Diffusing Or Passing Through Septum Selective As To Material Of A Component In Liquid/liquid Solvent Or Colloidal Extraction Patents (Class 210/644)
  • Patent number: 5817359
    Abstract: The present invention provides methods and for the dealcoholization of alcohol containing solutions, especially fermented beverages. In preferred embodiments the methods employ a novel controlled-strip evaporative perstraction technique following initial clarification to remove biomass, wherein strip solutions, dealcoholized beverage, or both are recycled for use in the strip solutions for dealcoholization of subsequent batches of feed beverage. In further preferred embodiments additives are introduced into the strip solution to further limit loss of volatile components during perstraction. Biomass removed by the clarification is then returned to the retentate product following perstration.
    Type: Grant
    Filed: October 11, 1996
    Date of Patent: October 6, 1998
    Assignee: Palassa Pty. Ltd.
    Inventors: Alan Sherman Michaels, R. Philip Canning, Paul Hogan
  • Patent number: 5817884
    Abstract: A process for preparing aldehydes by hydroformylation of olefinically unsaturated compounds with hydrogen and carbon monoxide in a homogeneous phase in the presence of a catalyst system comprising organometallic complex compounds and ligands of these complex compounds in molar excess, and separating off the catalyst system from the hydroformylation reaction mixture by pressure filtration on a semipermeable membrane of an aromatic polyamide, the mass molar ratio of the ligands present in excess to the aldehydes prepared is 9-30, preferably 10-25, in particular 10-15, with the ligands present in excess not being alkylammonium or arylammonium salts of sulfonated, carboxylated or phosphonated aromatic diphosphines which by maintaining the molar mass ratio, not only are high activation and selectivity values obtained in the hydroformylation itself, but also excellent retention values for the catalyst system are obtained in the membrane filtration step.
    Type: Grant
    Filed: May 14, 1997
    Date of Patent: October 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Helmut Bahrmann
  • Patent number: 5783075
    Abstract: A disposable dialysis apparatus which floats in a dialysate solution. The apparatus has a membrane support ring with a central opening surrounded by a downwardly extending tube. The open bottom of the tube supports a dialysis membrane. After the membrane has been loaded with a sample, the membrane is closed and the apparatus is suspended in the dialysate solution.
    Type: Grant
    Filed: June 23, 1997
    Date of Patent: July 21, 1998
    Assignee: Spectrum Medical Laboratories, Inc.
    Inventors: Roy Eddleman, F. Jesus Martinez, William Martin, Dieter Stute
  • Patent number: 5773667
    Abstract: A process for preparing aldehydes comprising hydroformylating olefinically unsaturated compounds with hydrogen and carbon monoxide in a homogeneous phase in the presence of a catalyst system comprising rhodium complex compounds and aromatic phosphines in a molar excess and separating off the catalyst system from the hydroformylation reaction mixture by pressure filtration on a semipermeable membrane of an aromatic polyamide by carrying out the hydroformylation at a pH of 2.5 to 4.3 using a molar ratio of phosphine:rhodium of at least 60 and at a rhodium concentration of at least 10 ppm by weight, based on the olefinically unsaturated compound used, and using, as aromatic phosphines, special alkylammonium and/or arylammonium salts of sulfonated or carboxylated triarylphosphines which process leads to excellent activities and selectivities in the hydroformylation step itself and also to high retention values in the membrane filtration step.
    Type: Grant
    Filed: May 14, 1997
    Date of Patent: June 30, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Helmut Bahrmann, Thomas Muller, Rainer Lukas
  • Patent number: 5770086
    Abstract: The hydrogel-forming polymers are used as absorbents for collecting and concentrating solutions. A solution to be concentrated can be contained in a dialysis membrane, with the hydrogel-forming polymer, or mixture thereof, on the outer surface of the membrane. A hydrogel-forming polymer can be added directly to the solution to be concentrated and the resulting concentrate separated from the gel by filtration of decanting. A hydrogel-forming polymer can be placed in a container formed of porous material and the container can be added to the solution to be concentrated and physically removed after concentration has occurred. Hydrogel-forming polymer can be used as a liquid collection in diagnostic membrane assay cartridges.
    Type: Grant
    Filed: January 25, 1996
    Date of Patent: June 23, 1998
    Assignee: Eureka| Science Corp.
    Inventors: Andris Indriksons, Patricia C. Andrews
  • Patent number: 5766480
    Abstract: A method is provided for priming a hollow fiber oxygenator which is integrated with a hollow tube heat exchanger. A closed priming circuit is created between a cardiosurgery reservoir, the combined hollow fiber oxygenator and heat exchanger and a vacuum source. Vacuum pressure is applied to the closed priming circuit to evacuate the residual air from the circuit. Priming solution is released from the cardiosurgery reservoir and fills the evacuated closed priming circuit.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: June 16, 1998
    Assignee: Minntech Corporation
    Inventors: Louis C. Cosentino, John E. Briddon, Richard P. Goldhaber, Paul H. Hess
  • Patent number: 5744039
    Abstract: Disclosed are a composite semipermeable membrane which is excellent in the chlorine resistance and also gives a high desalting faculty and a large water flux, in particular, under a low operation pressure and a production method thereof. The composite semipermeable membrane comprises a porous base material having formed thereon a semipermeable thin film formed by crosslinking polymerization of 2,6-diaminotoluene monomer or a mixture of 2,6-diaminotoluene monomer and other amino compound monomer with a polyfunctional crosslinking agent having at least two functional groups capable of reacting with the amino group(s) of the monomer(s) in one molecule in the presence of an amine salt.
    Type: Grant
    Filed: January 29, 1997
    Date of Patent: April 28, 1998
    Assignee: Nitto Denko Corporation
    Inventors: Hiroki Itoh, Masahiko Hirose, Katsumi Ishii
  • Patent number: 5744042
    Abstract: The present invention provides a process of separating substances bound to a first protein in a first liquid by means of a membrane separating the first liquid from a second liquid, the process comprising the steps of: a) impregnating the membrane by passing along the membrane a solution comprising a first acceptor protein having an acceptor function for the substances to be separated; b) dialyzing the first liquid against the second liquid, the second liquid comprising a second acceptor protein having an acceptor function for the substances to be separated, wherein the membrane separating the first and second liquids contains tunnel-like structures that permit passage of the substances to be separated to the second liquid but exclude passage of the first protein and the second acceptor protein.
    Type: Grant
    Filed: December 12, 1995
    Date of Patent: April 28, 1998
    Inventors: Jan Stange, Steffen Mitzner, Wolfgang Ramlow
  • Patent number: 5741424
    Abstract: Oxygen transfer to blood plasma in a blood oxygenator using a microporous membrane exposed to blood on one side and to oxygen on the other is facilitated by bonding an oxygen-carrying chemical such as hematin or a perfluorocarbon to at least the blood-contacting surface of the membrane.
    Type: Grant
    Filed: April 30, 1996
    Date of Patent: April 21, 1998
    Assignee: Medtronic, Inc.
    Inventors: Sean D. Plunkett, Henry W. Palermo
  • Patent number: 5736050
    Abstract: Current fluctuations typical of those observed with biological channels which are ion selective and inhibited by divalent cations and protons have been observed in synthetic membranes, and a process for controlling permeability of a synthetic membrane to ions and uncharged molecules may be used in a switch or sensor, for example to monitor the content of a solution, to trigger macroscopic events by local microscopic changes and to alter the ionic content of a solution e.g. desalination.
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: April 7, 1998
    Assignee: St. George's Hospital Medical School
    Inventors: Charles A. Pasternak, Charles L. Bashford, Donald T. Edmonds, Adolf A. Lev
  • Patent number: 5714072
    Abstract: The instant invention is directed to a method of solvent extraction. The steps of the method include: providing a dual-skinned asymmetric membrane; providing a feed containing a solute; and providing a solvent. The feed and the solvent are contacted across the membrane. The solute of the feed is extracted, and forming thereby a raffinate and an extract.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: February 3, 1998
    Assignee: Hoechst Celanese Corporation
    Inventors: Bradley W. Reed, Kamalesh K. Sirkar
  • Patent number: 5660722
    Abstract: Described is a hemo(dia)filtration apparatus (10) with two blood filters (60) and (12) connected in series and a sterile filter (38) connected upstream thereof. The first chambers (64) and (14) and the second chambers (68) and (16) of both blood filters (60) and (12) are connected to one another, respectively, by connecting lines (72) and (74). A means (76) is arranged in one of the connecting lines (72) and (74), which generates a positive transmembrane pressure in the direction of the blood path in one of the blood filters (60, 12) and a negative transmembrane pressure in the direction of the blood path (80) in the other blood filter (12, 60). This eliminates a costly substituate line with additional devices arranged therein, since the dialyzer fluid is passed as a substituate solution through the membrane of the one blood filter directly into the blood. Furthermore, with the use of suitable devices it is possible to precisely determine and individually adjust the filtrate and substituate flows.
    Type: Grant
    Filed: July 11, 1995
    Date of Patent: August 26, 1997
    Assignee: Fresenius AG
    Inventor: Bernd Nederlof
  • Patent number: 5646205
    Abstract: An ionomer for an ion complex membrane useful for the separation of water-organic solvent by osmosis or low pressure osmosis as well as by pervaporation and a method for producing ion complex membrane therefrom are disclosed. The ionomer for producing ion complex membrane can be prepared by heat polymerization of an alkyl compound having pyridyl groups such as 1,3-di(4-pyridyl) propane at both terminal ends with a dihaloalkane compound such as dibromooctane and dichloroheptane having two halogen atoms at both terminal ends or with one or two halogen atoms affixed to intermediate carbon atoms in a polar solvent such as acrylonitrile. An ion complex membrane can be produced by preparing a membrane of a polycation or polyanion in a solution casting method and dipping the membrane in a solution of polycation or polyanion for 24 hours to give an ion complex membrane. This ion complex membrane may be a single membrane or composite membrane. Composite membrane includes a plain membrane and a hollow fiber membrane.
    Type: Grant
    Filed: June 14, 1995
    Date of Patent: July 8, 1997
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Kew Ho Lee, Jung Hoon Kim, Jong Geon Jegal
  • Patent number: 5637224
    Abstract: A vaporizable solute transfer system for transferring a vaporizable solute from an aqueous feed solution to an extractant liquid comprises a fluid tight housing, a porous membrane which divides the housing into a feed solution chamber and an extractant chamber, and a vacuum atmosphere chamber formed of a nonporous material. The housing has feed solution inlet and outlet ports which communicate with the feed solution chamber, an extraction inlet port which communicates with the extractant chamber, and a vacuum outlet port which communicates with the vacuum atmosphere chamber. The vaporizable solute transfer system also includes a pressure difference control means for maintaining a difference between a liquid pressure of a feed solution chamber and a liquid pressure of an extractant liquid in the extractant chamber substantially within a predetermined pressure range so that an interface between the feed solution and the extractant is substantially immobilized at the membrane.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: June 10, 1997
    Assignee: New Jersey Institute Of Technology
    Inventors: Kamalesh K. Sirkar, Dali Yang, Sudipto Majumdar, Suphan Kovenklioglu, Amitava Sengupta
  • Patent number: 5597486
    Abstract: A membrane-based tangential flow filtration system is disclosed which includes optimized performance capabilities by taking into account the variety of flux and component passage behavior occurring during filtration processing. The system maximizes the recovery of a desired component in the permeate from a sample solution containing two or more components, in minimum time and with minimum filtration area, by optimizing the mass flux of the desired component by continuously controlling the rate of addition of a diafiltrate solution to the system to maintain the optimum balance of component concentrations.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: January 28, 1997
    Assignee: Millipore Investment Holdings Limited
    Inventor: Herb Lutz
  • Patent number: 5589071
    Abstract: The present invention relates to an anion-exchange membrane extractor for boric acid separation, which is capable of separating boric acid from the radioactive liquid waste concentrated by evaporation of the radioactive liquid waste produced in the pressurized light water reactor and a method of separating boric acid from the radioactive liquid waste employing the extractor. The onion-exchange membrane extractor for boric acid separation which comprises: an upper cell being equipped with an inlet, an outlet, and fluid-injecting holes; a concentrate cell, an extract cell and a lower cell, each of which is equipped with an inlet, an outlet, fluid-injecting holes, and a supporting shelf on the upper layer; a.
    Type: Grant
    Filed: July 14, 1995
    Date of Patent: December 31, 1996
    Assignee: Korea Advanced Institute of Science and Technology
    Inventors: Kun-Jai Lee, Jong-Kil Park
  • Patent number: 5567388
    Abstract: An inorganic carbon removing part defined by has a double tube structure formed by an inner tube of polytetrafluoroethylene having continuous pores and an outer tube of resin. An acidified sample solution is guided into the inner tube and an alkalified sample solution is guided into the outer tube, and inorganic carbon contained in the acidified sample solution is outwardly moved toward the alkalified sample solution to be removed. The acidified sample solution, from which inorganic carbon is removed, is injected into a combustion tube, so that a carbon component contained in the sample solution is converted into carbon dioxide and detected by a detecting part. Since the alkalified sample solution contains purgeable organic carbon components of the same concentration as the acidified sample solution, the content of total organic carbon is correctly measured with no loss of the purgeable organic carbon components.
    Type: Grant
    Filed: September 8, 1995
    Date of Patent: October 22, 1996
    Assignee: Shimadzu Corporation
    Inventors: Youzo Morita, Keiji Inoue
  • Patent number: 5562828
    Abstract: Spent acid contaminated with metal salts in a hot solution removed from a metal pickling bath is directed to one side of an anionic membrane to separate acid ions from the metal salt solution by diffusion dialysis through the membrane. Most of the metal salts in the remaining low acidity mother liquor are crystallized by refrigerating the mother liquor. The crystals are dewatered (in a centrifuge, for example) to produce a commercially viable noncorrosive byproduct, and the substantially decontaminated mother liquor is directed to the opposite side of the diffusion membrane, where it receives the acid ions diffusing through the membrane, and is then recycled to the pickling bath. Heat interchange between the hot spent acid solution and the recycled acid lowers the temperature of the spent acid to an optimum value for dialysis while raising the temperature of the recycled acid to close to the bath temperature.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: October 8, 1996
    Inventors: Douglas R. Olsen, Daniel E. Bailey
  • Patent number: 5547579
    Abstract: Acids contaminated with multi-valent metal salts are purified by a process which involves treatment in an acid sorption unit (ASU) and a nanofiltration unit (NFU). The feed solution can first be delivered to the ASU, which produces two solutions, one high in acid concentration and the other high in metal salt concentration. The high acid concentration solution can be treated in the NFU to produce an acid end product and a reject metal salt solution which can be recirculated to the feed of the NFU. Alternatively, the high metal salt solution can be treated in the NFU, and its permeate recirculated to the ASU as eluate. In an alternative configuration, the feed is delivered first to the NFU. In all cases, the membrane reject solution from the NFU is recirculated to increase the metal salt concentration. A second NFU can be used to process the solution from the ASU which contains a high metal salt concentration.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: August 20, 1996
    Assignee: Eco-Tec Limited
    Inventor: Craig J. Brown
  • Patent number: 5520813
    Abstract: A process for separating monovalent ions from a sodium-bearing radioactive waste stream which comprises contacting the sodium-bearing radioactive waste stream against at least one ion exchange membrane having permselectivity for monovalent ions wherein the monovalent ions permeate or diffuse across the ion exchange membrane to form a permeate of a monovalent ion-enriched stream and wherein a retentate is formed from the sodium-bearing radioactive waste stream which is substantially depleted of monovalent ions.
    Type: Grant
    Filed: January 23, 1995
    Date of Patent: May 28, 1996
    Inventors: Amos Korin, Netta Korin
  • Patent number: 5512181
    Abstract: The-silica content of cooling water blow-down waters is reduced by contacting these waters with a colloidal alumina which adsorbs a portion of the silica. The blow-down is then dialyzed to produce a permeate having a reduced silica content. In a preferred embodiment of the invention the permeate is recycled.
    Type: Grant
    Filed: November 1, 1993
    Date of Patent: April 30, 1996
    Assignee: Nalco Chemical Company
    Inventor: Stephen A. Matchett
  • Patent number: 5509895
    Abstract: An anticoagulant composition for a blood dialysis circuit contains a fatty acid derivative in liquid form at ambient temperature, and an antioxidant. The antioxidant is contained in an amount of 0.0001 to 5.0 parts by weight relative to 100 parts by weight of the fatty acid derivative. An air trap chamber device for a blood dialysis circuit contains a vessel for storing blood dialysed by a dialysis unit, an inlet tube for introducing the blood treated with dialysis into a liquid in the vessel selected from the group consisting of a layer of the aforementioned anticoagulant composition, and the blood, a measurement unit for measuring the pressure of air in the vessel lying above the layer of the anticoagulant composition, an adjustment unit for adjusting the pressure of the air and an outlet tube for conducting the blood treated with dialysis out of the vessel.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 23, 1996
    Assignee: NOF Corporation
    Inventors: Yasuhisa Noguchi, Toshio Kasama
  • Patent number: 5510035
    Abstract: The present invention relates to a method of processing white liquor (3) obtained from the causticization step of a pulp mill, in which method infeed white liquor (3) principally contains sodium hydroxide (6) and sodium sulfide (7). The method according to the invention is characterized in that the sodium hydroxide (6) contained in the white liquor (3) is separated from the white liquor (3) either entirely or partly by means of a diffusion dialysis membrane process (4). The invention is further characterized in that the sodium hydroxide (6) separated from the white liquor (3) is advantageously entirely returned back to the chemical circulation of the pulp mill.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: April 23, 1996
    Assignee: Enso-Gutzeit Oy
    Inventors: Marjo Toronen, Hannu Kurittu
  • Patent number: 5503749
    Abstract: A process for the purification of aqueous solutions of amine-oxides, characterized in that said solutions are contacted with an aqueous purification solution of an alkali hydroxide and/or ion pair reagent by means of an anion active membrane. By means of the process according to the invention, an efficient separation, particularly of anions of lower carboxylic acids and inorganic acids, can be achieved.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: April 2, 1996
    Assignee: Lenzinc Aktiengesellschaft
    Inventors: Johann Manner, Heinrich Firgo, Wolfram Kalt, Werner Richardt
  • Patent number: 5503741
    Abstract: A device for the dialysis of a sample. The device embodies a hermetically sealed sample chamber formed by a gasket with dialysis membranes affixed to each side in substantially parallel relationship. The gasket is impermeable to the sample being dialyzed, but is penetrable and reusable such that a needle or the like can be inserted through the gasket into the chamber and then withdrawn without sample being permitted to leak. The gasket is of sufficient thickness to accommodate insertion of a needle. In a further embodiment, the device is fitted into a rigid housing containing windows exposing the dialysis membranes and further containing a channel parallel to the dialysis membranes for directing a needle into the gasket in a direction substantially perpendicular to the edge of the gasket so that the needle can access the chamber without contacting the surfaces of the membranes.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: April 2, 1996
    Assignee: Pierce Chemical Company
    Inventor: Carl Clark
  • Patent number: 5498339
    Abstract: A fluid mixture from which an unsaturated hydrocarbon has to be separated, is passed in the first stage at superatmospheric pressure to one side of a first semiselective gas separation membrane with a non-porous active layer, and a liquid complexing agent is passed along the other side of said first membrane, where said unsaturated hydrocarbon is bound through complexation in the interface of membrane and complexing agent. In the second stage said unsaturated hydrocarbon is dissociated from the complexing agent through temperature increase, the mixture of complexing agent and dissociated unsaturated preferably is passed at superatmospheric pressure to one side of a second semiselective membrane with a non-porous active layer and the unsaturated hydrocarbon migrates to the other side of the membrane and is discharged. Finally, the complexing agent is recycled.
    Type: Grant
    Filed: July 15, 1994
    Date of Patent: March 12, 1996
    Assignees: DSM N.V., Nederlandse Organisatie Voor Toegepast Natuurwetenschappelljk Onderzoek Tno
    Inventors: Raimond J. M. Creusen, Everardus C. A. Hendriks, Jan H. Hanemaaijer
  • Patent number: 5498823
    Abstract: This invention relates to a method for effectively separating an unsaturated hydrocarbon from a feedstock containing at least two similar unsaturated hydrocarbons comprising passing the feedstock over one side of an ionopore membrane charged with a facilitator having an affinity for each of the at least two similar unsaturated hydrocarbons and recovering from a second side of the membrane permeate containing predominantly one of the at least two similar unsaturated hydrocarbons, the similar unsaturated hydrocarbons being selected from the group consisting essentially of aromatic, alkene, and diene hydrocarbons.This invention further relates to a method for achieving liquid phase separation of at least two competing components from a feedstock containing the components such that the separation factor for the competing components is at least about 4 times the separation factor calculated when permeating single components using the same membrane and under the same conditions.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: March 12, 1996
    Assignee: Regents of the University of Colorado
    Inventors: Richard D. Noble, Paul M. Thoen, Carl A. Koval
  • Patent number: 5487831
    Abstract: Carbon clusters, such as C.sub.60 and C.sub.70 fullerenes are separated by means of a recognition selector having the formula: ##STR1## wherein R.sub.1 is ##STR2## wherein R.sub.2 is O, S or NR.sub.12 wherein R.sub.12 is independently hydrogen or P.dbd.O with the proviso that when R.sub.12 is P.dbd.O, then only one such group is present and all R.sub.2 's are additionally bonded to R.sub.12,R.sub.4 is independently O, S or NH,R.sub.3 and R.sub.5 are each independently hydrogen or lower alkyl,n and o are each independently zero, 1, 2 or 3,p, q, r, s and t are each independently zero or 1,Ar is a monocyclic or ortho-fused polycyclic aromatic moiety having up to 10 carbon atoms, either of which may be unsubstituted or substituted with one or more lower alkyl, NO.sub.2, N(R.sub.6).sub.3.sup.30, CN COOR.sub.7, SO.sub.3 H, COR.sub.8 and OR.sub.9 wherein R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are each independently hydrogen or lower alkyl;W is H or CH.dbd.CH.sub.2 ; andm is 1 to 10.
    Type: Grant
    Filed: March 23, 1994
    Date of Patent: January 30, 1996
    Assignee: Research Corporation Technologies, Inc.
    Inventors: William H. Pirkle, Christopher J. Welch
  • Patent number: 5484531
    Abstract: The intention is a process for removing inorganic salts from aqueous mixtures of organic compositions capable of forming micelles. The aqueous mixture is subjected to ultrafiltration to remove the inorganic salts and recover the organic compositions in the retentate.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: January 16, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Norbert Kuehne, Manfred Biermann, Jochen Jacobs, Ansgar Behler
  • Patent number: 5472613
    Abstract: There is disclosed a method for removing a volatile component from a feed or process stream comprising (1) absorbing or adsorbing the volatile component into an absorbent or adsorbent material in an equilibrium process, wherein feed is pumped through a mixture chamber of a device, wherein the device comprises the mixture chamber and a vapor chamber, wherein the mixture chamber comprises a plurality of films comprising absorbent or adsorbent materials, wherein the film is configured to have a first side communicating with the mixture chamber and a second side communicating with the vapor chamber, and (2) removing the volatile component from the absorbent or adsorbent material by applying heat to the mixture chamber and simultaneously applying a gas phase within the vapor chamber such that the volatile component is collected in a gaseous state in the vapor chamber.
    Type: Grant
    Filed: April 15, 1994
    Date of Patent: December 5, 1995
    Assignee: EnviroSep Inc.
    Inventor: Richard W. Schofield
  • Patent number: 5458848
    Abstract: Method of deodorizing in order to remove malodorous compounds which are present in or formed from a liquid formulation containing at least one compound bearing a thiol functional group, of formula:HS--A--Y--B (I)in which:1) the liquid formulation is placed in contact with an inert membrane which is permeable to the malodorous compounds and impermeable to the compound(s) of formula (I); and2) the malodorous compounds which have passed through the membrane are placed in contact with at least one chemical substance reacting with the said malodorous compounds and/or with at least one physical adsorption substance having a large specific surface area which binds the said malodorous compounds.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: October 17, 1995
    Assignee: L'Oreal
    Inventor: Herve Burgaud
  • Patent number: 5430224
    Abstract: A feed stream comprising a mixture of at least two separable components is separated into a permeate rich in one or more components and a retentate lean in those same components by a process comprising dissolving the feed in a supercritical solvent under supercritical conditions to produce a solution and contacting the solution with a dense, non-porous perstraction membrane having a first and a second surface, said contacting being along a first surface, wherein a portion of the feed dissolves into the first surface of the membrane, migrates through the perstraction membrane under a concentration gradient and emerges from the membrane at the second surface, as a permeate, the permeate being removed from the second surface by use of a sweep fluid comprising a supercritical solvent at supercritical conditions which may be the same as or different from the supercritical solvent in which the feed is dissolved.
    Type: Grant
    Filed: April 15, 1994
    Date of Patent: July 4, 1995
    Assignee: Exxon Research & Engineering Company
    Inventor: Robert C. Schucker
  • Patent number: 5421815
    Abstract: An anticoagulant composition for a blood dialysis circuit contains a fatty acid derivative in liquid form at ambient temperature, and an antioxidant. The antioxidant is contained in an amount of 0.0001 to 5.0 parts by weight relative to 100 parts by weight of the fatty acid derivative. An air trap chamber device for a blood dialysis circuit contains a vessel for storing blood dialysed by a dialysis unit, an inlet tube for introducing the blood treated with dialysis into a liquid in the vessel selected from the group consisting of a layer of the aforementioned anticoagulant composition, and the blood, a measurement unit for measuring the pressure of air in the vessel lying above the layer of the anticoagulant composition, an adjustment unit for adjusting the pressure of the air and an outlet tube for conducting the blood treated with dialysis out of the vessel.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: June 6, 1995
    Assignee: NOF Corporation
    Inventors: Yasuhisa Noguchi, Toshio Kasama
  • Patent number: 5416198
    Abstract: A polycationic system for the removal of polyanions from a fluid medium is formed by, first, activating a biocompatible hydroxylated support with an organic sulfonyl chloride, such as p-toluene-sulfonyl chloride, in the presence of a dialkylamino pyridine activation catalyst, such as 4-dimethylamino-pyridine (DMAP). The activated support is then reacted with a polymer having a polyamide backbone with pendent alkyl amine groups, such as poly-L-lysine (PLL), to form C--N bonds between an activated carbon from the hydroxylated polymer and an amine group from the polymeric polyamide. Finally, any unreacted activated sites on the hydroxylated polymer are capped or removed with an effective amount of capping agent such as a mercapto (--SH), hydroxy (--OH) or amino (--NH.sub.2) containing compound which reacts with the unreacted activated sites. The pendent alkyl amines on the polyamide backbone exist, at the appropriate pH, as polycations.
    Type: Grant
    Filed: February 5, 1993
    Date of Patent: May 16, 1995
    Assignee: Research Medical, Inc.
    Inventors: Christopher G. Anderson, James C. McRea
  • Patent number: 5382365
    Abstract: The present invention relates to a process for at least partial dehydration of an aqueous composition, in which said composition to be dehydrated is brought into contact, through the intermediacy of a microporous hydrophobic membrane, with a receiving phase whose water activity is substantially lower than that of the aqueous composition and in which the aqueous composition, at least partially dehydrated, is recovered. The invention also relates to devices enabling the process to be implemented, especially continuously.
    Type: Grant
    Filed: October 21, 1992
    Date of Patent: January 17, 1995
    Assignee: Cogia
    Inventor: Philippe Deblay
  • Patent number: 5380628
    Abstract: Fine particle photographic coupler dispersions are prepared by forming a dispersion of a photographic coupler, coupler solvent and auxiliary coupler solvent in an aqueous gelatin medium containing at least about 1% by weight of an anionic surfactant selected from the group consisting of alkali metal salts of alkarylene sulfonic acids, alkali metal salts of alkyl sulfates, alkaryl sulfonate salts, and alkyl sulfosuccinates; and washing the dispersion with water for a time sufficient to remove at least one-fourth of the surfactant.
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: January 10, 1995
    Assignee: Eastman Kodak Company
    Inventors: John F. Sawyer, Paul L. Zengerle
  • Patent number: 5324428
    Abstract: A disposable dialysis apparatus suspended in a dialysate solution. The dialysis apparatus has a tubular membrane which is opened at the top and bottom. A closed base member and collar seals the bottom of the tubular membrane. An open upper member and collar is sealed to the top of the tubular membrane, and a cap may be affixed to the top of the open upper member to seal the contents.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: June 28, 1994
    Assignee: Spectrum Medical Industries, Inc.
    Inventor: James E. Flaherty
  • Patent number: 5306427
    Abstract: A process is set forth for the separation of one or more, more permeable components from one or more, less permeable components in a feed stream. The process suggests two membrane separation stages in series wherein the feed is introduced into the low pressure side of the first stage, the permeate stream from the first stage is compressed and introduced into the high pressure side of the second stage and wherein the non-permeate stream from the second stage is recycled to the high pressure side of the first stage.
    Type: Grant
    Filed: July 12, 1993
    Date of Patent: April 26, 1994
    Assignee: Permea, Inc.
    Inventor: Jianguo Xu
  • Patent number: 5300228
    Abstract: A method for separating and recovering an acid, which comprises contacting to one side of a diffusion dialysis membrane an acid solution containing an acid having an acid radical with a formula weight of at most 200 and impurities and to the other side of the membrane water or a dilute acid solution, to separate and recover the acid in the solution, wherein the diffusion dialysis membrane comprises a cation exchange membrane having certain specific properties or comprises a main layer of an anion exchanger and a surface layer of the cation exchange membrane having certain specific properties formed on the main layer at the side of which is contact with the acid solution.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: April 5, 1994
    Assignee: Asahi Glass Company Ltd.
    Inventors: Yoshio Sugaya, Misaki Kanazawa, Haruhisa Miyake
  • Patent number: 5290440
    Abstract: A high performance chiral selector having the formula: ##STR1## wherein Ar is a monocyclic or ortho-fused polycyclic aromatic moiety having up to 10 ring carbon atoms, either of which may be unsubstituted or substituted with one or more C.sub.1 to C.sub.6 alkyl, C.sub.1 to C.sub.6 alkoxy, NO.sub.2, N(R.sub.5).sub.3.sup.+, CN, COOR.sub.6, SO.sub.3 H and COR.sub.7 groups wherein R.sub.5, R.sub.6 and R.sub.7 are each independently hydrogen or C.sub.1 to C.sub.6 alkyl;R.sub.1 and R.sub.2 ar each independently hydrogen, C.sub.1 to C.sub.6 alkyl or phenyl;R.sub.3 and R.sub.4 are each independently C.sub.1 to C.sub.12 alkyl or C.sub.2 to C.sub.12 alkenyl; andm and n are each independently zero or 1, said compound being an R or an S enantiomer or a mixture of R and S enantiomers.
    Type: Grant
    Filed: June 23, 1992
    Date of Patent: March 1, 1994
    Assignee: Research Corporation Technologies, Inc.
    Inventors: William H. Pirkle, Christopher J. Welch, William E. Bowen, Qing Yang
  • Patent number: 5288712
    Abstract: The selectivity of a membrane pervaporation aromatics/non-aromatics separation process is unexpectedly improved by the recycle of permeate to the separation process for co-processing with fresh feed. The selectivity obtained is greater than that achieved by processing either the feed or a recycle permeate stream by itself.
    Type: Grant
    Filed: October 7, 1992
    Date of Patent: February 22, 1994
    Assignee: Exxon Research & Engineering Co.
    Inventor: Tan J. Chen
  • Patent number: 5281430
    Abstract: There is disclosed an osmotic concentration cell wherein the flow chamber of the osmotic concentration cell has a continually changing flow path to provide a region of high turbulence to a semipermeable membrane defining the flow chamber. High turbulence at a first semipermeable membrane interface significantly reduces membrane fouling during osmotic concentration and allows for concentration of products with high suspended solids content. The inventive osmotic concentration cell can be used for a variety of purposes including, for example, producing low alcohol wine, concentrating a thin wine into a premium wine, concentrating a low quality grape juice into a higher quality grape juice for fermenting a more premium wine, concentrating various fruit or vegetable juices, and concentrating various beverages, such as teas or coffee.
    Type: Grant
    Filed: December 8, 1992
    Date of Patent: January 25, 1994
    Assignee: Osmotek, Inc.
    Inventors: John R. Herron, Edward G. Beaudry, Carl E. Jochums, Luis E. Medina
  • Patent number: 5277821
    Abstract: Method and apparatus are provided for accomplishing improved separation and purification of an analyte by mass transfer between immiscible phases employing microporous hollow-fiber membranes. The invention eliminates several problems of the prior art. A number of possible modes of separation by mass transfer are possible according to the invention, including liquid-liquid extraction, back extraction, simultaneous forward and back extraction, gas absorption into a liquid, gas stripping from a liquid and simultaneous gas absorption and stripping.
    Type: Grant
    Filed: August 19, 1991
    Date of Patent: January 11, 1994
    Assignee: SymBiotech Incorporated
    Inventors: Robert W. Coughlin, Edward M. Davis, Pramod Z. Rao
  • Patent number: 5275736
    Abstract: A method and device for producing thermodynamically free iodine in which a source material containing thermodynamically free iodine is introduced to one side of an iodine solving solid barrier through which the thermodynamically free iodine passes by dispersion to the other side of the solid barrier until an equilibrium of thermodynamically free iodine vapor pressure is reached across the barrier. In a preferred embodiment of the invention, the degree to which the thermodynamically free iodine disperses to the other side of the iodine solving barrier may be controlled by means which reduce the vapor pressure of thermodynamically free iodine such as the variation of temperature of the iodine source material or of the other side of the barrier as well as the use of an iodine complexing compound or in combination with the source material.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: January 4, 1994
    Assignee: Iomech Limited
    Inventor: Dennis H. O'Dowd
  • Patent number: 5276244
    Abstract: A process for separating a mixture of aluminum alkyl and alpha-olefin, said process comprising contacting a silica modified inorganic membrane filter with said mixture and recovering, as the permeate, an alpha-olefin fraction which contains a lower concentration of aluminum alkyl than in said mixture, as the retentate, an aluminum alkyl fraction which contains a higher concentration of aluminum alkyl than in said mixture.
    Type: Grant
    Filed: March 30, 1993
    Date of Patent: January 4, 1994
    Assignee: Ethyl Corporation
    Inventors: Kaung-Far Lin, William B. Waites
  • Patent number: 5254258
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: October 19, 1993
    Assignee: Research Corporation Technologies, Inc.
    Inventors: William H. Pirkle, John A. Burke, III
  • Patent number: 5252219
    Abstract: A process is set forth for the separation of one or more, more permeable components from one or more, less permeable components in a feed stream. The process suggests two membrane separation stages in series wherein the feed is introduced into the high pressure side of the first stage, the non-permeate stream from the first stage is introduced into the high pressure side of the second stage and wherein the permeate stream from the second stage is compressed and recycled to the low pressure side of the first stage.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: October 12, 1993
    Assignee: Permea, Inc.
    Inventor: Jianguo Xu
  • Patent number: 5252220
    Abstract: Method and apparatus are provided for accomplishing improved liquid-liquid extraction employing microporous hollow-fiber membranes. A number of possible modes of liquid-liquid extraction are possible according to the invention.
    Type: Grant
    Filed: September 25, 1989
    Date of Patent: October 12, 1993
    Assignee: SymBiotech Incorporated
    Inventors: Robert W. Coughlin, Edward M. Davis
  • Patent number: 5248425
    Abstract: This invention relates to an improved thermite coated molten metal filter. According to the invention, a molten metal filter is coated with an aqueous thermite coating slurry containing oleic acid, water-miscible surfactants, water-soluble binders, and water-soluble dispersants.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: September 28, 1993
    Assignee: Corning Incorporated
    Inventor: Shy-Hsien Wu
  • Patent number: RE35292
    Abstract: Organometallic compounds and/or metal carbonyls are separated from their solutions in organic media with the aid of semi-permeable membranes made of aromatic polyamides.
    Type: Grant
    Filed: January 5, 1994
    Date of Patent: July 9, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Helmut Bahrmann, Michael Haubs, Willi Kreuder, Thomas Muller