With Hydrogen Patents (Class 208/89)
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Patent number: 12090468Abstract: An improved hydrotreating catalyst and process for making a base oil product. The catalyst comprises a base extrudate of a high nanopore volume amorphous silica alumina (ASA) and alumina. The catalyst and process use a high nanopore volume ASA/alumina based catalyst to produce hydrotreated dewaxed base oil products from a hydrocarbon feedstock. The base extrudate comprises ASA having a pore volume in the 11-20 nm pore diameter range of 0.2 to 0.9 cc/g and an alumina having a pore volume in the 11-20 nm pore diameter range of 0.01 to 1.0 cc/g. The base extrudate formed has a total pore volume in the 2-50 nm pore diameter range of 0.12 to 1.80 cc/g. The catalyst further comprises at least one modifier element from Groups 6 to 10 and Group 14 of the Periodic Table. The catalyst and process provide improved aromatics saturation.Type: GrantFiled: March 11, 2021Date of Patent: September 17, 2024Assignee: CHEVRON U.S.A. INC.Inventors: Yihua Zhang, Guan-Dao Lei
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Patent number: 11873463Abstract: A method for re-refining used oils comprises contacting feedstock comprising purified used oil with extraction solvent to perform continuous liquid-liquid solvent extraction, to produce an extract stream comprising the extraction solvent and an extract dissolved in the extraction solvent. The feedstock and the extraction solvent are agitated by a variable speed agitator during the solvent extraction at a selected agitation speed. The extract is separated from the extraction solvent and subjected to a continuous flow liquid phase hydrogenation treatment to produce an oil product. A system for performing the method includes a purification unit for purifying the used oil; an extraction column for extracting the extract from the feedstock; and a continuous flow liquid phase hydrogenation unit. The extraction column comprises an agitator configured to agitate the feedstock and the extraction solvent flowing through the extraction column at a variable agitation speed.Type: GrantFiled: February 5, 2020Date of Patent: January 16, 2024Assignee: ReGen III Corp.Inventors: Gordon Driedger, Zachary Moore
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Patent number: 11801488Abstract: A method of preparing an alumina catalyst including: performing primary calcination of an alumina precursor at a primary calcination temperature to form a mixed-phase alumina including 1% to 15% by weight of alpha-alumina, 60% to 95% by weight of theta-alumina, and 4% to 25% by weight of delta-alumina; steam-treating the mixed-phase alumina with water vapor at a steam-treating temperature lower than the primary calcination temperature to form activated mixed-phase alumina; and performing secondary calcination of the activated mixed-phase alumina at a secondary calcination temperature higher than the steam treatment temperature and lower than the primary calcination temperature after step S2. An alumina catalyst prepared using the method, and a method of preparing propylene using the alumina catalyst.Type: GrantFiled: November 17, 2020Date of Patent: October 31, 2023Assignee: LG CHEM, LTD.Inventors: Young Sub Keum, Dae Heung Choi, Joo Young Cheon, Hyeon Bin Kim
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Patent number: 11731112Abstract: Bulk catalysts comprised of nickel, molybdenum, tungsten and titanium and methods for synthesizing bulk catalysts are provided. The catalysts are useful for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.Type: GrantFiled: March 3, 2021Date of Patent: August 22, 2023Assignee: Chevron U.S.A. Inc.Inventors: Xiaoying Ouyang, Viorel Duma, Alexander Kuperman, Ibrahim Uckung, Theodorus Ludovicus Michael Maesen, Axel Brait, Charles Wilson
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Patent number: 11578277Abstract: The present invention discloses an integrated process scheme for producing (i) high-octane gasoline blending stream (ii) high aromatic heavy naphtha stream which is a suitable feedstock for benzene, toluene, and xylene (BTX) production and (iii) high cetane ultra-low sulphur diesel (ULSD) stream suitable for blending in refinery diesel pool.Type: GrantFiled: November 5, 2021Date of Patent: February 14, 2023Assignee: INDIAN OIL CORPORATION LIMITEDInventors: Nayan Das, Mainak Sarkar, Ganesh Vitthalrao Butley, Ramesh Karumanchi, Sarvesh Kumar, Madhusudan Sau, Gurpreet Singh Kapur, Sankara Sri Venkata Ramakumar
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Patent number: 11572515Abstract: A hydrocracking process is disclosed. The hydrocracking process comprises hydrocracking a hydrocarbon feed stream in a hydrocracking reactor in the presence of a hydrogen stream and a hydrocracking catalyst to produce a hydrocracked effluent stream. The hydrocracked effluent stream is separated in a separator to provide a vapor hydrocracked stream and a liquid hydrocracked stream. The liquid hydrocracked stream is fractionated to provide a naphtha stream, a kerosene stream having a T90 temperature of about 204° C. (399° F.) to about 238° C. (460° F.), a diesel stream having a T90 temperature of about 360° C. (680° F.) to about 383° C. (721° F.) and an unconverted oil stream. The kerosene stream, the unconverted oil stream, and a portion of the diesel stream is recycled to the hydrocracking reactor for hydrocracking.Type: GrantFiled: December 31, 2020Date of Patent: February 7, 2023Assignee: UOP LLCInventors: Massimo Sangalli, John A. Petri, Magaly Estremera, Yoga R Ayar
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Patent number: 11505752Abstract: An advanced regulatory controller for a converter of a catalytic olefins unit is disclosed. A Fluid Catalytic Cracking (FCC) type converter (i.e., reactor-regenerator) is combined with an ethylene style cold-end for product recovery. The regulatory controller operates using an Advanced Regulatory Control (ARC) application using variables, such as a controlled variable, four disturbance variables, associated variable, and a manipulated variable. The ARC application manipulates fuel oil or tail gas flow to a regenerator in response to an expected future steady state value of a regenerator bed temperature resulting from changes in the values of a selected set of the variables.Type: GrantFiled: August 12, 2021Date of Patent: November 22, 2022Assignee: KELLOGG BROWN & ROOT LLCInventors: Jorge Javier Vazquez, Surajit Dasgupta, Michael Tallman, Priyesh Harilal Thakker
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Patent number: 11396631Abstract: A process for preparing a base oil from a waxy hydrocarbon feedstock is provided. The process comprises passing the hydrocarbon feedstock to a distillation column prior to dewaxing in order to recover a heavy wax cut. The heavy wax is then hydrocracked to lower boiling compounds which can be better isomerized to a base oil with an acceptable cloud point. The base oil yield is also increased.Type: GrantFiled: December 30, 2020Date of Patent: July 26, 2022Assignee: Chevron U.S.A. Inc.Inventors: Jay Parekh, Jifei Jia, Guan-Dao Lei, Kenny Peinado, Yihua Zhang, Shanying Lee
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Patent number: 11365358Abstract: An integrated process for conversion of a hydrocarbon stream comprising light naphtha to enhanced value products. The process includes passing the hydrocarbon stream through a first reactor, the first reactor being a catalytic bed reactor with a dual-function catalyst to simultaneously reform light naphtha to BTEX and crack light naphtha to ethane, propane, and butanes. Further, the process includes passing an effluent of the first reactor to a gas-liquid separating unit to generate a liquid stream and a gas stream, and passing the gas stream to a gas separator unit to remove hydrogen gas and methane and generate an enhanced gas stream. The process further includes passing the enhanced gas stream through a second reactor, the second reactor being a pyrolysis unit operated at steam cracking conditions to convert ethane, propane, and butanes in the enhanced gas stream to light.Type: GrantFiled: May 21, 2020Date of Patent: June 21, 2022Assignee: Saudi Arabian Oil CompanyInventors: Emad Naji Al-Shafei, Mohammed Z. Al-Bahar, Manal Al-Eid, Lianhui Ding, Ali Nader Al-Jishi, Ki-Hyouk Choi
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Patent number: 11236276Abstract: The present disclosure provides methods for hydroprocessing of heavy oils, such as pyrolysis tars. For example, a process for preparing a liquid hydrocarbon product includes providing a first process stream comprising a reduced reactivity tar, and blending the first process stream with a utility fluid to produce a second process stream comprising solids and a reduced reactivity, lower viscosity tar. The method can includes introducing the second process stream into a guard reactor without sulfiding the guard reactor catalyst(s) prior to introducing the second process stream into the guard reactor. The method includes hydroprocessing the second process stream in the guard reactor under mild hydroprocessing conditions to produce a third process stream. The method includes hydroprocessing the third process stream to produce a fourth process stream having a bromine number (BN) lower than 12 and comprising the liquid hydrocarbon product and the utility fluid.Type: GrantFiled: August 19, 2019Date of Patent: February 1, 2022Assignee: ExxonMobil Chemical Patents Inc.Inventors: Krystle J. Emanuele, Glenn A. Heeter, Kapil Kandel, Teng Xu
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Patent number: 11162039Abstract: A process for separating and upgrading a hydrocarbon feed includes passing the hydrocarbon feed to a distillation unit to separate it into at least a naphtha stream and a residue, passing the naphtha stream to a NHT that hydrotreats the naphtha stream to produce a hydrotreated naphtha, passing the hydrotreated naphtha to a NREF that reforms the hydrotreated naphtha to produce a reformate, passing the reformate to an ARC that processes the reformate to produce at least one aromatic product effluent and an aromatic bottoms stream, passing at least a portion of the residue to a residue hydroprocessing unit that hydroprocesses the portion of the residue to produce a hydroprocessed effluent, and passing a portion of the aromatic bottoms stream to the residue hydroprocessing unit to increase the solubility of the asphaltene compounds and reduce sedimentation. Systems for conducting the process are also disclosed.Type: GrantFiled: June 3, 2020Date of Patent: November 2, 2021Assignee: Saudi Arabian Oil CompanyInventors: Omer Refa Koseoglu, Robert Peter Hodgkins
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Patent number: 11124710Abstract: A naphtha hydrotreating process involves the use of a sulfur guard bed (SGB) with a controlled bypass which allows for control of the sulfur in the feed to a downstream processing unit. The SGB is installed on the light ends stripper bottoms stream in a naphtha hydrotreating unit.Type: GrantFiled: August 20, 2019Date of Patent: September 21, 2021Assignee: UOP LLCInventors: Steven B. Philoon, Patrick J. Bullen, Stanley J. Frey, Gail L. Gray, Dean E. Rende
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Patent number: 11123725Abstract: A method of making a multifunctional catalyst for upgrading pyrolysis oil includes contacting a hierarchical mesoporous zeolite support with a solution including at least a first metal catalyst precursor and a second metal catalyst precursor, each or both of which may include a heteropolyacid. The hierarchical mesoporous zeolite support may have an average pore size of from 2 nm to 40 nm. Contacting the hierarchical mesoporous zeolite support with the solution deposits or adsorbs the first metal catalyst precursor and the second catalyst precursor onto outer surfaces and pore surfaces of the hierarchical mesoporous zeolite support to produce a multifunctional catalyst precursor. The method further includes removing excess solution and calcining the multifunctional catalyst precursor to produce the multifunctional catalyst comprising at least a first metal catalyst and a second metal catalyst deposited on the outer surfaces and pore surfaces of the hierarchical mesoporous zeolite support.Type: GrantFiled: June 23, 2020Date of Patent: September 21, 2021Assignee: Saudi Arabian Oil CompanyInventors: Miao Sun, Ke Zhang, Veera Venkata R Tammana
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Patent number: 11046898Abstract: A process for separating and upgrading a hydrocarbon feed includes passing the hydrocarbon feed to a distillation unit to separate it into at least a naphtha stream and a residue, passing the naphtha stream to a NHT that hydrotreats the naphtha stream to produce a hydrotreated naphtha, passing the hydrotreated naphtha to an NREF that reforms the hydrotreated naphtha to produce a reformate, passing the reformate to an ARC that processes the reformate to produce at least one aromatic product effluent and an aromatic bottoms stream, and passing at least a portion of the aromatic bottoms stream comprising C9+ aromatic compounds to a steam cracking unit. The steam cracking unit may further upgrade the aromatic bottoms stream, which may increase the yields of greater value chemical intermediates and fuel blending components from the process. Systems for conducting the process are also described.Type: GrantFiled: May 15, 2020Date of Patent: June 29, 2021Assignee: Saudi Arabian Oil CompanyInventors: Omer Refa Koseoglu, Robert Peter Hodgkins
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Patent number: 11034895Abstract: The present invention describes a process for the production of base oils having a viscosity of greater than 4 centistokes from waste oils originating from industrial use or engine use, said process using a novel configuration for efficient and effective processing.Type: GrantFiled: January 22, 2020Date of Patent: June 15, 2021Assignee: Axens SAInventors: Trushit Oza, Jerome Bonnardot
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Patent number: 11001770Abstract: According to one embodiment, a heavy oil may be processed by a method that may include upgrading at least a portion of the heavy oil to form an upgraded oil, where the upgrading includes contacting the heavy oil with a hydrodemetalization catalyst, a transition catalyst, a hydrodenitrogenation catalyst, and a hydrocracking catalyst to remove at least a portion of metals, nitrogen, or aromatics content from the heavy oil and form the upgraded oil. The method may further include passing at least a portion of the upgraded oil to a refinery operation.Type: GrantFiled: July 16, 2018Date of Patent: May 11, 2021Assignee: Saudi Arabian Oil CompanyInventors: Kareemuddin Shaik, Lianhui Ding, Mazin Tamimi, Ibrahim Abba, Abdennour Bourane
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Patent number: 10883057Abstract: Provided is a method for separating normal paraffin and isoparaffin from raffinates of a benzene, toluene, and xylene (BTX) reforming process including C5 to C8 light naphtha, the method including: a liquid hydrogenation process for removing olefin by feeding raffinates in which hydrogen is dissolved into a reactor filled with a hydrogenation catalyst.Type: GrantFiled: March 20, 2019Date of Patent: January 5, 2021Assignees: SK Innovation Co., Ltd., SK Energy Co., Ltd.Inventors: Hyeon Hui Lee, Min Su Koo, Young Bin Seo, Hye Ryun Seo, Ju Hoe Kim
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Patent number: 10845355Abstract: A system and a method for determining the aromatic content and naphthene content of a naphtha fraction of a stream is provided, by conducting analysis on the crude oil sample. Crude oil analysis data is obtained from the sample, and modules or steps are performed to calculate an index. The index is used to assign aromatic content and naphthene content to the crude oil sample.Type: GrantFiled: January 5, 2016Date of Patent: November 24, 2020Assignee: SAUDI ARABIAN OIL COMPANYInventor: Omer Refa Koseoglu
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Patent number: 10793792Abstract: According to one or more embodiments presently described, a feedstock oil may be processed by a method which may include hydrotreating the feedstock oil to reduce or remove one or more of sulfur content, metals content, nitrogen content, or aromatics content to produce a hydrotreated oil stream; separating at least a portion of the hydrotreated oil stream into a at least a lesser boiling point oil fraction stream and a greater boiling point oil fraction stream in a first separator; hydrocracking the greater boiling point oil fraction stream; and steam cracking the lesser boiling point oil fraction stream.Type: GrantFiled: October 31, 2017Date of Patent: October 6, 2020Assignee: Saudi Arabian Oil CompanyInventors: Lianhui Ding, Essam Al-Sayed, Sherif Mohamed, Ibrahim Al-Nutaifi, Alberto Lozano Ballesteros, Ibrahim Abba
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Patent number: 10760024Abstract: A method for providing renewable natural gas (RNG) includes removing hydrogen sulfide and/or carbon dioxide from biogas to provide partially purified biogas, which may be stored in a mobile storage tank. The partially purified biogas is transported to a biogas upgrading facility, at least partially by truck, rail, or ship. At the biogas upgrading facility, the partially purified biogas is further purified to provide the RNG, which can be injected into a distribution system (e.g., natural gas grid) and/or provided for use in transportation.Type: GrantFiled: August 30, 2019Date of Patent: September 1, 2020Assignee: Iogen CorporationInventors: Patrick J. Foody, John Dechman
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Patent number: 10655076Abstract: The present invention relates to an assorted co-staging and counter stage hydro-treating process configuration scheme is disclosed for deep desulfurization and deep hydro-treating of diesel range hydrocarbons for obtaining diesel product having product sulfur less than 10 ppm and cetane number more than 51.Type: GrantFiled: March 6, 2019Date of Patent: May 19, 2020Assignee: INDIAN OIL CORPORATION LIMITEDInventors: Mainak Sarkar, Darshankumar Manubhai Dave, Ganesh Vitthalrao Butley, Ramesh Karumanchi, Arun Arangarasu, Sarvesh Kumar, Madhusudan Sau, Debasis Bhattacharyya, Sanjiv Kumar Mazumdar, Sankara Sri Venkata Ramakumar
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Patent number: 10639618Abstract: A method of wax oil hydrocracking includes the steps of pre-hydrotreating wax oil to obtain a pre-hydrotreated material flow; controlling the pre-hydrotreated material flow and a hydrogen-containing material flow to contact with a first hydrocracking catalyst to obtain a first hydrocracked material flow, and dividing the first hydrocracked material flow into a first hydrocracked material flow A and a first hydrocracked material flow B; controlling the flow B and a hydrogen-containing material flow to contact with a second hydrocracking catalyst to obtain a second hydrocracked material flow, and then separating and fractionating the second hydrocracked material flow to obtain a hydrocracked tail oil product; controlling the flow A, at least a part of the hydrocracked tail oil product, and a hydrogen-containing material flow to contact with a hydrogenation isocracking catalyst to obtain a hydrogenation isocracked material flow, and then separating and fractionating the obtained hydrogenation isocracked materialType: GrantFiled: December 28, 2018Date of Patent: May 5, 2020Assignees: China Petroleum & Chemical Corporation, Dalian Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.Inventors: Tao Liu, Baozhong Li, Ronghui Zeng, Yuzhuo Zhao, Zhenmin Bai, Xiangchen Fang, Yan Wang, Xuehui Zhang, Chang Liu
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Patent number: 10550334Abstract: A process is disclosed for shifting the product of a hydrocracker in a hydrocarbon refinery back and forth from a more naphtha focused product slate to a more diesel focused product slate to take advantage of price and demand shifts between gasoline and diesel by using a naphtha selective catalyst and temporarily passivating the catalyst with a basic material such as ammonia in the hydrocracker. The ammonia passivates the acid catalyst sites on the catalyst and produces more total liquids and more diesel with attractive cold flow and pour point properties for a temporary period. When implemented in a temporary manner and the flow of ammonia is suspended the hydrocracker product slate returns to a more gasoline focused slate.Type: GrantFiled: December 12, 2018Date of Patent: February 4, 2020Assignee: PHILLIPS 66 COMPANYInventors: Xiaochun Xu, Jianhua Yao
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Patent number: 10400184Abstract: Heavy oil feeds are hydroprocessed in the presence of a solvent and in the presence of a catalyst with a median pore size of about 85 ? to about 120 ? under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst.Type: GrantFiled: August 29, 2012Date of Patent: September 3, 2019Assignee: ExxonMobil Research and Engineering CompanyInventors: Hyung Suk Woo, Jane Chi-Ya Cheng, Teh C. Ho, Stephen Harold Brown
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Patent number: 10301560Abstract: A process and apparatus for two stage hydrocracking saturates aromatics from the first stage hydrocracking unit to prevent production of HPNA's. The saturated HPNA's can be hydrocracked in the second stage to minimize or eliminate purged unconverted oil to approach or obtain maximum conversion. In an aspect, the second stage hydrocracking reactor and hydrotreating reactor may be located in the same vessel.Type: GrantFiled: May 18, 2017Date of Patent: May 28, 2019Assignee: UOP LLCInventors: Haiyan Wang, Richard K. Hoehn, Xin X. Zhu
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Patent number: 10287515Abstract: A method for producing an American Petroleum Institute Standards Group III Base Stock from vacuum gas oil, by injecting hydrogen, heating, saturating the mixture through hydrogen reactors connected in series with a liquid hourly space velocity (LHSV)?1 from 0.5 to 2.5, forming a saturated heated base oil, and coproduct. The method fractionates the saturated heated base oil while simultaneously refluxing a cooled light oil fraction forming an American Petroleum Institute Standards Group III Base Stock with less than 0.03% sulfur, with greater than 90% saturates and a viscosity index greater than 120 as defined by ASTM D-2270, a viscosity from 2 to 10 centistokes as defined by ASTM D-445 a boiling point range from 600 degrees F. to 1050 degrees F. as defined by ASTM D-86, and a cold crank viscosity (CCS) between 1200 and 5000 centipoise at minus 25 degrees C. and as defined by ASTM D-5293.Type: GrantFiled: November 27, 2018Date of Patent: May 14, 2019Inventors: Benjamin Cowart, David Peel, Frank Lappin, James Craig Smith
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Patent number: 10173950Abstract: Systems and processes for maximizing the production of benzene and para-xylene from heavy reformate are provided. An integrated process and system may include a C9 dealkylation reactor, a transalkylation reactor, and a C10+ dealkylation reactor. The integrated process and system for producing benzene and para-xylene may be configured to additionally produce alkanes in the presence of hydrogen or olefins in the absence of hydrogen. The transalkylation reactor may perform transalkylation of product from the C9 dealkylation reactor and xylene isomerization.Type: GrantFiled: November 29, 2017Date of Patent: January 8, 2019Assignee: Saudi Arabian Oil CompanyInventors: Raed H. Abudawoud, Zhonglin Zhang
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Patent number: 10131595Abstract: The inventive process is directed to the production of xylenes through integration of aromatics methylation and transalkylation. This integrated process maximizes the production of xylenes and eliminates or minimizes the production of benzene.Type: GrantFiled: March 14, 2013Date of Patent: November 20, 2018Assignee: GTC Technology US LLCInventors: Zhongyi Ding, Weihua Jin, Joseph C. Gentry, Mircea Cretoiu
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Patent number: 9765266Abstract: Catalytic system which can be used in processes for the hydroconversion of heavy oils by means of hydrotreatment in slurry phase, characterized in that it comprises: a catalyst, having the function of hydrogenating agent, containing MoS2 or WS2 or mixtures thereof in lamellar form or an oil-soluble precursor thereof; a co-catalyst, having nanometric or micronic particle-sizes, selected from cracking and/or denitrogenation catalysts. The co-catalyst preferably consists of zeolites having small-sized crystals and with a low aggregation degree between the primary particles, and/or oxides or sulfides or precursors of sulfides of Ni and/or Co in a mixture with Mo and/or W.Type: GrantFiled: June 8, 2009Date of Patent: September 19, 2017Assignee: ENI S.p.A.Inventors: Giuseppe Bellussi, Giacomo Rispoli, Angela Carati
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Patent number: 9688924Abstract: The invention provides a process for hydrogenating a low-sulphur feed into very low sulphur and very low aromatic hydrocarbon fluids having a boiling range in the range of from 100 to 400° C. and a boiling range of not more than 80° C., comprising the step of catalytically hydrogenating said feed at a temperature from 80 to 180° C. and at a pressure from 60 to 160 bars.Type: GrantFiled: November 19, 2010Date of Patent: June 27, 2017Assignee: Total Marketing ServicesInventors: Francois Dalemat, Anne-Eline Gilles, Gildas Morvan
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Patent number: 9636662Abstract: This invention relates to a hydrodesulfurization catalyst, a method for preparing the catalyst, and a method for the preparation of low sulfur gasoline fuel with minimal loss of RON. The catalyst particles include a group VIB metal and a support material having relatively high surface area, and optionally includes one or more group VIIIB metal. The method for preparing the catalyst allows for greater loading of the active metal species on the surface of the support material under aqueous reaction conditions.Type: GrantFiled: February 23, 2009Date of Patent: May 2, 2017Assignee: Saudi Arabian Oil CompanyInventors: Ki-Hyouk Choi, Sameer Ali Al-Ghamdi, Ali H. Al-Shareef, Ali H. Al-Hamadah
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Patent number: 9523050Abstract: Processes for co-processing renewable feedstock and petroleum distillate feed. The petroleum distillate feed is hydrotreated in a first reaction zone. The renewable feedstock is deoxygenated in a second reaction zone. The effluent stream from the two reaction zones are combined. A heavy portion of the combined effluent stream may be hydrocracked. Hydrogen sulfide may be removed from the effluent and used in the second reaction zone to maintain the catalyst during periods of non-processing.Type: GrantFiled: December 18, 2014Date of Patent: December 20, 2016Assignee: UOP LLCInventors: Venkat Ram Naidu Pandranki, Krishnan Vaidyanathan
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Patent number: 9434621Abstract: A mesoporous composite titanium oxide, which is composed of a mesoporous titanium oxide, the outside surface and the wall of pores of the mesoporous titanium oxide are modified by inorganic matters; inorganic matter contains at least one element selected from carbon, silicon, sulphur, phosphorus and selenium in an amount of 0.01%-25%, on amount of the element mass, of the mass of said mesoporous composite titanium oxide material; at least one mean pore size of pore distribution of the mesoporous compound titanium oxide material is 3-15 nm, the specific surface area is 50-250 m2/g, and the pore volume is 0.05-0.4 cm3/g. As a catalyst carrier, the rate of conversion of the hydrodesulfurization reaction of the material reaches as high as 98 percent, and as a lithium ion battery cathode material, the specific capacity of the lithium ion battery cathode material reaches as high as 220 mAh/g.Type: GrantFiled: August 28, 2009Date of Patent: September 6, 2016Assignees: NANJING UNIVERSITY OF TECHNOLOGY, NANJING TAIWEI TECHNOLOGY CO., LTD.Inventors: Zhuhong Yang, Yudan Zhu, Xiaohua Lu, Changsong Wang, Licheng Li, Linghong Lv, Wei Zhuang, Chang Liu, Xin Feng
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Patent number: 9359563Abstract: One exemplary embodiment can be a process for initializing hydroprocessing. Generally, the process can include providing a hydrocarbon feed to a hydrotreating zone within which the hydrotreating temperature is catalytically limited, passing an effluent from the hydrotreating zone to a hydrocracking zone, and adding a gas to the effluent that has a higher temperature than the effluent. Thus, the temperature of the effluent may be raised, facilitating hydrocracking reactions within the hydrocracking zone.Type: GrantFiled: April 15, 2013Date of Patent: June 7, 2016Assignee: UOP LLCInventor: Christopher Lepine Standing
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Patent number: 9353319Abstract: Embodiments of a method for producing a diesel range material having improved cold flow properties are provided. In one embodiment, the method includes the steps of providing a waxy diesel range feedstock, producing an intermediary product stream containing a predetermined amount of oxygenated organocompounds from the waxy diesel range feedstock, and contacting the intermediary product stream with a dewaxing catalyst under process conditions at which the oxygenated organocompounds chemically interact with the dewaxing catalyst to convert a portion of the n-paraffins within the intermediary product stream to iso-paraffins while minimizing cracking of the diesel range material.Type: GrantFiled: July 10, 2014Date of Patent: May 31, 2016Assignee: UOP LLCInventors: Peter Kokayeff, Suheil F. Abdo
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Patent number: 9284501Abstract: An integrated slurry hydroprocessing and steam pyrolosyis process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil, a steam pyrolysis residual liquid fraction and slurry reside are combined and treated in a hydroprocessing zone in the presence of hydrogen under conditions effective to produce an effluent having an increased hydrogen content. The effluent is thermally cracked with steam under conditions effective to produce a mixed product stream and steam pyrolysis residual liquid fraction. The mixed product stream is separated and olefins and aromatics are recovered and hydrogen is purified and recycled.Type: GrantFiled: March 20, 2013Date of Patent: March 15, 2016Assignee: Saudi Arabian Oil CompanyInventors: Esam Sayed, Raheel Shafi, Abdul Rahman Zafer Akhras, Abdennour Bourane, Ibrahim A. Abba
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Patent number: 9255230Abstract: An integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil is provided to produce olefinic and aromatic petrochemicals. Crude oil and hydrogen are charged to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity. Hydroprocessed effluent is thermally cracked in the presence of steam to produce a mixed product stream, which is separated. Hydrogen from the mixed product stream is purified and recycled to the hydroprocessing zone, and olefins and aromatics are recovered from the separated mixed product stream.Type: GrantFiled: April 17, 2013Date of Patent: February 9, 2016Assignee: Saudi Arabian Oil CompanyInventors: Raheel Shafi, Julio Hasselmeyer, Abdennour Bourane, Ibrahim A. Abba, Abdul Rahman Zafer Akhras
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Patent number: 9228140Abstract: An integrated hydrotreating, steam pyrolysis and catalytic cracking process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil and hydrogen are charged to a hydroprocessing zone under conditions effective to produce a hydroprocessed effluent, which is thermally cracked in the presence of steam in a steam pyrolysis zone to produce a mixed product stream. Heavy components are catalytically cracked, which are derived from one or more of the hydroprocessed effluent, a heated stream within the steam pyrolysis zone, or the mixed product stream catalytically cracking. Catalytically cracked products are produced, which are combined with the mixed product stream and the combined stream is separated, and olefins and aromatics are recovered as product streams.Type: GrantFiled: March 20, 2013Date of Patent: January 5, 2016Assignee: Saudi Arabian Oil CompanyInventors: Ibrahim A. Abba, Raheel Shafi, Abdennour Bourane, Essam Sayed, Abdul Rahman Zafer Akhras
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Patent number: 9174202Abstract: A catalyst usable in hydrotreatment processes: an alumina-based amorphous support, phosphorus, a C1-C4 dialkyl succinate, acetic acid and a hydro-dehydrogenizing function of at least one group VIII element and at least one group VIB element, preferably made up of cobalt and molybdenum, a catalyst whose Raman spectrum comprises the most intense bands characteristic of the Keggin heteropolyanions (974 and/or 990 cm?1), C1-C4 dialkyl succinate and acetic acid (896 cm?1). Preferably, the dialkyl succinate concerned is dimethyl succinate and its main band is at 853 cm?1.Type: GrantFiled: December 8, 2010Date of Patent: November 3, 2015Assignees: TOTAL RAFFINAGE MARKETING, IFP ENERGIES NOUVELLESInventors: Karin Marchand, Bertrand Guichard, Mathieu Digne, Michael Rebeilleau, Sylvie Lopez, Antoine Hugon, Audrey Bonduelle
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Patent number: 9169450Abstract: The present invention is directed to a process for converting heavy hydrocarbonaceous feeds to jet and diesel products: using a single reactor, dual catalyst system; or using a single reactor, multiple catalyst system.Type: GrantFiled: February 12, 2008Date of Patent: October 27, 2015Assignee: Chevron U.S.A. Inc.Inventor: Cong-Yan Chen
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Patent number: 9163180Abstract: A process for the conversion of carbon-based material to fuel bases by a hybrid route combining direct ebullent bed liquefaction and indirect liquefaction by gasification followed by a Fischer-Tropsch synthesis, including a stage of production of hydrogen resulting from non-fossil resources and a reverse water gas reaction stage. This process makes it possible to limit emissions of greenhouse gases.Type: GrantFiled: December 6, 2012Date of Patent: October 20, 2015Assignee: IFP ENERGIES NOUVELLESInventors: Pierre Marion, Alain Quignard, Wilfried Weiss
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Patent number: 9109169Abstract: A gasoline blending components production system useful for producing both aromatics and gasoline blending components from naphtha. The production system includes a light hydrocracked naphtha splitter, a medium hydrocracked naphtha splitter, a naphtha hydrotreater, an isomerization unit, a continuous catalytic reformer and aromatics complex. The production system is operable to produce both refined benzene and para-xylene products in addition to medium hydrocracked naphtha, isomerate, a C7s cut and a C9+ cut, which are useful for gasoline blending without additional treatment. A method for producing gasoline blending components while maximizing aromatic production includes introducing both stabilized hydrocracked naphtha to the light hydrocracked naphtha splitter and straight run naphtha to the naphtha hydrotreater. Operating the production system produces three types of hydrocracked naphtha: a light hydrocracked naphtha, a medium hydrocracked naphtha and a heavy hydrocracked naphtha.Type: GrantFiled: May 2, 2013Date of Patent: August 18, 2015Assignee: Saudi Arabian Oil CompanyInventors: Fahad Al-Therwi, Noaman Al-Fudail, Mansoor Aleidi
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Patent number: 9101854Abstract: A system and method of cracking hydrocarbon feedstocks is provided that allows for significant flexibility in terms of the desired product yield. An integrated process includes introducing the feedstock and hydrogen into a first hydrocracking reaction zone containing a first hydrocracking catalyst to produce a first zone effluent. The first zone effluent and optionally additional hydrogen are passed to a second hydrocracking reaction zone containing a second hydrocracking catalyst to produce a second zone effluent. The second zone effluent is conveyed to a fractionating zone to at least a low boiling fraction and a high boiling fraction, and optionally one or more intermediate fractions. The bottoms fraction is passed to a fluidized catalytic cracking reaction and separation zone, from which olefins and gasoline are recovered. At least a portion of remaining cycle oil is passed from the fluidized catalytic cracking reaction and separation zone to the first and/or second hydrocracking reaction zone.Type: GrantFiled: March 23, 2011Date of Patent: August 11, 2015Assignee: Saudi Arabian Oil CompanyInventors: Omer Refa Koseoglu, Musaed Muhammad Al-Thubaiti, Ali Mahmood Al-Somali
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Patent number: 9074159Abstract: Embodiments of a process for improving a re-refined lube oil stream are provided. The process comprises the steps of introducing a gas stream comprising hydrogen (H2) and the re-refined lube oil stream comprising hydroprocessed used lube oil to a hydrogenation reactor that contain Group VIII catalyst. A gas to oil feed ratio rate of from about 30 to about 100 Nm3 H2/m3 is used to introduce the streams to the reactor. The hydroprocessed used lube oil is hydrogenated with the H2 in the reactor such that an effluent is formed containing hydrogenated re-refined lube oil having about 2 wt. % or less of aromatics and about 55 wt. % or less of naphthenes. The reactor is operating at a temperature of from about 250 to about 300° C.Type: GrantFiled: October 6, 2010Date of Patent: July 7, 2015Assignee: UOP LLCInventors: Steven F. Zink, Tom Kalnes, Mark VanWees
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Patent number: 9074143Abstract: Slurry hydrocracking a heavy hydrocarbon feed produces a HVGO stream and a pitch stream. At least a portion of the pitch stream is subjected to SDA to prepare a DAO stream low in metals. The DAO is blended with at least a portion of the HVGO stream to provide turbine or marine fuel with acceptable properties for combustion in gas turbines or for marine fuel grades.Type: GrantFiled: December 11, 2009Date of Patent: July 7, 2015Assignee: UOP LLCInventors: James F. McGehee, Lorenz J. Bauer
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Patent number: 9074146Abstract: A process and apparatus are disclosed for hydrotreating a hydrocarbon feed in a hydrotreating unit and hydrocracking a second hydrocarbon stream in a hydrocracking unit. The hydrocracking unit and the hydrotreating unit may share the same recycle gas compressor. A make-up hydrogen stream may also be compressed in the recycle gas compressor. A hydrocracking separator separates recycle gas and hydrocarbons from the hydrocracking unit to be processed with effluent from the hydrotreating unit.Type: GrantFiled: March 29, 2012Date of Patent: July 7, 2015Assignee: UOP LLCInventors: Paul R. Zimmerman, Peter Kokayeff
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Patent number: 9062258Abstract: The invention relates to a process for the catalytic hydrotreating of a feedstock of petroleum origin of diesel fuel type and of a feedstock of biological origin based on vegetable oils and/or animal fats in a stationary bed catalytic hydrotreating unit, the said process being characterized in that the feedstock of petroleum origin is introduced into the said reactor upstream of the feedstock of biological origin. It also relates to a catalytic hydrotreating unit for the implementation of the said process and to a corresponding hydrorefining unit.Type: GrantFiled: December 11, 2007Date of Patent: June 23, 2015Assignee: TOTAL RAFFINAGE MARKETINGInventors: Vincent Mayeur, Cesar Vergel, Gildas Morvan, Laurent Mariette, Michael Hecquet
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Publication number: 20150144529Abstract: A process for the hydrotreatment of a vacuum distillate type hydrocarbon feed containing nitrogen-containing compounds is described, comprising a first step in which the feed is brought into contact with a catalyst in its oxide form, then a second step in which the feed is brought into contact with a dried catalyst comprising at least one organic compound containing oxygen and/or nitrogen.Type: ApplicationFiled: November 26, 2014Publication date: May 28, 2015Applicant: IFP ENERGIES NOUVELLESInventors: Magalie ROY-AUBERGER, Emmanuelle GUILLON, Aline GREZAUD
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Publication number: 20150136648Abstract: Methods of treating coal tar using reactive distillation are described. The methods include introducing a coal tar stream into a reactive distillation zone which has a reaction zone and a separation zone. The reaction zone contains a hydrotreating catalyst and an absorbent. The coal tar stream is contacted with a hydrogen stream in the reaction zone to remove contaminants from the coal tar stream, and the treated coal tar stream is separated into at least two fractions.Type: ApplicationFiled: August 28, 2014Publication date: May 21, 2015
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Publication number: 20150136652Abstract: A process for hydrotreating a coal tar stream is described. A coal tar stream is provided, and the coal tar stream is expanded with an inert gas stream to provide an expanded liquid coal tar stream. The expanded liquid coal tar stream is hydrotreated. The coal tar stream can be reacted with a hydrocarbon solvent before it is expanded.Type: ApplicationFiled: August 26, 2014Publication date: May 21, 2015Inventors: Maureen L. Bricker, Paul T. Barger, Joseph A. Kocal, Matthew Lippmann, Kurt M. Vanden Bussche