Abstract: An electrical insulating oil having excellent oxidation stability, thermal stability and/or hydrogen absorbability consisting essentially of (A) a base hydrocarbon oil obtained by hydrofining and then dewaxing a fraction boiling at 280.degree.-400.degree. derived from a paraffin or mixed base crude oil, (B) a highly aromatic hydrocarbon oil obtained by hydrofining and/or distilling a heavy hydrocarbon fraction boiling at 250.degree.-400.degree. C produced as a by-product at the time of catalytically reforming naphtha or the like and, if desired, (C) an oil obtained by treating a lubricating oil fraction boiling at 230.degree.-500.degree. C derived from a crude petroleum oil.
Abstract: A low sulfur coke product is obtained in an integrated fluid coking and gasification process in which an oxygen-containing gas is introduced into the upper portion of the gasification zone and steam is introduced into the lower portion of the gasification zone. The desired degree of coke desulfurization is controlled by controlling the thickness of the gasifier coke layer on the gaseous reactor leaving solids per pass.
Abstract: A process for hydrotreating middle distillate fraction petroleum feed stocks wherein hydrogen requirements for the hydrotreater are reduced by first passing the feed stock and steam to a steam hydroconversion zone over a dual function catalyst comprising molybdenum on a chromium supported on ferric oxide support or on a high surface area alumina support. In the steam hydroconversion zone a portion of the feed reacts with the steam to produce hydrogen via a steam reforming reaction. This hydrogen is used in situ to saturate a substantial portion of the olefins and remove some of the sulfur compounds present in the feed stock, thereby partially refining same. The partially refined feed is then passed to a hydrotreating zone for further treatment with greatly reduced hydrogen requirements in said hydrotreating zone.
Abstract: A process for producing a low sulfur content fuel oil in a high yield from a starting oil having a high sulfur content, which comprises (1) treating a residual petroleum oil with hydrogen at a temperature of about 350.degree. to 450.degree. C and a pressure of about 50 to 200 Kg/cm.sup.2 at a liquid hourly space velocity of about 0.2 to 4 l/H.l in the presence of a catalyst, (2) introducing an inert gas or steam at a temperature of about 400.degree. to 900.degree.C and pyrolyzing the treated oil at a temperature of about 350.degree. to 500.degree.C and at a pressure of about atmospheric pressure to 100 Kg/cm.sup.2 with a residence time of about 0.5 to 10 hours, and (3) hydrodesulfurizing the pyrolyzed oil at a temperature of about 300.degree. to 400.degree.C and a pressure of about 30 to 100 Kg/cm.sup.2 at a liquid hourly space velocity of about 0.5 to 4 l/H.l in the presence of a desulfurizing catalyst.
Abstract: In producing low sulfur fuel oil by the ebullated bed hydroconversion of petroleum residue, the resulting heavy vacuum bottoms sulfur-containing residue material is utilized to produce hydrogen. The residue material from the hydroconversion operation is gasified to provide a fuel gas, which is then used to fire a steam-methane reformer. The chemical requirements for hydrogen production are met by feeding a portion of light gaseous products from the hydroconversion step to the catalytic side of the steam-methane reformer. A low sulfur fuel oil distillate product is recovered from the reactor effluent streams and can be further hydrotreated as desired. Thus, all hydrogen required in the H-Oil reactor for hydroconversion and desulfurization is ultimately produced from the residual oil feed material, by using the heavy product residue material to produce a fuel gas and converting the light hydrocarbons to hydrogen.
Type:
Grant
Filed:
February 15, 1974
Date of Patent:
August 3, 1976
Assignee:
Hydrocarbon Research, Inc.
Inventors:
Ronald H. Wolk, Axel R. Johnson, Govanon Nongbri
Abstract: A heat soaked polymer by-product from the production of gasoline using the 90.degree.-400.degree.F. steam cracker naphtha as feed is upgraded by first subjecting the same to a thermal polymerization and then subjecting the thermal polymerization product to a hydrotreating or hydrogenation step or both. Generally, the hydrotreatment is accomplished at relatively mild conditions so as to avoid any change in aromatic ring structure. Hydrogenation, on the other hand, is accomplished at more severe conditions so as to effect hydrogenation of the aromatic rings. In those cases where a mild hydrotreatment only is used, the products obtained are, generally, useful as aromatic oils of light color. Where more severe hydrogenation is used, on the other hand, the products are useful as naphthenic oils.