With Hydrogen Patents (Class 208/89)
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Patent number: 7087152Abstract: A waxy hydrocarbon feed is catalytically dewaxed with a catalyst that has been selectively activated. The selective activation of the catalyst involves contacting the dewaxing catalyst with a feed mixture containing waxy hydrocarbon and at least one oxygenate. The process results in improved catalyst performance resulting in improved yield of isomerate at equivalent pour.Type: GrantFiled: October 3, 2003Date of Patent: August 8, 2006Assignee: ExxonMobil Research and Engineering CompanyInventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer
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Patent number: 7077947Abstract: A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreated feedstock is hydrodewaxed using a dewaxing catalyst that has been selectively activated by oxygenate treatment. The hydrodewaxed product may then be hydrofinished.Type: GrantFiled: October 3, 2003Date of Patent: July 18, 2006Assignee: ExxonMobil Research and Engineering CompanyInventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer, David W. Larkin, John E. Gallagher, Jr., Jeenok T. Kim
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Patent number: 7074321Abstract: An integrated hydrocarbon conversion process for the production of low sulfur fuels utilizing a hydrocracking zone, a diesel hydrodesulfurization zone, a fluid catalytic cracking zone and a gasoline hydrodesulfurization zone. The hydrocracking zone is used to convert at least a portion of the feedstock into diesel boiling range hydrocarbons which are desulfurized in the first hydrodesulfurization zone. The unconverted feedstock is introduced into a fluid catalytic cracking zone to produce gasoline boiling range hydrocarbons which are desulfurized in a second hydrodesulfurization zone.Type: GrantFiled: November 12, 2002Date of Patent: July 11, 2006Assignee: UOP LLCInventor: Tom N. Kalnes
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Patent number: 7041211Abstract: A hydrocracking process wherein a hydrocarbonaceous feedstock and hydrogen is passed to a denitrification and desulfurization reaction zone and then directly to a hot, high pressure stripper utilizing a hot, hydrogen-rich stripping gas to produce a liquid hydrocarbonaceous stream which is passed to a hydrocracking zone. The resulting effluent from the hydrocracking zone is then directly passed to the hot, high pressure stripper. A vapor stream from the hot, high pressure stripper is passed to a post-treat hydrogenation reaction zone to saturate at least a portion of the aromatic compounds contained therein.Type: GrantFiled: May 29, 2003Date of Patent: May 9, 2006Assignee: UOP LLCInventor: Tom N. Kalnes
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Patent number: 6972086Abstract: The invention relates to a process for the production of gasoline with a low sulfur content comprising at least three stages: a first stage in which the sulfur-containing compounds present in the gasoline are at least partially transformed into H2S and into saturated sulfur-containing compounds; a second stage whose purpose is to eliminate the H2S from the gasoline produced in the first stage; and a third stage in which the saturated sulfur-containing compounds remaining in the gasoline are transformed into H2S. The process according to the invention optionally also comprises a pretreatment stage whose purpose is to hydrogenate the diolefins of the feedstock before the first stage.Type: GrantFiled: July 3, 2001Date of Patent: December 6, 2005Assignee: Institut Français du PétroleInventors: Blaise Didillon, Denis Uzio, Jean-Luc Nocca, Quentin Debuisschert
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Patent number: 6951605Abstract: A method to produce high quality lube oil products involving hydrotreating a waxy feed to produce a hydrotreated feed and subsequently hydrodewaxing the hydrotreated feed and hydrofinishing the hydrodewaxed feed.Type: GrantFiled: October 3, 2003Date of Patent: October 4, 2005Assignee: ExxonMobil Research and Engineering CompanyInventors: Ian A. Cody, William J. Murphy
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Patent number: 6930219Abstract: A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of silica containing at least 97% by volume of pores having a pore size ranging from about 15 ? to about 30 ? and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2?. The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.Type: GrantFiled: December 6, 2002Date of Patent: August 16, 2005Assignee: ABB Lummus Global Inc.Inventors: Zhiping Shan, Jacobus Cornelius Jansen, Chuen Y. Yeh, Philip J. Angevine, Thomas Maschmeyer, Mohamed S. Hamdy
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Patent number: 6884339Abstract: A process for the production of very high quality base oils optionally with simultaneous production of high quality middle distillates comprises the stages for hydrotreatment, preferably hydrocracking, on Y or beta zeolite, and atmospheric distillation. The effluent is subjected to a catalytic dewaxing on the ZSM-48 catalyst. The process then comprises a hydrofinishing stage for hydrogenating the aromatic compounds, preferably on a catalyst that comprises at least one noble metal of group VIII, chlorine and fluorine, and the stages of atmospheric and vacuum distillation. The hydrofinishing stage is conducted at a temperature lower by 20-200° C. than the catalytic dewaxing stage.Type: GrantFiled: April 20, 2001Date of Patent: April 26, 2005Assignee: Institut Francais du PetroleInventors: Eric Benazzi, Pierre Marion, Alain Billon, Christophe Gueret, Jean-Claude Hipeaux, Jean Paul Gouzard
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Patent number: 6863802Abstract: A process for upgrading at least one of a Fischer-Tropsch naphtha and a Fischer-Tropsch distillate to produce at least one of a gasoline component, a distillate fuel or a lube base feedstock component. The process includes reforming a Fischer-Tropsch naphtha to produce hydrogen by-product and a gasoline component with a research octane rating of at least about 80. The process further includes upgrading a Fischer-Tropsch distillate using the hydrogen by-product to produce a distillate fuel and/or a lube base feedstock component.Type: GrantFiled: January 31, 2002Date of Patent: March 8, 2005Assignee: Chevron U.S.A.Inventors: Dennis J. O'Rear, Lawrence W. Jossens
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Patent number: 6858131Abstract: Feed oil is subject to atmospheric distillation, to thereby be separated into light oil or light distillate and atmospheric residue oil. The light distillate is catalytically contacted with pressurized hydrogen in the presence of a catalyst, resulting in a first hydrotreating step being executed. In this instance, various fractions of the light distillate produced in the atmospheric distillation are subject to hydrotreating in a lump. The atmospheric residue oil is then separated into a light matter and a heavy matter. The light matter is subject to second hydrotreating in the presence of a catalyst to produce refined oil (light matter), which is mixed with refined oil produced in the first hydrotreating to prepare a mixture. The mixture is used as gas turbine fuel oil.Type: GrantFiled: September 10, 1999Date of Patent: February 22, 2005Assignee: JGC CorporationInventors: Tsuyoshi Okada, Yoshinori Mashiko, Shinichi Tokuda, Tomoyoshi Sasaki, Kozo Imura, Makoto Inomata, Toshio Tanuma
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Patent number: 6841062Abstract: This invention relates to a crude oil desulfurization process which comprises hydrodesulfurizing a crude oil feed in a crude desulfurization unit. The desulfurized crude oil is then separated into a light gas oil fraction, a vacuum gas oil fraction and a vacuum residuum fraction. The vacuum gas oil is hydrocracked to form at least one low sulfur fuel product. The light gas oil fraction is hydrotreated. The vacuum gas oil may be hydrocracked in one or more stages. Hydrocracking in the second stage, if present, will convert of at least 20% of the first zone effluent, to create a low sulfur light gas oil fraction. The light gas oil fraction may then be hydrotreated.Type: GrantFiled: June 28, 2001Date of Patent: January 11, 2005Assignee: Chevron U.S.A. Inc.Inventor: Bruce E. Reynolds
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Patent number: 6835301Abstract: A process for hydroprocessing a hydrotreated liquid distillate stream to produce a stream exceptionally low in sulfur as well as aromatics. A hydrotreated distillate stream is further hydrotreated in a co-current reaction zone wherein the reaction product is passed to a separation drum wherein a vapor product is collected overhead and a liquid product is passed to a aromatics saturation zone countercurrent to the flow of hydrogen treat gas.Type: GrantFiled: December 7, 1999Date of Patent: December 28, 2004Assignee: Exxon Research and Engineering CompanyInventors: Edward S. Ellis, Henry Jung, William E. Lewis
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Patent number: 6830678Abstract: The invention relates to a process of producing gasoline with a low sulphur content from a feedstock containing sulphur. This process comprises at least one step a1 of selectively hydrogenating the diolefins and acetylenic compounds, at least one separation of the gasoline (step b) obtained at step a1 into at least three fractions, at least one step c1 of treating the heavy gasoline separated at step b on a catalyst enabling the unsaturated sulphur compounds to be at least partially decomposed or hydrogenated and at least one step d to remove the sulphur and nitrogen from at least one intermediate fraction, followed by catalytic reforming.Type: GrantFiled: March 29, 2001Date of Patent: December 14, 2004Assignee: Institut Francais DuPetroleInventors: Blaise Didillon, Denis Uzio, Quentin Debuisschert, Jean-Luc Nocca
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Patent number: 6824673Abstract: A process for producing distillate boiling range streams that are low in both sulfur and aromatics. A distillate feedstock is treated in a first hydrodesulfurization stage in the presence of a hydrogen-containing treat gas and a hydrodesulfurization catalyst, thereby resulting in partial desufurization of the stream. The partially desulfurized distillate stream is then treated in a second hydrodesulfurization stage, also in the presence of a hydrogen-containing treat gas and a hydrodesulfurization catalyst. The hydrogen-containing treat gas is cascaded from the next downstream reaction stage, which is an aromatics hydrogenation stage.Type: GrantFiled: April 20, 2000Date of Patent: November 30, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Edward S. Ellis, Henry Jung, William E. Lewis, Larry L. Iaccino, Michele S. Touvelle, Gordon F. Stuntz
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Publication number: 20040232045Abstract: A process for producing a premium Fischer-Tropsch diesel fuel which comprises (a) hydroprocessing a waxy Fischer-Tropsch feed to remove the oxygenates that are present in the feed, whereby a first Fischer-Tropsch intermediate product is produced with reduced olefins and oxygenates relative to the Fischer-Tropsch feed; (b) separating the first Fischer-Tropsch intermediate product in a separation zone into a heavy Fischer-Tropsch fraction and a light Fischer-Tropsch fraction under controlled separation conditions; (c) hydroisomerizing the heavy Fischer-Tropsch fraction to improve the cold flow properties of the heavy Fischer-Tropsch fraction and recovering an isomerized heavy Fischer-Tropsch fraction; (d) mixing the isomerized heavy Fischer-Tropsch fraction with at least a portion of the light Fischer-Tropsch fraction of (b); and (e) recovering from the blend a Fischer-Tropsch derived diesel product meeting a target value for at least one pre-selected specification for diesel fuel.Type: ApplicationFiled: June 30, 2004Publication date: November 25, 2004Applicant: Chevron U.S.A. Inc.Inventors: Christopher A. Simmons, David R. Johnson, Jerome F. Mayer, John M. Rosenbaum, Richard O. Moore, Russell R. Krug
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Publication number: 20040232048Abstract: A catalyst comprising at least one ZBM-30 zeolite, synthesized in the presence of a particular structuring agent such as triethylenetetramine, at least one porous mineral matrix, at least one hydro-dehydrogenating element, preferably chosen from the elements of Group VIB and Group VIII of the periodic table, is used in order to improve the pour point of charges containing long (more than 10 carbon atoms) linear and/or slightly branched paraffins, in particular in order to convert, with a good yield, charges having high pour points to at least one cut having a low pour point and a high viscosity index for oil bases.Type: ApplicationFiled: March 24, 2004Publication date: November 25, 2004Inventors: Eric Benazzi, Emmanuelle Guillon, Johan Martens
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Publication number: 20040226860Abstract: Hydrocracking process for the conversion of a hydrocarbon feedstock that comprises a hydrorefining stage, in which the feedstock is brought into contact with the hydrogen in the presence of a hydrorefining catalyst at a temperature T1, a separation stage in which at least a portion of the converted products that are formed during the hydrorefining stage and a fraction that comprises the unconverted products are separated, and a hydrocracking stage in which the fraction that comprises the unconverted products is at least in part brought into contact with hydrogen in the presence of an amorphous hydrocracking catalyst that comprises a substrate, palladium and platinum, at a temperature T2 that is less than T1, whereby the difference between T1 and T2 is between 5 and 50° C., preferably between 10 and 40° C., and more preferably between 15 and 30° C.Type: ApplicationFiled: February 20, 2004Publication date: November 18, 2004Inventors: Patrick Bourges, Eric Benazzi, Patrick Euzen
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Publication number: 20040222131Abstract: Processes for generating and removing oxidized sulfur species, and in particular sulfoxides, from crude oil and various fractions derived therefrom. Initially, the sulfur species present in the crude oil or fractions derived from the crude oil, is oxidized such that substantially all of the sulfur species are converted to sulfoxides and/or a combination of sulfoxides and sulfones. Thereafter, the fossil fuel containing the oxidized sulfur species are subjected to conventional hydrodesulfurization processes where substantially all of the sulfones are converted to hydrogen sulfide gas.Type: ApplicationFiled: May 5, 2003Publication date: November 11, 2004Inventor: Mark Cullen
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Patent number: 6814856Abstract: A process for transforming a gas oil cut from a conversion process or from an aromatic crude is described, the aim of the process being to improve the cetane number of said cut. The process comprises at least one hydrogenation step in which said gas oil cut is passed, in the presence of hydrogen, over a catalyst comprising an amorphous mineral support, at least one compound of a group VIB metal, at least one compound of a non noble group VIII metal and at least phosphorous or a compound of phosphorous, the process then comprising a hydrocracking step in which the hydrogenated feed is passed, in the presence of hydrogen, over a catalyst comprising an acidic support, at least one compound of a group VIB metal and at least one compound of a non noble group VIII metal.Type: GrantFiled: May 4, 2000Date of Patent: November 9, 2004Assignee: Institut Francais du PetroleInventors: Marcel Aussillous, Alain Billion, Patrick Briot, Christophe Gueret, Slavik Kasztelan, Narhalie Marchal, Pierre Marion
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Publication number: 20040206667Abstract: A process with an increased efficiency for the preparation of middle distillates with excellent properties at low temperatures and substantially without oxygenated organic compounds, starting from a synthetic mixture of hydrocarbons at least partly waxy, containing a fraction of alcohols, comprising the separation of the mixture into a low-boiling fraction and a high-boiling fraction; the subsequent hydrogenation of the low-boiling fraction under such conditions as to avoid any substantial variation in its average molecular weight; the joining of at least a part of the hydrogenated fraction with said high-boiling fraction, and the subsequent catalytic hydrocracking treatment of the mixture of hydrocarbons thug formed, to obtain a substantial conversion of the waxy part into middle distillate.Type: ApplicationFiled: May 27, 2004Publication date: October 21, 2004Inventors: Vincenzo Calemma, Silvia Guanziroli, Silvia Pavoni, Roberto Giardino
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Patent number: 6797154Abstract: With this invention, high conversion of heavy gas oils and the production of high quality products is possible in a single high-pressure loop with reaction stages operating at different pressure and conversion levels. The flexibility offered is great and will allow the refiner to avoid decrease in product quality while at the same time minimizing capital cost. Feeds with varying boiling ranges can be introduced at different sections of the process, thereby minimizing the consumption of hydrogen and further reducing capital investment.Type: GrantFiled: March 21, 2002Date of Patent: September 28, 2004Assignee: Chevron U.S.A. Inc.Inventors: Ujjal Kumar Mukherjee, Wai Seung W. Louie, Arthur J. Dahlberg
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Patent number: 6793804Abstract: An integrated hydrotreating process which produces a high quality feed for the FCC to maintain sulfur in FCC gasoline to a level lower than 30 ppm from a high boiling feedstock and an ultra low sulfur diesel stream preferably less than 10 ppm from a cracked diesel boiling material. The high boiling feedstock is firstly hydrotreated to reduce the concentration of heterogeneous compounds which produces lower boiling hydrocarbonaceous compounds boiling in the diesel range and the resulting hydrotreated high boiling feedstock is separated in a high pressure stripper. The resulting hydrocarbonaceous compounds boiling in the diesel range together with other cracked and/or straight run material in the diesel boiling range are further hydrotreated in an integrated second hydrotreating zone to meet ultra low sulfur diesel specifications and a high cetane index.Type: GrantFiled: November 7, 2001Date of Patent: September 21, 2004Assignee: UOP LLCInventors: David A. Lindsay, Gary R. Brierley, Tom N. Kalnes
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Publication number: 20040173501Abstract: Embodiments include processes for producing streams containing organic molecules (for example, diesel fuels and diesel fuel blending agents) including ultra-low severity hydrotreatment of at least a portion of a hydrocarbon synthesis product stream. Also, streams containing organic molecules (for example, diesel fuels and diesel fuel blending agents) produced by the processes are described.Type: ApplicationFiled: March 5, 2003Publication date: September 9, 2004Applicant: ConocoPhillips CompanyInventors: Keith H. Lawson, Douglas S. Jack, Craig T. Barker, Sridhar Gopalakrishnan, Rafael L. Espinoza
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Patent number: 6787026Abstract: This invention is directed to a process for hydroprocessing vacuum gas oils and other feeds in order to produce unconverted oil suitable for use as base oil feed for white oils, Group III oils, and BMCI (Bureau of Mines Correlation Index) ethylene plant feed. Ammonia, hydrogen sulfide, and light products are removed from the first stage at high pressure in order to produce a higher quality of unconverted oil that is suitable for Group III base oils.Type: GrantFiled: October 28, 2002Date of Patent: September 7, 2004Assignee: Chevron U.S.A. Inc.Inventor: Darush Farshid
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Patent number: 6787025Abstract: In the refining of crude oil, vacuum gas oil hydrotreaters and hydrocrackers are used to remove impurities such as sulfur, nitrogen, and metals from the crude oil. Typically, the middle distillate boiling material (boiling in the range from 250° F.-735° F.) from VGO hydrotreating or moderate severity hydrocrackers does not meet the smoke point, the cetane number or the aromatic specification. In most cases, this middle distillate is separately upgraded by a middle distillate hydrotreater or, alternatively, the middle distillate is blended into the general fuel oil pool or used as home heating oil. With this invention, the middle distillate is hydrotreated in the same high pressure loop as the vacuum gas oil hydrotreating reactor or the moderate severity hydrocracking reactor.Type: GrantFiled: December 17, 2001Date of Patent: September 7, 2004Assignee: Chevron U.S.A. Inc.Inventors: Ujjal Kumar Mukherjee, Wai Seung W. Louie, Arthur J. Dahlberg
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Publication number: 20040159581Abstract: Process for transforming a gas-oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a hydrocracking stage, whereby the latter uses a catalyst that contains at least one zeolite. The conversion of products that have a boiling point of less than 150° C. is, throughout the two stages of hydrocracking and hydrorefining, less than 40% by weight and, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the hydrocracking stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.Type: ApplicationFiled: February 19, 2003Publication date: August 19, 2004Applicant: Institut Francais du PetroleInventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Pierre Marion
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Publication number: 20040159582Abstract: A process for producing a premium Fischer-Tropsch diesel fuel which comprises (a) hydroprocessing a waxy Fischer-Tropsch feed to remove the oxygenates that are present in the feed, whereby a first Fischer-Tropsch intermediate product is produced with reduced olefins and oxygenates relative to the Fischer-Tropsch feed; (b) separating the first Fischer-Tropsch intermediate product in a separation zone into a heavy Fischer-Tropsch fraction and a light Fischer-Tropsch fraction under controlled separation conditions; (c) hydroisomerizing the heavy Fischer-Tropsch fraction to improve the cold flow properties of the heavy Fischer-Tropsch fraction and recovering an isomerized heavy Fischer-Tropsch fraction; (d) mixing the isomerized heavy Fischer-Tropsch fraction with at least a portion of the light Fischer-Tropsch fraction of (b); and (e) recovering from the blend a Fischer-Tropsch derived diesel product meeting a target value for at least one pre-selected specification for diesel fuel.Type: ApplicationFiled: February 18, 2003Publication date: August 19, 2004Inventors: Christopher A. Simmons, David R. Johnson, Jerome F. Mayer, John M. Rosenbaum
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Patent number: 6776898Abstract: A novel process for forming hydrocarbon waxes from synthesis gas is disclosed. This invention teaches a process whereby a Fischer-Tropsch wax can be formulated such that the wax softness as defined by ASTM Standard Test Method for Needle Penetration of waxes (ASTM D-1321) can be adjusted to within a region most preferred for end use applications while simultaneously removing undesirable impurities, such as oxygenates (e.g., primary alcohols), olefins, and trace levels of aromatics. In a Fischer-Tropsch reactor, Fischer-Tropsch wax is formed from synthesis gas in a catalyzed reaction. The Fischer Tropsch wax is then subjected to a relatively mild hydroprocessing over a hydroisomerization catalyst under conditions such that essentially no boiling point conversion is obtained, but yet chemical conversions (e.g., hydrogenation and mild isomerization) occur yielding a high purity, hydrocarbon wax product of reduced hardness.Type: GrantFiled: April 4, 2000Date of Patent: August 17, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Robert J. Wittenbrink, Daniel Francis Ryan
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Publication number: 20040144691Abstract: A process to prepare a base oil starting from a slack wax containing feedstock by (a) contacting the feedstock in the presence of hydrogen with a sulphided hydrodesulphurisation catalyst having nickel and tungsten on an acid amorphous silica-alumina carrier and (b) performing a pour point reducing step on the effluent of step (a) to obtain the base oil.Type: ApplicationFiled: December 5, 2003Publication date: July 29, 2004Inventors: Gerard Benard, Eric Duprey, Johannes Anthonius Robert Van Veen
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Publication number: 20040138059Abstract: This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them.Type: ApplicationFiled: October 30, 2003Publication date: July 15, 2004Inventors: Patrick Euzen, Carole Bobin, Magalie Roy-Auberger, Eric Benazzi, Patrick Bourges, Christophe Gueret
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Publication number: 20040118745Abstract: A novel apparatus for producing sweet synthetic crude from a heavy hydrocarbon feed comprising: an upgrader for receiving said heavy hydrocarbon feed and producing a distillate fraction including sour products, and high-carbon content by-products; a gasifier for receiving the high-carbon content by-products and producing synthetic fuel gas and sour by-products; a hydroprocessing unit for receiving the sour by-products and hydrogen gas, thereby producing gas and sweet crude; and a hydrogen recovery unit for receiving said synthetic fuel gas and producing further hydrogen gas and hydrogen-depleted synthetic fuel gas, said further hydrogen gas being supplied to said hydroprocessing unit.Type: ApplicationFiled: February 4, 2004Publication date: June 24, 2004Inventors: Philip Rettger, Randall Goldstein, Jim Arnold, Yoram Bronicki, J Robert Friday
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Publication number: 20040112792Abstract: A method to produce high quality lube oil products involving hydrotreating a waxy feed to produce a hydrotreated feed and subsequently hydroisomerizing and hydrodewaxing the hydrotreated waxy feed.Type: ApplicationFiled: October 14, 2003Publication date: June 17, 2004Inventors: William J. Murphy, Ian A. Cody, Bernard G. Silbernagel
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Publication number: 20040108248Abstract: A method to produce high quality lube oil products involving hydrotreating a waxy feed to produce a hydrotreated feed and subsequently hydrodewaxing the hydrofinishing the waxy feed.Type: ApplicationFiled: October 3, 2003Publication date: June 10, 2004Inventors: Ian A. Cody, William J. Murphy
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Publication number: 20040108246Abstract: A waxy hydrocarbon feed is catalytically dewaxed with a catalyst that has been selectively activated. The selective activation of the catalyst involves contacting the dewaxing catalyst with a feed mixture containing waxy hydrocarbon and at least one oxygenate. The process results in improved catalyst performance resulting in improved yield of isomerate at equivalent pour.Type: ApplicationFiled: October 3, 2003Publication date: June 10, 2004Inventors: Ian A. Cody, William J. Murphy, Sylvain S. Hantzer
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Publication number: 20040108250Abstract: An integrated process is disclosed for dewaxing hydrocarbon feedstocks in a sour environment. The process includes hydrotreating, dewaxing, hydrofinishing or combination thereof wherein there is no disengagement between any of the process steps.Type: ApplicationFiled: October 3, 2003Publication date: June 10, 2004Inventors: William J. Murphy, Ian A. Cody, Jacob B. Angelo, Zhaozhong Jiang, Jeffrey C. Trewella
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Publication number: 20040108249Abstract: A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreating step is under conditions such that the amount of conversion to 343° C. minus is less than 5 wt. % of the feedstock and the VI increase is less than 4 VI over the feedstock. Hydrodewaxing uses a low alpha catalyst and hydrofinishing is accomplished with a catalyst based on the M41S family.Type: ApplicationFiled: October 3, 2003Publication date: June 10, 2004Inventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer, David W. Larkin, John E. Gallagher, Jeenok T. Kim
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Publication number: 20040079677Abstract: This invention is directed to a process for hydroprocessing vacuum gas oils and other feeds in order to produce unconverted oil suitable for use as base oil feed for white oils, Group III oils, and BMCI (Bureau of Mines Correlation Index) ethylene plant feed. Ammonia, hydrogen sulfide, and light products are removed from the first stage at high pressure in order to produce a higher quality of unconverted oil that is suitable for Group III base oils.Type: ApplicationFiled: October 28, 2002Publication date: April 29, 2004Inventor: Darush Farshid
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Patent number: 6726836Abstract: A fuel processing method is operable to remove substantially all of the sulfur present in an undiluted hydrocarbon fuel stock supply which is used to power a fuel cell power plant in a mobile environment, such as an automobile, bus, truck, boat, or the like; or in a stationary environment. The power plant hydrogen fuel source can be gasoline, diesel fuel, or other like fuels which contain relatively high levels of organic sulfur compounds such as mercaptans, sulfides, disulfides, thiophenes and the like. The undiluted hydrocarbon fuel supply is passed through a nickel reactant desulfurizer bed wherein essentially all of the sulfur in the organic sulfur compounds reacts with the nickel reactant, and is converted to nickel sulfide, while the now desulfurized hydrocarbon fuel supply continues through the remainder of the fuel processing system. The method involves adding hydrogen to the fuel stream prior to the desulfurizing step. The method can be used to desulfurize either a liquid or a gaseous fuel stream.Type: GrantFiled: September 1, 2000Date of Patent: April 27, 2004Assignee: UTC Fuel Cells, LLCInventors: Roger R. Lesieur, Brian A. Cocolicchio, Antonio M. Vincitore
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Patent number: 6723229Abstract: A four stage process for producing high quality white oils, particularly food or medicinal grade mineral oils from mineral oil distillates. The first reaction stage employs a sulfur resistant hydrotreating catalyst and produces a product suitable for use as a high quality lubricating oil base stock. The second reaction stage employs a hydrogenation/hydrodesulfurization catalyst. The third stage employs a reduced metal sulfur sorbent producing a product stream which is low in aromatics and which has substantially “nil” sulfur. The final reaction stage employs a selective hydrogenation catalyst that produces a product suitable as a food or medicinal grade white oil.Type: GrantFiled: February 27, 2002Date of Patent: April 20, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Sylvain S. Hantzer, Jean Willem Beeckman, Stephen J. McCarthy, Arthur Paul Werner
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Publication number: 20040065587Abstract: A process to prepare a base oil having a saturates content of more than 90 wt %, a sulphur content of less than 0.Type: ApplicationFiled: October 16, 2003Publication date: April 8, 2004Inventors: Marc Collin, Eric Duprey
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Publication number: 20040050753Abstract: The invention concerns a process for moderate pressure hydrocracking (i.e., at a hydrogen partial pressure of more than 70 bars and at most 100 bars) with a conversion of at least 80% by volume, of a feed with a T5 temperature in the range 250° C. to 400° C. and a T95 temperature of at most 470° C. (T5 and T95 measured in accordance with ASTM-D2887), to produce a diesel with a 95% distillation point of less than 360° C., a sulphur content of at most 50 ppm and a cetane number of more than 51. The process operates with or without a recycle of the liquid effluent. Highly advantageously, it can be integrated into a refinery layout comprising catalytic cracking.Type: ApplicationFiled: September 22, 2003Publication date: March 18, 2004Inventors: Pierre Marion, Eric Benazzi, Didier Duee, Christophe Gueret, Alain Billon
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Patent number: 6702936Abstract: A novel apparatus for producing sweet synthetic crude from a heavy hydrocarbon feed comprising: an upgrader for receiving said heavy hydrocarbon feed and producing a distillate fraction including sour products, and high-carbon content by-products; a gasifier for receiving the high-carbon content by-products and producing synthetic fuel gas and sour by-products; a hydroprocessing unit for receiving the sour by-products and hydrogen gas, thereby producing gas and sweet crude; and a hydrogen recovery unit for receiving said synthetic fuel gas and producing further hydrogen gas and hydrogen-depleted synthetic fuel gas, said further hydrogen gas being supplied to said hydroprocessing unit.Type: GrantFiled: December 26, 2001Date of Patent: March 9, 2004Assignee: Ormat Industries Ltd.Inventors: Philip Rettger, Randall Goldstein, Jim Arnold
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Publication number: 20040040888Abstract: This invention relates to an improved process for hydrocracking into a stage of hydrocarbon feedstocks, using in a first reaction zone a pretreatment catalyst that exhibits a low acidity according to a standard activity test and an amorphous acid catalyst for hydrocracking that is free of zeolite in a second reaction zone that is located downstream from the first.Type: ApplicationFiled: June 6, 2003Publication date: March 4, 2004Inventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Tivadar Cseri, Hugues Dulot
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Publication number: 20040031725Abstract: According to the method of manufacturing refined oil of the present invention, refined oil which has a viscosity of 20 cst or lower at 135° C., a pour point of 30° C. or lower, an alkali metal content of 1 wt ppm or less, a vanadium content of 10 wt ppm or less and a sulfur content of 0.3 wt % or lower can be prepared, by bringing feed oil into contact with hydrogen in the presence of the demetalizing/desulfurizing catalyst 3 and the hydrogenolysis catalyst 5. This method can decrease the viscosity, pour point and sulfur concentration of the refined oil to sufficiently low levels, and decreases the production cost.Type: ApplicationFiled: September 8, 2003Publication date: February 19, 2004Inventors: Shigeki Nagamatsu, Makoto Inomata, Susumu Kasahara
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Publication number: 20040020825Abstract: Process for transforming a gas oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a subsequent stage, whereby the latter uses a catalyst that is selected from the group that consists of hydrorcfining catalysts and catalysts that comprise at least one mixed oxide, a metal of group VIB, and a non-noble metal of group VIII. The conversion of products that have a boiling point of less than 150° C. is, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the subsequent stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.Type: ApplicationFiled: February 19, 2003Publication date: February 5, 2004Applicant: Institut Francais du PetroleInventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Pierre Marion
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Patent number: 6676829Abstract: A method is provided for removing sulfur from an effluent produced by hydrotreating a hydrocarbon feed, said effluent having a heavy fraction containing polyaromatic sulfur compounds and a lighter fraction, said method comprising contacting the effluent with a noble metal containing hydrodearomatization catalyst on a support under super-atmospheric hydrogen pressure and reaction conditions sufficient to hydrogenate at least one ring of said polyaromatic sulfur compounds and thereby produce a product with a reduced sulfur content.Type: GrantFiled: December 8, 1999Date of Patent: January 13, 2004Assignee: Mobil Oil CorporationInventors: Philip J. Angevine, Anna B. Gorshteyn, Larry A. Green, Yuk Mui Louie, David A. Pappal, Peter J. Owens, Richard J. Quann, Jolie A. Rhinehart
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Publication number: 20040004021Abstract: The present invention concerns an improved procedure for producing basic oils and in particular very high quality oils, i.e. oils possessing a high viscosity index (VI), a low aromatics content, good UV stability and a low pour point, from oil cuts having an initial boiling point higher than 340° C., possibly with simultaneous production of middle distillates (in particular gasoils and kerosene) of very high quality, i.e. having a low aromatics content and a low pour point.Type: ApplicationFiled: July 14, 2003Publication date: January 8, 2004Inventors: Eric Benazzi, Christophe Gueret, Pierre Marion, Alain Billon
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Patent number: 6669872Abstract: An electrical oil having reduced gassing tendency includes a major amount of a paraffinic or naphthenic basestock and a blend of certain hindered phenols, especially a blend of 2,6-di-t-butyl phenol and 2,6-di-t-butyl cresol. A further enhanced gassing tendency can be provided to the electrical oil by including a tolyltriazole derivative.Type: GrantFiled: July 13, 2001Date of Patent: December 30, 2003Assignee: ExxonMobil Research and Engineering CompanyInventors: Christopher Jeffrey Still Kent, Jacob B. Angelo
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Patent number: 6656342Abstract: A method for hydroprocessing hydrocarbon products, preferably Fischer-Tropsch products, and a reactor useful for performing the method, are disclosed. The reactor includes one or more first catalyst beds comprising a catalyst useful for conducting relatively severe hydroprocessing and one or more second catalyst beds comprising a catalyst useful for conducting relatively mild hydroprocessing. The second catalyst beds are located at a position in the reactor where they can receive the products from the first catalyst bed(s), at least one of each of the first and second catalyst bed(s) comprises a catalyst grading scheme sufficient to remove at least a portion of any particulates from their respective feeds, and the reactor is set up to receive hydrocarbon feeds at a position above or within the first catalyst bed(s) and above or within the second catalyst bed(s).Type: GrantFiled: April 4, 2001Date of Patent: December 2, 2003Assignee: Chevron U.S.A. Inc.Inventors: Ben D. Smith, Richard O. Moore, Jr.
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Patent number: 6656343Abstract: The invention provides a process for the production of a synthetic naphtha fuel suitable for use in compression ignition (CI) engines, the process including at least the steps of hydrotreating at least a fraction of a Fischer-Tropsch (FT) synthesis reaction product of CO and H2, or a derivative thereof, hydrocracking at least a fraction of the FT synthesis product or a derivative thereof, and fractionating the process products to obtain a desired synthetic naphtha fuel characteristic. The invention also provides a synthetic naphtha fuel made by the process as well as a fuel composition and a Cloud Point depressant for a diesel containing fuel composition, said fuel composition and said depressant including the synthetic naphtha of the invention.Type: GrantFiled: October 5, 2001Date of Patent: December 2, 2003Assignee: Sasol Technology (Pty) Ltd.Inventor: Luis Pablo Dancuart