 2012Assignee: IFP Energies NouvellesInventors: Pierre-Yves Le Goff, Fabienne Le Peltier, Jean Giraud, Sylvie Lacombe, Christophe Chau
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Publication number: 20120024755Abstract: A guard bed or absorber is placed upstream of a transalkylation reactor to avoid deposition of halide and/or halogen species on the catalysts in said reactor.Type: ApplicationFiled: July 14, 2011Publication date: February 2, 2012Inventors: James H. Beech, JR., Julia E. Steinheider, Doron Levin, Selma S. Lawrence
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Publication number: 20110315599Abstract: An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or with only a high pressure separation so that the dewaxing still occurs under sour conditions. Various combinations of hydrotreating, catalytic dewaxing, hydrocracking, and hydrofinishing can be used to produce fuel products and lubricant base oil products.Type: ApplicationFiled: June 27, 2011Publication date: December 29, 2011Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Krista Marie Prentice, Michel Daage, Ajit Bhaskar Dandekar, Christopher Gordon Oliveri, Rohit Vijay, Stephen J. McCarthy, Wenyih F. Lai, Bradley R. Fingland
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Publication number: 20110233111Abstract: A method for thermally cracking a carboxylic acid containing hydrocarbonaceous feed wherein the feed is first processed in a vaporization step that contains at least one catalyst effective to convert carboxylic acid species to carbon dioxide and hydrocarbon and/or lower molecular weight acids and hydrocarbon.Type: ApplicationFiled: March 29, 2010Publication date: September 29, 2011Inventor: Kenneth M. Webber
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Publication number: 20110226664Abstract: A process for producing hydrocarbon products, comprising: a) operating a process unit in an alkylate mode wherein greater than 50 wt % of a C5+ hydrocarbon stream from the process unit boils at 137.8° C. or below, b) adjusting one or more process conditions in the process unit, and c) after the adjusting step, operating the process unit in a distillate mode wherein greater than 50 wt % of the C5+ hydrocarbon stream from the process unit boils above 137.8° C. Also, a process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in the alkylate mode and in the distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.Type: ApplicationFiled: March 17, 2010Publication date: September 22, 2011Inventors: Hye-Kyung Timken, Shawn Winter, Howard S. Lacheen, Sven Ivar Hommeltoft
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Publication number: 20110114538Abstract: Process mainly for the production of high-quality kerosene and diesel fuels and for the coproduction of hydrogen from a so-called light naphtha cut to which any quantity of LPG cut can be added, employing the following successive stages: dehydrogenation of the paraffins, oligomerization of the olefins and hydrogenation of the oligomerized olefins, the process permitting the production of kerosene and diesel fuels meeting market specifications, or even improved relative to the latter.Type: ApplicationFiled: November 12, 2010Publication date: May 19, 2011Applicant: IFP ENERGIES NOUVELLESInventors: Jean COSYNS, Annick Pucci, Quentin Debuisschert, Fabienne Le Peltier
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Publication number: 20110089080Abstract: A method of manufacturing high-quality naphthenic base oils comprising a high aromatic content and a large amount of impurities with a boiling point higher than that of gasoline. High-quality naphthenic base oil may be manufactured from light cycle oil (LCO) and slurry oil (SLO), which are inexpensive, and have a high aromatic content, a large amount of impurities, and which are effluents of a fluidized catalytic cracking (FCC) unit. The method also relates to the pretreatment process of a feedstock, where the amounts of impurities (sulfur, nitrogen, polynuclear aromatic compounds and various metals components) in the feedstock are reduced.Type: ApplicationFiled: August 7, 2008Publication date: April 21, 2011Applicant: SK Lubricants Co., Ltd.Inventors: Chang Kuk Kim, Jee Sun Shin, Kyung Seok Noh, Ju Hyun Lee, Byoung In Lee, Seung Woo Lee, Do Woan Kim, Sam Ryong Park, Seong Han Song, Gyung Rok Kim, Yoon Mang Hwang
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Publication number: 20110083997Abstract: This invention relates to a process for hydroprocessing heavy oil under process intensification conditions to form an upgraded hydrocarbon product.Type: ApplicationFiled: October 11, 2010Publication date: April 14, 2011Inventors: Laura J. Silva, Anna Lee Tonkovich, Stephen Claude LeViness, Kai Tod Paul Jarosch, Edward Rode
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Patent number: 7736491Abstract: A process for the fluid catalytic cracking of mixed hydrocarbon feeds from different sources is described, such as feeds A and B of different crackability, the process being especially directed to obtaining light fractions such as LPG and comprising injecting feed A in the base of the riser reactive section and feed B, of lower crackability, at a height between 10% and 80% of the riser, with feed B comprising between 5% and 50% of the total processed feed. The process requires that the feeds present differences in the contaminant content, improved dispersion of feeds A and B and feed B injection temperature same or higher than that of feed A.Type: GrantFiled: May 19, 2004Date of Patent: June 15, 2010Assignee: Petroleo Brasileiro S.A. - PetrobrasInventors: Claudia Maria de Lacerda Alvarenga Baptista, Henrique Soares Cerqueira, Emanuel Freire Sandes
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Patent number: 7727378Abstract: A process to prepare a waxy raffinate product by performing the following steps: (a) subjecting a Fischer-Tropsch derived product having a weight ratio of compounds boiling above 540° C. and compounds boiling between 370 and 540° C. of greater than 2 to a hydroconversion step and (b) fractionating the effluent of step (a) to obtain products boiling in the fuels range and a waxy raffinate product boiling between 350 and 600° C.Type: GrantFiled: July 2, 2004Date of Patent: June 1, 2010Assignee: Shell Oil CompanyInventors: Jan Lodewijk Maria Dierickx, Arend Hoek, Lip Piang Kueh
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Patent number: 7708877Abstract: A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the converted oil while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. Fully converted oil is subsequently hydrofinished for the nearly complete removal of hetoroatoms such as sulfur and nitrogen.Type: GrantFiled: April 24, 2006Date of Patent: May 4, 2010Assignee: Chevron USA Inc.Inventors: Darush Farshid, Bruce Reynolds
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Patent number: 7658836Abstract: The process of producing middle distillates from effluents obtained by a Fischer-Tropsch synthesis, comprises a step for hydro-treatment and purification and/or decontamination by passage over a multi-functional guard bed prior to a step of hydrocracking/hydroisomerization. The guard bed reduces the amount of unsaturated compounds, oxygen-containing compounds, particulate mineral solids, and organometallic compounds.Type: GrantFiled: July 17, 2006Date of Patent: February 9, 2010Assignees: Institut Francais du Petrole, ENI S.p.A.Inventors: Patrick Euzen, Vincenzo Calemma
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Patent number: 7550215Abstract: Low-energy, low-capital hydrogen production is disclosed. A reforming exchanger 14 is placed in parallel with an autothermal reformer (ATR) 10 to which are supplied a preheated steam-hydrocarbon mixture. An air-steam mixture is supplied to the burner/mixer of the ATR 10 to obtain a syngas effluent at 650°-1050° C. The effluent from the ATR is used to heat the reforming exchanger, and combined reformer effluent is shift converted and separated into a mixed gas stream and a hydrogen-rich product stream. High capital cost equipment such as steam-methane reformer and air separation plant are not required.Type: GrantFiled: May 21, 2007Date of Patent: June 23, 2009Assignee: Kellogg Brown & Root LLCInventors: Avinash Malhotra, James Hanlan Gosnell
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Publication number: 20090071871Abstract: A process for the preparation of hydrocarbon products, comprising the steps of (a) providing a stream containing oxygenates; (b) mixing the said stream with a recycle stream to form a gasoline feed stream; (c) contacting the gasoline feed stream with one or more gasoline synthesis catalysts to obtain an effluent stream comprising higher hydrocarbons boiling in the gasoline range; (d) withdrawing from step (c) the effluent stream; and (e) splitting a part of the effluent stream to form the recycle stream which is optionally further reduced in content of water or enriched in hydrogen, then pressurised and recycled to step (b).Type: ApplicationFiled: September 12, 2008Publication date: March 19, 2009Inventors: Finn Joensen, Bodil Voss, Niels Christian Schiodt
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Patent number: 7442290Abstract: Mesoporous aluminum oxides with high surface areas have been synthesized using inexpensive, small organic templating agents instead of surfactants. Optionally, some of the aluminum can be framework-substituted by one or more other elements. The material has high thermal stability and possesses a three-dimensionally randomly connected mesopore network with continuously tunable pore sizes. This material can be used as catalysts for dehydration, hydrotreating, hydrogenation, catalytic reforming, steam reforming, amination, Fischer-Tropsch synthesis and Diels-Alder synthesis, etc.Type: GrantFiled: March 21, 2007Date of Patent: October 28, 2008Assignee: Lummus Technology Inc.Inventors: Zhiping Shan, Jacobus Cornelius Jansen, Chuen Y. Yeh, Philip J. Angevine, Thomas Maschmeyer
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Patent number: 7435329Abstract: A reforming and isomerization process has been developed. A reforming feedstream is charged to a reforming zone containing a reforming catalyst and operating at reforming conditions to generate a reforming zone effluent. Hydrogen and an isomerization feedstream is charged into an isomerization zone to contact an isomerization catalyst at isomerization conditions to increase the branching of the hydrocarbons. The isomerization catalyst is a solid acid catalyst comprising a support comprising a sulfated oxide or hydroxide of at least an element of Group IVB, a first component being at least one lanthanide series element, mixtures thereof, or yttrium, and a second component being a platinum group metal or mixtures thereof. The reforming zone effluent and the isomerization zone effluent are each separated to form a light ends stream and a product stream. The light ends streams are combined for processing in a net gas re-contacting zone.Type: GrantFiled: September 6, 2005Date of Patent: October 14, 2008Assignee: UOP LLCInventors: Douglas A. Nafis, Gregory F. Maher, Lynn H. Rice, William D. Schlueter, Ralph D. Gillespie, Michelle J. Cohn
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Publication number: 20080156695Abstract: A process for reforming a hydrocarbon stream in a reforming unit can include passing a gas including a halogen-containing material from a product separation zone through an adsorption zone to remove at least some of the halogen-containing material before the gas enters a first reforming stage having at least one fixed bed reaction zone.Type: ApplicationFiled: September 7, 2007Publication date: July 3, 2008Inventors: Gary A. Dziabis, Leon Yuan, David J. Fecteau
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Patent number: 7261805Abstract: A process for upgrading a hydrocarbon feedstock containing waxy components and having an end boiling point exceeding 650° F., which includes contacting the feedstock at superatmospheric hydrogen partial pressure with an isomerization dewaxing catalyst that includes ZSM-48 and contacting the feedstock with a hydrocracking catalyst to produce an upgraded product with a reduced wax content. Each catalyst is present in an amount sufficient to reduce the cloud point and the pour point of the feedstock at a conversion of greater than about 10%, and an overall distillate yield of greater than about 10% results from the process.Type: GrantFiled: May 2, 2003Date of Patent: August 28, 2007Assignee: ExxonMobil Research and Engineering CompanyInventors: Michael T. Grove, Randall D. Partridge, Terry E. Helton, David A. Pappal, Philip J. Angevine, Dominick N. Mazzone