With Hydrogen Patents (Class 208/89)
  • Patent number: 7470358
    Abstract: An integrated process for the production of low sulfur diesel. The process utilizes a middle distillate hydrocarbon stream and a heavy distillate hydrocarbon stream. The middle distillate hydrocarbon feedstock is reacted with a hydrogen rich gaseous stream having a first pressure in a hydrodesulfurization reaction zone and the heavy distillate hydrocarbon feedstock is reacted with a hydrogen rich gaseous stream having a second pressure in a hydrocracking zone.
    Type: Grant
    Filed: December 19, 2005
    Date of Patent: December 30, 2008
    Assignee: UOP LLC
    Inventor: Tom N. Kalnes
  • Patent number: 7449102
    Abstract: A process for the production of low sulfur diesel and a residual hydrocarbon stream containing a reduced concentration of sulfur. A residual hydrocarbon feedstock and a heavy distillate hydrocarbon feedstock are used in the process.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: November 11, 2008
    Assignee: UOP LLC
    Inventor: Tom N. Kalnes
  • Patent number: 7449421
    Abstract: A catalyst comprising at least one zeolite (molecular sieve) chosen from the group formed by the TON structure type zeolites (Theta-1, ZSM-22, ISI-1, NU-10 and KZ-2) and at least one zeolite chosen from the group formed by the zeolites (ZSM-48, EU-2, EU-11 and ZBM-30), at least one porous mineral matrix, at least one hydro-dehydrogenating element, preferably chosen from the elements of Group VIB and Group VIII of the periodic table, is used for the conversion of hydrocarbons, in particular for the reduction of the pour point of charges containing long (more than 10 carbon atoms) linear and/or slightly branched paraffins, in particular in order to convert, with a good yield, charges having high pour points to at least one cut having a low pour point and a high viscosity index for oil bases.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: November 11, 2008
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Emmanuelle Guillon, Johan Martens
  • Publication number: 20080237090
    Abstract: Olefins can impose deleterious effect on hydrocarbon reforming processes used to generate hydrogen-enriched gas, and thus are converted into saturated compounds. Since the hydrogenation process to convert the olefins into saturated compound, difficulties arise in attempting to regulate the temperature of the hydrogenation. To facilitate temperature regulation, the hydrogenation reaction is carried out in a shell-tube reactor, containing catalyst-filled tubes, which is operated under isothermal or essentially isothermal conditions. Preferably, the heat exchange medium introduced into the shell side of the reactor to regulate the hydrogenation temperature is boiling water.
    Type: Application
    Filed: March 30, 2007
    Publication date: October 2, 2008
    Inventors: Nicholas Musich, Raju S. Natarajan, Harald Klein
  • Patent number: 7429318
    Abstract: A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreated feedstock is hydrodewaxed using a dewaxing catalyst that has been selectively activated by oxygenate treatment. The hydrodewaxed product may then be hydrofinished.
    Type: Grant
    Filed: May 18, 2006
    Date of Patent: September 30, 2008
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer, David W. Larkin, John E. Gallagher, Jr., Jeenok T. Kim
  • Patent number: 7427349
    Abstract: The present invention relates to the field of hydroprocessing, and more particularly relates to a process directed to fuels hydrocracking and distillate feed hydrofining. This process has at least two stages. A relatively unconverted hydrofined product may be removed prior to the second stage, providing flexibility. In another embodiment, fresh feed may be added prior to the second stage. In both embodiments, fuels production is maintained at a constant level.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: September 23, 2008
    Assignee: Chevron U.S.A. Inc.
    Inventors: Ujjal K. Mukherjee, Kevin L. Hofer, Darush Farshid
  • Patent number: 7427348
    Abstract: A process with an increased efficiency for the preparation of middle distillates with excellent properties at low temperatures and substantially without oxygenated organic compounds, starting from a synthetic mixture of hydrocarbons at least partly waxy, containing a fraction of alcohols, comprising the separation of the mixture into a low-boiling fraction and a high-boiling fraction; the subsequent hydrogenation of the low-boiling fraction under such conditions as to avoid any substantial variation in its average molecular weight; the joining of at least a part of the hydrogenated fraction with said high-boiling fraction, and the subsequent catalytic hydrocracking treatment of the mixture of hydrocarbons thug formed, to obtain a substantial conversion of the waxy part into middle distillate.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: September 23, 2008
    Assignees: ENI S.p.A., Enitecnologie S.p.A., Institut Francais du Petrole
    Inventors: Vincenzo Calemma, Silvia Guanziroli, Silvia Pavoni, Roberto Giardino
  • Patent number: 7419582
    Abstract: A hydrocracking process wherein the feedstock is hydrotreated and the liquid and gaseous effluent from the hydrotreater is directly introduced into the upper end of a hydrocracking vessel which provides a liquid seal to prevent the passage of the gaseous stream containing hydrogen sulfide and ammonia from the hydrotreater to enter the hydrocracking zone containing hydrocracking catalyst. Fresh hydrogen is then introduced into the hydrocracking zone. An apparatus for hydrocracking a hydrocarbon feedstock is also disclosed.
    Type: Grant
    Filed: July 11, 2006
    Date of Patent: September 2, 2008
    Assignee: UOP LLC
    Inventors: Richard K. Hoehn, Vasant P. Thakkar, Vedula K. Murty, Douglas W. Kocher-Cowan, Jennifer L. Anderson
  • Patent number: 7416653
    Abstract: Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. In some embodiments, gas is produced during contact with one or more catalysts and the crude feed.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: August 26, 2008
    Assignee: Shell Oil Company
    Inventors: Scott Lee Wellington, Thomas Fairchild Brownscombe, Stanley Nemec Milam
  • Patent number: 7407571
    Abstract: A novel apparatus for producing sweet synthetic crude from a heavy hydrocarbon feed includes: an upgrader for receiving the heavy hydrocarbon feed and producing a distillate fraction including sour products, and high-carbon content by-products; a gasifier for receiving the high-carbon content by-products and producing synthetic fuel gas and sour by-products; a hydroprocessing unit for receiving the sour by-products and hydrogen gas, thereby producing gas and sweet crude; and a hydrogen recovery unit for receiving the synthetic fuel gas and producing further hydrogen gas and hydrogen-depleted synthetic fuel gas, the further hydrogen gas being supplied to the hydroprocessing unit.
    Type: Grant
    Filed: December 24, 2002
    Date of Patent: August 5, 2008
    Assignee: Ormat Industries Ltd.
    Inventors: Philip Rettger, Randall Goldstein, Jim Arnold, Yoram Bronicki, J. Robert Friday
  • Publication number: 20080159928
    Abstract: A process is provided to produce an ultra low sulfur diesel with less than about 10 ppm sulfur using a two-phase or liquid-phase continuous reaction zone to convert a diesel boiling range distillate preferably obtained from a mild hydrocracking unit. In one aspect, the diesel boiling range distillate is introduced to the liquid-phase continuous reaction zone over-saturated with hydrogen in an amount effective so that the liquid phase remains substantially saturated with hydrogen throughout the reaction zone as the reactions proceed.
    Type: Application
    Filed: December 29, 2006
    Publication date: July 3, 2008
    Inventors: Peter Kokayeff, Laura E. Leonard, Michael R. Smith
  • Patent number: 7390394
    Abstract: The invention is directed to a method of making a catalyst comprising an intermediate pore size molecular sieve, preferably a zeolite of the MTT or TON type. SSZ-32 and ZSM-22 are examples of such molecular sieves. This catalyst is modified with a metal or metals selected from the group consisting of Ca, Cr, Mg, La, Ba, Pr, Sr, K and Nd. The catalyst is additionally loaded with a Group VIII metal or metals for hydrogenation purposes. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is isomerized.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: June 24, 2008
    Assignee: Chevron U.S.A. Inc.
    Inventors: Joseph A. Biscardi, Darren P. Fong, Paul Marcantonio
  • Patent number: 7384537
    Abstract: According to the method of manufacturing refined oil of the present invention, refined oil which has a viscosity of 20 cst or lower at 135° C., a pour point of 30° C. or lower, an alkali metal content of 1 wt ppm or less, a vanadium content of 10 wt ppm or less and a sulfur content of 0.3 wt % or lower can be prepared, by bringing feed oil into contact with hydrogen in the presence of the demetalizing/desulfurizing catalyst 3 and the hydrogenolysis catalyst 5. This method can decrease the viscosity, pour point and sulfur concentration of the refined oil to sufficiently low levels, and decreases the production cost.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: June 10, 2008
    Assignee: JGC Corporation
    Inventors: Shigeki Nagamatsu, Makoto Inomata, Susumu Kasahara
  • Patent number: 7384538
    Abstract: A process for the hydroisomerization of a waxy feed having a major portion boiling above 650° F. to produce a lubricating base oil having a lower pour point, said process comprising (a) passing the waxy feed along with hydrogen gas through a hydroisomerization zone maintained at a hydrogen partial pressure of between about 100 psia and about 400 psia, said hydroisomerization zone comprising a catalyst bed containing at least two active wax hydroisomerization catalysts, said catalysts comprising at least (i) a first catalyst comprising an active hydrogenation component and a 1-D, 10-ring molecular sieve having a maximum crystallographic free diameter of the channels equal to 6.2 ? units or greater and (ii) a second catalyst comprising an active hydrogenation component and a 1-D, 10-ring molecular sieve having a maximum crystallographic free diameter of the channels equal to 5.
    Type: Grant
    Filed: November 2, 2004
    Date of Patent: June 10, 2008
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen J. Miller
  • Patent number: 7381321
    Abstract: Process for transforming a gas-oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a hydrocracking stage, whereby the latter uses a catalyst that contains at least one zeolite. The conversion of products that have a boiling point of less than 150° C. is, throughout the two stages of hydrocracking and hydrorefining, less than 40% by weight and, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the hydrocracking stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: June 3, 2008
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Pierre Marion
  • Patent number: 7374667
    Abstract: For the production of gasoline with a low sulfur content, a process comprises at least one stage for transformation of sulfur-containing compounds consisting of an alkylation or adsorption of sulfur-containing compounds and/or an increasing of the weight of light sulfur-containing compounds, at least one stage for treatment in the presence of an acid catalyst and at least one desulfurization treatment of at least a portion of the gasoline. The process can also optionally comprise at least one stage for selective hydrogenation of diolefins and optionally at least one fractionation of the gasoline that is obtained into at least two fractions: light gasoline and heavy gasoline.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: May 20, 2008
    Assignees: BP Corporation North America, Inc., Institute Francais du Petrole
    Inventors: Quentin Debuisschert, Denis Uzio, Jean-Luc Nocca, Florent Picard, David B Arnett, Mike Grayson, Donald E Zeek, Carl Snider
  • Patent number: 7351326
    Abstract: Thermal cracking in a riser cracking, closed cyclone, fluidized catalytic cracking process is reduced. A snorkel or flow conduit having an inlet just above the catalyst stripper moves stripper vapor into the closed cyclone. The system preferably operates without a stripper cap, relying on fluid dynamics to isolate stripper vapor from upper parts of the vessel containing the riser outlet. Preferably the snorkel is at least partially supported by, and ideally is inside, the primary cyclone dipleg. Reduced residence time of stripper vapor in the vessel containing the stripper and the closed cyclone system reduces thermal cracking of stripper vapor.
    Type: Grant
    Filed: July 16, 2003
    Date of Patent: April 1, 2008
    Inventor: Hartley Owen
  • Patent number: 7344633
    Abstract: A process to prepare a base oil having a saturates content of more than 90 wt %, a sulphur content of less than 0.03 wt %, and, a viscosity index of between 80 and 120 from a solvent refined base oil feedstock, which process comprises: (a) contacting the solvent refined base oil feedstock in the presence of a hydrogen containing gas in a first reaction zone containing one or more fixed beds of a catalyst, which catalyst comprises at least one Group VIB metal component and at least one non-noble Group VIII metal component supported on a refractory oxide carrier; and (b) contacting the effluent of step (a) in the presence of a hydrogen containing gas in a second reaction zone containing one or more fixed beds of a catalyst, which catalyst comprises a catalyst comprising a noble metal component supported on an amorphous refractory oxide carrier, wherein the oil feedstock in step (a) flows counter-current to the up flowing hydrogen containing gas.
    Type: Grant
    Filed: April 19, 2002
    Date of Patent: March 18, 2008
    Assignee: Shell Oil Company
    Inventors: Marc Collin, Eric Duprey
  • Patent number: 7345211
    Abstract: The invention includes a process for producing synthetic middle distillates and synthetic middle distillates produced therefrom. In one embodiment, the process comprises fractionating a hydrocarbon synthesis product to at least generate a light middle distillate, a heavy middle distillate, and a waxy fraction; thermally cracking the waxy fraction; and isomerizing the heavy middle distillate. A synthetic diesel or blending component is formed by the combination of at least a portion of the light middle distillate; at least a portion or fraction of the thermally cracked product; and at least a portion or fraction of the isomerized product. In some embodiments, the hydrocarbon synthesis product and/or the thermally cracked product may be hydrotreated. In other embodiments, a synthetic middle distillate comprises at least two fractions: a light fraction with not more than 10% branched hydrocarbons, and a heavy fraction with at least 30% branched hydrocarbons.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: March 18, 2008
    Assignee: ConocoPhillips Company
    Inventors: Rafael L. Espinoza, Keith H. Lawson
  • Patent number: 7341657
    Abstract: Disclosed is a process for reducing sulfur and olefin contents in gasoline, comprising contacting gasoline feedstock and hydrogen with a hydrorefining catalyst and an paraffin-modification catalyst. The effluent of the process is separated to obtain a hydrotreated gasoline fraction free of mercaptan and having a low content of sulfur, e.g. less than 200 ppm, a low content of olefins, e.g. less than 20% by volume, and little octane loss. The hydrotreated gasoline fraction can be used as blending component of a final gasoline product.
    Type: Grant
    Filed: December 22, 2003
    Date of Patent: March 11, 2008
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Dadong Li, Yulin Shi, Yunjian Hu, Yuanbing Xi, Mingfeng Li, Yahua Shi
  • Patent number: 7335295
    Abstract: There is provided a coated zeolite catalyst in which the accessibility of the acid sites on the external surfaces of the zeolite is controlled and a process for converting hydrocarbons utilizing the coated zeolite catalyst. The zeolite catalyst comprises core crystals of a first zeolite and a discontinuous layer of smaller size second crystals of a second zeolite which cover at least a portion of the external surface of the first crystals The coated zeolite catalyst finds particular application in hydrocarbon conversion processes where catalyst activity in combination with zeolite structure are important for reaction selectivity, e.g., catalytic cracking, alkylation, disproportional of toluene, isomerization, and transalkylation reactions.
    Type: Grant
    Filed: June 7, 2004
    Date of Patent: February 26, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jannetje Maatje van den Berge, Gary David Mohr, Kenneth Ray Clem, Wilfried Jozef Mortier, Machteld Maria Mertens, Michael C. Bradford
  • Patent number: 7332071
    Abstract: Process for transforming a gas oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a subsequent stage, whereby the latter uses a catalyst that is selected from the group that consists of hydrorefining catalysts and catalysts that comprise at least one mixed oxide, a metal of group VIB, and a non-noble metal of group VIII. The conversion of products that have a boiling point of less than 150° C. is, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the subsequent stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: February 19, 2008
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Pierre Marion
  • Patent number: 7326331
    Abstract: The invention concerns a process for producing middle distillates from effluents obtained from the Fischer-Tropsch process, comprising separating a heavy cut with an initial boiling point of 120-200° C., hydrotreating said cut and fractionating the hydrotreated cut to obtain at least one intermediate fraction and at least one fraction that is heavier than the intermediate fraction. The intermediate fraction boils between T1 and T2, T1 being in the range 120-200° C. and T2 being in the range 300-410° C. The heavy and intermediate fractions are treated over a hydrocracking/hydroisomerisation catalyst and the effluents obtained are distilled. The invention also concerns a unit.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: February 5, 2008
    Assignees: Institut Francais du Petrole, AGIP Petroli, ENI S.p.A., Enitechnologies E Uffici Di Via
    Inventors: Eric Benazzi, Christophe Gueret
  • Patent number: 7311814
    Abstract: Hydrocarbon fluids are produced by hydrocracking a vacuum gas oil stream, fractionating and/or hydrogenating the hydrocracked vacuum gas oil. The fluids typically have ASTM D86 boiling point ranges within the range 100° C. to 400° C. the range being no more than 75° C., they also have a naphthenic content greater than 60%, the naphthenics containing polycyclic materials, an aromatic content below 2% and an aniline point below 100° C. The fluids are particularly useful as solvents, for printing inks, drilling fluids, metal working fluids and as silicone extenders.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: December 25, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Pierre-Yves Guyomar, Andre A. Theyskens
  • Patent number: 7300565
    Abstract: The invention relates to a process to prepare a microcrystalline wax and a middle distillate fuel by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch product, wherein the weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch product have at least 30 carbon atoms, (b) performing one or more distillate separations on the effluent of step (a) to obtain a middle distillate fuel fraction and a microcrystalline wax having an initial boiling point of between 500 and 600° C.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: November 27, 2007
    Assignee: Shell Oil Company
    Inventor: Arend Hoek
  • Patent number: 7300567
    Abstract: Process for the removal of coloured compounds in a hydrocarbon feedstock comprising the steps of hydrotreating the feedstock in presence of a first hydrotreating catalyst under conditions being effective in hydrogenation of hydrogenable compounds being present in the feedstock and hydrotreating an effluent from the first hydrotreating step in a second catalytic hydrotreating step being carried out in a second hydrotreating reactor at hydrotreating conditions, wherein the effluent from the first hydrotreating step is separated into a gas phase and a mixed gas and liquid phase prior to the second hydrotreating step, and the mixed phase is hydrotreated in the second hydrotreating step without further addition of hydrogen.
    Type: Grant
    Filed: June 8, 2004
    Date of Patent: November 27, 2007
    Assignee: Haldor Topsoe A/S
    Inventors: Rasmus Breivik, Johan Mogensen, Kim Grøn Knudsen, Johannes Wrisberg, Bent Sarup
  • Patent number: 7288181
    Abstract: The instant invention relates to a process to produce high octane, low sulfur naphtha products through the removal of basic nitrogen-containing compounds with subsequent skeletal isomerization of feed olefins and hydrotreating.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: October 30, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Stuart S. Shih, David L. Stern, Madhav Acharya
  • Patent number: 7282138
    Abstract: A distillate fuel feed is hydrotreated to remove heteroatoms and then separated into light and heavy hydrotreated fractions, with the heavy fraction catalytically dewaxed to improve low temperature properties. The hydrotreating and dewaxing are conducted in separate stages, which may be in the same reactor vessel. Fresh hydrogen may be passed into the dewaxing stage, with the dewaxing stage gaseous effluent then passed into the hydrotreating stage to provide hydrogen for the hydrotreating. Existing hydrotreating reaction vessels and facilities may be retrofitted to add one or more dewaxing stages.
    Type: Grant
    Filed: September 10, 2004
    Date of Patent: October 16, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Edward S. Ellis, Ramesh Gupta, William J. Novak
  • Patent number: 7282465
    Abstract: A catalyst comprising at least one ZBM-30 zeolite, synthesized in the presence of a particular structuring agent such as triethylenetetramine, at least one porous mineral matrix, at least one hydro-dehydrogenating element, preferably chosen from the elements of Group VIB and Group VIII of the periodic table, is used in order to improve the pour point of charges containing long (more than 10 carbon atoms) linear and/or slightly branched paraffins, in particular in order to convert, with a good yield, charges having high pour points to at least one cut having a low pour point and a high viscosity index for oil bases.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: October 16, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Emmanuelle Guillon, Johan Martens
  • Patent number: 7282137
    Abstract: A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreating step is under conditions such that the amount of conversion to 343° C. minus is less than 5 wt. % of the feedstock and the VI increase is less than 4 VI over the feedstock. Hydrodewaxing uses a low alpha catalyst and hydrofinishing is accomplished with a catalyst based on the M41S family.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: October 16, 2007
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer, David W. Larkin, John E. Gallagher, Jr., Jeenok T. Kim
  • Patent number: 7276150
    Abstract: The process for desulfurizing a gas oil fraction according to the invention comprises a low-boiling gas oil fraction hydrodesulfurization step (I) wherein a low-boiling gas oil fraction is desulsurized under the condition of a H2/Oil ratio of 70 to 200 Nm3/kl to obtain a treated oil, a high-boiling gas oil fraction hydrodesulfurization step (II) wherein a high-boiling gas oil fraction is desulsurized under the condition of a H2Oil ratio of 200 to 800 Nm3/kl to obtain a treated oil, and a step (III) wherein the treated oil obtained in the step (I) is mixed with the treated oil obtained in the step (II), and in this process, at least a part of a gas containing unreacted hydrogen in the step (II) is used for the hydrodesulfurization of the step (I).
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: October 2, 2007
    Assignee: JGC Corporation
    Inventors: Shigeki Nagamatsu, Jun Abe, Akira Sugimoto, Makoto Inomata, Tetsuya Watanabe
  • Patent number: 7276151
    Abstract: Feed oil is subject to atmospheric distillation, to thereby be separated into light oil or light distillate and atmospheric residue oil. The light distillate is catalytically contacted with pressurized hydrogen in the presence of a catalyst, resulting in a first hydrotreating step being executed. In this instance, various fractions of the light distillate produced in the atmospheric distillation are subject to hydrotreating in a lump. The atmospheric residue oil is then separated into a light matter and a heavy matter. The light matter is subject to second hydrotreating in the presence of a catalyst to produce refined oil (light matter), which is mixed with refined oil produced in the first hydrotreating to prepare a mixture. The mixture is used as gas turbine fuel oil.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: October 2, 2007
    Assignee: JGC Corporation
    Inventors: Tsuyoshi Okada, Yoshinori Mashiko, Shinichi Tokuda, Tomoyoshi Sasaki, Kozo Imura, Makoto Inomata, Toshio Tanuma
  • Patent number: 7270738
    Abstract: This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 ?, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 ?, of less than 0.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: September 18, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Patrick Euzen, Carole Bobin, Magalie Roy-Auberger, Eric Benazzi, Patrick Bourges, Christophe Gueret
  • Patent number: 7261809
    Abstract: A process for removing organic sulfur compounds from heavy boiling range naphtha in a dual purpose reactor wherein the heavy boiling range naphtha is fed downflow over a fixed bed of hydrodesulfurization zone and then treated with hydrogen in a hydrodesulfurization catalytic distillation zone. Vapor containing hydrogen sulfide is removed between the zones. Preferably the heavy boiling range naphtha is produced by treating a full boiling range naphtha to concurrently react diolefins and mercaptans and split the light and heavy boiling range naphtha in a distillation column reactor.
    Type: Grant
    Filed: November 15, 2002
    Date of Patent: August 28, 2007
    Assignee: Catalytic Distillation Technologies
    Inventor: Amarjit S. Bakshi
  • Patent number: 7261806
    Abstract: A process to prepare a base oil starting from a slack wax containing feedstock by (a) contacting the feedstock in the presence of hydrogen with a sulphided hydrodesulphurisation catalyst having nickel and tungsten on an acid amorphous silica-alumina carrier and (b) performing a pour point reducing step on the effluent of step (a) to obtain the base oil.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: August 28, 2007
    Assignee: Shell Oil Company
    Inventors: Gerard Benard, Eric Duprey, Johannes Anthonius Robert Van Veen
  • Patent number: 7250107
    Abstract: For producing basic oils and in particular very high quality oils, i.e. oils possessing a high viscosity index (VI), a low aromatics content, good UV stability and a low pour point, from oil cuts having an initial boiling point higher than 340° C., possibly with simultaneous production of middle distillates (in particular gasoils and kerosene) of very high quality, i.e. having a low aromatics content and a low pour point, the invention provides a flexible procedure for producing oils and middle distillates from a charge containing heteroatoms, i.e. containing more than 200 ppm by weight of nitrogen, and more than 500 ppm by weight of sulphur. The procedure comprises at least one hydrorefining stage, at least one stage of catalytic dewaxing on zeolite, and at least one hydrofinishing stage.
    Type: Grant
    Filed: July 23, 2001
    Date of Patent: July 31, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Christophe Gueret, Pierre Marion, Alain Billon
  • Patent number: 7238274
    Abstract: First (210) and second (240) feedstocks are hydrotreated in an integrated hydrogenation plant (200) using a hot separator (230) that provides a vapor stream containing at least some of the hydrotreated first feedstock (210), wherein the second feedstock (240) is mixed with the vapor stream at a position downstream of the separator (240) and upstream of the a second hydrotreating (250) reactor to form a mixed second feedstock that is fed into the second hydrotreating reactor (250) to produce a ultra-low sulfur product.
    Type: Grant
    Filed: April 3, 2002
    Date of Patent: July 3, 2007
    Assignee: Fluor Technologies Corporation
    Inventor: James Turner
  • Patent number: 7238275
    Abstract: At least two feedstocks (210A) (210B) with different boiling point ranges are hydrotreated in an integrated hydrogenation plant (200) using an interbed separator (240) that is fluidly coupled between two hydrogenation reactors (230A) (230B). Contemplated configurations and methods will significantly reduce construction and operating cost by integration of at least two hydrogenation processes of two different feedstocks into one process, and/or by providing process conditions that reduce use of catalyst in at least one of the reactors.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: July 3, 2007
    Assignee: Fluor Technologies Corporation
    Inventors: Steven Stupin, Garry Jacobs
  • Patent number: 7232848
    Abstract: An apparatus for converting a gaseous and/or liquid feed fluid to gaseous and/or liquid products using a solid catalyst comprises a reactor, a liquid phase disposed within the reactor volume, a fixed catalyst at least partially disposed in the liquid phase, a cooling system having a cooling element in thermal contact with the liquid phase, a feed inlet positioned to feed the feed fluid into the reactor volume, and a fluid outlet in fluid communication with the liquid phase. The catalyst is contained in a catalyst container and the container may be adjacent to said cooling element, extend through said cooling element, or may surround the catalyst container. The catalyst may be a Fischer-Tropsch catalyst.
    Type: Grant
    Filed: September 9, 2002
    Date of Patent: June 19, 2007
    Assignee: ConocoPhillips Company
    Inventors: Sergio R. Mohedas, Rafael L. Espinoza, Jianping Zhang
  • Patent number: 7229548
    Abstract: A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: June 12, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Kenneth L. Riley, Stuart L. Soled, Sabato Miseo, Frans L. Plantenga, Marinus Bruce Cerfontain, Sonja Eijsbouts, Eelko Brevoord
  • Patent number: 7223333
    Abstract: Conducting the hydrodesulphurization of gasoline cuts in the presence of a catalyst comprising at least one support, at least one element of group VIII and tungsten, in which the atomic ratio (element of group VIII)/(element of group VIII+tungsten) is greater than 0.15 and less than 0.50, preferably 0.35–0.40 inclusive.
    Type: Grant
    Filed: June 2, 2003
    Date of Patent: May 29, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Denis Uzio, Stephane Cremer, Carine Petit-Clair, Nathalie Marchal-George, Christophe Bouchy, Florent Picard
  • Patent number: 7220350
    Abstract: A waxy hydrocarbon feed is catalytically treated with a dewaxing catalyst that has been selectively activated. The selective activation of the catalyst involves treating the catalyst with at least one oxygenate. The selectively activated catalyst can then be used to dewax waxy hydrocarbon to improve yield and product quality of the isomerate product.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: May 22, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer
  • Patent number: 7201838
    Abstract: Fischer-Tropsch hydrocarbon synthesis using a cobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided 10-ring, 1-dimensional zeolite catalyst that has been reduced and then treated by contacting it with the synthesized hydrocarbons containing one or more oxygenates, including indigenous oxygenate. Tail gas from the hydrodewaxing reactor can be used for the hydrocarbon synthesis.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: April 10, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Adeana Richelle Bishop, William Berlin Genetti, Jack Wayne Johnson, Loren Leon Ansell, Nancy Marie Page
  • Patent number: 7198712
    Abstract: For desulfurization and, if necessary, for denitrification of hydrocarbon fractions the hydrocarbon mixture is brought into contact with a non-aqueous ionic liquid of general formula Q+A?, wherein Q+ is a ammonium, phosphonium or sulfonium cation, that contains at least one alkylating agent of the formula RX?, making it possible to form ionic sulfur-containing derivatives (and, if necessary, nitrogen-containing derivatives) that have a preferred solubility in the ionic liquid; and the ionic liquid is separated from the hydrocarbon mixture that is low in sulfur and nitrogen by decanting.
    Type: Grant
    Filed: June 17, 2003
    Date of Patent: April 3, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Helene Olivier-Bourbigou, Denis Uzio, Lionel Magna, Fabrice Diehl
  • Patent number: 7160436
    Abstract: An improved hydrocracking process of hydrocarbon charges, in two stages with an intermediate separation, in which the second-stage of hydrocracking is carried out in the presence of an added nitrogen content which is greater than 150 ppm by weight, preferably about 500 ppm by weight, and preferably in the presence of a Y zeolite catalyst, produces high yields of middle distillate.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: January 9, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Jean-Marie Deves, Pierre Marion, Christophe Gueret, Alain Billon, Patrick Bourges
  • Patent number: 7156978
    Abstract: A system comprising: a paraffin feed produced by the Fischer-Tropsch process is fractionable into at least three fractions: an intermediate fraction boiling between T1 and T2, T1 being in the range 120–200° C. and T2 being more than 300° C. and less than 410° C., a light fraction boiling below it and a heavy fraction boiling above it; at least a portion of the intermediate fraction is hydrotreated then at least a portion thereof is passed over an amorphous hydroisomerisation/hydrocracking catalyst; the heavy fraction is passed over an amorphous hydroisomerisation/hydrocracking catalyst with a conversion of 370° C.+ products into 370° C.? products of more than 80% by weight; the hydrocracked/hydroisomerised fractions are distilled to obtain middle distillates (kerosine, gas oil).
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: January 2, 2007
    Assignees: Institut Francais du Petrole, AGIP Petroli S.p.A., ENI S.p.A., EniTecnolgie SpA
    Inventors: Eric Benazzi, Christophe Gueret
  • Patent number: 7132043
    Abstract: Process to prepare a lubricating base oil starting from a lubricating base oil which is obtained by first removing part of the aromatic compounds from a petroleum fraction boiling in the lubricating oil range by solvent extraction and subsequently dewaxing the solvent extracted product, wherein the following steps are performed, (a) contacting the lubricating base oil with a suitable sulphided hydrotreating catalyst in a first hydrotreating step; (b) separating the effluent of step (a) into a gaseous fraction and a liquid fraction; (c) contacting the liquid fraction of step (b) with a catalyst comprising a noble metal component supported on an amorphous refractory oxide carrier in the presence of hydrogen in a second hydrotreating step; and (d) recovering the lubricating base oil.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: November 7, 2006
    Assignee: Shell Oil Company
    Inventors: Eric Duprey, Jean-Paul Fattaz, Roland Albert Charles Garin, Patrick Moureaux
  • Patent number: 7128828
    Abstract: A process for producing food grade wax which contains exceedingly low levels of nitrogen, sulfur and aromatic compounds. A waxy feedstock is firstly hydrotreated in a first hydrogenation zone to reduce the level of contaminants such as sulfur, nitrogen and aromatic compounds, and the resulting effluent from the first hydrogenation zone is introduced into a hot, high pressure stripper and contacted with a hot, hydrogen-rich stripping gas to remove ammonia and hydrogen sulfide. The stripped, hot liquid hydrocarbons are removed from the bottom of the hot, high-pressure stripper to further reduce the concentration of aromatic compounds by being hydrogenated in a second hydrogenation zone containing a platinum or palladium catalyst.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: October 31, 2006
    Assignee: UOP LLC
    Inventor: Tom N. Kalnes
  • Patent number: 7108779
    Abstract: A process for the production of low sulfur hydrocarbonaceous products. The hydrocarbon feedstocks are processed in integrated desulfurization zone, hydrocracking and hydrogenation zones to produce ultra low sulfur diesel, low sulfur naphtha products and low sulfur heavy distillate.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: September 19, 2006
    Assignee: UOP LLC
    Inventor: Vasant P. Thakkar
  • Patent number: 7097760
    Abstract: A catalytic hydrocracking process for the production of ultra low sulfur diesel wherein a hydrocarbonaceous feedstock is hydrocracked at elevated temperature and pressure to obtain conversion to diesel boiling range hydrocarbons. The resulting hydrocracking zone effluent is hydrogen stripped in a stripping zone maintained at essentially the same pressure as the hydrocracking zone to produce a first gaseous hydrocarbonaceous stream and a first liquid hydrocarbonaceous stream. The first gaseous hydrocarbonaceous stream containing diesel boiling range hydrocarbons is introduced into a desulfurization zone and subsequently partially condensed to produce a hydrogen-rich gaseous stream and a second liquid hydrocarbonaceous stream containing diesel boiling range hydrocarbons. The first liquid stream is separated to produce a third liquid hydrocarbonaceous stream containing diesel boiling range hydrocarbons which is also introduced into the desulfurization zone. An ultra low sulfur diesel product stream is recovered.
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: August 29, 2006
    Assignee: UOP LLC
    Inventors: Tom N. Kalnes, Vasant P. Thakkar, Richard K. Hoehn